@article{StrehmelBerdzinskiStrauchetal.2014,
  author    = {Strehmel, Veronika and Berdzinski, Stefan and Strauch, Peter and Hoffmann-Jacobsen, Kerstin and Strehmel, Bernd},
  title     = {Investigation of molecular solvents and ionic liquids with a dual probe},
  series = {Zeitschrift f{\"u}r physikalische Chemie : international journal of research in physical chemistry and chemical physics},
  volume    = {228},
  journal   = {Zeitschrift f{\"u}r physikalische Chemie : international journal of research in physical chemistry and chemical physics},
  number    = {2-3},
  publisher = {De Gruyter},
  address   = {Berlin},
  issn      = {0942-9352},
  doi       = {10.1515/zpch-2014-0453},
  pages     = {155 -- 169},
  year      = {2014},
  abstract  = {A dual probe was investigated by UV-Vis, fluorescence, and ESR spectroscopy. It comprises the pyrene chromophore and the paramagnetic 2,2,6,6-tetramethylpiperidinyl-N-oxyl radical that are covalently linked together via an ester bridge. The dual probe was used to investigate molecular solvents of different polarity as well as ionic liquids bearing either imidazolium or pyrrolidinium cations and various anions, such as bis(trifluoromethylsulfonyl)imide, tetrafluoroborate, tris(pentafluoroethyl)trifluorophosphate, or dicyanamide. The dual probe does not show solvatochromism that is typical for some pyrenes. Furthermore, the dual probe is considerable less mobile compared to 2,2,6,6-tetramethylpiperidinyl-N-oxyl (TEMPO) without additional substituent as detected by ESR spectroscopy. This is caused by the bulky pyrenyl substituent bound at the dual probe resulting in a reduced mobility of the dual probe.},
  language  = {en}
}
@article{BarthSiegmannBeuermannetal.2012,
  author    = {Barth, Johannes and Siegmann, Rebekka and Beuermann, Sabine and Russell, Gregory T. and Buback, Michael},
  title     = {Investigations into chain-length-dependent termination in bulk radical polymerization of 1H, 1H, 2H, 2H-Tridecafluorooctyl methacrylate},
  series = {Macromolecular chemistry and physics},
  volume    = {213},
  journal   = {Macromolecular chemistry and physics},
  number    = {1},
  publisher = {Wiley-Blackwell},
  address   = {Malden},
  issn      = {1022-1352},
  doi       = {10.1002/macp.201100479},
  pages     = {19 -- 28},
  year      = {2012},
  abstract  = {The SP-PLP-EPR technique is used to carry out a detailed investigation of the radical termination kinetics of 1H, 1H, 2H, 2H-tridecafluorooctyl methacrylate (TDFOMA) in bulk at relatively low conversion. Composite-model behavior for chain-length-dependent termination rate coefficients, kti,i, is observed. It is found that for TDFOMA, ic approximate to 60 independent of temperature, and as approximate to 0.65 and al approximate to 0.2 at 80 degrees C and above. However, at lower temperatures the situation is strikingly different, with the significantly higher average values of as = 0.89 +/- 0.15 and al = 0.32 +/- 0.10 being obtained at 50 degrees C and below. This makes TDFOMA the first monomer to be found that exhibits clearly different exponent values, as and al, at lower and higher temperature, and that has both a high as, like an acrylate, and a high ic, like a methacrylate.},
  language  = {en}
}