@article{FerreroGodardPalmerietal.2018, author = {Ferrero, Silvio and Godard, Gaston and Palmeri, Rosaria and Wunder, Bernd and Cesare, Bernardo}, title = {Partial melting of ultramafic granulites from Dronning Maud Land, Antarctica}, series = {American mineralogist : an international journal of earth and planetary materials}, volume = {103}, journal = {American mineralogist : an international journal of earth and planetary materials}, number = {4}, publisher = {Mineralogical Society of America}, address = {Chantilly}, issn = {0003-004X}, doi = {10.2138/am-2018-6214}, pages = {610 -- 622}, year = {2018}, abstract = {In the Pan-African belt of the Dronning Maud Land, Antarctica, crystallized melt inclusions (nanogranitoids) occur in garnet from ultramafic granulites. The granulites contain the peak assemblage pargasite+garnet+clinopyroxene with rare relict orthopyroxene and biotite, and retrograde symplectites at contacts between garnet and amphibole. Garnet contains two generations of melt inclusions. Type 1 inclusions, interpreted as primary, are isolated, < 10 mu m in size, and generally have negative crystal shapes. They contain kokchetavite, kumdykolite, and phlogopite, with quartz and zoisite as minor phases, and undevitrified glass was identified in one inclusion. Type 2 inclusions are < 30 mu m in size, secondary, and contain amphibole, feldspars, and zoisite. Type 2 inclusions appear to be the crystallization products of a melt that coexisted with an immiscible CO2-rich fluid. The nanogranitoids were re-homogenized after heating in a piston-cylinder in a series of four experiments to investigate their composition. The conditions ranged between 900 and 950 degrees C at 1.5-2.4 GPa. Type 1 inclusions are trachytic and ultrapotassic, whereas type 2 melts are dacitic to rhyolitic. Thermodynamic modeling of the ultramafic composition in the MnNCKFMASHTO system shows that anatexis occurred at the end of the prograde P-T path, between the solidus (at ca. 860 degrees C-1.4 GPa) and the peak conditions (at ca. 960 degrees C-1.7 GPa). The model melt composition is felsic and similar to that of type 1 inclusions, particularly when the melting degree is low (< 1 mol\%), close to the solidus. However the modeling fails to reproduce the highly potassic signature of the melt and its low H2O content. The combination of petrology, melt inclusion study, and thermodynamic modeling supports the interpretation that melt was produced by anatexis of the ultramafic boudins near peak P-T conditions, and that type 1 inclusions contain the anatectic melt that was present during garnet growth. The felsic, ultrapotassic composition of the primary anatectic melts is compatible with low melting degrees in the presence of biotite and amphibole as reactants.}, language = {en} } @article{CarvalhoBartoliFerrietal.2019, author = {Carvalho, Bruna B. and Bartoli, Omar and Ferri, Fabio and Cesare, Bernardo and Ferrero, Silvio and Remusat, Laurent and Capizzi, Luca Samuele and Poli, Stefano}, title = {Anatexis and fluid regime of the deep continental crust: New clues from melt and fluid inclusions in metapelitic migmatites from Ivrea Zone (NW Italy)}, series = {Journal of metamorphic geology}, volume = {37}, journal = {Journal of metamorphic geology}, number = {7}, publisher = {Wiley}, address = {Hoboken}, issn = {0263-4929}, doi = {10.1111/jmg.12463}, pages = {951 -- 975}, year = {2019}, abstract = {We investigate the inclusions hosted in peritectic garnet from metapelitic migmatites of the Kinzigite Formation (Ivrea Zone, NW Italy) to evaluate the starting composition of the anatectic melt and fluid regime during anatexis throughout the upper amphibolite facies, transition, and granulite facies zones. Inclusions have negative crystal shapes, sizes from 2 to 10 mu m and are regularly distributed in the core of the garnet. Microstructural and micro-Raman investigations indicate the presence of two types of inclusions: crystallized silicate melt inclusions (i.e., nanogranitoids, NI), and fluid inclusions (FI). Microstructural evidence suggests that FI and NI coexist in the same cluster and are primary (i.e., were trapped simultaneously during garnet growth). FI have similar compositions in the three zones and comprise variable proportions of CO2, CH4, and N-2, commonly with siderite, pyrophyllite, and kaolinite, suggesting a COHN composition of the trapped fluid. The mineral assemblage in the NI contains K-feldspar, plagioclase, quartz, biotite, muscovite, chlorite, graphite and, rarely, calcite. Polymorphs such as