@article{SchneiderWetterichSchirrmeisteretal.2016, author = {Schneider, Andrea and Wetterich, Sebastian and Schirrmeister, Lutz and Herzschuh, Ulrike and Meyer, Hanno and Pestryakova, Luidmila Agafyevna}, title = {Freshwater ostracods (Crustacea) and environmental variability of polygon ponds in the tundra of the Indigirka Lowland, north-east Siberia}, series = {Polar research : a Norwegian journal of Polar research}, volume = {35}, journal = {Polar research : a Norwegian journal of Polar research}, publisher = {Society of Exploration Geophysicists}, address = {Abingdon}, issn = {0800-0395}, doi = {10.3402/polar.v35.25225}, pages = {22}, year = {2016}, abstract = {Freshwater ostracods (Crustacea, Ostracoda) are valuable biological indicators. In Arctic environments, their habitat conditions are barely known and the abundance and diversity of ostracods is documented only in scattered records with incomplete ecological characterization. To determine the taxonomic range of ostracod assemblages and their habitat conditions in polygon ponds in the Indigirka Lowland, north-east Siberia, we collected more than 100 living ostracod individuals per site with a plankton net (mesh size 65 mm) and an exhaustor system from 27 water bodies and studied them in the context of substrate and hydrochemical data. During the summer of 2011, a single pond site and its ostracod population was selected for special study. This first record of the ostracod fauna in the Indigirka Lowland comprises eight species and three additional taxa. Fabaeformiscandona krochini and F. groenlandica were documented for the first time in continental Siberia. Repeated sampling of a low-centre polygon pond yielded insights into the population dynamics of F. pedata. We identified air temperature and precipitation as the main external drivers of water temperatures, water levels, ion concentrations and water stable isotope composition on diurnal and seasonal scales.}, language = {en} } @article{SchneidervanSchaikZangerleetal.2016, author = {Schneider, A. -K. and van Schaik, L. and Zangerle, A. and Eccard, Jana and Schroeder, B.}, title = {Which abiotic filters shape earthworm distribution patterns at the catchment scale?}, series = {European journal of soil science}, volume = {67}, journal = {European journal of soil science}, publisher = {Wiley-Blackwell}, address = {Hoboken}, issn = {1351-0754}, doi = {10.1111/ejss.12346}, pages = {431 -- 442}, year = {2016}, abstract = {Earthworms affect various soil ecosystem processes in their role as ecosystem engineers. The spatial distribution of earthworms determines the spatial distribution of their functional effects. In particular, earthworm-induced macropore networks may act as preferential flow pathways. In this research we aimed to determine earthworm distributions at the catchment scale with species distribution models (SDMs). We used land-use types, temporally invariant topography-related variables and plot-scale soil characteristics such as pH and organic matter content. We used data from spring 2013 to estimate probability distributions of the occurrence of ten earthworm species. To assess the robustness of these models, we tested temporal transferability by evaluating the accuracy of predictions from the models derived for the spring data with the predictions from data of two other field surveys in autumn 2012 and 2013. In addition, we compared the performance of SDMs based (i) on temporally varying plot-scale predictor variables with (ii) those based on temporally invariant catchment-scale predictors. Models based on catchment-scale predictors, especially land use and slope, experience a small loss of predictive performance only compared with plot-scale SDMs but have greater temporal transferability. Earthworm distribution maps derived from this kind of SDM are a prerequisite for understanding the spatial distribution patterns of functional effects related to earthworms.}, language = {en} } @article{Schmiegel2016, author = {Schmiegel, Tobias}, title = {Diskussionsbericht zum Vortrag von Prof. Dr. Ulrich Torggler LL.M. (Comell), (Universit{\"a}t Wien) "Psychologie der Massen - Neue Herausforderungen zur Einhegung von Fanverhalten im Profisport"}, series = {Aktuelle Rechtsfragen im Profifußball : psychologische Faktoren und rechtliche Gestaltung}, journal = {Aktuelle Rechtsfragen im Profifußball : psychologische Faktoren und rechtliche Gestaltung}, publisher = {Nomos}, address = {Bade-Baden}, isbn = {978-3-8487-2326-3}, pages = {181 -- 186}, year = {2016}, language = {de} } @article{SchmiedelArayaBortolottoetal.2016, author = {Schmiedel, Ute and Araya, Yoseph and Bortolotto, Maria Ieda and Boeckenhoff, Linda and Hallwachs, Winnie and Janzen, Daniel and Kolipaka, Shekhar S. and Novotny, Vojtech and Palm, Matilda and Parfondry, Marc and Smanis, Athanasios and Toko, Pagi}, title = {Contributions of paraecologists and parataxonomists to research, conservation, and social development}, series = {Conservation biology : the journal of the Society for Conservation Biology}, volume = {30}, journal = {Conservation biology : the journal of the Society for Conservation Biology}, publisher = {Wiley-Blackwell}, address = {Hoboken}, issn = {0888-8892}, doi = {10.1111/cobi.12661}, pages = {506 -- 519}, year = {2016}, abstract = {Citizen science has been gaining momentum in the United States and Europe, where citizens are literate and often interested in science. However, in developing countries, which have a dire need for environmental data, such programs are slow to emerge, despite the large and untapped human resources in close proximity to areas of high biodiversity and poorly known floras and faunas. Thus, we propose that the parataxonomist and paraecologist approach, which originates from citizen-based science, is well suited to rural areas in developing countries. Being a paraecologist or a parataxonomist is a vocation and entails full-time employment underpinned by extensive training, whereas citizen science involves the temporary engagement of volunteers. Both approaches have their merits depending on the context and objectives of the research. We examined 4 ongoing paraecologist or parataxonomist programs in Costa Rica, India, Papua New Guinea, and southern Africa and compared their origins, long-term objectives, implementation strategies, activities, key challenges, achievements, and implications for resident communities. The programs supported ongoing research on biodiversity assessment, monitoring, and management, and participants engaged in non-academic capacity development in these fields. The programs in Southern Africa related to specific projects, whereas the programs in Costa Rica, India, and Papua New Guinea were designed for the long term, provided sufficient funding was available. The main focus of the paraecologists' and parataxonomists' activities ranged from collection and processing of specimens (Costa Rica and Papua New Guinea) or of socioeconomic and natural science data (India and Southern Africa) to communication between scientists and residents (India and Southern Africa). As members of both the local land user and research communities, paraecologists and parataxonomists can greatly improve the flow of biodiversity information to all users, from local stakeholders to international academia.}, language = {en} } @article{SchmiedchenLongardtLouietal.2016, author = {Schmiedchen, Bettina and Longardt, Ann Carolin and Loui, Andrea and Buehrer, Christoph and Raila, Jens and Schweigert, Florian J.}, title = {Effect of vitamin A supplementation on the urinary retinol excretion in very low birth weight infants}, series = {European journal of pediatrics : official organ of the Belgian Pediatric Association}, volume = {175}, journal = {European journal of pediatrics : official organ of the Belgian Pediatric Association}, publisher = {Springer}, address = {New York}, issn = {0340-6199}, doi = {10.1007/s00431-015-2647-9}, pages = {365 -- 372}, year = {2016}, abstract = {Despite high-dose vitamin A supplementation of very low birth weight infants (VLBW, <1500 g), their vitamin A status does not improve substantially. Unknown is the impact of urinary retinol excretion on the serum retinol concentration in these infants. Therefore, the effect of high-dose vitamin A supplementation on the urinary vitamin A excretion in VLBW infants was investigated. Sixty-three VLBW infants were treated with vitamin A (5000 IU intramuscular, 3 times/week for 4 weeks); 38 untreated infants were classified as control group. On days 3 and 28 of life, retinol, retinol-binding protein 4 (RBP4), glomerular filtration rate, proteinuria, and Tamm-Horsfall protein were quantified in urine. On day 3 of life, substantial retinol and RBP4 losses were found in both groups, which significantly decreased until day 28. Notwithstanding, the retinol excretion was higher (P<0.01) under vitamin A supplementation as compared to infants of the control group. On day 28 of life, the urinary retinol concentrations were predictive for serum retinol concentrations in the vitamin A treated (P<0.01), but not in the control group (P=0.570). Conclusion: High urinary retinol excretion may limit the vitamin A supplementation efficacy in VLBW infants. Advanced age and thus postnatal kidney maturation seems to be an important contributor in the prevention of urinary retinol losses.