@article{ZuritaSanchezHenkel2012, author = {Zurita-Sanchez, Jorge R. and Henkel, Carsten}, title = {Acoustic waves from mechanical impulses due to fluorescence resonant energy (Forster) transfer Blowing a whistle with light}, series = {epl : a letters journal exploring the frontiers of physics}, volume = {97}, journal = {epl : a letters journal exploring the frontiers of physics}, number = {4}, publisher = {EDP Sciences}, address = {Mulhouse}, issn = {0295-5075}, doi = {10.1209/0295-5075/97/43002}, pages = {6}, year = {2012}, abstract = {We present a momentum transfer mechanism mediated by electromagnetic fields that originates in a system of two nearby molecules: one excited (donor D*) and the other in ground state (acceptor A). An intermolecular force related to fluorescence resonant energy or Forster transfer (FRET) arises in the unstable D* A molecular system, which differs from the equilibrium van der Waals interaction. Due to the its finite lifetime, a mechanical impulse is imparted to the relative motion in the system. We analyze the FRET impulse when the molecules are embedded in free space and find that its magnitude can be much greater than the single recoil photon momentum, getting comparable with the thermal momentum (Maxwell-Boltzmann distribution) at room temperature. In addition, we propose that this FRET impulse can be exploited in the generation of acoustic waves inside a film containing layers of donor and acceptor molecules, when a picosecond laser pulse excites the donors. This acoustic transient is distinguishable from that produced by thermal stress due to laser absorption, and may therefore play a role in photoacoustic spectroscopy. The effect can be seen as exciting a vibrating system like a string or organ pipe with light; it may be used as an opto-mechanical transducer.}, language = {en} } @article{ZhuKolloscheLuetal.2012, author = {Zhu, Jian and Kollosche, Matthias and Lu, Tongqing and Kofod, Guggi and Suo, Zhigang}, title = {Two types of transitions to wrinkles in dielectric elastomers}, series = {Soft matter}, volume = {8}, journal = {Soft matter}, number = {34}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {1744-683X}, doi = {10.1039/c2sm26034d}, pages = {8840 -- 8846}, year = {2012}, abstract = {A membrane of a dielectric elastomer coated with compliant electrodes may form wrinkles as the applied voltage is ramped up. We present a combination of experiment and theory to investigate the transition to wrinkles using a clamped membrane subject to a constant force and a voltage ramp. Two types of transitions are identified. In type-I transition, the voltage-stretch curve is N-shaped, and flat and wrinkled regions coexist in separate areas of the membrane. The type-I transition progresses by nucleation of small wrinkled regions, followed by the growth of the wrinkled regions at the expense of the flat regions, until the entire membrane is wrinkled. By contrast, in type-II transition, the voltage-stretch curve is monotonic, and the entire flat membrane becomes wrinkled with no nucleation barrier. The two types of transitions are analogous to the first and the second order phase transitions. While the type-I transition is accompanied by a jump in the vertical displacement, type-II transition is accompanied by a continuous change in the vertical displacement. Such transitions may enable applications in muscle-like actuation and energy harvesting, where large deformation and large energy of conversion are desired.}, language = {en} } @article{ZakrevskyyRichterZakrevskaetal.2012, author = {Zakrevskyy, Yuriy and Richter, Marcel and Zakrevska, Svitlana and Lomadze, Nino and von Klitzing, Regine and Santer, Svetlana}, title = {Light-controlled reversible manipulation of microgel particle size using azobenzene-containing surfactant}, series = {Advanced functional materials}, volume = {22}, journal = {Advanced functional materials}, number = {23}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {1616-301X}, doi = {10.1002/adfm.201200617}, pages = {5000 -- 5009}, year = {2012}, abstract = {The light-induced reversible switching of the swelling of microgel particles triggered by photo-isomerization and binding/unbinding of a photosensitive azobenzene-containing surfactant is reported. The interactions between the microgel (N-isopropylacrylamide, co-monomer: allyl acetic acid, crosslinker: N,N'-methylenebisacrylamide) and the surfactant are studied by UV-Vis spectroscopy, dynamic and electrophoretic light scattering measurements. Addition of the surfactant above a critical concentration leads to contraction/collapse of the microgel. UV light irradiation results in trans-cis isomerization of the azobenzene unit incorporated into the surfactant tail and causes an unbinding of the more hydrophilic cis isomer from the microgel and its reversible swelling. The reversible contraction can be realized by blue light irradiation that transfers the surfactant back to the more hydrophobic trans conformation, in which it binds to the microgel. The phase diagram of the surfactant-microgel interaction and transitions (aggregation, contraction, and precipitation) is constructed and allows prediction of changes in the system when the concentration of one or both components is varied. Remote and reversible switching between different states can be realized by either UV or visible light irradiation.}, language = {en} } @article{WirgesRaabeQiu2012, author = {Wirges, Werner and Raabe, Sebastian and Qiu, Xunlin}, title = {Dielectric elastomer and ferroelectret films combined in a single device how do they reinforce each other?}, series = {Applied physics : A, Materials science \& processing}, volume = {107}, journal = {Applied physics : A, Materials science \& processing}, number = {3}, publisher = {Springer}, address = {New York}, issn = {0947-8396}, doi = {10.1007/s00339-012-6833-6}, pages = {583 -- 588}, year = {2012}, abstract = {Dielectric elastomers (DE) are soft polymer materials exhibiting large deformations under electrostatic stress. When a prestretched elastomer is stuck to a flat plastic frame, a complex structure that can be used as an actuator (DEA) is formed due to self-organization and energy minimization. Here, such a DEA was equipped with a ferroelectret film. Ferroelectrets are internally charged polymer foams or void-containing polymer-film systems combining large piezoelectricity with mechanical flexibility and elastic compliance. In their dielectric spectra, ferroelectrets show piezoelectric resonances that can be used to analyze their electromechanical properties. The antiresonance frequencies ( ) of ferroelectret films not only are directly related to their geometric parameters, but also are sensitive to the boundary conditions during measurement. In this paper, a fluoroethylenepropylene (FEP) ferroelectret film with tubular void channels was glued to a plastic frame prior to the formation of self-organized minimum-energy DEA structure. The dielectric resonance spectrum (DRS) of the ferroelectret film was measured in-situ during the actuation of the DEA under applied voltage. It is found that the antiresonance frequency is a monotropic function of the bending angle of the actuator. Therefore, the actuation of DEAs can be used to modulate the of ferroelectrets, while the can also be taken for in-situ diagnosis and for precise control of the actuation of the DEA. Combination of DEAs and ferroelectrets brings a number of possibilities for application.}, language = {en} } @article{WinkelmannLevermannMartinetal.2012, author = {Winkelmann, Ricarda and Levermann, Anders and Martin, Maria A. and Frieler, Katja}, title = {Increased future ice discharge from Antarctica owing to higher snowfall}, series = {Nature : the international weekly journal of science}, volume = {492}, journal = {Nature : the international weekly journal of science}, number = {7428}, publisher = {Nature Publ. Group}, address = {London}, issn = {0028-0836}, doi = {10.1038/nature11616}, pages = {239 -- +}, year = {2012}, abstract = {Anthropogenic climate change is likely to cause continuing global sea level rise(1), but some processes within the Earth system may mitigate the magnitude of the projected effect. Regional and global climate models simulate enhanced snowfall over Antarctica, which would provide a direct offset of the future contribution to global sea level rise from cryospheric mass loss(2,3) and ocean expansion(4). Uncertainties exist in modelled snowfall(5), but even larger uncertainties exist in the potential changes of dynamic ice discharge from Antarctica(1,6) and thus in the ultimate fate of the precipitation-deposited ice mass. Here we show that snowfall and discharge are not independent, but that future ice discharge will increase by up to three times as a result of additional snowfall under global warming. Our results, based on an ice-sheet model(7) forced by climate simulations through to the end of 2500 (ref. 8), show that the enhanced discharge effect exceeds the effect of surface warming as well as that of basal ice-shelf melting, and is due to the difference in surface elevation change caused by snowfall on grounded versus floating ice. Although different underlying forcings drive ice loss from basal melting versus increased snowfall, similar ice dynamical processes are nonetheless at work in both; therefore results are relatively independent of the specific representation of the transition zone. In an ensemble of simulations designed to capture ice-physics uncertainty, the additional dynamic ice loss along the coastline compensates between 30 and 65 per cent of the ice gain due to enhanced snowfall over the entire continent. This results in a dynamic ice loss of up to 1.25 metres in the year 2500 for the strongest warming scenario. The reported effect thus strongly counters a potential negative contribution to global sea level by the Antarctic Ice Sheet.}, language = {en} } @article{WertheimerStGeorgesRobillardLerougeetal.2012, author = {Wertheimer, Michael R. and St-Georges-Robillard, Amelie and Lerouge, Sophie and Mwale, Fackson and Elkin, Bentsian and Oehr, Christian and Wirges, Werner and Gerhard, Reimund}, title = {Amine-rich organic thin films for cell culture - possible electrostatic effects in cell-surface interactions}, series = {Japanese journal of applied physics}, volume = {51}, journal = {Japanese journal of applied physics}, number = {11}, publisher = {Japan Soc. of Applied Physics}, address = {Tokyo}, issn = {0021-4922}, doi = {10.1143/JJAP.51.11PJ04}, pages = {5}, year = {2012}, abstract = {In recent communications from these laboratories, we observed that amine-rich thin organic layers are very efficient surfaces for the adhesion of mammalian cells. We prepare such deposits by plasma polymerization at low pressure, atmospheric pressure, or by vacuum-ultraviolet photo-polymerization. More recently, we have also investigated a commercially available material, Parylene diX AM. In this article we first briefly introduce literature relating to electrostatic interactions between cells, proteins, and charged surfaces. We then present certain selected cell-response results that pertain to applications in orthopedic and cardiovascular medicine: we discuss the influence of surface properties on the observed behaviors of two particular cell lines, human U937 monocytes, and Chinese hamster ovary cells. Particular emphasis is placed on possible electrostatic attractive forces due to positively charged R-NH3+ groups and negatively charged proteins and cells, respectively. Experiments carried out with electrets, polymers with high positive or negative surface potentials are added for comparison.