@misc{AntonLaschewsky1994, author = {Anton, Peter and Laschewsky, Andr{\´e}}, title = {Solubilization by polysoaps}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-17327}, year = {1994}, abstract = {The aqueous solubilization power of several series of micellar homopolymers and copolymers (polysoaps) is investigated. Using five insoluble or poorly water-soluble dyes, comparisons of the capacities are made with respect ot the influence of structural variables such as the polymer backbone, the polymer geometry, the comonomer content, and the charge of the hydrophilic group. Some guidelines for polysoap structures suited for efficient solubilization are established. Noteworthy is that the solubilization capacities of the polysoaps are neither linked to the ability to reduce the surface tension of water, nor to the polarity of the solubilization sites deduced from spectroscopic probes.}, language = {en} } @misc{AscherChinPetzoldetal.1994, author = {Ascher, Uri M. and Chin, Hongsheng and Petzold, Linda R. and Reich, Sebastian}, title = {Stabilization of constrained mechanical systems with DAEs and invariant manifolds}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-15698}, year = {1994}, abstract = {Many methods have been proposed for the simulation of constrained mechanical systems. The most obvious of these have mild instabilities and drift problems. Consequently, stabilization techniques have been proposed A popular stabilization method is Baumgarte's technique, but the choice of parameters to make it robust has been unclear in practice. Some of the simulation methods that have been proposed and used in computations are reviewed here, from a stability point of view. This involves concepts of differential-algebraic equation (DAE) and ordinary differential equation (ODE) invariants. An explanation of the difficulties that may be encountered using Baumgarte's method is given, and a discussion of why a further quest for better parameter values for this method will always remain frustrating is presented. It is then shown how Baumgarte's method can be improved. An efficient stabilization technique is proposed, which may employ explicit ODE solvers in case of nonstiff or highly oscillatory problems and which relates to coordinate projection methods. Examples of a two-link planar robotic arm and a squeezing mechanism illustrate the effectiveness of this new stabilization method.}, language = {en} } @misc{AscherChinReich1994, author = {Ascher, Uri M. and Chin, Hongsheng and Reich, Sebastian}, title = {Stabilization of DAEs and invariant manifolds}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-15625}, year = {1994}, abstract = {Many methods have been proposed for the stabilization of higher index differential-algebraic equations (DAEs). Such methods often involve constraint differentiation and problem stabilization, thus obtaining a stabilized index reduction. A popular method is Baumgarte stabilization, but the choice of parameters to make it robust is unclear in practice. Here we explain why the Baumgarte method may run into trouble. We then show how to improve it. We further develop a unifying theory for stabilization methods which includes many of the various techniques proposed in the literature. Our approach is to (i) consider stabilization of ODEs with invariants, (ii) discretize the stabilizing term in a simple way, generally different from the ODE discretization, and (iii) use orthogonal projections whenever possible. The best methods thus obtained are related to methods of coordinate projection. We discuss them and make concrete algorithmic suggestions.}, language = {en} } @misc{CsikszentmihalyiSchiefele1994, author = {Csikszentmihalyi, Mihaly and Schiefele, Ulrich}, title = {Interest and the Quality of Experience in Classrooms}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-33647}, year = {1994}, abstract = {This study investigated the relation between interest in four different subject areas (mathematics, biology, English, history) and the quality of experience in class. The strength of interest as a predictor of experience was contrasted with that of achievement motivation and scholastic ability. A total of208 highly able freshmen and sophomores completed interest ratings, an achievement motivation questionnaire, and the Preliminary Scholastic Aptitude Test (PSAT). These assessments were followed by one week of experience sampling. In addition, grades were available for the subject areas involved. The results showed that interest was a significant predictor of the experience of potency, intrinsic motivation, self-esteem, and perception of skill. Controlling for ability and achievement motivation did not decrease the strength of these relations. Achievement motivation and ability proved to be considerably weaker predictors of the quality of experience than was interest. In addition, interest contributed significantly to the prediction of grades in mathematics, biology, and history, but not English. The main results and some limitations of the study are discussed, and suggestions for future research are made.