@article{HuppertBlasiusOlinkyetal.2005, author = {Huppert, Amit and Blasius, Bernd and Olinky, Ronen and Stone, Lewi}, title = {A Model for Seasonal Phytoplankton Blooms}, year = {2005}, abstract = {We analyse a generic bottom-up nutrient phytoplankton model to help understand the dynamics of seasonally recurring algae blooms. The deterministic model displays a wide spectrum of dynamical behaviours, from simple cyclical blooms which trigger annually, to irregular chaotic blooms in which both the time between outbreaks and their magnitudes are erratic. Unusually, despite the persistent seasonal forcing, it is extremely difficult to generate blooms that are both annually recurring and also chaotic or irregular (i.e. in amplitude) even though this characterizes many real time series. Instead the model has a tendency to `skip' with outbreaks often being suppressed from one year to the next. This behaviour is studied in detail and we develop an analytical expression to describe the model's flow in phase space, yielding insights into the mechanism of the bloom recurrence. We also discuss how modifications to the equations through the inclusion of appropriate functional forms can generate more realistic dynamics.}, language = {en} } @article{LangMellinger2005, author = {Lang, Sidney B. and Mellinger, Axel}, title = {A package of Mathematica programs for training students in the use of LIMM and its analysis}, year = {2005}, abstract = {A package of programs written using the symbolic mathematics program, Mathematicatrademark, has been developed. Its principal usage is in teaching the LIMM method to students and demonstrating data analysis by means of the Polynomial Regularization Method (PRM). A large number of variables can be changed in the program and their effects can be shown graphically. Students at the University of Potsdam and Monash University have used the program successfully}, language = {en} } @article{CironeNegrettiCalarcoetal.2005, author = {Cirone, M. A. and Negretti, Antonio and Calarco, T. and Kr{\"u}ger, P. and Schmiedmayer, J{\"o}rg}, title = {A simple quantum gate with atom chips}, year = {2005}, abstract = {We present a simple scheme for implementing an atomic phase gate using two degrees of freedom for each atom and discuss its realization with cold rubidium atoms on atom chips. We investigate the performance of this collisional phase gate and show that gate operations with high fidelity can be realized in magnetic traps that are currently available on atom chips}, language = {en} } @article{ColinCorbettDurtetal.2005, author = {Colin, S and Corbett, J and Durt, T and Gross, David}, title = {About SICPOVMs and discrete Wigner distributions}, year = {2005}, abstract = {A set of d(2) vectors in a Hilbert space of dimension d is called equiangular if each pair of vectors encloses the same angle. The projection operators onto these vectors define a POVM which is distinguished by its high degree of symmetry. Measures of this kind are called symmetric informationally complete, or SIC POVMs for short, and could be applied for quantum state tomography. Despite its simple geometrical description, the problem of constructing SIC POVMs or even proving their existence seems to be very hard. It is our purpose to introduce two applications of discrete Wigner functions to the analysis of the problem at hand. First, we will present a method for identifying symmetries of SIC POVMs under Clifford operations. This constitutes an alternative approach to a structure described before by Zauner and Appleby. Further, a simple and geometrically motivated construction for an SIC POVM in dimensions two and three is given (which, unfortunately, allows no generalization). Even though no new structures are found, we hope that the re- formulation of the problem may prove useful for future inquiries}, language = {en} } @article{ChristensenSchulteLadbeckSanchezetal.2005, author = {Christensen, Lise Bech and Schulte-Ladbeck, R. E. and Sanchez, Sebastian F. and Becker, Thomas and Jahnke, Knud and Kelz, A. and Roth, Martin M. and Wisotzki, Lutz}, title = {Abundances and kinematics of a candidate sub-damped Lymana galaxy toward PHL 1226}, year = {2005}, abstract = {The spectrum of the quasar PHL 1226 is known to have a strong Mg II and sub-damped Lymanalpha (sub-DLA) absorption line system with N(H I) = (5 +/- 2) x 10(19) cm(-2) at z = 0.1602. Using integral field spectra from the Potsdam Multi Aperture Spectrophotometer (PMAS) we investigate a galaxy at an impact parameter of 6".4 which is most probably responsible for the absorption lines. A fainter galaxy at a similar redshift and a slightly larger distance from the QSO is known to exist, but we assume that the absorption is caused by the more nearby galaxy. From optical Balmer lines we estimate an intrinsic reddening consistent with 0, and a moderate star formation rate of 0.5 M-circle dot yr(-1) is inferred from the Ha luminosity. Using nebular emission line ratios we find a solar oxygen abundance 12 + log (O/H) = 8.7 +/- 0.1 and a solar nitrogen to oxygen abundance ratio log (N/O) = -1.0 +/- 0.2. This abundance is larger than those of all known sub-DLA systems derived from analyses of metal absorption lines in quasar spectra. On the other hand, the properties are compatible with the most metal rich galaxies responsible for strong Mg II absorption systems. These two categories can be reconciled if we assume an abundance gradient similar to local galaxies. Under that assumption we predict abundances 12 + log (O/H) = 7.1 and log (N/O) = -1.9 for the sub-DLA cloud, which is similar to high redshift DLA and sub-DLA systems. We find evidence for a rotational velocity of similar to200 km s(-1) over a length of similar to7 kpc. From the geometry and kinematics of the galaxy we estimate that the absorbing cloud does not belong to a rotating disk, but could originate in a rotating halo}, language = {en} } @article{KappeOstermeyerMenzel2005, author = {Kappe, Philip and Ostermeyer, Martin and Menzel, Ralf}, title = {Active mode locking of a phase-conjugating SBS-laser oscillator}, issn = {0946-2171}, year = {2005}, abstract = {We present a flashlamp-pumped Nd: YAG laser simultaneously emitting pulse structures on microsecond, nanosecond and picosecond time scales. Within a microsecond flashlamp pump pulse a nonlinear reflector based on stimulated Brillouin scattering (SBS) generates several Q-switch pulses. The phase-conjugating effect of the SBS reflector provides a compensation of phase distortions generated inside the laser rod, resulting in transverse fundamental mode operation. Additional acousto-optic loss modulation inside the resonator leads to mode locking. As a result, each Q-switch pulse is subdivided into several picosecond pulses. Energies of up to 2 mJ for the mode-locked pulses with durations between 220 and 800 ps are demonstrated. The wide variability of the laser's temporal output parameters as well as its high beam quality make it a splendid tool for fundamental research in laser materials processing}, language = {en} } @article{KappeOstermeyerMenzel2005, author = {Kappe, Philip and Ostermeyer, Martin and Menzel, Ralf}, title = {Active mode locking of a phase-conjugating SBS-laser oscillator}, issn = {0946-2171}, year = {2005}, language = {en} } @article{AbelAhnertKurthsetal.2005, author = {Abel, Markus and Ahnert, Karsten and Kurths, R. and Mandelj, S.