}, language = {en} } @article{WendtMolaro2012, author = {Wendt, Martin and Molaro, P.}, title = {QSO 0347-383 and the invariance of m(p)/m(e) in the course of cosmic time}, series = {Astronomy and astrophysics : an international weekly journal}, volume = {541}, journal = {Astronomy and astrophysics : an international weekly journal}, number = {3}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {0004-6361}, doi = {10.1051/0004-6361/201218862}, pages = {8}, year = {2012}, abstract = {Context. The variation of the dimensionless fundamental physical constant mu = m(p)/m(e) - the proton to electron mass ratio - can be constrained via observation of Lyman and Werner lines of molecular hydrogen in the spectra of damped Lyman alpha systems (DLAs) in the line of sight to distant QSOs. Aims. Our intention is to maximize the possible precision of quasar absorption spectroscopy with regard to the investigation of the variation of the proton-to-electron mass-ratio mu. The demand for precision requires an understanding of the errors involved and effective techniques to handle present systematic errors. Methods. An analysis based on UVES high resolution data sets of QSO 0347-383 and its DLA is put forward and new approaches to some of the steps involved in the data analysis are introduced. We apply corrections for the observed offsets between discrete spectra and for the first time we find indications for inter-order distortions. Results. Drawing on VLT-UVES observations of QSO 0347-383 in 2009 our analysis yields Delta mu/mu = (4.3 +/- 7.2) x 10(-6) at z(abs) = 3.025. Conclusions. Current analyzes tend to underestimate the impact of systematic errors. Based on the scatter of the measured redshifts and the corresponding low significance of the redshift-sensitivity correlation we estimate the limit of accuracy of line position measurements to similar to 220 m s (1), consisting of roughly 150 m s (1) due to the uncertainty of the absorption line fit and about 150 m s (1) allocated to systematics related to instrumentation and calibration.}, language = {en} } @article{WeberFrankBommeletal.2012, author = {Weber, Cornelia and Frank, C. and Bommel, Sebastian and Rukat, Tammo and Leitenberger, Wolfram and Sch{\"a}fer, Peter and Schreiber, Frank and Kowarik, Stefan}, title = {Chain-length dependent growth dynamics of n-alkanes on silica investigated by energy-dispersive x-ray reflectivity in situ and in real-time}, series = {The journal of chemical physics : bridges a gap between journals of physics and journals of chemistr}, volume = {136}, journal = {The journal of chemical physics : bridges a gap between journals of physics and journals of chemistr}, number = {20}, publisher = {American Institute of Physics}, address = {Melville}, issn = {0021-9606}, doi = {10.1063/1.4719530}, pages = {7}, year = {2012}, abstract = {We compare the growth dynamics of the three n-alkanes C36H74, C40H82, and C44H90 on SiO2 using real-time and in situ energy-dispersive x-ray reflectivity. All molecules investigated align in an upright-standing orientation on the substrate and exhibit a transition from layer-by-layer growth to island growth after about 4 monolayers under the conditions employed. Simultaneous fits of the reflected intensity at five distinct points in reciprocal space show that films formed by longer n-alkanes roughen faster during growth. This behavior can be explained by a chain-length dependent height of the Ehrlich-Schwoebel barrier. Further x-ray diffraction measurements after growth indicate that films consisting of longer n-alkanes also incorporate more lying-down molecules in the top region. While the results reveal behavior typical for chain-like molecules, the findings can also be useful for the optimization of organic field effect transistors where smooth interlayers of n-alkanes without coexistence of two or more molecular orientations are required.}, language = {en} } @article{WangLackXieetal.2012, author = {Wang, Feipeng and Lack, Alexander and Xie, Zailai and Fr{\"u}bing, Peter and Taubert, Andreas and Gerhard, Reimund}, title = {Ionic-liquid-induced ferroelectric polarization in poly(vinylidene fluoride) thin films}, series = {Applied physics letters}, volume = {100}, journal = {Applied physics letters}, number = {6}, publisher = {American Institute of Physics}, address = {Melville}, issn = {0003-6951}, doi = {10.1063/1.3683526}, pages = {4}, year = {2012}, abstract = {Thin films of ferroelectric beta-phase poly(vinylidene fluoride) (PVDF) were spin-coated from a solution that contained small amounts of the ionic liquid (IL) 1-ethyl-3-methylimidazolium nitrate. A remanent polarization of 60 mC/m(2) and a quasi-static pyroelectric coefficient of 19 mu C/m(2)K at 30 degrees C were observed in the films. It is suggested that the IL promotes the formation of the beta phase through dipolar interactions between PVDF chain-molecules and the IL. The dipolar interactions are identified as Coulomb attraction between hydrogen atoms in PVDF chains and anions in IL. The strong crystallinity increase is probably caused by the same dipolar interaction as well.}, language = {en} } @article{ValoriGreenDemoulinetal.2012, author = {Valori, Gherardo and Green, Lucie M. and Demoulin, Pascal and Vargas Dominguez, S. and van Driel-Gesztelyi, L. and Wallace, A. and Baker, Daniel N. and Fuhrmann, Marcel}, title = {Nonlinear force-free extrapolation of emerging flux with a global twist and serpentine fine structures}, series = {Solar physics : a journal for solar and solar-stellar research and the study of solar terrestrial physics}, volume = {278}, journal = {Solar physics : a journal for solar and solar-stellar research and the study of solar terrestrial physics}, number = {1}, publisher = {Springer}, address = {Dordrecht}, issn = {0038-0938}, doi = {10.1007/s11207-011-9865-8}, pages = {73 -- 97}, year = {2012}, abstract = {We study the flux emergence process in NOAA active region 11024, between 29 June and 7 July 2009, by means of multi-wavelength observations and nonlinear force-free extrapolation. The main aim is to extend previous investigations by combining, as much as possible, high spatial resolution observations to test our present understanding of small-scale (undulatory) flux emergence, whilst putting these small-scale events in the context of the global evolution of the active region. The combination of these techniques allows us to follow the whole process, from the first appearance of the bipolar axial field on the east limb, until the buoyancy instability could set in and raise the main body of the twisted flux tube through the photosphere, forming magnetic tongues and signatures of serpentine field, until the simplification of the magnetic structure into a main bipole by the time the active region reaches the west limb. At the crucial time of the main emergence phase high spatial resolution spectropolarimetric measurements of the photospheric field are employed to reconstruct the three-dimensional structure of the nonlinear force-free coronal field, which is then used to test the current understanding of flux emergence processes. In particular, knowledge of the coronal connectivity confirms the identity of the magnetic tongues as seen in their photospheric signatures, and it exemplifies how the twisted flux, which is emerging on small scales in the form of a sea-serpent, is subsequently rearranged by reconnection into the large-scale field of the active region. In this way, the multi-wavelength observations combined with a nonlinear force-free extrapolation provide a coherent picture of the emergence process of small-scale magnetic bipoles, which subsequently reconnect to form a large-scale structure in the corona.}, language = {en} } @article{ValoriDemoulinPariat2012, author = {Valori, Gherardo and Demoulin, Pascal and Pariat, E.}, title = {Comparing values of the relative magnetic helicity in finite volumes}, series = {Solar physics : a journal for solar and solar-stellar research and the study of solar terrestrial physics}, volume = {278}, journal = {Solar physics : a journal for solar and solar-stellar research and the study of solar terrestrial physics}, number = {2}, publisher = {Springer}, address = {Dordrecht}, issn = {0038-0938}, doi = {10.1007/s11207-012-9951-6}, pages = {347 -- 366}, year = {2012}, abstract = {Relative magnetic helicity, as a conserved quantity of ideal magnetohydrodynamics, has been highlighted as an important quantity to study in plasma physics. Due to its nonlocal nature, its estimation is not straightforward in both observational and numerical data. In this study we derive expressions for the practical computation of the gauge-independent relative magnetic helicity in three-dimensional finite domains. The derived expressions are easy to implement and rapid to compute. They are derived in Cartesian coordinates, but can be easily written in other coordinate systems. We apply our method to a numerical model of a force-free equilibrium containing a flux rope, and compare the results with those obtained employing known half-space equations. We find that our method requires a much smaller volume than half-space expressions to derive the full helicity content. We also prove that values of relative magnetic helicity of different magnetic fields can be compared with each other in the same sense as free-energy values can. Therefore, relative magnetic helicity can be meaningfully and directly compared between different datasets, such as those from different active regions, but also within the same dataset at different times. Typical applications of our formulae include the helicity computation in three-dimensional models of the solar atmosphere, e.g., coronal-field reconstructions by force-free extrapolation and discretized magnetic fields of numerical simulations.}, language = {en} } @article{TurhanSaracGencturketal.2012, author = {Turhan, Metehan C. and Sarac, A. Sezai and Gencturk, Asli and Gilsing, Hans-Detlev and Faltz, Heike and Schulz, Burkhard}, title = {Electrochemical impedance characterization and potential dependence of poly[3,4-(2,2-dibutylpropylenedioxy)thiophene] nanostructures on single carbon fiber microelectrode}, series = {Synthetic metals : the journal of electronic polymers and electronic molecular materials}, volume = {162}, journal = {Synthetic metals : the journal of electronic polymers and electronic molecular materials}, number = {5-6}, publisher = {Elsevier}, address = {Lausanne}, issn = {0379-6779}, doi = {10.1016/j.synthmet.2012.01.012}, pages = {511 -- 515}, year = {2012}, abstract = {The electropolymerization of 3,4-(2,2-dibutylpropylenedioxy)thiophene (ProDOT-Bu-2) onto single carbon fiber microelectrode (SCFME) was conducted in acetonitrile (ACN) containing sodium perchlorate (NaClO4) as electrolyte and investigated by cyclic voltammetry (CV). The nanostructured films of poly[3,4-(2,2-dibutyl-propyleneclioxy)thiophene] (PProDOT-Bu-2) which were depositing showed complete reversible redox behavior in monomer-free electrolyte solution. The capacitive behavior of the films was investigated by electrochemical impedance spectroscopy (EIS) at applied potentials from 0.1 V to 1.3 V. The analysis by equivalent circuit modeling revealed an applied potential around 0.4V to be most suitable for the system PProDOT-Bu-2/SCFME as a double layer supercapacitor component inducing a double layer capacitance C-d, value of 62 mFcm(-2).}, language = {en} } @article{TrotzkyChenFleschetal.2012, author = {Trotzky, S. and Chen, Y-A. and Flesch, A. and McCulloch, I. P. and Schollw{\"o}ck, U. and Eisert, J. and Bloch, I.