}, language = {en} } @book{Schmidt2016, author = {Schmidt, Thorsten Ingo}, title = {Finanzierungspflichten und Konnexit{\"a}tsprinzip}, series = {Recht der Steuern und der {\"o}ffentlichen Finanzordnung ; 10}, journal = {Recht der Steuern und der {\"o}ffentlichen Finanzordnung ; 10}, editor = {Gosch, Dietmar and Hufeld, Ulrich and Kirchhof, Gregor and Rust, Alexander and Schenke, Ralf and Tappe, Henning and Weitemeyer, Birgit}, publisher = {Nomos}, address = {Baden-Baden}, isbn = {978-3-8487-2822-0}, publisher = {Universit{\"a}t Potsdam}, pages = {86}, year = {2016}, abstract = {Die Finanzkrise der Kommunen beruht auch auf der {\"U}bertragung staatlicher Aufgaben ohne entsprechenden finanziellen Ausgleich. Davor sollen nun das grundgesetzliche Aufgaben{\"u}bertragungsverbot vom Bund auf die Kommunen und die landesverfassungsrechtlichen Konnexit{\"a}tsregeln beim Transfer vom Land auf die Kommunen sch{\"u}tzen. Zwar ist anerkannt, dass diese Vorschriften f{\"u}r Sachaufgaben gelten. Doch ist streitig, ob dies auch f{\"u}r die Auferlegung von Finanzierungspflichten zu gelten hat. Der Autor vergleicht die landesverfassungsrechtlichen Bestimmungen in ihrer Auslegung durch das jeweilige Landesverfassungsgericht und arbeitet unter besonderer Ber{\"u}cksichtigung der nordrhein-westf{\"a}lischen Rechtslage heraus, dass die {\"U}bertragungsvorschriften nicht umgangen werden d{\"u}rfen. {\"U}bertragung einer Sachaufgabe und Auferlegung einer Finanzierungspflicht sind funktionell gleichwertig und beide konnexit{\"a}tsrelevant. Der Autor ist Direktor des Kommunalwissenschaftlichen Instituts der Universit{\"a}t Potsdam.}, language = {de} } @book{Schmidt2016, author = {Schmidt, Thorsten Ingo}, title = {Das Mitverwaltungsmodell}, series = {Kommunalrechtliche Studien ; 3}, journal = {Kommunalrechtliche Studien ; 3}, editor = {Br{\"u}ning, Christoph and Schmidt, Thorsten Ingo}, publisher = {Nomos}, address = {Baden-Baden}, isbn = {978-3-8487-2797-1}, publisher = {Universit{\"a}t Potsdam}, pages = {165}, year = {2016}, abstract = {Demographischer Wandel einerseits und zunehmende Aufgaben andererseits erzwingen bei finanzieller Notlage kommunale Reformen. Vielfach antworten die Landesgesetzgeber auf diesen Reformbedarf mit immer gr{\"o}ßeren kommunalen Einheiten. Um dieser „Flucht in die Einheitsgemeinde" entgegenzuwirken, entwickelt der Verfasser das Mitverwaltungsmodell: Eine Gemeinde bleibt zwar rechtlich selbstst{\"a}ndig, bedient sich aber der hauptamtlichen Verwaltung einer anderen Gemeinde. Die M{\"o}glichkeit einer solchen {\"o}ffentlich-rechtlichen Gesch{\"a}ftsbesorgung wird unter Wahrung der Selbstverwaltungsgarantie beider Gemeinden entfaltet. Die notwendigen gesetzlichen Bestimmungen und vertraglichen Regelungen werden entworfen. Dieses Modell soll im Rahmen der Brandenburgischen Verwaltungsstrukturreform umgesetzt werden und kann auch anderen L{\"a}ndern als Vorbild dienen. Der Autor ist Direktor des Kommunalwissenschaftlichen Instituts der Universit{\"a}t Potsdam.}, language = {de} } @article{SchmidtSaxenhoferDrewesetal.2016, author = {Schmidt, Sabrina and Saxenhofer, Moritz and Drewes, Stephan and Schlegel, Mathias and Wanka, Konrad M. and Frank, Raphael and Klimpel, Sven and von Blanckenhagen, Felix and Maaz, Denny and Herden, Christiane and Freise, Jona and Wolf, Ronny and Stubbe, Michael and Borkenhagen, Peter and Ansorge, Hermann and Eccard, Jana and Lang, Johannes and Jourdain, Elsa and Jacob, Jens and Marianneau, Philippe and Heckel, Gerald and Ulrich, Rainer G{\"u}nter}, title = {High genetic structuring of Tula hantavirus}, series = {Archives of virology}, volume = {161}, journal = {Archives of virology}, publisher = {Springer}, address = {Wien}, issn = {0304-8608}, doi = {10.1007/s00705-016-2762-6}, pages = {1135 -- 1149}, year = {2016}, abstract = {Tula virus (TULV) is a vole-associated hantavirus with low or no pathogenicity to humans. In the present study, 686 common voles (Microtus arvalis), 249 field voles (Microtus agrestis) and 30 water voles (Arvicola spec.) were collected at 79 sites in Germany, Luxembourg and France and screened by RT-PCR and TULV-IgG ELISA. TULV-specific RNA and/or antibodies were detected at 43 of the sites, demonstrating a geographically widespread distribution of the virus in the studied area. The TULV prevalence in common voles (16.7 \%) was higher than that in field voles (9.2 \%) and water voles (10.0 \%). Time series data at ten trapping sites showed evidence of a lasting presence of TULV RNA within common vole populations for up to 34 months, although usually at low prevalence. Phylogenetic analysis demonstrated a strong genetic structuring of TULV sequences according to geography and independent of the rodent species, confirming the common vole as the preferential host, with spillover infections to co-occurring field and water voles. TULV phylogenetic clades showed a general association with evolutionary lineages in the common vole as assessed by mitochondrial DNA sequences on a large geographical scale, but with local-scale discrepancies in the contact areas.}, language = {en} } @article{SchmidtWalzJonesetal.2016, author = {Schmidt, Katja and Walz, Ariane and Jones, Isobel and Metzger, Marc J.}, title = {The Sociocultural Value of Upland Regions in the Vicinity of Cities in Comparison With Urban Green Spaces}, series = {Mountain research and development}, volume = {36}, journal = {Mountain research and development}, publisher = {American Geophysical Union}, address = {Lawrence}, issn = {0276-4741}, doi = {10.1659/MRD-JOURNAL-D-16-00044.1}, pages = {465 -- 474}, year = {2016}, language = {en} } @misc{SchmidtSachseWalz2016, author = {Schmidt, Katja and Sachse, Rene and Walz, Ariane}, title = {Current role of social benefits in ecosystem service assessments}, series = {Landscape and urban planning : an international journal of landscape ecology, planning and design}, volume = {149}, journal = {Landscape and urban planning : an international journal of landscape ecology, planning and design}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0169-2046}, doi = {10.1016/j.landurbplan.2016.01.005}, pages = {49 -- 64}, year = {2016}, abstract = {Ecosystem services have a significant impact on human wellbeing. While ecosystem services are frequently represented by monetary values, social values and underlying social benefits remain underexplored. The purpose of this study is to assess whether and how social benefits have been explicitly addressed within socio-economic and socio-cultural ecosystem services research, ultimately allowing a better understanding between ecosystem services and human well-being. In this paper, we reviewed 115 international primary valuation studies and tested four hypotheses associated to the identification of social benefits of ecosystem services using logistic regressions. Tested hypotheses were that (1) social benefits are mostly derived in studies that assess cultural ecosystem services as opposed to other ecosystem service types, (2) there is a pattern of social benefits and certain cultural ecosystem services assessed simultaneously, (3) monetary valuation techniques go beyond expressing monetary values and convey social benefits, and (4) directly addressing stakeholde\&\#341;s views the consideration of social benefits in ecosystem service assessments. Our analysis revealed that (1) a variety of social benefits are valued in studies that assess either of the four ecosystem service types, (2) certain social benefits are likely to co-occur in combination with certain cultural ecosystem services, (3) of the studies that employed monetary valuation techniques, simulated market approaches overlapped most frequently with the assessment of social benefits and (4) studies that directly incorporate stakeholder's views were more likely to also assess social benefits.