}, language = {en} } @misc{ElsenbeerCasselZuniga1994, author = {Elsenbeer, Helmut and Cassel, Keith and Zu{\~n}iga, L.}, title = {Throughfall in the terra firme forest of Western Amazonia}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-16955}, year = {1994}, abstract = {Throughfall measurements were made under primary terra firme rainforest in the Rio Pichis valley, in the Upper Amazon Basin of Peru. Based on 214 precipitation events over nearly 18 months, throughfall was estimated to be 83.1±8.8\% of gross precipitation. Regression analysis of all events revealed that gross precipitation is the only significant explanatory variable; the use of one-burst events does not significantly improve the regression relationship. Gross precipitation is, however, a poor predictor of throughfall for small rainfall events. The two forest structure parameters, canopy capacity, S, and free throughfall coefficient, p, were determined to be 1.3±0.2 mm and 0.32±0.18 mm. Rainfall intensity was found to influence these parameters. New methods which attempt to minimize the influence of meteorologic variables are used to estimate the potential values of these canopy parameters.}, language = {en} } @misc{ElsenbeerWestBonell1994, author = {Elsenbeer, Helmut and West, Adam and Bonell, Mike}, title = {Hydrologic pathways and stormflow hydrochemistry at South Creek, northeast Queensland}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-16904}, year = {1994}, abstract = {Earlier investigations at South Creek in northeastern Queensland established the importance of overland flow as a hydrologic pathway in this tropical rainforest environment. Since this pathway is 'fast', transmitting presumably 'new' water, its importance should be reflected in the stormflow chemistry of South Creek: the greater the volumentric contribution to the stormflow hydrograph, the more similarity between the chemical composition of streamwater and of overland flow is to be expected. Water samples were taken during two storm events in an ephemeral gully (gully A), an intermittent gully (gully B) and at the South Creek catchment outlet; additional spot checks were made in several poorly defined rills. The chemical composition of 'old' water was determined from 45 baseflow samples collected throughout February. The two events differed considerably in their magnitudes, intensities and antecedent moisture conditions. In both events, the stormflow chemistry in South Creek was characterized by a sharp decrease in Ca, Mg, Na, Si, Cl, EC, ANC, alkalinity and total inorganic carbon. pH remained nearly constant with discharge, whereas K increased sharply, as did sulfate in an ill-defined manner. In event 1, this South Creek stormflow pattern was closely matched by the pattern in gully A, implying a dominant contribution of 'new' water. This match was confirmed by the spot samples from rills. Gully B behaved like South Creek itself, but with a dampened 'new' water signal, indicating less overland flow generation in its subcatchment. In event 2, which occurred five days later, the initial 'new' water signal in gully A was rapidly overwhelmed by a different signal which is attributed to rapid drainage from a perched water table. This study shows that stormflow in this rainforest catchment consists predominantly of 'new' water which reaches the stream channel via 'fast' pathways. Where the ephemeral gullies delivering overland flow are incised deeply enough to intersect a perched water table, a delayed, 'old' water-like signal may be transmitted.}, language = {en} } @misc{HenkelCourtoisAspect1994, author = {Henkel, Carsten and Courtois, Jean-Yves and Aspect, Alain}, title = {Atomic diffraction by a thin phase grating}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-42269}, year = {1994}, abstract = {We present a semiclassical perturbation method for the description of atomic diffraction by a weakly modulated potential. It proceeds in a way similar to the treatment of light diffraction by a thin phase grating, and consists in calculating the atomic wavefunction by means of action integrals along the classical trajectories of the atoms in the absence of the modulated part of the potential. The capabilities and the validity condition of the method are illustrated on the well-known case of atomic diffraction by a Gaussian standing wave. We prove that in this situation the perturbation method is equivalent to the Raman-Nath approximation, and we point out that the usually-considered Raman-Nath validity condition can lead to inaccuracies in the evaluation of the phases of the diffraction amplitudes. The method is also applied to the case of an evanescent wave reflection grating, and an analytical expression for the diffraction pattern at any incidence angle is obtained for the first time. Finally, the application of the method to other situations is briefly discussed.