@article{Steinmetz2016, author = {Steinmetz, Matthias}, title = {Die Vermessung des Universums}, series = {Vision als Aufgabe : das Leibniz-Universum im 21. Jahrhundert}, journal = {Vision als Aufgabe : das Leibniz-Universum im 21. Jahrhundert}, publisher = {Berlin-Brandenburgische Akademie der Wissenschaften}, address = {Berlin}, isbn = {978-3-939818-67-0}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:b4-opus4-25899}, pages = {197 -- 210}, year = {2016}, language = {de} } @article{ReindlRauchMillerBertolamietal.2016, author = {Reindl, Nicole and Rauch, Thomas and Miller Bertolami, Marcelo Miguel and Todt, Helge Tobias and Werner, K.}, title = {Breaking news from the HST}, series = {Monthly notices of the Royal Astronomical Society}, volume = {464}, journal = {Monthly notices of the Royal Astronomical Society}, publisher = {Oxford Univ. Press}, address = {Oxford}, issn = {0035-8711}, doi = {10.1093/mnrasl/slw175}, pages = {L51 -- L55}, year = {2016}, abstract = {SAO 244567 is a rare example of a star that allows us to witness stellar evolution in real time. Between 1971 and 1990, it changed from a B-type star into the hot central star of the Stingray Nebula. This observed rapid heating has been a mystery for decades, since it is in strong contradiction with the low mass of the star and canonical post-asymptotic giant branch (AGB) evolution. We speculated that SAO 244567 might have suffered from a late thermal pulse (LTP) and obtained new observations with Hubble Space Telescope (HST)/COS to follow the evolution of the surface properties of SAO 244567 and to verify the LTP hypothesis. Our non-LTE spectral analysis reveals that the star cooled significantly since 2002 and that its envelope is now expanding. Therefore, we conclude that SAO 244567 is currently on its way back towards the AGB, which strongly supports the LTP hypothesis. A comparison with state-of-the-art LTP evolutionary calculations shows that these models cannot fully reproduce the evolution of all surface parameters simultaneously, pointing out possible shortcomings of stellar evolution models. Thereby, SAO 244567 keeps on challenging stellar evolution theory and we highly encourage further investigations.}, language = {en} } @article{ZehbeZaslanskyMochalesetal.2016, author = {Zehbe, Rolf and Zaslansky, Paul and Mochales, Carolina and Mueller, Wolf-Dieter and Fleck, Claudia}, title = {Synchrotron micro tomographic evaluation of multilayered zirconia ceramics-Volumetric effects after indentation}, series = {Journal of the European Ceramic Society}, volume = {36}, journal = {Journal of the European Ceramic Society}, publisher = {Elsevier}, address = {Oxford}, issn = {0955-2219}, doi = {10.1016/j.jeurceramsoc.2015.09.015}, pages = {171 -- 177}, year = {2016}, abstract = {Electrophoretic deposition was used to produce zirconia specimen consisting of alternating layers of fully stabilized cubic zirconia and partially stabilized tetragonal zirconia. In this configuration, the tetragonal stabilized zirconia layers can undergo transformation toughening upon mechanical induced stresses, while the cubic stabilized layers can act as confining element. To understand the volumetric changes due to transformation toughening in these layered materials after indentation, we used an advanced synchrotron-based X-ray mu CT setup and compared the results with surface sensitive methods like Raman spectroscopy, AFM and white light interferometry. The high spatial resolution and the adapted beam energy between the absorption edges of zirconia and yttria allowed discriminating between individual layers due to differences in their yttria content. Furthermore we were able to identify single indents and link volume changes to different physical effects in the different stabilized zirconia parts and visualize the three dimensional volume around only few micrometre sized indents. (C) 2015 Elsevier Ltd. All rights reserved.}, language = {en} } @article{ZehbeMochalesRadziketal.2016, author = {Zehbe, Rolf and Mochales, Carolina and Radzik, Daniela and Mueller, Wolf-Dieter and Fleck, Claudia}, title = {Electrophoretic deposition of multilayered (cubic and tetragonal stabilized) zirconia ceramics for adapted crack deflection}, series = {Journal of the European Ceramic Society}, volume = {36}, journal = {Journal of the European Ceramic Society}, publisher = {Elsevier}, address = {Oxford}, issn = {0955-2219}, doi = {10.1016/j.jeurceramsoc.2015.08.022}, pages = {357 -- 364}, year = {2016}, abstract = {The electrophoretic deposition process was used to produce multi-layered ceramics consisting of alternating layers of fully stabilized cubic zirconia and partially stabilized tetragonal zirconia to make use of their different mechanical behaviour, investigating the possibility to deflect advancing cracks at the interfaces of the different layers. This crack deflection is apparently impacted by a toughening mechanism only found in the tetragonal stabilized zirconia polymorph and is characterized by the stress induced transformation of the metastable tetragonal phase into the monoclinic one, which is accompanied by a volume increase resulting in a closing mechanism for advancing cracks. While improving the electrophoretic deposition process, we investigated the transformation toughening mechanism at the layer interfaces and their effect on crack propagation. Investigations involved a combination of different imaging methods, including light microscopy, white light interferometry, atomic force microscopy, scanning electron microscopy, energy dispersive X-ray spectroscopy and Raman spectroscopy. (C) 2015 Elsevier Ltd. All rights reserved.}, language = {en} } @article{MengelFeldmannLevermann2016, author = {Mengel, Matthias and Feldmann, Johannes and Levermann, Anders}, title = {Linear sea-level response to abrupt ocean warming of major West Antarctic ice basin}, series = {Nature climate change}, volume = {6}, journal = {Nature climate change}, publisher = {Nature Publ. Group}, address = {London}, issn = {1758-678X}, doi = {10.1038/NCLIMATE2808}, pages = {71 -- +}, year = {2016}, abstract = {Antarctica's contribution to global sea-level rise has recently been increasing1. Whether its ice discharge will become unstable and decouple from anthropogenic forcing2,3,4 or increase linearly with the warming of the surrounding ocean is of fundamental importance5. Under unabated greenhouse-gas emissions, ocean models indicate an abrupt intrusion of warm circumpolar deep water into the cavity below West Antarctica's Filchner-Ronne ice shelf within the next two centuries6,7. The ice basin's retrograde bed slope would allow for an unstable ice-sheet retreat8, but the buttressing of the large ice shelf and the narrow glacier troughs tend to inhibit such instability9,10,11. It is unclear whether future ice loss will be dominated by ice instability or anthropogenic forcing. Here we show in regional and continental-scale ice-sheet simulations, which are capable of resolving unstable grounding-line retreat, that the sea-level response of the Filchner-Ronne ice basin is not dominated by ice instability and follows the strength of the forcing quasi-linearly. We find that the ice loss reduces after each pulse of projected warm water intrusion. The long-term sea-level contribution is approximately proportional to the total shelf-ice melt. Although the local instabilities might dominate the ice loss for weak oceanic warming12, we find that the upper limit of ice discharge from the region is determined by the forcing and not by the marine ice-sheet instability.}, language = {en} } @article{Baushev2016, author = {Baushev, Anton N.}, title = {Can the dark matter annihilation signal be significantly boosted by substructures?}, series = {Journal of cosmology and astroparticle physics}, volume = {30}, journal = {Journal of cosmology and astroparticle physics}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {1475-7516}, doi = {10.1088/1475-7516/2016/01/018}, pages = {12 -- 18}, year = {2016}, abstract = {A very general cosmological consideration suggests that, along with galactic dark matter halos, much smaller dark matter structures may exist. These structures are usually called `clumps', and their mass extends to 10\&\#8722;6 M \&\#8857; or even lower. The clumps should give the main contribution into the signal of dark matter annihilation, provided that they have survived until the present time. Recent observations favor a cored profile for low-mass astrophysical halos. We consider cored clumps and show that they are significantly less firm than the standard NFW ones. In contrast to the standard scenario, the cored clumps should have been completely destroyed inside ~ 20 kpc from the Milky Way center. The dwarf spheroidals should not contain any dark matter clumps. On the other hand, even under the most pessimistic assumption about the clump structure, the clumps should have survived in the Milky Way at a distance exceeding 50 kpc from the center, as well as in low-density cosmic structures. There they significantly boost the dark matter annihilation. We show that at least 70\% of the clumps endured the primordial structure formation should still exist untouched in the present-day Universe.}, language = {en} } @article{KuznetsovTurukinaChernyshovetal.2016, author = {Kuznetsov, Alexander P. and Turukina, Ludmila V. and Chernyshov, Nikolai Yu and Sedova, Yuliya V.}, title = {Oscillations and Synchronization in a System of Three Reactively Coupled Oscillators}, series = {International journal of bifurcation and chaos : in applied sciences and engineering}, volume = {26}, journal = {International journal of bifurcation and chaos : in applied sciences and engineering}, publisher = {World Scientific}, address = {Singapore}, issn = {0218-1274}, doi = {10.1142/S0218127416500103}, pages = {31 -- 39}, year = {2016}, abstract = {We consider a system of three interacting van der Pol oscillators with reactive coupling. Phase equations are derived, using proper order of expansion over the coupling parameter. The dynamics of the system is studied by means of the bifurcation analysis and with the method of Lyapunov exponent charts. Essential and physically meaningful features of the reactive coupling are discussed.