@article{VukicevicNeffeLuetzowetal.2015, author = {Vukicevic, Radovan and Neffe, Axel T. and Luetzow, Karola and Pierce, Benjamin F. and Lendlein, Andreas}, title = {Conditional Ultrasound Sensitivity of Poly[(N-isopropylacrylamide)-co-(vinyl imidazole)] Microgels for Controlled Lipase Release}, series = {Macromolecular rapid communications}, volume = {36}, journal = {Macromolecular rapid communications}, number = {21}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {1022-1336}, doi = {10.1002/marc.201500311}, pages = {1891 -- 1896}, year = {2015}, abstract = {Triggering the release of cargo from a polymer network by ultrasonication as an external, non-invasive stimulus can be an interesting concept for on-demand release. Here, it is shown that, in pH-and thermosensitive microgels, the ultrasound sensitivity of the polymer network depends on the external conditions. Crosslinked poly[(N-isopropylacrylamide)-co-(vinyl imidazole)] microgels showed a volume phase transition temperature (VPTT) of 25-50 degrees C, which increases with decreasing pH. Above the VPTT the polymer chains are collapsed, while below VPTT they are extended. Only in the case of maximum observed swelling, where the polymer chains are expanded, the microgels are mechanically fragmented through ultrasonication. In contrast, when the polymer chains are partially collapsed it is not possible to manipulate the microgels by ultrasound. Additionally, the ultrasound-induced on-demand release of wheat germ lipase from the microgels could be demonstrated successfully. The principle of conditional ultrasound sensitivity is likely to be general and can be used for selection of matrix-cargo combinations.}, language = {en} } @article{VukicevicVukovicStoyanovetal.2012, author = {Vukicevic, Radovan and Vukovic, Ivana and Stoyanov, Hristiyan and Korwitz, Andreas and Pospiech, Doris and Kofod, Guggi and Loos, Katja and ten Brinke, Gerrit and Beuermann, Sabine}, title = {Poly(vinylidene fluoride)-functionalized single-walled carbon nanotubes for the preparation of composites with improved conductivity}, series = {Polymer Chemistry}, volume = {3}, journal = {Polymer Chemistry}, number = {8}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {1759-9954}, doi = {10.1039/c2py20166f}, pages = {2261 -- 2265}, year = {2012}, abstract = {The surface of single-walled carbon nanotubes (SWCNTs) was functionalized with azide-terminated poly(vinylidene fluoride) (PVDF). Functionalization was confirmed by dispersibility, Raman spectroscopy, and thermogravimetric analyses. Raman spectra show disordering of the SWCNTs, thus, strongly suggesting that PVDF was covalently attached to SWCNTs. Functionalized SWCNTs were mixed with commercially available PVDF in a twin-screw extruder and thin films were obtained by melt-pressing. Films containing 0.5 and 1 wt\% PVDF-functionalized SWCNTs exhibited significantly improved electrical conductivity compared to PVDF films containing pristine SWCNTs.}, language = {en} } @article{VukicevicSchwadtkeSchmueckeretal.2012, author = {Vukicevic, Radovan and Schwadtke, Ulrike and Schmuecker, Simon and Schaefer, Philipp and Kuckling, Dirk and Beuermann, Sabine}, title = {Alkyne-azide coupling of tailored poly(vinylidene fluoride) and polystyrene for the synthesis of block copolymers}, series = {Polymer Chemistry}, volume = {3}, journal = {Polymer Chemistry}, number = {2}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {1759-9954}, doi = {10.1039/c1py00427a}, pages = {409 -- 414}, year = {2012}, abstract = {The synthesis of block copolymers consisting of poly(vinylidene fluoride) (PVDF) and polystyrene (PS) is reported. Firstly, a propargyl-functionalized alkoxyamine initiator (PgOTIPNO) was prepared and subsequently used for the preparation of a propargyl-terminated PS homopolymer of different chain lengths with low dispersities via nitroxide-mediated radical polymerization. A tailored PVDF homopolymer with iodine end groups originating from iodine transfer polymerization was transformed to PVDF with azide end group. Then, alkyne-terminated PS with different molecular weights and azide-terminated PVDF were joined together via copper-catalyzed alkyne-azide coupling. The block copolymers were characterized using H-1-NMR, F-19-NMR, IR, SEC, and DSC.