}, language = {en} } @misc{HenkelCourtoisKaiseretal.1994, author = {Henkel, Carsten and Courtois, Jean-Yves and Kaiser, Robin and Westbrook, C. and Aspect, Alain}, title = {Phase shifts of atomic de Broglie waves at an evanescent wave mirror}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-42289}, year = {1994}, abstract = {A detailed theoretical investigation of the reflection of an atomic de Broglie wave at an evanescent wave mirror is presented. The classical and the semiclassical descriptions of the reflection process are reviewed, and a full wave-mechanical approach based on the analytical soution of the corresponding Schr{\"o}dinger equation is presented. The phase shift at reflection is calculated exactly and interpreted in terms of instantaneous reflection of the atom at an effective mirror. Besides the semiclassical regime of reflection describable by the WKB method, a pure quantum regime of reflection is identified in the limit where the incident de Broglie wavelength is large compared to the evanescent wave decay length.}, language = {en} } @misc{HenkelSteaneKaiseretal.1994, author = {Henkel, Carsten and Steane, Andrew M. and Kaiser, Robin and Dalibard, Jean}, title = {A modulated mirror for atomic interferometry}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-42279}, year = {1994}, abstract = {A novel atomic beam splitter, using reflection of atoms off an evanescent light wave, is investigated theoretically. The intensity or frequency of the light is modulated in order to create sidebands on the reflected de Broglie wave. The weights and phases of the various sidevands are calculated using three different approaches: the Born approximation, a semiclassical path integral approach, and a numerical solution of the time-dependent Schrdinger equation. We show how this modulated mirror could be used to build practical atomic interferometers.}, language = {en} } @misc{KlieglMayrKrampe1994, author = {Kliegl, Reinhold and Mayr, Ulrich and Krampe, Ralf}, title = {Time-accuracy functions for determining process and person differences : an application to cognitive aging}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-17101}, year = {1994}, abstract = {A paradigm for the determination of time-accuracy functions (TAFs) for individual participants is introduced for two pairs of tasks differing in cognitive complexity, that is, word scanning vs cued recognition and figural scanning vs figural reasoning. TAFs can be used to test dissociations of cognitive processes beyond scale-related ambiguities of ordinal interactions. The approach is applied to examine the cognitive-aging hypothesis that a single slowing factor can account for interactions between adult age and cognitive task complexity. Twenty young and 20 old adults participated in 17 sessions. Presentation times required for 75, 87.5, and 100\% accuracies were determined for each task with a variant of the psychophysical method of limits. Accuracy was fit by negatively accelerated functions of presentation time. State-trace analyses showed that different slowing factors are required for high- and low-complexity tasks. Relations to speed-accuracy and performance-resource functions are discussed.}, language = {en} } @misc{KoeberleLaschewsky1994, author = {K{\"o}berle, Peter and Laschewsky, Andr{\´e}}, title = {Hybrid materials from organic polymers and inorganic salts}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-26884}, year = {1994}, abstract = {The prepaparation of amorphous, homogeneous blends of zwitterionic polymers and transition metal salts was investigated. Homogeneous miscibility was achieved in many cases up to equimolar amounts of salt, depending on the anion and cation chosen. Various analytical techniques point to a solid state solution of the inorganic ions in the polymer matrix.