}, title = {Additive nonparametric reconstruction of dynamical systems from time series}, issn = {1063-651X}, year = {2005}, abstract = {We present a nonparametric way to retrieve an additive system of differential equations in embedding space from a single time series. These equations can be treated with dynamical systems theory and allow for long-term predictions. We apply our method to a modified chaotic Chua oscillator in order to demonstrate its potential}, language = {en} } @article{ZollerHainzlHolschneideretal.2005, author = {Zoller, Gert and Hainzl, Sebastian and Holschneider, Matthias and Ben-Zion, Yehuda}, title = {Aftershocks resulting from creeping sections in a heterogeneous fault}, issn = {0094-8276}, year = {2005}, abstract = {We show that realistic aftershock sequences with space-time characteristics compatible with observations are generated by a model consisting of brittle fault segments separated by creeping zones. The dynamics of the brittle regions is governed by static/kinetic friction, 3D elastic stress transfer and small creep deformation. The creeping parts are characterized by high ongoing creep velocities. These regions store stress during earthquake failures and then release it in the interseismic periods. The resulting postseismic deformation leads to aftershock sequences following the modified Omori law. The ratio of creep coefficients in the brittle and creeping sections determines the duration of the postseismic transients and the exponent p of the modified Omori law}, language = {en} } @article{Blasius2005, author = {Blasius, Bernd}, title = {Anomalous phase synchronization in two asymmetrically coupled oscillators in the presence of noise}, year = {2005}, abstract = {We study the route to synchronization in two noisy, nonisochronous oscillators. Anomalous phase synchronization arises if both oscillators differ in their respective value of nonisochronicity and it is characterized by a strong detuning of the oscillator frequencies with the onset of coupling. Here we show that anomalous synchronization, both in limit-cycle or chaotic oscillators, can considerably be enlarged under the influence of asymmetrical coupling and noise. In these systems we describe a number of noise induced effects, such as an inversion of the natural frequency difference and coupling induced desynchronization of two identical oscillators. Our results can be explained in terms of a noisy particle in a tilted washboard potential}, language = {en} } @phdthesis{Kubas2005, author = {Kubas, Daniel}, title = {Applications of Galactic Microlensing}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-5179}, school = {Universit{\"a}t Potsdam}, year = {2005}, abstract = {Subject of this work is the study of applications of the Galactic Microlensing effect, where the light of a distant star (source) is bend according to Einstein's theory of gravity by the gravitational field of intervening compact mass objects (lenses), creating multiple (however not resolvable) images of the source. Relative motion of source, observer and lens leads to a variation of deflection/magnification and thus to a time dependant observable brightness change (lightcurve), a so-called microlensing event, lasting weeks to months. The focus lies on the modeling of binary-lens events, which provide a unique tool to fully characterize the lens-source system and to detect extra-solar planets around the lens star. Making use of the ability of genetic algorithms to efficiently explore large and intricate parameter spaces in the quest for the global best solution, a modeling software (Tango) for binary lenses is developed, presented and applied to data sets from the PLANET microlensing campaign. For the event OGLE-2002-BLG-069 the 2nd ever lens mass measurement has been achieved, leading to a scenario, where a G5III Bulge giant at 9.4 kpc is lensed by an M-dwarf binary with total mass of M=0.51 solar masses at distance 2.9 kpc. Furthermore a method is presented to use the absence of planetary lightcurve signatures to constrain the abundance of extra-solar planets.}, subject = {Planeten}, language = {en} } @phdthesis{Dittrich2005, author = {Dittrich, Bianca}, title = {Aspects of classical and quantum dynamics of canonical general relativity}, address = {Potsdam}, pages = {173 S.}, year = {2005}, language = {en} } @article{BelykhOsipovKucklaenderetal.2005, author = {Belykh, Vladimir N. and Osipov, Grigory V. and Kuckl{\"a}nder, Nina and Blasius, Bernd and Kurths, J{\"u}rgen}, title = {Automatic control of phase synchronization in coupled complex oscillators}, year = {2005}, abstract = {We present an automatic control method for phase locking of regular and chaotic non-identical oscillations, when all subsystems interact via feedback. This method is based on the well known principle of feedback control which takes place in nature and is successfully used in engineering. In contrast to unidirectional and bidirectional coupling, the approach presented here supposes the existence of a special controller, which allows to change the parameters of the controlled systems. First we discuss general principles of automatic phase synchronization (PS) for arbitrary coupled systems with a controller whose input is given by a special quadratic form of coordinates of the individual systems and its output is a result of the application of a linear differential operator. We demonstrate the effectiveness of our approach for controlled PS on several examples: (i) two coupled regular oscillators, (ii) coupled regular and chaotic oscillators, (iii) two coupled chaotic R"ossler oscillators, (iv) two coupled foodweb models, (v) coupled chaotic R"ossler and Lorenz oscillators, (vi) ensembles of locally coupled regular oscillators, (vii) ensembles of locally coupled chaotic oscillators, and (viii) ensembles of globally coupled chaotic oscillators.}, language = {en} } @phdthesis{Streibel2005, author = {Streibel, Martin Albert Gerhard}, title = {Bestimmung von Ozonabbauraten {\"u}ber der Arktis und Antarktis mittels Ozonsonden- und Satellitendaten}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-6570}, school = {Universit{\"a}t Potsdam}, year = {2005}, abstract = {Diese Arbeit besch{\"a}ftigt sich mit der chemischen Ozonzerst{\"o}rung im arktischen und antarktischen stratosph{\"a}rischen Polarwirbel. Diese wird durch Abbauprodukte von anthropogen emittierten Fluorchlorkohlenwasserstoffen und Halonen, Chlor- und Bromradikale, verursacht. Studien in denen der gemessene und modellierte Ozonabbau verglichen wird zeigen, dass die Prozeße bekannt sind, der quantitative Verlauf allerdings nicht vollst{\"a}ndig verstanden ist. Die Prozesse, die zur Ozonzerst{\"o}rung f{\"u}hren sind in beiden Polarwirbeln {\"a}hnlich. Allerdings f{\"a}llt als Konsequenz unterschiedlicher meteorologischer Bedingungen der chemische Ozonabbau im arktischen Polarwirbel weniger drastisch aus als {\"u}ber der Antarktis. Der arktische Polarwirbel ist im Mittel st{\"a}rker dynamisch gest{\"o}rt als der antarktische und weist eine st{\"a}rkere Jahr-zu-Jahr Variabilit{\"a}t auf. Das erschwert die Messung des chemischen Ozonabbaus. Zur Trennung des chemischen Ozonabbaus von der dynamischen Umverteilung des Ozons im arktischen Polarwirbel wurde die Matchmethode entwickelt. Bei dieser Methode werden Luftpakete innerhalb des Polarwirbels mehrfach beprobt, um den chemischen Anteil der Ozon{\"a}nderung zu quantifizieren. Zur Identifizierung von doppelt beprobten Luftpaketen werden Trajektorien aus Windfeldern berechnet. K{\"o}nnen zwei Messungen im Rahmen bestimmter Qualit{\"a}tskriterien durch eine Trajektorie verbunden werden, kann die Ozondifferenz zwischen beiden Sondierungen berechnet und als chemischer Ozonabbau interpretiert werden. Eine solche Koinzidenz wird Match genannt. Der Matchmethode liegt ein statistischer Ansatz zugrunde, so dass eine Vielzahl solcher doppelt beprobter Luftmassen vorliegen muss, um gesicherte Aussagen {\"u}ber die Ozonzerst{\"o}rung gewinnen zu k{\"o}nnen. So erh{\"a}lt man die Ozonzerst{\"o}rung in einem bestimmten Zeitintervall, also Ozonabbauraten. Um die Anzahl an doppelt beprobten Luftpackten