}, language = {en} } @article{SchmidtRoedigerGruneretal.2016, author = {Schmidt, Carsten and Roediger, Stefan and Gruner, Melanie and Moncsek, Anja and Stohwasser, Ralf and Hanack, Katja and Schierack, Peter and Schroeder, Christian}, title = {Multiplex localization of sequential peptide epitopes by use of a planar microbead chip}, series = {Analytica chimica acta : an international journal devoted to all branches of analytical chemistry}, volume = {908}, journal = {Analytica chimica acta : an international journal devoted to all branches of analytical chemistry}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0003-2670}, doi = {10.1016/j.aca.2015.12.030}, pages = {150 -- 160}, year = {2016}, abstract = {Epitope mapping is crucial for the characterization of protein-specific antibodies. Commonly, small overlapping peptides are chemically synthesized and immobilized to determine the specific peptide sequence. In this study, we report the use of a fast and inexpensive planar microbead chip for epitope mapping. We developed a generic strategy for expressing recombinant peptide libraries instead of using expensive synthetic peptide libraries. A biotin moiety was introduced in vivo at a defined peptide position using biotin ligase. Peptides in crude Escherichia coli lysate were coupled onto streptavidin-coated microbeads by incubation, thereby avoiding tedious purification procedures. For read-out we used a multiplex planar microbead chip with size- and fluorescence-encoded microbead populations. For epitope mapping, up to 18 populations of peptide-loaded microbeads (at least 20 microbeads per peptide) displaying the primary sequence of a protein were analyzed simultaneously. If an epitope was recognized by an antibody, a secondary fluorescence-labeled antibody generated a signal that was quantified, and the mean value of all microbeads in the population was calculated. We mapped the epitopes for rabbit anti-PA28 gamma (proteasome activator 28 gamma) polyclonal serum, for a murine monoclonal antibody against PA28 gamma, and for a murine monoclonal antibody against the hamster polyoma virus major capsid protein VP1 as models. In each case, the identification of one distinct peptide sequence out of up to 18 sequences was possible. Using this approach, an epitope can be mapped multiparametrically within three weeks. (C) 2016 Elsevier B.V. All rights reserved.}, language = {en} } @article{SchmidtLorenz2016, author = {Schmidt, Burkhard and Lorenz, Ulf}, title = {WavePacket}, series = {Computer physics communications : an international journal devoted to computational physics and computer programs in physics}, volume = {213}, journal = {Computer physics communications : an international journal devoted to computational physics and computer programs in physics}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0010-4655}, doi = {10.1016/j.cpc.2016.12.007}, pages = {223 -- 234}, year = {2016}, abstract = {WavePacket is an open-source program package for the numerical simulation of quantum-mechanical dynamics. It can be used to solve time-independent or time-dependent linear Schr{\"o}dinger and Liouville-von Neumann-equations in one or more dimensions. Also coupled equations can be treated, which allows to simulate molecular quantum dynamics beyond the Born-Oppenheimer approximation. Optionally accounting for the interaction with external electric fields within the semiclassical dipole approximation, WavePacket can be used to simulate experiments involving tailored light pulses in photo-induced physics or chemistry. The graphical capabilities allow visualization of quantum dynamics 'on the fly', including Wigner phase space representations. Being easy to use and highly versatile, WavePacket is well suited for the teaching of quantum mechanics as well as for research projects in atomic, molecular and optical physics or in physical or theoretical chemistry. The present Part I deals with the description of closed quantum systems in terms of Schr{\"o}dinger equations. The emphasis is on discrete variable representations for spatial discretization as well as various techniques for temporal discretization. The upcoming Part II will focus on open quantum systems and dimension reduction; it also describes the codes for optimal control of quantum dynamics. The present work introduces the MATLAB version of WavePacket 5.2.1 which is hosted at the Sourceforge platform, where extensive Wiki-documentation as well as worked-out demonstration examples can be found.}, language = {en} } @article{SchmidtZiemannPentzienetal.2016, author = {Schmidt, Birgit Angelika and Ziemann, Martin Andreas and Pentzien, Simone and Gabsch, Toralf and Koch, Werner and Kr{\"u}ger, J{\"o}rg}, title = {Technical analysis of a Central Asian wall painting detached from a Buddhist cave temple on the northern Silk Road}, series = {Studies in Conservation}, volume = {61}, journal = {Studies in Conservation}, publisher = {Routledge, Taylor \& Francis Group}, address = {Abingdon}, issn = {0039-3630}, doi = {10.1179/2047058414Y.0000000152}, pages = {113 -- 122}, year = {2016}, abstract = {A great number of Central Asian wall paintings, archeological materials, architectural fragments, and textiles, as well as painting fragments on silk and paper, make up the so called Turfan Collection at the Asian Art Museum in Berlin. The largest part of the collection comes from the Kucha region, a very important cultural center in the third to ninth centuries. Between 1902 and 1914, four German expeditions traveled along the northern Silk Road. During these expeditions, wall paintings were detached from their original settings in Buddhist cave complexes. This paper reports a technical study of a wall painting, existing in eight fragments, from the Buddhist cave no. 40 (Ritterhohle). Its original painted surface is soot blackened and largely illegible. Gruwedel, leader of the first and third expeditions, described the almost complete destruction of the rediscovered temple complex and evidence of fire damage. The aim of this case study is to identify the materials used for the wall paintings. Furthermore, soot deposits as well as materials from conservation interventions were of interest. Non-invasive analyses were preferred but a limited number of samples were taken to provide more precise information on the painting technique. By employing optical and scanning electron microscopy, energy dispersive X-ray spectroscopy, micro X-ray fluorescence spectroscopy, X-ray diffraction analysis, and Raman spectroscopy, a layer sequence of earthen render, a ground layer made of gypsum, and a paint layer containing a variety of inorganic pigments were identified.}, language = {en} } @article{SchmidtWolfEhlert2016, author = {Schmidt, Bernd and Wolf, Felix and Ehlert, Christopher}, title = {Systematic Investigation into the Matsuda-Heck Reaction of alpha-Methylene Lactones: How Conformational Constraints Direct the beta-H-Elimination Step}, series = {The journal of organic chemistry}, volume = {81}, journal = {The journal of organic chemistry}, publisher = {American Chemical Society}, address = {Washington}, issn = {0022-3263}, doi = {10.1021/acs.joc.6b02207}, pages = {11235 -- 11249}, year = {2016}, abstract = {alpha-Methylene-gamma-butyrolactone and alpha-methylene-gamma-valerolactone undergo Pd-catalyzed Matsuda-Heck couplings with arene diazonium salts to alpha-benzyl butenolides or pentenolides, respectively, or to alpha-benzylidene lactones. The observed regioselectivity is strongly ring size dependent, with six-membered rings giving exclusively alpha-benzyl pentenolides, whereas the five-membered alpha-methylene lactone reacts to mixtures of regioisomers with a high proportion of (E)-alpha-benzylidene-gamma-butyrolactones. DFT calculations suggest that the reasons for these differences are not thermodynamic but kinetic in nature. The relative energies of the conformers of the Pd sigma-complexes resulting from insertion into the Pd-aryl bond were correlated with the dihedral angles between Pd and endo-beta-H. This correlation revealed that in the case of the six-membered lactone an energetically favorable conformer adopts a nearly synperiplanar Pd/endo-beta-H arrangement, whereas for the analogous Pd sigma-complex of the five-membered lactone the smallest Pd/endo-beta-H dihedral angle is observed for a conformer with a comparatively high potential energy. The optimized conditions for Matsuda-Heck arylations of exo-methylene lactones were eventually applied to the synthesis of the natural product anemarcoumarin A.}, language = {en} } @article{SchmidtWolfBrunner2016, author = {Schmidt, Bernd and Wolf, Felix and Brunner, Heiko}, title = {Styrylsulfonates and -Sulfonamides through Pd-Catalysed Matsuda-Heck Reactions of Vinylsulfonic Acid Derivatives and Arenediazonium Salts}, series = {European journal of organic chemistry}, journal = {European journal of organic chemistry}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {1434-193X}, doi = {10.1002/ejoc.201600469}, pages = {2972 -- 2982}, year = {2016}, abstract = {Arene diazonium salts undergo Matsuda-Heck reactions with vinylsulfonates and -sulfonamides to give styrylsulfonic acid derivatives in high to excellent yields and with high to excellent selectivities. By quantifying the evolution of nitrogen over time in a gas-meter apparatus, the reactivities of ethylvinylsulfonate and the benchmark olefin methyl acrylate were compared for an electron-rich and an -deficient arene diazonium salt. Tertiary sulfonamides react in Matsuda-Heck couplings with high conversions, but require long reaction times, which prevents the determination of kinetic data through the measurement of nitrogen evolution. Secondary sulfonamides were found to be unreactive. From these results, the following order of reactivity could be deduced: H2C=CHCO2Me > H2C=CHSO2OEt > H2C=CHSO2N(Me)Bn >> H2C=CHSO2NHBn. Through the Matsuda-Heck coupling of 5-indolyldiazonium salt and a tertiary vinylsulfonamide, the synthesis of the C-5-substituted indole part of the antimigraine drug naratriptan was accomplished in high yield.