@article{ZhangHayerAlSutietal.2006,
  author    = {Zhang, Ning and Hayer, Anna and Al-Suti, Mohammed K. and Al-Belushi, Rayya A. and Khan, Muhammad S. and K{\"o}hler, Anna},
  title     = {The effect of delocalization on the exchange energy in meta- and para-linked Pt-containing carbazole polymers and monomers},
  doi       = {10.1063/1.2200351},
  year      = {2006},
  abstract  = {A series of novel platinum-containing carbazole monomers and polymers was synthesized and fully characterized by UV-VIS absorption, luminescence, and photoinduced absorption studies. In these compounds, a carbazole unit is incorporated into the main chain via either a para- or a meta-linkage. We discuss the effects of linkage and polymerization on the energy levels of S-1, T-1, and T-n. The S-1-T-1 splitting observed for the meta-linked monomer (0.4 eV) is only half of that in the para-linked monomer (0.8 eV). Upon polymerization, the exchange energy in the para- linked compound reduces, yet still remains larger than in the meta-linked polymer. We attribute the difference in exchange energy to the difference in wave function overlap between electron and hole in these compounds. (c) 2006 American Institute of Physics},
  language  = {en}
}