@article{SinghMellinger2015, author = {Singh, Rajeev and Mellinger, Axel}, title = {Measurement of through-thickness thermal diffusivity of thermoplastics using thermal wave method}, series = {Indian journal of physics}, volume = {89}, journal = {Indian journal of physics}, number = {4}, publisher = {Indian Association for the Cultivation of Science}, address = {Kolkata}, issn = {0973-1458}, doi = {10.1007/s12648-014-0579-2}, pages = {361 -- 368}, year = {2015}, abstract = {Thermo-physical properties, such as thermal conductivity, thermal diffusivity and specific heat are important quantities that are needed to interpret and characterize thermoplastic materials. Such characterization is necessary for many applications, ranging from aerospace engineering to food packaging, electrical and electronic industry and medical science. In this work, the thermal diffusivity of commercially available polymeric films is measured in the thickness direction at room temperature using thermal wave method. The results obtained with this method are in good agreement with theoretical and experimental values.}, language = {en} } @article{QiuMellingerWirgesetal.2007, author = {Qiu, Xunlin and Mellinger, Axel and Wirges, Werner and Gerhard, Reimund}, title = {Spectroscopic study of dielectric barrier discharges in cellular polypropylene ferroelectrets}, doi = {10.1063/1.2786597}, year = {2007}, abstract = {The transient light emission from the dielectric barrier discharges (DBDs) in cellular polypropylene ferroelectrets subjected to high electric poling fields was spectroscopically measured. The spectrum shows strong emission from the second positive system of molecular nitrogen, N-2(C (3)Pi(u))-> N-2(B (3)Pi(g)), and the first negative system of N-2(+), N-2(+)(B (2)Sigma(+)(u))-> N-2(+)(X (2)Sigma(+)(g)), consistent with a DBD in air. When a dc voltage is applied stepwise to the ferroelectret film, light emission starts above a threshold, coinciding with the threshold voltage in obtaining piezoelectricity. From selected vibronic band strength ratios, the electric field in the discharge was determined and found to agree with Townsend breakdown.}, language = {en} } @article{QiuMellingerWirgesetal.2007, author = {Qiu, Xunlin and Mellinger, Axel and Wirges, Werner and Gerhard, Reimund}, title = {Dielectric barrier discharges during the generation of ferroelectrets : optical spectroscopy for process monitoring}, isbn = {978-1-4244-1482-6}, year = {2007}, language = {en} } @article{QiuMellingerWegeneretal.2007, author = {Qiu, Xunlin and Mellinger, Axel and Wegener, Michael and Wirges, Werner and Gerhard, Reimund}, title = {Barrier discharges in cellular polypropylene ferroelectrets : how do they influence the electromechanical properties?}, year = {2007}, language = {en} } @article{QiuGerhardMellinger2011, author = {Qiu, Xunlin and Gerhard, Reimund and Mellinger, Axel}, title = {Turning polymer foams or polymer-film systems into ferroelectrets dielectric barrier discharges in voids}, series = {IEEE transactions on dielectrics and electrical insulation}, volume = {18}, journal = {IEEE transactions on dielectrics and electrical insulation}, number = {1}, publisher = {Inst. of Electr. and Electronics Engineers}, address = {Piscataway}, issn = {1070-9878}, doi = {10.1109/TDEI.2011.5704490}, pages = {34 -- 42}, year = {2011}, abstract = {Polymer foams and void-containing polymer-film systems with internally charged voids combine large piezoelectricity with mechanical flexibility and elastic compliance. This new class of soft materials (often called ferro-or piezoelectrets) has attracted considerable attention from science and industry. It has been found that the voids can be internally charged by means of dielectric barrier discharges (DBDs) under high electric fields. The charged voids can be considered as man-made macroscopic dipoles. Depending on the ferroelectret structure and the pressure of the internal gas, the voids may be highly compressible. Consequently, very large dipole-moment changes can be induced by mechanical or electrical stresses, leading to large piezoelectricity. DBD charging of the voids is a critical process for rendering polymer foams piezoelectric. Thus a comprehensive exploration of DBD charging is essential for the understanding and the optimization of piezoelectricity in ferroelectrets. Recent studies show that DBDs in the voids are triggered when the internal electric field reaches a threshold value according to Townsend's model of Paschen breakdown. During the DBDs, charges of opposite polarity are generated and trapped at the top and bottom internal surfaces of the gas-filled voids, respectively. The deposited charges induce an electric field opposite to the externally applied one and thus extinguish the DBDs. Back discharges may eventually be triggered when the external voltage is reduced or turned off. In order to optimize the efficiency of DBD charging, the geometry (in particular the height) of the voids, the type of gas and its pressure inside the voids are essential factors to be considered and to be optimized. In addition, the influence of the plasma treatment on the internal void surfaces during the DBDs should be taken into consideration.