}, language = {en} } @article{SchmidtRiemer2016, author = {Schmidt, Bernd and Riemer, Martin}, title = {Microwave-Promoted Deprenylation: Prenyl Ether as a Thermolabile Phenol Protecting Group}, series = {Synthesis}, volume = {48}, journal = {Synthesis}, publisher = {Thieme}, address = {Stuttgart}, issn = {0039-7881}, doi = {10.1055/s-0035-1561366}, pages = {1399 -- 1406}, year = {2016}, abstract = {para-Substituted aryl prenyl ethers undergo a deprenylation reaction upon microwave irradiation. This offers the opportunity to use a prenyl ether as a thermolabile protecting group in the synthesis of natural products with a chromone structure, which proceeds via a tandem deprenylation/6-endo-cyclization sequence.}, language = {en} } @article{SchmidtRiemer2016, author = {Schmidt, Bernd and Riemer, Martin}, title = {Synthesis of Allyl- and Prenylcoumarins via Microwave-Promoted Tandem Claisen Rearrangement/Wittig Olefination}, series = {Synthesis}, volume = {48}, journal = {Synthesis}, publisher = {Thieme}, address = {Stuttgart}, issn = {0039-7881}, doi = {10.1055/s-0035-1560501}, pages = {141 -- 149}, year = {2016}, abstract = {Allyl, dimethylallyl, crotyl, and prenyl ethers of various aromatic ortho-hydroxy carbonyl compounds undergo a tandem sequence of Claisen rearrangement, carbonyl olefination, and cyclization upon microwave irradiation in the presence of a stabilized ylide. The products are multiply substituted 6- or 8-allylated or prenylated coumarins (2H-chromen-2-ones).}, language = {en} } @article{SchmidtAudoerschKunz2016, author = {Schmidt, Bernd and Audoersch, Stephan and Kunz, Oliver}, title = {Stereoselective Synthesis of 2Z,4E-Configured Dienoates through Tethered Ring Closing Metathesis}, series = {Synthesis}, volume = {48}, journal = {Synthesis}, publisher = {Thieme}, address = {Stuttgart}, issn = {0039-7881}, doi = {10.1055/s-0035-1562536}, pages = {4509 -- 4518}, year = {2016}, language = {en} } @article{SchmidtRabschBroekeretal.2016, author = {Schmidt, Andreas and Rabsch, Wolfgang and Br{\"o}ker, Nina Kristin and Barbirz, Stefanie}, title = {Bacteriophage tailspike protein based assay to monitor phase variable glucosylations in Salmonella O-antigens}, series = {BMC microbiology}, volume = {16}, journal = {BMC microbiology}, publisher = {BioMed Central}, address = {London}, issn = {1471-2180}, doi = {10.1186/s12866-016-0826-0}, pages = {2214 -- 2226}, year = {2016}, abstract = {Background: Non-typhoid Salmonella Typhimurium (S. Typhimurium) accounts for a high number of registered salmonellosis cases, and O-serotyping is one important tool for monitoring epidemiology and spread of the disease. Moreover, variations in glucosylated O-antigens are related to immunogenicity and spread in the host. However, classical autoagglutination tests combined with the analysis of specific genetic markers cannot always reliably register phase variable glucose modifications expressed on Salmonella O-antigens and additional tools to monitor O-antigen glucosylation phenotypes of S. Typhimurium would be desirable. Results: We developed a test for the phase variable O-antigen glucosylation state of S. Typhimurium using the tailspike proteins (TSP) of Salmonella phages 9NA and P22. We used this ELISA like tailspike adsorption (ELITA) assay to analyze a library of 44 Salmonella strains. ELITA was successful in discriminating strains that carried glucose 1-6 linked to the galactose of O-polysaccharide backbone (serotype O1) from non-glucosylated strains. This was shown by O-antigen compositional analyses of the respective strains with mass spectrometry and capillary electrophoresis. The ELITA test worked rapidly in a microtiter plate format and was highly O-antigen specific. Moreover, TSP as probes could also detect glucosylated strains in flow cytometry and distinguish multiphasic cultures differing in their glucosylation state. Conclusions: Tailspike proteins contain large binding sites with precisely defined specificities and are therefore promising tools to be included in serotyping procedures as rapid serotyping agents in addition to antibodies. In this study, 9NA and P22TSP as probes could specifically distinguish glucosylation phenotypes of Salmonella on microtiter plate assays and in flow cytometry. This opens the possibility for flow sorting of cell populations for subsequent genetic analyses or for monitoring phase variations during large scale O-antigen preparations necessary for vaccine production.}, language = {en} } @article{SchmidtRabschBroekeretal.2016, author = {Schmidt, Andreas and Rabsch, Wolfgang and Broeker, Nina K. and Barbirz, Stefanie}, title = {Bacteriophage tailspike protein based assay to monitor phase variable glucosylations in Salmonella O-antigens}, series = {BMC microbiology}, volume = {16}, journal = {BMC microbiology}, publisher = {BioMed Central}, address = {London}, issn = {1471-2180}, doi = {10.1186/s12866-016-0826-0}, pages = {11}, year = {2016}, abstract = {Background Non-typhoid Salmonella Typhimurium (S. Typhimurium) accounts for a high number of registered salmonellosis cases, and O-serotyping is one important tool for monitoring epidemiology and spread of the disease. Moreover, variations in glucosylated O-antigens are related to immunogenicity and spread in the host. However, classical autoagglutination tests combined with the analysis of specific genetic markers cannot always reliably register phase variable glucose modifications expressed on Salmonella O-antigens and additional tools to monitor O-antigen glucosylation phenotypes of S. Typhimurium would be desirable. Results We developed a test for the phase variable O-antigen glucosylation state of S. Typhimurium using the tailspike proteins (TSP) of Salmonella phages 9NA and P22. We used this ELISA like tailspike adsorption (ELITA) assay to analyze a library of 44 Salmonella strains. ELITA was successful in discriminating strains that carried glucose 1-6 linked to the galactose of O-polysaccharide backbone (serotype O1) from non-glucosylated strains. This was shown by O-antigen compositional analyses of the respective strains with mass spectrometry and capillary electrophoresis. The ELITA test worked rapidly in a microtiter plate format and was highly O-antigen specific. Moreover, TSP as probes could also detect glucosylated strains in flow cytometry and distinguish multiphasic cultures differing in their glucosylation state. Conclusions Tailspike proteins contain large binding sites with precisely defined specificities and are therefore promising tools to be included in serotyping procedures as rapid serotyping agents in addition to antibodies. In this study, 9NA and P22TSP as probes could specifically distinguish glucosylation phenotypes of Salmonella on microtiter plate assays and in flow cytometry. This opens the possibility for flow sorting of cell populations for subsequent genetic analyses or for monitoring phase variations during large scale O-antigen preparations necessary for vaccine production.}, language = {en} } @article{SchlaegelLewis2016, author = {Schl{\"a}gel, Ulrike and Lewis, Mark A.}, title = {A framework for analyzing the robustness of movement models to variable step discretization}, series = {Journal of mathematical biology}, volume = {73}, journal = {Journal of mathematical biology}, publisher = {Springer}, address = {Heidelberg}, issn = {0303-6812}, doi = {10.1007/s00285-016-0969-5}, pages = {815 -- 845}, year = {2016}, abstract = {When sampling animal movement paths, the frequency at which location measurements are attempted is a critical feature for data analysis. Important quantities derived from raw data, e.g. travel distance or sinuosity, can differ largely based on the temporal resolution of the data. Likewise, when movement models are fitted to data, parameter estimates have been demonstrated to vary with sampling rate. Thus, biological statements derived from such analyses can only be made with respect to the resolution of the underlying data, limiting extrapolation of results and comparison between studies. To address this problem, we investigate whether there are models that are robust against changes in temporal resolution. First, we propose a mathematically rigorous framework, in which we formally define robustness as a model property. We then use the framework for a thorough assessment of a range of basic random walk models, in which we also show how robustness relates to other probabilistic concepts. While we found robustness to be a strong condition met by few models only, we suggest a new method to extend models so as to make them robust. Our framework provides a new systematic, mathematically founded approach to the question if, and how, sampling rate of movement paths affects statistical inference.}, language = {en} } @article{SchlaegelLewis2016, author = {Schl{\"a}gel, Ulrike and Lewis, Mark A.}, title = {Robustness of movement models: can models bridge the gap between temporal scales of data sets and behavioural processes?