@article{NazirMeilingCywinskietal.2015,
  author    = {Nazir, Rashid and Meiling, Till Thomas and Cywinski, Piotr J. and Gryko, Daniel T.},
  title     = {Synthesis and Optical Properties of alpha,beta-Unsaturated Ketones Bearing a Benzofuran Moiety},
  series = {Asian journal of organic chemistry : an ACES journal},
  volume    = {4},
  journal   = {Asian journal of organic chemistry : an ACES journal},
  number    = {9},
  publisher = {Wiley-VCH},
  address   = {Weinheim},
  issn      = {2193-5807},
  doi       = {10.1002/ajoc.201500242},
  pages     = {929 -- 935},
  year      = {2015},
  abstract  = {Five pi-expanded alpha,beta-unsaturated ketones have been prepared from a strongly electron-rich benzofuran derivative via Knoevenagel reaction and aldol condensation. The incorporation of two 6-didodecylaminobenzofuran-2-yl groups at the periphery of D-pi-A and D-pi-A-pi-D molecules resulted in dyes with excellent solubility in the majority of organic solvents. In contrast to the majority of alpha,beta-unsaturated ketones, these dyes emit relatively strongly in the red region with a fluorescence quantum yield up to 40\%. They also display strong solvatofluorochromism with emission shifting from 570 nm in toluene to 670 nm in CHCl3. Depending on the chemical structure, they two-photon cross-sections (sigma(2)) are up to 1700 GM (1 GM=10(50) cm(4)s photon(-1)).},
  language  = {en}
}