@article{BehlBalkMansfeldetal.2021,
  author    = {Behl, Marc and Balk, Maria and Mansfeld, Ulrich and Lendlein, Andreas},
  title     = {Phase morphology of multiblock copolymers differing in sequence of blocks},
  series = {Macromolecular materials and engineering},
  volume    = {306},
  journal   = {Macromolecular materials and engineering},
  number    = {3},
  publisher = {Wiley-VCH},
  address   = {Weinheim},
  issn      = {1439-2054},
  doi       = {10.1002/mame.202000672},
  pages     = {9},
  year      = {2021},
  abstract  = {The chemical nature, the number length of integrated building blocks, as well as their sequence structure impact the phase morphology of multiblock copolymers (MBC) consisting of two non-miscible block types. It is hypothesized that a strictly alternating sequence should impact phase segregation. A library of well-defined MBC obtained by coupling oligo(epsilon-caprolactone) (OCL) of different molecular weights (2, 4, and 8 kDa) with oligotetrahydrofuran (OTHF, 2.9 kDa) via Steglich esterification results in strictly alternating (MBCalt) or random (MBCran) MBC. The three different series has a weight average molecular weight (M-w) of 65 000, 165 000, and 168 000 g mol(-1) for MBCalt and 80 500, 100 000, and 147 600 g mol(-1) for MBCran. When the chain length of OCL building blocks is increased, the tendency for phase segregation is facilitated, which is attributed to the decrease in chain mobility within the MBC. Furthermore, it is found that the phase segregation disturbs the crystallization by causing heterogeneities in the semi-crystalline alignment, which is attributed to an increase of the disorder of the OCL semi-crystalline alignment.},
  language  = {en}
}
@article{CabezaMuellerPereyraetal.2018,
  author    = {Cabeza, Sandra and M{\"u}ller, Bernd R. and Pereyra, Ricio and Fernandez, Ricardo and Gonzalez-Doncel, Gaspar and Bruno, Giovanni},
  title     = {Evidence of damage evolution during creep of Al-Mg alloy using synchrotron X-ray refraction},
  series = {Journal of applied crystallography},
  volume    = {51},
  journal   = {Journal of applied crystallography},
  publisher = {International Union of Crystallography},
  address   = {Chester},
  issn      = {1600-5767},
  doi       = {10.1107/S1600576718001449},
  pages     = {420 -- 427},
  year      = {2018},
  abstract  = {In order to provide further evidence of damage mechanisms predicted by the recent solid-state transformation creep (SSTC) model, direct observation of damage accumulation during creep of Al-3.85Mg was made using synchrotron X-ray refraction. X-ray refraction techniques detect the internal specific surface (i.e. surface per unit volume) on a length scale comparable to the specimen size, but with microscopic sensitivity. A significant rise in the internal specific surface with increasing creep time was observed, providing evidence for the creation of a fine grain substructure, as predicted by the SSTC model. This substructure was also observed by scanning electron microscopy.},
  language  = {en}
}