}, language = {en} } @phdthesis{Vukicevic2011, author = {Vukicevic, Radovan}, title = {Iodine- and azide-terminated poly(vinylidene fluoride) as a building block for the preparation of hybrid materials and block copolymers}, address = {Potsdam}, pages = {122 S.}, year = {2011}, language = {en} } @article{VukicevicBeuermann2011, author = {Vukicevic, Radovan and Beuermann, Sabine}, title = {Fullerenes decorated with poly(vinylidene fluoride)}, series = {Macromolecules : a publication of the American Chemical Society}, volume = {44}, journal = {Macromolecules : a publication of the American Chemical Society}, number = {8}, publisher = {American Chemical Society}, address = {Washington}, issn = {0024-9297}, doi = {10.1021/ma102754c}, pages = {2597 -- 2603}, year = {2011}, abstract = {Fullerenes decorated with poly(vinylidene fluoride) (PVDF) were synthesized in a three-step procedure: Iodine transfer polymerization of vinylidene fluoride with C(6)F(12)I(2) as the chain transfer agent was carried out in supercritical carbon dioxide to synthesize iodine-terminated PVDF, which was subsequently transformed to azide-terminated polymer. Finally, azide-terminated PVDF chains were attached to a fullerene core under microwave irradiation at 160 degrees C in 1.5 h. The materials were characterized by NMR, FT-IR, UV/vis, GPC, elemental analysis, and DSC. On average, 4-5 PVDF chains are attached to one C(60) moiety. FT-IR spectra and DSC measurements indicate that the polymer end groups strongly affect the crystallinity of the material. For PVDF with azide end groups and PVDF attached to fullerenes the fraction of the beta polymorph is dominant while alpha polymorphs are almost absent.}, language = {en} } @inproceedings{VukicevicSchreiberBeuermann2011, author = {Vukicevic, Radovan and Schreiber, Ulrike and Beuermann, Sabine}, title = {Azide-terminated poly(vinylidene fluoride) as building block for nanocomposite materials and block copolymers}, series = {Abstracts of papers : joint conference / The Chemical Institute of Cananda, CIC, American Chemical Society, ACS}, volume = {242}, booktitle = {Abstracts of papers : joint conference / The Chemical Institute of Cananda, CIC, American Chemical Society, ACS}, number = {16}, publisher = {American Chemical Society}, address = {Washington}, issn = {0065-7727}, pages = {1}, year = {2011}, language = {en} } @inproceedings{SchreiberVukicevicBeuermann2011, author = {Schreiber, Ulrike and Vukicevic, Radovan and Beuermann, Sabine}, title = {Block copolymers of poly(vinylidene fluoride) obtained via 1,3 dipolar cycloaddition}, series = {Abstracts of papers : joint conference / The Chemical Institute of Cananda, CIC, American Chemical Society, ACS}, volume = {242}, booktitle = {Abstracts of papers : joint conference / The Chemical Institute of Cananda, CIC, American Chemical Society, ACS}, publisher = {American Chemical Society}, address = {Washington}, issn = {0065-7727}, pages = {1}, year = {2011}, language = {en} } @article{VukicevicHierzenbergerHildetal.2010, author = {Vukicevic, Radovan and Hierzenberger, Peter and Hild, Sabine and Beuermann, Sabine}, title = {Functionalization of carbon black nanoparticles with poly(vinylidene fluoride)}, issn = {0887-624X}, doi = {10.1002/Pola.24277}, year = {2010}, abstract = {The surface of carbon black (CB) nanoparticles was functionalized with poly(vinylidene fluoride) (PVDF) either by trapping of macroradicals or by cycloaddition. PVDF with two iodine end groups (I-PVDF-I) obtained from iodine transfer polymerization in supercritical CO2 was heated in the presence of CB and the C-I bond was cleaved resulting in a reaction between the macroradical and the CB surface. To allow for cycloaddition of PVDF to the CB surface for a number of polymers, the iodine end groups were replaced by azide end groups. In addition, microwave irradiation was applied to the functionalization. The influence of temperature, time, polymer concentration, and polymer molar mass on the functionalization reaction was examined.}, language = {en} }