@article{SieberYaxleyHermann2020,
  author    = {Sieber, Melanie Jutta and Yaxley, Gregory M. and Hermann, J{\"o}rg},
  title     = {Investigation of fluid-driven carbonation of a hydrated, forearc mantle wedge using serpentinite cores in high-pressure experiments},
  series = {Journal of petrology},
  volume    = {61},
  journal   = {Journal of petrology},
  number    = {3},
  publisher = {Oxford Univ. Press},
  address   = {Oxford},
  issn      = {0022-3530},
  doi       = {10.1093/petrology/egaa035},
  pages     = {24},
  year      = {2020},
  abstract  = {High-pressure experiments were performed to investigate the effectiveness, rate and mechanism of carbonation of serpentinites by a carbon-saturated COH fluid at 1.5-2.5 GPa and 375-700 degrees C. This allows a better understanding of the fate and redistribution of slab-derived carbonic fluids when they react with the partially hydrated mantle within and above the subducting slab under pressure and temperature conditions corresponding to the forearc mantle. Interactions between carbon-saturated CO2-H2O-CH4 fluids and serpentinite were investigated using natural serpentinite cylinders with natural grain sizes and shapes in piston-cylinder experiments. The volatile composition of post-run fluids was quantified by gas chromatography. Solid phases were examined by Raman spectroscopy, electron microscopy and laser ablation inductively coupled plasma mass spectrometry. Textures, porosity and phase abundances of recovered rock cores were visualized and quantified by three-dimensional, high-resolution computed tomography. We find that carbonation of serpentinites is efficient at sequestering CO2 from the interacting fluid into newly formed magnesite. Time-series experiments demonstrate that carbonation is completed within similar to 96 h at 2 GPa and 600 degrees C. With decreasing CO2, aq antigorite is replaced first by magnesite + quartz followed by magnesite + talc + chlorite in distinct, metasomatic fronts. Above antigorite stability magnesite + enstatite + talc + chlorite occur additionally. The formation of fluid-permeable reaction zones enhances the reaction rate and efficiency of carbonation. Carbonation probably occurs via an interface-coupled replacement process, whereby interconnected porosity is present within reaction zones after the experiment. Consequently, carbonation of serpentinites is self-promoting and efficient even if fluid flow is channelized into veins. We conclude that significant amounts of carbonates may accumulate, over time, in the hydrated forearc mantle.},
  language  = {en}
}
@article{SieberYaxleyHermann2022,
  author    = {Sieber, Melanie Jutta and Yaxley, Greg and Hermann, J{\"o}rg},
  title     = {COH-fluid induced metasomatism of peridotites in the forearc mantle},
  series = {Contributions to Mineralogy and Petrology},
  volume    = {177},
  journal   = {Contributions to Mineralogy and Petrology},
  number    = {4},
  publisher = {Springer},
  address   = {New York},
  issn      = {0010-7999},
  doi       = {10.1007/s00410-022-01905-w},
  pages     = {22},
  year      = {2022},
  abstract  = {Devolatilization of subducting lithologies liberates COH-fluids. These may become partially sequestered in peridotites in the slab and the overlying forearc mantle, affecting the cycling of volatiles and fluid mobile elements in subduction zones. Here we assess the magnitudes, timescales and mechanism of channelized injection of COH-fluids doped with Ca-aq(2+), Sr-aq(2+) and Ba-aq(2+) into the dry forearc mantle by performing piston cylinder experiments between 1-2.5 GPa and 600-700 degrees C. Cylindrical cores of natural spinel-bearing harzburgites were used as starting materials. Based on mineral assemblage and composition three reaction zones are distinguishable from the rim towards the core of primary olivine and orthopyroxene grains. Zone 1 contains carbonates + quartz +/- kyanite and zone 2 contains carbonates + talc +/- chlorite. Olivine is further replaced in zone 3 by either antigorite+ magnesite or magnesite +talc within or above antigorite stability, respectively. Orthopyroxene is replaced in zone 3 by talc + chlorite. Mineral assemblages and the compositions of secondary minerals depend on fluid composition and the replaced primary silicate. The extent of alteration depends on fluid CO2 content and fluid/rock-ratio, and is further promoted by fluid permeable reaction zones and reaction driven cracking. Our results show that COH-fluid induced metasomatism of the forearc mantle is self-perpetuating and efficient at sequestering Ca-aq(2+), Sr-aq(2+), Ba-aq(2+) and CO2aq into newly formed carbonates. This process is fast with 90\% of the available C sequestered and nearly 50\% of the initial minerals altered at 650 degrees C, 2 GPa within 55 h. The dissolution of primary silicates under high COH-fluid/rock-ratios, as in channelized fluid flow, enriches SiO2aq in the fluid, while CO2aq is sequestered into carbonates. In an open system, the remaining CO2-depleted, Si-enriched aqueous fluid may cause Si-metasomatism in the forearc further away from the injection of the COH-fluid into peridotite.},
  language  = {en}
}
@article{SieberBrinkLeysetal.2020,
  author    = {Sieber, Melanie Jutta and Brink, Frank J. and Leys, Clyde and King, Penelope L. and Henley, Richard W.},
  title     = {Prograde and retrograde metasomatic reactions in mineralised magnesium- silicate skarn in the Cu-Au Ertsberg East Skarn System, Ertsberg, Papua Province, Indonesia},
  series = {Ore geology reviews},
  volume    = {125},
  journal   = {Ore geology reviews},
  publisher = {Elsevier},
  address   = {Amsterdam},
  issn      = {0169-1368},
  doi       = {10.1016/j.oregeorev.2020.103697},
  pages     = {14},
  year      = {2020},
  abstract  = {The 2.7-2.9 Ma Ertsberg East Skarn System (EESS) is a world-class Cu-Au skarn that formed within and adjacent to an intrusion within a paleodepth of 0.5 km and > 2.5 km. Its economic mineralisation developed by sustained reaction of magmatic fluid with contact metamorphosed siliciclastic and carbonate rocks at the margin of the adjacent Ertsberg quartz monzodiorite intrusion. Based on high-resolution mineral mapping, chemical analysis and thermodynamic calculations, the multistage formation processes of the exoskarn components of the EESS are examined in the context of changing pressure, temperature, fluid composition and fluid phase. We show that contact metamorphism of dolomitic sediments occurred at 51 +/- 5 MPa, between 700 degrees C and 800 degrees C and in the presence of a H2O-CO2-fluid containing similar to 10 to similar to 70 mol\% CO2. This prograde metamorphism formed a forsterite + diopside + calcite + phlogopite + spinel assemblage. Such forsterite-dominated skarns account for similar to 55 vol\% of the EESS exoskarns. Rare pargasite (previously unrecognized in this deposit) formed locally in the metamorphosed carbonate sequence where the protolith was composed of supratidal evaporites with dolomitic carbonate and interlayered calc-silicate rocks. The subsequent flux of a lower pressure magmatic gas containing SO2(g) caused sulphate metasomatism. This high temperature gas alteration of the metamorphic assemblage also caused skarn Cu-Fe-sulphide mineralisation. The influx of a SO2 gas through fracture permeability occurred at a temperature between similar to 600 and 700 degrees C and caused calcite to be replaced by anhydrite, with the coupled release of H2S(g). This in-situ release of H2S(g) scavenged trace Cu from the gas phase to deposit Cu-Fe-sulphides, which make the economic value of the distinct. We demonstrate that the formation of metal sulphides within forsterite skarns of the Ertsberg East Skarn System required a minimum flux of similar to 1,050 Mt SO2(g) and show that volcanic degassing may have occurred over a time span of similar to 3,900 years. As the system waned, the ambient fluid resulted in partial retrograde serpentinization of olivine and diopside without carbonation, and at temperatures sufficiently high to preserve anhydrite.},
  language  = {en}
}