}, language = {en} } @article{YadavalliLoebnerPapkeetal.2016, author = {Yadavalli, Nataraja Sekhar and Loebner, Sarah and Papke, Thomas and Sava, Elena and Hurduc, Nicolae and Santer, Svetlana}, title = {A comparative study of photoinduced deformation in azobenzene containing polymer films}, series = {Soft matter}, volume = {12}, journal = {Soft matter}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {1744-683X}, doi = {10.1039/c6sm00029k}, pages = {2593 -- 2603}, year = {2016}, abstract = {In this paper two groups supporting different views on the mechanism of light induced polymer deformation argue about the respective underlying theoretical conceptions, in order to bring this interesting debate to the attention of the scientific community. The group of Prof. Nicolae Hurduc supports the model claiming that the cyclic isomerization of azobenzenes may cause an athermal transition of the glassy azobenzene containing polymer into a fluid state, the so-called photo-fluidization concept. This concept is quite convenient for an intuitive understanding of the deformation process as an anisotropic flow of the polymer material. The group of Prof. Svetlana Santer supports the re-orientational model where the mass-transport of the polymer material accomplished during polymer deformation is stated to be generated by the light-induced re-orientation of the azobenzene side chains and as a consequence of the polymer backbone that in turn results in local mechanical stress, which is enough to irreversibly deform an azobenzene containing material even in the glassy state. For the debate we chose three polymers differing in the glass transition temperature, 32 degrees C, 87 degrees C and 95 degrees C, representing extreme cases of flexible and rigid materials. Polymer film deformation occurring during irradiation with different interference patterns is recorded using a homemade set-up combining an optical part for the generation of interference patterns and an atomic force microscope for acquiring the kinetics of film deformation. We also demonstrated the unique behaviour of azobenzene containing polymeric films to switch the topography in situ and reversibly by changing the irradiation conditions. We discuss the results of reversible deformation of three polymers induced by irradiation with intensity (IIP) and polarization (PIP) interference patterns, and the light of homogeneous intensity in terms of two approaches: the re-orientational and the photo-fluidization concepts. Both agree in that the formation of opto-mechanically induced stresses is a necessary prerequisite for the process of deformation. Using this argument, the deformation process can be characterized either as a flow or mass transport.}, language = {en} } @misc{TeifCherstvy2016, author = {Teif, Vladimir B. and Cherstvy, Andrey G.}, title = {Chromatin and epigenetics: current biophysical views}, series = {AIMS biophysics}, volume = {3}, journal = {AIMS biophysics}, publisher = {American Institute of Mathematical Sciences}, address = {Springfield}, issn = {2377-9098}, doi = {10.3934/biophy.2016.1.88}, pages = {88 -- 98}, year = {2016}, abstract = {Recent advances in high-throughput sequencing experiments and their theoretical descriptions have determined fast dynamics of the "chromatin and epigenetics" field, with new concepts appearing at high rate. This field includes but is not limited to the study of DNA-protein-RNA interactions, chromatin packing properties at different scales, regulation of gene expression and protein trafficking in the cell nucleus, binding site search in the crowded chromatin environment and modulation of physical interactions by covalent chemical modifications of the binding partners. The current special issue does not pretend for the full coverage of the field, but it rather aims to capture its development and provide a snapshot of the most recent concepts and approaches. Eighteen open-access articles comprising this issue provide a delicate balance between current theoretical and experimental biophysical approaches to uncover chromatin structure and understand epigenetic regulation, allowing free flow of new ideas and preliminary results.}, language = {en} } @article{LiebigSarhanPrietzeletal.2016, author = {Liebig, Ferenc and Sarhan, Radwan Mohamed and Prietzel, Claudia Christina and Reinecke, Antje and Koetz, Joachim}, title = {"Green" gold nanotriangles: synthesis, purification by polyelectrolyte/micelle depletion flocculation and performance in surface-enhanced Raman scattering}, series = {RSC Advances}, volume = {6}, journal = {RSC Advances}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {2046-2069}, doi = {10.1039/c6ra04808k}, pages = {33561 -- 33568}, year = {2016}, abstract = {The aim of this study was to develop a one-step synthesis of gold nanotriangles (NTs) in the presence of mixed phospholipid vesicles followed by a separation process to isolate purified NTs. Negatively charged vesicles containing AOT and phospholipids, in the absence and presence of additional reducing agents (polyampholytes, polyanions or low molecular weight compounds), were used as a template phase to form anisotropic gold nanoparticles. Upon addition of the gold chloride solution, the nucleation process is initiated and both types of particles, i.e., isotropic spherical and anisotropic gold nanotriangles, are formed simultaneously. As it was not possible to produce monodisperse nanotriangles with such a one-step procedure, the anisotropic nanoparticles needed to be separated from the spherical ones. Therefore, a new type of separation procedure using combined polyelectrolyte/micelle depletion flocculation was successfully applied. As a result of the different purification steps, a green colored aqueous dispersion was obtained containing highly purified, well-defined negatively charged flat nanocrystals with a platelet thickness of 10 nm and an edge length of about 175 nm. The NTs produce promising results in surface-enhanced Raman scattering.}, language = {en} } @article{SandmannGarzMenzel2016, author = {Sandmann, Michael and Garz, Andreas and Menzel, Ralf}, title = {Physiological response of two different Chlamydomonas reinhardtii strains to light-dark rhythms}, series = {Botany}, volume = {94}, journal = {Botany}, publisher = {NRC Research Press}, address = {Ottawa}, issn = {1916-2790}, doi = {10.1139/cjb-2015-0144}, pages = {53 -- 64}, year = {2016}, abstract = {Cells of a cell-wall deficient line (cw15-type) of Chlamydomonas reinhardtii and of the corresponding wild type were grown during repetitive light-dark cycles. In a direct comparison, both lines showed approximately the same relative biomass increase during light phase but the cw-line produced significantly more, and smaller, daughter cells. Throughout the light period the average cellular starch content, the cellular chlorophyll content, the cellular rate of dark respiration, and the cellular rate of photosynthesis of the cw-line was lower. Despite this, several non-cell volume related parameters like the development of starch content per cell volume were clearly different over time between the strains. Additionally, the chlorophyll-based photosynthesis rates were 2-fold higher in the mutant than in the wild-type cells, and the ratio of chlorophyll a to chlorophyll b as well as the light-saturation index were also consistently higher in the mutant cells. Differences in the starch content were also confirmed by single cell analyses using a sensitive SHG-based microscopy approach. In summary, the cw15-type mutant deviates from its genetic background in the entire cell physiology. Both lines should be used in further studies in comparative systems biology with focus on the detailed relation between cell volume increase, photosynthesis, starch metabolism, and daughter cell productivity.}, language = {en} } @article{FrielerMengelLevermann2016, author = {Frieler, Katja and Mengel, M. and Levermann, Anders}, title = {Delaying future sea-level rise by storing water in Antarctica}, series = {Earth system dynamics}, volume = {7}, journal = {Earth system dynamics}, publisher = {Copernicus}, address = {G{\"o}ttingen}, issn = {2190-4979}, doi = {10.5194/esd-7-203-2016}, pages = {203 -- 210}, year = {2016}, abstract = {Even if greenhouse gas emissions were stopped today, sea level would continue to rise for centuries, with the long-term sea-level commitment of a 2 degrees C warmer world significantly exceeding 2 m. In view of the potential implications for coastal populations and ecosystems worldwide, we investigate, from an ice-dynamic perspective, the possibility of delaying sea-level rise by pumping ocean water onto the surface of the Antarctic ice sheet. We find that due to wave propagation ice is discharged much faster back into the ocean than would be expected from a pure advection with surface velocities. The delay time depends strongly on the distance from the coastline at which the additional mass is placed and less strongly on the rate of sea-level rise that is mitigated. A millennium-scale storage of at least 80\% of the additional ice requires placing it at a distance of at least 700 km from the coastline. The pumping energy required to elevate the potential energy of ocean water to mitigate the currently observed 3 mmyr(-1) will exceed 7\% of the current global primary energy supply. At the same time, the approach offers a comprehensive protection for entire coastlines particularly including regions that cannot be protected by dikes.}, language = {en} } @article{SandevIominKantzetal.2016, author = {Sandev, T. and Iomin, Alexander and Kantz, Holger and Metzler, Ralf and Chechkin, Aleksei V.}, title = {Comb Model with Slow and Ultraslow Diffusion}, series = {Mathematical modelling of natural phenomena}, volume = {11}, journal = {Mathematical modelling of natural phenomena}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {0973-5348}, doi = {10.1051/mmnp/201611302}, pages = {18 -- 33}, year = {2016}, abstract = {We consider a generalized diffusion equation in two dimensions for modeling diffusion on a comb-like structures. We analyze the probability distribution functions and we derive the mean squared displacement in x and y directions. Different forms of the memory kernels (Dirac delta, power-law, and distributed order) are considered. It is shown that anomalous diffusion may occur along both x and y directions. Ultraslow diffusion and some more general diffusive processes are observed as well. We give the corresponding continuous time random walk model for the considered two dimensional diffusion-like equation on a comb, and we derive the probability distribution functions which subordinate the process governed by this equation to the Wiener process.}, language = {en} } @article{PavlenkoSanderMitzscherlingetal.2016, author = {Pavlenko, Elena S. and Sander, Mathias and Mitzscherling, S. and Pudell, Jan-Etienne and Zamponi, Flavio and Roessle, M. and Bojahr, Andre and Bargheer, Matias}, title = {Azobenzene - functionalized polyelectrolyte nanolayers as ultrafast optoacoustic transducers}, series = {Nanoscale}, volume = {8}, journal = {Nanoscale}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {2040-3364}, doi = {10.1039/c6nr01448h}, pages = {13297 -- 13302}, year = {2016}, abstract = {We introduce azobenzene-functionalized polyelectrolyte multilayers as efficient, inexpensive optoacoustic transducers for hyper-sound strain waves in the GHz range. By picosecond transient reflectivity measurements we study the creation of nanoscale strain waves, their reflection from interfaces, damping by scattering from nanoparticles and propagation in soft and hard adjacent materials like polymer layers, quartz and mica. The amplitude of the generated strain epsilon similar to 5 x 10(-4) is calibrated by ultrafast X-ray diffraction.