@misc{MondalBhuniaDemeshkoetal.2013, author = {Mondal, Suvendu Sekhar and Bhunia, Asamanjoy and Demeshko, Serhiy and Kelling, Alexandra and Schilde, Uwe and Janiak, Christoph and Holdt, Hans-J{\"u}rgen}, title = {Synthesis of a Co(II)-imidazolate framework from an anionic linker precursor}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-94424}, pages = {39 -- 42}, year = {2013}, abstract = {A Co(II)-imidazolate-4-amide-5-imidate based MOF, IFP-5, is synthesized by using an imidazolate anion-based novel ionic liquid as a linker precursor under solvothermal conditions. IFP-5 shows significant amounts of gas (N2, CO2, CH4 and H2) uptake capacities. IFP-5 exhibits an independent high spin Co(II) centre and antiferromagnetic coupling.}, language = {en} } @misc{ZehbeKolloscheLardongetal.2017, author = {Zehbe, Kerstin and Kollosche, Matthias and Lardong, Sebastian and Kelling, Alexandra and Schilde, Uwe and Taubert, Andreas}, title = {Ionogels based on poly(methyl methacrylate) and metal-containing ionic liquids}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-400607}, pages = {16}, year = {2017}, abstract = {Ionogels (IGs) based on poly(methyl methacrylate) (PMMA) and the metal-containing ionic liquids (ILs) bis-1-butyl-3-methlimidazolium tetrachloridocuprate(II), tetrachloride cobaltate(II), and tetrachlorido manganate(II) have been synthesized and their mechanical and electrical properties have been correlated with their microstructure. Unlike many previous examples, the current IGs show a decreasing stability in stress-strain experiments on increasing IL fractions. The conductivities of the current IGs are lower than those observed in similar examples in the literature. Both effects are caused by a two-phase structure with micrometer-sized IL-rich domains homogeneously dispersed an IL-deficient continuous PMMA phase. This study demonstrates that the IL-polymer miscibility and the morphology of the IGs are key parameters to control the (macroscopic) properties of IGs.}, language = {en} }