}, language = {en} } @misc{LeimkuhlerReich1994, author = {Leimkuhler, Benedict and Reich, Sebastian}, title = {Symplectic integration of constrained Hamiltonian systems}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-15653}, year = {1994}, abstract = {A Hamiltonian system in potential form (formula in the original abstract) subject to smooth constraints on q can be viewed as a Hamiltonian system on a manifold, but numerical computations must be performed in Rn. In this paper methods which reduce "Hamiltonian differential algebraic equations" to ODEs in Euclidean space are examined. The authors study the construction of canonical parameterizations or local charts as well as methods based on the construction of ODE systems in the space in which the constraint manifold is embedded which preserve the constraint manifold as an invariant manifold. In each case, a Hamiltonian system of ordinary differential equations is produced. The stability of the constraint invariants and the behavior of the original Hamiltonian along solutions are investigated both numerically and analytically.}, language = {en} } @misc{NeuschaeferRubeDeVriesHaeneckeetal.1994, author = {Neusch{\"a}fer-Rube, Frank and DeVries, Christa and H{\"a}necke, Kristina and Jungermann, Kurt and P{\"u}schel, Gerhard Paul}, title = {Molecular cloning and expression of a prostaglandin E₂ receptor of the EP₃ϐ subtype from rat hepatocytes}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-45830}, year = {1994}, abstract = {Rat hepatocytes have previously been reported to possess prostaglandin E₂ receptors of the EP₃-type (EP₃-receptors) that inhibit glucagonstimulated glycogenolysis by decreasing cAMP. Here, the isolation of a functional EP₃ϐ receptor cDNA clone from a rat hepatocyte cDNA library is reported. This clone can be translated into a 362-amino-acid protein, that displays over 95\% homology to the EP₃ϐ receptor from mouse mastocytoma. The amino- and carboxy-terminal region of the protein are least conserved. Transiently transfected HEK 293 cells expressed a single binding site for PGE₂ with an apparent Kd of 15 nM. PGE₂ > PGF₂α > PGD₂ competed for [³H]PGE₂ binding sites as did the EP₃ receptor agonists M\&B 28767 = sulprostone > misoprostol but not the EP₁ receptor antagonist SC 19220. In stably transfected CHO cells M\&B 28767 > sulprostone = PGE₂ > misoprostol > PGF₂α inhibited the forskolin-elicited cAMP formation. Thus, the characteristics of the EP₃ϐ receptor of rat hepatocytes closely resemble those of the EP₃ϐ receptor of mouse mastocytoma.}, language = {en} } @misc{PueschelChrist1994, author = {P{\"u}schel, Gerhard Paul and Christ, Bruno}, title = {Inhibition by PGE₂ of glucagon-induced increase in phosphoenolpyruvate carboxykinase mRNA and acceleration of mRNA degradation in cultured rat hepatocytes}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-45792}, year = {1994}, abstract = {In cultured rat hepatocytes the key gluconeogenic enzyme phosphoenolpyruvate carboxykinase (PCK) is known to be induced by glucagon via an elevation of cAMP. Prostaglandin E₂ has been shown to antagonize the glucagon-activated cAMP formation, glycogen phosphorylase activity and glucose output in hepatocytes. It was the purpose of the current investigation to study the potential of PGE₂ to inhibit the glucagon-induced expression of PCK on the level of mRNA and enzyme activity. PCK mRNA and enzyme activity were increased by 0.1 nM glucagon to a maximum after 2 h and 4 h, respectively. This increase was completely inhibited if 10 μM PGE2 was added concomitantly with glucagon. This inhibition by PGE₂ of glucagon-induced PCK activity was abolished by pertussis toxin treatment. When added at the maximum of PCK mRNA at 2 h, PGE₂ accelerated the decay of mRNA and reduced enzyme activity. This effect was not reversed by pertussis toxin treatment. Since in liver PGE₂ is derived from Kupffer cells, which play a key role in the local inflammatory response, the present data imply that during inflammation PGE₂ may reduce the hepatic gluconeogenic capacity via a Gᵢ-linked signal chain.}, language = {en} } @misc{Reich1994, author = {Reich, Sebastian}, title = {Momentum conserving symplectic integrators}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-16824}, year = {1994}, abstract = {In this paper, we show that symplectic partitioned Runge-Kutta methods conserve momentum maps corresponding to linear symmetry groups acting on the phase space of Hamiltonian differential equations by extended point transformation. We also generalize this result to constrained systems and show how this conservation property relates to the symplectic integration of Lie-Poisson systems on certain submanifolds of the general matrix group GL(n).