@article{IntravaiaBehuninHenkeletal.2016, author = {Intravaia, F. and Behunin, R. O. and Henkel, Carsten and Busch, K. and Dalvit, D. A. R.}, title = {Non-Markovianity in atom-surface dispersion forces}, series = {Physical review : A, Atomic, molecular, and optical physics}, volume = {94}, journal = {Physical review : A, Atomic, molecular, and optical physics}, publisher = {American Physical Society}, address = {College Park}, issn = {2469-9926}, doi = {10.1103/PhysRevA.94.042114}, pages = {16}, year = {2016}, abstract = {We discuss the failure of the Markov approximation in the description of atom-surface fluctuation-induced interactions, both in equilibrium (Casimir-Polder forces) and out of equilibrium (quantum friction). Using general theoretical arguments, we show that the Markov approximation can lead to erroneous predictions of such phenomena with regard to both strength and functional dependencies on system parameters. In particular, we show that the long-time power-law tails of two-time dipole correlations and their corresponding low-frequency behavior, neglected in the Markovian limit, affect the prediction of the force. Our findings highlight the importance of non-Markovian effects in dispersion interactions.}, language = {en} } @article{IurchukSchickBranetal.2016, author = {Iurchuk, V. and Schick, D. and Bran, J. and Colson, D. and Forget, A. and Halley, D. and Koc, Azize and Reinhardt, Mathias and Kwamen, C. and Morley, N. A. and Bargheer, Matias and Viret, M. and Gumeniuk, R. and Schmerber, G. and Doudin, B. and Kundys, B.}, title = {Optical Writing of Magnetic Properties by Remanent Photostriction}, series = {Physical review letters}, volume = {117}, journal = {Physical review letters}, publisher = {American Physical Society}, address = {College Park}, issn = {0031-9007}, doi = {10.1103/PhysRevLett.117.107403}, pages = {5}, year = {2016}, abstract = {We present an optically induced remanent photostriction in BiFeO3, resulting from the photovoltaic effect, which is used to modify the ferromagnetism of Ni film in a hybrid BiFeO3/Ni structure. The 75\% change in coercivity in the Ni film is achieved via optical and nonvolatile control. This photoferromagnetic effect can be reversed by static or ac electric depolarization of BiFeO3. Hence, the strain dependent changes in magnetic properties are written optically, and erased electrically. Light-mediated straintronics is therefore a possible approach for low-power multistate control of magnetic elements relevant for memory and spintronic applications.}, language = {en} } @article{IvanovCioniBekkietal.2016, author = {Ivanov, Valentin D. and Cioni, Maria-Rosa L. and Bekki, Kenji and de Grijs, Richard and Emerson, Jim and Gibson, Brad K. and Kamath, Devika and van Loon, Jacco Th. and Piatti, Andres E. and For, Bi-Qing}, title = {New quasars behind the Magellanic Clouds. Spectroscopic confirmation of near-infrared selected candidates}, series = {Current biology}, volume = {588}, journal = {Current biology}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {1432-0746}, doi = {10.1051/0004-6361/201527398}, pages = {12}, year = {2016}, abstract = {Context. Quasi-stellar objects (quasars) located behind nearby galaxies provide an excellent absolute reference system for astrometric studies, but they are difficult to identify because of fore-and background contamination. Deep wide-field, high angular resolution surveys spanning the entire area of nearby galaxies are needed to obtain a complete census of such quasars. Aims. We embarked on a program to expand the quasar reference system behind the Large and the Small Magellanic Clouds, the Magellanic Bridge, and the Magellanic Stream that connects the Clouds with the Milky Way. Methods. Hundreds of quasar candidates were selected based on their near-infrared colors and variability properties from the ongoing public ESO VISTA Magellanic Clouds survey. A subset of 49 objects was followed up with optical spectroscopy. Results. We confirmed the quasar nature of 37 objects (34 new identifications): four are low redshift objects, three are probably stars, and the remaining three lack prominent spectral features for a secure classification. The bona fide quasars, identified from their broad emisison lines, are located as follows: 10 behind the LMC, 13 behind the SMC, and 14 behind the Bridge. The quasars span a redshift range from z similar to 0.5 to z similar to 4.1. Conclusions. Upon completion the VMC survey is expected to yield a total of similar to 1500 quasars with Y < 19.32 mag, J < 19.09 mag, and K-s < 18.04 mag.}, language = {en} } @article{JaphaZhouKeiletal.2016, author = {Japha, Yonathan and Zhou, Shuyu and Keil, Mark and Folman, Ron and Henkel, Carsten and Vardi, Amichay}, title = {Suppression and enhancement of decoherence in an atomic Josephson junction}, series = {NEW JOURNAL OF PHYSICS}, volume = {18}, journal = {NEW JOURNAL OF PHYSICS}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {1367-2630}, doi = {10.1088/1367-2630/18/5/055008}, pages = {22}, year = {2016}, abstract = {We investigate the role of interatomic interactions when a Bose gas, in a double-well potential with a finite tunneling probability (a 'Bose-Josephson junction'), is exposed to external noise. We examine the rate of decoherence of a system initially in its ground state with equal probability amplitudes in both sites. The noise may induce two kinds of effects: firstly, random shifts in the relative phase or number difference between the two wells and secondly, loss of atoms from the trap. The effects of induced phase fluctuations are mitigated by atom-atom interactions and tunneling, such that the dephasing rate may be suppressed by half its single-atom value. Random fluctuations may also be induced in the population difference between the wells, in which case atom-atom interactions considerably enhance the decoherence rate. A similar scenario is predicted for the case of atom loss, even if the loss rates from the two sites are equal. We find that if the initial state is number-squeezed due to interactions, then the loss process induces population fluctuations that reduce the coherence across the junction. We examine the parameters relevant for these effects in a typical atom chip device, using a simple model of the trapping potential, experimental data, and the theory of magnetic field fluctuations near metallic conductors. These results provide a framework for mapping the dynamical range of barriers engineered for specific applications and set the stage for more complex atom circuits ('atomtronics').}, language = {en} } @article{JeonJavanainenMartinezSearaetal.2016, author = {Jeon, Jae-Hyung and Javanainen, Matti and Martinez-Seara, Hector and Metzler, Ralf and Vattulainen, Ilpo}, title = {Protein Crowding in Lipid Bilayers Gives Rise to Non-Gaussian Anomalous Lateral Diffusion of Phospholipids and Proteins}, series = {Physical review : X, Expanding access}, volume = {6}, journal = {Physical review : X, Expanding access}, publisher = {American Physical Society}, address = {College Park}, issn = {2160-3308}, doi = {10.1103/PhysRevX.6.021006}, pages = {17}, year = {2016}, abstract = {Biomembranes are exceptionally crowded with proteins with typical protein-to-lipid ratios being around 1:50 - 1:100. Protein crowding has a decisive role in lateral membrane dynamics as shown by recent experimental and computational studies that have reported anomalous lateral diffusion of phospholipids and membrane proteins in crowded lipid membranes. Based on extensive simulations and stochastic modeling of the simulated trajectories, we here investigate in detail how increasing crowding by membrane proteins reshapes the stochastic characteristics of the anomalous lateral diffusion in lipid membranes. We observe that correlated Gaussian processes of the fractional Langevin equation type, identified as the stochastic mechanism behind lipid motion in noncrowded bilayer, no longer adequately describe the lipid and protein motion in crowded but otherwise identical membranes. It turns out that protein crowding gives rise to a multifractal, non-Gaussian, and spatiotemporally heterogeneous anomalous lateral diffusion on time scales from nanoseconds to, at least, tens of microseconds. Our investigation strongly suggests that the macromolecular complexity and spatiotemporal membrane heterogeneity in cellular membranes play critical roles in determining the stochastic nature of the lateral diffusion and, consequently, the associated dynamic phenomena within membranes. Clarifying the exact stochastic mechanism for various kinds of biological membranes is an important step towards a quantitative understanding of numerous intramembrane dynamic phenomena.}, language = {en} } @article{KamannHusserBrinchmannetal.2016, author = {Kamann, S. and Husser, T. -O. and Brinchmann, Jarle and Emsellem, E. and Weilbacher, Peter Michael and Wisotzki, Lutz and Wendt, Martin and Krajnovic, D. and Roth, M. M. and Bacon, Roland and Dreizler, S.}, title = {MUSE crowded field 3D spectroscopy of over 12 000 stars in the globular cluster NGC 6397}, series = {Tectonophysics : international journal of geotectonics and the geology and physics of the interior of the earth}, volume = {588}, journal = {Tectonophysics : international journal of geotectonics and the geology and physics of the interior of the earth}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {1432-0746}, doi = {10.1051/0004-6361/201527065}, pages = {12}, year = {2016}, abstract = {We present a detailed analysis of the kinematics of the Galactic globular cluster NGC 6397 based on more than similar to 18 000 spectra obtained with the novel integral field spectrograph MUSE. While NGC 6397 is often considered a core collapse cluster, our analysis suggests a flattening of the surface brightness profile at the smallest radii. Although it is among the nearest globular clusters, the low velocity dispersion of NGC 6397 of < 5 km s(-1) imposes heavy demands on the quality of the kinematical data. We show that despite its limited spectral resolution, MUSE reaches an accuracy of 1 km s(-1) in the analysis of stellar spectra. We find slight evidence for a rotational component in the cluster and the velocity dispersion profile that we obtain shows a mild central cusp. To investigate the nature of this feature, we calculate spherical Jeans models and compare these models to our kinematical data. This comparison shows that if a constant mass-to-light ratio is assumed, the addition of an intermediate-mass black hole with a mass of 600 M-circle dot brings the model predictions into agreement with our data, and therefore could be at the origin of the velocity dispersion profile. We further investigate cases with varying mass-to-light ratios and find that a compact dark stellar component can also explain our observations. However, such a component would closely resemble the black hole from the constant mass-to-light ratio models as this component must be confined to the central similar to 5 ' of the cluster and must have a similar mass. Independent constraints on the distribution of stellar remnants in the cluster or kinematic measurements at the highest possible spatial resolution should be able to distinguish the two alternatives.