@article{SchmidtRiemer2015,
  author    = {Schmidt, Bernd and Riemer, Martin},
  title     = {Synthesis of Magnaldehydes B and E and Dictyobiphenyl B by Microwave-Promoted Cross-Coupling of Boronophenols},
  series = {European journal of organic chemistry},
  journal   = {European journal of organic chemistry},
  number    = {17},
  publisher = {Wiley-VCH},
  address   = {Weinheim},
  issn      = {1434-193X},
  doi       = {10.1002/ejoc.201500350},
  pages     = {3760 -- 3766},
  year      = {2015},
  abstract  = {Magnaldehydes B and E along with their 4'-methylated derivatives are naturally occurring 2,4'-biphenols that have been isolated from the Magnoliaceae. Herein, these natural products have been synthesized from a common intermediate, which was obtained by a microwave-promoted, hetero-geneously catalyzed, and protecting-group-free Suzuki-Miyaura coupling reaction in an aqueous medium. These reaction conditions were also successfully applied to a one-step synthesis of the slime mold metabolite dictyobiphenyl B.},
  language  = {en}
}
@article{SchmidtWolfBrunner2016,
  author    = {Schmidt, Bernd and Wolf, Felix and Brunner, Heiko},
  title     = {Styrylsulfonates and -Sulfonamides through Pd-Catalysed Matsuda-Heck Reactions of Vinylsulfonic Acid Derivatives and Arenediazonium Salts},
  series = {European journal of organic chemistry},
  journal   = {European journal of organic chemistry},
  publisher = {Wiley-VCH},
  address   = {Weinheim},
  issn      = {1434-193X},
  doi       = {10.1002/ejoc.201600469},
  pages     = {2972 -- 2982},
  year      = {2016},
  abstract  = {Arene diazonium salts undergo Matsuda-Heck reactions with vinylsulfonates and -sulfonamides to give styrylsulfonic acid derivatives in high to excellent yields and with high to excellent selectivities. By quantifying the evolution of nitrogen over time in a gas-meter apparatus, the reactivities of ethylvinylsulfonate and the benchmark olefin methyl acrylate were compared for an electron-rich and an -deficient arene diazonium salt. Tertiary sulfonamides react in Matsuda-Heck couplings with high conversions, but require long reaction times, which prevents the determination of kinetic data through the measurement of nitrogen evolution. Secondary sulfonamides were found to be unreactive. From these results, the following order of reactivity could be deduced: H2C=CHCO2Me > H2C=CHSO2OEt > H2C=CHSO2N(Me)Bn >> H2C=CHSO2NHBn. Through the Matsuda-Heck coupling of 5-indolyldiazonium salt and a tertiary vinylsulfonamide, the synthesis of the C-5-substituted indole part of the antimigraine drug naratriptan was accomplished in high yield.},
  language  = {en}
}
@article{SchmidtGeissler2011,
  author    = {Schmidt, Bernd and Geissler, Diana},
  title     = {Ru- and Pd-Catalysed Synthesis of 2-Arylfurans by One-Flask Heck Arylation/Oxidation},
  series = {European journal of organic chemistry},
  journal   = {European journal of organic chemistry},
  number    = {25},
  publisher = {Wiley-VCH},
  address   = {Weinheim},
  issn      = {1434-193X},
  doi       = {10.1002/ejoc.201100549},
  pages     = {4814 -- 4822},
  year      = {2011},
  abstract  = {2,5-Disubstituted furans were synthesized by one-flask Heck arylation/oxidation sequences. The starting materials are 2-substituted 2,3-dihydrofurans, conveniently available by RCM/isomerization sequences, and arenediazonium salts. These react in ligand-free Heck reactions to afford 2,5-disub-stituted 2,5-dihydrofurans, which are oxidized to the corresponding furans without isolation or intermediate workup. The oxidation is conveniently achieved with chloranil or DDQ, depending on the substrate.},
  language  = {en}
}
@article{SandSchmidt2021,
  author    = {Sand, Patrick and Schmidt, Bernd},
  title     = {Pd-catalyzed oxidative sulfoalkenylation of acetanilides and traceless removal of the catalyst directing group},
  series = {ChemistrySelect},
  volume    = {6},
  journal   = {ChemistrySelect},
  number    = {14},
  publisher = {Wiley-VCH},
  address   = {Weinheim},
  issn      = {2365-6549},
  doi       = {10.1002/slct.202101009},
  pages     = {3563 -- 3567},
  year      = {2021},
  abstract  = {The palladium-catalyzed oxidative Heck-reaction, also referred to as Fujiwara-Moritani-reaction, has been investigated for the synthesis of styrenylsulfonyl compounds. Acetanilides and vinylsulfonyl compounds undergo dehydrogenative coupling reactions in moderate to quantitative yields, using benzoquinone as the oxidant of choice. Potassium peroxodisulfate, which had previously been identified as a superior oxidant for the coupling with acrylates, did not provide any coupling products with these olefins. Traceless removal of the catalyst directing group through a deacetylation-diazotation-coupling (DDC) sequence was demonstrated for 2-arylethene sulfones.},
  language  = {en}
}
@article{SchmidtElizarovRiemeretal.2015,
  author    = {Schmidt, Bernd and Elizarov, Nelli and Riemer, Nastja and H{\"o}lter, Frank},
  title     = {Acetamidoarenediazonium Salts: Opportunities for Multiple Arene Functionalization},
  series = {European journal of organic chemistry},
  journal   = {European journal of organic chemistry},
  number    = {26},
  publisher = {Wiley-VCH},
  address   = {Weinheim},
  issn      = {1434-193X},
  doi       = {10.1002/ejoc.201500795},
  pages     = {5826 -- 5841},
  year      = {2015},
  abstract  = {Unlike their ortho counterparts, meta- and para-acetamidoanilines can be converted into the corresponding acetamidoarenediazonium salts. These offer various opportunities for multiple Pd-catalyzed arene functionalization reactions, such as Matsuda-Heck-, Suzuki-Miyaura- or Fujiwara-Moritani couplings.},
  language  = {en}
}