}, language = {en} } @misc{Selting1994, author = {Selting, Margret}, title = {Question intonation revisited : the intonation of conversational questions}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-43179}, year = {1994}, abstract = {Content: 1. Introduction 2. Aim and approach of the present analysis 3. Non-restrictive 'open' conversational questions 4. More restrictive "narrower" questions 5. "Deviant cases" 6. Conclusions}, language = {en} } @misc{Selting1994, author = {Selting, Margret}, title = {Emphatic speech style : with special focus on the prosodic signalling of heightened emotive involvement in conservation}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-37933}, year = {1994}, abstract = {After a review of previous work on the prosody of emotional involvement, data extracts from natural conversations are analyzed in order to argue for the constitution of an 'emphatic (speech) style', which linguistic devices are used to signal heightened emotive involvement. Participants use prosodic cues, in co-occurrence with syntactic and lexical cues, to contextualize turn-constructional units as 'emphatic'. Only realizations of prosodic categories that are marked in relation to surrounding uses of these categories have the power to contextualize units as displaying 'more-than-normal involvement'. In the appropriate context, and in cooccurrence with syntactic and lexical cues and sequential position, the context-sensitive interpretation of this involvement is 'emphasis'. Prosodic marking is used in addition to various unmarked cues that signal and constitute different activity types in conversation. Emphatic style highlights and reinforms particular conversational activities, and makes certain types of recipient responses locally relevant. In particular, switches from non-emphatic to emphatic style are used to contextualize 'peaks of involvement' or 'climaxes' in story-telling. These are shown in the paper to be 'staged' by speakers and treated by recipients as marked activities calling for displays of alignment with respect to the matter at hand. Signals of emphasis are deployable as techniques for locally organizing demonstrations of shared understanding and participant reciprocity in conversational interaction.}, language = {en} } @misc{WatanabePueschelGardemannetal.1994, author = {Watanabe, Yuji and P{\"u}schel, Gerhard Paul and Gardemann, Andreas and Jungermann, Kurt}, title = {Presinusoidal and proximal intrasinusoidal confluence of hepatic artery and portal vein in rat liver : functional evidence by orthograde and retrograde bivascular perfusion}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-16702}, year = {1994}, abstract = {The site of confluence of the artery and the portal vein in the liver still appears to be controversial. Anatomical studies suggested a presinusoidal or an intrasinusoidal confluence in the first, second or even final third of the sinusoids. The objective of this investigation was to study the problem with functional biochemical techniques. Rat livers were perfused through the hepatic artery and simultaneously either in the orthograde direction from the portal vein to the hepatic vein or in the retrograde direction from the hepatic vein to the portal vein. Arterial how was linearly dependent on arterial pressure between 70 cm H2O and 120 cm H2O at a constant portal or hepatovenous pressure of 18 cm H2O. An arterial pressure of 100 cm H2O was required for the maintenance of a homogeneous orthograde perfusion of the whole parenchyma and of a physiologic ratio of arterial to portal how of about 1:3. Glucagon was infused either through the artery or the portal vein and hepatic vein, respectively, to a submaximally effective ''calculated'' sinusoidal concentration after mixing of 0.1 nmol/L. During orthograde perfusions, arterial and portal glucagon caused the same increases in glucose output. Yet during retrograde perfusions, hepatovenous glucagon elicited metabolic alterations equal to those in orthograde perfusions, whereas arterial glucagon effected changes strongly reduced to between 10\% and 50\%. Arterially infused trypan blue was distributed homogeneously in the parenchyma during orthograde perfusions, whereas it reached clearly smaller areas of parenchyma during retrograde perfusions. Finally, arterially applied acridine orange was taken up by all periportal hepatocytes in the proximal half of the acinus during orthograde perfusions but only by a much smaller portion of periportal cells in the proximal third of the acinus during retrograde perfusions. These findings suggest that in rat liver, the hepatic artery and the portal vein mix before and within the first third of the sinusoids, rather than in the middle or even last third.}, language = {en} }