}, language = {en} } @article{KappelArnoldHaus2016, author = {Kappel, David and Arnold, Gabriele and Haus, Rainer}, title = {Multi-spectrum retrieval of Venus IR surface emissivity maps from VIRTIS/VEX nightside measurements at Themis Regio}, series = {Icarus : international journal of solar system studies}, volume = {265}, journal = {Icarus : international journal of solar system studies}, publisher = {Elsevier}, address = {San Diego}, issn = {0019-1035}, doi = {10.1016/j.icarus.2015.10.014}, pages = {42 -- 62}, year = {2016}, abstract = {Renormalized emissivity maps of Themis Regio at the three surface windows are determined from 64 measurement repetitions. Retrieval errors are estimated by a statistical evaluation of maps derived from various disjoint selections of spectra and using different assumptions on the interfering parameters. Double standard deviation errors for the three surface windows amount to 3\%, 8\%, and 4\%, respectively, allowing geologic interpretation. A comparison to results from an earlier error analysis based on synthetic spectra shows that unconsidered time variations of interfering atmospheric parameters are a major error source. Spatial variations of the 1.02 mu m surface emissivity of 20\% that correspond to the difference between unweathered granitic and basaltic rocks would be easily detectable, but such variations are ruled out for the studied target area. Emissivity anomalies of up to 8\% are detected at both 1.02 and 1.18 mu m. At present sensitivity, no anomalies are identified at 1.10 mu m, but anomalies exceeding the determined error level can be excluded. With single standard deviation significance, all three maps show interesting spatial emissivity variations. (C) 2015 Elsevier Inc. All rights reserved.}, language = {en} } @article{KegelesOriti2016, author = {Kegeles, Alexander and Oriti, Daniele}, title = {Generalized conservation laws in non-local field theories}, series = {Journal of physics : A, Mathematical and theoretical}, volume = {49}, journal = {Journal of physics : A, Mathematical and theoretical}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {1751-8113}, doi = {10.1088/1751-8113/49/13/135401}, pages = {119 -- 134}, year = {2016}, abstract = {We propose a geometrical treatment of symmetries in non-local field theories, where the non-locality is due to a lack of identification of field arguments in the action. We show that the existence of a symmetry of the action leads to a generalized conservation law, in which the usual conserved current acquires an additional non-local correction term, obtaining a generalization of the standard Noether theorem. We illustrate the general formalism by discussing the specific physical example of complex scalar field theory of the type describing the hydrodynamic approximation of Bose-Einstein condensates. We expect our analysis and results to be of particular interest for the group field theory formulation of quantum gravity.}, language = {en} } @article{KimShpritsBlake2016, author = {Kim, Kyung-Chan and Shprits, Yuri and Blake, J. Bernard}, title = {Fast injection of the relativistic electrons into the inner zone and the formation of the split-zone structure during the Bastille Day storm in July 2000}, series = {Journal of geophysical research : Space physics}, volume = {121}, journal = {Journal of geophysical research : Space physics}, publisher = {American Geophysical Union}, address = {Washington}, issn = {2169-9380}, doi = {10.1002/2015JA022072}, pages = {8329 -- 8342}, year = {2016}, abstract = {During the July 2000 geomagnetic storm, known as the Bastille Day storm, Solar, Anomalous, and Magnetospheric Particle Explorer (SAMPEX)/Heavy Ion Large Telescope (HILT) observed a strong injection of similar to 1MeV electrons into the slot region (L similar to 2.5) during the storm main phase. Then, during the following month, electrons were clearly seen diffusing inward down to L=2 and forming a pronounced split structure encompassing a narrow, newly formed slot region around L=3. SAMPEX observations are first compared with electron and proton observations on HEO-3 and NOAA-15 to validate that the observed unusual dynamics was not caused by proton contamination of the SAMPEX instrument. The time-dependent 3-D Versatile Electron Radiation Belt (VERB) simulation of 1MeV electron flux evolution is compared with the SAMPEX/HILT observations. The results show that the VERB code predicts overall time evolution of the observed split structure. The simulated split structure is produced by pitch angle scattering into the Earth atmosphere of similar to 1MeV electrons by plasmaspheric hiss.}, language = {en} } @article{KomarovBazhenov2016, author = {Komarov, Maxim and Bazhenov, Maxim}, title = {Linking dynamics of the inhibitory network to the input structure}, series = {Journal of computational neuroscience}, volume = {41}, journal = {Journal of computational neuroscience}, publisher = {Springer}, address = {Dordrecht}, issn = {0929-5313}, doi = {10.1007/s10827-016-0622-8}, pages = {367 -- 391}, year = {2016}, language = {en} } @article{KopyshevGalvinGenzeretal.2016, author = {Kopyshev, Alexey and Galvin, Casey J. and Genzer, Jan and Lomadze, Nino and Santer, Svetlana}, title = {Polymer brushes modified by photosensitive azobenzene containing polyamines}, series = {Polymer : the international journal for the science and technology of polymers}, volume = {98}, journal = {Polymer : the international journal for the science and technology of polymers}, publisher = {Elsevier}, address = {Oxford}, issn = {0032-3861}, doi = {10.1016/j.polymer.2016.03.050}, pages = {421 -- 428}, year = {2016}, abstract = {This paper describes a strategy for preparing photosensitive polymeric grafts on flat solid surfaces by loading diblock-copolymer or homopolymer brushes with cationic azobenzene-containing surfactants. In contrast to previous work, we utilize photosensitive surfactants that bear positively-charged polyamine head groups whose charge varies between 1(+) and 3(+). Poly(methylmethacrylate-b-methacrylic acid) (PMMA-b-PMAA) brushes were prepared by employing atom transfer radical polymerization, where the bottom poly(methyl methacrylate) block was grown first followed by the synthesis of t-butyl methacrylate block that after de-protection yielded poly(methacrylic acid). We used PMMA-b-PMAA brushes with constant grafting density and length of the PMMA block, and three different lengths of the PMAA block. The azobenzene-based surfactants attached only to the PMAA block. The degree of binding (i.e., the number of surfactant molecules per binding site on the brush backbone) of the surfactants to the brush depends strongly on the valence of the surfactant head-group; within the brushes the concentration of the surfactant carrying unit charge is larger than that of multivalent surfactants. We detect pronounced response of the brush topography on irradiation with UV interference pattern even at very low degree of binding (as small as 0.08) of multi-valence surfactant. Areas on the sample that receive the highest UV dose exhibit chain scission. By removing the ruptured chains from the substrate via good solvent, one uncovers a surface topographical relief grating, whose spatial arrangement follows the intensity distribution of the UV light on the sample during irradiation. Due to strong coupling of the multi-valence surfactants to the polymer brush, it was possible in some cases to completely remove the polyelectrolyte block from the PMMA layer. The application of multi-valence azobenzene surfactants for triggering brush photosensitive has important advantage over usage of surfactant with unit charge because relative to single-valence surfactants much lower concentrations of the multivalent surfactant are needed to achieve comparable response upon UV irradiation. (C) 2016 Elsevier Ltd. All rights reserved.}, language = {en} } @article{KopyshevGalvinPatiletal.2016, author = {Kopyshev, Alexey and Galvin, Casey J. and Patil, Rohan R. and Genzer, Jan and Lomadze, Nino and Feldmann, David and Zakrevski, Juri and Santer, Svetlana}, title = {Light-Induced Reversible Change of Roughness and Thickness of Photosensitive Polymer Brushes}, series = {Applied physics : A, Materials science \& processing}, volume = {8}, journal = {Applied physics : A, Materials science \& processing}, publisher = {American Chemical Society}, address = {Washington}, issn = {1944-8244}, doi = {10.1021/acsami.6b06881}, pages = {19175 -- 19184}, year = {2016}, abstract = {We investigate light-induced changes in thickness and roughness of photosensitive polymer brushes containing azobenzene cationic surfactants by atomic force microscopy (AFM) in real time during light irradiation. Because the cis-state of azobenzene unit requires more free volume than its trans counterpart, the UV light-induced expansion of polymer thin films associated with the trans-to-cis isomerism of azobenzene groups is expected to occur. This phenomenon is well documented in physisorbed polymer films containing azobenzene groups. In contrast, photosensitive polymer brushes show a decrease in thickness under UV irradiation. We have found that the azobenzene surfactants in their trans-state form aggregates within the brush. Under irradiation, the surfactants undergo photoisomerization to the cis-state, which is more hydrophilic. As a consequence, the aggregates within the brush are disrupted, and the polymer brush contracts. When subsequently irradiated with blue light the polymer brush thickness returns back to its initial value. This behavior is related to isomerization of the surfactant to the more hydrophobic trans-state and subsequent formation of surfactant aggregates within the polymer brush. The photomechanical function of the dry polymer brush, i.e., contraction and expansion, was found to be reversible with repeated irradiation cycles and requires only a few seconds for switching. In addition to the thickness change, the roughness of the brush also changes reversibly between a few Angstroms (blue light) and several nanometers (UV light). Photosensitive polymer brushes represent smart films with light responsive thickness and roughness that could be used for generating dynamic fluctuating surfaces, the function of which can be turned on and off in a controllable manner on a nanometer length scale.}, language = {en} } @article{KretschmerCoumouDongesetal.2016, author = {Kretschmer, Marlene and Coumou, Dim and Donges, Jonathan and Runge, Jakob}, title = {Using Causal Effect Networks to Analyze Different Arctic Drivers of Midlatitude Winter Circulation}, series = {Journal of climate}, volume = {29}, journal = {Journal of climate}, publisher = {American Meteorological Soc.