@article{Dietrich2000, author = {Dietrich, Volkmar}, title = {[Projekt] : Wie Fische im Wasser leben}, year = {2000}, language = {de} } @article{SperlichKoeckerling2022, author = {Sperlich, Eric and K{\"o}ckerling, Martin}, title = {[Nb6Cl14(pyrazine)(4)], a versatile precursor for ligand-supported hexanuclear niobium cluster compounds: synthesis, characterization, follow-up reactions, and intermolecular interactions}, series = {Inorganic chemistry}, volume = {61}, journal = {Inorganic chemistry}, number = {5}, publisher = {American Chemical Society}, address = {Washington}, issn = {0020-1669}, doi = {10.1021/acs.inorgchem.1c03109}, pages = {2409 -- 2420}, year = {2022}, abstract = {The compound [Nb6Cl14(pyrazine)(4)]center dot 2CH(2)Cl(2) (1) was investigated for its suitability as a starting compound for new ligand-supported hexanuclear niobium cluster compounds. The synthesis, stability to air and increased temperature, solubility and usability for subsequent reactions of 1, and purification and separation of the reaction products are discussed. The compounds with cluster units [Nb6Cl14L4], where L = iso-quinoline N-oxides (2), 1,1-dimethylethylenediamines (3), or thiazoles (4), and [Nb6Cl14(PEt3)(3.76)(Et3PO)(0.24)]-[Nb6Cl14(MeCN)(4)]center dot 4MeCN (5) are presented as follow-up products. The crystal structures of compounds 1-5 are analyzed, and the structures are discussed with respect to their intraand intermolecular bonding situations and crystal packing. In addition to hydrogen bonds and pi-pi interactions, the appearance of chalcogen and halogen bonds and lone pair-pi interactions between Nb-6 cluster units was observed for the first time.}, language = {en} } @article{SperlichKoeckerling2021, author = {Sperlich, Eric and K{\"o}ckerling, Martin}, title = {[Nb6Cl12(CH3OH)4(OCH3)2] ⋅ DABCO ⋅ 1.66 CH2Cl2}, series = {Zeitschrift f{\"u}r anorganische und allgemeine Chemie : ZAAC = Journal of inorganic and general chemistry}, volume = {647}, journal = {Zeitschrift f{\"u}r anorganische und allgemeine Chemie : ZAAC = Journal of inorganic and general chemistry}, number = {18}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {0044-2313}, doi = {10.1002/zaac.202100138}, pages = {1759 -- 1763}, year = {2021}, abstract = {An easy-to-do synthesis for the hexanuclear niobium cluster compound [Nb6Cl12(CH3OH)(4)(OCH3)(2)] . DABCO . 1.66 CH2Cl2 has been developed. An one-pot reaction between the cluster precursor [Nb6Cl14(H2O)(4)] . 4H(2)O and methanol with the addition of DABCO leads to the crystallization of the title compound in high yield within a few minutes. The single-crystal X-ray structure of this cluster compound has been determined. Very strong, nearly symmetric intercluster hydrogen bonds Nb-6-MeO...H...OMe-Nb-6 are present between the cluster units. A bridging co-crystalline DABCO molecule is also involved in a three-dimensional hydrogen-bonding network.}, language = {en} } @article{Dietrich1993, author = {Dietrich, Volkmar}, title = {[Kap.]Carbons{\"a}uren-Ester und Seifen und Waschmittel}, year = {1993}, language = {de} } @article{Dietrich1991, author = {Dietrich, Volkmar}, title = {[Kap.] Seifen und Waschmittel : Stoffe und chemische Reaktionen}, year = {1991}, language = {de} } @article{Mederow1999, author = {Mederow, Gabriele}, title = {[Kap.] Seifen und Projekt: Seifen und Reinigungsmittel, Kunststoffe}, year = {1999}, language = {de} } @article{Mederow1997, author = {Mederow, Gabriele}, title = {[Kap.] Makromolekulare Stoffe}, year = {1997}, language = {de} } @article{Dietrich1991, author = {Dietrich, Volkmar}, title = {[Kap.] Ermittlung der Zusammensetzung und Struktur von Stoffen}, year = {1991}, language = {de} } @article{Dietrich1999, author = {Dietrich, Volkmar}, title = {[Kap.] Carbons{\"a}uren, Ester-Fette, Seifen und Waschmittel}, year = {1999}, language = {de} } @article{Dietrich2000, author = {Dietrich, Volkmar}, title = {[Kap.] Alkans{\"a}uren, Ester-Fette, Seifen und Waschmittel}, year = {2000}, language = {de} } @article{Kosman2024, author = {Kosman, Admiʾel}, title = {?של מי הנקמה}, series = {אלכסון}, journal = {אלכסון}, year = {2024}, language = {mul} } @article{Mackenbach2011, author = {Mackenbach, Werner}, title = {? De la identidad a la sociabilidad? representationes de la convivencia en las literaturas centroamericanas y caribe{\~n}as}, isbn = {978-3-938944-54-7}, year = {2011}, language = {es} } @article{Weiss2004, author = {Weiß, Norman}, title = {9. Forum Globale Fragen des Ausw{\"a}rtigen Amtes: „Fest entschlossen, unsere Kr{\"a}fte zu vereinen ... " - die Vereinten Nationen als Motor globaler Strukturpolitik <2003, Berlin> / [Tagungsbericht]}, series = {MenschenRechtsMagazin : MRM ; Informationen, Meinungen, Analysen}, volume = {9}, journal = {MenschenRechtsMagazin : MRM ; Informationen, Meinungen, Analysen}, number = {1}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, issn = {1434-2820}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-55725}, pages = {106}, year = {2004}, abstract = {Tagungsbericht: Ausw{\"a}rtiges Amt: „Fest entschlossen, unsere Kr{\"a}fte zu vereinen . . . " - die Vereinten Nationenals Motor globaler Strukturpolitik <2003, Berlin> / (9. Forum Globale Fragen des Ausw{\"a}rtigen Amtes)am 11. und 12. Dezember 2003.}, language = {de} } @article{ZehmFudickarHansetal.2008, author = {Zehm, Daniel and Fudickar, Werner and Hans, Melanie and Schilde, Uwe and Kelling, Alexandra and Linker, Torsten}, title = {9,10-Diarylanthracenes as molecular switches : syntheses, properties, isomerisations and their reactions with singlet oxygen}, issn = {0947-6539}, year = {2008}, abstract = {A series of 9,10-diarylanthracenes with various substituents at the ortho positions have been synthesised by palladium-catalysed cross-coupling reactions. Such compounds exhibit interesting physical properties and can be applied as molecular switches. Despite the high steric demand of the substituents, products were formed in moderate-to-good yields. In some cases, microwave conditions further improved yields. Bis-coupling afforded two isomers (syn and anti) that do not interconvert at room temperature. These products were easily separated and their relative stereochemistries were unequivocally assigned by NMR spectroscopy and X-ray analysis. The syn and anti isomers exhibit different physical properties (e.g., melting points and solubilities) and interconversion by rotation around the aryl-aryl axis commences at <100 °C for fluoro-substituted diarylanthracenes and at >300 °C for alkyl- or alkoxy-substituted diarylanthracenes. The reactions with singlet oxygen were studied separately and revealed different reactivities and reaction pathways. The yields and reactivities depend on the size and electronic nature of the substituents. The anti isomers form the same 9,10-endoperoxides as the syn species, occasionally accompanied by unexpected 1,4-endoperoxides as byproducts. Thermolysis of the endoperoxides exclusively yielded the syn isomers. The interesting rotation around the aryl-aryl axis allows the application of 9,10-diarylanthracenes as molecular switches, which are triggered by light and air under mild conditions. Finally, the oxygenation and thermolysis sequence provides a simple, synthetic access to a single stereoisomer (syn) from an unselective coupling step.}, language = {en} } @article{SchultzeFossSchmidt2020, author = {Schultze, Christiane and Foß, Stefan and Schmidt, Bernd}, title = {8-Prenylflavanones through microwave promoted tandem claisen rearrangement/6-endo-trig cyclization and cross metathesis}, series = {European journal of organic chemistry}, volume = {2020}, journal = {European journal of organic chemistry}, number = {47}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {1434-193X}, doi = {10.1002/ejoc.202001378}, pages = {7373 -- 7384}, year = {2020}, abstract = {Prenylated flavanones were obtained from ortho-allyloxy chalcones through a one-pot sequence of Claisen rearrangement and 6-endo-trig cyclization, followed by olefin cross metathesis of the intermediate allyl flavanones with 2-methyl-2-butene. The synthetic utility of this route is illustrated for the synthesis of several naturally occurring prenyl flavanones.}, language = {en} } @article{YenesewTwinomuhweziKiremireetal.2009, author = {Yenesew, Abiy and Twinomuhwezi, Hannington and Kiremire, Bernard T. and Mbugua, Martin N. and Gitu, Peter M. and Heydenreich, Matthias and Peter, Martin G.}, title = {8-Methoxyneorautenol and radical scavenging flavonoids from Erythrina abyssinica}, issn = {1011-3924}, year = {2009}, abstract = {A new pterocarpan (named 8-methoxyneorautenol) was isolated from the acetone ext. of the root bark of Erythrina abyssinica. In addn., the known isoflavonoid derivs. eryvarin L, erycristagallin and shinpterocarpin were identified for the first time from the roots of this plant. The structures were detd. on the basis of spectroscopic evidence. The new compd. showed selective antimicrobial activity against Trichophyton mentagrophytes. The acetone ext. of the root bark of E. abyssinica showed radical scavenging activity towards 2,2-diphenyl-1-picrylhydrazyl radical (DPPH). The pterocarpenes, 3-hydroxy-9-methoxy-10-(3,3-dimethylallyl)pterocarpene and erycristagallin, were the most active constituents of the roots of this plant and showing dose-dependent activities similar to that of the std. quercetin. [on SciFinder (R)]}, language = {en} } @article{YenesewMushibeIndulietal.2005, author = {Yenesew, Abiy and Mushibe, E. K. and Induli, M. and Derese, Solomon and Midiwo, Jacob O. and Kabaru, Jacques M. and Heydenreich, Matthias and Koch, Andreas and Peter, Martin G.}, title = {7a-O-methyldeguelol, a modified rotenoid with an open ring-C, from the roots of Derris trifoloata}, issn = {0031-9422}, year = {2005}, abstract = {From the acetone extract of the roots of Derris trifoliata an isollavonoid derivative, named 7a-O- methyldeguelol, a modified rotenoid with an open ring-C, representing a new sub-class of isollavonoids (the sub-class is here named as rotenoloid), was isolated and characterised. In addition, the known rotenoids, rotenone, deguelin and alpha-toxicarol, were identified. The structures were determined on the basis of spectroscopic evidence. Rotenone and deguelin were identified as the larvicidal principles of the acetone extract of the roots of Derris trifoliata. (c) 2005 Elsevier Ltd. All rights reserved}, language = {en} } @article{Kosta1996, author = {Kosta, Peter}, title = {70 Years Existence of the Prague Linguistic Circle and 100th Anniversary of Roman Jakobsons Birthday, (Prag, 28. - 30.3.1996).}, year = {1996}, language = {en} } @article{Brechenmacher2019, author = {Brechenmacher, Thomas}, title = {70 Jahre Israel}, series = {Historisch-politische Mitteilungen : Archiv f{\"u}r Christlich-Demokratische Politik}, volume = {26}, journal = {Historisch-politische Mitteilungen : Archiv f{\"u}r Christlich-Demokratische Politik}, publisher = {B{\"o}hlau}, address = {Wien}, isbn = {978-3-412-51847-9}, pages = {5 -- 15}, year = {2019}, abstract = {Schon kurz nach dem Zweiten Weltkrieg wurde die These vertreten, die Shoah sei ein wichtiger, wenn nicht gar entscheidender Faktor f{\"u}r die Gr{\"u}ndung des Staates Israel gewesen. Der Essay arbeitet heraus, dass der nationalsozialistische Judenmord sicherlich eine moralisch-legitimatorische Funktion gehabt hat, ein unmittelbarer kausaler Zusammenhang mit der Staatsgr{\"u}ndung aber nicht nachzuweisen ist.}, language = {de} } @article{ZimmermannHerrmann2021, author = {Zimmermann, Andreas and Herrmann, Franziska}, title = {70 Jahre Genfer Fl{\"u}chtlingskonvention}, series = {Informationsbrief Ausl{\"a}nderrecht}, journal = {Informationsbrief Ausl{\"a}nderrecht}, number = {6}, publisher = {Luchterhand}, address = {K{\"o}ln ; Neuwied}, issn = {0174-2108}, pages = {221 -- 227}, year = {2021}, language = {de} } @article{MuivaMutisyaMachariaHeydenreichetal.2014, author = {Muiva-Mutisya, Lois and Macharia, Bernard and Heydenreich, Matthias and Koch, Andreas and Akala, Hoseah M. and Derese, Solomon and Omosa, Leonidah K. and Yusuf, Amir O. and Kamau, Edwin and Yenesew, Abiy}, title = {6 alpha-Hydroxy-alpha-toxicarol and (+)-tephrodin with antiplasmodial activities from Tephrosia species}, series = {Phytochemistry letters}, volume = {10}, journal = {Phytochemistry letters}, publisher = {Elsevier}, address = {Amsterdam}, issn = {1874-3900}, doi = {10.1016/j.phytol.2014.09.002}, pages = {179 -- 183}, year = {2014}, abstract = {The CH2Cl2/MeOH (1: 1) extract of the roots of Tephrosia villosa showed good antiplasmodial activity against the chloroquine-sensitive (D6) and chloroquine-resistant (W2) strains of Plasmodium falciparum with IC50 values of 3.1 +/- 0.4 and 1.3 +/- 0.3 mu g/mL, respectively. Chromatographic separation of the extract yielded a new rotenoid, 6 alpha-hydroxy-alpha-toxicarol, along with five known rotenoids, (rotenone, deguelin, sumatrol, 12 alpha-hydroxy-alpha-toxicarol and villosinol). Similar treatment of the extract of the stem of Tephrosia purpurea (IC50 = 4.1 +/- 0.4 and 1.9 +/- 0.2 mu g/mL against D6 and W2 strains of P. falciparum, respectively) yielded a new flavone having a unique substituent at C-7/C-8 [trivial name (+)-tephrodin], along with the known flavonoids tachrosin, obovatin methyl ether and derrone. The relative configuration and the most stable conformation in (+)-tephrodin was determined by NMR and theoretical energy calculations. The rotenoids and flavones tested showed good to moderate antiplasmodial activities (IC50 = 9 +/- 23 mu M). Whereas the cytotoxicity of rotenoids is known, the flavones (+)-tephrodin and tachrosin did not show significant cytotoxicity (IC50 > 100 mu M;) against mammalian African monkey kidney (vero) and human larynx carcinoma (HEp2) cell lines. (C) 2014 Phytochemical Society of Europe. Published by Elsevier B.V. All rights reserved.