}, title = {Probing the relaxation towards equilibrium in an isolated strongly correlated one-dimensional Bose gas}, series = {Nature physics}, volume = {8}, journal = {Nature physics}, number = {4}, publisher = {Nature Publ. Group}, address = {London}, issn = {1745-2473}, doi = {10.1038/NPHYS2232}, pages = {325 -- 330}, year = {2012}, abstract = {The problem of how complex quantum systems eventually come to rest lies at the heart of statistical mechanics. The maximum-entropy principle describes which quantum states can be expected in equilibrium, but not how closed quantum many-body systems dynamically equilibrate. Here, we report the experimental observation of the non-equilibrium dynamics of a density wave of ultracold bosonic atoms in an optical lattice in the regime of strong correlations. Using an optical superlattice, we follow its dynamics in terms of quasi-local densities, currents and coherences-all showing a fast relaxation towards equilibrium values. Numerical calculations based on matrix-product states are in an excellent quantitative agreement with the experimental data. The system fulfills the promise of being a dynamical quantum simulator, in that the controlled dynamics runs for longer times than present classical algorithms can keep track of.}, language = {en} } @article{Tonita2012, author = {Tonita, Aaryn}, title = {Distributional sources for black hole initial data}, series = {Classical and quantum gravit}, volume = {29}, journal = {Classical and quantum gravit}, number = {1}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0264-9381}, doi = {10.1088/0264-9381/29/1/015001}, pages = {16}, year = {2012}, abstract = {Black hole initial data are usually produced using Bowen-York-type puncture initial data or by applying an excision boundary condition. The benefits of the Bowen-York initial data are the ability to specify the spin and momentum of the system as parameters of the initial data. In an attempt to extend these benefits to other formulations of the Einstein constraints, the puncture method is reformulated using distributions as source terms. It is shown how the Bowen-York puncture black hole initial data and the trumpet variation are generated by distributional sources. A heuristic argument is presented to argue that these sources are the general sources of spin and momentum. In order to clarify the meaning of other distributional sources, an exact family of initial data with generalized sources to the Hamiltonian constraint are studied; spinning trumpet black hole initial data and black hole initial data with higher order momentum sources are also studied.}, language = {en} } @article{TomovskiSandevMetzleretal.2012, author = {Tomovski, Zivorad and Sandev, Trifce and Metzler, Ralf and Dubbeldam, Johan}, title = {Generalized space-time fractional diffusion equation with composite fractional time derivative}, series = {Physica : europhysics journal ; A, Statistical mechanics and its applications}, volume = {391}, journal = {Physica : europhysics journal ; A, Statistical mechanics and its applications}, number = {8}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0378-4371}, doi = {10.1016/j.physa.2011.12.035}, pages = {2527 -- 2542}, year = {2012}, abstract = {We investigate the solution of space-time fractional diffusion equations with a generalized Riemann-Liouville time fractional derivative and Riesz-Feller space fractional derivative. The Laplace and Fourier transform methods are applied to solve the proposed fractional diffusion equation. The results are represented by using the Mittag-Leffler functions and the Fox H-function. Special cases of the initial and boundary conditions are considered. Numerical scheme and Grunwald-Letnikov approximation are also used to solve the space-time fractional diffusion equation. The fractional moments of the fundamental solution of the considered space-time fractional diffusion equation are obtained. Many known results are special cases of those obtained in this paper. We investigate also the solution of a space-time fractional diffusion equations with a singular term of the form delta(x). t-beta/Gamma(1-beta) (beta > 0).}, language = {en} } @article{ThompsonKliemToeroek2012, author = {Thompson, W. T. and Kliem, Bernhard and Toeroek, Tibor}, title = {3D reconstruction of a rotating erupting prominence}, series = {Solar physics : a journal for solar and solar-stellar research and the study of solar terrestrial physics}, volume = {276}, journal = {Solar physics : a journal for solar and solar-stellar research and the study of solar terrestrial physics}, number = {1-2}, publisher = {Springer}, address = {Dordrecht}, issn = {0038-0938}, doi = {10.1007/s11207-011-9868-5}, pages = {241 -- 259}, year = {2012}, abstract = {A bright prominence associated with a coronal mass ejection (CME) was seen erupting from the Sun on 9 April 2008. This prominence was tracked by both the Solar Terrestrial Relations Observatory (STEREO) EUVI and COR1 telescopes, and was seen to rotate about the line of sight as it erupted; therefore, the event has been nicknamed the "Cartwheel CME." The threads of the prominence in the core of the CME quite clearly indicate the structure of a weakly to moderately twisted flux rope throughout the field of view, up to heliocentric heights of 4 solar radii. Although the STEREO separation was 48A degrees, it was possible to match some sharp features in the later part of the eruption as seen in the 304 line in EUVI and in the H alpha-sensitive bandpass of COR1 by both STEREO Ahead and Behind. These features could then be traced out in three-dimensional space, and reprojected into a view in which the eruption is directed toward the observer. The reconstructed view shows that the alignment of the prominence to the vertical axis rotates as it rises up to a leading-edge height of a parts per thousand aEuro parts per thousand 2.5 solar radii, and then remains approximately constant. The alignment at 2.5 solar radii differs by about 115A degrees from the original filament orientation inferred from H alpha and EUV data, and the height profile of the rotation, obtained here for the first time, shows that two thirds of the total rotation are reached within a parts per thousand aEuro parts per thousand 0.5 solar radii above the photosphere. These features are well reproduced by numerical simulations of an unstable moderately twisted flux rope embedded in external flux with a relatively strong shear field component.}, language = {en} } @article{ThomasMatuschekGrima2012, author = {Thomas, Philipp and Matuschek, Hannes and Grima, Ramon}, title = {Intrinsic noise analyzer A software package for the exploration of stochastic biochemical kinetics using the system size expansion}, series = {PLoS one}, volume = {7}, journal = {PLoS one}, number = {6}, publisher = {PLoS}, address = {San Fransisco}, issn = {1932-6203}, doi = {10.1371/journal.pone.0038518}, pages = {20}, year = {2012}, abstract = {The accepted stochastic descriptions of biochemical dynamics under well-mixed conditions are given by the Chemical Master Equation and the Stochastic Simulation Algorithm, which are equivalent. The latter is a Monte-Carlo method, which, despite enjoying broad availability in a large number of existing software packages, is computationally expensive due to the huge amounts of ensemble averaging required for obtaining accurate statistical information. The former is a set of coupled differential-difference equations for the probability of the system being in any one of the possible mesoscopic states; these equations are typically computationally intractable because of the inherently large state space. Here we introduce the software package intrinsic Noise Analyzer (iNA), which allows for systematic analysis of stochastic biochemical kinetics by means of van Kampen's system size expansion of the Chemical Master Equation. iNA is platform independent and supports the popular SBML format natively. The present implementation is the first to adopt a complementary approach that combines state-of-the-art analysis tools using the computer algebra system Ginac with traditional methods of stochastic simulation. iNA integrates two approximation methods based on the system size expansion, the Linear Noise Approximation and effective mesoscopic rate equations, which to-date have not been available to non-expert users, into an easy-to-use graphical user interface. In particular, the present methods allow for quick approximate analysis of time-dependent mean concentrations, variances, covariances and correlations coefficients, which typically outperforms stochastic simulations. These analytical tools are complemented by automated multi-core stochastic simulations with direct statistical evaluation and visualization. We showcase iNA's performance by using it to explore the stochastic properties of cooperative and non-cooperative enzyme kinetics and a gene network associated with circadian rhythms. The software iNA is freely available as executable binaries for Linux, MacOSX and Microsoft Windows, as well as the full source code under an open source license.}, language = {en} } @article{ThielemannKuehnHoffmannFoehlisch2012, author = {Thielemann-K{\"u}hn, Nele and Hoffmann, P. and F{\"o}hlisch, Alexander}, title = {A versatile detector for total fluorescence and electron yield experiments}, series = {Review of scientific instruments : a monthly journal devoted to scientific instruments, apparatus, and techniques}, volume = {83}, journal = {Review of scientific instruments : a monthly journal devoted to scientific instruments, apparatus, and techniques}, number = {9}, publisher = {American Institute of Physics}, address = {Melville}, issn = {0034-6748}, doi = {10.1063/1.4754126}, pages = {3}, year = {2012}, abstract = {The combination of a non-coated silicon photodiode with electron repelling meshes makes a versatile detector for total fluorescence yield and electron yield techniques highly suitable for x-ray absorption spectroscopy. In particular, a copper mesh with a bias voltage allows to suppress or transmit the electron yield signal. The performance of this detection scheme has been characterized by near edge x-ray absorption fine structure studies of thermal oxidized silicon and sapphire. The results show that the new detector probes both electron yield and for a bias voltage exceeding the maximum photon energy the total fluorescence yield.