@phdthesis{Jelicic2011, author = {Jelicic, Aleksandra}, title = {Combining polymethacrylates and ionic liquids : a way to create and understand}, address = {Potsdam}, pages = {161 S.}, year = {2011}, language = {en} } @article{JelicicGarciaBeuermann2009, author = {Jelicic, Aleksandra and Garcia, Nuria and Beuermann, Sabine}, title = {Influence of ionic liquid structure on the propagation kinetics of methyl methacrylate}, issn = {0024-9297}, doi = {10.1021/ma900774e}, year = {2009}, language = {en} } @article{JelicicGarciaLoehmannsroebenetal.2009, author = {Jelicic, Aleksandra and Garcia, Nuria and L{\"o}hmannsr{\"o}ben, Hans-Gerd and Beuermann, Sabine}, title = {Prediction of the ionic liquid influence on propagation rate coefficients in methyl methacrylate radical polymerizations based on Kamlet-Taft solvatochromic parameters}, issn = {0024-9297}, doi = {10.1021/ma9017907}, year = {2009}, language = {en} } @article{SiegmannJelicic2010, author = {Siegmann, Rebekka and Jelicic, Aleksandra}, title = {Propagation and termination kinetics of PEGylated methacrylate radical polymerizations}, issn = {1022-1352}, doi = {10.1002/macp.200900527}, year = {2010}, abstract = {Propagation and chain-length averaged termination rate coefficients, k(p) and , for radical polymerizations of methacrylates carrying poly(ethylene glycol) (PEG) units are reported. kp derived from pulsed laser initiated polymerizations in bulk, in organic solvents, and in ionic liquids follows the methacrylate-type family behavior. Contrary, diffusion controlled k(t) values obtained from chemically initiated polymerizations with in-line FT- NIR monitoring of monomer conversion are strongly affected by the PEG units in the ester group. Compared to alkyl methacrylates is unexpectedly high. Moreover, of poly(ethylene glycol) ethyl ether methacrylate shows a significant reduction in k(t) already at 15\% conversion, whereas dodecyl methacrylate is constant up to at least 70\% conversion.}, language = {en} } @article{JelicicYasinBeuermann2011, author = {Jelicic, Aleksandra and Yasin, Muttaqin and Beuermann, Sabine}, title = {Toward the description and prediction of solvent induced variations in Methacrylate Propagation Rate Coefficients on the basis of Solvatochromic Parameters}, series = {Macromolecular reaction engineering}, volume = {5}, journal = {Macromolecular reaction engineering}, number = {5-6}, publisher = {Wiley-Blackwell}, address = {Malden}, issn = {1862-832X}, doi = {10.1002/mren.201000058}, pages = {232 -- 242}, year = {2011}, abstract = {Benzyl methacrylate (BzMA) propagation rate coefficients, k(p), were determined in ionic liquids and common organic solvents via pulsed-laser polymerizations with subsequent polymer analysis by size-exclusion chromatography (PLP-SEC). The aim of the work is to gain a deeper understanding of the solvent influence on k(p) and to develop a general correlation between solvent-induced variations in k(p) and solvent properties. Applying a linear solvation energy relationship (LSER), which correlates k(p) to solvent solvatochromic parameters, suggests that dipolarity/polarizability determines the solvent influence on k(p). To compare the solvent influence on BzMA k(p) with data for methyl methacrylate, hydroxypropyl methacrylate, and 2-ethoxyethyl methacrylate normalized k(p) data were treated by a single LSER, providing a universal treatment of the solvent influence on the propagation kinetics of the four monomers. Further, the predictive capabilities of this universal correlation were tested with additional monomers from the methacrylate family.}, language = {en} } @article{XieJelicicWangetal.2010, author = {Xie, Zai-Lai and Jelicic, Aleksandra and Wang, Feipeng and Rabu, Pierre and Friedrich, Alwin and Beuermann, Sabine and Taubert, Andreas}, title = {Transparent, flexible, and paramagnetic ionogels based on PMMA and the iron-based ionic liquid 1-butyl-3- methylimidazolium tetrachloroferrate(III) [Bmim][FeCl4]}, issn = {0959-9428}, doi = {10.1039/C0jm01733g}, year = {2010}, abstract = {The iron-containing ionic liquid (IL) 1-butyl-3-methylimidazolium tetrachloroferrate(III) [Bmim][FeCl4] has been used as a building block in the synthesis of transparent, ion-conducting, and paramagnetic ionogels. UV/Vis spectroscopy shows that the coordination around the Fe(III) ion does slightly change upon incorporation of the IL into PMMA. The thermal stability of the PMMA increases significantly with IL incorporation. In particular, the onset weight loss observed at ca. 265 degrees C for pure PMMA is completely suppressed. The ionic conductivity shows a strong temperature dependence and increases with increasing IL weight fractions. The magnetic properties are similar to those reported for the pure IL and are not affected by the incorporation into the PMMA matrix. The resulting ionogel is thus an interesting prototype for soft, flexible, and transparent materials combining the mechanical properties of the matrix with the functionality of the metal-containing IL, such as magnetism.}, language = {en} }