@article{GeueHennebergPietsch2002, author = {Geue, Thomas and Henneberg, Oliver and Pietsch, Ullrich}, title = {X-ray reflectivity from sinusoidal surface relief gratings}, issn = {0023-4753}, year = {2002}, language = {en} } @article{PietschGeueHennebergetal.2003, author = {Pietsch, Ullrich and Geue, Thomas and Henneberg, Oliver and Saphiannikova, Marina}, title = {X-ray investigations of formation efficiency of buried azobenzene polymer density gratings}, doi = {10.1063/1.1554753}, year = {2003}, language = {en} } @article{HennebergGeueSaphiannikovaetal.2003, author = {Henneberg, Oliver and Geue, Thomas and Saphiannikova, Marina and Pietsch, Ullrich and Rochon, Paul}, title = {X-ray and VIS light scattering from light-induced polymer gratings}, doi = {10.1088/0022-3727/36/10A/350}, year = {2003}, language = {en} } @article{HennebergPanznerPietschetal.2004, author = {Henneberg, Oliver and Panzner, Tobias and Pietsch, Ullrich and Geue, Thomas and Saphiannikova, Marina and Rochon, Paul and Finkelstein, Kenneth D.}, title = {X-ray and VIS light scattering from light-induced polymer gratings}, issn = {0044-2968}, year = {2004}, abstract = {Sinusoidally shaped surface relief gratings made of polymer films containing, azobenzene moieties can be created by holographic illumination with laser light of about lambda approximate to 500 nm. The remarkable material transport takes place at temperatures far (100 K) below the glass transition temperature of the material. As probed by visible light scattering the efficiency of grating formation crucially depends on the polarization state of the laser light and is maximal when circular polarization is used. In contrast to VIS light scattering X-ray diffraction is most sensitive for periodic surface undulations with amplitudes below 10 nm. Thus, combined in-situ X-ray and visible light scattering at CHESS were used to investigate the dynamics of surface relief grating formations upon laser illumination. The time development of grating peaks up to 9th order at laser power of P = 20 mW/cm(2) could be investigated, even the onset of grating formation as a function of light polarization. A linear growth of grating amplitude was observed for all polarizations. The growth velocity is maximal using circularly polarized light but very small for s-polarized light}, language = {en} } @article{StillerKarageorgievBuchsteineretal.2003, author = {Stiller, Burkhard and Karageorgiev, Peter and Buchsteiner, Andrea and Geue, Thomas and Henneberg, Oliver and Brehmer, Ludwig and Natansohn, Almeria and Hollricher, Olga}, title = {Using light as a tool : optically Induced mass transport generated in Near-Fields}, issn = {0038-7355 -}, year = {2003}, language = {en} } @article{HennebergPietschPanzneretal.2006, author = {Henneberg, Oliver and Pietsch, Ullrich and Panzner, Tobias and Geue, Thomas and Finkelstein, Kenneth D.}, title = {Simultaneous X-ray and visible light diffraction for the investigation of surface relief and density grating formation in azobenzene containing polymer films}, issn = {1542-1406}, doi = {10.1080/15421400500383345}, year = {2006}, abstract = {The development of surface relief and density patterns in azobenzene polymer films was studied by diffraction at two different wavelengths. We used x-ray diffraction of synchrotron radiation at 0.124 nm in combination with visible light diffraction at a wavelength of 633 nm. In contrast to visible light scattering x-ray diffraction allows the separation of a surface relief and a density grating contribution due to the different functional dependence of the scattering power. Additionally, the x-ray probe is most sensitive for the onset of the surface grating formation}, language = {en} } @article{SaphiannikovaHennebergGeneetal.2004, author = {Saphiannikova, Marina and Henneberg, Oliver and Gene, T. M. and Pietsch, Ullrich and Rochon, Paul}, title = {Nonlinear effects during inscription of azobenzene surface relief gratings}, issn = {1520-6106}, year = {2004}, abstract = {Surface relief gratings were inscribed on azobenzene polymer films using a pulselike exposure of an Ar+ laser. The inscription process was initiated by a sequence of short pulses followed by much longer relaxation pauses. The development of the surface relief grating was probed by a He-Ne laser measuring the scattering intensity of the first- order grating peak. The growth time of the surface relief grating was found to be larger than the length of the pulses used. This unusual behavior can be considered as a nonlinear material response associated with the trans-cis isomerization of azobenzene moieties. In this study the polymer stress was assumed to be proportional to the number of cis-isomers. One-dimensional viscoelastic analysis was used to derive the polymer deformation. The rate of trans-cis isomerization increases with the intensity of the inscribing light; in the dark it is equal to the rate of thermal cis- trans isomerization. The respective relaxation times were estimated by fitting theoretical deformation curves to experimental data}, language = {en} } @article{PietschSaphiannikovaHennebergetal.2004, author = {Pietsch, Ullrich and Saphiannikova, Marina and Henneberg, Oliver and Geue, Thomas}, title = {Non-linear effects during inscription of azobenzene surface relief gratings}, year = {2004}, language = {en} } @article{SaphiannikovaGeueHennebergetal.2004, author = {Saphiannikova, Marina and Geue, Thomas and Henneberg, Oliver and Morawetz, Knut and Pietsch, Ullrich}, title = {Linear viscoelastic analysis of formation and relaxation of azobenzene polymer gratings}, doi = {10.1063/1.1642606}, year = {2004}, abstract = {Surface relief gratings on azobenzene containing polymer films were prepared under irradiation by actinic light. Finite element modeling of the inscription process was carried out using linear viscoelastic analysis. It was assumed that under illumination the polymer film undergoes considerable plastification, which reduces its original Young's modulus by at least three orders of magnitude. Force densities of about 10(11) N/m(3) were necessary to reproduce the growth of the surface relief grating. It was shown that at large deformations the force of surface tension becomes comparable to the inscription force and therefore plays an essential role in the retardation of the inscription process. In addition to surface profiling the gradual development of an accompanying density grating was predicted for the regime of continuous exposure. Surface grating development under pulselike exposure cannot be explained in the frame of an incompressible fluid model. However, it was easily reproduced using the viscoelastic model with finite compressibility. (C) 2004 American Institute of Physics}, language = {en} } @article{HennebergGeueSaphiannikovaetal.2002, author = {Henneberg, Oliver and Geue, Thomas and Saphiannikova, Marina and Natansohn, Almeria and Rochon, Paul and Finkelstein, Kenneth D.}, title = {Investigation of material flow on inscribing a polymer surface grating probing X-ray and VIS light scattering}, issn = {0927-7757}, year = {2002}, language = {en} }