}, language = {en} } @article{TeriacaAndrettaAuchereetal.2012, author = {Teriaca, Luca and Andretta, Vincenzo and Auchere, Frederic and Brown, Charles M. and Buchlin, Eric and Cauzzi, Gianna and Culhane, J. Len and Curdt, Werner and Davila, Joseph M. and Del Zanna, Giulio and Doschek, George A. and Fineschi, Silvano and Fludra, Andrzej and Gallagher, Peter T. and Green, Lucie and Harra, Louise K. and Imada, Shinsuke and Innes, Davina and Kliem, Bernhard and Korendyke, Clarence and Mariska, John T. and Martinez-Pillet, Valentin and Parenti, Susanna and Patsourakos, Spiros and Peter, Hardi and Poletto, Luca and Rutten, Robert J. and Schuehle, Udo and Siemer, Martin and Shimizu, Toshifumi and Socas-Navarro, Hector and Solanki, Sami K. and Spadaro, Daniele and Trujillo-Bueno, Javier and Tsuneta, Saku and Dominguez, Santiago Vargas and Vial, Jean-Claude and Walsh, Robert and Warren, Harry P. and Wiegelmann, Thomas and Winter, Berend and Young, Peter}, title = {LEMUR large european module for solar ultraviolet research}, series = {Experimental astronomy : an international journal on astronomical instrumentation and data analysis}, volume = {34}, journal = {Experimental astronomy : an international journal on astronomical instrumentation and data analysis}, number = {2}, publisher = {Springer}, address = {Dordrecht}, issn = {0922-6435}, doi = {10.1007/s10686-011-9274-x}, pages = {273 -- 309}, year = {2012}, abstract = {The solar outer atmosphere is an extremely dynamic environment characterized by the continuous interplay between the plasma and the magnetic field that generates and permeates it. Such interactions play a fundamental role in hugely diverse astrophysical systems, but occur at scales that cannot be studied outside the solar system. Understanding this complex system requires concerted, simultaneous solar observations from the visible to the vacuum ultraviolet (VUV) and soft X-rays, at high spatial resolution (between 0.1'' and 0.3''), at high temporal resolution (on the order of 10 s, i.e., the time scale of chromospheric dynamics), with a wide temperature coverage (0.01 MK to 20 MK, from the chromosphere to the flaring corona), and the capability of measuring magnetic fields through spectropolarimetry at visible and near-infrared wavelengths. Simultaneous spectroscopic measurements sampling the entire temperature range are particularly important. These requirements are fulfilled by the Japanese Solar-C mission (Plan B), composed of a spacecraft in a geosynchronous orbit with a payload providing a significant improvement of imaging and spectropolarimetric capabilities in the UV, visible, and near-infrared with respect to what is available today and foreseen in the near future. The Large European Module for solar Ultraviolet Research (LEMUR), described in this paper, is a large VUV telescope feeding a scientific payload of high-resolution imaging spectrographs and cameras. LEMUR consists of two major components: a VUV solar telescope with a 30 cm diameter mirror and a focal length of 3.6 m, and a focal-plane package composed of VUV spectrometers covering six carefully chosen wavelength ranges between 170 and 1270 . The LEMUR slit covers 280'' on the Sun with 0.14'' per pixel sampling. In addition, LEMUR is capable of measuring mass flows velocities (line shifts) down to 2 km s (-aEuro parts per thousand 1) or better. LEMUR has been proposed to ESA as the European contribution to the Solar C mission.}, language = {en} } @article{TepperGarciaRichterSchayeetal.2012, author = {Tepper-Garcia, Thorsten and Richter, Philipp and Schaye, Joop and Booth, C. M. and Dalla Vecchia, Claudio and Theuns, Tom}, title = {Absorption signatures of warm-hot gas at low redshift: broad H?i Lya absorbers}, series = {Monthly notices of the Royal Astronomical Society}, volume = {425}, journal = {Monthly notices of the Royal Astronomical Society}, number = {3}, publisher = {Wiley-Blackwell}, address = {Hoboken}, issn = {0035-8711}, doi = {10.1111/j.1365-2966.2012.21545.x}, pages = {1640 -- 1663}, year = {2012}, abstract = {We investigate the physical state of H?i absorbing gas at low redshift (z = 0.25) using a subset of cosmological, hydrodynamic simulations from the OverWhelmingly Large Simulations project, focusing in particular on broad (bHI=40 km s-1) H?i Lya absorbers (BLAs), which are believed to originate in shock-heated gas in the warm-hot intergalactic medium (WHIM). Our fiducial model, which includes radiative cooling by heavy elements and feedback by supernovae and active galactic nuclei, predicts that by z = 0.25 nearly 60?per cent of the gas mass ends up at densities and temperatures characteristic of the WHIM and we find that half of this fraction is due to outflows. The standard H?i observables (distribution of H?i column densities NH?I, distribution of Doppler parameters bHI, bHINH?I correlation) and the BLA line number density predicted by our simulations are in remarkably good agreement with observations. BLAs arise in gas that is hotter, more highly ionized and more enriched than the gas giving rise to typical Lya forest absorbers. The majority of the BLAs arise in warm-hot [log?(T/?K) similar to 5] gas at low (log?? < 1.5) overdensities. On average, thermal broadening accounts for at least 60?per cent of the BLA linewidth, which in turn can be used as a rough indicator of the thermal state of the gas. Detectable BLAs account for only a small fraction of the true baryon content of the WHIM at low redshift. In order to detect the bulk of the mass in this gas phase, a sensitivity at least one order of magnitude better than achieved by current ultraviolet spectrographs is required. We argue that BLAs mostly trace gas that has been shock heated and enriched by outflows and that they therefore provide an important window on a poorly understood feedback process.}, language = {en} } @article{TemirbayevZhanabaevTarasovetal.2012, author = {Temirbayev, Amirkhan A. and Zhanabaev, Zeinulla Zh. and Tarasov, Stanislav B. and Ponomarenko, Vladimir I. and Rosenblum, Michael}, title = {Experiments on oscillator ensembles with global nonlinear coupling}, series = {Physical review : E, Statistical, nonlinear and soft matter physics}, volume = {85}, journal = {Physical review : E, Statistical, nonlinear and soft matter physics}, number = {1}, publisher = {American Physical Society}, address = {College Park}, issn = {1539-3755}, doi = {10.1103/PhysRevE.85.015204}, pages = {4}, year = {2012}, abstract = {We experimentally analyze collective dynamics of a population of 20 electronic Wien-bridge limit-cycle oscillators with a nonlinear phase-shifting unit in the global feedback loop. With an increase in the coupling strength we first observe formation and then destruction of a synchronous cluster, so that the dependence of the order parameter on the coupling strength is not monotonic. After destruction of the cluster the ensemble remains nevertheless coherent, i.e., it exhibits an oscillatory collective mode (mean field). We show that the system is now in a self-organized quasiperiodic state, predicted in Rosenblum and Pikovsky [Phys. Rev. Lett. 98, 064101 (2007)]. In this state, frequencies of all oscillators are smaller than the frequency of the mean field, so that the oscillators are not locked to the mean field they create and their dynamics is quasiperiodic. Without a nonlinear phase-shifting unit, the system exhibits a standard Kuramoto-like transition to a fully synchronous state. We demonstrate a good correspondence between the experiment and previously developed theory. We also propose a simple measure which characterizes the macroscopic incoherence-coherence transition in a finite-size ensemble.}, language = {en} } @article{TelezhinskyDwarkadasPohl2012, author = {Telezhinsky, Igor O. and Dwarkadas, Vikram V. and Pohl, Martin}, title = {Time-dependent escape of cosmic rays from supernova remnants, and their interaction with dense media}, series = {Astronomy and astrophysics : an international weekly journal}, volume = {541}, journal = {Astronomy and astrophysics : an international weekly journal}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {0004-6361}, doi = {10.1051/0004-6361/201118639}, pages = {11}, year = {2012}, abstract = {Context. Supernova remnants (SNRs) are thought to be the main source of Galactic cosmic rays (CRs) up to the "knee" in CR spectrum. During the evolution of a SNR, the bulk of the CRs are confined inside the SNR shell. The highest-energy particles leave the system continuously, while the remaining adiabatically cooled particles are released when the SNR has expanded sufficiently and decelerated so that the magnetic field at the shock is no longer able to confine them. Particles escaping from the parent system may interact with nearby molecular clouds, producing.-rays in the process via pion decay. The soft gamma-ray spectra observed for a number of SNRs interacting with molecular clouds, however, challenge current theories of non-linear particle acceleration that predict harder spectra. Aims. We study how the spectrum of escaped particles depends on the time-dependent acceleration history in both Type Ia and core-collapse SNRs, as well as on different assumptions about the diffusion coefficient in the vicinity of the SNR. Methods. We solve the CR transport equation in a test-particle approach combined with numerical simulations of SNR evolution. Results. We extend our method for calculating the CR acceleration in SNRs to trace the escaped particles in a large volume around SNRs. We calculate the evolution of the spectra of CRs that have escaped from a SNR into a molecular cloud or dense shell for two diffusion models. We find a strong confinement of CRs in a close region around the SNR, and a strong dilution effect for CRs that were able to propagate out as far as a few SNR radii.}, language = {en} } @article{TelezhinskyDwarkadasPohl2012, author = {Telezhinsky, Igor O. and Dwarkadas, Vikram V. and Pohl, Martin}, title = {Particle spectra from acceleration at forward and reverse shocks of young Type Ia Supernova Remnants}, series = {Astroparticle physics}, volume = {35}, journal = {Astroparticle physics}, number = {6}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0927-6505}, doi = {10.1016/j.astropartphys.2011.10.001}, pages = {300 -- 311}, year = {2012}, abstract = {We study cosmic-ray acceleration in young Type Ia Supernova Remnants (SNRs) by means of test-particle diffusive shock acceleration theory and 1-D hydrodynamical simulations of their evolution. In addition to acceleration at the forward shock, we explore the particle acceleration at the reverse shock in the presence of a possible substantial magnetic field, and consequently the impact of this acceleration on the particle spectra in the remnant. We investigate the time evolution of the spectra for various time-dependent profiles of the magnetic field in the shocked region of the remnant. We test a possible influence on particle spectra of the Alfvenic drift of scattering centers in the precursor regions of the shocks. In addition, we study the radiation spectra and morphology in a broad band from radio to gamma-rays. It is demonstrated that the reverse shock contribution to the cosmic-ray particle population of young Type la SNRs may be significant, modifying the spatial distribution of particles and noticeably affecting the volume-integrated particle spectra in young SNRs. In particular spectral structures may arise in test-particle calculations that are often discussed as signatures of non-linear cosmic-ray modification of shocks. Therefore, the spectrum and morphology of emission, and their time evolution, differ from pure forward-shock solutions.}, language = {en} } @article{SurlanHamannKubatetal.2012, author = {Surlan, B. and Hamann, Wolf-Rainer and Kubat, Jirij and Oskinova, Lida and Feldmeier, Achim}, title = {Three-dimensional radiative transfer in clumped hot star winds I influence of clumping on the resonance line formation}, series = {Astronomy and astrophysics : an international weekly journal}, volume = {541}, journal = {Astronomy and astrophysics : an international weekly journal}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {0004-6361}, doi = {10.1051/0004-6361/201118590}, pages = {11}, year = {2012}, abstract = {Context. The true mass-loss rates from massive stars are important for many branches of astrophysics. For the correct modeling of the resonance lines, which are among the key diagnostics of stellar mass-loss, the stellar wind clumping has been found to be very important. To incorporate clumping into a radiative transfer calculation, three-dimensional (3D) models are required. Various properties of the clumps may have a strong impact on the resonance line formation and, therefore, on the determination of empirical mass-loss rates. Aims. We incorporate the 3D nature of the stellar wind clumping into radiative transfer calculations and investigate how different model parameters influence the resonance line formation. Methods. We develop a full 3D Monte Carlo radiative transfer code for inhomogeneous expanding stellar winds. The number density of clumps follows the mass conservation. For the first time, we use realistic 3D models that describe the dense as well as the tenuous wind components to model the formation of resonance lines in a clumped stellar wind. At the same time, we account for non-monotonic velocity fields. Results. The 3D density and velocity wind inhomogeneities show that there is a very strong impact on the resonance line formation. The different parameters describing the clumping and the velocity field results in different line strengths and profiles. We present a set of representative models for various sets of model parameters and investigate how the resonance lines are affected. Our 3D models show that the line opacity is lower for a larger clump separation and shallower velocity gradients within the clumps. Conclusions. Our model demonstrates that to obtain empirically correct mass-loss rates from the UV resonance lines, the wind clumping and its 3D nature must be taken into account.