}, language = {en} } @article{HollaenderKossackKolloscheetal.2016, author = {Holl{\"a}nder, Lars and Kossack, Wilhelm and Kollosche, Matthias and Wirges, Werner and Kremer, Friedrich and Gerhard, Reimund}, title = {Influence of the remanent polarisation on the liquid crystal alignment in composite films of ferroelectric poly(vinylidene fluoride-trifluoroethylene) and a cyanobiphenyl-based liquid crystal}, series = {Liquid crystals : an international journal of science and technology}, volume = {43}, journal = {Liquid crystals : an international journal of science and technology}, publisher = {Editions Rodopi BV}, address = {Abingdon}, issn = {0267-8292}, doi = {10.1080/02678292.2016.1185174}, pages = {1514 -- 1521}, year = {2016}, abstract = {Polymer-dispersed liquid crystals (PDLCs) of ferroelectric poly(vinylidene fluoride-trifluoroethylene) and nematic 4-cyano-4\&\#697;-n-hexylbiphenyl (6CB) or 4-cyano-4\&\#697;-n-pentylbiphenyl (5CB) were prepared to study the effect of the remanent polarisation of the polymer on the liquid crystal alignment. We measured the macroscopic alignment of the liquid crystal molecules in the thickness direction by means of Infrared Transition-Moment Orientational Analysis. Electrical poling at 100 V/µm caused an increased order parameter up to 0.15. After subsequent annealing above the nematic-to-isotropic phase-transition temperature, the order parameter was reduced to 0.02. Nevertheless, the order parameter was still higher than for non-poled film indicating a slight orientation in thickness direction. Both values are lower than those expected from model calculations. In agreement with dielectric measurements, we attribute this result to the shielding effect of mobile charge carriers within the liquid crystal inclusions.}, language = {en} } @article{MuenchKipfstuhlFreitagetal.2016, author = {M{\"u}nch, Thomas and Kipfstuhl, Sepp and Freitag, Johannes and Meyer, Hanno and Laepple, Thomas}, title = {Regional climate signal vs. local noise: a two-dimensional view of water isotopes in Antarctic firn at Kohnen Station, Dronning Maud Land}, series = {Climate of the past : an interactive open access journal of the European Geosciences Union}, volume = {12}, journal = {Climate of the past : an interactive open access journal of the European Geosciences Union}, publisher = {Copernicus}, address = {G{\"o}ttingen}, issn = {1814-9324}, doi = {10.5194/cp-12-1565-2016}, pages = {1565 -- 1581}, year = {2016}, abstract = {In low-accumulation regions, the reliability of delta O-18-derived temperature signals from ice cores within the Holocene is unclear, primarily due to the small climate changes relative to the intrinsic noise of the isotopic signal. In order to learn about the representativity of single ice cores and to optimise future ice-core-based climate reconstructions, we studied the stable-water isotope composition of firn at Kohnen Station, Dronning Maud Land, Antarctica. Analysing delta O-18 in two 50m long snow trenches allowed us to create an unprecedented, two-dimensional image characterising the isotopic variations from the centimetre to the 100-metre scale. Our results show seasonal layering of the isotopic composition but also high horizontal isotopic variability caused by local stratigraphic noise. Based on the horizontal and vertical structure of the isotopic variations, we derive a statistical noise model which successfully explains the trench data. The model further allows one to determine an upper bound for the reliability of climate reconstructions conducted in our study region at seasonal to annual resolution, depending on the number and the spacing of the cores taken.}, language = {en} } @article{GhoshCherstvyPetrovetal.2016, author = {Ghosh, Surya K. and Cherstvy, Andrey G. and Petrov, Eugene P. and Metzler, Ralf}, title = {Interactions of rod-like particles on responsive elastic sheets}, series = {Soft matter}, volume = {12}, journal = {Soft matter}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {1744-683X}, doi = {10.1039/c6sm01522k}, pages = {7908 -- 7919}, year = {2016}, abstract = {What are the physical laws of the mutual interactions of objects bound to cell membranes, such as various membrane proteins or elongated virus particles? To rationalise this, we here investigate by extensive computer simulations mutual interactions of rod-like particles adsorbed on the surface of responsive elastic two-dimensional sheets. Specifically, we quantify sheet deformations as a response to adhesion of such filamentous particles. We demonstrate that tip-to-tip contacts of rods are favoured for relatively soft sheets, while side-by-side contacts are preferred for stiffer elastic substrates. These attractive orientation-dependent substrate-mediated interactions between the rod-like particles on responsive sheets can drive their aggregation and self-assembly. The optimal orientation of the membrane-bound rods is established via responding to the elastic energy profiles created around the particles. We unveil the phase diagramme of attractive-repulsive rod-rod interactions in the plane of their separation and mutual orientation. Applications of our results to other systems featuring membrane-associated particles are also discussed.}, language = {en} } @article{YangGuehrVecchioneetal.2016, author = {Yang, Jie and G{\"u}hr, Markus and Vecchione, Theodore and Robinson, Matthew Scott and Li, Renkai and Hartmann, Nick and Shen, Xiaozhe and Coffee, Ryan and Corbett, Jeff and Fry, Alan and Gaffney, Kelly and Gorkhover, Tais and Hast, Carsten and Jobe, Keith and Makasyuk, Igor and Reid, Alexander and Robinson, Joseph and Vetter, Sharon and Wang, Fenglin and Weathersby, Stephen and Yoneda, Charles and Wang, Xijie and Centurion, Martin}, title = {Femtosecond gas phase electron diffraction with MeV electrons}, series = {Faraday discussions}, volume = {194}, journal = {Faraday discussions}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {1359-6640}, doi = {10.1039/c6fd00071a}, pages = {563 -- 581}, year = {2016}, abstract = {We present results on ultrafast gas electron diffraction (UGED) experiments with femtosecond resolution using the MeV electron gun at SLAC National Accelerator Laboratory. UGED is a promising method to investigate molecular dynamics in the gas phase because electron pulses can probe the structure with a high spatial resolution. Until recently, however, it was not possible for UGED to reach the relevant timescale for the motion of the nuclei during a molecular reaction. Using MeV electron pulses has allowed us to overcome the main challenges in reaching femtosecond resolution, namely delivering short electron pulses on a gas target, overcoming the effect of velocity mismatch between pump laser pulses and the probe electron pulses, and maintaining a low timing jitter. At electron kinetic energies above 3 MeV, the velocity mismatch between laser and electron pulses becomes negligible. The relativistic electrons are also less susceptible to temporal broadening due to the Coulomb force. One of the challenges of diffraction with relativistic electrons is that the small de Broglie wavelength results in very small diffraction angles. In this paper we describe the new setup and its characterization, including capturing static diffraction patterns of molecules in the gas phase, finding time-zero with sub-picosecond accuracy and first time-resolved diffraction experiments. The new device can achieve a temporal resolution of 100 fs root-mean-square, and sub-angstrom spatial resolution. The collimation of the beam is sufficient to measure the diffraction pattern, and the transverse coherence is on the order of 2 nm. Currently, the temporal resolution is limited both by the pulse duration of the electron pulse on target and by the timing jitter, while the spatial resolution is limited by the average electron beam current and the signal-to-noise ratio of the detection system. We also discuss plans for improving both the temporal resolution and the spatial resolution.}, language = {en} } @article{GhoshCherstvyGrebenkovetal.2016, author = {Ghosh, Surya K. and Cherstvy, Andrey G. and Grebenkov, Denis S. and Metzler, Ralf}, title = {Anomalous, non-Gaussian tracer diffusion in crowded two-dimensional environments}, series = {NEW JOURNAL OF PHYSICS}, volume = {18}, journal = {NEW JOURNAL OF PHYSICS}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {1367-2630}, doi = {10.1088/1367-2630/18/1/013027}, pages = {16}, year = {2016}, abstract = {A topic of intense current investigation pursues the question of how the highly crowded environment of biological cells affects the dynamic properties of passively diffusing particles. Motivated by recent experiments we report results of extensive simulations of the motion of a finite sized tracer particle in a heterogeneously crowded environment made up of quenched distributions of monodisperse crowders of varying sizes in finite circular two-dimensional domains. For given spatial distributions of monodisperse crowders we demonstrate how anomalous diffusion with strongly non-Gaussian features arises in this model system. We investigate both biologically relevant situations of particles released either at the surface of an inner domain or at the outer boundary, exhibiting distinctly different features of the observed anomalous diffusion for heterogeneous distributions of crowders. Specifically we reveal an asymmetric spreading of tracers even at moderate crowding. In addition to the mean squared displacement (MSD) and local diffusion exponent we investigate the magnitude and the amplitude scatter of the time averaged MSD of individual tracer trajectories, the non-Gaussianity parameter, and the van Hove correlation function. We also quantify how the average tracer diffusivity varies with the position in the domain with a heterogeneous radial distribution of crowders and examine the behaviour of the survival probability and the dynamics of the tracer survival probability. Inter alia, the systems we investigate are related to the passive transport of lipid molecules and proteins in two-dimensional crowded membranes or the motion in colloidal solutions or emulsions in effectively two-dimensional geometries, as well as inside supercrowded, surface adhered cells.