@article{SchulzOrgzallDiezetal.2010,
  author    = {Schulz, Burkhard and Orgzall, Ingo and Diez, Isabel and Dietzel, Birgit and Tauer, Klaus},
  title     = {Template mediated formation of shaped polypyrrole particles},
  issn      = {0927-7757},
  doi       = {10.1016/j.colsurfa.2009.11.034},
  year      = {2010},
  abstract  = {The formation of different micro- and nanostructures during the chemical synthesis of polypyrrole is reviewed shortly based on the conceptions of hard- and soft-templating models. Contrary to other models that emphasize the role of micelles it is found here that during the oxidative polymerization of pyrole using sulfonic acid dopants a crystalline hard template is found in the first steps of the reaction before the addition of the oxidant. This template is formed by a complex consisting of 2,5-bis(pyrrole-2-yl)pyrrolidine and the sulfonic acid anion. The acid catalyzed formation of this specific tripyrrole is discussed. (C) 2009 Elsevier B.V. All rights reserved.},
  language  = {en}
}