}, language = {en} } @article{StromanPohlNiemiecetal.2012, author = {Stroman, Thomas and Pohl, Martin and Niemiec, Jacek and Bret, Antoine}, title = {Could cosmic rays affect instabilities in the Transition layer of nonrealativistic collisionless shocks?}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, volume = {746}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, number = {1}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0004-637X}, doi = {10.1088/0004-637X/746/1/24}, pages = {10}, year = {2012}, abstract = {There is an observational correlation between astrophysical shocks and nonthermal particle distributions extending to high energies. As a first step toward investigating the possible feedback of these particles on the shock at the microscopic level, we perform particle-in-cell (PIC) simulations of a simplified environment consisting of uniform, interpenetrating plasmas, both with and without an additional population of cosmic rays. We vary the relative density of the counterstreaming plasmas, the strength of a homogeneous parallel magnetic field, and the energy density in cosmic rays. We compare the early development of the unstable spectrum for selected configurations without cosmic rays to the growth rates predicted from linear theory, for assurance that the system is well represented by the PIC technique. Within the parameter space explored, we do not detect an unambiguous signature of any cosmic-ray-induced effects on the microscopic instabilities that govern the formation of a shock. We demonstrate that an overly coarse distribution of energetic particles can artificially alter the statistical noise that produces the perturbative seeds of instabilities, and that such effects can be mitigated by increasing the density of computational particles.}, language = {en} } @article{SteyrleuthnerSchubertHowardetal.2012, author = {Steyrleuthner, Robert and Schubert, Marcel and Howard, Ian and Klaum{\"u}nzer, Bastian and Schilling, Kristian and Chen, Zhihua and Saalfrank, Peter and Laquai, Frederic and Facchetti, Antonio and Neher, Dieter}, title = {Aggregation in a high-mobility n-type low-bandgap copolymer with implications on semicrystalline morphology}, series = {Journal of the American Chemical Society}, volume = {134}, journal = {Journal of the American Chemical Society}, number = {44}, publisher = {American Chemical Society}, address = {Washington}, issn = {0002-7863}, doi = {10.1021/ja306844f}, pages = {18303 -- 18317}, year = {2012}, abstract = {We explore the photophysics of P(NDI2OD-T2), a high-mobility and air-stable n-type donor/acceptor polymer. Detailed steady-state UV-vis and photoluminescence (PL) measurements on solutions of P(NDI2OD-T2) reveal distinct signatures of aggregation. By performing quantum chemical calculations, we can assign these spectral features to unaggregated and stacked polymer chains. NMR measurements independently confirm the aggregation phenomena of P(NDI2OD-T2) in solution. The detailed analysis of the optical spectra shows that aggregation is a two-step process with different types of aggregates, which we confirm by time-dependent PL measurements. Analytical ultracentrifugation measurements suggest that aggregation takes place within the single polymer chain upon coiling. By transferring these results to thin P(NDI2OD-T2) films, we can conclude that film formation is mainly governed by the chain collapse, leading in general to a high aggregate content of similar to 45\%. This process also inhibits the formation of amorphous and disordered P(NDI2OD-T2) films.}, language = {en} } @article{SereshkiLomholtMetzler2012, author = {Sereshki, L. E. and Lomholt, M. A. and Metzler, Ralf}, title = {A solution to the subdiffusion-efficiency paradox inactive states enhance reaction efficiency at subdiffusion conditions in living cells}, series = {epl : a letters journal exploring the frontiers of physics}, volume = {97}, journal = {epl : a letters journal exploring the frontiers of physics}, number = {2}, publisher = {EDP Sciences}, address = {Mulhouse}, issn = {0295-5075}, doi = {10.1209/0295-5075/97/20008}, pages = {6}, year = {2012}, abstract = {Macromolecular crowding in living biological cells effects subdiffusion of larger biomolecules such as proteins and enzymes. Mimicking this subdiffusion in terms of random walks on a critical percolation cluster, we here present a case study of EcoRV restriction enzymes involved in vital cellular defence. We show that due to its so far elusive propensity to an inactive state the enzyme avoids non-specific binding and remains well-distributed in the bulk cytoplasm of the cell. Despite the reduced volume exploration capability of subdiffusion processes, this mechanism guarantees a high efficiency of the enzyme. By variation of the non-specific binding constant and the bond occupation probability on the percolation network, we demonstrate that reduced nonspecific binding are beneficial for efficient subdiffusive enzyme activity even in relatively small bacteria cells. Our results corroborate a more local picture of cellular regulation.}, language = {en} } @article{SendAbboudLeitenbergeretal.2012, author = {Send, Sebastian and Abboud, Ali and Leitenberger, Wolfram and Weiss, Manfred S. and Hartmann, Robert and Str{\"u}der, Lothar and Pietsch, Ullrich}, title = {Analysis of polycrystallinity in hen egg-white lysozyme using a pnCCD}, series = {Journal of applied crystallography}, volume = {45}, journal = {Journal of applied crystallography}, number = {6}, publisher = {Wiley-Blackwell}, address = {Hoboken}, issn = {0021-8898}, doi = {10.1107/S0021889812015038}, pages = {517 -- 522}, year = {2012}, abstract = {A crystal of hen egg-white lysozyme was analyzed by means of energy-dispersive X-ray Laue diffraction with white synchrotron radiation at 2.7 angstrom resolution using a pnCCD detector. From Laue spots measured in a single exposure of the arbitrarily oriented crystal, the lattice constants of the tetragonal unit cell could be extracted with an accuracy of about 2.5\%. Scanning across the sample surface, Laue images with split reflections were recorded at various positions. The corresponding diffraction patterns were generated by two crystalline domains with a tilt of about 1 degrees relative to each other. The obtained results demonstrate the potential of the pnCCD for fast X-ray screening of crystals of macromolecules or proteins prior to conventional X-ray structure analysis. The described experiment can be automatized to quantitatively characterize imperfect single crystals or polycrystals.}, language = {en} } @article{SeemuellerMuellerRoesler2012, author = {Seem{\"u}ller, Anna and M{\"u}ller, E. M. and R{\"o}sler, Frank}, title = {EEG-power and -coherence changes in a unimodal and a crossmodal working memory task with visual and kinesthetic stimuli}, series = {International journal of psychophysiology}, volume = {83}, journal = {International journal of psychophysiology}, number = {1}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0167-8760}, doi = {10.1016/j.ijpsycho.2011.10.009}, pages = {87 -- 95}, year = {2012}, abstract = {We investigated EEG-power and EEG-coherence changes in a unimodal and a crossmodal matching-to-sample working memory task with either visual or kinesthetic stimuli. Angle-shaped trajectories were used as stimuli presented either as a moving dot on a screen or as a passive movement of a haptic device. Effects were evaluated during the different phases of encoding, maintenance, and recognition. Alpha power was modulated during encoding by the stimulus modality, and in crossmodal conditions during encoding and maintenance by the expected modality of the upcoming test stimulus. These power modulations were observed over modality-specific cortex regions. Systematic changes of coherence for crossmodal compared to unimodal tasks were not observed during encoding and maintenance but only during recognition. There, coherence in the theta-band increased between electrode sites over left central and occipital cortex areas in the crossmodal compared to the unimodal conditions. The results underline the importance of modality-specific representations and processes in unimodal and crossmodal working memory tasks. Crossmodal recognition of visually and kinesthetically presented object features seems to be related to a direct interaction of somatosensory/motor and visual cortex regions by means of long-range synchronization in the theta-band and such interactions seem to take place at the beginning of the recognition phase, i.e. when crossmodal transfer is actually necessary.}, language = {en} } @article{SchwabedalPikovskijKralemannetal.2012, author = {Schwabedal, Justus T. C. and Pikovskij, Arkadij and Kralemann, Bj{\"o}rn and Rosenblum, Michael}, title = {Optimal phase description of chaotic oscillators}, series = {Physical review : E, Statistical, nonlinear and soft matter physics}, volume = {85}, journal = {Physical review : E, Statistical, nonlinear and soft matter physics}, number = {2}, publisher = {American Physical Society}, address = {College Park}, issn = {1539-3755}, doi = {10.1103/PhysRevE.85.026216}, pages = {9}, year = {2012}, abstract = {We introduce an optimal phase description of chaotic oscillations by generalizing the concept of isochrones. On chaotic attractors possessing a general phase description, we define the optimal isophases as Poincare surfaces showing return times as constant as possible. The dynamics of the resultant optimal phase is maximally decoupled from the amplitude dynamics and provides a proper description of the phase response of chaotic oscillations. The method is illustrated with the Rossler and Lorenz systems.