@article{KaaSternemannAppeletal.2022, author = {Kaa, Johannes M. and Sternemann, Christian and Appel, Karen and Cerantola, Valerio and Preston, Thomas R. and Albers, Christian and Elbers, Mirko and Libon, Lelia and Makita, Mikako and Pelka, Alexander and Petitgirard, Sylvain and Pl{\"u}ckthun, Christian and Roddatis, Vladimir and Sahle, Christoph J. and Spiekermann, Georg and Schmidt, Christian and Schreiber, Anja and Sakrowski, Robin and Tolan, Metin and Wilke, Max and Zastrau, Ulf and Konopkova, Zuzana}, title = {Structural and electron spin state changes in an x-ray heated iron carbonate system at the Earth's lower mantle pressures}, series = {Physical review research}, volume = {4}, journal = {Physical review research}, number = {3}, publisher = {American Physical Society}, address = {College Park}, issn = {2643-1564}, doi = {10.1103/PhysRevResearch.4.033042}, pages = {9}, year = {2022}, abstract = {The determination of the spin state of iron-bearing compounds at high pressure and temperature is crucial for our understanding of chemical and physical properties of the deep Earth. Studies on the relationship between the coordination of iron and its electronic spin structure in iron-bearing oxides, silicates, carbonates, iron alloys, and other minerals found in the Earth's mantle and core are scarce because of the technical challenges to simultaneously probe the sample at high pressures and temperatures. We used the unique properties of a pulsed and highly brilliant x-ray free electron laser (XFEL) beam at the High Energy Density (HED) instrument of the European XFEL to x-ray heat and probe samples contained in a diamond anvil cell. We heated and probed with the same x-ray pulse train and simultaneously measured x-ray emission and x-ray diffraction of an FeCO3 sample at a pressure of 51 GPa with up to melting temperatures. We collected spin state sensitive Fe K beta(1,3) fluorescence spectra and detected the sample's structural changes via diffraction, observing the inverse volume collapse across the spin transition. During x-ray heating, the carbonate transforms into orthorhombic Fe4C3O12 and iron oxides. Incipient melting was also observed. This approach to collect information about the electronic state and structural changes from samples contained in a diamond anvil cell at melting temperatures and above will considerably improve our understanding of the structure and dynamics of planetary and exoplanetary interiors.}, language = {en} } @article{ZielhoferSchmidtReicheetal.2022, author = {Zielhofer, Christoph and Schmidt, Johannes and Reiche, Niklas and Tautenhahn, Marie and Ballasus, Helen and Burkart, Michael and Linst{\"a}dter, Anja and Dietze, Elisabeth and Kaiser, Knut and Mehler, Natascha}, title = {The lower Havel River Region (Brandenburg, Germany)}, series = {Water}, volume = {14}, journal = {Water}, number = {3}, publisher = {MDPI}, address = {Basel}, issn = {2073-4441}, doi = {10.3390/w14030480}, pages = {23}, year = {2022}, abstract = {Instrumental data show that the groundwater and lake levels in Northeast Germany have decreased over the past decades, and this process has accelerated over the past few years. In addition to global warming, the direct influence of humans on the local water balance is suspected to be the cause. Since the instrumental data usually go back only a few decades, little is known about the multidecadal to centennial-scale trend, which also takes long-term climate variation and the long-term influence by humans on the water balance into account. This study aims to quantitatively reconstruct the surface water areas in the Lower Havel Inner Delta and of adjacent Lake Gulpe in Brandenburg. The analysis includes the calculation of surface water areas from historical and modern maps from 1797 to 2020. The major finding is that surface water areas have decreased by approximately 30\% since the pre-industrial period, with the decline being continuous. Our data show that the comprehensive measures in Lower Havel hydro-engineering correspond with groundwater lowering that started before recent global warming. Further, large-scale melioration measures with increasing water demands in the upstream wetlands beginning from the 1960s to the 1980s may have amplified the decline in downstream surface water areas.}, language = {en} } @article{KrokeSchmidtAminietal.2022, author = {Kroke, Anja and Schmidt, Annemarie and Amini, Anna M. and Kalotai, Nicole and Lehmann, Andreas and Haardt, Julia and Bauer, J{\"u}rgen M. and Bischoff-Ferrari, Heike A. and Boeing, Heiner and Egert, Sarah and Ellinger, Sabine and K{\"u}hn, Tilman and Louis, Sandrine and Lorkowski, Stefan and Nimptsch, Katharina and Remer, Thomas and Schulze, Matthias B. and Siener, Roswitha and Stangl, Gabriele and Volkert, Dorothee and Zittermann, Armin and Buyken, Anette E. and Watzl, Bernhard and Schwingshackl, Lukas}, title = {Dietary protein intake and health-related outcomes: a methodological protocol for the evidence evaluation and the outline of an evidence to decision framework underlying the evidence-based guideline of the German Nutrition Society}, series = {European journal of nutrition}, volume = {61}, journal = {European journal of nutrition}, number = {4}, publisher = {Springer Nature}, address = {Heidelberg}, organization = {German Nutr Soc}, issn = {1436-6207}, doi = {10.1007/s00394-021-02789-5}, pages = {2091 -- 2101}, year = {2022}, abstract = {Purpose: The present work aimed to delineate (i) a revised protocol according to recent methodological developments in evidence generation, to (ii) describe its interpretation, the assessment of the overall certainty of evidence and to (iii) outline an Evidence to Decision framework for deriving an evidence-based guideline on quantitative and qualitative aspects of dietary protein intake. Methods A methodological protocol to systematically investigate the association between dietary protein intake and several health outcomes and for deriving dietary protein intake recommendations for the primary prevention of various non-communicable diseases in the general adult population was developed. Results The developed methodological protocol relies on umbrella reviews including systematic reviews with or without meta-analyses. Systematic literature searches in three databases will be performed for each health-related outcome. The methodological quality of all selected systematic reviews will be evaluated using a modified version of AMSTAR 2, and the outcome-specific certainty of evidence for systematic reviews with or without meta-analysis will be assessed with NutriGrade. The general outline of the Evidence to Decision framework foresees that recommendations in the derived guideline will be given based on the overall certainty of evidence as well as on additional criteria such as sustainability. Conclusion The methodological protocol permits a systematic evaluation of published systematic reviews on dietary protein intake and its association with selected health-related outcomes. An Evidence to Decision framework will be the basis for the overall conclusions and the resulting recommendations for dietary protein intake.}, language = {en} }