zu erh{\"o}hen wurde eine aktive Koordinierung der Ozonsondenaufstiege entwickelt. Im Rahmen dieser Arbeit wurden Matchkampagnen w{\"a}hrend des arktischen Winters 2002/2003 und zum ersten Mal w{\"a}hrend eines antarktischen Winter (2003) durchgef{\"u}hrt. Aus den gewonnenen Daten wurden Ozonabbauraten in beiden Polarwirbeln bestimmt. Diese Abbauraten dienen zum einen der Evaluierung von Modellen, erm{\"o}glichen aber auch den direkten Vergleich von Ozonabbauraten in beiden Polarwirbeln. Der Winter 2002/2003 war zu Beginn durch sehr tiefe Temperaturen in der mittleren und unteren Stratosph{\"a}re charakterisiert, so dass die Matchkampagne Ende November gestartet wurde. Ab Januar war der Polarwirbel zeitweise stark dynamisch gest{\"o}rt. Die Kampagne ging bis Mitte M{\"a}rz. F{\"u}r den H{\"o}henbereich von 400 bis 550 K potentieller Temperatur (15-23 km) konnten Ozonabbauraten und der Verlust in der Gesamts{\"a}ule berechnet werden. Die Ozonabbauraten wurden in verschiedenen Tests auf ihre Stabilit{\"a}t {\"u}berpr{\"u}ft. Der antarktische Polarwirbel war vom Beginn des Winters bis Mitte Oktober 2003 sehr kalt und stellte Ende September kurzzeitig den Rekord f{\"u}r die gr{\"o}ßte bisher aufgetretene Ozonloch-Fl{\"a}che ein. Es konnten f{\"u}r den Kampagnenzeitraum, Anfang Juni bis Anfang Oktober, Ozonabbauraten im H{\"o}henbereich von 400 bis 550 K potentieller Temperatur ermittelt werden. Der zeitliche Verlauf des Ozonabbaus war dabei auf fast allen H{\"o}henniveaus identisch. Die Zunahme des Sonnenlichtes im Polarwirbel mit der Zeit f{\"u}hrt zu einem starken Anwachsen der Ozonabbauraten. Ab Mitte September gingen die Ozonabbauraten auf Null zur{\"u}ck, da bis zu diesem Zeitpunkt das gesamte Ozon zwischen ca. 14 und 21 km zerst{\"o}rt wurde. Im letzten Teil der Arbeit wird ein neuer Algorithmus auf Basis der multivariaten Regression vorgestellt, mit dem Ozonabbauraten aus Ozonprofilen verschiedener Sensoren gleichzeitig berechnet werden k{\"o}nnen. Dabei k{\"o}nnen neben der Ozonabbaurate die systematischen Fehler zwischen den einzelnen Sensoren bestimmt werden. Dies wurde exemplarisch am antarktischen Winter 2003 f{\"u}r das 475 K potentielle Temperatur Niveau gezeigt. Neben den Ozonprofilen der Sonden wurden Daten von zwei Satellitenexperimenten verwendet. Die mit der multivariaten Matchtechnik berechneten Ozonabbauraten stimmen gut mit den Ozonabbauraten der Einzelsensor-Matchans{\"a}tze {\"u}berein.}, subject = {Ozon}, language = {de} } @article{PoschelBrilliantovZaikin2005, author = {Poschel, T. and Brilliantov, Nikolai V. and Zaikin, Alexei}, title = {Bistability and noise-enhanced velocity of rolling motion}, year = {2005}, abstract = {We investigate the motion of a hard cylinder rolling down a soft, inclined plane. The cylinder is subjected to a viscous drag force and stochastic fluctuations due to the surrounding rnedium. In a wide range of parameters we observe bistability of the rolling velocity. In dependence on the parameters, increasing noise level may lead to increasing or decreasing average velocity of the cylinder. The approximative analytical theory agrees with numerical results}, language = {en} } @article{MakHayerPascuetal.2005, author = {Mak, Chris S. K. and Hayer, Anna and Pascu, S. I. and Watkins, Scott E. and Holmes, Andrew B. and K{\"o}hler, Anna and Friend, Richard H.}, title = {Blue-to-green electrophosphorescence of iridium-based cyclometallated materials.}, issn = {0022-4936}, doi = {10.1039/b508695gb70}, year = {2005}, language = {en} } @article{HeringerWaltherMoreiraWesseletal.2005, author = {Heringer-Walther, Silvia and Moreira, M. C. V. and Wessel, Niels and Saliba, J. L. and Silvia-Barra, J. and Pena, J. L. B. and Becker, S. and Siems, W. E. and Schultheiss, H. P. and Walther, T.}, title = {Brain natriuretic peptide predicts survival in Chagas' disease more effectively than atrial natriuretic peptide}, issn = {1355-6037}, year = {2005}, language = {en} } @article{PenacoradaSoutodeSajaetal.2005, author = {Penacorada, Florencio and Souto, Jorge and de Saja, J. A. and Brehmer, Ludwig}, title = {Brewster angle microscopy and surface potential measurements of Langmuir-Blodgett films of zinc tri(tert-butyl)- 4-sulphophthalocyanine}, issn = {0169-4332}, year = {2005}, abstract = {The formation of a Langmuir monolayer of an amphiphilic derivative of zinc phthalocyanine (Na[(ZnPcSO3)-S-t]) has been studied by means of surface potential technique and Brewster angle microscopy. The experiments were undertaken in order to understand the behaviour of this monolayer with a well-defined surface pressure isotherm. The floating film is described as a truly monomolecular layer formed by very rigid islands in which the phthalocyanine units tend to take on a preferential orientation with their planes perpendicular to the air-water interface, for high values of the surface pressure. (c) 2004 Elsevier B.V. All rights reserved}, language = {en} } @article{VianaGrebogiPintoetal.2005, author = {Viana, R. L. and Grebogi, Celso and Pinto, S. E. D. and Lopes, S. R. and Batista, A. M. and Kurths, J{\"u}rgen}, title = {Bubbling bifurcation : loss of synchronization and shadowing breakdown in complex systems}, year = {2005}, abstract = {Complex dynamical systems with many degrees of freedom may exhibit a wealth of collective phenomena related to high-dimensional chaos. This paper focuses on a lattice of coupled logistic maps to investigate the relationship between the loss of chaos synchronization and the onset of shadowing breakdown via unstable dimension variability in complex systems. In the neighborhood of the critical transition to strongly non-hyperbolic behavior, the system undergoes on-off intermittency with respect to the synchronization manifold. This has been confirmed by numerical diagnostics of synchronization and non-hyperbolic behavior, the latter using the statistical properties of finite-time Lyapunov exponents. (c) 2005 Elsevier B.V. All rights reserved}, language = {en} } @article{LyubimovStraubeLyubimova2005, author = {Lyubimov, Dmitry V. and Straube, Arthur V. and Lyubimova, T. P.}, title = {Capture of particles of dust by convective flow}, issn = {1070-6631}, year = {2005}, abstract = {Interaction of particles of dust with vortex convective flows is under theoretical consideration. It is assumed that the volume fraction of solid phase is small, variations of density due to nonuniform distribution of particles and those caused by temperature nonisothermality of medium are comparable. Equations for the description of thermal buoyancy convection of a dusty medium are developed in the framework of the generalized Boussinesq approximation taking into account finite velocity of particle sedimentation. The capture of a cloud of dust particles by a vortex convective flow is considered, general criterion for the formation of such a cloud is obtained. The peculiarities of a steady state in the form of a dust cloud and backward influence of the solid phase on the carrier flow are studied in detail for a vertical layer heated from the sidewalls. It is shown that in the case, when this backward influence is essential, a hysteresis behavior is possible. The stability analysis of the steady state is performed. It turns out that there is a narrow range of governing parameters, in which such a steady state is stable. (c) 2005 American Institute of Physics}, language = {en} } @article{TalalaevTommElsaesseretal.2005, author = {Talalaev, V and Tomm, JW and Elsaesser, T and Zeimer, Ute and Fricke, J and Knauer, A and Kissel, H and Weyers, Markus and Tarasov, GG and Grenzer, J{\"o}rg and Pietsch, Ullrich}, title = {Carrier dynamics in laterally strain-modulated InGaAs quantum wells}, year = {2005}, abstract = {We investigate the transient recombination