}, language = {en} } @article{SchubertDolfenFrischetal.2012, author = {Schubert, Marcel and Dolfen, Daniel and Frisch, Johannes and Roland, Steffen and Steyrleuthner, Robert and Stiller, Burkhard and Chen, Zhihua and Scherf, Ullrich and Koch, Norbert and Facchetti, Antonio and Neher, Dieter}, title = {Influence of aggregation on the performance of All-Polymer Solar Cells containing Low-Bandgap Naphthalenediimide Copolymers}, series = {dvanced energy materials}, volume = {2}, journal = {dvanced energy materials}, number = {3}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {1614-6832}, doi = {10.1002/aenm.201100601}, pages = {369 -- 380}, year = {2012}, abstract = {The authors present efficient all-polymer solar cells comprising two different low-bandgap naphthalenediimide (NDI)-based copolymers as acceptors and regioregular P3HT as the donor. It is shown that these naphthalene copolymers have a strong tendency to preaggregate in specific organic solvents, and that preaggregation can be completely suppressed when using suitable solvents with large and highly polarizable aromatic cores. Organic solar cells prepared from such nonaggregated polymer solutions show dramatically increased power conversion efficiencies of up to 1.4\%, which is mainly due to a large increase of the short circuit current. In addition, optimized solar cells show remarkable high fill factors of up to 70\%. The analysis of the blend absorbance spectra reveals a surprising anticorrelation between the degree of polymer aggregation in the solid P3HT:NDI copolymer blends and their photovoltaic performance. Scanning near-field optical microscopy (SNOM) and atomic force microscopy (AFM) measurements reveal important information on the blend morphology. It is shown that films with high degree of aggregation and low photocurrents exhibit large-scale phase-separation into rather pure donor and acceptor domains. It is proposed that, by suppressing the aggregation of NDI copolymers at the early stage of film formation, the intermixing of the donor and acceptor component is improved, thereby allowing efficient harvesting of photogenerated excitons at the donoracceptor heterojunction.}, language = {en} } @article{SchneidervonDeimlingMeinshausenLevermannetal.2012, author = {Schneider von Deimling, Thomas and Meinshausen, Malte and Levermann, Anders and Huber, Veronika and Frieler, Katja and Lawrence, D. M. and Brovkin, Victor}, title = {Estimating the near-surface permafrost-carbon feedback on global warming}, series = {Biogeosciences}, volume = {9}, journal = {Biogeosciences}, number = {2}, publisher = {Copernicus}, address = {G{\"o}ttingen}, issn = {1726-4170}, doi = {10.5194/bg-9-649-2012}, pages = {649 -- 665}, year = {2012}, abstract = {Thawing of permafrost and the associated release of carbon constitutes a positive feedback in the climate system, elevating the effect of anthropogenic GHG emissions on global-mean temperatures. Multiple factors have hindered the quantification of this feedback, which was not included in climate carbon-cycle models which participated in recent model intercomparisons (such as the Coupled Carbon Cycle Climate Model Intercomparison Project - (CMIP)-M-4). There are considerable uncertainties in the rate and extent of permafrost thaw, the hydrological and vegetation response to permafrost thaw, the decomposition timescales of freshly thawed organic material, the proportion of soil carbon that might be emitted as carbon dioxide via aerobic decomposition or as methane via anaerobic decomposition, and in the magnitude of the high latitude amplification of global warming that will drive permafrost degradation. Additionally, there are extensive and poorly characterized regional heterogeneities in soil properties, carbon content, and hydrology. Here, we couple a new permafrost module to a reduced complexity carbon-cycle climate model, which allows us to perform a large ensemble of simulations. The ensemble is designed to span the uncertainties listed above and thereby the results provide an estimate of the potential strength of the feedback from newly thawed permafrost carbon. For the high CO2 concentration scenario (RCP8.5), 33-114 GtC (giga tons of Carbon) are released by 2100 (68\% uncertainty range). This leads to an additional warming of 0.04-0.23 degrees C. Though projected 21st century permafrost carbon emissions are relatively modest, ongoing permafrost thaw and slow but steady soil carbon decomposition means that, by 2300, about half of the potentially vulnerable permafrost carbon stock in the upper 3 m of soil layer (600-1000 GtC) could be released as CO2, with an extra 1-4\% being released as methane. Our results also suggest that mitigation action in line with the lower scenario RCP3-PD could contain Arctic temperature increase sufficiently that thawing of the permafrost area is limited to 9-23\% and the permafrost-carbon induced temperature increase does not exceed 0.04-0.16 degrees C by 2300.}, language = {en} } @article{SchickBojahrHerzogetal.2012, author = {Schick, Daniel and Bojahr, Andre and Herzog, Marc and von Korff Schmising, Clemens and Shayduk, Roman and Leitenberger, Wolfram and Gaa, P. and Bargheer, Matias}, title = {Normalization schemes for ultrafast x-ray diffraction using a table-top laser-driven plasma source}, series = {Review of scientific instruments : a monthly journal devoted to scientific instruments, apparatus, and techniques}, volume = {83}, journal = {Review of scientific instruments : a monthly journal devoted to scientific instruments, apparatus, and techniques}, number = {2}, publisher = {American Institute of Physics}, address = {Melville}, issn = {0034-6748}, doi = {10.1063/1.3681254}, pages = {7}, year = {2012}, abstract = {We present an experimental setup of a laser-driven x-ray plasma source for femtosecond x-ray diffraction. Different normalization schemes accounting for x-ray source intensity fluctuations are discussed in detail. We apply these schemes to measure the temporal evolution of Bragg peak intensities of perovskite superlattices after ultrafast laser excitation.}, language = {en} } @article{ScheweLevermann2012, author = {Schewe, Jacob and Levermann, Anders}, title = {A statistically predictive model for future monsoon failure in India}, series = {Environmental research letters}, volume = {7}, journal = {Environmental research letters}, number = {4}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {1748-9326}, doi = {10.1088/1748-9326/7/4/044023}, pages = {9}, year = {2012}, abstract = {Indian monsoon rainfall is vital for a large share of the world's population. Both reliably projecting India's future precipitation and unraveling abrupt cessations of monsoon rainfall found in paleorecords require improved understanding of its stability properties. While details of monsoon circulations and the associated rainfall are complex, full-season failure is dominated by large-scale positive feedbacks within the region. Here we find that in a comprehensive climate model, monsoon failure is possible but very rare under pre-industrial conditions, while under future warming it becomes much more frequent. We identify the fundamental intraseasonal feedbacks that are responsible for monsoon failure in the climate model, relate these to observational data, and build a statistically predictive model for such failure. This model provides a simple dynamical explanation for future changes in the frequency distribution of seasonal mean all-Indian rainfall. Forced only by global mean temperature and the strength of the Pacific Walker circulation in spring, it reproduces the trend as well as the multidecadal variability in the mean and skewness of the distribution, as found in the climate model. The approach offers an alternative perspective on large-scale monsoon variability as the result of internal instabilities modulated by pre-seasonal ambient climate conditions.}, language = {en} } @article{SchattauerReinholdAlbrechtetal.2012, author = {Schattauer, Sylvia and Reinhold, Beate and Albrecht, Steve and Fahrenson, Christoph and Schubert, Marcel and Janietz, Silvia and Neher, Dieter}, title = {Influence of sintering on the structural and electronic properties of TiO2 nanoporous layers prepared via a non-sol-gel approach}, series = {Colloid and polymer science : official journal of the Kolloid-Gesellschaft}, volume = {290}, journal = {Colloid and polymer science : official journal of the Kolloid-Gesellschaft}, number = {18}, publisher = {Springer}, address = {New York}, issn = {0303-402X}, doi = {10.1007/s00396-012-2708-9}, pages = {1843 -- 1854}, year = {2012}, abstract = {In this work, a nonaqueous method is used to fabricate thin TiO2 layers. In contrast to the common aqueous sol-gel approach, our method yields layers of anatase nanocrystallites already at low temperature. Raman spectroscopy, electron microscopy and charge extraction by linearly increasing voltage are employed to study the effect of sintering temperature on the structural and electronic properties of the nanocrystalline TiO2 layer. Raising the sintering temperature from 120 to 600 A degrees C is found to alter the chemical composition, the layer's porosity and its surface but not the crystal phase. The room temperature mobility increases from 2 x 10(-6) to 3 x 10(-5) cm(2)/Vs when the sinter temperature is increased from 400 to 600 A degrees C, which is explained by a better interparticle connectivity. Solar cells comprising such nanoporous TiO2 layers and a soluble derivative of cyclohexylamino-poly(p-phenylene vinylene) were fabricated and studied with regard to their structural and photovoltaic properties. We found only weak polymer infiltration into the oxide layer for sintering temperatures up to 550 A degrees C, while the polymer penetrated deeply into titania layers that were sintered at 600 A degrees C. Best photovoltaic performance was reached with a nanoporous TiO2 film sintered at 550 A degrees C, which yielded a power conversion efficiency of 0.5 \%. Noticeably, samples with the TiO2 layer dried at 120 A degrees C displayed short-circuit currents and open circuit voltages only about 15-20 \% lower than for the most efficient devices, meaning that our nonaqueous route yields titania layers with reasonable transport properties even at low sintering temperatures.}, language = {en} } @article{ScharsichLohwasserSommeretal.2012, author = {Scharsich, Christina and Lohwasser, Ruth H. and Sommer, Michael and Asawapirom, Udom and Scherf, Ullrich and Thelakkat, Mukundan and Neher, Dieter and Koehler, Anna}, title = {Control of aggregate formation in poly(3-hexylthiophene) by solvent, molecular weight, and synthetic method}, series = {Journal of polymer science : B, Polymer physics}, volume = {50}, journal = {Journal of polymer science : B, Polymer physics}, number = {6}, publisher = {Wiley-Blackwell}, address = {Hoboken}, issn = {0887-6266}, doi = {10.1002/polb.23022}, pages = {442 -- 453}, year = {2012}, abstract = {Aggregate formation in poly(3-hexylthiophene) depends on molecular weight, solvent, and synthetic method. The interplay of these parameters thus largely controls device performance. In order to obtain a quantitative understanding on how these factors control the resulting electronic properties of P3HT, we measured absorption in solution and in thin films as well as the resulting field effect mobility in transistors. By a detailed analysis of the absorption spectra, we deduce the fraction of aggregates formed, the excitonic coupling within the aggregates, and the conjugation length within the aggregates, all as a function of solvent quality for molecular weights from 5 to 19 kDa. From this, we infer in which structure the aggregated chains pack. Although the 5 kDa samples form straight chains, the 11 and 19 kDa chains are kinked or folded, with conjugation lengths that increase as the solvent quality reduces. There is a maximum fraction of aggregated chains (about 55 +/- 5\%) that can be obtained, even for poor solvent quality. We show that inducing aggregation in solution leads to control of aggregate properties in thin films. As expected, the field-effect mobility correlates with the propensity to aggregation. Correspondingly, we find that a well-defined synthetic approach, tailored to give a narrow molecular weight distribution, is needed to obtain high field effect mobilities of up to 0.01 cm2/Vs for low molecular weight samples (=11 kDa), while the influence of synthetic method is negligible for samples of higher molecular weight, if low molecular weight fractions are removed by extraction.