}, language = {en} } @article{PhamPetreBerquezetal.2009, author = {Pham, Cong Duc and Petre, Anca and Berquez, Laurent and Flores Su{\´a}rez, Rosaura and Mellinger, Axel and Wirges, Werner and Gerhard, Reimund}, title = {3D high-resolution mapping of polarization profiles in thin poly(vinylidenefluoride-trifluoroethylene) (PVDF- TrFE) films using two thermal techniques}, issn = {1070-9878}, doi = {10.1109/TDEI.2009.5128505}, year = {2009}, abstract = {In this paper, two non-destructive thermal methods are used in order to determine, with a high degree of accuracy, three-dimensional polarization distributions in thin films (12 mu m) of poly(vinylidenefluoride- trifluoroethylene) (PVDF-TrFE). The techniques are the frequency-domain Focused Laser Intensity Modulation Method (FLIMM) and time-domain Thermal-Pulse Tomography (TPT). Samples were first metalized with grid-shaped electrode and poled. 3D polarization mapping yielded profiles which reproduce the electrode-grid shape. The polarization is not uniform across the sample thickness. Significant polarization values are found only at depths beyond 0.5 mu m from the sample surface. Both methods provide similar results, TPT method being faster, whereas the FLIMM technique has a better lateral resolution.}, language = {en} } @article{MellingerWegenerWirgesetal.2006, author = {Mellinger, Axel and Wegener, Michael and Wirges, Werner and Mallepally, Rajendar Reddy and Gerhard, Reimund}, title = {Thermal and temporal stability of ferroelectret films made from cellular polypropylene/air composites}, year = {2006}, abstract = {Ferroelectrets are thin films of polymer foams, exhibiting piezoelectric properties after electrical charging. Ferroelectret foams usually consist of a cellular polymer structure filled with air. Polymer-air composites are elastically soft due to their high air content as well as due to the size and shape of the polymer walls. Their elastically soft composite structure is one essential key for the working principle of ferroelectrets, besides the permanent trapping of electric charges inside the polymer voids. The elastic properties allow large deformations of the electrically charged voids. However, the composite structure can also possibly limit the stability and consequently the range of applications because of, e. g., penetration of gas and liquids accompanied by discharge phenomena or because of a mechanical pre-load which may be required during the application. Here, we discuss various stability aspects related to the piezoelectric properties of polypropylene ferroelectrets. Near and below room temperature, the piezoelectric effect and the stability of the trapped charges are practically independent from humidity during long-time storage in a humid atmosphere or water, or from operating conditions, such as continuous mechanical excitation. Thermal treatment of cellular polypropylene above -10 degrees C leads to a softening of the voided structure which is apparent from the decreasing values of the elastic modulus. This decrease results in an increase of the piezoelectric activity. Heating above 60 degrees C, however, leads to a decrease in piezoelectricity}, language = {en} } @article{MellingerWegenerWirgesetal.2006, author = {Mellinger, Axel and Wegener, Michael and Wirges, Werner and Mallepally, Rajendar Reddy and Gerhard, Reimund}, title = {Thermal and temporal stability of ferroelectret films made from cellular polypropylene/air composites}, year = {2006}, language = {en} } @article{MellingerWegenerWirgesetal.2001, author = {Mellinger, Axel and Wegener, Michael and Wirges, Werner and Gerhard, Reimund}, title = {Thermally stable dynamic piezoelectricity in sandwich films of porous and non-porous amorphous fluoropolymer}, year = {2001}, language = {en} } @article{MellingerSinghWegeneretal.2005, author = {Mellinger, Axel and Singh, Rajeev and Wegener, Michael and Wirges, Werner and Gerhard, Reimund and Lang, Sidney B.}, title = {Three-dimensional mapping of polarization profiles with thermal pulses}, issn = {0003-6951}, year = {2005}, abstract = {High-resolution, large-area three-dimensional mapping of polarization profiles in electret polymers was carried out by means of a fast thermal pulse technique with a focused laser beam. A lateral resolution of 38 mu m and a near- surface depth resolution of less than 0.5 mu m was achieved. At larger depths, fast thermal diffusion in the metal electrode rather than the laser spot size becomes the limiting factor for the lateral resolution. (c) 2005 American Institute of Physics}, language = {en} }