}, language = {en} } @article{GanopolskiWinkelmannSchellnhuber2016, author = {Ganopolski, A. and Winkelmann, Ricarda and Schellnhuber, Hans Joachim}, title = {Critical insolation-CO2 relation for diagnosing past and future glacial inception}, series = {Nature : the international weekly journal of science}, volume = {529}, journal = {Nature : the international weekly journal of science}, publisher = {Nature Publ. Group}, address = {London}, issn = {0028-0836}, doi = {10.1038/nature16494}, pages = {200 -- U159}, year = {2016}, abstract = {The past rapid growth of Northern Hemisphere continental ice sheets, which terminated warm and stable climate periods, is generally attributed to reduced summer insolation in boreal latitudes(1-3). Yet such summer insolation is near to its minimum at present(4), and there are no signs of a new ice age(5). This challenges our understanding of the mechanisms driving glacial cycles and our ability to predict the next glacial inception(6). Here we propose a critical functional relationship between boreal summer insolation and global carbon dioxide (CO2) concentration, which explains the beginning of the past eight glacial cycles and might anticipate future periods of glacial inception. Using an ensemble of simulations generated by an Earth system model of intermediate complexity constrained by palaeoclimatic data, we suggest that glacial inception was narrowly missed before the beginning of the Industrial Revolution. The missed inception can be accounted for by the combined effect of relatively high late-Holocene CO2 concentrations and the low orbital eccentricity of the Earth(7). Additionally, our analysis suggests that even in the absence of human perturbations no substantial build-up of ice sheets would occur within the next several thousand years and that the current interglacial would probably last for another 50,000 years. However, moderate anthropogenic cumulative CO2 emissions of 1,000 to 1,500 gigatonnes of carbon will postpone the next glacial inception by at least 100,000 years(8,9). Our simulations demonstrate that under natural conditions alone the Earth system would be expected to remain in the present delicately balanced interglacial climate state, steering clear of both large-scale glaciation of the Northern Hemisphere and its complete deglaciation, for an unusually long time.}, language = {en} } @article{ArchambaultArcherAuneetal.2016, author = {Archambault, S. and Archer, A. and Aune, T. and Barnacka, Anna and Benbow, W. and Bird, R. and Buchovecky, M. and Buckley, J. H. and Bugaev, V. and Byrum, K. and Cardenzana, J. V. and Cerruti, M. and Chen, Xuhui and Ciupik, L. and Collins-Hughes, E. and Connolly, M. P. and Cui, W. and Dickinson, H. J. and Dumm, J. and Eisch, J. D. and Falcone, A. and Feng, Q. and Finley, J. P. and Fleischhack, H. and Flinders, A. and Fortin, P. and Fortson, L. and Furniss, A. and Gillanders, G. H. and Griffin, S. and Grube, J. and Gyuk, G. and Huetten, M. and Hakansson, Nils and Hanna, D. and Holder, J. and Humensky, T. B. and Johnson, C. A. and Kaaret, P. and Kar, P. and Kelley-Hoskins, N. and Kertzman, M. and Khassen, Y. and Kieda, D. and Krause, M. and Krennrich, F. and Kumar, S. and Lang, M. J. and Maier, G. and McArthur, S. and McCann, A. and Meagher, K. and Millis, J. and Moriarty, P. and Mukherjee, R. and Nieto, D. and Ong, R. A. and Otte, A. N. and Pandel, D. and Park, N. and Pelassa, V. and Pohl, Martin and Popkow, A. and Pueschel, Elisa and Quinn, J. and Ragan, K. and Reynolds, P. T. and Richards, G. T. and Roache, E. and Rousselle, J. and Rulten, C. and Santander, M. and Sembroski, G. H. and Shahinyan, K. and Smith, A. W. and Staszak, D. and Telezhinsky, Igor O. and Tucci, J. V. and Tyler, J. and Vincent, S. and Wakely, S. P. and Weiner, O. M. and Weinstein, A. and Wilhelm, Alina and Williams, D. A. and Zitzer, B.}, title = {EXCEPTIONALLY BRIGHT TEV FLARES FROM THE BINARY LS I+61 degrees 303}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics ; Part 2, Letters}, volume = {817}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics ; Part 2, Letters}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {2041-8205}, doi = {10.3847/2041-8205/817/1/L7}, pages = {6}, year = {2016}, abstract = {The TeV binary system LS I +61 degrees 303 is known for its regular, non-thermal emission pattern that traces the orbital period of the compact object in its 26.5 day orbit around its B0 Ve star companion. The system typically presents elevated TeV emission around apastron passage with flux levels between 5\% and 15\% of the steady flux from the Crab Nebula (> 300 GeV). In this article, VERITAS observations of LS I + 61 degrees. 303 taken in late 2014 are presented, during which bright TeV flares around apastron at flux levels peaking above 30\% of the Crab Nebula flux were detected. This is the brightest such activity from this source ever seen in the TeV regime. The strong outbursts have rise and fall times of less than a day. The short timescale of the flares, in conjunction with the observation of 10 TeV photons from LS I + 61 degrees 303 during the flares, provides constraints on the properties of the accelerator in the source.}, language = {en} } @article{LeonhardtGerhardtHoeppneretal.2016, author = {Leonhardt, Helmar and Gerhardt, Matthias and Hoeppner, Nadine and Kr{\"u}ger, Kirsten and Tarantola, Marco and Beta, Carsten}, title = {Cell-substrate impedance fluctuations of single amoeboid cells encode cell-shape and adhesion dynamics}, series = {Physical review : E, Statistical, nonlinear and soft matter physics}, volume = {93}, journal = {Physical review : E, Statistical, nonlinear and soft matter physics}, publisher = {American Physical Society}, address = {College Park}, issn = {2470-0045}, doi = {10.1103/PhysRevE.93.012414}, pages = {8}, year = {2016}, abstract = {We show systematic electrical impedance measurements of single motile cells on microelectrodes. Wild-type cells and mutant strains were studied that differ in their cell-substrate adhesion strength. We recorded the projected cell area by time-lapse microscopy and observed irregular oscillations of the cell shape. These oscillations were correlated with long-term variations in the impedance signal. Superposed to these long-term trends, we observed fluctuations in the impedance signal. Their magnitude clearly correlated with the adhesion strength, suggesting that strongly adherent cells display more dynamic cell-substrate interactions.}, language = {en} } @article{SchreckPietzschKennedyetal.2016, author = {Schreck, Simon and Pietzsch, Annette and Kennedy, Brian and Sathe, Conny and Miedema, Piter S. and Techert, Simone and Strocov, Vladimir N. and Schmitt, Thorsten and Hennies, Franz and Rubensson, Jan-Erik and F{\"o}hlisch, Alexander}, title = {Ground state potential energy surfaces around selected atoms from resonant inelastic x-ray scattering}, series = {Scientific reports}, volume = {6}, journal = {Scientific reports}, publisher = {Nature Publ. Group}, address = {London}, issn = {2045-2322}, doi = {10.1038/srep20054}, pages = {7}, year = {2016}, abstract = {Thermally driven chemistry as well as materials' functionality are determined by the potential energy surface of a systems electronic ground state. This makes the potential energy surface a central and powerful concept in physics, chemistry and materials science. However, direct experimental access to the potential energy surface locally around atomic centers and to its long-range structure are lacking. Here we demonstrate how sub-natural linewidth resonant inelastic soft x-ray scattering at vibrational resolution is utilized to determine ground state potential energy surfaces locally and detect long-range changes of the potentials that are driven by local modifications. We show how the general concept is applicable not only to small isolated molecules such as O2 but also to strongly interacting systems such as the hydrogen bond network in liquid water. The weak perturbation to the potential energy surface through hydrogen bonding is observed as a trend towards softening of the ground state potential around the coordinating atom. The instrumental developments in high resolution resonant inelastic soft x-ray scattering are currently accelerating and will enable broad application of the presented approach. With this multidimensional potential energy surfaces that characterize collective phenomena such as (bio)molecular function or high-temperature superconductivity will become accessible in near future.}, language = {en} } @article{RaetzelWilkensMenzel2016, author = {R{\"a}tzel, Dennis and Wilkens, Martin and Menzel, Ralf}, title = {Gravitational properties of light-the gravitational field of a laser pulse}, series = {NEW JOURNAL OF PHYSICS}, volume = {18}, journal = {NEW JOURNAL OF PHYSICS}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {1367-2630}, doi = {10.1088/1367-2630/18/2/023009}, pages = {16}, year = {2016}, abstract = {The gravitational field of a laser pulse of finite lifetime, is investigated in the framework of linearized gravity. Although the effects are very small, they may be of fundamental physical interest. It is shown that the gravitational field of a linearly polarized light pulse is modulated as the norm of the corresponding electric field strength, while no modulations arise for circular polarization. In general, the gravitational field is independent of the polarization direction. It is shown that all physical effects are confined to spherical shells expanding with the speed of light, and that these shells are imprints of the spacetime events representing emission and absorption of the pulse. Nearby test particles at rest are attracted towards the pulse trajectory by the gravitational field due to the emission of the pulse, and they are repelled from the pulse trajectory by the gravitational field due to its absorption. Examples are given for the size of the attractive effect. It is recovered that massless test particles do not experience any physical effect if they are co-propagating with the pulse, and that the acceleration of massless test particles counter-propagating with respect to the pulse is four times stronger than for massive particles at rest. The similarities between the gravitational effect of a laser pulse and Newtonian gravity in two dimensions are pointed out. The spacetime curvature close to the pulse is compared to that induced by gravitational waves from astronomical sources.