@article{MusolffSchmidtSelleetal.2015,
  author    = {Musolff, Andreas and Schmidt, Christian and Selle, Benny and Fleckenstein, Jan H.},
  title     = {Catchment controls on solute export},
  series = {Advances in water resources},
  volume    = {86},
  journal   = {Advances in water resources},
  publisher = {Elsevier},
  address   = {Oxford},
  issn      = {0309-1708},
  doi       = {10.1016/j.advwatres.2015.09.026},
  pages     = {133 -- 146},
  year      = {2015},
  abstract  = {Dynamics of solute export from catchments can be classified in terms of chemostatic and chemodynamic export regimes by an analysis of concentration-discharge relationships. Previous studies hypothesized that distinct export regimes emerge from the presence of solute mass stores within the catchment and their connectivity to the stream. However, so far a direct link of solute export to identifiable catchment characteristics is missing. Here we investigate long-term time series of stream water quality and quantity of nine neighboring catchments in Central Germany ranging from relatively pristine mountain catchments to agriculturally dominated lowland catchments, spanning large gradients in land use, geology, and climatic conditions. Given the strong collinearity of catchment characteristics we used partial least square regression analysis to quantify the predictive power of these characteristics for median concentrations and the metrics of export regime. We can show that median concentrations and metrics of the export regimes of major ions and nutrients can indeed be inferred from catchment characteristics. Strongest predictors for median concentrations were the share of arable land, discharge per area, runoff coefficient and available water capacity in the root zone of the catchments. The available water capacity in the root zone, the share of arable land being artificially drained and the topographic gradient were found to be the most relevant predictors for the metrics of export regime. These catchment characteristics can represent the size of solute mass store such as the fraction of arable land being a measure for the store of nitrate. On the other hand, catchment characteristics can be a measure for the connectivity of these solute stores to the stream such as the fraction of tile drained land in the catchments. This study demonstrates the potential of data-driven, top down analyses using simple metrics to classify and better understand dominant controls of solute export from catchments. (C) 2015 Elsevier Ltd. All rights reserved.},
  language  = {en}
}
@article{MusolffSchmidtRodeetal.2016,
  author    = {Musolff, Andreas and Schmidt, Christian and Rode, Michael and Lischeid, Gunnar and Weise, Stephan M. and Fleckenstein, Jan H.},
  title     = {Groundwater head controls nitrate export from an agricultural lowland catchment},
  series = {Advances in water resources},
  volume    = {96},
  journal   = {Advances in water resources},
  publisher = {Elsevier},
  address   = {Oxford},
  issn      = {0309-1708},
  doi       = {10.1016/j.advwatres.2016.07.003},
  pages     = {95 -- 107},
  year      = {2016},
  abstract  = {Solute concentration variability is of fundamental importance for the chemical and ecological state of streams. It is often closely related to discharge variability and can be characterized in terms of a solute export regime. Previous studies, especially in lowland catchments, report that nitrate is often exported with an accretion pattern of increasing concentrations with increasing discharge. Several modeling approaches exist to predict the export regime of solutes from the spatial relationship of discharge generating zones with solute availability in the catchment. For a small agriculturally managed lowland catchment in central Germany, we show that this relationship is controlled by the depth to groundwater table and its temporal dynamics. Principal component analysis of groundwater level time series from wells distributed throughout the catchment allowed derivation of a representative groundwater level time series that explained most of the discharge variability. Groundwater sampling revealed consistently decreasing nitrate concentrations with an increasing thickness of the unsaturated zone. The relationships of depth to groundwater table to discharge and to nitrate concentration were parameterized and integrated to successfully model catchment discharge and nitrate export on the basis of groundwater level variations alone. This study shows that intensive and uniform agricultural land use likely results in a clear and consistent concentration-depth relationship of nitrate, which can be utilized in simple approaches to predict stream nitrate export dynamics at the catchment scale. (C) 2016 Elsevier Ltd. All rights reserved.},
  language  = {en}
}