}, language = {en} } @article{ZhangHuangHuangetal.2018, author = {Zhang, Yang and Huang, Wentao and Huang, Baochun and van Hinsbergen, Douwe J. J. and Yang, Tao and Dupont-Nivet, Guillaume and Guo, Zhaojie}, title = {53-43Ma Deformation of Eastern Tibet Revealed by Three Stages of Tectonic Rotation in the Gongjue Basin}, series = {Journal of geophysical research : Solid earth}, volume = {123}, journal = {Journal of geophysical research : Solid earth}, number = {5}, publisher = {American Geophysical Union}, address = {Washington}, issn = {2169-9313}, doi = {10.1002/2018JB015443}, pages = {3320 -- 3338}, year = {2018}, abstract = {The Gongjue basin from the eastern Qiangtang terrane is located in the transition region where the regional structural lineation curves from east-west-oriented in Tibet to north-south-oriented in Yunnan. In this study, we sampled the red beds in the basin from the lower Gongjue to upper Ranmugou formations for the first time covering the entire stratigraphic profile. The stratigraphic ages are bracketed within 53-43Ma by new detrital zircon U-Pb ages constraining the maximum deposition age to 52.51.5Ma. Rock magnetic and petrographic studies indicate that detrital magnetite and hematite are the magnetic carriers. Positive reversals and fold tests demonstrate that the characteristic remanent magnetization has a primary origin. The Gongjue and Ranmugou formations yield mean characteristic remanent magnetization directions of D-s/I-s=31.0 degrees/21.3 degrees and D-s/I-s=15.9 degrees/22.0 degrees, respectively. The magnetic inclination of these characteristic remanent magnetizations is significantly shallowed compared to the expected inclination for the locality. However, the elongation/inclination correction method does not provide a meaningful correction, likely because of syn-depositional rotation. Rotations relative to the Eurasian apparent polar wander path occurred in three stages: Stage I, 33.33.4 degrees clockwise rotation during the deposition of the Gongjue and lower Ranmugou formations; Stage II, 26.93.7 degrees counterclockwise rotation during deposition of the lower and middle Ranmugou formation; and Stage III, 17.73.3 degrees clockwise rotation after 43Ma. The complex rotation history recorded in the basin is possibly linked to sinistral shear along the Qiangtang block during India indentation into Asia and the early stage of the extrusion of the northwestern Indochina blocks away from eastern Tibet.}, language = {en} } @article{Gerhard2021, author = {Gerhard, Reimund}, title = {50 years of International Symposia on Electrets from 1967 to 2017}, series = {IEEE electrical insulation magazine / Institute of Electrical and Electronics Engineers}, volume = {37}, journal = {IEEE electrical insulation magazine / Institute of Electrical and Electronics Engineers}, number = {2}, publisher = {IEEE}, address = {New York, NY}, issn = {0883-7554}, doi = {10.1109/MEI.2021.9352710}, pages = {50 -- 55}, year = {2021}, abstract = {The prehistory of electrets is not known yet, but it is quite likely that the electrostatic charging behavior of amber (Greek: τ{\`o} ηλεκτρoν, i.e., "electron") already was familiar to people in ancient cultures (China, Egypt, Greece, etc.), before the Greek philosopher and scientist Thales of Miletus (6th century BCE)-or rather his disciples and followers-reported it in writing (cf. Figure 1). More than two millennia later, William Gilbert (1544-1603), the physician of Queen Elizabeth I, coined the term "electric" in his book De Magnete, Magneticisque Corporibus, et de Magno Magnete Tellure (1600) for dielectric materials that attract like amber and that included sulfur and glass [1]. The second half of the 18th century saw the invention of the electrophorus or electrophore [2], a capacitive electret device, in 1762 by Johan Carl Wilcke (1732-1796).}, language = {en} } @article{OstermeyerMenzel1999, author = {Ostermeyer, Martin and Menzel, Ralf}, title = {50 Watt average output power with 1.2*DL beam quality from a single rod Nd:YALO laser with phase-conjugating SBS mirror}, year = {1999}, language = {en} } @article{Crome2022, author = {Crome, Erhard}, title = {50 jahre Grundlagenvertrag}, series = {WeltTrends : das außenpolitische Journal}, volume = {30}, journal = {WeltTrends : das außenpolitische Journal}, publisher = {WeltTrends}, address = {Potsdam}, isbn = {978-3-947802-91-3}, issn = {0944-8101}, pages = {56 -- 60}, year = {2022}, language = {de} } @article{Weiss1999, author = {Weiß, Norman}, title = {50 Jahre Europarat}, series = {MenschenRechtsMagazin : MRM ; Informationen, Meinungen, Analysen}, volume = {4}, journal = {MenschenRechtsMagazin : MRM ; Informationen, Meinungen, Analysen}, number = {2}, issn = {1434-2820}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-54668}, pages = {62 -- 64}, year = {1999}, abstract = {Tagungsbericht: Weiß, Norman: 50 Jahre Europarat: Gr{\"u}ndungsvisionen und Bilanz <1999, Potsdam> / 50 Jahre Europarat: Gr{\"u}ndungsvisionen und Bilanz, Tagung am 5. Mai 1999 Das MenschenRechtsZentrum der Universit{\"a}t Potsdam und die Konrad-Adenauer-Stiftung (Bildungswerk Potsdam) veranstalteten gemeinsam am 5. Mai 1999 eine Tagung aus Anlaß des 50j{\"a}hrigen Bestehens des Europarats in Straßburg. Nach einer kurzen Darstellung der historischen Fakten wird ein {\"U}berblick {\"u}ber Inhalt und Ablauf der Veranstaltung gegeben werden.}, language = {de} } @article{Klein2001, author = {Klein, Eckart}, title = {50 Jahre Europarat}, year = {2001}, language = {de} } @article{Weiss1999, author = {Weiß, Norman}, title = {50 Jahre Allgemeine Erkl{\"a}rung der Menschenrechte : zusammenfassender Bericht {\"u}ber drei Veranstaltungen}, year = {1999}, language = {de} } @article{WyschkonSchulzGallitetal.2017, author = {Wyschkon, Anne and Schulz, Franziska and Gallit, Finja Sunnyi and Poltz, Nadine and Kohn-Henkel, Juliane and Moraske, Svenja and Bond{\"u}, Rebecca and von Aster, Michael G. and Esser, G{\"u}nter}, title = {5-Jahres-Verlauf der LRS}, series = {Zeitschrift f{\"u}r Kinder- und Jugendpsychiatrie und Psychotherapie}, volume = {46}, journal = {Zeitschrift f{\"u}r Kinder- und Jugendpsychiatrie und Psychotherapie}, number = {2}, publisher = {Hogrefe}, address = {Bern}, issn = {1422-4917}, doi = {10.1024/1422-4917/a000535}, pages = {107 -- 122}, year = {2017}, abstract = {Fragestellung: Untersucht wird der Verlauf von Kindern mit Lese-Rechtschreibst{\"o}rungen (LRS) {\"u}ber gut 5 Jahre unter Ber{\"u}cksichtigung des Einflusses des Geschlechts der Betroffenen. Außerdem werden Auswirkungen der LRS auf das sp{\"a}tere Schriftsprachniveau und den Schulerfolg {\"u}berpr{\"u}ft. Methodik: Eingangs wurden 995 Sch{\"u}ler zwischen 6 und 16 Jahren untersucht. Ein Teil dieser Kinder ist nach 43 sowie 63 Monaten nachuntersucht worden. Eine LRS wurde diagnostiziert, wenn f{\"u}r das Lesen bzw. Rechtschreiben das doppelte Diskrepanzkriterium von 1.5 Standardabweichungen zur nonverbalen Intelligenz und dem Mittelwert der Klassenstufe erf{\"u}llt war und gleichzeitig keine Minderbegabung vorlag. Ergebnisse: Die LRS weist {\"u}ber einen Zeitraum von 63 Monaten eine hohe St{\"o}rungspersistenz von knapp 70 \% auf. Der 5-Jahres-Verlauf der mittleren Lese- und Rechtschreibleistungen wurde nicht vom Geschlecht beeinflusst. Trotz durchschnittlicher Intelligenz blieben die LRS-Sch{\"u}ler in der Schriftsprache mindestens eine Standardabweichung hinter durchschnittlich und etwa 0.5 Standardabweichungseinheiten hinter unterdurchschnittlich intelligenten Kindern zur{\"u}ck. Der Schulerfolg der LRS-Sch{\"u}ler glich dem unterdurchschnittlich intelligenter Kinder und fiel deutlich schlechter aus als bei durchschnittlich intelligenten Kontrollkindern. Schlussfolgerungen: Eine LRS stellt ein erhebliches Entwicklungsrisiko dar, was fr{\"u}hzeitige Diagnostik- und Therapiemaßnahmen erfordert. Daf{\"u}r sind reliable und im Hinblick auf die resultierenden Pr{\"a}valenzraten sinnvolle, allgemein anerkannte Diagnosekriterien essenziell.}, language = {de} } @article{SengeRyppaFazekasetal.2011, author = {Senge, Mathias O. and Ryppa, Claudia and Fazekas, Marijana and Zawadzka, Monika and Dahms, Katja}, title = {5,10-A2B2-Type meso-Substituted PorphyrinsuA Unique Class of Porphyrins with a Realigned Dipole Moment}, series = {Chemistry - a European journal}, volume = {17}, journal = {Chemistry - a European journal}, number = {48}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {0947-6539}, doi = {10.1002/chem.201101934}, pages = {13562 -- 13573}, year = {2011}, abstract = {Current applications in porphyrin chemistry require the use of unsymmetrically substituted porphyrins. Many current industrial interests in optics and biomedicine require systems with either pushpull (electron-donating and -withdrawing groups) or amphiphilic systems (hydrophobic and hydrophilic groups). In this context we present the class of 5,10-A2B2-type porphyrins for which two different substituents are positioned in diagonally opposite meso positions. Thus, the intramolecular dipole moment in these tetrapyrroles is positioned along a beta-beta vector passing through two pyrrole rings. This is opposite to the situation of the frequently used 5,15-A2BC porphyrins for which the dipole moment is oriented along a mesomeso axis. We have elaborated syntheses of the 5,10-A2B2 porphyrins by using transition-metal-catalyzed transformations of 5,10-A2 porphyrins or direct substitutions reactions thereof; this gives the target molecules in 2277\% overall yields. The compounds exhibit interesting structural, spectroscopic, and optical features and can serve as building blocks for new porphyrin arrays and applications.}, language = {en} } @article{MazurekBudzyńskaBehlNeumannetal.2022, author = {Mazurek-Budzyńska, Magdalena and Behl, Marc and Neumann, Richard and Lendlein, Andreas}, title = {4D-actuators by 3D-printing combined with water-based curing}, series = {Materials today. Communications}, volume = {30}, journal = {Materials today. Communications}, publisher = {Elsevier}, address = {Amsterdam}, issn = {2352-4928}, doi = {10.1016/j.mtcomm.2021.102966}, pages = {7}, year = {2022}, abstract = {The shape and the actuation capability of state of the art robotic devices typically relies on multimaterial systems from a combination of geometry determining materials and actuation components. Here, we present multifunctional 4D-actuators processable by 3D-printing, in which the actuator functionality is integrated into the shaped body. The materials are based on crosslinked poly(carbonate-urea-urethane) networks (PCUU), synthesized in an integrated process, applying reactive extrusion and subsequent water-based curing. Actuation capability could be added to the PCUU, prepared from aliphatic oligocarbonate diol, isophorone diisocyanate (IPDI) and water, in a thermomechanical programming process. When programmed with a strain of epsilon(prog) = 1400\% the PCUU networks exhibited actuation apparent by reversible elongation epsilon'(rev) of up to 22\%. In a gripper a reversible bending epsilon'(rev)((be)(nd)()) in the range of 37-60\% was achieved when the actuation temperature (T-high) was varied between 45 degrees C and 49 degrees C. The integration of actuation and shape formation could be impressively demonstrated in two PCUU-based reversible fastening systems, which were able to hold weights of up to 1.1 kg. In this way, the multifunctional materials are interesting candidate materials for robotic applications where a freedom in shape design and actuation is required as well as for sustainable fastening systems.