}, language = {en} } @article{SandevMetzlerTomovski2012, author = {Sandev, Trifce and Metzler, Ralf and Tomovski, Zivorad}, title = {Velocity and displacement correlation functions for fractional generalized Langevin equations}, series = {Fractional calculus and applied analysis : an international journal for theory and applications}, volume = {15}, journal = {Fractional calculus and applied analysis : an international journal for theory and applications}, number = {3}, publisher = {Versita}, address = {Warsaw}, issn = {1311-0454}, doi = {10.2478/s13540-012-0031-2}, pages = {426 -- 450}, year = {2012}, abstract = {We study analytically a generalized fractional Langevin equation. General formulas for calculation of variances and the mean square displacement are derived. Cases with a three parameter Mittag-Leffler frictional memory kernel are considered. Exact results in terms of the Mittag-Leffler type functions for the relaxation functions, average velocity and average particle displacement are obtained. The mean square displacement and variances are investigated analytically. Asymptotic behaviors of the particle in the short and long time limit are found. The model considered in this paper may be used for modeling anomalous diffusive processes in complex media including phenomena similar to single file diffusion or possible generalizations thereof. We show the importance of the initial conditions on the anomalous diffusive behavior of the particle.}, language = {en} } @article{SanderHamannTodt2012, author = {Sander, A. and Hamann, Wolf-Rainer and Todt, Helge Tobias}, title = {The Galactic WC stars Stellar parameters from spectral analyses indicate a new evolutionary sequence}, series = {Astronomy and astrophysics : an international weekly journal}, volume = {540}, journal = {Astronomy and astrophysics : an international weekly journal}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {0004-6361}, doi = {10.1051/0004-6361/201117830}, pages = {79}, year = {2012}, abstract = {Context. The life cycles of massive stars from the main sequence to their explosion as supernovae or gamma ray bursts are not yet fully clear, and the empirical results from spectral analyses are partly in conflict with current evolutionary models. The spectral analysis of Wolf-Rayet stars requires the detailed modeling of expanding stellar atmospheres in non-LTE. The Galactic WN stars have been comprehensively analyzed with such models of the latest stage of sophistication, while a similarly comprehensive study of the Galactic WC sample remains undone. Aims. We aim to establish the stellar parameters and mass-loss rates of the Galactic WC stars. These data provide the empirical basis of studies of (i) the role of WC stars in the evolution of massive stars, (ii) the wind-driving mechanisms, and (iii) the feedback of WC stars as input to models of the chemical and dynamical evolution of galaxies. Methods. We analyze the nearly complete sample of un-obscured Galactic WC stars, using optical spectra as well as ultraviolet spectra when available. The observations are fitted with theoretical spectra, using the Potsdam Wolf-Rayet (PoWR) model atmosphere code. A large grid of line-blanked models has been established for the range of WC subtypes WC4 - WC8, and smaller grids for the WC9 parameter domain. Both WO stars and WN/WC transit types are also analyzed using special models. Results. Stellar and atmospheric parameters are derived for more than 50 Galactic WC and two WO stars, covering almost the whole Galactic WC population as far as the stars are single, and un-obscured in the visual. In the Hertzsprung-Russell diagram, the WC stars reside between the hydrogen and the helium zero-age main sequences, having luminosities L from 10(4.9) to 10(5.6) L-circle dot. The mass-loss rates scale very tightly with L-0.8. The two WO stars in our sample turn out to be outstandingly hot (approximate to 200 kK) and do not fit into the WC scheme. Conclusions. By comparing the empirical WC positions in the Hertzsprung-Russell diagram with evolutionary models, and from recent supernova statistics, we conclude that WC stars have evolved from initial masses between 20 solar masses and 45 M-circle dot. In contrast to previous assumptions, it seems that WC stars in general do not descend from the most massive stars. Only the WO stars might stem from progenitors that have been initially more massive than 45 M-circle dot.}, language = {en} } @article{SalzmannHeimelDuhmetal.2012, author = {Salzmann, Ingo and Heimel, Georg and Duhm, Steffen and Oehzelt, Martin and Pingel, Patrick and George, Benjamin M. and Schnegg, Alexander and Lips, Klaus and Blum, Ralf-Peter and Vollmer, Antje and Koch, Norbert}, title = {Intermolecular hybridization governs molecular electrical doping}, series = {Physical review letters}, volume = {108}, journal = {Physical review letters}, number = {3}, publisher = {American Physical Society}, address = {College Park}, issn = {0031-9007}, doi = {10.1103/PhysRevLett.108.035502}, pages = {5}, year = {2012}, abstract = {Current models for molecular electrical doping of organic semiconductors are found to be at odds with other well-established concepts in that field, like polaron formation. Addressing these inconsistencies for prototypical systems, we present experimental and theoretical evidence for intermolecular hybridization of organic semiconductor and dopant frontier molecular orbitals. Common doping-related observations are attributed to this phenomenon, and controlling the degree of hybridization emerges as a strategy for overcoming the present limitations in the yield of doping-induced charge carriers.}, language = {en} } @article{RychkovYablokovRychkov2012, author = {Rychkov, Dmitry and Yablokov, M. and Rychkov, A.}, title = {Chemical and physical surface modification of PTFE films-an approach to produce stable electrets}, series = {Applied physics : A, Materials science \& processing}, volume = {107}, journal = {Applied physics : A, Materials science \& processing}, number = {3}, publisher = {Springer}, address = {New York}, issn = {0947-8396}, doi = {10.1007/s00339-012-6834-5}, pages = {589 -- 596}, year = {2012}, abstract = {The thermal stability of positive charge has been investigated in chemically and physically treated polytetrafluoroethylene (PTFE) films. It has been found that virgin films, oriented by the manufacturer, display an increase in thermal stability of positive charge with an increase of the initial value of surface potential. Such an anomalous behavior is explained by the influence of a negative tribocharge, trapped some small distance below the surface. In PTFE samples treated with orthophosphoric acid and with tetraethoxysilane, a considerable improvement of positive charge stability has been achieved, but no influence of the initial value of surface potential has been observed. However, this influence should be kept in mind when comparing charge stability in virgin and modified samples. In nonoriented PTFE films, no influence of the initial value of surface potential on charge stability has been observed. This could be due to the fact that these films did not possess a noticeable negative tribocharge. After the treatment in glow-discharge defluorination, oxidation and appearance of polar groups have been detected on the surface. These changes in chemical composition of a PTFE surface resulted in a noticeable improvement in thermal stability of positively charged electrets. This improvement is attributed to the formation of deeper traps on the modified surface.}, language = {en} } @article{RychkovGerhardIvanovetal.2012, author = {Rychkov, Dmitry and Gerhard, Reimund and Ivanov, Vadim and Rychkov, Andrey}, title = {Enhanced electret charge stability on Polyethylene Films treated with Titanium-Tetrachloride vapor}, series = {IEEE transactions on dielectrics and electrical insulation}, volume = {19}, journal = {IEEE transactions on dielectrics and electrical insulation}, number = {4}, publisher = {Inst. of Electr. and Electronics Engineers}, address = {Piscataway}, issn = {1070-9878}, pages = {1305 -- 1311}, year = {2012}, abstract = {Low-density polyethylene (LDPE) films have been treated with titanium-tetrachloride vapor by means of the molecular-layer-deposition method. It is shown that such a treatment leads to a considerable improvement of the electret properties for both positively and negatively charged films. The temperature stability of the electret homo-charge has been increased by approximately 60 degrees C. At the same time, the temporal stability of charge is also considerably improved. Modified low-density polyethylene films show no "cross-over phenomenon" when charged to higher voltages. Thus, it is now possible to produce electrets from polyethylene films with high initial charge densities, but without a strongly reduced charge stability. The influence of a chemical treatment with titanium-tetrachloride vapor on charge injection from aluminum electrodes into polyethylene films was also investigated. It is found that the interface between an aluminum electrode and a modified LDPE surface layer has different injection properties for positive and negative charges. Electrons can be injected across the modified interface, whereas injection of holes is either very limited or non-existent.}, language = {en} } @article{RychkovAltafimQiuetal.2012, author = {Rychkov, Dmitry and Altafim, Ruy Alberto Pisani and Qiu, Xunlin and Gerhard, Reimund}, title = {Treatment with orthophosphoric acid enhances the thermal stability of the piezoelectricity in low-density polyethylene ferroelectrets}, series = {Journal of applied physics}, volume = {111}, journal = {Journal of applied physics}, number = {12}, publisher = {American Institute of Physics}, address = {Melville}, issn = {0021-8979}, doi = {10.1063/1.4729866}, pages = {5}, year = {2012}, abstract = {Ferroelectrets have been fabricated from low-density polyethylene (LDPE) films by means of a template-based lamination. The temperature dependence of the piezoelectric d(33) coefficient has been investigated. It was found that low-density polyethylene ferroelectrets have rather low thermal stability with the piezoelectric coefficient decaying almost to zero already at 100 degrees C. This behavior is attributed to the poor electret properties of the polyethylene films used for the fabrication of the ferroelectrets. In order to improve the charge trapping and the thermal stability of electret charge and piezoelectricity, LDPE ferroelectrets were treated with orthophosphoric acid. The treatment resulted in considerable improvements of the charge stability in LDPE films and in ferroelectret systems made from them. For example, the charge and piezoelectric-coefficient decay curves shifted to higher temperatures by 60 K and 40 K, respectively. It is shown that the decay of the piezoelectric coefficient in LDPE ferroelectrets is governed by the relaxation of less stable positive charges. The treatment also leads to noticeable changes in the chemical composition of the LDPE surface. Infrared spectroscopy reveals absorption bands attributed to phosphorus-containing structures, while scanning electron microscopy shows new island-like structures, 50-200 nm in diameter, on the modified surface.