}, language = {en} } @article{KappelArnoldHaus2016, author = {Kappel, David and Arnold, Gabriele and Haus, Rainer}, title = {Multi-spectrum retrieval of Venus IR surface emissivity maps from VIRTIS/VEX nightside measurements at Themis Regio}, series = {Icarus : international journal of solar system studies}, volume = {265}, journal = {Icarus : international journal of solar system studies}, publisher = {Elsevier}, address = {San Diego}, issn = {0019-1035}, doi = {10.1016/j.icarus.2015.10.014}, pages = {42 -- 62}, year = {2016}, abstract = {Renormalized emissivity maps of Themis Regio at the three surface windows are determined from 64 measurement repetitions. Retrieval errors are estimated by a statistical evaluation of maps derived from various disjoint selections of spectra and using different assumptions on the interfering parameters. Double standard deviation errors for the three surface windows amount to 3\%, 8\%, and 4\%, respectively, allowing geologic interpretation. A comparison to results from an earlier error analysis based on synthetic spectra shows that unconsidered time variations of interfering atmospheric parameters are a major error source. Spatial variations of the 1.02 mu m surface emissivity of 20\% that correspond to the difference between unweathered granitic and basaltic rocks would be easily detectable, but such variations are ruled out for the studied target area. Emissivity anomalies of up to 8\% are detected at both 1.02 and 1.18 mu m. At present sensitivity, no anomalies are identified at 1.10 mu m, but anomalies exceeding the determined error level can be excluded. With single standard deviation significance, all three maps show interesting spatial emissivity variations. (C) 2015 Elsevier Inc. All rights reserved.}, language = {en} } @article{GeHeYan2016, author = {Ge, J. X. and He, J. H. and Yan, Huirong}, title = {Effects of turbulent dust grain motion to interstellar chemistry}, series = {Monthly notices of the Royal Astronomical Society}, volume = {455}, journal = {Monthly notices of the Royal Astronomical Society}, publisher = {Oxford Univ. Press}, address = {Oxford}, issn = {0035-8711}, doi = {10.1093/mnras/stv2560}, pages = {3570 -- 3587}, year = {2016}, abstract = {Theoretical studies have revealed that dust grains are usually moving fast through the turbulent interstellar gas, which could have significant effects upon interstellar chemistry by modifying grain accretion. This effect is investigated in this work on the basis of numerical gas-grain chemical modelling. Major features of the grain motion effect in the typical environment of dark clouds (DC) can be summarized as follows: (1) decrease of gas-phase (both neutral and ionic) abundances and increase of surface abundances by up to 2-3 orders of magnitude; (2) shifts of the existing chemical jumps to earlier evolution ages for gas-phase species and to later ages for surface species by factors of about 10; (3) a few exceptional cases in which some species turn out to be insensitive to this effect and some other species can show opposite behaviours too. These effects usually begin to emerge from a typical DC model age of about 10(5) yr. The grain motion in a typical cold neutral medium (CNM) can help overcome the Coulomb repulsive barrier to enable effective accretion of cations on to positively charged grains. As a result, the grain motion greatly enhances the abundances of some gas-phase and surface species by factors up to 2-6 or more orders of magnitude in the CNM model. The grain motion effect in a typical molecular cloud (MC) is intermediate between that of the DC and CNM models, but with weaker strength. The grain motion is found to be important to consider in chemical simulations of typical interstellar medium.}, language = {en} } @article{PuhlmannHenkelHeueretal.2016, author = {Puhlmann, Dirk and Henkel, Carsten and Heuer, Axel and Pieplow, Gregor and Menzel, Ralf}, title = {Characterization of a remote optical element with bi-photons}, series = {Physica scripta : an international journal for experimental and theoretical physics}, volume = {91}, journal = {Physica scripta : an international journal for experimental and theoretical physics}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0031-8949}, doi = {10.1088/0031-8949/91/2/023006}, pages = {113 -- 114}, year = {2016}, abstract = {We present a simple setup that exploits the interference of entangled photon pairs. 'Signal' photons are sent through a Mach-Zehnder-like interferometer, while 'idlers' are detected in a variable polarization state. Two-photon interference (in coincidence detection) is observed with very high contrast and for significant time delays between signal and idler detection events. This is explained by quantum erasure of the polarization tag and a delayed choice protocol involving a non-local virtual polarizer. The phase of the two-photon fringes is scanned by varying the path length in the signal beam or by rotating a birefringent crystal in the idler beam. We exploit this to characterize one beam splitter of the signal photon interferometer (reflection and transmission amplitudes including losses), using only information about coincidences and control parameters in the idler path. This is possible because our bi-photon state saturates the Greenberger-Yelin-Englert inequality between contrast and predictability.}, language = {en} } @misc{Metzler2016, author = {Metzler, Ralf}, title = {PROTEIN PHYSICS Forever ageing}, series = {Nature physics}, volume = {12}, journal = {Nature physics}, publisher = {Nature Publ. Group}, address = {London}, issn = {1745-2473}, doi = {10.1038/nphys3585}, pages = {113 -- 114}, year = {2016}, abstract = {Single-molecule techniques have long given us insight into the motion and interactions of individual molecules. But simulations now show that the dynamics inside single proteins is not as simple as we thought — and that proteins are forever changing.}, language = {en} } @article{SandinSteffenSchoenberneretal.2016, author = {Sandin, C. and Steffen, M. and Schoenberner, D. and R{\"u}hling, Ute}, title = {Hot bubbles of planetary nebulae with hydrogen-deficient winds I. Heat conduction in a chemically stratified plasma}, series = {Frontiers in psychology}, volume = {586}, journal = {Frontiers in psychology}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {1432-0746}, doi = {10.1051/0004-6361/201527357}, pages = {11}, year = {2016}, abstract = {Heat conduction has been found a plausible solution to explain discrepancies between expected and measured temperatures in hot bubbles of planetary nebulae (PNe). While the heat conduction process depends on the chemical composition, to date it has been exclusively studied for pure hydrogen plasmas in PNe. A smaller population of PNe show hydrogen-deficient and helium-and carbon-enriched surfaces surrounded by bubbles of the same composition; considerable differences are expected in physical properties of these objects in comparison to the pure hydrogen case. The aim of this study is to explore how a chemistry-dependent formulation of the heat conduction affects physical properties and how it affects the X-ray emission from PN bubbles of hydrogen-deficient stars. We extend the description of heat conduction in our radiation hydrodynamics code to work with any chemical composition. We then compare the bubble-formation process with a representative PN model using both the new and the old descriptions. We also compare differences in the resulting X-ray temperature and luminosity observables of the two descriptions. The improved equations show that the heat conduction in our representative model of a hydrogen-deficient PN is nearly as efficient with the chemistry-dependent description; a lower value on the diffusion coefficient is compensated by a slightly steeper temperature gradient. The bubble becomes somewhat hotter with the improved equations, but differences are otherwise minute. The observable properties of the bubble in terms of the X-ray temperature and luminosity are seemingly unaffected.}, language = {en} } @article{CioniBekkiGirardietal.2016, author = {Cioni, Maria-Rosa L. and Bekki, Kenji and Girardi, Leo and de Grijs, Richard and Irwin, Mike J. and Ivanov, Valentin D. and Marconi, Marcella and Oliveira, Joana M. and Piatti, Andres E. and Ripepi, Vincenzo and van Loon, Jacco Th.}, title = {XVII. Proper motions of the Small Magellanic Cloud and the Milky Way globular cluster 47 Tucanae}, series = {Physical review : E, Statistical, nonlinear and soft matter physics}, volume = {586}, journal = {Physical review : E, Statistical, nonlinear and soft matter physics}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {1432-0746}, doi = {10.1051/0004-6361/201527004}, pages = {67 -- 75}, year = {2016}, abstract = {Aims. In this study we use multi-epoch near-infrared observations from the VISTA survey of the Magellanic Cloud system (VMC) to measure the proper motions of different stellar populations in a tile of 1.5 deg2 in size in the direction of the Galactic globular cluster 47 Tuc. We obtain the proper motion of the cluster itself, of the Small Magellanic Cloud (SMC), and of the field Milky Way stars. Methods. Stars of the three main stellar components are selected according to their spatial distributions and their distributions in colour\&\#8722;magnitude diagrams. Their average coordinate displacement is computed from the difference between multiple Ks-band observations for stars as faint as Ks = 19 mag. Proper motions are derived from the slope of the best-fitting line among ten VMC epochs over a time baseline of ~1 yr. Background galaxies are used to calibrate the absolute astrometric reference frame. Results. The resulting absolute proper motion of 47 Tuc is (\&\#956;\&\#945;cos(\&\#948;), \&\#956;\&\#948;) = (+7.26 ± 0.03, \&\#8722;1.25 ± 0.03) mas yr-1. This measurement refers to about 35 000 sources distributed between 10\&\#8242; and 60\&\#8242; from the cluster centre. For the SMC we obtain (\&\#956;\&\#945;cos(\&\#948;), \&\#956;\&\#948;) = (+1.16 ± 0.07, \&\#8722;0.81 ± 0.07) mas yr-1 from about 5250 red clump and red giant branch stars. The absolute proper motion of the Milky Way population in the line of sight (l = 305.9, b = \&\#8722;44.9) of this VISTA tile is (\&\#956;\&\#945;cos(\&\#948;), \&\#956;\&\#948;) = (+10.22 ± 0.14, \&\#8722;1.27 ± 0.12) mas yr-1 and has been calculated from about 4000 sources. Systematic uncertainties associated with the astrometric reference system are 0.18 mas yr-1. Thanks to the proper motion we detect 47 Tuc stars beyond its tidal radius.