@phdthesis{Hahn2012, author = {Hahn, Simone}, title = {Extration von Hexachloroplatinat(IV) mit phoshorylierten Merrifield-Harzen aus salzsauren L{\"o}sungen}, address = {Potsdam}, pages = {X, 127, XXX S.}, year = {2012}, language = {de} } @article{HahnHoldt2012, author = {Hahn, Simone and Holdt, Hans-J{\"u}rgen}, title = {Extraction of hexachloroplatinate from hydrochloric acid solutions with phosphorylated hexane-1,6-diyl polymers}, series = {Reactive \& functional polymers}, volume = {72}, journal = {Reactive \& functional polymers}, number = {11}, publisher = {Elsevier}, address = {Amsterdam}, issn = {1381-5148}, doi = {10.1016/j.reactfunctpolym.2012.08.004}, pages = {878 -- 888}, year = {2012}, abstract = {A series of diols (diethylene glycol, triethylene glycol, butane-1,4-diol and hexane-1,6-diol) were immobilized onto Merrifield resin and subsequently phosphorylated with dialkyl chlorophosphate (alkyl = Me, Et, Bu). The resins bearing hexane-1,6-diyl groups exhibited very good extraction abilities in regard to precious metal chloro complexes like platinum(IV), palladium(II) and rhodium(III). In batch experiments, more than 98\% of Pt(IV) is extracted even when the metal and the hydrochloric acid concentration is enhanced significantly. Elution can be achieved with a solution of 0.5 mol L-1 thiourea in 0.1 mol L-1 hydrochloric acid. In the presence of other noble metals, platinum(IV) is preferentially bound. The extraction yield decreases in slightly acidic solution in the following order: Pt(IV)approximate to Pd(II)>Rh(III) and changes with increasing hydrochloric acid concentration to Pt(IV)>Pd(II)>> Rh(III). At different ratios of metal and acid, the temperature has nearly no influence on the platinum extraction. On slightly acidic media, the extraction of rhodium decreases by 30\% when the temperature is increased from 10 degrees C to 40 degrees C. When the acid and metal concentration is enhanced, the palladium extraction decreases by 7-9\%, depending on the resin.}, language = {en} } @article{HahnTraegerHoldt2015, author = {Hahn, Simone and Tr{\"a}ger, Juliane and Holdt, Hans-J{\"u}rgen}, title = {Solid-Phase extraction of Pt(IV) with Dialkyl-(hexane-1,6-diyl) phosphate modified merrifield resins from aqueous chloride media in column operations}, series = {Separation and purification technology}, volume = {50}, journal = {Separation and purification technology}, number = {2}, publisher = {Taylor \& Francis Group}, address = {Philadelphia}, issn = {0149-6395}, doi = {10.1080/01496395.2014.968264}, pages = {191 -- 206}, year = {2015}, abstract = {A series of three dialkyl phosphate resins with a Merrifield resin support was used to extract platinum from acidic media. In column operations total capacities of 85-130 mg/g were gained. The presence of palladium and rhodium results in the order: Pt(IV) > Pd(II) >> Rh(III). From a leach liquor gained from spent automotive catalysts metals forming anionic chloro complexes are co-extracted only to a small extent. However, in order to separate and enrich platinum a selective back-extraction can be done with a sodium thiocyanate solution. A second elution step with acidic thiourea leads to a mixed solution of palladium and rhodium.}, language = {en} } @article{HahnKellingSchildeetal.2008, author = {Hahn, Simone and Kelling, Alexandra and Schilde, Uwe and Holdt, Hans-J{\"u}rgen}, title = {Crystal structure of bis(2-ethylthiomethylpyridine)platinum(II) hexachloroplatinate, [Pt(C8H11NS)2][PtCl6]}, issn = {1433-7266}, doi = {10.1524/ncrs.2008.0216}, year = {2008}, abstract = {C16H22Cl6N2Pt2S2, orthorhombic, Pbca (no. 61), a = 15.5660(8) angstrom, b = 17.4892(9) angstrom, c = 18.161 (1) angstrom, V = 4944. 1 angstrom(3), Z = 8, R-gt(F) = 0.030, wR(ref)(F-2) = 0.055, T = 210 K.}, language = {en} }