}, language = {en} } @article{RusconiVallerianiDunlopetal.2012, author = {Rusconi, Marco and Valleriani, Angelo and Dunlop, John William Chapman and Kurths, J{\"u}rgen and Weinkamer, Richard}, title = {Quantitative approach to the stochastics of bone remodeling}, series = {epl : a letters journal exploring the frontiers of physics}, volume = {97}, journal = {epl : a letters journal exploring the frontiers of physics}, number = {2}, publisher = {EDP Sciences}, address = {Mulhouse}, issn = {0295-5075}, doi = {10.1209/0295-5075/97/28009}, pages = {6}, year = {2012}, abstract = {During life bones constantly adapt their structure to their mechanical environment via a mechanically controlled process called bone remodeling. For trabecular bone, this process modifies the thickness of each trabecula leading occasionally to full resorption. We describe the irreversible dynamics of the trabecular thickness distribution (TTD) by means of a Markov chain discrete in space and time. By using thickness data from adult patients, we derive the transition probabilities in the chain. This allows a quantification, in terms of geometrical quantities, of the control of bone remodeling and thus to determine the evolution of the TTD with age.}, language = {en} } @article{RoyPikovskij2012, author = {Roy, S. and Pikovskij, Arkadij}, title = {Spreading of energy in the Ding-Dong model}, series = {Chaos : an interdisciplinary journal of nonlinear science}, volume = {22}, journal = {Chaos : an interdisciplinary journal of nonlinear science}, number = {2}, publisher = {American Institute of Physics}, address = {Melville}, issn = {1054-1500}, doi = {10.1063/1.3695369}, pages = {7}, year = {2012}, abstract = {We study the properties of energy spreading in a lattice of elastically colliding harmonic oscillators (Ding-Dong model). We demonstrate that in the regular lattice the spreading from a localized initial state is mediated by compactons and chaotic breathers. In a disordered lattice, the compactons do not exist, and the spreading eventually stops, resulting in a finite configuration with a few chaotic spots.}, language = {en} } @article{RisseKussmaulKruegeretal.2012, author = {Risse, Sebastian and Kussmaul, Bj{\"o}rn and Kr{\"u}ger, Hartmut and Kofod, Guggi}, title = {A versatile method for enhancement of electromechanical sensitivity of silicone elastomers}, series = {RSC Advances}, volume = {2}, journal = {RSC Advances}, number = {24}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {2046-2069}, doi = {10.1039/c2ra21541a}, pages = {9029 -- 9035}, year = {2012}, abstract = {Dielectric elastomer actuators (DEAs) draw their function from their dielectric and mechanical properties. The paper describes the fabrication and various properties of molecularly grafted silicone elastomer films. This was achieved by addition of high-dipole molecular co-substituents to off-the-shelf silicone elastomer kits, Elastosil RT 625 and Sylgard 184 by Wacker and Dow Corning, respectively. Strong push-pull dipoles were chemically grafted to both polymer networks during a one step film formation process. All manufactured films were characterized using (13) C-NMR and FT-IR spectroscopy, confirming a successful attachment of the dipoles to the silicone network. Differential scanning calorimetry (DSC) results showed that grafted dipoles were distributed homogeneously throughout the material avoiding the formation of nano-scale aggregates. The permittivity increased with the amount of dipole at all frequencies, while the Young's modulus and electrical breakdown strength were reduced. Actuation strain measurements in the pure shear configuration independently confirmed the increase in electromechanical sensitivity. The ability to enhance electromechanical properties of off-the-shelf materials could strongly expand the range of actuator properties available to researchers and end-users.}, language = {en} } @article{RisseKussmaulKruegeretal.2012, author = {Risse, Sebastian and Kussmaul, Bjoern and Kr{\"u}ger, Hartmut and Kofod, Guggi}, title = {Synergistic improvement of actuation properties with compatibilized high permittivity filler}, series = {Advanced functional materials}, volume = {22}, journal = {Advanced functional materials}, number = {18}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {1616-301X}, doi = {10.1002/adfm.201200320}, pages = {3958 -- 3962}, year = {2012}, abstract = {Electroactive polymers can be used for actuators with many desirable features, including high electromechanical energy density, low weight, compactness, direct voltage control, and complete silence during actuation. These features may enable personalized robotics with much higher ability to delicately manipulate their surroundings than can be achieved with currently available actuators; however, much work is still necessary to enhance the electroactive materials. Electric field-driven actuator materials are improved by an increase in permittivity and by a reduction in stiffness. Here, a synergistic enhancement method based on a macromolecular plasticizing filler molecule with a combination of both high dipole moment and compatibilizer moieties, synthesized to simultaneously ensure improvement of electromechanical properties and compatibility with the host matrix is presented. Measurements show an 85\% increase in permittivity combined with 290\% reduction in mechanical stiffness. NMR measurements confirm the structure of the filler while DSC measurements confirm that it is compatible with the host matrix at all the mixture ratios investigated. Actuation strain measurements in the pure shear configuration display an increase in sensitivity to the electrical field of more than 450\%, confirming that the filler molecule does not only improve dielectric and mechanical properties, it also leads to a synergistic enhancement of actuation properties by simple means.}, language = {en} } @article{RieraGogolinEisert2012, author = {Riera, Arnau and Gogolin, Christian and Eisert, Jens}, title = {Thermalization in nature and on a quantum computer}, series = {Physical review letters}, volume = {108}, journal = {Physical review letters}, number = {8}, publisher = {American Physical Society}, address = {College Park}, issn = {0031-9007}, doi = {10.1103/PhysRevLett.108.080402}, pages = {5}, year = {2012}, abstract = {In this work, we show how Gibbs or thermal states appear dynamically in closed quantum many-body systems, building on the program of dynamical typicality. We introduce a novel perturbation theorem for physically relevant weak system-bath couplings that is applicable even in the thermodynamic limit. We identify conditions under which thermalization happens and discuss the underlying physics. Based on these results, we also present a fully general quantum algorithm for preparing Gibbs states on a quantum computer with a certified runtime and error bound. This complements quantum Metropolis algorithms, which are expected to be efficient but have no known runtime estimates and only work for local Hamiltonians.}, language = {en} } @article{Richter2012, author = {Richter, Philipp}, title = {Cold gas accretion by high-velocity clouds and their connection to QSO Absorption-line systems}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, volume = {750}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, number = {2}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0004-637X}, doi = {10.1088/0004-637X/750/2/165}, pages = {11}, year = {2012}, abstract = {We combine H I 21 cm observations of the Milky Way, M31, and the local galaxy population with QSO absorption-line measurements to geometrically model the three-dimensional distribution of infalling neutral-gas clouds ("high-velocity clouds" (HVCs)) in the extended halos of low-redshift galaxies. We demonstrate that the observed distribution of HVCs around the Milky Way and M31 can be modeled by a radial exponential decline of the mean H I volume-filling factor in their halos. Our model suggests a characteristic radial extent of HVCs of R-halo similar to 50 kpc, a total H I mass in HVCs of similar to 10(8) M-circle dot, and a neutral-gas accretion rate of similar to 0.7 M-circle dot yr(-1) for M31/Milky-Way-type galaxies. Using a Holmberg-like luminosity scaling of the halo size of galaxies we estimate R-halo similar to 110 kpc for the most massive galaxies. The total absorption cross-section of HVCs at z approximate to 0 most likely is dominated by galaxies with total H I masses between 10(8.5) and 10(10) M-circle dot. Our model indicates that the H I disks of galaxies and their surrounding HVC population can account for 30\%-100\% of intervening QSO absorption-line systems with log N(H I) >= 17.5 at z approximate to 0. We estimate that the neutral-gas accretion rate density of galaxies at low redshift from infalling HVCs is dM(H) (I)/dt/dV approximate to 0.022 M-circle dot yr(-1) Mpc(-3), which is close to the measured star formation rate density in the local universe. HVCs thus may play an important role in the ongoing formation and evolution of galaxies.}, language = {en} } @article{RettigPohl2012, author = {Rettig, R. and Pohl, M.}, title = {The properties of non-thermal X-ray filaments in young supernova remnants}, series = {Astronomy and astrophysics : an international weekly journal}, volume = {545}, journal = {Astronomy and astrophysics : an international weekly journal}, number = {5}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {0004-6361}, doi = {10.1051/0004-6361/201219409}, pages = {9}, year = {2012}, abstract = {Context. Young supernova remnants (SNRs) exhibit narrow filaments of non-thermal X-ray emission whose widths can be limited either by electron energy losses or damping of the magnetic field. Aims. We want to investigate whether or not different models of these filaments can be observationally tested. Methods. Using observational parameters of four historical remnants, we calculated the filament profiles and compared the spectra of the filaments with those of the total non-thermal emission. For that purpose, we solved a one-dimensional stationary transport equation for the isotropic differential number density of the electrons. Results. We find that the difference between the spectra of filament and total non-thermal emission above 1 keV is more pronounced in the damping model than in the energy-loss model. Conclusions. A considerable damping of the magnetic field can result in an observable difference between the spectra of filament and total non-thermal emission, thus potentially permitting an observational discrimination between the energy-loss model and the damping model of the X-ray filaments.}, language = {en} } @article{PingelSchwarzlNeher2012, author = {Pingel, P. and Schwarzl, R. and Neher, Dieter}, title = {Effect of molecular p-doping on hole density and mobility in poly(3-hexylthiophene)}, series = {Applied physics letters}, volume = {100}, journal = {Applied physics letters}, number = {14}, publisher = {American Institute of Physics}, address = {Melville}, issn = {0003-6951}, doi = {10.1063/1.3701729}, pages = {3}, year = {2012}, abstract = {Employing impedance spectroscopy, we have studied the hole density, conductivity, and mobility of poly(3-hexylthiophene), P3HT, doped with the strong molecular acceptor tetrafluorotetracyanoquinodimethane, F(4)TCNQ. We find that the hole density increases linearly with the F(4)TCNQ concentration. Furthermore, the hole mobility is decreased upon doping at low-to-medium doping level, which is rationalized by an analytic model of carrier mobility in doped organic semiconductors [V. I. Arkhipov, E. V. Emelianova, P. Heremans, and H. Bassler, Phys. Rev. B 72, 235202 (2005)]. We infer that the presence of ionized F(4)TCNQ molecules in the P3HT layer increases energetic disorder, which diminishes the carrier mobility.}, language = {en} }