}, language = {en} } @article{KumphHenkelRabletal.2016, author = {Kumph, Muir and Henkel, Carsten and Rabl, Peter and Brownnutt, Michael and Blatt, Rainer}, title = {Electric-field noise above a thin dielectric layer on metal electrodes}, series = {NEW JOURNAL OF PHYSICS}, volume = {18}, journal = {NEW JOURNAL OF PHYSICS}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {1367-2630}, doi = {10.1088/1367-2630/18/2/023020}, pages = {1125 -- 1136}, year = {2016}, abstract = {The electric-field noise above a layered structure composed of a planar metal electrode covered by a thin dielectric is evaluated and it is found that the dielectric film considerably increases the noise level, in proportion to its thickness. Importantly, even a thin (mono) layer of a low-loss dielectric can enhance the noise level by several orders of magnitude compared to the noise above a bare metal. Close to this layered surface, the power spectral density of the electric field varies with the inverse fourth power of the distance to the surface, rather than with the inverse square, as it would above a bare metal surface. Furthermore, compared to a clean metal, where the noise spectrum does not vary with frequency (in the radio-wave and microwave bands), the dielectric layer can generate electricfield noise which scales in inverse proportion to the frequency. For various realistic scenarios, the noise levels predicted from this model are comparable to those observed in trapped-ion experiments. Thus, these findings are of particular importance for the understanding and mitigation of unwanted heating and decoherence in miniaturized ion traps.}, language = {en} } @article{GodecMetzler2016, author = {Godec, Aljaz and Metzler, Ralf}, title = {First passage time distribution in heterogeneity controlled kinetics: going beyond the mean first passage time}, series = {Scientific reports}, volume = {6}, journal = {Scientific reports}, publisher = {Nature Publ. Group}, address = {London}, issn = {2045-2322}, doi = {10.1038/srep20349}, pages = {11}, year = {2016}, abstract = {The first passage is a generic concept for quantifying when a random quantity such as the position of a diffusing molecule or the value of a stock crosses a preset threshold (target) for the first time. The last decade saw an enlightening series of new results focusing mostly on the so-called mean and global first passage time (MFPT and GFPT, respectively) of such processes. Here we push the understanding of first passage processes one step further. For a simple heterogeneous system we derive rigorously the complete distribution of first passage times (FPTs). Our results demonstrate that the typical FPT significantly differs from the MFPT, which corresponds to the long time behaviour of the FPT distribution. Conversely, the short time behaviour is shown to correspond to trajectories connecting directly from the initial value to the target. Remarkably, we reveal a previously overlooked third characteristic time scale of the first passage dynamics mirroring brief excursion away from the target.}, language = {en} } @article{ZaksTomov2016, author = {Zaks, Michael A. and Tomov, Petar}, title = {Onset of time dependence in ensembles of excitable elements with global repulsive coupling}, series = {Physical review : E, Statistical, nonlinear and soft matter physics}, volume = {93}, journal = {Physical review : E, Statistical, nonlinear and soft matter physics}, publisher = {American Physical Society}, address = {College Park}, issn = {2470-0045}, doi = {10.1103/PhysRevE.93.020201}, pages = {5}, year = {2016}, abstract = {We consider the effect of global repulsive coupling on an ensemble of identical excitable elements. An increase of the coupling strength destabilizes the synchronous equilibrium and replaces it with many attracting oscillatory states, created in the transcritical heteroclinic bifurcation. The period of oscillations is inversely proportional to the distance from the critical parameter value. If the elements interact with the global field via the first Fourier harmonics of their phases, the stable equilibrium is in one step replaced by the attracting continuum of periodic motions.}, language = {en} } @article{SebekToenjesKiss2016, author = {Sebek, Michael and T{\"o}njes, Ralf and Kiss, Istvan Z.}, title = {Complex Rotating Waves and Long Transients in a Ring Network of Electrochemical Oscillators with Sparse Random Cross-Connections}, series = {Physical review letters}, volume = {116}, journal = {Physical review letters}, publisher = {American Physical Society}, address = {College Park}, issn = {0031-9007}, doi = {10.1103/PhysRevLett.116.068701}, pages = {3001 -- 3009}, year = {2016}, abstract = {We perform experiments and phase model simulations with a ring network of oscillatory electrochemical reactions to explore the effect of random connections and nonisochronicity of the interactions on the pattern formation. A few additional links facilitate the emergence of the fully synchronized state. With larger nonisochronicity, complex rotating waves or persistent irregular phase dynamics can derail the convergence to global synchronization. The observed long transients of irregular phase dynamics exemplify the possibility of a sudden onset of hypersynchronous behavior without any external stimulus or network reorganization.}, language = {en} } @misc{BattistonFarmerFlacheetal.2016, author = {Battiston, Stefano and Farmer, J. Doyne and Flache, Andreas and Garlaschelli, Diego and Haldane, Andrew G. and Heesterbeek, Hans and Hommes, Cars and Jaeger, Carlo and May, Robert and Scheffer, Marten}, title = {COMPLEX SYSTEMS Complexity theory and financial regulation}, series = {Science}, volume = {351}, journal = {Science}, publisher = {American Assoc. for the Advancement of Science}, address = {Washington}, issn = {0036-8075}, doi = {10.1126/science.aad0299}, pages = {818 -- 819}, year = {2016}, abstract = {Traditional economic theory could not explain, much less predict, the near collapse of the financial system and its long-lasting effects on the global economy. Since the 2008 crisis, there has been increasing interest in using ideas from complexity theory to make sense of economic and financial markets. Concepts, such as tipping points, networks, contagion, feedback, and resilience have entered the financial and regulatory lexicon, but actual use of complexity models and results remains at an early stage. Recent insights and techniques offer potential for better monitoring and management of highly interconnected economic and financial systems and, thus, may help anticipate and manage future crises.}, language = {en} } @article{AbeysekaraArchambaultArcheretal.2016, author = {Abeysekara, A. U. and Archambault, S. and Archer, A. and Benbow, W. and Bird, R. and Buchovecky, M. and Buckley, J. H. and Byrum, K. and Cardenzana, J. V. and Cerruti, M. and Chen, Xuhui and Christiansen, J. L. and Ciupik, L. and Cui, W. and Dickinson, H. J. and Eisch, J. D. and Errando, M. and Falcone, A. and Fegan, D. J. and Feng, Q. and Finley, J. P. and Fleischhack, H. and Fortin, P. and Fortson, L. and Furniss, A. and Gillanders, G. H. and Griffin, S. and Grube, J. and Gyuk, G. and Huetten, M. and Hakansson, Nils and Hanna, D. and Holder, J. and Humensky, T. B. and Johnson, C. A. and Kaaret, P. and Kar, P. and Kelley-Hoskins, N. and Kertzman, M. and Kieda, D. and Krause, M. and Krennrich, F. and Kumar, S. and Lang, M. J. and Lin, T. T. Y. and Maier, G. and McArthur, S. and McCann, A. and Meagher, K. and Moriarty, P. and Mukherjee, R. and Nieto, D. and Ong, R. A. and Otte, A. N. and Park, N. and Perkins, J. S. and Petrashyk, A. and Pohl, Martin and Popkow, A. and Pueschel, Elisa and Quinn, J. and Ragan, K. and Ratliff, G. and Reynolds, P. T. and Richards, G. T. and Roache, E. and Santander, M. and Sembroski, G. H. and Shahinyan, K. and Staszak, D. and Telezhinsky, Igor O. and Tucci, J. V. and Tyler, J. and Vincent, S. and Wakely, S. P. and Weiner, O. M. and Weinstein, A. and Williams, D. A. and Zitzer, B.}, title = {A SEARCH FOR BRIEF OPTICAL FLASHES ASSOCIATED WITH THE SETI TARGET KIC 8462852}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics ; Part 2, Letters}, volume = {818}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics ; Part 2, Letters}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {2041-8205}, doi = {10.3847/2041-8205/818/2/L33}, pages = {6}, year = {2016}, abstract = {The F-type star KIC. 8462852 has recently been identified as an exceptional target for search for extraterrestrial intelligence (SETI) observations. We describe an analysis methodology for optical SETI, which we have used to analyze nine hours of serendipitous archival observations of KIC. 8462852 made with the VERITAS gamma-ray observatory between 2009 and 2015. No evidence of pulsed optical beacons, above a pulse intensity at the Earth of approximately 1 photon m(-2), is found. We also discuss the potential use of imaging atmospheric Cherenkov telescope arrays in searching for extremely short duration optical transients in general.}, language = {en} } @article{LiuKliemTitovetal.2016, author = {Liu, Rui and Kliem, Bernhard and Titov, Viacheslav S. and Chen, Jun and Wang, Yuming and Wang, Haimin and Liu, Chang and Xu, Yan and Wiegelmann, Thomas}, title = {STRUCTURE, STABILITY, AND EVOLUTION OF MAGNETIC FLUX ROPES FROM THE PERSPECTIVE OF MAGNETIC TWIST}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, volume = {818}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0004-637X}, doi = {10.3847/0004-637X/818/2/148}, pages = {22}, year = {2016}, abstract = {We investigate the evolution of NOAA Active Region (AR) 11817 during 2013 August 10-12, when it developed a complex field configuration and produced four confined, followed by two eruptive, flares. These C-and-above flares are all associated with a magnetic flux rope (MFR) located along the major polarity inversion line, where shearing and converging photospheric flows are present. Aided by the nonlinear force-free field modeling, we identify the MFR through mapping magnetic connectivities and computing the twist number \${{ \mathcal T }}_{w}\$ for each individual field line. The MFR is moderately twisted (\$| {{ \mathcal T }}_{w}| \lt 2\$) and has a well-defined boundary of high squashing factor Q. We found that the field line with the extremum \$| {{ \mathcal T }}_{w}| \$ is a reliable proxy of the rope axis, and that the MFR's peak \$| {{ \mathcal T }}_{w}| \$ temporarily increases within half an hour before each flare while it decreases after the flare peak for both confined and eruptive flares. This pre-flare increase in \$| {{ \mathcal T }}_{w}| \$ has little effect on the AR's free magnetic energy or any other parameters derived for the whole region, due to its moderate amount and the MFR's relatively small volume, while its decrease after flares is clearly associated with the stepwise decrease in the whole region's free magnetic energy due to the flare. We suggest that \${{ \mathcal T }}_{w}\$ may serve as a useful parameter in forewarning the onset of eruption, and therefore, the consequent space weather effects. The helical kink instability is identified as the prime candidate onset mechanism for the considered flares.