@article{ThomasKleinpeter2005, author = {Thomas, Steffen and Kleinpeter, Erich}, title = {A novel empirical approach for the structure elucidation of disilanes by empirical estimation of their Si-29 chemical shifts}, issn = {0022-2860}, year = {2005}, abstract = {In C-13 NMR spectroscopy, there are many empirical methods for fast and exact computation of C-13 chemical shifts; comparable procedures for Si-29 NMR chemical shifts are not existing or are older than 20 years. On basis of the largest database of Si-29 chemical shifts available, along this paper a relatively simple procedure for the similarly exact calculation of the Si-29 chemical shifts of disilanes (average margin of error ca. 3.7 ppm) is given. (c) 2005 Elsevier B.V. All rights reserved}, language = {en} }