}, language = {en} } @article{DzhunushalievSchmidt1999, author = {Dzhunushaliev, Vladimir and Schmidt, Hans-J{\"u}rgen}, title = {4D wormhole with signature change in the presence of extra dimensions}, series = {General relativity and quantum cosmology : preprints gr-qc}, volume = {9908076}, journal = {General relativity and quantum cosmology : preprints gr-qc}, year = {1999}, language = {en} } @article{AllroggenvanSchaikTronicke2015, author = {Allroggen, Niklas and van Schaik, N. Loes M. B. and Tronicke, Jens}, title = {4D ground-penetrating radar during a plot scale dye tracer experiment}, series = {Journal of applied geophysics}, volume = {118}, journal = {Journal of applied geophysics}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0926-9851}, doi = {10.1016/j.jappgeo.2015.04.016}, pages = {139 -- 144}, year = {2015}, abstract = {Flow phenomena in the unsaturated zone are highly variable in time and space. Thus, it is challenging to measure and monitor such processes under field conditions. Here, we present a new setup and interpretation approach for combining a dye tracer experiment with a 4D ground-penetrating radar (GPR) survey. Therefore, we designed a rainfall experiment during which we measured three surface-based 3D GPR surveys using a pair of 500 MHz antennas. Such a survey setup requires accurate acquisition and processing techniquesto extract time-lapse information supporting the interpretation of selected cross-sections photographed after excavating the site. Our results reveal patterns of traveltime changes in the measured GPR data, which are associated with soil moisture changes. As distinct horizons are present at our site, such changes can be quantified and transferred into changes in total soil moisture content. Our soil moisture estimates are similar to the amount of infiltrated water, which confirms our experimental approach and makes us confident for further developing this strategy, especially, with respect to improving the temporal and spatial resolution. (C) 2015 Elsevier B.V. All rights reserved.}, language = {en} } @article{KrmičekTimmermanZiemannetal.2020, author = {Krm{\´i}ček, Luk{\´a}š and Timmerman, Martin Jan and Ziemann, Martin Andreas and Sudo, Masafumi and Ulrych, Jaromir}, title = {40Ar/39Ar step-heating dating of phlogopite and kaersutite megacrysts from the Železn{\´a} hůrka (Eisenb{\"u}hl) Pleistocene scoria cone, Czech Republic}, series = {Geologica Carpathica}, volume = {71}, journal = {Geologica Carpathica}, number = {4}, publisher = {Veda}, address = {Bratislava}, issn = {1335-0552}, doi = {10.31577/GeolCarp.71.4.6}, pages = {382 -- 387}, year = {2020}, abstract = {(40)A/Ar-39 step-heating of mica and amphibole megacrysts from hauyne-bearing olivine melilitite scoria/tephra from the Zelezna hurka yielded a 435 +/- 108 ka isotope correlation age for phlogopite and a more imprecise 1.55 Ma total gas age of the kaersutite megacryst. The amphibole megacrysts may constitute the first, and the younger phlogopite megacrysts the later phase of mafic, hydrous melilitic magma crystallization. It cannot be ruled out that the amphibole megacrysts are petrogenetically unrelated to tephra and phlogopite megacrysts and were derived from mantle xenoliths or disaggregated older, deep crustal pegmatites. This is in line both with the rarity of amphibole at Zelezna hurka and with the observed signs of magmatic resorption at the edges of amphibole crystals.}, language = {en} } @article{FranzSudoKhomenko2022, author = {Franz, Gerhard and Sudo, Masafumi and Khomenko, Vladimir}, title = {40Ar/39Ar dating of a hydrothermal pegmatitic buddingtonite-muscovite assemblage from Volyn, Ukraine}, series = {European journal of mineralogy : EJM : an international journal on mineralogy, petrology, geochemistry, and related sciences}, volume = {34}, journal = {European journal of mineralogy : EJM : an international journal on mineralogy, petrology, geochemistry, and related sciences}, number = {1}, publisher = {Copernicus}, address = {G{\"o}ttingen}, issn = {0935-1221}, doi = {10.5194/ejm-34-7-2022}, pages = {7 -- 18}, year = {2022}, abstract = {We determined Ar-40/Ar-39 ages of buddingtonite, occurring together with muscovite, with the laser-ablation method. This is the first attempt to date the NH4-feldspar buddingtonite, which is typical for sedimentary-diagenetic environments of sediments, rich in organic matter, or in hydrothermal environments, associated with volcanic geyser systems. The sample is a hydrothermal breccia, coming from the Paleoproterozoic pegmatite field of the Korosten Plutonic Complex, Volyn, Ukraine. A detailed characterization by optical methods, electron microprobe analyses, backscattered electron imaging, and IR analyses showed that the buddingtonite consists of euhedral-appearing platy crystals of tens of micrometers wide, 100 or more micrometers in length, which consist of fine-grained fibers of <= 1 mu m thickness. The crystals are sector and growth zoned in terms of K-NH4-H3O content. The content of K allows for an age determination with the Ar-40/Ar-39 method, as well as in the accompanying muscovite, intimately intergrown with the buddingtonite. The determinations on muscovite yielded an age of 1491 +/- 9 Ma, interpreted as the hydrothermal event forming the breccia. However, buddingtonite apparent ages yielded a range of 563 +/- 14 Ma down to 383 +/- 12 Ma, which are interpreted as reset ages due to Ar loss of the fibrous buddingtonite crystals during later heating. We conclude that buddingtonite is suited for Ar-40/Ar-39 age determinations as a supplementary method, together with other methods and minerals; however, it requires a detailed mineralogical characterization, and the ages will likely represent minimum ages.}, language = {en} } @article{SchwarzerHuamaniCanoetal.2010, author = {Schwarzer, Christian and Huamani, Fatima Cßceres and Cano, Asunci{\´o}n and La Torre, Mar{\´i}a I. La and Weigend, Maximilian}, title = {400 years for long-distance dispersal and divergence in the northern atacama desert : insights from the Huaynaputina pumice slopes of Moquegua, Peru}, issn = {0140-1963}, doi = {10.1016/j.jaridenv.2010.05.034}, year = {2010}, abstract = {The Huaynaputina eruption (1600 AD, Moquegua, S Peru) in the northern Atacama Desert denuded the Ornate area of all vegetation and deposited deep pumice layers. Data on the flora, climate and soil characteristics of these slopes near Ornate at 1600-2600 m a.s.l. are provided. Fifty-nine angiosperm species established themselves on the pumice slopes in the past ca. 400 years, with the bulk of the small and herbaceous species and several species new records for Peru. Three Ornate sites were sampled in both a dry and a wet year and species numbers differed widely (14 versus 45 spp.). Among areas compared floristic composition is most similar to the Lomas de Tacna, and has less in common with geographically closer Lomas or Sierra formations. Nine species represent highly disjunct populations (200->700 km) from their nearest known living populations in central Peru, Chile, or Argentina/Bolivia and appear to have reached the area via long-distance dispersal. Abiotic conditions may have played an important role in limiting the establishment of species from the neighboring vegetation. Four taxa on the pumice slopes show clear morphological differences to populations elsewhere, two of them may represent neoendemics of the Ornate pumice, indicating rapid morphological divergence. (C) 2010 Elsevier Ltd. All rights reserved.}, language = {en} } @article{Moeller2005, author = {M{\"o}ller, Angelika}, title = {40 Jahre Mathematikklub und 30 Jahre Andreas Klee als Leiter des Klubs}, year = {2005}, language = {de} } @article{LazarevaShainyanKleinpeter2010, author = {Lazareva, Nataliya F. and Shainyan, Bagrat A. and Kleinpeter, Erich}, title = {4-Alkyl-2,2,6,6-tetramethyl-1,4,2,6-oxaazadisilinanes : synthesis, structure, and conformational analysis}, issn = {0894-3230}, doi = {10.1002/Poc.1605}, year = {2010}, abstract = {4-Alkyl-2,2,6,6-tetramethyl-1,4,2,6-oxaazadisilinanes RN[CH2Si(Me)2]2O [R = Me (1), i-Pr (2)] were synthesized by two methods which provided good yields up to 84\%. Low temperature NMR study of compounds (1) and (2) revealed a frozen ring inversion with the energy barriers of 8.5 and 7.7 kcal/mol at 163 and 143 K, respectively, which is substantially lower than that for their carbon analog, N-methylmorpholine. DFT calculations performed on the example of molecule (1) showed that N-Meax conformer to exist in the sofa conformation with the coplanar fragment C-Si-O-Si-C, and its N-Meeq conformer in a flattened chair conformation.}, language = {en} } @article{AwadSchildeStrauch2011, author = {Awad, Duha Jawad and Schilde, Uwe and Strauch, Peter}, title = {4,4 '-Bis(tert-butyl)-2,2 '-bipyridinedichlorometal(II) - Synthesis, structure and EPR spectroscopy}, series = {Inorganica chimica acta : the international inorganic chemistry journal}, volume = {365}, journal = {Inorganica chimica acta : the international inorganic chemistry journal}, number = {1}, publisher = {Elsevier}, address = {Lausanne}, issn = {0020-1693}, doi = {10.1016/j.ica.2010.08.035}, pages = {127 -- 132}, year = {2011}, abstract = {Due to the better solubility of the 4,4'-substituted bipyridine ligand a series of 4,4'0-bis(tert-butyl)-2,2'-bipyridinedichlorometal(II) complexes, [M(tbbpy)Cl(2)], with M = Cu, Ni, Zn, Pd, Pt was synthesised and characterised. The blue copper complex 4,4'-bis(tert-butyl)-2,2'-bipyridinedichlorocopper(II) was isolated in two different polymorphic forms, as prisms 1 with a solvent inclusion and solvent-free as needles 2. Both structures were determined by X-ray structure analysis. They crystallise in the monoclinic space group P2(1)/c with four molecules in the unit cell, but with different unit cells and packing motifs. Whereas in the prisms 1, with the unit cell parameters a = 12.1613(12), b = 10.6363(7), c = 16.3074(15) angstrom, eta = 94.446(8)degrees, the packing is dominated by intra-and intermolecular hydrogen bonds, in the needles 2, with a = 7.738(1), b = 18. 333(2), c = 13.291(3) angstrom, beta = 97.512(15)degrees, only intramolecular hydrogen bonds appear and the complex molecules are arranged in columns which are stabilised by p-p-stacking interactions. In both complexes the copper has a tetrahedrally distorted coordination sphere. These copper complexes were also studied by EPR spectroscopy in solution, as frozen glass and diamagnetically diluted powder with the analogue [Pd(tbbpy)Cl(2)] as host lattice.}, language = {en} } @article{DereseBarasaAkalaetal.2014, author = {Derese, Solomon and Barasa, Leonard and Akala, Hoseah M. and Yusuf, Amir O. and Kamau, Edwin and Heydenreich, Matthias and Yenesew, Abiy}, title = {4 '-Prenyloxyderrone from the stem bark of Millettia oblata ssp teitensis and the antiplasmodial activities of isoflavones from some Millettia species}, series = {Phytochemistry letters}, volume = {8}, journal = {Phytochemistry letters}, publisher = {Elsevier}, address = {Amsterdam}, issn = {1874-3900}, doi = {10.1016/j.phytol.2014.02.001}, pages = {69 -- 72}, year = {2014}, abstract = {The CH2Cl2/MeOH (1: 1) extract of the stem bark of Millettia oblata ssp. teitensis showed antiplasmodial activity (IC50 = 10-12 mu g/mL) against the chloroquine-sensitive (D6) and chloroquine-resistant (W2) strains of Plasmodium falciparum. Chromatographic separation of the extract led to the isolation of a new isoflavone, 4'-prenyloxyderrone (1), together with known isoflavones (8-O-methylretusin, durmillone, maximaisoflavone B, maximaisoflavone H and maximaisoflavone J), a rotenoid (tephrosin) and a triterpene (lupeol). Similar investigation of Millettia leucantha resulted in the identification of the isoflavones afrormosin and wistin, and the flavone chrysin. The identification of these compounds was based on their spectroscopic data. Five of the isoflavones isolated from these plants as well as 11 previously reported compounds from Millettia dura were tested and showed good to moderate antiplasmodial activities (IC50 = 13-53 mu M), with the new compound, 4'-prenyloxyderrone, being the most active (IC50 = 13-15 mu M).}, language = {en} } @article{SarauliPetersXuetal.2014, author = {Sarauli, David and Peters, Kristina and Xu, Chenggang and Schulz, Burkhard and Fattakhova-Rohlfing, Dina and Lisdat, Fred}, title = {3D-Electrode architectures for enhanced direct bioelectrocatalysis of pyrroloquinoline quinone-dependent glucose dehydrogenase}, series = {ACS applied materials \& interfaces}, volume = {6}, journal = {ACS applied materials \& interfaces}, number = {20}, publisher = {American Chemical Society}, address = {Washington}, issn = {1944-8244}, doi = {10.1021/am5046026}, pages = {17887 -- 17893}, year = {2014}, abstract = {We report on the fabrication of a complex electrode architecture for efficient direct bioelectrocatalysis. In the developed procedure, the redox enzyme pyrroloquinoline quinone-dependent glucose dehydrogenase entrapped in a sulfonated polyaniline [poly(2-methoxyaniline-5-sulfonic acid)-co-aniline] was immobilized on macroporous indium tin oxide (macroITO) electrodes. The use of the 3D-conducting scaffold with a large surface area in combination with the conductive polymer enables immobilization of large amounts of enzyme and its efficient communication with the electrode, leading to enhanced direct bioelectrocatalysis. In the presence of glucose, the fabricated bioelectrodes show an exceptionally high direct bioelectrocatalytical response without any additional mediator. The catalytic current is increased more than 200-fold compared to planar ITO electrodes. Together with a high long-term stability (the current response is maintained for >90\% of the initial value even after 2 weeks of storage), the transparent 3D macroITO structure with a conductive polymer represents a valuable basis for the construction of highly efficient bioelectronic units, which are useful as indicators for processes liberating glucose and allowing optical and electrochemical transduction.