}, series = {Journal of mathematical biology}, volume = {73}, journal = {Journal of mathematical biology}, publisher = {Springer}, address = {Heidelberg}, issn = {0303-6812}, doi = {10.1007/s00285-016-1005-5}, pages = {1691 -- 1726}, year = {2016}, language = {en} } @article{Schlosser2016, author = {Schlosser, Rainer}, title = {Stochastic dynamic pricing and advertising in isoelastic oligopoly models}, series = {European Journal of Operational Research}, volume = {259}, journal = {European Journal of Operational Research}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0377-2217}, doi = {10.1016/j.ejor.2016.11.021}, pages = {1144 -- 1155}, year = {2016}, abstract = {In this paper, we analyze stochastic dynamic pricing and advertising differential games in special oligopoly markets with constant price and advertising elasticity. We consider the sale of perishable as well as durable goods and include adoption effects in the demand. Based on a unique stochastic feedback Nash equilibrium, we derive closed-form solution formulas of the value functions and the optimal feedback policies of all competing firms. Efficient simulation techniques are used to evaluate optimally controlled sales processes over time. This way, the evolution of optimal controls as well as the firms' profit distributions are analyzed. Moreover, we are able to compare feedback solutions of the stochastic model with its deterministic counterpart. We show that the market power of the competing firms is exactly the same as in the deterministic version of the model. Further, we discover two fundamental effects that determine the relation between both models. First, the volatility in demand results in a decline of expected profits compared to the deterministic model. Second, we find that saturation effects in demand have an opposite character. We show that the second effect can be strong enough to either exactly balance or even overcompensate the first one. As a result we are able to identify cases in which feedback solutions of the deterministic model provide useful approximations of solutions of the stochastic model.}, language = {en} } @article{Schlosser2016, author = {Schlosser, Rainer}, title = {Joint stochastic dynamic pricing and advertising with time-dependent demand}, series = {Geophysical journal international}, volume = {73}, journal = {Geophysical journal international}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0165-1889}, doi = {10.1016/j.jedc.2016.10.006}, pages = {439 -- 452}, year = {2016}, abstract = {This paper examines the sale of a finite number of items in a class of stochastic dynamic pricing and advertising models with time-dependent demand elasticities. We prove structural properties of the optimal expected profits with respect to time, inventory level, price impact, advertising impact and different model parameters, such as discount rate, marginal unit costs, and holding costs. We find that the value of an additional item (opportunity costs) is decreasing in the unit costs, the discount rate, the holding cost rate and the number of items left to sell. We also derive structural properties of optimal joint pricing and advertising strategies. This way, we obtain general qualitative insights in the complex interplay and the mutual dependence of optimal pricing and advertising decisions. Among other properties, we show that a higher advertising impact leads to higher optimal prices and lower advertising rates, which in turn implies a lower speed of sale. The results obtained help practitioners to respond to changes in market conditions by adjusting price and advertising accordingly. Our results allow speeding up numerical computations of decisions as the set of possible actions can be reduced significantly. Our analysis implies general results for pure pricing as well as pure advertising models with time-dependent demand elasticities. (C) 2016 Elsevier B.V. All rights reserved.}, language = {en} } @article{SchleussnerRogeljSchaefferetal.2016, author = {Schleussner, Carl-Friedrich and Rogelj, Joeri and Schaeffer, Michiel and Lissner, Tabea and Licker, Rachel and Fischer, Erich M. and Knutti, Reto and Levermann, Anders and Frieler, Katja and Hare, William}, title = {Science and policy characteristics of the Paris Agreement temperature goal}, series = {Nature climate change}, volume = {6}, journal = {Nature climate change}, publisher = {Nature Publ. Group}, address = {London}, issn = {1758-678X}, doi = {10.1038/NCLIMATE3096}, pages = {827 -- 835}, year = {2016}, language = {en} } @article{SchleussnerLissnerFischeretal.2016, author = {Schleussner, Carl-Friedrich and Lissner, Tabea K. and Fischer, Erich M. and Wohland, Jan and Perrette, Mahe and Golly, Antonius and Rogelj, Joeri and Childers, Katelin and Schewe, Jacob and Frieler, Katja and Mengel, Matthias and Hare, William and Schaeffer, Michiel}, title = {Differential climate impacts for policy-relevant limits to global warming: the case of 1.5 degrees C and 2 degrees C}, series = {Earth system dynamics}, volume = {7}, journal = {Earth system dynamics}, publisher = {Copernicus}, address = {G{\"o}ttingen}, issn = {2190-4979}, doi = {10.5194/esd-7-327-2016}, pages = {327 -- 351}, year = {2016}, abstract = {Robust appraisals of climate impacts at different levels of global-mean temperature increase are vital to guide assessments of dangerous anthropogenic interference with the climate system. The 2015 Paris Agreement includes a two-headed temperature goal: "holding the increase in the global average temperature to well below 2 degrees C above pre-industrial levels and pursuing efforts to limit the temperature increase to 1.5 degrees C". Despite the prominence of these two temperature limits, a comprehensive overview of the differences in climate impacts at these levels is still missing. Here we provide an assessment of key impacts of climate change at warming levels of 1.5 degrees C and 2 degrees C, including extreme weather events, water availability, agricultural yields, sea-level rise and risk of coral reef loss. Our results reveal substantial differences in impacts between a 1.5 degrees C and 2 degrees C warming that are highly relevant for the assessment of dangerous anthropogenic interference with the climate system. For heat-related extremes, the additional 0.5 degrees C increase in global-mean temperature marks the difference between events at the upper limit of present-day natural variability and a new climate regime, particularly in tropical regions. Similarly, this warming difference is likely to be decisive for the future of tropical coral reefs. In a scenario with an end-of-century warming of 2 degrees C, virtually all tropical coral reefs are projected to be at risk of severe degradation due to temperature-induced bleaching from 2050 onwards. This fraction is reduced to about 90\% in 2050 and projected to decline to 70\% by 2100 for a 1.5 degrees C scenario. Analyses of precipitation-related impacts reveal distinct regional differences and hot-spots of change emerge. Regional reduction in median water availability for the Mediterranean is found to nearly double from 9\% to 17\% between 1.5 degrees C and 2 degrees C, and the projected lengthening of regional dry spells increases from 7 to 11\%. Projections for agricultural yields differ between crop types as well as world regions. While some (in particular high-latitude) regions may benefit, tropical regions like West Africa, South-East Asia, as well as Central and northern South America are projected to face substantial local yield reductions, particularly for wheat and maize. Best estimate sea-level rise projections based on two illustrative scenarios indicate a 50cm rise by 2100 relative to year 2000-levels for a 2 degrees C scenario, and about 10 cm lower levels for a 1.5 degrees C scenario. In a 1.5 degrees C scenario, the rate of sea-level rise in 2100 would be reduced by about 30\% compared to a 2 degrees C scenario. Our findings highlight the importance of regional differentiation to assess both future climate risks and different vulnerabilities to incremental increases in global-mean temperature. The article provides a consistent and comprehensive assessment of existing projections and a good basis for future work on refining our understanding of the difference between impacts at 1.5 degrees C and 2 degrees C warming.}, language = {en} } @article{SchleussnerDongesEngemannetal.2016, author = {Schleussner, Carl-Friedrich and Donges, Jonathan and Engemann, Denis A. and Levermann, Anders}, title = {Clustered marginalization of minorities during social transitions induced by co-evolution of behaviour and network structure}, series = {Scientific reports}, volume = {6}, journal = {Scientific reports}, publisher = {Nature Publ. Group}, address = {London}, issn = {2045-2322}, doi = {10.1038/srep30790}, pages = {3407 -- 3417}, year = {2016}, abstract = {Large-scale transitions in societies are associated with both individual behavioural change and restructuring of the social network. These two factors have often been considered independently, yet recent advances in social network research challenge this view. Here we show that common features of societal marginalization and clustering emerge naturally during transitions in a co-evolutionary adaptive network model. This is achieved by explicitly considering the interplay between individual interaction and a dynamic network structure in behavioural selection. We exemplify this mechanism by simulating how smoking behaviour and the network structure get reconfigured by changing social norms. Our results are consistent with empirical findings: The prevalence of smoking was reduced, remaining smokers were preferentially connected among each other and formed increasingly marginalized clusters. We propose that self-amplifying feedbacks between individual behaviour and dynamic restructuring of the network are main drivers of the transition. This generative mechanism for co-evolution of individual behaviour and social network structure may apply to a wide range of examples beyond smoking.