}, language = {en} } @article{ShiEijtSandeepetal.2016, author = {Shi, Wenqin and Eijt, Stephan W. H. and Sandeep, Chandramathi Sukumaran Suchand and Siebbeles, Laurens D. A. and Houtepen, Arjan J. and Kinge, Sachin and Bruck, Ekkes and Barbiellini, Bernardo and Bansil, Arun}, title = {Ligand-surface interactions and surface oxidation of colloidal PbSe quantum dots revealed by thin-film positron annihilation methods}, series = {Applied physics letters}, volume = {108}, journal = {Applied physics letters}, publisher = {American Institute of Physics}, address = {Melville}, issn = {0003-6951}, doi = {10.1063/1.4942609}, pages = {213 -- 230}, year = {2016}, abstract = {Positron Two Dimensional Angular Correlation of Annihilation Radiation (2D-ACAR) measurements reveal modifications of the electronic structure and composition at the surfaces of PbSe quantum dots (QDs), deposited as thin films, produced by various ligands containing either oxygen or nitrogen atoms. In particular, the 2D--ACAR measurements on thin films of colloidal PbSe QDs capped with oleic acid ligands yield an increased intensity in the electron momentum density (EMD) at high momenta compared to PbSe quantum dots capped with oleylamine. Moreover, the EMD of PbSe QDs is strongly affected by the small ethylenediamine ligands, since these molecules lead to small distances between QDs and favor neck formation between near neighbor QDs, inducing electronic coupling between neighboring QDs. The high sensitivity to the presence of oxygen atoms at the surface can be also exploited to monitor the surface oxidation of PbSe QDs upon exposure to air. Our study clearly demonstrates that positron annihilation spectroscopy applied to thin films can probe surface transformations of colloidal semiconductor QDs embedded in functional layers. (C) 2016 AIP Publishing LLC.}, language = {en} } @article{LenskeWagnerWirthetal.2016, author = {Lenske, Gerlinde and Wagner, Wolfgang and Wirth, Joachim and Thillmann, Hubertina and Cauet, Eva and Liepertz, Sven and Leutner, Detlev}, title = {The importance of pedagogical knowledge for classroom management and for and for students' achievement}, series = {Zeitschrift f{\~A}¼r Erziehungswissenschaft}, volume = {19}, journal = {Zeitschrift f{\~A}¼r Erziehungswissenschaft}, publisher = {Springer}, address = {Wiesbaden}, issn = {1434-663X}, doi = {10.1007/s11618-015-0659-x}, pages = {211 -- 233}, year = {2016}, abstract = {Im Rahmen der vorliegenden Studie wurde untersucht, ob das p{\"a}dagogisch-psychologische Wissen von Lehrkr{\"a}ften die prozessuale Qualit{\"a}t des Physikunterrichts mit Blick auf die Klassenf{\"u}hrung und den Lernzuwachs der Sch{\"u}lerinnen und Sch{\"u}ler beeinflusst. Das p{\"a}dagogisch-psychologische Professionswissen, konzeptualisiert als ein f{\"a}cher{\"u}bergreifendes, handlungsleitendes Wissen {\"u}ber Strategien und Mittel zur Unterrichtsgestaltung, wurde {\"u}ber einen Paper-Pencil-Test, bestehend aus einer Skala zum deklarativen und einer Skala zum konditional-prozeduralen Wissen erhoben (Lenske et al. 2015). Als ein grundlegendes Merkmal prozessualer Unterrichtsqualit{\"a}t wurde die Klassenf{\"u}hrung anhand von Videoratings zu zwei Messzeitpunkten (zwei Unterrichtsstunden) erfasst. Der Lernzuwachs der Sch{\"u}lerinnen und Sch{\"u}ler wurde {\"u}ber standardisierte Fachwissenstests im Pr{\"a}-Post-Testdesign gemessen. Die Stichprobe umfasst 34 Gymnasiallehrkr{\"a}fte und deren Sch{\"u}lerinnen und Sch{\"u}ler (N = 993). Auf Basis eines Complex-Bootstrap-Mediations-Modells zeigte sich, dass das p{\"a}dagogisch-psychologische Professionswissen {\"u}ber die Klassenf{\"u}hrung vermittelt den Lernzuwachs der Sch{\"u}ler und Sch{\"u}lerinnen positiv beeinflusst. In the present study it was investigated whether the pedagogical knowledge of teachers has an influence on the process quality of physics instruction and on the learning achievement of students as well. Pedagogical knowledge, conceptualized as knowledge about strategies in classroom instruction that is domain-general and relevant for teaching behaviors, was measured using a paper-and-pencil test with two scales: one scale on declarative knowledge, the other on conditional-procedural knowledge (Lenske et al. 2015). As a basic aspect of the process quality of classroom instruction, classroom management was assessed using video ratings of two lessons from each participating teacher. Students' learning achievement was assessed using standardized domain-specific knowledge tests in a pretest-posttest design. The sample included 34 teachers from higher-track secondary schools and their students (N = 993). A complex bootstrapping mediation model shows that teachers' pedagogical knowledge, mediated by their classroom management, has a positive effect on their students' learning achievement.}, language = {de} } @article{ReinhardtKocLeitenbergeretal.2016, author = {Reinhardt, Matthias and Koc, Azize and Leitenberger, Wolfram and Gaal, Peter and Bargheer, Matias}, title = {Optimized spatial overlap in optical pump-X-ray probe experiments with high repetition rate using laser-induced surface distortions}, series = {Journal of synchrotron radiation}, volume = {23}, journal = {Journal of synchrotron radiation}, publisher = {International Union of Crystallography}, address = {Chester}, issn = {1600-5775}, doi = {10.1107/S1600577515024443}, pages = {474 -- 479}, year = {2016}, abstract = {Ultrafast X-ray diffraction experiments require careful adjustment of the spatial overlap between the optical excitation and the X-ray probe pulse. This is especially challenging at high laser repetition rates. Sample distortions caused by the large heat load on the sample and the relatively low optical energy per pulse lead to only tiny signal changes. In consequence, this results in small footprints of the optical excitation on the sample, which turns the adjustment of the overlap difficult. Here a method for reliable overlap adjustment based on reciprocal space mapping of a laser excited thin film is presented.}, language = {en} } @article{EckertMiedemaQuevedoetal.2016, author = {Eckert, Sebastian and Miedema, P. S. and Quevedo, W. and Fondell, Mattis and Beye, Martin and Pietzsch, Annette and Ross, M. and Khalil, M. and F{\"o}hlisch, Alexander}, title = {Molecular structures and protonation state of 2-Mercaptopyridine in aqueous solution}, series = {Chemical physics letters}, volume = {647}, journal = {Chemical physics letters}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0009-2614}, doi = {10.1016/j.cplett.2016.01.050}, pages = {103 -- 106}, year = {2016}, abstract = {The speciation of 2-Mercaptopyridine in aqueous solution has been investigated with nitrogen 1s Near Edge X-ray Absorption Fine Structure spectroscopy and time dependent Density Functional Theory. The prevalence of distinct species as a function of the solvent basicity is established. No indications of dimerization towards high concentrations are found. The determination of different molecular structures of 2-Mercaptopyridine in aqueous solution is put into the context of proton-transfer in keto-enol and thione-thiol tautomerisms. (C) 2016 The Authors. Published by Elsevier B.V.}, language = {en} } @article{WenzKalkuhlSteckeletal.2016, author = {Wenz, Leonie and Kalkuhl, Matthias and Steckel, Jan Christoph and Creutzig, Felix}, title = {Teleconnected food supply shocks}, series = {Environmental research letters}, volume = {11}, journal = {Environmental research letters}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {1748-9326}, doi = {10.1088/1748-9326/11/3/035007}, pages = {10}, year = {2016}, abstract = {The 2008-2010 food crisis might have been a harbinger of fundamental climate-induced food crises with geopolitical implications. Heat-wave-induced yield losses in Russia and resulting export restrictions led to increases in market prices for wheat across the Middle East, likely contributing to the Arab Spring. With ongoing climate change, temperatures and temperature variability will rise, leading to higher uncertainty in yields for major nutritional crops. Here we investigate which countries are most vulnerable to teleconnected supply-shocks, i.e. where diets strongly rely on the import of wheat, maize, or rice, and where a large share of the population is living in poverty. We find that the Middle East is most sensitive to teleconnected supply shocks in wheat, Central America to supply shocks in maize, and Western Africa to supply shocks in rice. Weighing with poverty levels, Sub-Saharan Africa is most affected. Altogether, a simultaneous 10\% reduction in exports of wheat, rice, and maize would reduce caloric intake of 55 million people living in poverty by about 5\%. Export bans in major producing regions would put up to 200 million people below the poverty line at risk, 90\% of which live in Sub-Saharan Africa. Our results suggest that a region-specific combination of national increases in agricultural productivity and diversification of trade partners and diets can effectively decrease future food security risks.}, language = {en} } @article{WisotzkiBaconBlaizotetal.2016, author = {Wisotzki, Lutz and Bacon, Roland and Blaizot, J. and Brinchmann, Jarle and Herenz, Edmund Christian and Schaye, Joop and Bouche, Nicolas and Cantalupo, Sebastiano and Contini, Thierry and Carollo, C. M. and Caruana, Joseph and Courbot, J. -B. and Emsellem, E. and Kamann, S. and Kerutt, Josephine Victoria and Leclercq, F. and Lilly, S. J. and Patricio, V. and Sandin, C. and Steinmetz, Matthias and Straka, Lorrie A. and Urrutia, Tanya and Verhamme, A. and Weilbacher, Peter Michael and Wendt, Martin}, title = {Extended Lyman alpha haloes around individual high-redshift galaxies revealed by MUSE}, series = {Science}, volume = {587}, journal = {Science}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {1432-0746}, doi = {10.1051/0004-6361/201527384}, pages = {27}, year = {2016}, abstract = {We report the detection of extended Ly alpha emission around individual star-forming galaxies at redshifts z = 3-6 in an ultradeep exposure of the Hubble Deep Field South obtained with MUSE on the ESO-VLT. The data reach a limiting surface brightness (1 sigma) of similar to 1 x 10(-19) erg s(-1) cm(-2) arcsec(-2) in azimuthally averaged radial profiles, an order of magnitude improvement over previous narrowband imaging. Our sample consists of 26 spectroscopically confirmed Ly alpha-emitting, but mostly continuum-faint (m(AB) greater than or similar to 27) galaxies. In most objects the Ly alpha emission is considerably more extended than the UV continuum light. While five of the faintest galaxies in the sample show no significantly detected Ly alpha haloes, the derived upper limits suggest that this is due to insufficient S/N. Ly alpha haloes therefore appear to be ubiquitous even for low-mass (similar to 10(8)-10(9) M-circle dot) star-forming galaxies at z > 3. We decompose the Ly alpha emission of each object into a compact component tracing the UV continuum and an extended halo component, and infer sizes and luminosities of the haloes. The extended Ly alpha emission approximately follows an exponential surface brightness distribution with a scale length of a few kpc. While these haloes are thus quite modest in terms of their absolute sizes, they are larger by a factor of 5-15 than the corresponding rest-frame UV continuum sources as seen by HST. They are also much more extended, by a factor similar to 5, than Ly alpha haloes around low-redshift star-forming galaxies. Between similar to 40\% and greater than or similar to 90\% of the observed Ly alpha flux comes from the extended halo component, with no obvious correlation of this fraction with either the absolute or the relative size of the Ly alpha halo. Our observations provide direct insights into the spatial distribution of at least partly neutral gas residing in the circumgalactic medium of low to intermediate mass galaxies at z > 3.