and transfer properties of nonequilibrium carriers in an In0.16Ga0.84As/GaAs quantum well (QW) with an additional lateral confinement implemented by a patterned stressor layer. The structure thus contains QW- and quantum-wire-like areas. At low excitation densities, photoluminescence (PL) transients from both areas are well described by a rate equation model for a three-level system with a saturable interlevel carrier transfer representing the lateral drift of carriers from the QW regions into the wires. Small-signal carrier lifetimes for QW, wires, and transfer time from QW to wire are 180, 190, and 28 ps, respectively. For high excitation densities the time constants of the observed transients increase, in agreement with the model. In addition, QW and wire PL lines merge indicating a smoothening of the potential difference, i.e., the effective carrier confinement caused by the stressor structure becomes weaker with increasing excitation. (c) 2005 American Institute of Physics}, language = {en} } @article{HenkelJoulain2005, author = {Henkel, Carsten and Joulain, Karl}, title = {Casimir force between designed materials : what is possible and what not}, issn = {0295-5075}, year = {2005}, abstract = {We establish strict upper limits for the Casimir interaction between multilayered structures of arbitrary dielectric or diamagnetic materials. We discuss the appearance of different power laws due to frequency-dependent material constants. Simple analytical expressions are in good agreement with numerical calculations based on Lifshitz theory. We discuss the improvements required for current ( meta) materials to achieve a repulsive Casimir force}, language = {en} } @article{BaptistaKurths2005, author = {Baptista, Murilo da Silva and Kurths, J{\"u}rgen}, title = {Chaotic channel}, issn = {1539-3755}, year = {2005}, abstract = {This work combines the theory of chaotic synchronization with the theory of information in order to introduce the chaotic channel, an active medium formed by connected chaotic systems. This subset of a large chaotic net represents the path along which information flows. We show that the possible amount of information exchange between the transmitter, where information enters the net, and the receiver, the destination of the information, is proportional to the level of synchronization between these two special subsystems}, language = {en} } @phdthesis{Boroudjerdi2005, author = {Boroudjerdi, Hoda}, title = {Charged polymer-macroion complexes}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-6282}, school = {Universit{\"a}t Potsdam}, year = {2005}, abstract = {This work explores the equilibrium structure and thermodynamic phase behavior of complexes formed by charged polymer chains (polyelectrolytes) and oppositely charged spheres (macroions). Polyelectrolyte-macroion complexes form a common pattern in soft-matter physics, chemistry and biology, and enter in numerous technological applications as well. From a fundamental point of view, such complexes are interesting in that they combine the subtle interplay between electrostatic interactions and elastic as well as entropic effects due to conformational changes of the polymer chain, giving rise to a wide range of structural properties. This forms the central theme of theoretical studies presented in this thesis, which concentrate on a number of different problems involving strongly coupled complexes, i.e. complexes that are characterized by a large adsorption energy and small chain fluctuations. In the first part, a global analysis of the structural phase behavior of a single polyelectrolyte-macroion complex is presented based on a dimensionless representation, yielding results that cover a wide range of realistic system parameters. Emphasize is made on the interplay between the effects due to the polyelectrolytes chain length, salt concentration and the macroion charge as well as the mechanical chain persistence length. The results are summarized into generic phase diagrams characterizing the wrapping-dewrapping behavior of a polyelectrolyte chain on a macroion. A fully wrapped chain state is typically obtained at intermediate salt concentrations and chain lengths, where the amount of polyelectrolyte charge adsorbed on the macroion typically exceeds the bare macroion charge leading thus to a highly overcharged complex. Perhaps the most striking features occur when a single long polyelectrolyte chain is complexed with many oppositely charged spheres. In biology, such complexes form between DNA (which carries the cell's genetic information) and small oppositely charged histone proteins serving as an efficient mechanism for packing a huge amount of DNA into the micron-size cell nucleus in eucaryotic cells. The resultant complex fiber, known as the chromatin fiber, appears with a diameter of 30~nm under physiological conditions. Recent experiments indicate a zig-zag spatial arrangement for individual DNA-histone complexes (nucleosome core particles) along the chromatin fiber. A numerical method is introduced in this thesis based on a simple generic chain-sphere cell model that enables one to investigate the mechanism of fiber formation on a systematic level by incorporating electrostatic and elastic contributions. As will be shown, stable complex fibers exhibit an impressive variety of structures including zig-zag, solenoidal and beads-on-a-string patterns, depending on system parameters such as salt concentration, sphere charge as well as the chain contour length (per sphere). The present results predict fibers of compact zig-zag structure within the physiologically relevant regime with a diameter of about 30~nm, when DNA-histone parameters are adopted. In the next part, a numerical method is developed in order to investigate the role of thermal fluctuations on the structure and thermodynamic phase behavior of polyelectrolyte-macroion complexes. This is based on a saddle-point approximation, which allows to describe the experimentally observed reaction (or complexation) equilibrium in a dilute solution of polyelectrolytes and macroions on a systematic level. This equilibrium is determined by the entropy loss a single polyelectrolyte chain suffers as it binds to an oppositely charged macroion. This latter quantity can be calculated from the spectrum of polyelectrolyte fluctuations around a macroion, which is determined by means of a normal-mode analysis. Thereby, a stability phase diagram is obtained, which exhibits qualitative agreement with experimental findings. At elevated complex concentrations, one needs to account for the inter-complex interactions as well. It will be shown that at small separations, complexes undergo structural changes in such a way that positive patches from one complex match up with negative patches on the other. Furthermore, one of the polyelectrolyte chains may bridge between the two complexes. These mechanisms lead to a strong inter-complex attraction. As a result, the second virial coefficient associated with the inter-complex interaction becomes negative at intermediate salt concentrations in qualitative agreement with recent experiments on solutions of nucleosome core particles.