}, address = {Boston}, issn = {0894-8755}, doi = {10.1175/JCLI-D-15-0654.1}, pages = {4069 -- 4081}, year = {2016}, abstract = {In recent years, the Northern Hemisphere midlatitudes have suffered from severe winters like the extreme 2012/13 winter in the eastern United States. These cold spells were linked to a meandering upper-tropospheric jet stream pattern and a negative Arctic Oscillation index (AO). However, the nature of the drivers behind these circulation patterns remains controversial. Various studies have proposed different mechanisms related to changes in the Arctic, most of them related to a reduction in sea ice concentrations or increasing Eurasian snow cover. Here, a novel type of time series analysis, called causal effect networks (CEN), based on graphical models is introduced to assess causal relationships and their time delays between different processes. The effect of different Arctic actors on winter circulation on weekly to monthly time scales is studied, and robust network patterns are found. Barents and Kara sea ice concentrations are detected to be important external drivers of the midlatitude circulation, influencing winter AO via tropospheric mechanisms and through processes involving the stratosphere. Eurasia snow cover is also detected to have a causal effect on sea level pressure in Asia, but its exact role on AO remains unclear. The CEN approach presented in this study overcomes some difficulties in interpreting correlation analyses, complements model experiments for testing hypotheses involving teleconnections, and can be used to assess their validity. The findings confirm that sea ice concentrations in autumn in the Barents and Kara Seas are an important driver of winter circulation in the midlatitudes.}, language = {en} } @article{KrollKernKubinetal.2016, author = {Kroll, Thomas and Kern, Jan and Kubin, Markus and Ratner, Daniel and Gul, Sheraz and Fuller, Franklin D. and L{\"o}chel, Heike and Krzywinski, Jacek and Lutman, Alberto and Ding, Yuantao and Dakovski, Georgi L. and Moeller, Stefan and Turner, Joshua J. and Alonso-Mori, Roberto and Nordlund, Dennis L. and Rehanek, Jens and Weniger, Christian and Firsov, Alexander and Brzhezinskaya, Maria and Chatterjee, Ruchira and Lassalle-Kaiser, Benedikt and Sierra, Raymond G. and Laksmono, Hartawan and Hill, Ethan and Borovik, Andrew S. and Erko, Alexei and F{\"o}hlisch, Alexander and Mitzner, Rolf and Yachandra, Vittal K. and Yano, Junko and Wernet, Philippe and Bergmann, Uwe}, title = {X-ray absorption spectroscopy using a self-seeded soft X-ray free-electron laser}, series = {Optics express : the international electronic journal of optics}, volume = {24}, journal = {Optics express : the international electronic journal of optics}, publisher = {Optical Society of America}, address = {Washington}, issn = {1094-4087}, doi = {10.1364/OE.24.022469}, pages = {22469 -- 22480}, year = {2016}, abstract = {X-ray free electron lasers (XFELs) enable unprecedented new ways to study the electronic structure and dynamics of transition metal systems. L-edge absorption spectroscopy is a powerful technique for such studies and the feasibility of this method at XFELs for solutions and solids has been demonstrated. However, the required x-ray bandwidth is an order of magnitude narrower than that of self-amplified spontaneous emission (SASE), and additional monochromatization is needed. Here we compare L-edge x-ray absorption spectroscopy (XAS) of a prototypical transition metal system based on monochromatizing the SASE radiation of the linac coherent light source (LCLS) with a new technique based on self-seeding of LCLS. We demonstrate how L-edge XAS can be performed using the self-seeding scheme without the need of an additional beam line monochromator. We show how the spectral shape and pulse energy depend on the undulator setup and how this affects the x-ray spectroscopy measurements. (C) 2016 Optical Society of America}, language = {en} } @article{KronbergRashevDalyetal.2016, author = {Kronberg, Elena A. and Rashev, M. V. and Daly, P. W. and Shprits, Yuri and Turner, D. L. and Drozdov, Alexander and Dobynde, M. and Kellerman, Adam C. and Fritz, T. A. and Pierrard, V. and Borremans, K. and Klecker, B. and Friedel, R.}, title = {Contamination in electron observations of the silicon detector on board}, series = {Space Weather: The International Journal of Research and Applications}, volume = {14}, journal = {Space Weather: The International Journal of Research and Applications}, publisher = {American Geophysical Union}, address = {Washington}, issn = {1542-7390}, doi = {10.1002/2016SW001369}, pages = {449 -- 462}, year = {2016}, abstract = {Since more than 15 years, the Cluster mission passes through Earth's radiation belts at least once every 2 days for several hours, measuring the electron intensity at energies from 30 to 400 keV. These data have previously been considered not usable due to contamination caused by penetrating energetic particles (protons at >100 keV and electrons at >400 keV). In this study, we assess the level of distortion of energetic electron spectra from the Research with Adaptive Particle Imaging Detector (RAPID)/Imaging Electron Spectrometer (IES) detector, determining the efficiency of its shielding. We base our assessment on the analysis of experimental data and a radiation transport code (Geant4). In simulations, we use the incident particle energy distribution of the AE9/AP9 radiation belt models. We identify the Roederer L values, L\&\#8902;, and energy channels that should be used with caution: at 3\&\#8804;L\&\#8902;\&\#8804;4, all energy channels (40-400 keV) are contaminated by protons (\&\#8771;230 to 630 keV and >600 MeV); at L\&\#8902;\&\#8771;1 and 4-6, the energy channels at 95-400 keV are contaminated by high-energy electrons (>400 keV). Comparison of the data with electron and proton observations from RBSP/MagEIS indicates that the subtraction of proton fluxes at energies \&\#8771; 230-630 keV from the IES electron data adequately removes the proton contamination. We demonstrate the usefulness of the corrected data for scientific applications.}, language = {en} } @article{KruesemannSchwarzlMetzler2016, author = {Kruesemann, Henning and Schwarzl, Richard and Metzler, Ralf}, title = {Ageing Scher-Montroll Transport}, series = {Transport in Porous Media}, volume = {115}, journal = {Transport in Porous Media}, publisher = {Springer}, address = {New York}, issn = {0169-3913}, doi = {10.1007/s11242-016-0686-y}, pages = {327 -- 344}, year = {2016}, abstract = {We study the properties of ageing Scher-Montroll transport in terms of a biased subdiffusive continuous time random walk in which the waiting times between consecutive jumps of the charge carriers are distributed according to the power law probability with . As we show, the dynamical properties of the Scher-Montroll transport depend on the ageing time span between the initial preparation of the system and the start of the observation. The Scher-Montroll transport theory was originally shown to describe the photocurrent in amorphous solids in the presence of an external electric field, but it has since been used in many other fields of physical sciences, in particular also in the geophysical context for the description of the transport of tracer particles in subsurface aquifers. In the absence of ageing () the photocurrent of the classical Scher-Montroll model or the breakthrough curves in the groundwater context exhibit a crossover between two power law regimes in time with the scaling exponents and . In the presence of ageing a new power law regime and an initial plateau regime of the current emerge. We derive the different power law regimes and crossover times of the ageing Scher-Montroll transport and show excellent agreement with simulations of the process. Experimental data of ageing Scher-Montroll transport in polymeric semiconductors are shown to agree well with the predictions of our theory.}, language = {en} } @phdthesis{Kruesemann2016, author = {Kr{\"u}semann, Henning}, title = {First passage phenomena and single-file motion in ageing continuous time random walks and quenched energy landscapes}, school = {Universit{\"a}t Potsdam}, pages = {122}, year = {2016}, abstract = {In der Physik gibt es viele Prozesse, die auf Grund ihrer Komplexit{\"a}t nicht durch physikalische Gleichungen beschrieben werden k{\"o}nnen, beispielsweise die Bewegung eines Staubkorns in der Luft. Durch die vielen St{\"o}ße mit Luftmolek{\"u}len f{\"u}hrt es eine Zufallsbewegung aus, die so genannte Diffusion. Auch Molek{\"u}le in biologischen Zellen diffundieren, jedoch befinden sich in einer solchen Zelle im selben Volumen viel mehr oder viel gr{\"o}ßere Molek{\"u}le. Das beobachtete Teilchen st{\"o}ßt dementsprechend {\"o}fter mit anderen zusammen und die Diffusion wird langsamer, sie wird subdiffusiv. Mit der Zeit kann sich die Charakteristik der Subdiffusion {\"a}ndern; dies wird als (mikroskopisches) Altern bezeichnet. Ich untersuche in der vorliegenden Arbeit zwei mathematische Modelle f{\"u}r eindimensionale Subdiffusion, einmal den continuous time random walk (CTRW) und einmal die Zufallsbewegung in einer eingefrorenen Energielandschaft (QEL=quenched energy landscape). Beide sind Sprungprozesse, das heißt, sie sind Abfolgen von r{\"a}umlichen Spr{\"u}ngen, die durch zufallsverteilte Wartezeiten getrennt sind. Die Wartezeiten in der QEL sind r{\"a}umlich korrelliert, w{\"a}hrend sie im CTRW unkorrelliert sind. Ich untersuche in der vorliegenden Arbeit verschiedene statistische Gr{\"o}ßen in beiden Modellen. Zun{\"a}chst untersuche ich den Einfluss des Alters und den Einfluss der Korrellationen einer QEL auf die Verteilung der Zeiten, die das diffundierendes Teilchen ben{\"o}tigt, um eine (r{\"a}umliche) Schwelle zu {\"u}berqueren. Ausserdem bestimme ich den Effekt des Alters auf Str{\"o}me von (sub)diffundierenden Partikeln, die sich auf eine absorbierende Barriere zubewegen. Zuletzt besch{\"a}ftige ich mich mit der Diffusion einer eindimensionalen Anordnung von Teilchen in einer QEL, in der diese als harte Kugeln miteinander wechselwirken. Dabei vergleiche ich die gemeinsame Bewegung in einer QEL und als individuelle CTRWs miteinander {\"u}ber die Standartabweichung von der Startposition, f{\"u}r die ich das Mittel {\"u}ber mehrere QELs untersuche. Meine Arbeit setzt sich zusammen aus theoretischen {\"U}berlegungen und Berechnungen sowie der Simulation der Zufallsprozesse. Die Ergebnisse der Simulation und, soweit vorhanden, experimentelle Daten werden mit der Theorie verglichen.}, language = {en} } @article{KuikLauerChurkinaetal.2016, author = {Kuik, Friderike and Lauer, Axel and Churkina, Galina and Van der Gon, Hugo A. C. Denier and Fenner, Daniel and Mar, Kathleen A. and Butler, Tim M.