@article{OmorogieBabalolaUnuabonahetal.2012,
  author    = {Omorogie, Martins O. and Babalola, Jonathan Oyebamiji and Unuabonah, Emmanuel I. and Gong, Jian Ru},
  title     = {Kinetics and thermodynamics of heavy metal ions sequestration onto novel Nauclea diderrichii seed biomass},
  series = {BIORESOURCE TECHNOLOGY},
  volume    = {118},
  journal   = {BIORESOURCE TECHNOLOGY},
  number    = {8},
  publisher = {ELSEVIER SCI LTD},
  address   = {OXFORD},
  issn      = {0960-8524},
  doi       = {10.1016/j.biortech.2012.04.053},
  pages     = {576 -- 579},
  year      = {2012},
  abstract  = {This study reports the sequestration of Cd(II) and Hg(II) using a new biosorbent. Nauclea diderrichii seed biomass. Experimental data obtained were fitted into kinetic and thermodynamic models. Experimental data fitted best into pseudo-second order kinetic model among others. Results obtained kinetically revealed that the biosorption of Cd(II) and Hg(II) using N. diderrichii seed biosorbent increased with increase in temperature. At the highest temperature, which was 333 K. the highest amount of metal biosorbed, q(e), for Cd(II) and Hg(II) obtained were 6.30 and 6.15 mg/g respectively. The biosorption of Cd(II) was kinetically faster than that of Hg(II), the highest initial biosorption rates for Cd(II) and Hg(II) were 56.19 and 4.39 mg/g min respectively. Thermodynamic parameters obtained by Erying equation from this study revealed that the biosorption process was spontaneous, feasible, endothermic with a decrease in the degree of chaos in the biosorption system. (C) 2012 Elsevier Ltd. All rights reserved.},
  language  = {en}
}
@article{OmorogieBabalolaUnuabonahetal.2016,
  author    = {Omorogie, Martins O. and Babalola, Jonathan Oyebamiji and Unuabonah, Emmanuel I. and Song, Weiguo and Gong, Jian Ru},
  title     = {Efficient chromium abstraction from aqueous solution using a low-cost biosorbent: Nauclea diderrichii seed biomass waste},
  series = {Journal of Saudi Chemical Society},
  volume    = {20},
  journal   = {Journal of Saudi Chemical Society},
  publisher = {Elsevier},
  address   = {Amsterdam},
  issn      = {1319-6103},
  doi       = {10.1016/j.jscs.2012.09.017},
  pages     = {49 -- 57},
  year      = {2016},
  abstract  = {Toxic Cr(III) which poses environmental hazard to flora and fauna was efficiently abstracted by low-cost Nauclea diderrichii seed biomass (NDS) with good sequestral capacity for this metal was investigated in this study. The NDS surface analyses showed that it has a specific surface area of 5.36 m(2)/g and pHpzc of 4.90. Thermogravimetric analysis of NDS showed three consecutive weight losses from 50-200 degrees C (ca. 5\%), 200-400 C (ca. 35\%), >400 degrees C (ca. 10\%), corresponding to external water molecules, structural water molecules and heat induced condensation reactions respectively. Differential thermogram of NDS presented a large endothermic peak between 20-510 degrees C suggesting bond breakage and dissociation with the ultimate release of small molecules. The experimental data showed kinetically fast biosorption with increased initial Cr(III) concentrations, indicating the role of external mass transfer mechanism as the rate controlling mechanism in this adsorption process. The Langmuir biosorption capacity of NDS was 483.81 mg/g. The use of the corrected Akaike Information Criterion tool for ranking equilibrium models suggested that the Freundlich model best described the experimental data, which is an indication of the heterogeneous nature of the active sites on the surface of NDS. N. diderrichii seed biomass is an easily sourced, cheap and environmental friendly biosorbent which will serve as a good and cost effective alternative to activated carbon for the treatment of polluted water and industrial effluents. (C) 2012 King Saud University. Production and hosting by Elsevier B.V. All rights reserved.},
  language  = {en}
}