@article{SchmidtRiemer2016, author = {Schmidt, Bernd and Riemer, Martin}, title = {Synthesis of Allyl- and Prenylcoumarins via Microwave-Promoted Tandem Claisen Rearrangement/Wittig Olefination}, series = {Synthesis}, volume = {48}, journal = {Synthesis}, publisher = {Thieme}, address = {Stuttgart}, issn = {0039-7881}, doi = {10.1055/s-0035-1560501}, pages = {141 -- 149}, year = {2016}, abstract = {Allyl, dimethylallyl, crotyl, and prenyl ethers of various aromatic ortho-hydroxy carbonyl compounds undergo a tandem sequence of Claisen rearrangement, carbonyl olefination, and cyclization upon microwave irradiation in the presence of a stabilized ylide. The products are multiply substituted 6- or 8-allylated or prenylated coumarins (2H-chromen-2-ones).}, language = {en} } @article{SchmidtHaukeMuehlenberg2014, author = {Schmidt, Bernd and Hauke, Sylvia and Muehlenberg, Nino}, title = {Imino glycals via Ruthenium-catalyzed RCM and isomerization}, series = {Synthesis}, volume = {46}, journal = {Synthesis}, number = {12}, publisher = {Thieme}, address = {Stuttgart}, issn = {0039-7881}, doi = {10.1055/s-0033-1338615}, pages = {1648 -- 1658}, year = {2014}, abstract = {N-Allyl-N-homoallylamines were converted in one step into cyclic enamides via a ruthenium-catalyzed assisted tandem catalytic ring-closing metathesis-isomerization sequence. The sequence relies on the in situ transformation of a metathesis active Ru-carbene into an isomerization active Ru-hydride by addition of hydroxide as a chemical trigger.}, language = {en} } @article{SchmidtRiemerSchilde2014, author = {Schmidt, Bernd and Riemer, Martin and Schilde, Uwe}, title = {Chroman-4-ones via microwave-promoted domino claisen rearrangement-oxa-michael addition: Synthesis of tabchromones A and B}, series = {Synlett : accounts and rapid communications in synthetic organic chemistry}, volume = {25}, journal = {Synlett : accounts and rapid communications in synthetic organic chemistry}, number = {20}, publisher = {Thieme}, address = {Stuttgart}, issn = {0936-5214}, doi = {10.1055/s-0034-1379364}, pages = {2943 -- 2946}, year = {2014}, abstract = {Allyl phenyl ethers with a pendant enone substituent undergo, upon microwave irradiation, a domino sequence of Claisen rearrangement and 6-endo-trig-cyclization to furnish functionalized chroman-4-ones. The natural products tabchromones A and B were synthesized via this method.}, language = {en} }