}, title = {Air quality modelling in the Berlin-Brandenburg region using WRF-Chem v3.7.1: sensitivity to resolution of model grid and input data}, series = {Geoscientific model development : an interactive open access journal of the European Geosciences Union}, volume = {9}, journal = {Geoscientific model development : an interactive open access journal of the European Geosciences Union}, publisher = {Copernicus}, address = {G{\"o}ttingen}, issn = {1991-959X}, doi = {10.5194/gmd-9-4339-2016}, pages = {4339 -- 4363}, year = {2016}, abstract = {Air pollution is the number one environmental cause of premature deaths in Europe. Despite extensive regulations, air pollution remains a challenge, especially in urban areas. For studying summertime air quality in the Berlin-Brandenburg region of Germany, the Weather Research and Forecasting Model with Chemistry (WRF-Chem) is set up and evaluated against meteorological and air quality observations from monitoring stations as well as from a field campaign conducted in 2014. The objective is to assess which resolution and level of detail in the input data is needed for simulating urban background air pollutant concentrations and their spatial distribution in the Berlin-Brandenburg area. The model setup includes three nested domains with horizontal resolutions of 15, 3 and 1 km and anthropogenic emissions from the TNO-MACC III inventory. We use RADM2 chemistry and the MADE/SORGAM aerosol scheme. Three sensitivity simulations are conducted updating input parameters to the single-layer urban canopy model based on structural data for Berlin, specifying land use classes on a sub-grid scale (mosaic option) and downscaling the original emissions to a resolution of ca. 1 km × 1 km for Berlin based on proxy data including traffic density and population density. The results show that the model simulates meteorology well, though urban 2 m temperature and urban wind speeds are biased high and nighttime mixing layer height is biased low in the base run with the settings described above. We show that the simulation of urban meteorology can be improved when specifying the input parameters to the urban model, and to a lesser extent when using the mosaic option. On average, ozone is simulated reasonably well, but maximum daily 8 h mean concentrations are underestimated, which is consistent with the results from previous modelling studies using the RADM2 chemical mechanism. Particulate matter is underestimated, which is partly due to an underestimation of secondary organic aerosols. NOx (NO + NO2) concentrations are simulated reasonably well on average, but nighttime concentrations are overestimated due to the model's underestimation of the mixing layer height, and urban daytime concentrations are underestimated. The daytime underestimation is improved when using downscaled, and thus locally higher emissions, suggesting that part of this bias is due to deficiencies in the emission input data and their resolution. The results further demonstrate that a horizontal resolution of 3 km improves the results and spatial representativeness of the model compared to a horizontal resolution of 15 km. With the input data (land use classes, emissions) at the level of detail of the base run of this study, we find that a horizontal resolution of 1 km does not improve the results compared to a resolution of 3 km. However, our results suggest that a 1 km horizontal model resolution could enable a detailed simulation of local pollution patterns in the Berlin-Brandenburg region if the urban land use classes, together with the respective input parameters to the urban canopy model, are specified with a higher level of detail and if urban emissions of higher spatial resolution are used.}, language = {en} } @article{KumphHenkelRabletal.2016, author = {Kumph, Muir and Henkel, Carsten and Rabl, Peter and Brownnutt, Michael and Blatt, Rainer}, title = {Electric-field noise above a thin dielectric layer on metal electrodes}, series = {NEW JOURNAL OF PHYSICS}, volume = {18}, journal = {NEW JOURNAL OF PHYSICS}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {1367-2630}, doi = {10.1088/1367-2630/18/2/023020}, pages = {1125 -- 1136}, year = {2016}, abstract = {The electric-field noise above a layered structure composed of a planar metal electrode covered by a thin dielectric is evaluated and it is found that the dielectric film considerably increases the noise level, in proportion to its thickness. Importantly, even a thin (mono) layer of a low-loss dielectric can enhance the noise level by several orders of magnitude compared to the noise above a bare metal. Close to this layered surface, the power spectral density of the electric field varies with the inverse fourth power of the distance to the surface, rather than with the inverse square, as it would above a bare metal surface. Furthermore, compared to a clean metal, where the noise spectrum does not vary with frequency (in the radio-wave and microwave bands), the dielectric layer can generate electricfield noise which scales in inverse proportion to the frequency. For various realistic scenarios, the noise levels predicted from this model are comparable to those observed in trapped-ion experiments. Thus, these findings are of particular importance for the understanding and mitigation of unwanted heating and decoherence in miniaturized ion traps.}, language = {en} } @article{KunnusJosefssonRajkovicetal.2016, author = {Kunnus, Kristjan and Josefsson, Ida and Rajkovic, Ivan and Schreck, Simon and Quevedo, Wilson and Beye, Martin and Gr{\"u}bel, Sebastian and Scholz, Mirko and Nordlund, Dennis and Zhang, Wenkai and Hartsock, Robert W. and Gaffney, Kelly J. and Schlotter, William F. and Turner, Joshua J. and Kennedy, Brian and Hennies, Franz and Techert, Simone and Wernet, Philippe and Odelius, Michael and F{\"o}hlisch, Alexander}, title = {Anti-Stokes resonant x-ray Raman scattering for atom specific and excited state selective dynamics}, series = {NEW JOURNAL OF PHYSICS}, volume = {18}, journal = {NEW JOURNAL OF PHYSICS}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {1367-2630}, doi = {10.1088/1367-2630/18/10/103011}, pages = {9}, year = {2016}, abstract = {Ultrafast electronic and structural dynamics of matter govern rate and selectivity of chemical reactions, as well as phase transitions and efficient switching in functional materials. Since x-rays determine electronic and structural properties with elemental, chemical, orbital and magnetic selectivity, short pulse x-ray sources have become central enablers of ultrafast science. Despite of these strengths, ultrafast x-rays have been poor at picking up excited state moieties from the unexcited ones. With time-resolved anti-Stokes resonant x-ray Raman scattering (AS-RXRS) performed at the LCLS, and ab initio theory we establish background free excited state selectivity in addition to the elemental, chemical, orbital and magnetic selectivity of x-rays. This unparalleled selectivity extracts low concentration excited state species along the pathway of photo induced ligand exchange of Fe(CO)(5) in ethanol. Conceptually a full theoretical treatment of all accessible insights to excited state dynamics with AS-RXRS with transform-limited x-ray pulses is given-which will be covered experimentally by upcoming transform-limited x-ray sources.}, language = {en} } @article{KunnusZhangDelceyetal.2016, author = {Kunnus, Kristjan and Zhang, Wenkai and Delcey, Mickael G. and Pinjari, Rahul V. and Miedema, Piter S. and Schreck, Simon and Quevedo, Wilson and Schr{\"o}der, Henning and F{\"o}hlisch, Alexander and Gaffney, Kelly J. and Lundberg, Marcus and Odelius, Michael and Wernet, Philippe}, title = {Viewing the Valence Electronic Structure of Ferric and Ferrous Hexacyanide in Solution from the Fe and Cyanide Perspectives}, series = {The journal of physical chemistry : B, Condensed matter, materials, surfaces, interfaces \& biophysical chemistry}, volume = {120}, journal = {The journal of physical chemistry : B, Condensed matter, materials, surfaces, interfaces \& biophysical chemistry}, publisher = {American Chemical Society}, address = {Washington}, issn = {1520-6106}, doi = {10.1021/acs.jpcb.6b04751}, pages = {7182 -- 7194}, year = {2016}, abstract = {The valence-excited states of ferric and ferrous hexacyanide ions in aqueous solution were mapped by resonant inelastic X-ray scattering (RIXS) at the Fe L-2,L-3 and N K edges. Probing of both the central Fe and the ligand N atoms enabled identification of the metal-and ligand-centered excited states, as well as ligand-to-metal and metal-to-ligand charge-transfer excited states. Ab initio calculations utilizing the RASPT2 method were used to simulate the Fe L-2,L-3-edge RIXS spectra and enabled quantification of the covalencies of both occupied and empty orbitals of pi and sigma symmetry. We found that pi back-donation in the ferric complex is smaller than that in the ferrous complex. This is evidenced by the relative amounts of Fe 3d character in the nominally 2 pi CN- molecular orbital of 7\% and 9\% in ferric and ferrous hexacyanide, respectively. Utilizing the direct sensitivity of Fe L-3-edge RIXS to the Fe 3d character in the occupied molecular orbitals, we also found that the donation interactions are dominated by sigma bonding. The latter was found to be stronger in the ferric complex, with an Fe 3d contribution to the nominally 5 sigma CN- molecular orbitals of 29\% compared to 20\% in the ferrous complex. These results are consistent with the notion that a higher charge at the central metal atom increases donation and decreases back-donation.}, language = {en} } @misc{KurpiersNeher2016, author = {Kurpiers, Jona and Neher, Dieter}, title = {Dispersive Non-Geminate Recombination in an Amorphous Polymer:Fullerene Blend}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-91541}, pages = {10}, year = {2016}, abstract = {Recombination of free charge is a key process limiting the performance of solar cells. For low mobility materials, such as organic semiconductors, the kinetics of non-geminate recombination (NGR) is strongly linked to the motion of charges. As these materials possess significant disorder, thermalization of photogenerated carriers in the inhomogeneously broadened density of state distribution is an unavoidable process. Despite its general importance, knowledge about the kinetics of NGR in complete organic solar cells is rather limited. We employ time delayed collection field (TDCF) experiments to study the recombination of photogenerated charge in the high-performance polymer:fullerene blend PCDTBT:PCBM. NGR in the bulk of this amorphous blend is shown to be highly dispersive, with a continuous reduction of the recombination coefficient throughout the entire time scale, until all charge carriers have either been extracted or recombined. Rapid, contact-mediated recombination is identified as an additional loss channel, which, if not properly taken into account, would erroneously suggest a pronounced field dependence of charge generation. These findings are in stark contrast to the results of TDCF experiments on photovoltaic devices made from ordered blends, such as P3HT:PCBM, where non-dispersive recombination was proven to dominate the charge carrier dynamics under application relevant conditions.}, language = {en} } @article{KurpiersNeher2016, author = {Kurpiers, Jona and Neher, Dieter}, title = {Dispersive Non-Geminate Recombination in an Amorphous Polymer:Fullerene Blend}, series = {Scientific reports}, volume = {6}, journal = {Scientific reports}, publisher = {Nature Publishing Group}, address = {London}, issn = {2045-2322}, doi = {10.1038/srep26832}, pages = {10}, year = {2016}, abstract = {Recombination of free charge is a key process limiting the performance of solar cells. For low mobility materials, such as organic semiconductors, the kinetics of non-geminate recombination (NGR) is strongly linked to the motion of charges. As these materials possess significant disorder, thermalization of photogenerated carriers in the inhomogeneously broadened density of state distribution is an unavoidable process. Despite its general importance, knowledge about the kinetics of NGR in complete organic solar cells is rather limited. We employ time delayed collection field (TDCF) experiments to study the recombination of photogenerated charge in the high-performance polymer:fullerene blend PCDTBT:PCBM. NGR in the bulk of this amorphous blend is shown to be highly dispersive, with a continuous reduction of the recombination coefficient throughout the entire time scale, until all charge carriers have either been extracted or recombined. Rapid, contact-mediated recombination is identified as an additional loss channel, which, if not properly taken into account, would erroneously suggest a pronounced field dependence of charge generation. These findings are in stark contrast to the results of TDCF experiments on photovoltaic devices made from ordered blends, such as P3HT:PCBM, where non-dispersive recombination was proven to dominate the charge carrier dynamics under application relevant conditions.