}, language = {en} } @article{ThompsonKliemToeroek2012, author = {Thompson, W. T. and Kliem, Bernhard and Toeroek, Tibor}, title = {3D reconstruction of a rotating erupting prominence}, series = {Solar physics : a journal for solar and solar-stellar research and the study of solar terrestrial physics}, volume = {276}, journal = {Solar physics : a journal for solar and solar-stellar research and the study of solar terrestrial physics}, number = {1-2}, publisher = {Springer}, address = {Dordrecht}, issn = {0038-0938}, doi = {10.1007/s11207-011-9868-5}, pages = {241 -- 259}, year = {2012}, abstract = {A bright prominence associated with a coronal mass ejection (CME) was seen erupting from the Sun on 9 April 2008. This prominence was tracked by both the Solar Terrestrial Relations Observatory (STEREO) EUVI and COR1 telescopes, and was seen to rotate about the line of sight as it erupted; therefore, the event has been nicknamed the "Cartwheel CME." The threads of the prominence in the core of the CME quite clearly indicate the structure of a weakly to moderately twisted flux rope throughout the field of view, up to heliocentric heights of 4 solar radii. Although the STEREO separation was 48A degrees, it was possible to match some sharp features in the later part of the eruption as seen in the 304 line in EUVI and in the H alpha-sensitive bandpass of COR1 by both STEREO Ahead and Behind. These features could then be traced out in three-dimensional space, and reprojected into a view in which the eruption is directed toward the observer. The reconstructed view shows that the alignment of the prominence to the vertical axis rotates as it rises up to a leading-edge height of a parts per thousand aEuro parts per thousand 2.5 solar radii, and then remains approximately constant. The alignment at 2.5 solar radii differs by about 115A degrees from the original filament orientation inferred from H alpha and EUV data, and the height profile of the rotation, obtained here for the first time, shows that two thirds of the total rotation are reached within a parts per thousand aEuro parts per thousand 0.5 solar radii above the photosphere. These features are well reproduced by numerical simulations of an unstable moderately twisted flux rope embedded in external flux with a relatively strong shear field component.}, language = {en} } @article{KoyanTronicke2020, author = {Koyan, Philipp and Tronicke, Jens}, title = {3D modeling of ground-penetrating radar data across a realistic sedimentary model}, series = {Computers \& geosciences : an international journal devoted to the publication of papers on all aspects of geocomputation and to the distribution of computer programs and test data sets ; an official journal of the International Association for Mathematical Geology}, volume = {137}, journal = {Computers \& geosciences : an international journal devoted to the publication of papers on all aspects of geocomputation and to the distribution of computer programs and test data sets ; an official journal of the International Association for Mathematical Geology}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0098-3004}, doi = {10.1016/j.cageo.2020.104422}, pages = {9}, year = {2020}, abstract = {Ground-penetrating radar (GPR) is an established geophysical tool to explore a wide range of near-surface environments. Today, the use of synthetic GPR data is largely limited to 2D because 3D modeling is computationally more expensive. In fact, only recent developments of modeling tools and powerful hardware allow for a time-efficient computation of extensive 3D data sets. Thus, 3D subsurface models and resulting GPR data sets, which are of great interest to develop and evaluate novel approaches in data analysis and interpretation, have not been made publicly available up to now.
We use a published hydrofacies data set of an aquifer-analog study within fluvio-glacial deposits to infer a realistic 3D porosity model showing heterogeneities at multiple spatial scales. Assuming fresh-water saturated sediments, we generate synthetic 3D GPR data across this model using novel GPU-acceleration included in the open-source software gprMax. We present a numerical approach to examine 3D wave-propagation effects in modeled GPR data. Using the results of this examination study, we conduct a spatial model decomposition to enable a computationally efficient 3D simulation of a typical GPR reflection data set across the entire model surface. We process the resulting GPR data set using a standard 3D structural imaging sequence and compare the results to selected input data to demonstrate the feasibility and potential of the presented modeling studies. We conclude on conceivable applications of our 3D GPR reflection data set and the underlying porosity model, which are both publicly available and, thus, can support future methodological developments in GPR and other near-surface geophysical techniques.}, language = {en} } @article{UhligMadaboosiSchmidtetal.2012, author = {Uhlig, Katja and Madaboosi, Narayanan and Schmidt, Stephan and J{\"a}ger, Magnus S. and Rose, J{\"u}rgen and Duschl, Claus and Volodkin, Dmitry V.}, title = {3d localization and diffusion of proteins in polyelectrolyte multilayers}, series = {Soft matter}, volume = {8}, journal = {Soft matter}, number = {47}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {1744-683X}, doi = {10.1039/c2sm26500a}, pages = {11786 -- 11789}, year = {2012}, abstract = {The interaction of diverse biomaterials with surfaces is more crucial than ever for biomedical applications to ensure efficiency and reproducibility. Very interesting surface materials are micrometer-thick polyelectrolyte multilayers. Not only their surface but also the bulk can be loaded with biomaterials like proteins or DNA for various purposes. Therefore, we established a method to analyze the lateral and vertical distribution of fluorescently labelled proteins of various size and charge in polyelectrolyte films composed of poly(L-lysine) and hyaluronic acid by confocal laser scanning microscopy. This approach enables us to measure the diffusion coefficients of the proteins via fluorescence recovery after photobleaching as a function of their vertical position in the film and facilitates the understanding of molecular interactions in the film with a high resolution in both space and time. As a result, we confirm that protein loading in the film is driven by electrostatic interactions - uncharged dextran molecules of 10 and 500 kDa do not diffuse into the film. Proteins of different sizes (3-11 nm) can diffuse relatively fast (D = 2-4 mm(2) s(-1)) independent of their net charge, indicating complex interpolymer interactions. This approach is a new powerful experimental tool to design the polyelectrolyte multilayers for bio-applications by finding a relationship between intermolecular interactions and mobility and availability of biomolecules to biological samples (e.g. cells) or detection units (e.g. biosensors).}, language = {en} } @article{PlatzWeckmannPeketal.2022, author = {Platz, Anna and Weckmann, Ute and Pek, Josef and Kovacikova, Svetlana and Klanica, Radek and Mair, Johannes and Aleid, Basel}, title = {3D imaging of the subsurface electrical resistivity structure in West Bohemia/Upper Palatinate covering mofettes and quaternary volcanic structures by using magnetotellurics}, series = {Tectonophysics : international journal of geotectonics and the geology and physics of the interior of the earth}, volume = {833}, journal = {Tectonophysics : international journal of geotectonics and the geology and physics of the interior of the earth}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0040-1951}, doi = {10.1016/j.tecto.2022.229353}, pages = {20}, year = {2022}, abstract = {The region of West Bohemia and Upper Palatinate belongs to the West Bohemian Massif. The study area is situated at the junction of three different Variscan tectonic units and hosts the ENE-WSW trending Ohre Rift as well as many different fault systems. The entire region is characterized by ongoing magmatic processes in the intra-continental lithospheric mantle expressed by a series of phenomena, including e.g. the occurrence of repeated earthquake swarms and massive degassing of mantle derived CO2 in form of mineral springs and mofettes. Ongoing active tectonics is mainly manifested by Cenozoic volcanism represented by different Quaternary volcanic structures. All these phenomena make the Ohre Rift a unique target area for European intra-continental geo-scientific research. With magnetotelluric (MT) measurements we image the subsurface distribution of the electrical resistivity and map possible fluid pathways. Two-dimensional (2D) inversion results by Munoz et al. (2018) reveal a conductive channel in the vicinity of the earthquake swarm region that extends from the lower crust to the surface forming a pathway for fluids into the region of the mofettes. A second conductive channel is present in the south of their model; however, their 2D inversions allow ambiguous interpretations of this feature. Therefore, we conducted a large 3D MT field experiment extending the study area towards the south. The 3D inversion result matches well with the known geology imaging different fluid/magma reservoirs at crust-mantle depth and mapping possible fluid pathways from the reservoirs to the surface feeding known mofettes and spas. A comparison of 3D and 2D inversion results suggests that the 2D inversion results are considerably characterized by 3D and off-profile structures. In this context, the new results advocate for the swarm earthquakes being located in the resistive host rock surrounding the conductive channels; a finding in line with observations e.g. at the San Andreas Fault, California.}, language = {en} } @article{BrellSeglGuanteretal.2019, author = {Brell, Maximilian and Segl, Karl and Guanter, Luis and Bookhagen, Bodo}, title = {3D hyperspectral point cloud generation}, series = {ISPRS journal of photogrammetry and remote sensing : official publication of the International Society for Photogrammetry and Remote Sensing}, volume = {149}, journal = {ISPRS journal of photogrammetry and remote sensing : official publication of the International Society for Photogrammetry and Remote Sensing}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0924-2716}, doi = {10.1016/j.isprsjprs.2019.01.022}, pages = {200 -- 214}, year = {2019}, abstract = {Remote Sensing technologies allow to map biophysical, biochemical, and earth surface parameters of the land surface. Of especial interest for various applications in environmental and urban sciences is the combination of spectral and 3D elevation information. However, those two data streams are provided separately by different instruments, namely airborne laser scanner (ALS) for elevation and a hyperspectral imager (HSI) for high spectral resolution data. The fusion of ALS and HSI data can thus lead to a single data entity consistently featuring rich structural and spectral information. In this study, we present the application of fusing the first pulse return information from ALS data at a sub-decimeter spatial resolution with the lower-spatial resolution hyperspectral information available from the HSI into a hyperspectral point cloud (HSPC). During the processing, a plausible hyperspectral spectrum is assigned to every first-return ALS point. We show that the complementary implementation of spectral and 3D information at the point-cloud scale improves object-based classification and information extraction schemes. This improvements have great potential for numerous land cover mapping and environmental applications.}, language = {en} } @article{PhamPetreBerquezetal.2009, author = {Pham, Cong Duc and Petre, Anca and Berquez, Laurent and Flores Su{\´a}rez, Rosaura and Mellinger, Axel and Wirges, Werner and Gerhard, Reimund}, title = {3D high-resolution mapping of polarization profiles in thin poly(vinylidenefluoride-trifluoroethylene) (PVDF- TrFE) films using two thermal techniques}, issn = {1070-9878}, doi = {10.1109/TDEI.2009.5128505}, year = {2009}, abstract = {In this paper, two non-destructive thermal methods are used in order to determine, with a high degree of accuracy, three-dimensional polarization distributions in thin films (12 mu m) of poly(vinylidenefluoride- trifluoroethylene) (PVDF-TrFE). The techniques are the frequency-domain Focused Laser Intensity Modulation Method (FLIMM) and time-domain Thermal-Pulse Tomography (TPT). Samples were first metalized with grid-shaped electrode and poled. 3D polarization mapping yielded profiles which reproduce the electrode-grid shape. The polarization is not uniform across the sample thickness. Significant polarization values are found only at depths beyond 0.5 mu m from the sample surface. Both methods provide similar results, TPT method being faster, whereas the FLIMM technique has a better lateral resolution.