@misc{KindelbergerSchmidt2002, author = {Kindelberger, Kilian and Schmidt, Heiko}, title = {Terror, Glaubenskrieg und Fundamentalismus}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-9499}, year = {2002}, language = {de} } @article{SchmidtWolfBrunner2016, author = {Schmidt, Bernd and Wolf, Felix and Brunner, Heiko}, title = {Styrylsulfonates and -Sulfonamides through Pd-Catalysed Matsuda-Heck Reactions of Vinylsulfonic Acid Derivatives and Arenediazonium Salts}, series = {European journal of organic chemistry}, journal = {European journal of organic chemistry}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {1434-193X}, doi = {10.1002/ejoc.201600469}, pages = {2972 -- 2982}, year = {2016}, abstract = {Arene diazonium salts undergo Matsuda-Heck reactions with vinylsulfonates and -sulfonamides to give styrylsulfonic acid derivatives in high to excellent yields and with high to excellent selectivities. By quantifying the evolution of nitrogen over time in a gas-meter apparatus, the reactivities of ethylvinylsulfonate and the benchmark olefin methyl acrylate were compared for an electron-rich and an -deficient arene diazonium salt. Tertiary sulfonamides react in Matsuda-Heck couplings with high conversions, but require long reaction times, which prevents the determination of kinetic data through the measurement of nitrogen evolution. Secondary sulfonamides were found to be unreactive. From these results, the following order of reactivity could be deduced: H2C=CHCO2Me > H2C=CHSO2OEt > H2C=CHSO2N(Me)Bn >> H2C=CHSO2NHBn. Through the Matsuda-Heck coupling of 5-indolyldiazonium salt and a tertiary vinylsulfonamide, the synthesis of the C-5-substituted indole part of the antimigraine drug naratriptan was accomplished in high yield.}, language = {en} } @article{PesterSchmidtRuppeletal.2015, author = {Pester, Christian W. and Schmidt, Kristin and Ruppel, Markus and Schoberth, Heiko G. and B{\"o}ker, Alexander}, title = {Electric-Field-Induced Order-Order Transition from Hexagonally Perforated Lamellae to Lamellae}, series = {Macromolecules : a publication of the American Chemical Society}, volume = {48}, journal = {Macromolecules : a publication of the American Chemical Society}, number = {17}, publisher = {American Chemical Society}, address = {Washington}, issn = {0024-9297}, doi = {10.1021/acs.macromol.5b01336}, pages = {6206 -- 6213}, year = {2015}, abstract = {Block copolymers form a variety of microphase morphologies due to their ability to phase separate. The hexagonally perforated lamellar (HPL) morphology represents an unusually long-lived, nonequilibrium transient structure between lamellar and cylindrical phases. We present a detailed study of a concentrated, HPL-forming poly(styrene-b-isoprene) diblock copolymer solution in toluene in the presence of an electric field. We will show that this phase is readily aligned by a moderate electric field and provide experimental evidence for an electric-field-induced order order transition toward the lamellar phase under sufficiently strong fields. This process is shown to be fully reversible as lamellar perforations reconnect immediately upon secession of the external stimulus, recovering highly aligned perforated lamellae.}, language = {en} } @article{DahmStillerMechieetal.2020, author = {Dahm, Torsten and Stiller, Manfred and Mechie, James and Heimann, Sebastian and Hensch, Martin and Woith, Heiko and Schmidt, Bernd and Gabriel, Gerald and Weber, Michael}, title = {Seismological and geophysical signatures of the deep crustal magma systems of the cenozoic volcanic fields Beneath the Eifel, Germany}, series = {Geochemistry, geophysics, geosystems}, volume = {21}, journal = {Geochemistry, geophysics, geosystems}, number = {9}, publisher = {American Geophysical Union}, address = {Washington}, issn = {1525-2027}, doi = {10.1029/2020GC009062}, pages = {21}, year = {2020}, abstract = {The Quaternary volcanic fields of the Eifel (Rhineland-Palatinate, Germany) had their last eruptions less than 13,000 years ago. Recently, deep low-frequency (DLF) earthquakes were detected beneath one of the volcanic fields showing evidence of ongoing magmatic activity in the lower crust and upper mantle. In this work, seismic wide- and steep-angle experiments from 1978/1979 and 1987/1988 are compiled, partially reprocessed and interpreted, together with other data to better determine the location, size, shape, and state of magmatic reservoirs in the Eifel region near the crust-mantle boundary. We discuss seismic evidence for a low-velocity gradient layer from 30-36 km depth, which has developed over a large region under all Quaternary volcanic fields of the Rhenish Massif and can be explained by the presence of partial melts. We show that the DLF earthquakes connect the postulated upper mantle reservoir with the upper crust at a depth of about 8 km, directly below one of the youngest phonolitic volcanic centers in the Eifel, where CO(2)originating from the mantle is massively outgassing. A bright spot in the West Eifel between 6 and 10 km depth represents a Tertiary magma reservoir and is seen as a model for a differentiated reservoir beneath the young phonolitic center today. We find that the distribution of volcanic fields is controlled by the Variscan lithospheric structures and terrane boundaries as a whole, which is reflected by an offset of the Moho depth, a wedge-shaped transparent zone in the lower crust and the system of thrusts over about 120 km length.}, language = {en} }