}, language = {en} } @article{KurpiersNeher2016, author = {Kurpiers, Jona and Neher, Dieter}, title = {Dispersive Non-Geminate Recombination in an Amorphous Polymer: Fullerene Blend}, series = {Scientific reports}, volume = {6}, journal = {Scientific reports}, publisher = {Nature Publ. Group}, address = {London}, issn = {2045-2322}, doi = {10.1038/srep26832}, pages = {10}, year = {2016}, abstract = {Recombination of free charge is a key process limiting the performance of solar cells. For low mobility materials, such as organic semiconductors, the kinetics of non-geminate recombination (NGR) is strongly linked to the motion of charges. As these materials possess significant disorder, thermalization of photogenerated carriers in the inhomogeneously broadened density of state distribution is an unavoidable process. Despite its general importance, knowledge about the kinetics of NGR in complete organic solar cells is rather limited. We employ time delayed collection field (TDCF) experiments to study the recombination of photogenerated charge in the high-performance polymer: fullerene blend PCDTBT:PCBM. NGR in the bulk of this amorphous blend is shown to be highly dispersive, with a continuous reduction of the recombination coefficient throughout the entire time scale, until all charge carriers have either been extracted or recombined. Rapid, contact-mediated recombination is identified as an additional loss channel, which, if not properly taken into account, would erroneously suggest a pronounced field dependence of charge generation. These findings are in stark contrast to the results of TDCF experiments on photovoltaic devices made from ordered blends, such as P3HT:PCBM, where non-dispersive recombination was proven to dominate the charge carrier dynamics under application relevant conditions.}, language = {en} } @article{KuznetsovTurukinaChernyshovetal.2016, author = {Kuznetsov, Alexander P. and Turukina, Ludmila V. and Chernyshov, Nikolai Yu and Sedova, Yuliya V.}, title = {Oscillations and Synchronization in a System of Three Reactively Coupled Oscillators}, series = {International journal of bifurcation and chaos : in applied sciences and engineering}, volume = {26}, journal = {International journal of bifurcation and chaos : in applied sciences and engineering}, publisher = {World Scientific}, address = {Singapore}, issn = {0218-1274}, doi = {10.1142/S0218127416500103}, pages = {31 -- 39}, year = {2016}, abstract = {We consider a system of three interacting van der Pol oscillators with reactive coupling. Phase equations are derived, using proper order of expansion over the coupling parameter. The dynamics of the system is studied by means of the bifurcation analysis and with the method of Lyapunov exponent charts. Essential and physically meaningful features of the reactive coupling are discussed.}, language = {en} } @article{Kuznetsov2016, author = {Kuznetsov, Sergey P.}, title = {Parametric chaos generator operating on a varactor diode with the instability limitation decay mechanism}, series = {Technical Physics}, volume = {61}, journal = {Technical Physics}, publisher = {Pleiades Publ.}, address = {New York}, issn = {1063-7842}, doi = {10.1134/S1063784216030129}, pages = {436 -- 445}, year = {2016}, abstract = {Equations are derived for a parametric chaos generator containing three oscillatory circuits and a variable-capacitance diode (varactor) and are reduced to equations for slow amplitudes of parametrically interacting modes. With allowance for quadratic nonlinearity, the problem is reduced to a system of three first-order differential equations for Pikovsky-Rabinovich-Trakhtengerts real amplitudes with a Lorenz-type attractor. In a more accurate description of nonlinearity of the varactor, the equations for slow amplitudes are complex-valued, which leads to the loss of robustness of chaotic dynamics, which is typical of the Lorenz attractor. The results of numerical calculations (portraits of attractors and Lyapunov exponents) in models with different approximation levels are compared.}, language = {en} } @article{LaeppleHoerholdMuenchetal.2016, author = {Laepple, Thomas and H{\"o}rhold, Maria and M{\"u}nch, Thomas and Freitag, Johannes and Wegner, Anna and Kipfstuhl, Sepp}, title = {Layering of surface snow and firn at Kohnen Station, Antarctica: Noise or seasonal signal?}, series = {Journal of geophysical research : Earth surface}, volume = {121}, journal = {Journal of geophysical research : Earth surface}, publisher = {American Geophysical Union}, address = {Washington}, issn = {2169-9003}, doi = {10.1002/2016JF003919}, pages = {1849 -- 1860}, year = {2016}, abstract = {The density of firn is an important property for monitoring and modeling the ice sheets as well as to model the pore close-off and thus to interpret ice core-based greenhouse gas records. One feature, which is still in debate, is the potential existence of an annual cycle of firn density in low-accumulation regions. Several studies describe or assume seasonally successive density layers, horizontally evenly distributed, as seen in radar data. On the other hand, high-resolution density measurements on firn cores in Antarctica and Greenland show no clear seasonal cycle in the top few meters. A major caveat of most existing snow-pit and firn-core-based studies is that they represent one vertical profile from a laterally heterogeneous density field. To overcome this, we created an extensive data set of horizontal and vertical density data at Kohnen Station, Dronning Maud Land, on the East Antarctic Plateau. We drilled and analyzed three 90m long firn cores as well as 143 one-meter-long vertical profiles from two elongated snow trenches to obtain a two-dimensional view of the density variations. The analysis of the 45m wide and 1m deep density fields reveals a seasonal cycle in density. However, the seasonality is overprinted by strong stratigraphic noise, making it invisible when analyzing single firn cores. Our density data set extends the view from the local ice core perspective to a hundred meter scale and thus supports linking spatially integrating methods such as radar and seismic studies to ice and firn cores.}, language = {en} } @article{LechleitnerBaldiniBreitenbachetal.2016, author = {Lechleitner, Franziska A. and Baldini, James U. L. and Breitenbach, Sebastian Franz Martin and Fohlmeister, Jens Bernd and McIntyre, Cameron and Goswami, Bedartha and Jamieson, Robert A. and van der Voort, Tessa S. and Prufer, Keith and Marwan, Norbert and Culleton, Brendan J. and Kennett, Douglas J. and Asmerom, Yemane and Polyak, Victor and Eglinton, Timothy I.}, title = {Hydrological and climatological controls on radiocarbon concentrations in a tropical stalagmite}, series = {Geochimica et cosmochimica acta : journal of the Geochemical Society and the Meteoritical Society}, volume = {194}, journal = {Geochimica et cosmochimica acta : journal of the Geochemical Society and the Meteoritical Society}, publisher = {Elsevier}, address = {Oxford}, issn = {0016-7037}, doi = {10.1016/j.gca.2016.08.039}, pages = {233 -- 252}, year = {2016}, abstract = {Precisely-dated stalagmites are increasingly important archives for the reconstruction of terrestrial paleoclimate at very high temporal resolution. In-depth understanding of local conditions at the cave site and of the processes driving stalagmite deposition is of paramount importance for interpreting proxy signals incorporated in stalagmite carbonate. Here we present a sub-decadally resolved dead carbon fraction (DCF) record for a stalagmite from Yok Balum Cave (southern Belize). The record is coupled to parallel stable carbon isotope (delta C-13) and U/Ca measurements, as well as radiocarbon (C-14) measurements from soils overlying the cave system. Using a karst carbon cycle model we disentangle the importance of soil and karst processes on stalagmite DCF incorporation, revealing a dominant host rock dissolution control on total DCF. Covariation between DCF, delta C-13, and U/Ca indicates that karst processes are a common driver of all three parameters, suggesting possible use of delta C-13 and trace element ratios to independently quantify DCF variability. A statistically significant multi-decadal lag of variable length exists between DCF and reconstructed solar activity, suggesting that solar activity influenced regional precipitation in Mesoamerica over the past 1500 years, but that the relationship was non-static. Although the precise nature of the observed lag is unclear, solar-induced changes in North Atlantic oceanic and atmospheric dynamics may play a role. (C) 2016 Elsevier Ltd. All rights reserved.}, language = {en} } @phdthesis{Lehmann2016, author = {Lehmann, Jascha In-su}, title = {Changes in extratropical storm track activity and their implications for extreme weather events}, pages = {221}, year = {2016}, language = {en} } @article{LenskeWagnerWirthetal.2016, author = {Lenske, Gerlinde and Wagner, Wolfgang and Wirth, Joachim and Thillmann, Hubertina and Cauet, Eva and Liepertz, Sven and Leutner, Detlev}, title = {The importance of pedagogical knowledge for classroom management and for and for students' achievement}, series = {Zeitschrift f{\~A}¼r Erziehungswissenschaft}, volume = {19}, journal = {Zeitschrift f{\~A}¼r Erziehungswissenschaft}, publisher = {Springer}, address = {Wiesbaden}, issn = {1434-663X}, doi = {10.1007/s11618-015-0659-x}, pages = {211 -- 233}, year = {2016}, abstract = {Im Rahmen der vorliegenden Studie wurde untersucht, ob das p{\"a}dagogisch-psychologische Wissen von Lehrkr{\"a}ften die prozessuale Qualit{\"a}t des Physikunterrichts mit Blick auf die Klassenf{\"u}hrung und den Lernzuwachs der Sch{\"u}lerinnen und Sch{\"u}ler beeinflusst. Das p{\"a}dagogisch-psychologische Professionswissen, konzeptualisiert als ein f{\"a}cher{\"u}bergreifendes, handlungsleitendes Wissen {\"u}ber Strategien und Mittel zur Unterrichtsgestaltung, wurde {\"u}ber einen Paper-Pencil-Test, bestehend aus einer Skala zum deklarativen und einer Skala zum konditional-prozeduralen Wissen erhoben (Lenske et al. 2015). Als ein grundlegendes Merkmal prozessualer Unterrichtsqualit{\"a}t wurde die Klassenf{\"u}hrung anhand von Videoratings zu zwei Messzeitpunkten (zwei Unterrichtsstunden) erfasst. Der Lernzuwachs der Sch{\"u}lerinnen und Sch{\"u}ler wurde {\"u}ber standardisierte Fachwissenstests im Pr{\"a}-Post-Testdesign gemessen. Die Stichprobe umfasst 34 Gymnasiallehrkr{\"a}fte und deren Sch{\"u}lerinnen und Sch{\"u}ler (N = 993). Auf Basis eines Complex-Bootstrap-Mediations-Modells zeigte sich, dass das p{\"a}dagogisch-psychologische Professionswissen {\"u}ber die Klassenf{\"u}hrung vermittelt den Lernzuwachs der Sch{\"u}ler und Sch{\"u}lerinnen positiv beeinflusst. In the present study it was investigated whether the pedagogical knowledge of teachers has an influence on the process quality of physics instruction and on the learning achievement of students as well. Pedagogical knowledge, conceptualized as knowledge about strategies in classroom instruction that is domain-general and relevant for teaching behaviors, was measured using a paper-and-pencil test with two scales: one scale on declarative knowledge, the other on conditional-procedural knowledge (Lenske et al. 2015). As a basic aspect of the process quality of classroom instruction, classroom management was assessed using video ratings of two lessons from each participating teacher. Students' learning achievement was assessed using standardized domain-specific knowledge tests in a pretest-posttest design. The sample included 34 teachers from higher-track secondary schools and their students (N = 993). A complex bootstrapping mediation model shows that teachers' pedagogical knowledge, mediated by their classroom management, has a positive effect on their students' learning achievement.