}, subject = {Biopolymere}, language = {en} } @article{WolfEisert2005, author = {Wolf, M. M. and Eisert, Jens}, title = {Classical information capacity of a class of quantum channels}, issn = {1367-2630}, year = {2005}, abstract = {We consider the additivity of the minimal output entropy and the classical information capacity of a class of quantum channels. For this class of channels, the norm of the output is maximized for the output being a normalized projection. We prove the additivity of the minimal output Renyi entropies with entropic parameters alpha is an element of [ 0, 2], generalizing an argument by Alicki and Fannes, and present a number of examples in detail. In order to relate these results to the classical information capacity, we introduce a weak form of covariance of a channel. We then identify various instances of weakly covariant channels for which we can infer the additivity of the classical information capacity. Both additivity results apply to the case of an arbitrary number of different channels. Finally, we relate the obtained results to instances of bi-partite quantum states for which the entanglement cost can be calculated}, language = {en} } @article{PietschPanznerLeitenbergeretal.2005, author = {Pietsch, Ullrich and Panzner, Tobias and Leitenberger, Wolfram and Vartanyants, Ivan A.}, title = {Coherence experiments at the EDR-beamline of BESSY II}, year = {2005}, language = {en} } @article{PietschPanznerLeitenbergeretal.2005, author = {Pietsch, Ullrich and Panzner, Tobias and Leitenberger, Wolfram and Vartanyants, Ivan A.}, title = {Coherence experiments using white synchrotron radiation}, year = {2005}, abstract = {Experiments at the bending magnet beamline at BESSY II (EDR beamline) profit from the excellent coherence properties of third generation synchrotron sources. Considering the exponentially decaying incident spectrum, and because no optical elements are installed except slits and vacuum windows, coherence experiments can be performed between 5 keV < E < 15 keV. First, the energy dependence of spatial coherence properties were determined measuring diffraction at single and double pinholes. Next, the coherent white radiation was used to probe the morphology of thin films in reflection geometry. The recorded intensity maps (reflectivity versus sample position) provide speckle patterns which reveal the locally varying sample morphology. Setting the incident angle, alpha(i), smaller or larger than the critical angle of total external reflection, alpha(c), one should be able to separate the surface height profile from the subsurface density modulation of a sample. The validity of this approach is verified at the example of reciprocal space maps taken from a polymer surface where we could reconstruct the lateral height profile from speckle data. (C) 2004 Elsevier B.V. All rights reserved}, language = {en} } @article{HoffmannBostroemFelbinger2005, author = {Hoffmann, H. and Bostr{\"o}m, Kim and Felbinger, Timo}, title = {Comment on Secure direct communication with a quantum one-time pad}, year = {2005}, abstract = {In the paper [Phys. Rev. A 69, 052319 (2004)], a quantum direct communication protocol is proposed which is claimed to be unconditionally secure even for the case of a noisy channel. We show that this is not the case by giving an undetectable attack scheme}, language = {en} } @article{FussmannBlasius2005, author = {Fussmann, Gregor F. and Blasius, Bernd}, title = {Community response to enrichment is highly sensitive to model structure}, year = {2005}, abstract = {Biologists use mathematical functions to model, understand, and predict nature. For most biological processes, however, the exact analytical form is not known. This is also true for one of the most basic life processes, the uptake of food or resources. We show that the use of a number of nearly indistinguishable functions, which can serve as phenomenological descriptors of resource uptake, may lead to alarmingly different dynamical behaviour in a simple community model. More specifically, we demonstrate that the degree of resource enrichment needed to destabilize the community dynamics depends critically on the mathematical nature of the uptake function.}, language = {en} } @article{ZenSaphiannikovaNeheretal.2005, author = {Zen, Achmad and Saphiannikova, Marina and Neher, Dieter and Asawapirom, Udom and Scherf, Ullrich}, title = {Comparative study of the field-effect mobility of a copolymer and a binary blend based on poly(3- alkylthiophene)s}, issn = {0897-4756}, year = {2005}, abstract = {The performance of highly soluble regioregular poly[ (3-hexylthiophene)-co-(3-octylthiophetie)] (P3HTOT) as a semiconducting material in organic field-effect transistors (OFETs) is presented in comparison to that of the corresponding homopolymers. Transistors made from as-prepared layers of P3HTOT exhibit a mobility of ca. 7 x 10(-3) cm(2) V-1 s(-1), which is comparable to the performance of transistors made from as-prepared poly(3-hexylthiophene) (P3HT) and almost 6 times larger than the mobility of transistors prepared with poly(3-octylthiophene) (P3OT). On the other hand, the solubility parameter delta(p) of P3HTOT is close to that of the highly soluble P3OT. Moreover, compared to a physical blend of poly(3-hexylthiophene) and poly(3-octylthiophene), the mobility of P3HTOT devices is almost twice as large and the performance does not degrade upon annealing at elevated temperatures. Therefore, the copolymer approach outlined here may be one promising step toward an optimum balance between a Sufficient processability of the polymers from common organic solvents, a high solid state order, and applicable OFET performances}, language = {en} } @article{SavaBrumaSchulzetal.2005, author = {Sava, Ion and Bruma, Maria and Schulz, Burkhard and K{\"o}pnick, Thomas}, title = {Comparison of properties of silicon-containing poly(amide-imide)s}, issn = {0954-0083}, year = {2005}, abstract = {New silicon-containing poly(amide-imide)s have been synthesized by direct polycondensation of various aromatic diamines with a dicarboxylic acid containing the dimethylsilylene group and preformed in-tide cycles. These polymers are easily soluble in polar amidic solvents such as N-methylpyrrolidinone (NMP) or dimethylformamide (DMF) and can be cast into thin flexible films or coatings from such solutions. They show high thermal stability, with initial decomposition temperature being above 400 C and glass transition temperature in the range of 220-270 degrees C. Very thin polymer films deposited by spincoating technique onto silicon wafers showed a smooth, pinhole-free surface in atomic force microscopy investigations}, language = {en} } @article{ZillmerPikovskij2005, author = {Zillmer, R{\"u}diger and Pikovskij, Arkadij}, title = {Continuous approach for the random-field Ising chain}, year = {2005}, abstract = {We study the random-field Ising chain in the limit of strong exchange coupling. In order to calculate the free energy we apply a continuous Langevin-type approach. This continuous model can be solved exactly, whereupon we are able to locate the crossover between an exponential and a power-law decay of the free energy with increasing coupling strength. In terms of magnetization, this crossover restricts the validity of the linear scaling. The known analytical results for the free energy are recovered in the corresponding limits. The outcomes of numerical computations for the free energy are presented, which confirm the results of the continuous approach. We also discuss the validity of the replica method which we then utilize to investigate the sample-to-sample fluctuations of the finite size free energy}, language = {en} } @article{NestKlamroth2005, author = {Nest, Mathias and Klamroth, Tillmann}, title = {Correlated many-electron dynamics : application to inelastic electron scattering at a metal film}, year = {2005}, abstract = {The multiconfiguration time-dependent Hartree-Fock and the time-dependent configuration interaction singles method are applied to the correlated many-electron dynamics of a one-dimensional jellium model system. We study the scattering of an initially free electron at a model film in the framework of both approaches. In particular, both methods are compared with regard to how they describe the underlying physical processes, namely inelastic electron