@article{SchmidtBerger2013, author = {Schmidt, Bernd and Berger, Ren{\´e}}, title = {A deacetylation-diazotation-coupling sequence - palladium-catalyzed CC bond formation with acetanilides as formal leaving groups}, series = {Advanced synthesis \& catalysis}, volume = {355}, journal = {Advanced synthesis \& catalysis}, number = {2-3}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {1615-4150}, doi = {10.1002/adsc.201200929}, pages = {463 -- 476}, year = {2013}, abstract = {Acetanilides can be deacetylated and diazotized in situ, and subsequently used in Pd-catalyzed coupling reactions without isolation of the diazonium intermediate. Heck reactions, Suzuki cross-coupling reactions, and a Pd-catalyzed [2+2+1]cycloaddition have been investigated as terminating CC bond-forming steps of this one-flask sequence. The sequence does not require the exchange of solvents or removal of by-products between the individual steps, but proceeds by addition of reagents and catalysts in due course.}, language = {en} }