}, language = {de} } @article{LeonhardtGerhardtHoeppneretal.2016, author = {Leonhardt, Helmar and Gerhardt, Matthias and Hoeppner, Nadine and Kr{\"u}ger, Kirsten and Tarantola, Marco and Beta, Carsten}, title = {Cell-substrate impedance fluctuations of single amoeboid cells encode cell-shape and adhesion dynamics}, series = {Physical review : E, Statistical, nonlinear and soft matter physics}, volume = {93}, journal = {Physical review : E, Statistical, nonlinear and soft matter physics}, publisher = {American Physical Society}, address = {College Park}, issn = {2470-0045}, doi = {10.1103/PhysRevE.93.012414}, pages = {8}, year = {2016}, abstract = {We show systematic electrical impedance measurements of single motile cells on microelectrodes. Wild-type cells and mutant strains were studied that differ in their cell-substrate adhesion strength. We recorded the projected cell area by time-lapse microscopy and observed irregular oscillations of the cell shape. These oscillations were correlated with long-term variations in the impedance signal. Superposed to these long-term trends, we observed fluctuations in the impedance signal. Their magnitude clearly correlated with the adhesion strength, suggesting that strongly adherent cells display more dynamic cell-substrate interactions.}, language = {en} } @misc{LevermannPetoukhovScheweetal.2016, author = {Levermann, Anders and Petoukhov, Vladimir and Schewe, Jacob and Schellnhuber, Hans Joachim}, title = {Abrupt monsoon transitions as seen in paleorecords can be explained by moisture-advection feedback}, series = {Proceedings of the National Academy of Sciences of the United States of America}, volume = {113}, journal = {Proceedings of the National Academy of Sciences of the United States of America}, publisher = {National Acad. of Sciences}, address = {Washington}, issn = {0027-8424}, doi = {10.1073/pnas.1603130113}, pages = {E2348 -- E2349}, year = {2016}, language = {en} } @article{LevermannWinkelmann2016, author = {Levermann, Anders and Winkelmann, Ricarda}, title = {A simple equation for the melt elevation feedback of ice sheets}, series = {The Cryosphere : TC ; an interactive open access journal of the European Geosciences Union}, volume = {10}, journal = {The Cryosphere : TC ; an interactive open access journal of the European Geosciences Union}, publisher = {Copernicus}, address = {G{\"o}ttingen}, issn = {1994-0416}, doi = {10.5194/tc-10-1799-2016}, pages = {1799 -- 1807}, year = {2016}, abstract = {In recent decades, the Greenland Ice Sheet has been losing mass and has thereby contributed to global sea-level rise. The rate of ice loss is highly relevant for coastal protection worldwide. The ice loss is likely to increase under future warming. Beyond a critical temperature threshold, a meltdown of the Greenland Ice Sheet is induced by the self-enforcing feedback between its lowering surface elevation and its increasing surface mass loss: the more ice that is lost, the lower the ice surface and the warmer the surface air temperature, which fosters further melting and ice loss. The computation of this rate so far relies on complex numerical models which are the appropriate tools for capturing the complexity of the problem. By contrast we aim here at gaining a conceptual understanding by deriving a purposefully simple equation for the self-enforcing feedback which is then used to estimate the melt time for different levels of warming using three observable characteristics of the ice sheet itself and its surroundings. The analysis is purely conceptual in nature. It is missing important processes like ice dynamics for it to be useful for applications to sea-level rise on centennial timescales, but if the volume loss is dominated by the feedback, the resulting logarithmic equation unifies existing numerical simulations and shows that the melt time depends strongly on the level of warming with a critical slow-down near the threshold: the median time to lose 10\% of the present-day ice volume varies between about 3500 years for a temperature level of 0.5 degrees C above the threshold and 500 years for 5 degrees C. Unless future observations show a significantly higher melting sensitivity than currently observed, a complete meltdown is unlikely within the next 2000 years without significant ice-dynamical contributions.}, language = {en} } @article{LiebigSarhanPrietzeletal.2016, author = {Liebig, Ferenc and Sarhan, Radwan Mohamed and Prietzel, Claudia Christina and Reinecke, Antje and Koetz, Joachim}, title = {"Green" gold nanotriangles: synthesis, purification by polyelectrolyte/micelle depletion flocculation and performance in surface-enhanced Raman scattering}, series = {RSC Advances}, volume = {6}, journal = {RSC Advances}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {2046-2069}, doi = {10.1039/c6ra04808k}, pages = {33561 -- 33568}, year = {2016}, abstract = {The aim of this study was to develop a one-step synthesis of gold nanotriangles (NTs) in the presence of mixed phospholipid vesicles followed by a separation process to isolate purified NTs. Negatively charged vesicles containing AOT and phospholipids, in the absence and presence of additional reducing agents (polyampholytes, polyanions or low molecular weight compounds), were used as a template phase to form anisotropic gold nanoparticles. Upon addition of the gold chloride solution, the nucleation process is initiated and both types of particles, i.e., isotropic spherical and anisotropic gold nanotriangles, are formed simultaneously. As it was not possible to produce monodisperse nanotriangles with such a one-step procedure, the anisotropic nanoparticles needed to be separated from the spherical ones. Therefore, a new type of separation procedure using combined polyelectrolyte/micelle depletion flocculation was successfully applied. As a result of the different purification steps, a green colored aqueous dispersion was obtained containing highly purified, well-defined negatively charged flat nanocrystals with a platelet thickness of 10 nm and an edge length of about 175 nm. The NTs produce promising results in surface-enhanced Raman scattering.}, language = {en} } @article{LigorioNardiSteyrleuthneretal.2016, author = {Ligorio, G. and Nardi, M. V. and Steyrleuthner, Robert and Ihiawakrim, D. and Crespo-Monteiro, N. and Brinkmann, Martin and Neher, Dieter and Koch, N.}, title = {Metal nanoparticle mediated space charge and its optical control in an organic hole-only device}, series = {Applied physics letters}, volume = {108}, journal = {Applied physics letters}, publisher = {American Institute of Physics}, address = {Melville}, issn = {0003-6951}, doi = {10.1063/1.4945710}, pages = {5}, year = {2016}, abstract = {We reveal the role of localized space charges in hole-only devices based on an organic semiconductor with embedded metal nanoparticles (MNPs). MNPs act as deep traps for holes and reduce the current density compared to a device without MNPs by a factor of 10(4) due to the build-up of localized space charge. Dynamic MNPs charged neutrality can be realized during operation by electron transfer from excitons created in the organic matrix, enabling light sensing independent of device bias. In contrast to the previous speculations, electrical bistability in such devices was not observed. (C) 2016 AIP Publishing LLC.}, language = {en} } @article{LiuKliemTitovetal.2016, author = {Liu, Rui and Kliem, Bernhard and Titov, Viacheslav S. and Chen, Jun and Wang, Yuming and Wang, Haimin and Liu, Chang and Xu, Yan and Wiegelmann, Thomas}, title = {STRUCTURE, STABILITY, AND EVOLUTION OF MAGNETIC FLUX ROPES FROM THE PERSPECTIVE OF MAGNETIC TWIST}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, volume = {818}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0004-637X}, doi = {10.3847/0004-637X/818/2/148}, pages = {22}, year = {2016}, abstract = {We investigate the evolution of NOAA Active Region (AR) 11817 during 2013 August 10-12, when it developed a complex field configuration and produced four confined, followed by two eruptive, flares. These C-and-above flares are all associated with a magnetic flux rope (MFR) located along the major polarity inversion line, where shearing and converging photospheric flows are present. Aided by the nonlinear force-free field modeling, we identify the MFR through mapping magnetic connectivities and computing the twist number \${{ \mathcal T }}_{w}\$ for each individual field line. The MFR is moderately twisted (\$| {{ \mathcal T }}_{w}| \lt 2\$) and has a well-defined boundary of high squashing factor Q. We found that the field line with the extremum \$| {{ \mathcal T }}_{w}| \$ is a reliable proxy of the rope axis, and that the MFR's peak \$| {{ \mathcal T }}_{w}| \$ temporarily increases within half an hour before each flare while it decreases after the flare peak for both confined and eruptive flares. This pre-flare increase in \$| {{ \mathcal T }}_{w}| \$ has little effect on the AR's free magnetic energy or any other parameters derived for the whole region, due to its moderate amount and the MFR's relatively small volume, while its decrease after flares is clearly associated with the stepwise decrease in the whole region's free magnetic energy due to the flare. We suggest that \${{ \mathcal T }}_{w}\$ may serve as a useful parameter in forewarning the onset of eruption, and therefore, the consequent space weather effects. The helical kink instability is identified as the prime candidate onset mechanism for the considered flares.