}, language = {en} } @article{SchennenTronickeWetterichetal.2016, author = {Schennen, Stephan and Tronicke, Jens and Wetterich, Sebastian and Allroggen, Niklas and Schwamborn, Georg and Schirrmeister, Lutz}, title = {3D ground-penetrating radar imaging of ice complex deposits in northern East Siberia}, series = {Geophysics}, volume = {81}, journal = {Geophysics}, publisher = {Society of Exploration Geophysicists}, address = {Tulsa}, issn = {0016-8033}, doi = {10.1190/GEO2015-0129.1}, pages = {WA195 -- WA202}, year = {2016}, abstract = {Ice complex deposits are characteristic, ice-rich formations in northern East Siberia and represent an important part in the arctic carbon pool. Recently, these late Quaternary deposits are the objective of numerous investigations typically relying on outcrop and borehole data. Many of these studies can benefit from a 3D structural model of the subsurface for upscaling their observations or for constraining estimations of inventories, such as the local carbon stock. We have addressed this problem of structural imaging by 3D ground-penetrating radar (GPR), which, in permafrost studies, has been primarily used for 2D profiling. We have used a 3D kinematic GPR surveying strategy at a field site located in the New Siberian Archipelago on top of an ice complex. After applying a 3D GPR processing sequence, we were able to trace two horizons at depths below 20 m. Taking available borehole and outcrop data into account, we have interpreted these two features as interfaces of major lithologic units and derived a 3D cryostratigraphic model of the subsurface. Our data example demonstrated that a 3D surveying and processing strategy was crucial at our field site and showed the potential of 3D GPR to image geologic structures in complex ice-rich permafrost landscapes.}, language = {en} } @article{KoyanTronickeAllroggen2021, author = {Koyan, Philipp and Tronicke, Jens and Allroggen, Niklas}, title = {3D ground-penetrating radar attributes to generate classified facies models}, series = {Geophysics}, volume = {86}, journal = {Geophysics}, number = {6}, publisher = {Society of Exploration Geophysicists}, address = {Tulsa}, issn = {0016-8033}, doi = {10.1190/GEO2021-0204.1}, pages = {B335 -- B347}, year = {2021}, abstract = {Ground-penetrating radar (GPR) is a standard geophysical technique used to image near-surface structures in sedimentary environments. In such environments, GPR data acquisition and processing are increasingly following 3D strategies. However, the processed GPR data volumes are typically still interpreted using selected 2D slices and manual concepts such as GPR facies analyses. In seismic volume interpretation, the application of (semi-)automated and reproducible approaches such as 3D attribute analyses as well as the production of attribute-based facies models are common practices today. In contrast, the field of 3D GPR attribute analyses and corresponding facies models is largely untapped. We have developed and applied a workflow to produce 3D attribute-based GPR facies models comprising the dominant sedimentary reflection patterns in a GPR volume, which images complex sandy structures on the dune island of Spiekeroog (Northern Germany). After presenting our field site and details regarding our data acquisition and processing, we calculate and filter 3D texture attributes to generate a database comprising the dominant texture features of our GPR data. Then, we perform a dimensionality reduction of this database to obtain meta texture attributes, which we analyze and integrate using composite imaging and (also considering additional geometric information) fuzzy c-means cluster analysis resulting in a classified GPR facies model. Considering our facies model and a corresponding GPR facies chart, we interpret our GPR data set in terms of near-surface sedimentary units, the corresponding depositional environments, and the recent formation history at our field site. Thus, we demonstrate the potential of our workflow, which represents a novel and clear strategy to perform a more objective and consistent interpretation of 3D GPR data collected across different sedimentary environments.}, language = {en} } @article{AllroggenHeinckeKoyanetal.2022, author = {Allroggen, Niklas and Heincke, Bjorn H. and Koyan, Philipp and Wheeler, Walter and Ronning, Jan S.}, title = {3D ground-penetrating radar attribute classification}, series = {Geophysics}, volume = {87}, journal = {Geophysics}, number = {4}, publisher = {Society of Exploration Geophysicists}, address = {Tulsa}, issn = {0016-8033}, doi = {10.1190/GEO2021-0651.1}, pages = {WB19 -- WB30}, year = {2022}, abstract = {Ground-penetrating radar (GPR) is a method that can provide detailed information about the near subsurface in sedimentary and carbonate environments. The classical interpretation of GPR data (e.g., based on manual feature selection) often is labor-intensive and limited by the experience of the intercally used for seismic interpretation, can provide faster, more repeatable, and less biased interpretations. We have recorded a 3D GPD data set collected across a paleokarst breccia pipe in the Billefjorden area on Spitsbergen, Svalbard. After performing advanced processing, we compare the results of a classical GPR interpretation to the results of an attribute-based classification. Our attribute classification incorporates a selection of dip and textural attributes as the input for a k-means clustering approach. Similar to the results of the classical interpretation, the resulting classes differentiate between undisturbed strata and breccias or fault zones. The classes also reveal details inside the breccia pipe that are not discerned in the classical fer that the intrapipe GPR facies result from subtle differences, such as breccia lithology, clast size, or pore-space filling.}, language = {en} } @article{IbarraLiuMeessenetal.2019, author = {Ibarra, Federico and Liu, Sibiao and Meeßen, Christian and Prezzi, Claudia Beatriz and Bott, Judith and Scheck-Wenderoth, Magdalena and Sobolev, Stephan Vladimir and Strecker, Manfred}, title = {3D data-derived lithospheric structure of the Central Andes and its implications for deformation: Insights from gravity and geodynamic modelling}, series = {Tectonophysics : international journal of geotectonics and the geology and physics of the interior of the earth}, volume = {766}, journal = {Tectonophysics : international journal of geotectonics and the geology and physics of the interior of the earth}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0040-1951}, doi = {10.1016/j.tecto.2019.06.025}, pages = {453 -- 468}, year = {2019}, abstract = {We present a new three-dimensional density model of the Central Andes characterizing the structure and composition of the lithosphere together with a geodynamic simulation subjected to continental intraplate shortening. The principal aim of this study is to assess the link between heterogeneities in the lithosphere and different deformation patterns and styles along the orogen-foreland system of the Central Andes. First, we performed a 3D integration of new geological and geophysical data with previous models through forward modelling of Bouguer anomalies. Subsequently, a geodynamic model was set-up and parametrized from the previously obtained 3D structure and composition. We do not find a unambigous correlation between the resulting density configuration and terrane boundaries proposed by other authors. Our models reproduce the observed Bouguer anomaly and deformation patterns in the foreland. We find that thin-skinned deformation in the Subandean fold-and thrust belt is controlled by a thick sedimentary layer and coeval underthrusting of thin crust of the foreland beneath the thick crust of the Andean Plateau. In the adjacent thick-skinned deformation province of the inverted Cretaceous extensional Santa Barbara System sedimentary strata are much thinner and crustal thickness transitions from greater values in the Andean to a more reduced thickness in the foreland. Our results show that deformation processes occur where the highest gradients of lithospheric strength are present between the orogen and the foreland, thus suggesting a spatial correlation between deformation and lithospheric strength.}, language = {en} } @article{KaiserCacaceScheckWenderoth2013, author = {Kaiser, Bj{\"o}rn Onno and Cacace, Mauro and Scheck-Wenderoth, Magdalena}, title = {3D coupled fluid and heat transport simulations of the Northeast German Basin and their sensitivity to the spatial discretization - different sensitivities for different mechanisms of heat transport}, series = {Environmental earth sciences}, volume = {70}, journal = {Environmental earth sciences}, number = {8}, publisher = {Springer}, address = {New York}, issn = {1866-6280}, doi = {10.1007/s12665-013-2249-7}, pages = {3643 -- 3659}, year = {2013}, abstract = {Based on a numerical model of the Northeast German Basin (NEGB), we investigate the sensitivity of the calculated thermal field as resulting from heat conduction, forced and free convection in response to consecutive horizontal and vertical mesh refinements. Our results suggest that computational findings are more sensitive to consecutive horizontal mesh refinements than to changes in the vertical resolution. In addition, the degree of mesh sensitivity depends strongly on the type of the process being investigated, whether heat conduction, forced convection or free thermal convection represents the active heat driver. In this regard, heat conduction exhibits to be relative robust to imposed changes in the spatial discretization. A systematic mesh sensitivity is observed in areas where forced convection promotes an effective role in shorten the background conductive thermal field. In contrast, free thermal convection is to be regarded as the most sensitive heat transport process as demonstrated by non-systematic changes in the temperature field with respect to imposed changes in the model resolution.}, language = {en} } @article{OstermeyerMenzel1997, author = {Ostermeyer, Martin and Menzel, Ralf}, title = {34 Watt flash lamp pumped single rod ND:YAG laser with 1.2 * DL beam quality via special resonator design}, year = {1997}, language = {en} } @article{Doelling2013, author = {D{\"o}lling, Irene}, title = {30 Years of feminist studies how do we deal with the feminist Heritage?}, series = {Feministische Studien : Zeitschrift f{\"u}r interdisziplin{\"a}re Frauen- und Geschlechterforschung}, volume = {31}, journal = {Feministische Studien : Zeitschrift f{\"u}r interdisziplin{\"a}re Frauen- und Geschlechterforschung}, number = {1}, publisher = {Lucius \& Lucius}, address = {Stuttgart}, issn = {0723-5186}, pages = {29 -- 34}, year = {2013}, language = {de} } @article{AtilawHeydenreichNdakalaetal.2014, author = {Atilaw, Yoseph and Heydenreich, Matthias and Ndakala, Albert and Akala, Hoseah M. and Kamau, Edwin and Yenesew, Abiy}, title = {3-Oxo-14 alpha, 15 alpha-epoxyschizozygine: A new schizozygane indoline alkaloid from Schizozygia coffaeoides}, series = {Phytochemistry letters}, volume = {10}, journal = {Phytochemistry letters}, publisher = {Elsevier}, address = {Amsterdam}, issn = {1874-3900}, doi = {10.1016/j.phytol.2014.07.003}, pages = {28 -- 31}, year = {2014}, abstract = {The stem bark extract of Schizozygia coffaeoides (Apocynaceae) showed moderate antiplasmodial activity (IC50 = 8-12 mu g/mL) against the chloroquine-sensitive (D6) and chloroquine-resistant (W2) strains of Plasmodium falciparum. Chromatographic separation of the extract led to the isolation of a new schizozygane indoline alkaloid, named 3-oxo-14 alpha, 15 alpha-epoxyschizozygine. In addition, two dimeric anthraquinones, cassiamin A and cassiamin B, were identified for the first time in the family Apocynaceae. The structures of the isolated compounds were deduced on the basis of spectroscopic evidence. The schizozygane indole alkaloids showed good to moderate antiplasmodial activities (IC50 = 13-52 mu m). (C) 2014 Phytochemical Society of Europe. Published by Elsevier B.V. All rights reserved.}, language = {en} } @article{MutaiHeydenreichThoithietal.2013, author = {Mutai, Peggoty and Heydenreich, Matthias and Thoithi, Grace and Mugumbate, Grace and Chibale, Kelly and Yenesew, Abiy}, title = {3-Hydroxyisoflavanones from the stem bark of dalbergia melanoxylon - isolation, antimycobacterial evaluation and molecular docking studies}, series = {Phytochemistry letters}, volume = {6}, journal = {Phytochemistry letters}, number = {4}, publisher = {Elsevier}, address = {Amsterdam}, issn = {1874-3900}, doi = {10.1016/j.phytol.2013.08.018}, pages = {671 -- 675}, year = {2013}, abstract = {Two new 3-hydroxyisoflavanones, (S)-3,4',5-trihydroxy-2',7-dimethoxy-3'-prenylisoflavanone (trivial name kenusanone F 7-methyl ether) and (S)-3,5-dihydroxy-2',7-dimethoxy-2 '',2 ''-dimethylpyrano[5 '',6 '':3',4']isoflavanone (trivial name sophoronol-7-methyl ether) along with two known compounds (dalbergin and formononetin) were isolated from the stem bark of Dalbergia melanoxylon. The structures were elucidated using spectroscopic techniques. Kenusanone F 7-methyl ether showed activity against Mycobacterium tuberculosis, whereas both of the new compounds were inactive against the malaria parasite Plasmodium falciparum at 10 mu g/ml. Docking studies showed that the new compounds kenusanone F 7-methyl ether and sophoronol-7-methyl ether have high affinity for the M. tuberculosis drug target INHA.