scattering, inverse photoemission, and electron impact ionization}, language = {en} } @article{CarvajalWesselVallverduetal.2005, author = {Carvajal, R. and Wessel, Niels and Vallverdu, M. and Caminal, P. and Voss, Andreas}, title = {Correlation dimension analysis of heart rate variability in patients with dilated cardiomyopathy}, issn = {0169-2607}, year = {2005}, abstract = {A correlation dimension analysis of heart rate variability (HRV) was applied to a group of 55 patients with dilated cardiomyopathy (DCM) and 55 healthy subjects as controls. The 24-h RR time series for each subject was divided into segments of 10,000 beats to determine the correlation dimension (CD) per segment. A study of the influence of the time delay (tag) in the calculation of CD was performed. Good discrimination between both groups (p < 0.005) was obtained with tag values of 5 or greater. CD values of DCM patients (8.4 ± 1.9) were significantly lower than CD values for controls (9.5 ± 1.9). An analysis of CD values of HRV showed that for healthy people, CD night values (10.6 ± 1.8) were significant greater than CD day values (9.2 ± 1.9), revealing a circadian rhythm. In DCM patients, this circadian rhythm was lost and there were no differences between CD values in day (8.8 ± 2.4) and night (8.9 ± 2. 1). © 2005 Elsevier Ireland Ltd. All rights reserved}, language = {en} } @phdthesis{Zoeller2005, author = {Z{\"o}ller, Gert}, title = {Critical states of seismicity : modeling and data analysis}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-7427}, school = {Universit{\"a}t Potsdam}, year = {2005}, abstract = {The occurrence of earthquakes is characterized by a high degree of spatiotemporal complexity. Although numerous patterns, e.g. fore- and aftershock sequences, are well-known, the underlying mechanisms are not observable and thus not understood. Because the recurrence times of large earthquakes are usually decades or centuries, the number of such events in corresponding data sets is too small to draw conclusions with reasonable statistical significance. Therefore, the present study combines both, numerical modeling and analysis of real data in order to unveil the relationships between physical mechanisms and observational quantities. The key hypothesis is the validity of the so-called "critical point concept" for earthquakes, which assumes large earthquakes to occur as phase transitions in a spatially extended many-particle system, similar to percolation models. New concepts are developed to detect critical states in simulated and in natural data sets. The results indicate that important features of seismicity like the frequency-size distribution and the temporal clustering of earthquakes depend on frictional and structural fault parameters. In particular, the degree of quenched spatial disorder (the "roughness") of a fault zone determines whether large earthquakes occur quasiperiodically or more clustered. This illustrates the power of numerical models in order to identify regions in parameter space, which are relevant for natural seismicity. The critical point concept is verified for both, synthetic and natural seismicity, in terms of a critical state which precedes a large earthquake: a gradual roughening of the (unobservable) stress field leads to a scale-free (observable) frequency-size distribution. Furthermore, the growth of the spatial correlation length and the acceleration of the seismic energy release prior to large events is found. The predictive power of these precursors is, however, limited. Instead of forecasting time, location, and magnitude of individual events, a contribution to a broad multiparameter approach is encouraging.}, subject = {Seismizit{\"a}t}, language = {en} } @article{BreuStosselSchraderetal.2005, author = {Breu, J. and Stossel, P. and Schrader, Sigurd and Starukhin, A. and Finkenzeller, W. J. and Yersin, H.}, title = {Crystal structure of fac-Ir(ppy)(3) and emission properties under ambient conditions and at high pressure}, issn = {0897-4756}, year = {2005}, abstract = {Solution and refinement of the crystal structure of fac-Ir(ppy)(3) is severely hampered by systematic twinning and pseudo-symmetry.fac-Ir(ppy)(3) Crystallizes in the centrosymmetric space group P (3) over bar as has been deduced from single-crystal structure refinement and investigations of the second harmonic generation (SHG) of fac-Ir(ppy)(3) powder as compared to two standard materials. The topology of the molecular packing of fac-Ir(ppy)(3) is identical to the packing observed for [Ru(bpy)(3)](0), however, the site symmetry of all Ir(ppy)(3) molecules is necessarily lowered from D-3 to C-3. Packing motifs with intermolecular "pi-pi interactions" of T-shaped and "shifted pi stack" geometry are realized. The systematic twinning leads to the occurrence of crystalline domains with rigorously alternating chirality within the bulk of the domains but with homochiral fac-Ir(ppy)(3) contacts at the domain interfaces. These differences in packing motifs are displayed in the emission spectra and in the high-pressure-induced shifts of the emission. The emission maximum of the bulk material at 18 350 cm(-1) (545 nm) and of the domain interfaces at 19 700 cm-1 (507 nm) experience for p < 25 kbar and T = 295 K red shifts of Delta nu/Delta p = -(12 +/- 2) cm(-1)/kbar, and -(22 +/- 4) cm(- 1)/kbar, respectively}, language = {en} } @phdthesis{Wessel2005, author = {Wessel, Niels}, title = {Data analysis and modeling of the cardiovascular system}, address = {Potsdam}, pages = {Getr. Z{\"a}hlung : graph. Darst.}, year = {2005}, language = {en} } @article{BragardMontbrioMendozaetal.2005, author = {Bragard, Jean and Montbrio, Ernest and Mendoza, C. and Boccaletti, Stefano and Blasius, Bernd}, title = {Defect-enhanced anomaly in frequency synchronization of asymmetrically coupled spatially extended systems}, year = {2005}, abstract = {We analytically establish and numerically show that anomalous frequency synchronization occurs in a pair of asymmetrically coupled chaotic space extended oscillators. The transition to anomalous behaviors is crucially dependent on asymmetries in the coupling configuration, while the presence of phase defects has the effect of enhancing the anomaly in frequency synchronization with respect to the case of merely time chaotic oscillators.}, language = {en} } @phdthesis{Kubowicz2005, author = {Kubowicz, Stephan}, title = {Design and characterization of multicompartment micelles in aqueous solution}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-5752}, school = {Universit{\"a}t Potsdam}, year = {2005}, abstract = {Self-assembly of polymeric building blocks is a powerful tool for the design of novel materials and structures that combine different properties and may respond to external stimuli. In the past decades, most studies were focused on the self-assembly of amphiphilic diblock copolymers in solution. The dissolution of these block copolymers in a solvent selective for one block results mostly in the formation of micelles. The micellar structure of diblock copolymers is inherently limited to a homogeneous core surrounded by a corona, which keeps the micelle in solution. Thus, for drug-delivery applications, such structures only offer a single domain (the hydrophobic inner core) for drug entrapment. Whereas multicompartment micelles composed of a water-soluble shell and a segregated hydrophobic core are novel, interesting morphologies for applications in a variety of fields including medicine, pharmacy and biotechnology. The separated incompatible compartments of the hydrophobic core could enable the selective entrapment and release of various hydrophobic drugs while the hydrophilic shell would permit the stabilization of these nanostructures in physiological media. However, so far, the preparation and control of stable multicompartment micellar systems are in the first stages and the number of morphological studies concerning such micelles is rather low. Thus considerably little is known about their exact inner structures. In the present study, we concentrate on four different approaches for the preparation of multicompartment micelles by self-assembly in aqueous media. A similarity of all approaches was that hydrocarbon and fluorocarbon blocks were selected for all employed copolymers since such segments tend to be strongly incompatible, and thus favor the segregation into distinct domains. Our studies have shown that the self-assembly of the utilized copolymers in aqueous solution leads in three cases to the formation of multicompartment micelles. As expected the shape and size of the micelles depend on the molecular architecture and to some extent also on the way of preparation. These novel structured colloids may serve as models as well as mimics for biological structures such as globular proteins, and may open interesting opportunities for nanotechnology applications.