}, language = {en} } @article{LiuSachseSpahnetal.2016, author = {Liu, Xiaodong and Sachse, Manuel and Spahn, Frank and Schmidt, Jurgen}, title = {Dynamics and distribution of Jovian dust ejected from the Galilean satellites}, series = {Journal of geophysical research, Planets}, volume = {121}, journal = {Journal of geophysical research, Planets}, publisher = {American Geophysical Union}, address = {Washington}, issn = {2169-9097}, doi = {10.1002/2016JE004999}, pages = {1141 -- 1173}, year = {2016}, abstract = {In this paper, the dynamical analysis of the Jovian dust originating from the four Galilean moons is presented. High-accuracy orbital integrations of dust particles are used to determine their dynamical evolution. A variety of forces are taken into account, including the Lorentz force, solar radiation pressure, Poynting-Robertson drag, solar gravity, the satellites' gravity, plasma drag, and gravitational effects due to nonsphericity of Jupiter. More than 20,000 dust particles from each source moon in the size range from 0.05 \&\#956;m to 1 cm are simulated over 8000 (Earth) years until each dust grain hits a sink (moons, Jupiter, or escape from the system). Configurations of dust number density in the Jovicentric equatorial inertial frame are calculated and shown. In a Jovicentric frame rotating with the Sun the dust distributions are found to be asymmetric. For certain small particle sizes, the dust population is displaced towards the Sun, while for certain larger sizes, the dust population is displaced away from the Sun. The average lifetime as a function of particle size for ejecta from each source moon is derived, and two sharp jumps in the average lifetime are analyzed. Transport of dust between the Galilean moons and to Jupiter is investigated. Most of the orbits for dust particles from Galilean moons are prograde, while, surprisingly, a small fraction of orbits are found to become retrograde mainly due to solar radiation pressure and Lorentz force. The distribution of orbital elements is also analyzed.}, language = {en} } @misc{LoebnerJelkenYadavallietal.2016, author = {Loebner, Sarah and Jelken, Joachim and Yadavalli, Nataraja Sekhar and Sava, Elena and Hurduc, Nicolae and Santer, Svetlana}, title = {Motion of Adsorbed Nano-Particles on Azobenzene Containing Polymer Films}, series = {Molecules}, volume = {21}, journal = {Molecules}, publisher = {MDPI}, address = {Basel}, issn = {1420-3049}, doi = {10.3390/molecules21121663}, pages = {397 -- 411}, year = {2016}, abstract = {We demonstrate in situ recorded motion of nano-objects adsorbed on a photosensitive polymer film. The motion is induced by a mass transport of the underlying photoresponsive polymer material occurring during irradiation with interference pattern. The polymer film contains azobenzene molecules that undergo reversible photoisomerization reaction from trans-to cis-conformation. Through a multi-scale chain of physico-chemical processes, this finally results in the macro-deformations of the film due to the changing elastic properties of polymer. The topographical deformation of the polymer surface is sensitive to a local distribution of the electrical field vector that allows for the generation of dynamic changes in the surface topography during irradiation with different light interference patterns. Polymer film deformation together with the motion of the adsorbed nano-particles are recorded using a homemade set-up combining an optical part for the generation of interference patterns and an atomic force microscope for acquiring the surface deformation. The particles undergo either translational or rotational motion. The direction of particle motion is towards the topography minima and opposite to the mass transport within the polymer film. The ability to relocate particles by photo-induced dynamic topography fluctuation offers a way for a non-contact simultaneous manipulation of a large number of adsorbed particles just in air at ambient conditions.}, language = {en} } @article{LoveChouHuangetal.2016, author = {Love, John A. and Chou, Shu-Hua and Huang, Ye and Bazan, Guillermo C. and Thuc-Quyen Nguyen,}, title = {Effects of solvent additive on "s-shaped" curves in solution-processed small molecule solar cells}, series = {Beilstein journal of organic chemistry}, volume = {12}, journal = {Beilstein journal of organic chemistry}, publisher = {Beilstein-Institut zur F{\~A}\Prderung der Chemischen Wissenschaften}, address = {Frankfurt, Main}, issn = {1860-5397}, doi = {10.3762/bjoc.12.249}, pages = {2543 -- 2555}, year = {2016}, abstract = {A novel molecular chromophore, p-SIDT(FBTThCA8)(2), is introduced as an electron-donor material for bulk heterojunction (BHJ) solar cells with broad absorption and near ideal energy levels for the use in combination with common acceptor materials. It is found that films cast from chlorobenzene yield devices with strongly s-shaped current-voltage curves, drastically limiting performance. We find that addition of the common solvent additive diiodooctane, in addition to facilitating crystallization, leads to improved vertical phase separation. This yields much better performing devices, with improved curve shape, demonstrating the importance of morphology control in BHJ devices and improving the understanding of the role of solvent additives.}, language = {en} } @article{LuDiPietroKoellnetal.2016, author = {Lu, Guanghao and Di Pietro, Riccardo and K{\"o}lln, Lisa Sophie and Nasrallah, Iyad and Zhou, Ling and Mollinger, Sonya and Himmelberger, Scott and Koch, Norbert and Salleo, Alberto and Neher, Dieter}, title = {Dual-Characteristic Transistors Based on Semiconducting Polymer Blends}, series = {Advanced electronic materials}, volume = {2}, journal = {Advanced electronic materials}, publisher = {Wiley-Blackwell}, address = {Hoboken}, issn = {2199-160X}, doi = {10.1002/aelm.201600267}, pages = {2344 -- 2351}, year = {2016}, abstract = {A dual-characteristic polymer field-effect transistor has markedly different characteristics in low and high voltage operations. In the low-voltage range (<5 V) it shows sharp subthreshold slopes (0.3-0.4 V dec\&\#8722;1), using which a low-voltage inverter with gain 8 is realized, while high-voltage (>5 V) induces symmetric current with regard to drain and gate voltages, leading to discrete differential (trans) conductances.}, language = {en} } @article{MartinJungbluthNideveretal.2016, author = {Martin, Nicolas F. and Jungbluth, Valentin and Nidever, David L. and Bell, Eric F. and Besla, Gurtina and Blum, Robert D. and Cioni, Maria-Rosa L. and Conn, Blair C. and Kaleida, Catherine C. and Gallart, Carme and Jin, Shoko and Majewski, Steven R. and Martinez-Delgado, David and Monachesi, Antonela and Munoz, Ricardo R. and Noel, Noelia E. D. and Olsen, Knut and Stringfellow, Guy S. and van der Marel, Roeland P. and Vivas, A. Katherina and Walker, Alistair R. and Zaritsky, Dennis}, title = {SMASH 1: A VERY FAINT GLOBULAR CLUSTER DISRUPTING IN THE OUTER REACHES OF THE LMC?}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics ; Part 2, Letters}, volume = {830}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics ; Part 2, Letters}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {2041-8205}, doi = {10.3847/2041-8205/830/1/L10}, pages = {92 -- 98}, year = {2016}, language = {en} } @article{MartinezGonzalezPastorYabarLaggetal.2016, author = {Martinez Gonzalez, M. J. and Pastor Yabar, A. and Lagg, A. and Asensio Ramos, A. and Collados Vera, M. and Solanki, S. K. and Balthasar, H. and Berkefeld, T. and Denker, Carsten and Doerr, H. P. and Feller, A. and Franz, M. and Gonz{\´a}lez Manrique, Sergio Javier and Hofmann, A. and Kneer, F. and Kuckein, Christoph and Louis, R. and von der L{\"u}he, O. and Nicklas, H. and Orozco, D. and Rezaei, R. and Schlichenmaier, R. and Schmidt, D. and Schmidt, W. and Sigwarth, M. and Sobotka, M. and Soltau, D. and Staude, J. and Strassmeier, Klaus G. and Verma, Meetu and Waldman, T. and Volkmer, R.}, title = {Inference of magnetic fields in the very quiet Sun}, series = {Journal of geophysical research : Earth surface}, volume = {596}, journal = {Journal of geophysical research : Earth surface}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {1432-0746}, doi = {10.1051/0004-6361/201628449}, pages = {11}, year = {2016}, abstract = {Context. Over the past 20 yr, the quietest areas of the solar surface have revealed a weak but extremely dynamic magnetism occurring at small scales (<500 km), which may provide an important contribution to the dynamics and energetics of the outer layers of the atmosphere. Understanding this magnetism requires the inference of physical quantities from high-sensitivity spectro-polarimetric data with high spatio-temporal resolution. Aims. We present high-precision spectro-polarimetric data with high spatial resolution (0.4") of the very quiet Sun at 1.56 mu m obtained with the GREGOR telescope to shed some light on this complex magnetism. Methods. We used inversion techniques in two main approaches. First, we assumed that the observed profiles can be reproduced with a constant magnetic field atmosphere embedded in a field-free medium. Second, we assumed that the resolution element has a substructure with either two constant magnetic atmospheres or a single magnetic atmosphere with gradients of the physical quantities along the optical depth, both coexisting with a global stray-light component. Results. Half of our observed quiet-Sun region is better explained by magnetic substructure within the resolution element. However, we cannot distinguish whether this substructure comes from gradients of the physical parameters along the line of sight or from horizontal gradients (across the surface). In these pixels, a model with two magnetic components is preferred, and we find two distinct magnetic field populations. The population with the larger filling factor has very weak (similar to 150 G) horizontal fields similar to those obtained in previous works. We demonstrate that the field vector of this population is not constrained by the observations, given the spatial resolution and polarimetric accuracy of our data. The topology of the other component with the smaller filling factor is constrained by the observations for field strengths above 250 G: we infer hG fields with inclinations and azimuth values compatible with an isotropic distribution. The filling factors are typically below 30\%. We also find that the flux of the two polarities is not balanced. From the other half of the observed quiet-Sun area similar to 50\% are two-lobed Stokes V profiles, meaning that 23\% of the field of view can be adequately explained with a single constant magnetic field embedded in a non-magnetic atmosphere. The magnetic field vector and filling factor are reliable inferred in only 50\% based on the regular profiles. Therefore, 12\% of the field of view harbour hG fields with filling factors typically below 30\%. At our present spatial resolution, 70\% of the pixels apparently are non-magnetised.}, language = {en} } @phdthesis{Marx2016, author = {Marx, Robert}, title = {A quantitative model of spatial correlations in parametric down conversion for investigating complementarity at a double slit}, school = {Universit{\"a}t Potsdam}, pages = {135}, year = {2016}, language = {en} } @article{MazurekYuGerhardetal.2016, author = {Mazurek, P. and Yu, L. and Gerhard, Reimund and Wirges, Werner and Skov, A. L.}, title = {Glycerol as high-permittivity liquid filler in dielectric silicone elastomers}, series = {Journal of applied polymer science}, volume = {133}, journal = {Journal of applied polymer science}, publisher = {Wiley-Blackwell}, address = {Hoboken}, issn = {0021-8995}, doi = {10.1002/app.44153}, pages = {8}, year = {2016}, abstract = {A recently reported novel class of elastomers was tested with respect to its dielectric properties. The new elastomer material is based on a commercially available poly(dimethylsiloxane) composition, which has been modified by embedding glycerol droplets into its matrix. The approach has two major advantages that make the material useful in a dielectric actuator. First, the glycerol droplets efficiently enhance the dielectric constant, which can reach astonishingly high values in the composite. Second, the liquid filler also acts as a softener that effectively decreases the elastic modulus of the composite. In combination with very low cost and easy preparation, the two property enhancements lead to an extremely attractive dielectric elastomer material. Experimental permittivity data are compared to various theoretical models that predict relative permittivity changes as a function of filler loading, and the applicability of the models is discussed. (c) 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 44153.