@article{HahnTraegerHoldt2015, author = {Hahn, Simone and Tr{\"a}ger, Juliane and Holdt, Hans-J{\"u}rgen}, title = {Solid-Phase extraction of Pt(IV) with Dialkyl-(hexane-1,6-diyl) phosphate modified merrifield resins from aqueous chloride media in column operations}, series = {Separation and purification technology}, volume = {50}, journal = {Separation and purification technology}, number = {2}, publisher = {Taylor \& Francis Group}, address = {Philadelphia}, issn = {0149-6395}, doi = {10.1080/01496395.2014.968264}, pages = {191 -- 206}, year = {2015}, abstract = {A series of three dialkyl phosphate resins with a Merrifield resin support was used to extract platinum from acidic media. In column operations total capacities of 85-130 mg/g were gained. The presence of palladium and rhodium results in the order: Pt(IV) > Pd(II) >> Rh(III). From a leach liquor gained from spent automotive catalysts metals forming anionic chloro complexes are co-extracted only to a small extent. However, in order to separate and enrich platinum a selective back-extraction can be done with a sodium thiocyanate solution. A second elution step with acidic thiourea leads to a mixed solution of palladium and rhodium.}, language = {en} }