}, subject = {Amphiphile Verbindungen}, language = {en} } @article{HainzlOgata2005, author = {Hainzl, Sebastian and Ogata, Y.}, title = {Detecting fluid signals in seismicity data through statistical earthquake modeling}, issn = {0148-0227}, year = {2005}, abstract = {[1] According to the well-known Coulomb failure criterion the variation of either stress or pore pressure can result in earthquake rupture. Aftershock sequences characterized by the Omori law are often assumed to be the consequence of varying stress, whereas earthquake swarms are thought to be triggered by fluid intrusions. The role of stress triggering can be analyzed by modeling solely three-dimensional (3-D) elastic stress changes in the crust, but fluid flows which initiate seismicity cannot be investigated without considering complex seismicity patterns resulting from both pore pressure variations and earthquake-connected stress field changes. We show that the epidemic-type aftershock sequence (ETAS) model is an appropriate tool to extract the primary fluid signal from such complex seismicity patterns. We analyze a large earthquake swarm that occurred in 2000 in Vogtland/NW Bohemia, central Europe. By fitting the stochastic ETAS model, we find that stress triggering is dominant in creating the observed seismicity patterns and explains the observed fractal interevent time distribution. External forcing, identified with pore pressure changes due to fluid intrusion, is found to directly trigger only a few percent of the total activity. However, temporal deconvolution indicates that a pronounced fluid signal initiated the swarm. These results are confirmed by our analogous investigation of model simulations in which earthquakes are triggered by fluid intrusion as well as stress transfers on a fault plane embedded in a 3-D elastic half-space. The deconvolution procedure based on the ETAS model is able to reveal the underlying pore pressure variations}, language = {en} } @misc{AllefeldFrischSchlesewsky2005, author = {Allefeld, Carsten and Frisch, Stefan and Schlesewsky, Matthias}, title = {Detection of early cognitive processing by event-related phase synchronization analysis}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-20126}, year = {2005}, abstract = {In order to investigate the temporal characteristics of cognitive processing, we apply multivariate phase synchronization analysis to event-related potentials. The experimental design combines a semantic incongruity in a sentence context with a physical mismatch (color change). In the ERP average, these result in an N400 component and a P300-like positivity, respectively. The synchronization analysis shows an effect of global desynchronization in the theta band around 288ms after stimulus presentation for the semantic incongruity, while the physical mismatch elicits an increase of global synchronization in the alpha band around 204ms. Both of these effects clearly precede those in the ERP average. Moreover, the delay between synchronization effect and ERP component correlates with the complexity of the cognitive processes.}, language = {en} } @article{RomanoThielKurthsetal.2005, author = {Romano, Maria Carmen and Thiel, M. and Kurths, J{\"u}rgen and Kiss, Istvan Z. and Hudson, J. L.}, title = {Detection of synchronization for non-phase-coherent and non-stationary data}, issn = {0295-5075}, year = {2005}, abstract = {We present a new method to detect phase as well as generalized synchronization in a wide class of complex systems. It is based on the recurrences of the system's trajectory to the neighborhood of a former state in phase space. We illustrate the applicability of the algorithm for the paradigmatic chaotic Rossler system in the funnel regime and for noisy data, where other methods to detect phase synchronization fail. Furthermore, we demonstrate for electrochemical experiments that the method can easily detect phase and generalized synchronization in non-phase- coherent and even non-stationary time series}, language = {en} } @article{ClaussenBrovkinCalovetal.2005, author = {Claussen, M. and Brovkin, Victor and Calov, R. and Ganopolski, A. and Kubatzki, C.}, title = {Did humankind prevent a Holocene glaciation?}, issn = {0165-0009}, year = {2005}, abstract = {Recently, W.F. Ruddiman (2003, Climatic Change, Vol. 61, pp. 261-293) suggested that the anthropocene, the geological epoch of significant anthropospheric interference with the natural Earth system, has started much earlier than previously thought (P. I. Crutzen and E. F. Stoermer, 2000, IGBP Newsletter, Vol. 429, pp. 623-628). Ruddiman proposed that due to human land use, atmospheric concentrations of CO2 and CH4 began to deviate from their natural declining trends some 8000 and 5000 years ago, respectively. Furthermore, Ruddiman concluded that greenhouse gas concentrations grew anomalously thereby preventing natural large-scale glaciation of northern North America that should have occurred some 4000-5000 years ago without human interference. Here we would like to comment on (a) natural changes in atmospheric CO2 concentration during the Holocene and (b) on the possibility of a Holocene glacial inception. We substantiate our comments by modelling results which suggest that the last three interglacials are not a proper analogue for Holocene climate variations. In particular, we show that our model does not yield a glacial inception during the last several thousand years even if a declining trend in atmospheric CO2 was assumed}, language = {en} } @article{MechauSaphiannikovaNeher2005, author = {Mechau, Norman and Saphiannikova, Marina and Neher, Dieter}, title = {Dielectric and mechanical properties of azobenzene polymer layers under visible and ultraviolet irradiation}, issn = {0024-9297}, year = {2005}, abstract = {Photoinduced changes in the mechanical and dielectric properties of azobenzene polymer films were measured utilizing the method of electromechanical spectroscopy. The measurements revealed a strong correlation between the time- dependent behavior of the plate compliance and the dielectric constant under irradiation. Actinic light causes a light softening of the film that also manifests itself in the increase of the dielectric constant, whereas ultraviolet irradiation results in an initial plasticization of the film followed by its hardening. The latter is accompanied by decrease of the dielectric constant. A semiquantitative model based on the kinetics of the photoisomerization process in azobenzene polymers is proposed. We assume that both visible and ultraviolet irradiation increase the free volume in the layer due to photoisomerization. Additionally, ultraviolet