kumdykolite, cristobalite, tridymite, and less commonly kokchetavite, were also found. Rehomogenized NI from the different zones show that all the melts are leucogranitic but have slightly different compositions. In samples from the upper amphibolite facies, melts are less mafic (FeO + MgO = 2.0-3.4 wt\%), contain 860-1700 ppm CO2 and reach the highest H2O contents (6.5-10 wt\%). In the transition zone melts have intermediate H2O (4.8-8.5 wt\%), CO2 (457-1534 ppm) and maficity (FeO + MgO = 2.3-3.9 wt\%). In contrast, melts at granulite facies reach highest CaO, FeO + MgO (3.2-4.7 wt\%), and CO2 (up to 2,400 ppm), with H2O contents comparable (5.4-8.3 wt\%) to the other two zones. Our results represent the first clear evidence for carbonic fluid-present melting in the Ivrea Zone. Anatexis of metapelites occurred through muscovite and biotite breakdown melting in the presence of a COH fluid, in a situation of fluid-melt immiscibility. The fluid is assumed to have been internally derived, produced initially by devolatilization of hydrous silicates in the graphitic protolith, then as a result of oxidation of carbon by consumption of Fe3+-bearing biotite during melting. Variations in the compositions of the melts are interpreted to result from higher T of melting. The H2O contents of the melts throughout the three zones are higher than usually assumed for initial H2O contents of anatectic melts. The CO2 contents are highest at granulite facies, and show that carbon-contents of crustal magmas are not negligible at high T. The activity of H2O of the fluid dissolved in granitic melts decreases with increasing metamorphic grade. Carbonic fluid-present melting of the deep continental crust represents, together with hydrate-breakdown melting reactions, an important process in the origin of crustal anatectic granitoids.}, language = {en} } @article{BartoliAcostaVigilFerreroetal.2016, author = {Bartoli, Omar and Acosta-Vigil, Antonio and Ferrero, Silvio and Cesare, Bernardo}, title = {Granitoid magmas preserved as melt inclusions in high-grade metamorphic rocks}, series = {American mineralogist : an international journal of earth and planetary materials}, volume = {101}, journal = {American mineralogist : an international journal of earth and planetary materials}, publisher = {Mineralogical Society of America}, address = {Chantilly}, issn = {0003-004X}, doi = {10.2138/am-2016-5541CCBYNCND}, pages = {1543 -- 1559}, year = {2016}, abstract = {This review presents a compositional database of primary anatectic granitoid magmas, entirely based on melt inclusions (MI) in high-grade metamorphic rocks. Although MI are well known to igneous petrologists and have been extensively studied in intrusive and extrusive rocks, MI in crustal rocks that have undergone anatexis (migmatites and granulites) are a novel subject of research. They are generally trapped along the heating path by peritectic phases produced by incongruent melting reactions. Primary MI in high-grade metamorphic rocks are small, commonly 5-10 pm in diameter, and their most common mineral host is peritectic garnet. In most cases inclusions have crystallized into a cryptocrystalline aggregate and contain a granitoid phase assemblage (nanogranitoid inclusions) with quartz, K-feldspar, plagioclase, and one or two mica depending on the particular circumstances. After their experimental remelting under high-confining pressure, nanogranitoid MI can be analyzed combining several techniques (EMP, LA-ICP-MS, NanoSIMS, Raman). The trapped melt is granitic and metaluminous to peraluminous, and sometimes granodioritic, tonalitic, and trondhjemitic in composition, in agreement with the different P-T-a(H2o) conditions of melting and protolith composition, and overlap the composition of experimental glasses produced at similar conditions. Being trapped along the up-temperature trajectory as opposed to classic MI in igneous rocks formed during down-temperature magma crystallization fundamental information provided by nanogranitoid MI is the pristine composition of the natural primary anatectic melt for the specific rock under investigation. So far similar to 600 nanogranitoid MI, coming from several occurrences from different geologic and geodynamic settings and ages, have been characterized. Although the compiled MI database should be expanded to other potential sources of crustal magmas, MI data collected so far can be already used as natural "starting-point" compositions to track the processes involved in formation and evolution of granitoid magmas.