@article{BahrkeEinarssonGislasonetal.2002, author = {Bahrke, Sven and Einarsson, Jon M. and Gislason, Johannes and Haebel, Sophie and Letzel, Matthias C. and Peter-Katalinic, Jasna and Peter, Martin G.}, title = {Sequence analysis of chitooligosaccharides by matrix-assisted laser desorption ionization postsource decay mass spectrometry}, year = {2002}, abstract = {Oligosaccharides composed of 2-acetamido-2-deoxy-D-glucopyranose (GlcNAc) and/or 2-amino-2-deoxy-D- glucopyranose (GlcN) were prepd. by chem. degrdn. of chitin or chitosan and sepd. by gel permeation chromatog. Oligosaccharides obtained after enzymic hydrolysis of chitosan [FA 0.19] with a fungal chitinase were derivatized by reductive amination with 2-aminoacridone and sequenced by matrix-assisted laser desorption ionization time-of-flight postsource decay (PSD) mass spectrometry (MS). The sequence of a trimer, D1A2, was established as D-A-A. The compn. of a hexamer D3A3 was .apprx.65\% D-A-D-D-A-A and 35\% D-D-A-D-A-A. The PSD MS of a nonamer D5A4-amac revealed four isobaric species D-X-Y-D-X-Y-D-A-A, where A is GlcNAc, D is GlcN, and X and Y (X ยน Y) are mutually either D or A. This structure motif was also obsd. in a dodecamer D7A5 which was composed of eight isobaric sequences of the general formula (D-X-Y)3- D-A-A.}, language = {en} } @article{LetzelPeterKatalinicPeter2001, author = {Letzel, Matthias C. and Peter-Katalinic, Jasna and Peter, Martin G.}, title = {Mass spectrometry of chitin and chitosan oligosaccharides}, year = {2001}, language = {en} } @article{LetzelSynstadEijsinketal.1999, author = {Letzel, Matthias C. and Synstad, Bjoenar and Eijsink, Vincent G. H. and Peter-Katalinic, Jasna and Peter, Martin G.}, title = {Libraries of chito-oligosaccharides of mixed acetylation patterns and their interactions with chitinases}, isbn = {3-9806494-5-8}, year = {1999}, language = {en} }