light increases the modulus of the polymer matrix due to the presence of a high density of azobenzene moieties in the cis state. These assumptions allowed us to reproduce the time- dependent behavior of the bulk compliance as well as the dielectric constant at different irradiation intensities, for both visible and ultraviolet light, with only two adjustable parameters}, language = {en} } @article{JaroszQuinnStephanetal.2005, author = {Jarosz, Grazyna and Quinn, P. D. and Stephan, Niels and Brehmer, Ludwig}, title = {Dielectric properties of zinc phthalocyanine thin films : effects of annealing in air and in N-2}, issn = {0040-6090}, year = {2005}, abstract = {This work presents the effects of ambient conditions, in particular oxygen and humidity, on the dielectric spectra of thin zinc phthalocyanine (ZnPc) films equipped with interdigitated electrodes and the effect of annealing in dry N-2 or in ambient air. The measurements were performed in the frequency range 10(-2)-10(5) Hz. The results indicate that the electric properties of ZnPc films are not only affected by oxygen but also by water vapour the presence of which always leads to the drop in alternating current conductance (ac-conductance). Moreover, at room temperature, the ac-conductance of ZnPc films previously exposed to air exhibits a reversible change with humidity, which makes these films attractive for humidity sensing applications. (C) 2004 Elsevier B.V. All rights reserved}, language = {en} } @article{OstermeyerKappeMenzeletal.2005, author = {Ostermeyer, Martin and Kappe, Philip and Menzel, Ralf and Wulfmeyer, Volker}, title = {Diode-pumped Nd : YAG master oscillator power amplifier with high pulse energy, excellent beam quality, and frequency-stabilized master oscillator as a basis for a next-generation lidar system}, issn = {0003-6935}, year = {2005}, abstract = {In the original publication [Ostermeyer et al., Appl. Opt., 44, 582-590 (2005)], Fig. 5 appeared twice as Figs. 4 and 5. This inaccuracy is corrected here. (c) 2005 Optical Society of America}, language = {en} } @book{OstermeyerKappeMenzeletal.2005, author = {Ostermeyer, Martin and Kappe, Philip and Menzel, Ralf and Wulfmeyer, Volker}, title = {Diode-pumped Nd : YAG master oscillator power amplifier with high pulse energy, excellent beam quality, and frequency-stabilized master oscillator as a basis for a next-generation lidar system}, year = {2005}, abstract = {A pulsed, diode-laser-pumped Nd:YAG master oscillator power amplifier (MOPA) in rod geometry, frequency stabilized with a modified Pound-Drever-Hall scheme is presented. The apparatus delivers 33-ns pulses with a maximum pulse energy of 0.5 J at 1064 nm. The system was set up in two different configurations for repetition rates of 100 or 250 Hz. The beam quality was measured to be 1.5 times the diffraction limit at a pulse energy of 405 mJ and a repetition rate of 100 Hz. At 250 Hz with the same pulse energy, the M-2 was better than 2.1. The radiation is frequency converted with an efficiency of 50\% to 532 nm. This MOPA system will be the pump laser of transmitters for a variety of high-end, scanning lidar systems. (C) 2005 Optical Society of America}, language = {en} } @article{TuncerWegenerGerhard2005, author = {Tuncer, Enis and Wegener, Michael and Gerhard, Reimund}, title = {Distribution of relaxation times in alpha-phase polyvinylidene fluoride}, issn = {0022-3093}, year = {2005}, abstract = {In this paper, a recently developed numerical method to analyze dielectric-spectroscopy data is applied to alpha-phase polyvinylidene fluoride (PVDF). The numerical procedure is non-parametric and does not contain any of the extensively used empirical formulas mentioned in the literature. The method basically recovers the unknown distribution of relaxation times of the generalized dielectric function representation by simultaneous application of the Monte Carlo integration method and of the constrained least-squares optimization. The relaxation map constructed after the numerical analysis is compared to a-phase PVDF data presented in the literature and results of the parametric analysis with a well- known empirical formula. (c) 2005 Elsevier B.V. All rights reserved}, language = {en} } @article{EgbeCarbonnierPauletal.2005, author = {Egbe, D. A. M. and Carbonnier, B. and Paul, E. L. and Muhlbacher, D. and Kietzke, Thomas and Birckner, Eckhard and Neher, Dieter and Grummt, U. W. and Pakula, T.}, title = {Diyne-containing PPVs : Solid-state properties and comparison of their photophysical and electrochemical properties with those of their Yne-containing counterparts}, issn = {0024-9297}, year = {2005}, abstract = {Diyne-containing poly(p-phenylene-vinylene)s, 4a-d, of general chemical structure-(Ph-C\&3bond; C-C\&3bond; C-Ph- CH\&3bond; CH-Ph-CH\&3bond; CH-)(n), obtained through polycondensation reactions of 1,4-bis(4-formyl-2,5-dioctyloxyphenyl)- buta-1,3-diyne (2) with various 2,5-dialkoxy-p-xylylenebis(diethylphosphonates), 3a-d, are the subject of this report. The polymers exhibit great disparity in their degree of polymerization, n, which might be ascribed to side-chain-related differences in reactivity of the reactive species during the polycondensation process and which led to n-dependent absorption (solution and solid state) and emission (solution) behaviors of the polymers. Polarizing optical microscopy and differential scanning calorimetry are employed to probe their thermal behavior. The structure is investigated by means of wide-angle X-ray diffraction for both isotropic and macroscopically oriented samples. Comparison of photophysical (experimental and theoretical) and electrochemical properties of the polymers with those of their yne- containing counterparts 6a-d [-(Ph-C\&3bond; C-Ph-CH\&3bond; CH-Ph-CH\&3bond; CH-)(n)] has been carried out. Similar photophysical behavior was observed for both types of polymers despite the difference in backbone conjugation pattern. The introduction of a second yne unit in 4 lowers the HOMO and LUMO levels, thereby enhancing the electron affinity of polymers 4 compared to polymers 6. The "wider opening" introduced by the second yne unit facilitates moreover the movement of charges during the electrochemical processes leading to minimal discrepancy, Delta E-g between the optical and electrochemical band gap energies. Polymers 6, in contrast, show significant side-chain-dependent Delta E-g values. Low turn-on voltages between 2 and 3 V and maximal luminous efficiencies between 0.32 and 1.25 cd/A were obtained from LED devices of configuration ITO/PEDOT:PSS/polymer 4/Ca/Al}, language = {en} } @article{ZhuArmbrusterKatzorke2005, author = {Zhu, M. Q. and Armbruster, Dieter and Katzorke, Ines}, title = {Does synchronization of networks of chaotic maps lead to control?}, issn = {1054-1500}, year = {2005}, abstract = {We consider networks of chaotic maps with different network topologies. In each case, they are coupled in such a way as to generate synchronized chaotic solutions. By using the methods of control of chaos we are controlling a single map into a predetermined trajectory. We analyze the reaction of the network to such a control. Specifically we show that a line of one-dimensional logistic maps that are unidirectionally coupled can be controlled from the first oscillator whereas a ring of diffusively coupled maps cannot be controlled for more than 5 maps. We show that rings with more elements can be controlled if every third map is controlled. The dependence of unidirectionally coupled maps on noise is studied. The noise level leads to a finite synchronization lengths for which maps can be controlled by a single location. A two-dimensional lattice is also studied. (C) 2005 American Institute of Physics}, language = {en} }