}, language = {en} } @misc{CesareAcostaVigilBartolietal.2015, author = {Cesare, Bernardo and Acosta-Vigil, Antonio and Bartoli, Omar and Ferrero, Silvio}, title = {What can we learn from melt inclusions in migmatites and granulites?}, series = {Lithos : an international journal of mineralogy, petrology, and geochemistry}, volume = {239}, journal = {Lithos : an international journal of mineralogy, petrology, and geochemistry}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0024-4937}, doi = {10.1016/j.lithos.2015.09.028}, pages = {186 -- 216}, year = {2015}, abstract = {With less than two decades of activity, research on melt inclusions (MI) in crystals from rocks that have undergone crustal anatexis - migmatites and granulites - is a recent addition to crustal petrology and geochemistry. Studies on this subject started with glassy inclusions in anatectic crustal enclaves in lavas, and then progressed to regionally metamorphosed and partially melted crustal rocks, where melt inclusions are normally crystallized into a cryptocrystalline aggregate (nanogranitoid). Since the first paper on melt inclusions in the granulites of the Kerala Khondalite Belt in 2009, reported and studied occurrences are already a few tens. Melt inclusions in migmatites and granulites show many analogies with their more common and long studied counterparts in igneous rocks, but also display very important differences and peculiarities, which are the subject of this review. Microstructurally, melt inclusions in anatectic rocks are small, commonly 10 mu m in diameter, and their main mineral host is peritectic garnet, although several other hosts have been observed. Inclusion contents vary from glass in enclaves that were cooled very rapidly from supersolidus temperatures, to completely crystallized material in slowly cooled regional migmatites. The chemical composition of the inclusions can be analyzed combining several techniques (SEM, EMP, NanoSIMS, LA-ICP-MS), but in the case of crystallized inclusions the experimental remelting under confining pressure in a piston cylinder is a prerequisite. The melt is generally granitic and peraluminous, although granodioritic to trondhjemitic compositions have also been found. Being mostly primary in origin, inclusions attest for the growth of their peritectic host in the presence of melt. As a consequence, the inclusions have the unique ability of preserving information on the composition of primary anatectic crustal melts, before they undergo any of the common following changes in their way to produce crustal magmas. For these peculiar features, melt inclusions in migmatites and granulites, largely overlooked so far, have the potential to become a fundamental tool for the study of crustal melting, crustal differentiation, and even the generation of the continental crust. (C) 2015 The Authors. Published by Elsevier B.V.}, language = {en} } @article{FerreroBragaBerkesietal.2014, author = {Ferrero, Silvio and Braga, R. and Berkesi, M. and Cesare, Bernardo and Ouazaa, N. Laridhi}, title = {Production of metaluminous melt during fluid-present anatexis: an example from the Maghrebian basement, La Galite Archipelago, central Mediterranean}, series = {Journal of metamorphic geology}, volume = {32}, journal = {Journal of metamorphic geology}, number = {2}, publisher = {Wiley-Blackwell}, address = {Hoboken}, issn = {0263-4929}, doi = {10.1111/jmg.12068}, pages = {209 -- 225}, year = {2014}, abstract = {Garnet brought to the surface by late Miocene granitoids at La Galite Archipelago (Central Mediterranean, Tunisia) contains abundant primary melt and fluid inclusions. Microstructural observations and mineral chemistry define the host garnet as a peritectic phase produced by biotite incongruent melting at ~800 degrees C and 0.5GPa, under fluid-present conditions. The trapped melt is leucogranitic with an unexpected metaluminous and almost peralkaline character. Fluid inclusions are one phase at room temperature, and contain a CO2-dominated fluid, with minor H2O, N-2 and CH4. Siderite and an OH-bearing phase were identified by Raman and IR spectroscopy within every analysed inclusion, and are interpreted as products of a post-entrapment carbonation/hydration reaction between the fluid and the host during cooling. The fluid present during anatexis is therefore inferred to have been originally richer in both H2O and CO2. The production of anatectic melt with a metaluminous signature can be explained as the result of partial melting of relatively Al-poor protoliths assisted by CO2-rich fluids.}, language = {en} }