}, language = {en} } @article{BaesGeryaSobolev2016, author = {Baes, Marzieh and Gerya, Taras V. and Sobolev, Stephan Vladimir}, title = {3-D thermo-mechanical modeling of plume-induced subduction initiation}, series = {Earth \& planetary science letters}, volume = {453}, journal = {Earth \& planetary science letters}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0012-821X}, doi = {10.1016/j.epsl.2016.08.023}, pages = {193 -- 203}, year = {2016}, abstract = {Here, we study the 3-D subduction initiation process induced by the interaction between a hot thermochemical mantle plume and oceanic lithosphere using thermo-mechanical viscoplastic finite difference marker-in-cell models. Our numerical modeling results show that self-sustaining subduction is induced by plume-lithosphere interaction when the plume is sufficiently buoyant, the oceanic lithosphere is sufficiently old and the plate is weak enough to allow the buoyant plume to. pass through it. Subduction initiation occurs following penetration of the lithosphere by the hot plume and the downward displacement of broken, nearly circular segments of lithosphere (proto-slabs) as a result of partially molten plume rocks overriding the proto-slabs. Our experiments show four different deformation regimes in response to plume-lithosphere interaction: a) self-sustaining subduction initiation, in which subduction becomes self-sustaining; b) frozen subduction initiation, in which subduction stops at shallow depths; c) slab break-off, in which the subducting circular slab breaks off soon after formation; and d) plume underplating, in which the plume does not pass through the lithosphere and instead spreads beneath it (i.e., failed subduction initiation). These regimes depend on several parameters, such as the size, composition, and temperature of the plume, the brittle/plastic strength and age of the oceanic lithosphere, and the presence/absence of lithospheric heterogeneities. The results show that subduction initiates and becomes self-sustaining when the lithosphere is older than 10 Myr and the non dimensional ratio of the plume buoyancy force and lithospheric strength above the plume is higher than approximately 2. The outcomes of our numerical experiments are applicable for subduction initiation in the modern and Precambrian Earth and for the origin of plume-related corona structures on Venus. (C) 2016 Elsevier B.V. All rights reserved.}, language = {en} } @article{GomezGarciaMeessenScheckWenderothetal.2019, author = {Gomez-Garcia, Angela Maria and Meeßen, Christian and Scheck-Wenderoth, Magdalena and Monsalve, Gaspar and Bott, Judith and Bernhardt, Anne and Bernal, Gladys}, title = {3-D Modeling of Vertical Gravity Gradients and the Delimitation of Tectonic Boundaries: The Caribbean Oceanic Domain as a Case Study}, series = {Geochemistry, geophysics, geosystems}, volume = {20}, journal = {Geochemistry, geophysics, geosystems}, number = {11}, publisher = {American Geophysical Union}, address = {Washington}, issn = {1525-2027}, doi = {10.1029/2019GC008340}, pages = {5371 -- 5393}, year = {2019}, abstract = {Geophysical data acquisition in oceanic domains is challenging, implying measurements with low and/or nonhomogeneous spatial resolution. The evolution of satellite gravimetry and altimetry techniques allows testing 3-D density models of the lithosphere, taking advantage of the high spatial resolution and homogeneous coverage of satellites. However, it is not trivial to discretise the source of the gravity field at different depths. Here, we propose a new method for inferring tectonic boundaries at the crustal level. As a novelty, instead of modeling the gravity anomalies and assuming a flat Earth approximation, we model the vertical gravity gradients (VGG) in spherical coordinates, which are especially sensitive to density contrasts in the upper layers of the Earth. To validate the methodology, the complex oceanic domain of the Caribbean region is studied, which includes different crustal domains with a tectonic history since Late Jurassic time. After defining a lithospheric starting model constrained by up-to-date geophysical data sets, we tested several a-priory density distributions and selected the model with the minimum misfits with respect to the VGG calculated from the EIGEN-6C4 data set. Additionally, the density of the crystalline crust was inferred by inverting the VGG field. Our methodology enabled us not only to refine, confirm, and/or propose tectonic boundaries in the study area but also to identify a new anomalous buoyant body, located in the South Lesser Antilles subduction zone, and high-density bodies along the Greater, Lesser, and Leeward Antilles forearcs.}, language = {en} } @article{GuillemoteauSimonHulinetal.2019, author = {Guillemoteau, Julien and Simon, Francois-Xavier and Hulin, Guillaume and Dousteyssier, Bertrand and Dacko, Marion and Tronicke, Jens}, title = {3-D imaging of subsurface magnetic permeability/susceptibility with portable frequency domain electromagnetic sensors for near surface exploration}, series = {Geophysical journal international}, volume = {219}, journal = {Geophysical journal international}, number = {3}, publisher = {Oxford Univ. Press}, address = {Oxford}, issn = {0956-540X}, doi = {10.1093/gji/ggz382}, pages = {1773 -- 1785}, year = {2019}, abstract = {The in-phase response collected by portable loop-loop electromagnetic induction (EMI) sensors operating at low and moderate induction numbers (<= 1) is typically used for sensing the magnetic permeability (or susceptibility) of the subsurface. This is due to the fact that the in-phase response contains a small induction fraction and a preponderant induced magnetization fraction. The magnetization fraction follows the magneto-static equations similarly to the magnetic method but with an active magnetic source. The use of an active source offers the possibility to collect data with several loop-loop configurations, which illuminate the subsurface with different sensitivity patterns. Such multiconfiguration soundings thereby allows the imaging of subsurface magnetic permeability/susceptibility variations through an inversion procedure. This method is not affected by the remnant magnetization and theoretically overcomes the classical depth ambiguity generally encountered with passive geomagnetic data. To invert multiconfiguration in-phase data sets, we propose a novel methodology based on a full-grid 3-D multichannel deconvolution (MCD) procedure. This method allows us to invert large data sets (e.g. consisting of more than a hundred thousand of data points) for a dense voxel-based 3-D model of magnetic susceptibility subject to smoothness constraints. In this study, we first present and discuss synthetic examples of our imaging procedure, which aim at simulating realistic conditions. Finally, we demonstrate the applicability of our method to field data collected across an archaeological site in Auvergne (France) to image the foundations of a Gallo-Roman villa built with basalt rock material. Our synthetic and field data examples demonstrate the potential of the proposed inversion procedure offering new and complementary ways to interpret data sets collected with modern EMI instruments.}, language = {en} } @article{ReiterHeidbach2014, author = {Reiter, Karsten and Heidbach, Oliver}, title = {3-D geomechanical-numerical model of the contemporary crustal stress state in the Alberta Basin (Canada)}, series = {Solid earth}, volume = {5}, journal = {Solid earth}, number = {2}, publisher = {Copernicus}, address = {G{\"o}ttingen}, issn = {1869-9510}, doi = {10.5194/se-5-1123-2014}, pages = {1123 -- 1149}, year = {2014}, abstract = {In the context of examining the potential usage of safe and sustainable geothermal energy in the Alberta Basin, whether in deep sediments or crystalline rock, the understanding of the in situ stress state is crucial. It is a key challenge to estimate the 3-D stress state at an arbitrarily chosen point in the crust, based on sparsely distributed in situ stress data. To address this challenge, we present a large-scale 3-D geomechanical-numerical model (700 km x 1200 km x 80 km) from a large portion of the Alberta Basin, to provide a 3-D continuous quantification of the contemporary stress orientations and stress magnitudes. To calibrate the model, we use a large database of in situ stress orientation (321 S-Hmax) as well as stress magnitude data (981 S-V, 1720 S-hmin and 2 (+11) S-Hmax) from the Alberta Basin. To find the best-fit model, we vary the material properties and primarily the displacement boundary conditions of the model. This study focusses in detail on the statistical calibration procedure, because of the large amount of available data, the diversity of data types, and the importance of the order of data tests. The best-fit model provides the total 3-D stress tensor for nearly the whole Alberta Basin, and allows estimation of stress orientation and stress magnitudes in advance of any well. First-order implications for the well design and configuration of enhanced geothermal systems are revealed. Systematic deviations of the modelled stress from the in situ data are found for stress orientations in the Peace River and the Bow Island Arch as well as for leak-off test magnitudes.}, language = {en} } @article{GholamrezaieScheckWenderothBottetal.2019, author = {Gholamrezaie, Ershad and Scheck-Wenderoth, Magdalena and Bott, Judith and Heidbach, Oliver and Strecker, Manfred}, title = {3-D crustal density model of the Sea of Marmara}, series = {Solid Earth}, volume = {10}, journal = {Solid Earth}, publisher = {Copernicus Publ.}, address = {G{\"o}ttingen}, issn = {1869-9510}, doi = {10.5194/se-10-785-2019}, pages = {785 -- 807}, year = {2019}, abstract = {Abstract. The Sea of Marmara, in northwestern Turkey, is a transition zone where the dextral North Anatolian Fault zone (NAFZ) propagates westward from the Anatolian Plate to the Aegean Sea Plate. The area is of interest in the context of seismic hazard of Istanbul, a metropolitan area with about 15 million inhabitants. Geophysical observations indicate that the crust is heterogeneous beneath the Marmara basin, but a detailed characterization of the crustal heterogeneities is still missing. To assess if and how crustal heterogeneities are related to the NAFZ segmentation below the Sea of Marmara, we develop new crustal-scale 3-D density models which integrate geological and seismological data and that are additionally constrained by 3-D gravity modeling. For the latter, we use two different gravity datasets including global satellite data and local marine gravity observation. Considering the two different datasets and the general non-uniqueness in potential field modeling, we suggest three possible "end-member" solutions that are all consistent with the observed gravity field and illustrate the spectrum of possible solutions. These models indicate that the observed gravitational anomalies originate from significant density heterogeneities within the crust. Two layers of sediments, one syn-kinematic and one pre-kinematic with respect to the Sea of Marmara formation are underlain by a heterogeneous crystalline crust. A felsic upper crystalline crust (average density of 2720 kgm⁻³) and an intermediate to mafic lower crystalline crust (average density of 2890 kgm⁻³) appear to be cross-cut by two large, dome-shaped mafic highdensity bodies (density of 2890 to 3150 kgm⁻³) of considerable thickness above a rather uniform lithospheric mantle (3300 kgm⁻³). The spatial correlation between two major bends of the main Marmara fault and the location of the highdensity bodies suggests that the distribution of lithological heterogeneities within the crust controls the rheological behavior along the NAFZ and, consequently, maybe influences fault segmentation and thus the seismic hazard assessment in the region.}, language = {en} } @article{WiederkehrBousquetZiemannetal.2011, author = {Wiederkehr, Michael and Bousquet, Romain and Ziemann, Martin Andreas and Berger, Alfons and Schmid, Stefan M.}, title = {3-D assessment of peak-metamorphic conditions by Raman spectroscopy of carbonaceous material an example from the margin of the Lepontine dome (Swiss Central Alps)}, series = {International journal of earth sciences}, volume = {100}, journal = {International journal of earth sciences}, number = {5}, publisher = {Springer}, address = {New York}, issn = {1437-3254}, doi = {10.1007/s00531-010-0622-2}, pages = {1029 -- 1063}, year = {2011}, abstract = {This study monitors regional changes in the crystallinity of carbonaceous matter (CM) by applying Micro-Raman spectroscopy to a total of 214 metasediment samples (largely so-called Bundnerschiefer) dominantly metamorphosed under blueschist- to amphibolite-facies conditions. They were collected within the northeastern margin of the Lepontine dome and easterly adjacent areas of the Swiss Central Alps. Three-dimensional mapping of isotemperature contours in map and profile views shows that the isotemperature contours associated with the Miocene Barrow-type Lepontine metamorphic event cut across refolded nappe contacts, both along and across strike within the northeastern margin of the Lepontine dome and adjacent areas. Further to the northeast, the isotemperature contours reflect temperatures reached during the Late Eocene subduction-related blueschist-facies event and/or during subsequent near-isothermal decompression; these contours appear folded by younger, large-scale post-nappe-stacking folds. A substantial jump in the recorded maximum temperatures across the tectonic contact between the frontal Adula nappe complex and surrounding metasediments indicates that this contact accommodated differential tectonic movement of the Adula nappe with respect to the enveloping Bundnerschiefer after maximum temperatures were reached within the northern Adula nappe, i.e. after Late Eocene time.