}, language = {en} } @article{PrzybillaFossatiHubrigetal.2016, author = {Przybilla, Norbert and Fossati, Luca and Hubrig, Swetlana and Nieva, M. -F. and Jaervinen, S. P. and Castro, Norberto and Schoeller, M. and Ilyin, Ilya and Butler, Keith and Schneider, F. R. N. and Oskinova, Lida and Morel, T. and Langer, N. and de Koter, A.}, title = {B fields in OB stars (BOB): Detection of a magnetic field in the He-strong star CPD-57 degrees 3509}, series = {Organic letters}, volume = {587}, journal = {Organic letters}, publisher = {EDP Sciences}, address = {Les Ulis}, organization = {BOB Collaboratio}, issn = {1432-0746}, doi = {10.1051/0004-6361/201527646}, pages = {15}, year = {2016}, abstract = {Methods. Spectropolarimetric observations with FORS2 and HARPSpol are analysed using two independent approaches to quantify the magnetic field strength. A high-S/N FLAMES/GIRAFFE spectrum is analysed using a hybrid non-LTE model atmosphere technique. Comparison with stellar evolution models constrains the fundamental parameters of the star. Results. We obtain a firm detection of a surface averaged longitudinal magnetic field with a maximum amplitude of about 1 kG. Assuming a dipolar configuration of the magnetic field, this implies a dipolar field strength larger than 3.3 kG. Moreover, the large amplitude and fast variation (within about 1 day) of the longitudinal magnetic field implies that CPD-57 degrees 3509 is spinning very fast despite its apparently slow projected rotational velocity. The star should be able to support a centrifugal magnetosphere, yet the spectrum shows no sign of magnetically confined material; in particular, emission in H alpha is not observed. Apparently, the wind is either not strong enough for enough material to accumulate in the magnetosphere to become observable or, alternatively, some leakage process leads to loss of material from the magnetosphere. The quantitative spectroscopic analysis of the star yields an effective temperature and a logarithmic surface gravity of 23 750 +/- 250 K and 4.05 +/- 0.10, respectively, and a surface helium fraction of 0.28 +/- 0.02 by number. The surface abundances of C, N, O, Ne, S, and Ar are compatible with the cosmic abundance standard, whereas Mg, Al, Si, and Fe are depleted by about a factor of 2. This abundance pattern can be understood as the consequence of a fractionated stellar wind. CPD-57 degrees 3509 is one of the most evolved He-strong stars known with an independent age constraint due to its cluster membership.}, language = {en} } @misc{BarniskeOskinovaHamann2016, author = {Barniske, Andreas and Oskinova, Lida and Hamann, Wolf-Rainer}, title = {Two extremely luminous WN stars in the Galactic center with circumstellar emission from dust and gas (vol 486, pg 971, 2008)}, series = {Physical chemistry, chemical physics : a journal of European Chemical Societies}, volume = {587}, journal = {Physical chemistry, chemical physics : a journal of European Chemical Societies}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {1432-0746}, doi = {10.1051/0004-6361/200809568e}, pages = {1}, year = {2016}, language = {en} } @article{Kuznetsov2016, author = {Kuznetsov, Sergey P.}, title = {Parametric chaos generator operating on a varactor diode with the instability limitation decay mechanism}, series = {Technical Physics}, volume = {61}, journal = {Technical Physics}, publisher = {Pleiades Publ.}, address = {New York}, issn = {1063-7842}, doi = {10.1134/S1063784216030129}, pages = {436 -- 445}, year = {2016}, abstract = {Equations are derived for a parametric chaos generator containing three oscillatory circuits and a variable-capacitance diode (varactor) and are reduced to equations for slow amplitudes of parametrically interacting modes. With allowance for quadratic nonlinearity, the problem is reduced to a system of three first-order differential equations for Pikovsky-Rabinovich-Trakhtengerts real amplitudes with a Lorenz-type attractor. In a more accurate description of nonlinearity of the varactor, the equations for slow amplitudes are complex-valued, which leads to the loss of robustness of chaotic dynamics, which is typical of the Lorenz attractor. The results of numerical calculations (portraits of attractors and Lyapunov exponents) in models with different approximation levels are compared.}, language = {en} } @article{ZehbeKolloscheLardongetal.2016, author = {Zehbe, Kerstin and Kollosche, Matthias and Lardong, Sebastian and Kelling, Alexandra and Schilde, Uwe and Taubert, Andreas}, title = {Ionogels Based on Poly(methyl methacrylate) and Metal-Containing Ionic Liquids: Correlation between Structure and Mechanical and Electrical Properties}, series = {International journal of molecular sciences}, volume = {17}, journal = {International journal of molecular sciences}, publisher = {MDPI}, address = {Basel}, issn = {1422-0067}, doi = {10.3390/ijms17030391}, pages = {16}, year = {2016}, abstract = {Ionogels (IGs) based on poly(methyl methacrylate) (PMMA) and the metal-containing ionic liquids (ILs) bis-1-butyl-3-methlimidazolium tetrachloridocuprate(II), tetrachloride cobaltate(II), and tetrachlorido manganate(II) have been synthesized and their mechanical and electrical properties have been correlated with their microstructure. Unlike many previous examples, the current IGs show a decreasing stability in stress-strain experiments on increasing IL fractions. The conductivities of the current IGs are lower than those observed in similar examples in the literature. Both effects are caused by a two-phase structure with micrometer-sized IL-rich domains homogeneously dispersed an IL-deficient continuous PMMA phase. This study demonstrates that the IL-polymer miscibility and the morphology of the IGs are key parameters to control the (macroscopic) properties of IGs.}, language = {en} } @article{BolotovOsipovPikovskij2016, author = {Bolotov, M. I. and Osipov, Grigory V. and Pikovskij, Arkadij}, title = {Marginal chimera state at cross-frequency locking of pulse-coupled neural networks}, series = {Physical review : E, Statistical, nonlinear and soft matter physics}, volume = {93}, journal = {Physical review : E, Statistical, nonlinear and soft matter physics}, publisher = {American Physical Society}, address = {College Park}, issn = {2470-0045}, doi = {10.1103/PhysRevE.93.032202}, pages = {6}, year = {2016}, abstract = {We consider two coupled populations of leaky integrate-and-fire neurons. Depending on the coupling strength, mean fields generated by these populations can have incommensurate frequencies or become frequency locked. In the observed 2:1 locking state of the mean fields, individual neurons in one population are asynchronous with the mean fields, while in another population they have the same frequency as the mean field. These synchronous neurons form a chimera state, where part of them build a fully synchronized cluster, while other remain scattered. We explain this chimera as a marginal one, caused by a self-organized neutral dynamics of the effective circle map.}, language = {en} } @misc{Goychuk2016, author = {Goychuk, Igor}, title = {Molecular machines operating on the nanoscale: from classical to quantum}, series = {Beilstein journal of nanotechnology}, volume = {7}, journal = {Beilstein journal of nanotechnology}, publisher = {Beilstein-Institut zur F{\~A}\Prderung der Chemischen Wissenschaften}, address = {Frankfurt, Main}, issn = {2190-4286}, doi = {10.3762/bjnano.7.31}, pages = {328 -- 350}, year = {2016}, abstract = {The main physical features and operating principles of isothermal nanomachines in the microworld, common to both classical and quantum machines, are reviewed. Special attention is paid to the dual, constructive role of dissipation and thermal fluctuations, the fluctuation-dissipation theorem, heat losses and free energy transduction, thermodynamic efficiency, and thermodynamic efficiency at maximum power. Several basic models are considered and discussed to highlight generic physical features. This work examines some common fallacies that continue to plague the literature. In particular, the erroneous beliefs that one should minimize friction and lower the temperature for high performance of Brownian machines, and that the thermodynamic efficiency at maximum power cannot exceed one-half are discussed. The emerging topic of anomalous molecular motors operating subdiffusively but very efficiently in the viscoelastic environment of living cells is also discussed.}, language = {en} } @article{PaulkeStranksKniepertetal.2016, author = {Paulke, Andreas and Stranks, Samuel D. and Kniepert, Juliane and Kurpiers, Jona and Wolff, Christian Michael and Sch{\"o}n, Natalie and Snaith, Henry J. and Brenner, Thomas J. K. and Neher, Dieter}, title = {Charge carrier recombination dynamics in perovskite and polymer solar cells}, series = {Applied physics letters}, volume = {108}, journal = {Applied physics letters}, publisher = {American Institute of Physics}, address = {Melville}, issn = {0003-6951}, doi = {10.1063/1.4944044}, pages = {252 -- 262}, year = {2016}, abstract = {Time-delayed collection field experiments are applied to planar organometal halide perovskite (CH3NH3PbI3) based solar cells to investigate charge carrier recombination in a fully working solar cell at the nanosecond to microsecond time scale. Recombination of mobile (extractable) charges is shown to follow second-order recombination dynamics for all fluences and time scales tested. Most importantly, the bimolecular recombination coefficient is found to be time-dependent, with an initial value of ca. 10(-9) cm(3)/s and a progressive reduction within the first tens of nanoseconds. Comparison to the prototypical organic bulk heterojunction device PTB7:PC71BM yields important differences with regard to the mechanism and time scale of free carrier recombination. (C) 2016 AIP Publishing LLC.}, language = {en} }