}, language = {en} } @article{SchlagintweitFrijiaParente2016, author = {Schlagintweit, Felix and Frijia, Gianluca and Parente, Mariano}, title = {Sarmentofascis zamparelliae n. sp., a new demosponge from the lower Campanian of southern Italy}, series = {Cretaceous research}, volume = {57}, journal = {Cretaceous research}, publisher = {Elsevier}, address = {London}, issn = {0195-6671}, doi = {10.1016/j.cretres.2015.07.018}, pages = {157 -- 164}, year = {2016}, abstract = {A new coralline sponge, exhibiting typical "stromatoporoid" bodyplan, is described as Sarmentofascis zamparelliae n. sp. from the lower Campanian of the southern Apennines, Italy. It is differentiated from Sarmentofascis cretacea (Turnsek) (Hauterivian of Montenegro) and Sarmentofascis chabrieri Termier, Termier and Vachard (Santonian of France) above all by its slender arborescent skeleton, exhibiting longitudinally distributed astrorhizae-like canals. S. zamparelliae n. sp. is the youngest representative of the genus and is reported from a period exhibiting a distinct decline of "stromatoporoid" sponges. With its clinogonal microstructure and occurrence in inner platform stromatoporoid-foraminiferan floatstones it can be considered a Late Cretaceous environmental analog to the Late Jurassic Cladocoropsis. (C) 2015 Elsevier Ltd. All rights reserved.}, language = {en} } @article{SchirrmeisterMeyerAndreevetal.2016, author = {Schirrmeister, Lutz and Meyer, Hanno and Andreev, Andrei and Wetterich, Sebastian and Kienast, Frank and Bobrov, Anatoly and Fuchs, Margret and Sierralta, Melanie and Herzschuh, Ulrike}, title = {Late Quaternary paleoenvironmental records from the Chatanika River valley near Fairbanks (Alaska)}, series = {Quaternary science reviews : the international multidisciplinary research and review journal}, volume = {147}, journal = {Quaternary science reviews : the international multidisciplinary research and review journal}, publisher = {Elsevier}, address = {Oxford}, issn = {0277-3791}, doi = {10.1016/j.quascirev.2016.02.009}, pages = {259 -- 278}, year = {2016}, abstract = {Perennially-frozen deposits are considered as excellent paleoenvironmental archives similar to lacustrine, deep marine, and glacier records because of the long-term and good preservation of fossil records under stable permafrost conditions. A permafrost tunnel in the Vault Creek Valley (Chatanika River Valley, near Fairbanks) exposes a sequence of frozen deposits and ground ice that provides a comprehensive set of proxies to reconstruct the late Quaternary environmental history of Interior Alaska. The multi-proxy approach includes different dating techniques (radiocarbon-accelerator mass spectrometry [AMS C-14], optically stimulated luminescence [OSL], thorium/uranium radioisotope disequilibria [Th-230/U]), as well as methods of sedimentology, paleoecology, hydrochemistry, and stable isotope geochemistry of ground ice. The studied sequence consists of 36-m-thick late Quaternary deposits above schistose bedrock. Main portions of the sequence accumulated during the early and middle Wisconsin periods. The lowermost unit A consists of about 9-m-thick ice-bonded fluvial gravels with sand and peat lenses. A late Sangamon (MIS 5a) age of unit A is assumed. Spruce forest with birch, larch, and some shrubby alder dominated the vegetation. High presence of Sphagnum spores and Cyperaceae pollen points to mires in the Vault Creek Valley. The overlying unit B consists of 10-m-thick alternating fluvial gravels, loess-like silt, and sand layers, penetrated by small ice wedges. OSL dates support a stadial early Wisconsin (MIS 4) age of unit B. Pollen and plant macrofossil data point to spruce forests with some birch interspersed with wetlands around the site. The following unit C is composed of 15-m-thick ice-rich loess-like and organic-rich silt with fossil bones and large ice wedges. Unit C formed during the interstadial mid-Wisconsin (MIS 3) and stadial late Wisconsin (MIS 2) as indicated by radiocarbon ages. Post-depositional slope processes significantly deformed both, ground ice and sediments of unit C. Pollen data show that spruce forests and wetlands dominated the area. The macrofossil remains of Picea, Larix, and Alnus incana ssp. tenuifolia also prove the existence of boreal coniferous forests during the mid-Wisconsin interstadial, which were replaced by treeless tundra-steppe vegetation during the late Wisconsin stadial. Unit C is discordantly overlain by the 2-m-thick late Holocene deposits of unit D. The pollen record of unit D indicates boreal forest vegetation similar to the modern one. The permafrost record from the Vault Creek tunnel reflects more than 90 ka of periglacial landscape dynamics triggered by fluvial and eolian accumulation, and formation of ice-wedge polygons and post depositional deformation by slope processes. The record represents a typical Wisconsin valley-bottom facies in Central Alaska. (C) 2016 Elsevier Ltd. All rights reserved.}, language = {en} } @phdthesis{Schindler2016, author = {Schindler, Sven}, title = {Honeypot Architectures for IPv6 Networks}, school = {Universit{\"a}t Potsdam}, pages = {164}, year = {2016}, language = {en} } @phdthesis{Schindler2016, author = {Schindler, J{\"o}rg Michael}, title = {Rechtsmetaphorologie - Ausblick auf eine Metaphorologie der Grundrechte}, series = {Schriften zur Rechtstheorie ; 281}, journal = {Schriften zur Rechtstheorie ; 281}, publisher = {Duncker \& Humblot}, address = {Berlin}, isbn = {978-3-428-14758-8}, school = {Universit{\"a}t Potsdam}, pages = {380}, year = {2016}, abstract = {Es existiert bisher in der deutschsprachigen Rechtswissenschaft keine umfassende Forschung zu Metaphern. Der vorliegende Band stellt einen wichtigen Beitrag zur Schließung dieser Forschungsl{\"u}cke dar. Auf gut zwei Dritteln der Studie wird ein als 'Rechtsmetaphorologie' bezeichnetes Forschungsprogramm theoretisch und methodologisch fundiert. Sie bietet zun{\"a}chst einen differenzierten Metaphernbegriff an, der das bislang gest{\"o}rte Verh{\"a}ltnis der Rechtswissenschaft zu 'Metaphern' weitgehend kl{\"a}rt. Danach fokussiert sie auf die Erscheinungsform der hier sog. 'pr{\"a}skriptiven Metapher'. Diese und ihre Anerkennung werden insbesondere philosophisch und anthropologisch legitimiert. Rechtswissenschaftliche Begriffe sind wohl fast immer pr{\"a}skriptive Metaphern. Ein herausragendes Beispiel bieten der Begriff der 'Grundrechte' und die zentralen Begriffe ihrer Dogmatik. Ihre Geschichte bis in die Gegenwart wird im letzten Drittel rechtsmetaphorologisch begr{\"u}ndet und in vielerlei Hinsicht neu erz{\"a}hlt}, language = {de} } @article{SchimkaSanterMujkicNinnemannetal.2016, author = {Schimka, Selina and Santer, Svetlana and Mujkic-Ninnemann, Nina M. and Bleger, David and Hartmann, Laura and Wehle, Marko and Lipowsky, Reinhard and Santer, Mark}, title = {Photosensitive Peptidomimetic for Light-Controlled, Reversible DNA Compaction}, series = {Biomacromolecules : an interdisciplinary journal focused at the interface of polymer science and the biological sciences}, volume = {17}, journal = {Biomacromolecules : an interdisciplinary journal focused at the interface of polymer science and the biological sciences}, publisher = {American Chemical Society}, address = {Washington}, issn = {1525-7797}, doi = {10.1021/acs.biomac.6b00052}, pages = {1959 -- 1968}, year = {2016}, abstract = {Light-induced DNA compaction as part of nonviral gene delivery was investigated intensively in the past years, although the bridging between the artificial light switchable compacting.agents and biodompatible light insensitive compacting agents was not achieved until now. In this paper, we report on light-induced compaction and decompaction of DNA molecules in the presence of a new typeof agent, a multivalent cationic peptidomimetic molecule containing a photosensitive Azo-group as a branch (Azo-PM). Az-o-PM is synthesized using a solid-phase procedure during Which anrazoberizene unit is attached as a side chain to an Oligo(arnidoamine) backbone. We shoW, that within a-certain Tange,of concentrations and under illumination with light of appropriate-wavelengths, these cationic Molecules induce reversible DNA compaction/decompaction by photo-isomerization of the incorporated azobenzene unit between a hydrophobic trans- and 4 hydrophilic cis-conformation, as characterized by dynamic light scattering and AFM measurements. In contrast to other molecular Species used for invasive DNA compaction, such as-widely used azobenzene containing cationic surfactant (Azo-TAR, C-4-Azo-OCX-TMAB), the presented peptidomimetic agent appears to lead to different compleication/compaction mechanisms., An investigation of Ato-PM in close proximity to a DNA segment by means of a molecular dynamics simulation sustains a picture in which Azo-PM acts as a multivalent counterion, with its rather large cationic oligo(amidoamine) backbone dominating the interaction with the double helix, fine-tuned or assisted by the presence" andisomerization state of the Azo-moiety. However, due to its peptidomimetic backbone, Azo-PM should be far less toxic than photosensitive surfactants and might represent a starting point for a conscious design of photoswitchable, biocompatible vectors for gene delivery.