@article{KuehnPingelBreusingetal.2011,
  author    = {Kuehn, Sergei and Pingel, Patrick and Breusing, Markus and Fischer, Thomas and Stumpe, Joachim and Neher, Dieter and Elsaesser, Thomas},
  title     = {High-Resolution Near-Field Optical Investigation of Crystalline Domains in Oligomeric PQT-12 Thin Films},
  series = {Advanced functional materials},
  volume    = {21},
  journal   = {Advanced functional materials},
  number    = {5},
  publisher = {Wiley-Blackwell},
  address   = {Malden},
  issn      = {1616-301X},
  doi       = {10.1002/adfm.201001978},
  pages     = {860 -- 868},
  year      = {2011},
  abstract  = {The structure and morphology on different length scales dictate both the electrical and optical properties of organic semiconductor thin films. Using a combination of spectroscopic methods, including scanning near-field optical microscopy, we study the domain structure and packing quality of highly crystalline thin films of oligomeric PQT-12 with 100 nanometer spatial resolution. The pronounced optical anisotropy of these layers measured by polarized light microscopy facilitates the identification of regions with uniform molecular orientation. We find that a hierarchical order on three different length scales exists in these layers, made up of distinct well-ordered dichroic areas at the ten-micrometer-scale, which are sub-divided into domains with different molecular in-plane orientation. These serve as a template for the formation of smaller needle-like crystallites at the layer surface. A high degree of crystalline order is believed to be the cause of the rather high field-effect mobility of these layers of 10(-3) cm 2 V(-1) s(-1), whereas it is limited by the presence of domain boundaries at macroscopic distances.},
  language  = {en}
}