}, language = {en} } @article{MengelFeldmannLevermann2016, author = {Mengel, Matthias and Feldmann, Johannes and Levermann, Anders}, title = {Linear sea-level response to abrupt ocean warming of major West Antarctic ice basin}, series = {Nature climate change}, volume = {6}, journal = {Nature climate change}, publisher = {Nature Publ. Group}, address = {London}, issn = {1758-678X}, doi = {10.1038/NCLIMATE2808}, pages = {71 -- +}, year = {2016}, abstract = {Antarctica's contribution to global sea-level rise has recently been increasing1. Whether its ice discharge will become unstable and decouple from anthropogenic forcing2,3,4 or increase linearly with the warming of the surrounding ocean is of fundamental importance5. Under unabated greenhouse-gas emissions, ocean models indicate an abrupt intrusion of warm circumpolar deep water into the cavity below West Antarctica's Filchner-Ronne ice shelf within the next two centuries6,7. The ice basin's retrograde bed slope would allow for an unstable ice-sheet retreat8, but the buttressing of the large ice shelf and the narrow glacier troughs tend to inhibit such instability9,10,11. It is unclear whether future ice loss will be dominated by ice instability or anthropogenic forcing. Here we show in regional and continental-scale ice-sheet simulations, which are capable of resolving unstable grounding-line retreat, that the sea-level response of the Filchner-Ronne ice basin is not dominated by ice instability and follows the strength of the forcing quasi-linearly. We find that the ice loss reduces after each pulse of projected warm water intrusion. The long-term sea-level contribution is approximately proportional to the total shelf-ice melt. Although the local instabilities might dominate the ice loss for weak oceanic warming12, we find that the upper limit of ice discharge from the region is determined by the forcing and not by the marine ice-sheet instability.}, language = {en} } @misc{Metzler2016, author = {Metzler, Ralf}, title = {PROTEIN PHYSICS Forever ageing}, series = {Nature physics}, volume = {12}, journal = {Nature physics}, publisher = {Nature Publ. Group}, address = {London}, issn = {1745-2473}, doi = {10.1038/nphys3585}, pages = {113 -- 114}, year = {2016}, abstract = {Single-molecule techniques have long given us insight into the motion and interactions of individual molecules. But simulations now show that the dynamics inside single proteins is not as simple as we thought — and that proteins are forever changing.}, language = {en} } @misc{MetzlerJeonCherstvy2016, author = {Metzler, Ralf and Jeon, J. -H. and Cherstvy, Andrey G.}, title = {Non-Brownian diffusion in lipid membranes: Experiments and simulations}, series = {Biochimica et biophysica acta : Biomembranes}, volume = {1858}, journal = {Biochimica et biophysica acta : Biomembranes}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0005-2736}, doi = {10.1016/j.bbamem.2016.01.022}, pages = {2451 -- 2467}, year = {2016}, abstract = {The dynamics of constituents and the surface response of cellular membranes also in connection to the binding of various particles and macromolecules to the membrane are still a matter of controversy in the membrane biophysics community, particularly with respect to crowded membranes of living biological cells. We here put into perspective recent single particle tracking experiments in the plasma membranes of living cells and supercomputing studies of lipid bilayer model membranes with and without protein crowding. Special emphasis is put on the observation of anomalous, non-Brownian diffusion of both lipid molecules and proteins embedded in the lipid bilayer. While single component, pure lipid bilayers in simulations exhibit only transient anomalous diffusion of lipid molecules on nanosecond time scales, the persistence of anomalous diffusion becomes significantly longer ranged on the addition of disorder through the addition of cholesterol or proteins and on passing of the membrane lipids to the gel phase. Concurrently, experiments demonstrate the anomalous diffusion of membrane embedded proteins up to macroscopic time scales in the minute time range. Particular emphasis will be put on the physical character of the anomalous diffusion, in particular, the occurrence of ageing observed in the experiments the effective diffusivity of the measured particles is a decreasing function of time. Moreover, we present results for the time dependent local scaling exponent of the mean squared displacement of the monitored particles. Recent results finding deviations from the commonly assumed Gaussian diffusion patterns in protein crowded membranes are reported. The properties of the displacement autocorrelation function of the lipid molecules are discussed in the light of their appropriate physical anomalous diffusion models, both for non-crowded and crowded membranes. In the last part of this review we address the upcoming field of membrane distortion by elongated membrane-binding particles. We discuss how membrane compartmentalisation and the particle-membrane binding energy may impact the dynamics and response of lipid membranes. This article is part of a Special Issue entitled: Biosimulations edited by Ilpo Vattulainen and Tomasz Rog. (C) 2016 The Authors. Published by Elsevier B.V.}, language = {en} } @article{MoradiZakrevskyyJavadietal.2016, author = {Moradi, N. and Zakrevskyy, Yuriy and Javadi, A. and Aksenenko, E. V. and Fainerman, V. B. and Lomadze, Nino and Santer, Svetlana and Miller, R.}, title = {Surface tension and dilation rheology of DNA solutions in mixtures with azobenzene-containing cationic surfactant}, series = {Colloids and surfaces : an international journal devoted to the principles and applications of colloid and interface science ; A, Physicochemical and engineering aspects}, volume = {505}, journal = {Colloids and surfaces : an international journal devoted to the principles and applications of colloid and interface science ; A, Physicochemical and engineering aspects}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0927-7757}, doi = {10.1016/j.colsurfa.2016.04.021}, pages = {186 -- 192}, year = {2016}, abstract = {The surface tension and dilational surface visco-elasticity of the individual solutions of the biopolymer DNA and the azobenzene-containing cationic surfactant AzoTAB, as well as their mixtures were measured using the drop profile analysis tensiometry. The negatively charged DNA molecules form complexes with the cationic surfactant AzoTAB. Mixed DNA + AzoTAB solutions exhibit high surface activity and surface layer elasticity. Extremes in the dependence of these characteristics on the AzoTAB concentration exist within the concentration range of 3 x 10(-6)-5 x 10(-5) M. The surface tension of the mixture shows a minimum with a subsequent maximum. In the same concentration range the elasticity shows first a maximum and then a subsequent minimum. A recently developed thermodynamic model was modified to account for the dependence of the adsorption equilibrium constant of the adsorbed complex on the cationic surfactant concentration. This modified theory shows good agreement with the experimental data both for the surface tension and the elasticity values over the entire range of studied AzoTAB concentrations. (C) 2016 Elsevier B.V. All rights reserved.}, language = {en} } @article{MorettiClementiniMarconietal.2016, author = {Moretti, M. I. and Clementini, Gisella and Marconi, V. Ripepi M. and Rubele, S. and Cioni, Maria-Rosa L. and Muraveva, T. and Groenewegen, M. A. T. and Cross, N. J. G. and Ivanov, V. D. and Piatti, A. E. and de Grijs, Richard}, title = {The VMC survey - XX. Identification of new Cepheids in the Small Magellanic Cloud}, series = {Monthly notices of the Royal Astronomical Society}, volume = {459}, journal = {Monthly notices of the Royal Astronomical Society}, publisher = {Oxford Univ. Press}, address = {Oxford}, issn = {0035-8711}, doi = {10.1093/mnras/stw716}, pages = {1687 -- 1697}, year = {2016}, abstract = {We present K-s-band light curves for 299 Cepheids in the Small Magellanic Cloud (SMC) of which 288 are new discoveries that we have identified using multi-epoch near-infrared photometry obtained by the VISTA survey of the Magellanic Clouds system (VMC). The new Cepheids have periods in the range from 0.34 to 9.1 d and cover the magnitude interval 12.9 <= currency sign < K-s > <= currency sign 17.6 mag. Our method was developed using variable stars previously identified by the optical microlensing survey OGLE. We focus on searching new Cepheids in external regions of the SMC for which complete VMC K-s-band observations are available and no comprehensive identification of different types of variable stars from other surveys exists yet.}, language = {en} } @article{MuellerNanovaGlaseretal.2016, author = {Mueller, Lars and Nanova, Diana and Glaser, Tobias and Beck, Sebastian and Pucci, Annemarie and Kast, Anne K. and Schroeder, Rasmus R. and Mankel, Eric and Pingel, Patrick and Neher, Dieter and Kowalsky, Wolfgang and Lovrincic, Robert}, title = {Charge-Transfer-Solvent Interaction Predefines Doping Efficiency in p-Doped P3HT Films}, series = {Chemistry of materials : a publication of the American Chemical Society}, volume = {28}, journal = {Chemistry of materials : a publication of the American Chemical Society}, publisher = {American Chemical Society}, address = {Washington}, issn = {0897-4756}, doi = {10.1021/acs.chemmater.6b01629}, pages = {4432 -- 4439}, year = {2016}, abstract = {Efficient electrical doping of organic semiconductors is a necessary prerequisite for the fabrication of high performance organic electronic devices. In this work, we study p-type doping of poly(3-hexylthiophene) (P3HT) with 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane (F(4)TCNQ) spin-cast from two different solvents. Using electron diffraction, we find strong dopant-induced pi-pi-stacking for films from the solvent chloroform, but not from chlorobenzene. This image is confirmed and expanded by the analysis of vibrational features of P3HT and polaron absorptions using optical spectroscopy. Here, a red-shifted polaron absorption is found in doped films from chloroform, caused by a higher conjugation length of the polymer backbone. These differences result in a higher conductivity of films from chloroform. We use optical spectroscopy on the corresponding blend solutions to shed light on the origin of this effect and propose a model to explain why solutions of doped P3HT reveal more aggregation of charged molecules in chlorobenzene, whereas more order is finally observed in dried films from chloroform. Our study emphasizes the importance of solvent parameters exceeding the bare solubility of pure dopant and host material for the preparation of highly conductive doped films.}, language = {en} }