@article{MishraAnoopSchettleretal.2015,
  author    = {Mishra, Praveen Kumar and Anoop, Ambili and Schettler, Georg and Prasad, Sushma and Jehangir, Arshid and Menzel, Peter and Naumann, Rudolf and Yousuf, A. R. and Basavaiah, Nathani and Deenadayalan, Kannan and Wiesner, Martin G. and Gaye, Birgit},
  title     = {Reconstructed late Quaternary hydrological changes from Lake Tso Moriri, NW Himalaya},
  series = {Quaternary international : the journal of the International Union for Quaternary Research},
  volume    = {371},
  journal   = {Quaternary international : the journal of the International Union for Quaternary Research},
  publisher = {Elsevier},
  address   = {Oxford},
  issn      = {1040-6182},
  doi       = {10.1016/j.quaint.2014.11.040},
  pages     = {76 -- 86},
  year      = {2015},
  abstract  = {We present the results of our investigations on the radiocarbon dated core sediments from the Lake Tso Moriri, NW Himalaya aimed at reconstructing palaeohydrological changes in this climatically sensitive region. Based on the detailed geochemical, mineralogical and sedimentological analysis, we recognise several short-term fluctuations superimposed upon seven major palaeohydrological stages identified in this lake since similar to 26 cal ka. Stage I (>20.2 cal ka): shallow lake characterised by input of coarse-grained detrital sediments; Stage II (20.2-16.4 cal ka): lake deepening and intensification of this trend ca. 18 cal ka; Stage III (16.4-11.2 cal ka): rising lake levels with a short term wet phase (13.1-11.7 cal ka); Stage IV (11.2-8.5 cal ka): early Holocene hydrological maxima and highest lake levels inferred to have resulted from early Holocene Indian monsoon intensification, as records from central Asia indicate weaker westerlies during this interval; Stage V (8.5-5.5 cal ka): mid-Holocene climate deterioration; Stage VI (5.5-2.7 cal ka): progressive lowering of lake level; Stage VII (2.7-0 cal ka): onset of modern conditions. The reconstructed hydrological variability in Lake Tso Moriri is governed by temperature changes (meltwater inflow) and monsoon precipitation (increased runoff). A regional comparison shows considerable differences with other palaeorecords from peninsular India during late Holocene. (C) 2014 Elsevier Ltd and INQUA. All rights reserved.},
  language  = {en}
}
@article{WilkeViethHillebrandNaumannetal.2015,
  author    = {Wilke, Franziska Daniela Helena and Vieth-Hillebrand, Andrea and Naumann, Rudolf and Erzinger, J{\"o}rg and Horsfield, Brian},
  title     = {Induced mobility of inorganic and organic solutes from black shales using water extraction: Implications for shale gas exploitation},
  series = {Applied geochemistry : journal of the International Association of Geochemistry and Cosmochemistry},
  volume    = {63},
  journal   = {Applied geochemistry : journal of the International Association of Geochemistry and Cosmochemistry},
  publisher = {Elsevier},
  address   = {Oxford},
  issn      = {0883-2927},
  doi       = {10.1016/j.apgeochem.2015.07.008},
  pages     = {158 -- 168},
  year      = {2015},
  abstract  = {The study reported here evaluates the degree to which metals, salt anions and organic compounds are released from shales by exposure to water, either in its pure form or mixed with additives commonly employed during shale gas exploitation. The experimental conditions used here were not intended to simulate the exploitation process itself, but nevertheless provided important insights into the effects additives have on solute partition behaviour under oxic to sub-oxic redox conditions. In order to investigate the mobility of major (e.g. Ca, Fe) and trace (e.g. As, Cd, Co, Mo, Pb, U) elements and selected organic compounds, we performed leaching tests with black shale samples from Bornholm, Denmark and Lower Saxony, Germany. Short-term experiments (24 h) were carried out at ambient pressure and temperatures of 100 degrees C using five different lab-made stimulation fluids. Two long-term experiments under elevated pressure and temperature conditions at 100 degrees C/100 bar were performed lasting 6 and 2 months, respectively, using a stimulation fluid containing commercially-available biocide, surfactant, friction reducer and clay stabilizer. Our results show that the amount of dissolved constituents at the end of the experiment is independent of the pH of the stimulation fluid but highly dependent on the composition of the black shale and the buffering capacity of specific components, namely pyrite and carbonates. Shales containing carbonates buffer the solution at pH 7-8. Sulphide minerals (e.g. pyrite) become oxidized and generate sulphuric acid leading to a pH of 2-3. This low pH is responsible for the overall much larger amount of cations dissolved from shales containing pyrite but little to no carbonate. The amount of elements released into the fluid is also dependent on the residence time, since as much as half of the measured 23 elements show highest concentrations within four days. Afterwards, the concentration of most of the elemental species decreased pointing to secondary precipitations. Generally, in our experiments less than 15\% of each analysed element contained in the black shale was mobilised into the fluid. (C) 2015 Elsevier Ltd. All rights reserved.},
  language  = {en}
}