@phdthesis{Duesterhoeft2013, author = {Duesterhoeft, Erik}, title = {The impact of metamorphic processes on physical properties: a view from thermodynamiccs to geodynamics}, address = {Potsdam}, pages = {102 S.}, year = {2013}, language = {en} } @article{PourteauBousquetVidaletal.2014, author = {Pourteau, Amaury and Bousquet, Romain and Vidal, Olivier and Plunder, Alexis and Duesterhoeft, Erik and Candan, Osman and Oberh{\"a}nsli, Roland}, title = {Multistage growth of Fe-Mg-carpholite and Fe-Mg-chloritoid, from field evidence to thermodynamic modelling}, series = {Contributions to mineralogy and petrology}, volume = {168}, journal = {Contributions to mineralogy and petrology}, number = {6}, publisher = {Springer}, address = {New York}, issn = {0010-7999}, doi = {10.1007/s00410-014-1090-7}, pages = {25}, year = {2014}, abstract = {We provide new insights into the prograde evolution of HP/LT metasedimentary rocks on the basis of detailed petrologic examination, element-partitioning analysis, and thermodynamic modelling of well-preserved Fe-Mg-carpholite- and Fe-Mg-chloritoid-bearing rocks from the Afyon Zone (Anatolia). We document continuous and discontinuous compositional (ferromagnesian substitution) zoning of carpholite (overall X-Mg = 0.27-0.73) and chloritoid (overall X-Mg = 0.07-0.30), as well as clear equilibrium and disequilibrium (i.e., reaction-related) textures involving carpholite and chloritoid, which consistently account for the consistent enrichment in Mg of both minerals through time, and the progressive replacement of carpholite by chloritoid. Mg/Fe distribution coefficients calculated between carpholite and chloritoid vary widely within samples (2.2-20.0). Among this range, only values of 7-11 correlate with equilibrium textures, in agreement with data from the literature. Equilibrium phase diagrams for metapelitic compositions are calculated using a newly modified thermodynamic dataset, including most recent data for carpholite, chloritoid, chlorite, and white mica, as well as further refinements for Fe-carpholite, and both chloritoid end-members, as required to reproduce accurately petrologic observations (phase relations, experimental constraints, Mg/Fe partitioning). Modelling reveals that Mg/Fe partitioning between carpholite and chloritoid is greatly sensitive to temperature and calls for a future evaluation of possible use as a thermometer. In addition, calculations show significant effective bulk composition changes during prograde metamorphism due to the fractionation of chloritoid formed at the expense of carpholite. We retrieve P-T conditions for several carpholite and chloritoid growth stages (1) during prograde stages using unfractionated, bulk-rock XRF analyses, and (2) at peak conditions using compositions fractionated for chloritoid. The P-T paths reconstructed for the Kutahya and Afyon areas shed light on contrasting temperature conditions for these areas during prograde and peak stages.}, language = {en} } @article{DuesterhoeftQuinterosOberhaenslietal.2014, author = {Duesterhoeft, Erik and Quinteros, Javier and Oberh{\"a}nsli, Roland and Bousquet, Romain and de Capitani, Christian}, title = {Relative impact of mantle densification and eclogitization of slabs on subduction dynamics: A numerical thermodynamic/thermokinematic investigation of metamorphic density evolution}, series = {Tectonophysics : international journal of geotectonics and the geology and physics of the interior of the earth}, volume = {637}, journal = {Tectonophysics : international journal of geotectonics and the geology and physics of the interior of the earth}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0040-1951}, doi = {10.1016/j.tecto.2014.09.009}, pages = {20 -- 29}, year = {2014}, abstract = {Understanding the relationships between density and spatio-thermal variations at convergent plate boundaries is important for deciphering the present-day dynamics and evolution of subduction zones. In particular, the interaction between densification due to mineralogical phase transitions and slab pull forces is subject to ongoing investigations. We have developed a two-dimensional subduction zone model that is based on thermodynamic equilibrium assemblage calculations and includes the effects of melting processes on the density distribution in the lithosphere. Our model calculates the "metamorphic density" of rocks as a function of pressure, temperature and chemical composition in a subduction zone down to 250 km. We have used this model to show how the hydration, dehydration, partial melting and fractionation processes of rocks all influence the metamorphic density and greatly depend on the temperature field within the subduction system. These processes are largely neglected by other approaches that reproduce the density distribution within this complex tectonic setting. Our model demonstrates that the initiation of edogitization (i.e., when crustal rocks reach higher densities than the ambient mantle) of the slab is not the only significant process that makes the descending slab denser and generates the slab pull force. Instead, the densification of the lithospheric mantle of the sinking slab starts earlier than eclogitization and contributes significantly to slab pull in the early stages of subduction. Accordingly, the complex metamorphic structure of the slab and the mantle wedge has an important impact on the development of subduction zones. (C) 2014 Elsevier B.V. All rights reserved.}, language = {en} }