}, language = {en} } @article{HoehnkeJohnson1995, author = {Hoehnke, Hans-J{\"u}rgen and Johnson, K. W.}, title = {3-characters are sufficient for the group determinant}, year = {1995}, language = {en} } @article{Gienow1992, author = {Gienow, Wilfried}, title = {2nd English Studies Conference at the Freie Universit{\"a}t Berlin}, year = {1992}, language = {en} } @article{EvansvanLoonHainichetal.2015, author = {Evans, Chris J. and van Loon, Jacco Th. and Hainich, Rainer and Bailey, M.}, title = {2dF-AAOmega spectroscopy of massive stars in the Magellanic Clouds The north-eastern region of the Large Magellanic Cloud}, series = {Astronomy and astrophysics : an international weekly journal}, volume = {584}, journal = {Astronomy and astrophysics : an international weekly journal}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {1432-0746}, doi = {10.1051/0004-6361/201525882}, pages = {19}, year = {2015}, abstract = {We present spectral classifications from optical spectroscopy of 263 massive stars in the north-eastern region of the Large Magellanic Cloud. The observed two-degree field includes the massive 30 Doradus star-forming region, the environs of SN1987A, and a number of star-forming complexes to the south of 30 Dor. These are the first classifications for the majority (203) of the stars and include eleven double-lined spectroscopic binaries. The sample also includes the first examples of early OC-type spectra (AA Omega 30 Dor 248 and 280), distinguished by the weakness of their nitrogen spectra and by C IV lambda 4658 emission. We propose that these stars have relatively unprocessed CNO abundances compared to morphologically normal O-type stars, indicative of an earlier evolutionary phase. From analysis of observations obtained on two consecutive nights, we present radial-velocity estimates for 233 stars, finding one apparent single-lined binary and nine (>3 sigma) outliers compared to the systemic velocity; the latter objects could be runaway stars or large-amplitude binary systems and further spectroscopy is required to investigate their nature.}, language = {en} } @article{OstermeyerHeuerMenzel1998, author = {Ostermeyer, Martin and Heuer, Axel and Menzel, Ralf}, title = {27 Watt average output power with 1.2*DL beam quality from a single rod Nd:YAG-Laser with phase conjugating SBS- mirror}, year = {1998}, language = {en} } @article{SchulzeBettBivouretal.2020, author = {Schulze, Patricia S. C. and Bett, Alexander J. and Bivour, Martin and Caprioglio, Pietro and Gerspacher, Fabian M. and Kabakl{\i}, {\"O}zde Ş. and Richter, Armin and Stolterfoht, Martin and Zhang, Qinxin and Neher, Dieter and Hermle, Martin and Hillebrecht, Harald and Glunz, Stefan W. and Goldschmidt, Jan Christoph}, title = {25.1\% high-efficiency monolithic perovskite silicon tandem solar cell with a high bandgap perovskite absorber}, series = {Solar RRL}, volume = {4}, journal = {Solar RRL}, number = {7}, publisher = {John Wiley \& Sons, Inc.}, address = {New Jersey}, pages = {10}, year = {2020}, abstract = {Monolithic perovskite silicon tandem solar cells can overcome the theoretical efficiency limit of silicon solar cells. This requires an optimum bandgap, high quantum efficiency, and high stability of the perovskite. Herein, a silicon heterojunction bottom cell is combined with a perovskite top cell, with an optimum bandgap of 1.68 eV in planar p-i-n tandem configuration. A methylammonium-free FA(0.75)Cs(0.25)Pb(I0.8Br0.2)(3) perovskite with high Cs content is investigated for improved stability. A 10\% molarity increase to 1.1 m of the perovskite precursor solution results in approximate to 75 nm thicker absorber layers and 0.7 mA cm(-2) higher short-circuit current density. With the optimized absorber, tandem devices reach a high fill factor of 80\% and up to 25.1\% certified efficiency. The unencapsulated tandem device shows an efficiency improvement of 2.3\% (absolute) over 5 months, showing the robustness of the absorber against degradation. Moreover, a photoluminescence quantum yield analysis reveals that with adapted charge transport materials and surface passivation, along with improved antireflection measures, the high bandgap perovskite absorber has the potential for 30\% tandem efficiency in the near future.}, language = {en} } @article{Rutschke1996, author = {Rutschke, Erich}, title = {25 Jahre Ramsar-Konvention zum Schutz von Feuchtgebieten}, year = {1996}, language = {de} } @article{Rutschke1998, author = {Rutschke, Erich}, title = {25 Jahre Ramsar-Konvention : zur Situation der "Feuchtgebiete von internationaler Bedeutung" im Land Brandenburg}, year = {1998}, language = {de} } @article{Weiss2000, author = {Weiß, Norman}, title = {25 Jahre KSZE / OSZE}, series = {MenschenRechtsMagazin : MRM ; Informationen, Meinungen, Analysen}, volume = {5}, journal = {MenschenRechtsMagazin : MRM ; Informationen, Meinungen, Analysen}, number = {3}, issn = {1434-2820}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-44214}, pages = {160 -- 172}, year = {2000}, abstract = {Inhalts{\"u}bersicht I. Einf{\"u}hrung II. Weltpolitischer Hintergrund und theoretische Grundlagen des KSZE-Prozesses 1. Der Weg nach Helsinki 2. Die Schlußakte von Helsinki 3. Von Helsinki nach Paris - 1975-1990 4. Aktuelle Entwicklungen III. {\"U}berblick {\"u}ber die Entwicklung der KSZE/OSZE IV. Die zehn Prinzipien - der "Dekalog" - aus dem Ersten Kapitel der Schlußakte V. Die menschliche Dimension der KSZE/OSZE VI. Schlußbetrachtungen}, language = {de} } @article{Rutschke1997, author = {Rutschke, Erich}, title = {25 Jahre Konvention zum Schutz von Feuchtgebieten : Anmerkungen zur Vertragsstaatenkonferenz der Ramsar- Konvention in Brisbane, Australien, M{\"a}rz 1996}, year = {1997}, language = {de} } @article{Rutschke1996, author = {Rutschke, Erich}, title = {25 Jahre Konvention zum Schutz von Feuchtgebieten}, year = {1996}, language = {de} } @article{Lueth1998, author = {L{\"u}th, Christoph}, title = {20. Jahrestagung der International Standing Conference for the History of Education (15.-18.08.1998), Universit{\"a}t Leuven}, issn = {0943- 7754}, year = {1998}, language = {de} } @article{Weiss2000, author = {Weiß, Norman}, title = {20 Jahre {\"U}bereinkommen zur Beseitigung jeder Form von Diskriminierung der Frau - (CEDAW)}, series = {MenschenRechtsMagazin : MRM ; Informationen, Meinungen, Analysen}, volume = {5}, journal = {MenschenRechtsMagazin : MRM ; Informationen, Meinungen, Analysen}, number = {1}, issn = {1434-2820}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-54688}, pages = {41}, year = {2000}, abstract = {Tagungsbericht: Weiß, Norman: 20 Jahre {\"U}bereinkommen zur Beseitigung jeder Form von Diskriminierung der Frau (CEDAW)<1999, Potsdam> / 20 Jahre {\"U}bereinkommen zur Beseitigung jeder Form von Diskriminierung der Frau (CEDAW), Tagung des Menschenrechtszentrums der Universit{\"a}t Potsdam am 25., 26. November 1999}, language = {de} } @article{SudfeldtMelterNaacke1996, author = {Sudfeldt, Christoph and Melter, Johannes and Naacke, Johannes}, title = {20 Jahre Ramsar-Konvention in Deutschland : Sitzt der Feuchtgebietsschutz auf dem Trockenen?}, year = {1996}, language = {de} } @article{Merle1995, author = {Merle, Werner}, title = {20 Jahre Fachgespr{\"a}che in Fischen : Gedanken eines Referenten}, year = {1995}, language = {de} } @article{Merle1995, author = {Merle, Werner}, title = {20 Jahre Fachgespr{\"a}che in Fischen : Gedanken eines Referenten}, year = {1995}, language = {de} } @article{StreichBeckenRitter2011, author = {Streich, Rita and Becken, Michael and Ritter, Oliver}, title = {2.5D controlled-source EM modeling with general 3D source geometries}, series = {Geophysics}, volume = {76}, journal = {Geophysics}, number = {6}, publisher = {Society of Exploration Geophysicists}, address = {Tulsa}, issn = {0016-8033}, doi = {10.1190/GEO2011-0111.1}, pages = {F387 -- F393}, year = {2011}, abstract = {Most 2.5D controlled-source electromagnetic (CSEM) modeling algorithms presented to date explicitly consider only sources that are point dipoles oriented parallel or perpendicular to the direction of constant conductivity. This makes simulations of complex source geometries expensive, requiring separate evaluations of many point dipole fields, and thus limits the practical applicability of such schemes for simulating and interpreting field data. We present a novel 2.5D CSEM modeling scheme that overcomes this limitation and permits efficient simulations of sources with general shape and orientation by evaluating fields for the entire source at once. We accommodate general sources by using a secondary field approach, in which primary fields are computed for the general source and a 1D background conductivity model. To carry out the required Fourier transforms between space and wavenumber domain using the same fast cosine and sine transform filters as in conventional algorithms, we split the primary and secondary fields into their symmetric and antisymmetric parts. For complex 3D source geometries, this approach is significantly more efficient than previous 2.5D algorithms. Our finite-difference algorithm also includes novel approaches for divergence correction at low frequencies and EM field interpolation across conductivity discontinuities. We describe the modeling scheme and demonstrate its accuracy and efficiency by comparisons of 2.5D-simulated data with 1D and 3D results.}, language = {en} } @article{HausmannAsholtThomaetal.2005, author = {Hausmann, Frank-Rutger and Asholt, Wolfgang and Thoma, Heinz and Zimmermann, Margarete and Sch{\"o}nert, J{\"o}rg and Schr{\"o}der, Konrad and Raible, Wolfgang and Ette, Ottmar}, title = {2. Podiumsdiskussion "Zukunft der Romanistik"}, year = {2005}, language = {de} } @article{Helmke1995, author = {Helmke, Christa}, title = {2. Internationale Session f{\"u}r Hochschullehrer und Sportp{\"a}dagogen an der Olympischen Akademie}, year = {1995}, language = {de} } @article{KolocourisKochKleinpeteretal.2015, author = {Kolocouris, Antonios and Koch, Andreas and Kleinpeter, Erich and Stylianakis, Ioannis}, title = {2-Substituted and 2,2-disubstituted adamantane derivatives as models for studying substituent chemical shifts and C-H-ax center dot center dot center dot Y-ax cyclohexane contacts-results from experimental and theoretical NMR spectroscopic chemical shifts and DFT structures}, series = {Tetrahedron}, volume = {71}, journal = {Tetrahedron}, number = {16}, publisher = {Elsevier}, address = {Oxford}, issn = {0040-4020}, doi = {10.1016/j.tet.2015.01.044}, pages = {2463 -- 2481}, year = {2015}, abstract = {The complete H-1 and C-13 NMR chemical shifts assignment for various 2-substituted and 2,2-disubstituted adamantane derivatives 1-38 in CDCl3 solution was realized on the basis of NMR experiments combined with chemical structure information and DFT-GIAO (B3LYP/6-31+G(d,p)-GIAO) calculations of chemical shifts in solution. Substituent-induced C-13 NMR chemical shifts (SCS) are discussed. C-H-ax center dot center dot center dot Y-ax contacts are a textbook prototype of steric hindrance in organic chemistry. The nature of these contacts will be further investigated in this work on basis of new adamantane derivatives, which are substituted at C-2 to provide models for 1,4-C-H-ax center dot center dot center dot Y-ax and 1,5-C-H-ax center dot center dot center dot Y-ax contacts. The B3LYP/6-31+G(d,p) calculations predicted the presence of NBO hyperconjugative attractive interactions between C-H-ax and Y-ax groups along C-H-ax center dot center dot center dot Y-ax contacts. The H-1 NMR signal separation, Delta delta(gamma-CH2), reflects the strength of the H-bonded C-H-ax center dot center dot center dot Y-ax contact. (C) 2015 Elsevier Ltd. All rights reserved.