@article{MachatschekSaretiaLendlein2021,
  author    = {Machatschek, Rainhard Gabriel and Saretia, Shivam and Lendlein, Andreas},
  title     = {Assessing the influence of temperature-memory creation on the degradation of copolyesterurethanes in ultrathin films},
  series = {Advanced materials interfaces},
  volume    = {8},
  journal   = {Advanced materials interfaces},
  number    = {6},
  publisher = {Wiley-VCH},
  address   = {Weinheim},
  issn      = {2196-7350},
  doi       = {10.1002/admi.202001926},
  pages     = {8},
  year      = {2021},
  abstract  = {Copolyesterurethanes (PDLCLs) based on oligo(epsilon-caprolactone) (OCL) and oligo(omega-pentadecalactone) (OPDL) segments are biodegradable thermoplastic temperature-memory polymers. The temperature-memory capability in these polymers with crystallizable control units is implemented by a thermomechanical programming process causing alterations in the crystallite arrangement and chain organization. These morphological changes can potentially affect degradation. Initial observations on the macroscopic level inspire the hypothesis that switching of the controlling units causes an accelerated degradation of the material, resulting in programmable degradation by sequential coupling of functions. Hence, detailed degradation studies on Langmuir films of a PDLCL with 40 wt\% OPDL content are carried out under enzymatic catalysis. The temperature-memory creation procedure is mimicked by compression at different temperatures. The evolution of the chain organization and mechanical properties during the degradation process is investigated by means of polarization-modulated infrared reflection absorption spectroscopy, interfacial rheology and to some extend by X-ray reflectivity. The experiments on PDLCL Langmuir films imply that degradability is not enhanced by thermal switching, as the former depends on the temperature during cold programming. Nevertheless, the thin film experiments show that the leaching of OCL segments does not induce further crystallization of the OPDL segments, which is beneficial for a controlled and predictable degradation.},
  language  = {en}
}
@article{SpoonerScheckWenderothCacaceetal.2022,
  author    = {Spooner, Cameron and Scheck-Wenderoth, Magdalena and Cacace, Mauro and Anikiev, Denis},
  title     = {How Alpine seismicity relates to lithospheric strength},
  series = {International journal of earth sciences},
  volume    = {111},
  journal   = {International journal of earth sciences},
  number    = {4},
  publisher = {Springer},
  address   = {Berlin ; Heidelberg},
  issn      = {1437-3254},
  doi       = {10.1007/s00531-022-02174-5},
  pages     = {1201 -- 1221},
  year      = {2022},
  abstract  = {Despite the amount of research focussed on the Alpine orogen, different hypotheses still exist regarding varying spatial seismicity distribution patterns throughout the region. Previous measurement-constrained regional 3D models of lithospheric density distribution and thermal field facilitate the generation of a data-based rheological model of the region. In this study, we compute the long-term lithospheric strength and compare its spatial variation to observed seismicity patterns. We demonstrate how strength maxima within the crust (similar to 1 GPa) and upper mantle (> 2 GPa) occur at temperatures characteristic of the onset of crystal plasticity in those rocks (crust: 200-400 degrees C; mantle: similar to 600 degrees C), with almost all seismicity occurring in these regions. Correlation in the northern and southern forelands between crustal and lithospheric strengths and seismicity show different patterns of event distribution, reflecting their different tectonic settings. Seismicity in the plate boundary setting of the southern foreland corresponds to the integrated lithospheric strength, occurring mainly in the weaker domains surrounding the strong Adriatic plate. In the intraplate setting of the northern foreland, seismicity correlates to modelled crustal strength, and it mainly occurs in the weaker and warmer crust beneath the Upper Rhine Graben. We, therefore, suggest that seismicity in the upper crust is linked to weak crustal domains, which are more prone to localise deformation promoting failure and, depending on the local properties of the fault, earthquakes at relatively lower levels of accumulated stress than their neighbouring stronger counterparts. Upper mantle seismicity at depths greater than modelled brittle conditions, can be either explained by embrittlement of the mantle due to grain-size sensitive deformation within domains of active or recent slab cooling, or by dissipative weakening mechanisms, such as thermal runaway from shear heating and/or dehydration reactions within an overly ductile mantle. Results generated in this study are available for open access use to further discussions on the region.},
  language  = {en}
}
@article{RodriguezPicedaScheckWenderothCacaceetal.2022,
  author    = {Rodriguez Piceda, Constanza and Scheck-Wenderoth, Magdalena and Cacace, Mauro and Bott, Judith and Strecker, Manfred},
  title     = {Long-Term Lithospheric Strength and Upper-Plate Seismicity in the Southern Central Andes, 29 degrees-39 degrees S},
  series = {Geochemistry, geophysics, geosystems},
  volume    = {23},
  journal   = {Geochemistry, geophysics, geosystems},
  number    = {3},
  publisher = {American Geophysical Union},
  address   = {Washington},
  issn      = {1525-2027},
  doi       = {10.1029/2021GC010171},
  pages     = {22},
  year      = {2022},
  abstract  = {We examined the relationship between the mechanical strength of the lithosphere and the distribution of seismicity within the overriding continental plate of the southern Central Andes (SCA, 29 degrees-39 degrees S), where the oceanic Nazca Plate changes its subduction angle between 33 degrees S and 35 degrees S, from subhorizontal in the north (<5 degrees) to steep in the south (similar to 30 degrees). We computed the long-term lithospheric strength based on an existing 3D model describing variations in thickness, density, and temperature of the main geological units forming the lithosphere of the SCA and adjacent forearc and foreland regions. The comparison between our results and seismicity within the overriding plate (upper-plate seismicity) shows that most of the events occur within the modeled brittle domain of the lithosphere. The depth where the deformation mode switches from brittle frictional to thermally activated ductile creep provides a conservative lower bound to the seismogenic zone in the overriding plate of the study area. We also found that the majority of upper-plate earthquakes occurs within the realm of first-order contrasts in integrated strength (12.7-13.3 log Pam in the Andean orogen vs. 13.5-13.9 log Pam in the forearc and the foreland). Specific conditions characterize the mechanically strong northern foreland of the Andes, where seismicity is likely explained by the effects of slab steepening.},
  language  = {en}
}
@article{NishiharaOhuchiKawazoeetal.2014,
  author    = {Nishihara, Yu and Ohuchi, Tomohiro and Kawazoe, Takaaki and Spengler, Dirk and Tasaka, Miki and Kikegawa, Takumi and Suzuki, Akio and Ohtani, Eiji},
  title     = {Rheology of fine-grained forsterite aggregate at deep upper mantle conditions},
  series = {Journal of geophysical research : Solid earth},
  volume    = {119},
  journal   = {Journal of geophysical research : Solid earth},
  number    = {1},
  publisher = {American Geophysical Union},
  address   = {Washington},
  issn      = {2169-9313},
  doi       = {10.1002/2013JB010473},
  pages     = {253 -- 273},
  year      = {2014},
  language  = {en}
}