}, language = {en} } @phdthesis{Schiller2016, author = {Schiller, Christof}, title = {The Politics of Welfare State Transformation in Germany}, series = {Routledge-EUI studies in the political economy of welfare ; 17}, journal = {Routledge-EUI studies in the political economy of welfare ; 17}, publisher = {Routledge}, address = {London}, isbn = {978-1-315-62390-0}, school = {Universit{\"a}t Potsdam}, pages = {273}, year = {2016}, language = {en} } @article{SchildgenRobinsonSavietal.2016, author = {Schildgen, Taylor F. and Robinson, Ruth A. J. and Savi, Sara and Phillips, William M. and Spencer, Joel Q. G. and Bookhagen, Bodo and Scherler, Dirk and Tofelde, Stefanie and Alonso, Ricardo N. and Kubik, Peter W. and Binnie, Steven A. and Strecker, Manfred}, title = {Landscape response to late Pleistocene climate change in NW Argentina: Sediment flux modulated by basin geometry and connectivity}, series = {Journal of geophysical research : Earth surface}, volume = {121}, journal = {Journal of geophysical research : Earth surface}, publisher = {American Geophysical Union}, address = {Washington}, issn = {2169-9003}, doi = {10.1002/2015JF003607}, pages = {392 -- 414}, year = {2016}, abstract = {Fluvial fill terraces preserve sedimentary archives of landscape responses to climate change, typically over millennial timescales. In the Humahuaca Basin of NW Argentina (Eastern Cordillera, southern Central Andes), our 29 new optically stimulated luminescence ages of late Pleistocene fill terrace sediments demonstrate that the timing of past river aggradation occurred over different intervals on the western and eastern sides of the valley, despite their similar bedrock lithology, mean slopes, and precipitation. In the west, aggradation coincided with periods of increasing precipitation, while in the east, aggradation coincided with decreasing precipitation or more variable conditions. Erosion rates and grain size dependencies in our cosmogenic Be-10 analyses of modern and fill terrace sediments reveal an increased importance of landsliding compared to today on the west side during aggradation, but of similar importance during aggradation on the east side. Differences in the timing of aggradation and the Be-10 data likely result from differences in valley geometry, which causes sediment to be temporarily stored in perched basins on the east side. It appears as if periods of increasing precipitation triggered landslides throughout the region, which induced aggradation in the west, but blockage of the narrow bedrock gorges downstream from the perched basins in the east. As such, basin geometry and fluvial connectivity appear to strongly influence the timing of sediment movement through the system. For larger basins that integrate subbasins with differing geometries or degrees of connectivity (like Humahuaca), sedimentary responses to climate forcing are likely attenuated.}, language = {en} } @article{SchildeKellingUmbreenetal.2016, author = {Schilde, Uwe and Kelling, Alexandra and Umbreen, Sumaira and Linker, Torsten}, title = {Crystal structures of three bicyclic carbohydrate derivatives}, series = {Acta crystallographica Section E ; Crystallographic communications}, volume = {72}, journal = {Acta crystallographica Section E ; Crystallographic communications}, number = {12}, publisher = {IUCR}, address = {Chester}, issn = {2056-9890}, doi = {10.1107/S2056989016018727}, pages = {1839 -- 1844}, year = {2016}, abstract = {The title compounds, [(1R,3R,4R,5R,6S)-4,5-bis(acetyloxy)-7-oxo-2-oxabicyclo- [4.2.0]octan-3-yl]methyl acetate, C14H18O8, (I), [(1S,4R,5S,6R)-5-acetyloxy-7- hydroxyimino-2-oxobicyclo[4.2.0]octan-4-yl acetate, C11H15NO6, (II), and [(3aR,5R,6R,7R,7aS)-6,7-bis(acetyloxy)-2-oxooctahydropyrano[3,2-b]pyrrol-5- yl]methyl acetate, C14H19NO8, (III), are stable bicyclic carbohydrate derivatives. They can easily be synthesized in a few steps from commercially available glycals. As a result of the ring strain from the four-membered rings in (I) and (II), the conformations of the carbohydrates deviate strongly from the ideal chair form. Compound (II) occurs in the boat form. In the five-membered lactam (III), on the other hand, the carbohydrate adopts an almost ideal chair conformation. As a result of the distortion of the sugar rings, the configurations of the three bicyclic carbohydrate derivatives could not be determined from their NMR coupling constants. From our three crystal structure determinations, we were able to establish for the first time the absolute configurations of all new stereocenters of the carbohydrate rings.}, language = {en} } @article{SchildeKellingUmbreenetal.2016, author = {Schilde, Uwe and Kelling, Alexandra and Umbreen, Sumaira and Linker, Torsten}, title = {Crystal structures of three bicyclic carbohydrate derivatives}, series = {Acta crystallographica, Section E, Crystallographic communications}, volume = {72}, journal = {Acta crystallographica, Section E, Crystallographic communications}, publisher = {International Union of Crystallography}, address = {Chester}, issn = {2056-9890}, doi = {10.1107/S2056989016018727}, pages = {1839 -- +}, year = {2016}, abstract = {The title compounds, [(1R,3R,4R,5R,6S)-4,5-bis(acetyloxy)-7-oxo-2-oxabicyclo-[4.2.0]octan-3-yl]methyl acetate, C14H18O8, (I), [(1S,4R,5S,6R)-5-acetyloxy-7-hydroxyimino-2-oxobicyclo[4.2.0] octan-4-yl acetate, C11H15NO6, (II), and [(3aR, 5R, 6R, 7R, 7aS)-6,7-bis(acetyloxy)-2-oxooctahydropyrano[3,2-b]pyrrol-5-yl] methyl acetate, C14H19NO8, (III), are stable bicyclic carbohydrate derivatives. They can easily be synthesized in a few steps from commercially available glycals. As a result of the ring strain from the four-membered rings in (I) and (II), the conformations of the carbohydrates deviate strongly from the ideal chair form. Compound (II) occurs in the boat form. In the five-membered lactam (III), on the other hand, the carbohydrate adopts an almost ideal chair conformation. As a result of the distortion of the sugar rings, the configurations of the three bicyclic carbohydrate derivatives could not be determined from their NMR coupling constants. From our three crystal structure determinations, we were able to establish for the first time the absolute configurations of all new stereocenters of the carbohydrate rings.}, language = {en} } @article{SchiefeleStutzSchaffner2016, author = {Schiefele, Ulrich and Stutz, Franziska and Schaffner, Ellen}, title = {Longitudinal relations between reading motivation and reading comprehension in the early elementary grades}, series = {Learning and individual differences}, volume = {51}, journal = {Learning and individual differences}, publisher = {Elsevier}, address = {Amsterdam}, issn = {1041-6080}, doi = {10.1016/j.lindif.2016.08.031}, pages = {49 -- 58}, year = {2016}, language = {en} } @article{SchiefeleSchaffner2016, author = {Schiefele, Ulrich and Schaffner, Ellen}, title = {Factorial and Construct Validity of aNew Instrument for the Assessment of Reading Motivation}, series = {Reading research quarterly}, volume = {51}, journal = {Reading research quarterly}, publisher = {Wiley-Blackwell}, address = {Hoboken}, issn = {0034-0553}, doi = {10.1002/rrq.134}, pages = {221 -- 237}, year = {2016}, abstract = {Reading motivation has been defined consistently as a multidimensional construct. However, there is some disagreement regarding the number and nature of the dimensions of reading motivation. In particular, there is a lack of studies investigating the dimensional structure and measurement invariance (e.g., across gender) of reading motivation questionnaires. Based on earlier instruments, qualitative findings referring to students' reasons for reading, and theoretical considerations, we developed the Reading Motivation Questionnaire (RMQ). A sample of 883 sixth-grade students was presented with 34 reading motivation items pertaining to seven dimensions. Five of these dimensions (i.e., curiosity, involvement, grades, competition, social recognition) referred to Wigfield and Guthrie's Motivations for Reading Questionnaire, whereas two dimensions (i.e., emotional regulation, relief from boredom) were based on recent qualitative findings. The results from confirmatory factor analyses supported the hypothesized factor structure. In addition, three higher order factors were identified: intrinsic, extrinsic, and regulatory reading motivation. Moreover, strict measurement invariance across female and male students and across groups with low versus high reading competence was established. Construct validity of the RMQ was supported by the contributions of the RMQ factors to reading amount, fluency, and comprehension and by the predicted gender differences in the dimensions of reading motivation.