}, language = {en} } @article{Schmidt1998, author = {Schmidt, Hans-J{\"u}rgen}, title = {2-dimensional representations of 4-dimensional gravitational waves}, year = {1998}, language = {en} } @article{GonzalesDiazKasperRainer1998, author = {Gonz{\´a}les-Diaz, P. F. and Kasper, Uwe and Rainer, Martin}, title = {2-Dimensional dilatonic gravity from multidimensional Einstein gravity}, year = {1998}, language = {en} } @article{DzambaskiMarkovicKleinpeteretal.2013, author = {Dzambaski, Zdravko and Markovic, Rade and Kleinpeter, Erich and Baranac-Stojanovic, Marija}, title = {2-Alkylidene-4-oxothiazolidine S-oxides - synthesis and stereochemistry}, series = {Tetrahedron}, volume = {69}, journal = {Tetrahedron}, number = {31}, publisher = {Elsevier}, address = {Oxford}, issn = {0040-4020}, doi = {10.1016/j.tet.2013.05.087}, pages = {6436 -- 6447}, year = {2013}, abstract = {A series of 5-unsubstituted and 5-substituted 2-alkylidene-4-oxothiazolidine-S-oxides were synthesized by the sulfur-oxidation with m-CPBA. The stereochemistry of 5-substituted sulfoxides was determined by means of NMR spectroscopy and DFT theoretical calculations. It was found that the thermodynamically less stable anti-isomer was initially formed in the course of the oxidation, but it underwent epimerization to the mixture enriched in the more stable syn-isomer, during the work-up process. The higher stability of syn-isomers is ascribed to the stronger hyperconjugative sigma(C-H)->sigma*(S-O) interaction versus the weaker sigma(C-C)->sigma*(S-O) delocalization in their anti-counterparts and to the existence of intramolecular 1,5-CH center dot center dot center dot C hydrogen bonds.}, language = {en} } @article{StrehmelRexhausenStrauch2010, author = {Strehmel, Veronika and Rexhausen, Hans and Strauch, Peter}, title = {2,2,6,6-Tetramethylpiperidine-1-yloxyl bound to the imidazolium ion by an acetamido group for investigation of ionic liquids}, issn = {0040-4039}, doi = {10.1016/j.tetlet.2009.11.124}, year = {2010}, abstract = {New spin probes bearing the 2,2,6,6-tetramethylpiperidine-1-yloxyl covalently bound to the imidazolium ion via a methylene spacer and an amide group are synthesized. If the anion is bis(trifluoromethylsulfonylimide) instead of iodide, the new spin probe has a similar structure as that of an ionic liquid. Nevertheless, the new spin probes are useful tools to investigate ionic liquids.}, language = {en} } @article{AwadConradKochetal.2010, author = {Awad, Duha Jawad and Conrad, Franziska and Koch, Andreas and Friedrich, Alwin and Poeppl, Andreas and Strauch, Peter}, title = {2,2'-Bipyridin-1,2-dithiolat Gemischtligand-Komplexe : Systhese, Charakterisierung und EPR-Spektroskopie}, issn = {0932-0776}, year = {2010}, abstract = {A series of new 2 2'-bipyridine/1 2-dithiolate transition metal complexes has been synthesised and characterised As 1,2-dithiolate ligands 1,2 dithiooxalate (dto) and 1 2-dithiosquarate (dtsq) were used It follows from the IR spectra that the multidentate dithiolate ligands coordinate exclusively via their sulfur atoms forming an MN2S2 coordination sphere The central metal ions (M) are Cu2+ Ni2+ Pd2+ Pt2+, and Zn2+ The complex [Cu-II(bpy)(dto)] could be studied by EPR spectroscopy and was measured as powder diamagnetically diluted in the isostructural [Ni-II(bpy)(dto)] host structure The spin density contribution calculated from the experimental parameters is compared with the electronic situation in the frontier orbitals namely in the semi occupied SOMO of the copper complex derived from quantum chemical calculations on different levels (EHT and DFT)}, language = {de} } @article{SchmidtRiemerKarras2013, author = {Schmidt, Bernd and Riemer, Martin and Karras, Manfred}, title = {2,2 '-Biphenols via protecting group-free thermal or microwave-accelerated suzuki-miyaura coupling in water}, series = {The journal of organic chemistry}, volume = {78}, journal = {The journal of organic chemistry}, number = {17}, publisher = {American Chemical Society}, address = {Washington}, issn = {0022-3263}, doi = {10.1021/jo401398n}, pages = {8680 -- 8688}, year = {2013}, abstract = {User-friendly protocols for the protecting group-free synthesis of 2,2'-biphenols via Suzuki-Miyaura coupling of o-halophenols and o-boronophenol are presented. The reactions proceed in water in the presence of simple additives such as K2CO3, KOH, KF, or TBAF and with commercially available Pd/C as precatalyst. Expensive or laboriously synthesized ligands or other additives are not required. In the case of bromophenols, efficient rate acceleration and short reaction times were accomplished by microwave irradiation.}, language = {en} } @article{KammerKellingBaieretal.2009, author = {Kammer, Stefan and Kelling, Alexandra and Baier, Heiko and Mickler, Wulfhard and Dosche, Carsten and Rurack, Knut and Kapp, Andreas and Lisdat, Fred and Holdt, Hans-J{\"u}rgen}, title = {2,11-dialkylated 1,12-diazaperylene copper(I) complexes : first supramolecular column assemblies by pi-pi stacking between homoleptic tetrahedral metal complexes, exhibiting low-energy MLCT transitions}, issn = {1434-1948}, doi = {10.1002/ejic.200900695}, year = {2009}, abstract = {2,11-Dialkylated 1,12-diazaperylenes (alkyl = Me, Et, iPr) dmedap, detdap and dipdap have been synthesized by reductive cyclization of 3,3-dialkylated 1,1-biisoquinolines 3a-c, resulting in the first copper(I) complexes of a large- surface ligand. The new copper(I) complexes show low-energy MLCT absorptions unprecedented for bis(-diimin)copper(I) complexes. The solid structures of the complexes[Cu(dipdap)2]BF4·CH2Cl2·1.5H2O, [Cu(dipdap)2]OTf·CH2Cl2, [Cu(dipdap)2]I·C2H4Cl2·THF·2H2O, [Cu(dmedap)2]OTf and [Cu(dipdap)2]AQSO3·H2O (AQSO3 = sodium 9,10-dihydro-9,10-dioxo-2- anthracenesulfonate) are reported. In [Cu(dipdap)2]BF4·CH2Cl2·1.5H2O, each copper(I) complex cation interacts with two others by - stacking interactions forming a novel supramolecular column structural motif running along the crystallographic c axis. In the crystalline compound [Cu(dipdap)2]AQSO3·H2O, aggregation between two complex cations and two additional anions by - stacking interactions is observed, leading to a tetrameric assembly. Furthermore, the three complex compounds [Cu(L)2]BF4 (L = dmedap, detdap, dipdap) were tested for sensory applications in aqueous buffer solutions in electrochemical studies of the complex immobilized on glassy carbon electrodes.}, language = {en} } @article{DzhunushalievSchmidt1999, author = {Dzhunushaliev, Vladimir and Schmidt, Hans-J{\"u}rgen}, title = {2+2-decomposable solutions of weyl gravity}, year = {1999}, language = {en} } @article{SchreiberHosemannBeuermann2011, author = {Schreiber, Ulrike and Hosemann, Benjamin and Beuermann, Sabine}, title = {1H,1H,2H,2H-Perfluorodecyl-Acrylate-Containing block copolymers from ARGET ATRP}, series = {Macromolecular chemistry and physics}, volume = {212}, journal = {Macromolecular chemistry and physics}, number = {2}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {1022-1352}, doi = {10.1002/macp.201000307}, pages = {168 -- 179}, year = {2011}, abstract = {Block copolymers of 1H,1H,2H,2H-perfluorodecyl acrylate (AC8) were obtained from ARGET ATRP. To obtain block copolymers of low dispersity the PAC8 block was synthesized in anisole with a CuBr(2)/PMDETA catalyst in the presence of tin(II) 2-ethylhexanoate as a reducing agent. The PAC8 block was subsequently used as macroinitiator for copolymerization with butyl and tert-butyl acrylate carried out in scCO(2). To achieve catalyst solubility in CO(2) two fluorinated ligands were employed. The formation of block copolymers was confirmed by size exclusion chromatography and DSC.}, language = {en} } @article{StarkeKochHoldtetal.1995, author = {Starke, Ines and Koch, Andreas and Holdt, Hans-J{\"u}rgen and Kleinpeter, Erich}, title = {1H, 13C, and 15N NMR study of the solution structure of metabridged bis(benzo-15-crown-5-ether)s}, year = {1995}, language = {en} } @article{HilfertSarodnickKempteretal.1998, author = {Hilfert, Liane and Sarodnick, Gerhard and Kempter, Gerhard and Kleinpeter, Erich}, title = {1H, 13C and 15 N NMR study and molecular modelling of 2,3- disubstituted quinoxalines with sterically hinderered aromatic and heteroaromatic substituents}, year = {1998}, language = {en} } @article{LehmannKleinpeter1993, author = {Lehmann, J. and Kleinpeter, Erich}, title = {1H NMR Lanthanideinduced Shift (LIS) investigations of highly flexible molecules : a new approach ; Part II}, year = {1993}, language = {en} } @article{LehmannKleinpeter1993, author = {Lehmann, J. and Kleinpeter, Erich}, title = {1H NMR Lanthanideinduced Shift (LIS) investigations of highly flexible molecules : a new approach}, year = {1993}, language = {en} } @article{LehmannKleinpeter1995, author = {Lehmann, J. and Kleinpeter, Erich}, title = {1H NMR lanthanide-induced shift investigations of highly flexible molecules, part III. Applications to alcohols, aldehydes, esters and amines}, year = {1995}, language = {en} } @article{PoleschnerHeydenreich1997, author = {Poleschner, Helmut and Heydenreich, Matthias}, title = {1H and 13C NMR Spectra and One-Bond 13C,13C Coupling Constants of 2-Alken-4-yn-1-ols, (E)-2-Alken-4-yn-1-yl Acetates and (E)-2-Alken-4-yn-1-als}, year = {1997}, language = {en} } @article{GuillemoteauSimonLuecketal.2016, author = {Guillemoteau, Julien and Simon, Francois-Xavier and L{\"u}ck, Erika and Tronicke, Jens}, title = {1D sequential inversion of portable multi-configuration electromagnetic induction data}, series = {Near surface geophysics}, volume = {14}, journal = {Near surface geophysics}, publisher = {Wiley-VCH}, address = {Houten}, issn = {1569-4445}, doi = {10.3997/1873-0604.2016029}, pages = {423 -- 432}, year = {2016}, abstract = {We present an algorithm that performs sequentially one-dimensional inversion of subsurface magnetic permeability and electrical conductivity by using multi-configuration electromagnetic induction sensor data. The presented method is based on the conversion of the in-phase and out-of-phase data into effective magnetic permeability and electrical conductivity of the equivalent homogeneous half-space. In the case of small-offset systems, such as portable electromagnetic induction sensors, for which in-phase and out-of-phase data are moderately coupled, the effective half-space magnetic permeability and electrical conductivity can be inverted sequentially within an iterative scheme. We test and evaluate the proposed inversion strategy using synthetic and field examples. First, we apply it to synthetic data for some highly magnetic environments. Then, the method is tested on real field data acquired in a basaltic environment to image a formation of archaeological interest. These examples demonstrate that a joint interpretation of in-phase and out-of-phase data leads to a better characterisation of the subsurface in magnetic environments such as volcanic areas.}, language = {en} } @article{GuillemoteauLueckTronicke2017, author = {Guillemoteau, Julien and L{\"u}ck, Erika and Tronicke, Jens}, title = {1D inversion of direct current data acquired with a rolling electrode system}, series = {Journal of applied geophysics}, volume = {146}, journal = {Journal of applied geophysics}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0926-9851}, doi = {10.1016/j.jappgeo.2017.09.010}, pages = {167 -- 177}, year = {2017}, abstract = {Direct current systems employing a kinematic surveying strategy allow to analyze the electrical resistivity of the subsurface for large areas (i.e., several hectares). Typical applications are found in precision agriculture, archaeological prospecting and soil sciences. With the typical survey setting, the collected data sets are often characterized by a rather high level of noise and a rather coarse lateral sampling compared to data acquired with fixed electrodes. We therefore present an efficient one-dimensional inversion approach in which we put special attention on modeling the effects of noise. We apply this method to data recorded with a five-offset equatorial dipole-dipole system employing rolling electrodes. By performing several synthetic tests with realistic noise levels, we found that the considered five-configuration soundings allow for a reliable imaging of two-layer cases in the uppermost two meters of the subsurface, where the subsurface can be assumed to follow a horizontally layered geometry within 3 m around the system. By analyzing the corresponding sensitivity functions, we also show that the equatorial dipole-dipole array is relatively well suited for a 1D inversion approach compared to standard in-line electrode arrays. To illustrate this aspect, we show that our method can provide results similar to those obtained with a 2D Wenner imaging procedure for data recorded across a well-constrained 2D target. We finally apply our method to a large five-offset data set acquired in an agricultural study. The final pseudo-3D model of electrical resistivity is in accordance with borehole data available for the surveyed area. Our results demonstrate the applicability and the versatility of the presented inversion approach for large-scale data sets as they are typically collected with such rolling electrode systems. (C) 2017 Elsevier B.V. All rights reserved.}, language = {en} } @article{Klessmann1993, author = {Kleßmann, Christoph}, title = {1990 : das Ende des Ost-West-Konfliktes : Deutschlands Vereinigung und die Anerkennung der polnischen Westgrenze}, year = {1993}, language = {de} } @article{Crome1992, author = {Crome, Erhard}, title = {1989 : das Ende einer "Langen Welle"? : Anmerkungen zur Marxdebatte}, year = {1992}, language = {de} }