}, language = {en} } @article{SchickLeGuyaderPontiusetal.2016, author = {Schick, Daniel and Le Guyader, Loic and Pontius, Niko and Radu, Ilie and Kachel, Torsten and Mitzner, Rolf and Zeschke, Thomas and Schuessler-Langeheine, Christian and F{\"o}hlisch, Alexander and Holldack, Karsten}, title = {Analysis of the halo background in femtosecond slicing experiments}, series = {Journal of synchrotron radiation}, volume = {23}, journal = {Journal of synchrotron radiation}, publisher = {International Union of Crystallography}, address = {Chester}, issn = {1600-5775}, doi = {10.1107/S160057751600401X}, pages = {700 -- 711}, year = {2016}, abstract = {The slicing facility FemtoSpeX at BESSY II offers unique opportunities to study photo-induced dynamics on femtosecond time scales by means of X-ray magnetic circular dichroism, resonant and non-resonant X-ray diffraction, and X-ray absorption spectroscopy experiments in the soft X-ray regime. Besides femtosecond X-ray pulses, slicing sources inherently also produce a so-called `halo' background with a different time structure, polarization and pointing. Here a detailed experimental characterization of the halo radiation is presented, and a method is demonstrated for its correct and unambiguous removal from femtosecond time-resolved data using a special laser triggering scheme as well as analytical models. Examples are given for time-resolved measurements with corresponding halo correction, and errors of the relevant physical quantities caused by either neglecting or by applying a simplified model to describe this background are estimated.}, language = {en} } @article{SchickEckertPontiusetal.2016, author = {Schick, Daniel and Eckert, Sebastian and Pontius, Niko and Mitzner, Rolf and F{\"o}hlisch, Alexander and Holldack, Karsten and Sorgenfrei, Nomi}, title = {Versatile soft X-ray-optical cross-correlator for ultrafast applications}, series = {Structural dynamics}, volume = {3}, journal = {Structural dynamics}, publisher = {American Institute of Physics}, address = {Melville}, issn = {2329-7778}, doi = {10.1063/1.4964296}, pages = {054304-1 -- 054304-8}, year = {2016}, abstract = {We present an X-ray-optical cross-correlator for the soft (> 150 eV) up to the hard X-ray regime based on a molybdenum-silicon superlattice. The cross-correlation is done by probing intensity and position changes of superlattice Bragg peaks caused by photoexcitation of coherent phonons. This approach is applicable for a wide range of X-ray photon energies as well as for a broad range of excitation wavelengths and requires no external fields or changes of temperature. Moreover, the cross-correlator can be employed on a 10 ps or 100 fs time scale featuring up to 50\% total X-ray reflectivity and transient signal changes of more than 20\%. (C) 2016 Author(s).}, language = {en} } @misc{SchernthanerGroopCooperetal.2016, author = {Schernthaner, G. and Groop, P. and Cooper, M. and Perkovic, V and Hocher, Berthold and Kanasaki, K. and Sharma, K. and Stanton, R. and Toto, R. and Cescutti, Jessica and Gordat, M. and Meinicke, T. and Koitka-Weber, A. and Woerle, H. and Eynatten, M.}, title = {EFFECTS OF LINAGLIPTIN ON GLYCAEMIC CONTROL AND ALBUMINURIA IN TYPE 2 DIABETES - THE MARLINA-T2D (TM) TRIAL}, series = {Nephrology}, volume = {21}, journal = {Nephrology}, publisher = {Wiley-Blackwell}, address = {Hoboken}, issn = {1320-5358}, doi = {10.1111/nep.12887}, pages = {60 -- 60}, year = {2016}, language = {en} } @article{SchererJeltschGrimmetal.2016, author = {Scherer, Cedric and Jeltsch, Florian and Grimm, Volker and Blaum, Niels}, title = {Merging trait-based and individual-based modelling: An animal functional type approach to explore the responses of birds to climatic and land use changes in semi-arid African savannas}, series = {Ecological modelling : international journal on ecological modelling and engineering and systems ecolog}, volume = {326}, journal = {Ecological modelling : international journal on ecological modelling and engineering and systems ecolog}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0304-3800}, doi = {10.1016/j.ecolmodel.2015.07.005}, pages = {75 -- 89}, year = {2016}, abstract = {Climate change and land use management practices are major drivers of biodiversity in terrestrial ecosystems. To understand and predict resulting changes in community structures, individual-based and spatially explicit population models are a useful tool but require detailed data sets for each species. More generic approaches are thus needed. Here we present a trait-based functional type approach to model savanna birds. The aim of our model is to explore the response of different bird functional types to modifications in habitat structure. The functional types are characterized by different traits, in particular body mass, which is related to life-history traits (reproduction and mortality) and spatial scales (home range area and dispersal ability), as well as the use of vegetation structures for foraging and nesting, which is related to habitat quality and suitability. We tested the performance of the functional types in artificial landscapes varying in shrub:grass ratio and clumping intensity of shrub patches. We found that an increase in shrub encroachment and a decrease in habitat quality caused by land use mismanagement and climate change endangered all simulated bird functional types. The strength of this effect was related to the preferred habitat. Furthermore, larger-bodied insectivores and omnivores were more prone to extinction due to shrub encroachment compared to small-bodied species. Insectivorous and omnivorous birds were more sensitive to clumping intensity of shrubs whereas herbivorous and carnivorous birds were most affected by a decreasing amount of grass cover. From an applied point of view, our findings emphasize that policies such as woody plant removal and a reduction in livestock stocking rates to prevent shrub encroachment should prioritize the enlargement of existing grassland patches. Overall, our results show that the combination of an individual-based modelling approach with carefully defined functional types can provide a powerful tool for exploring biodiversity responses to environmental changes. Furthermore, the increasing accumulation of worldwide data sets on species' core and soft traits (surrogates to determine core traits indirectly) on one side and the refinement of conceptual frameworks for animal functional types on the other side will further improve functional type approaches which consider the sensitivities of multiple species to climate change, habitat loss, and fragmentation.}, language = {en} } @article{Scherer2016, author = {Scherer, Anne}, title = {Die Rechtstellung des sogenannten politischen Beamten}, series = {Studere : Rechtszeitschrift der Universit{\"a}t Potsdam}, volume = {2016}, journal = {Studere : Rechtszeitschrift der Universit{\"a}t Potsdam}, number = {16}, publisher = {studere e.V.}, address = {Potsdam}, issn = {1867-6170}, pages = {15 -- 27}, year = {2016}, language = {de} } @article{SchennenTronickeWetterichetal.2016, author = {Schennen, Stephan and Tronicke, Jens and Wetterich, Sebastian and Allroggen, Niklas and Schwamborn, Georg and Schirrmeister, Lutz}, title = {3D ground-penetrating radar imaging of ice complex deposits in northern East Siberia}, series = {Geophysics}, volume = {81}, journal = {Geophysics}, publisher = {Society of Exploration Geophysicists}, address = {Tulsa}, issn = {0016-8033}, doi = {10.1190/GEO2015-0129.1}, pages = {WA195 -- WA202}, year = {2016}, abstract = {Ice complex deposits are characteristic, ice-rich formations in northern East Siberia and represent an important part in the arctic carbon pool. Recently, these late Quaternary deposits are the objective of numerous investigations typically relying on outcrop and borehole data. Many of these studies can benefit from a 3D structural model of the subsurface for upscaling their observations or for constraining estimations of inventories, such as the local carbon stock. We have addressed this problem of structural imaging by 3D ground-penetrating radar (GPR), which, in permafrost studies, has been primarily used for 2D profiling. We have used a 3D kinematic GPR surveying strategy at a field site located in the New Siberian Archipelago on top of an ice complex. After applying a 3D GPR processing sequence, we were able to trace two horizons at depths below 20 m. Taking available borehole and outcrop data into account, we have interpreted these two features as interfaces of major lithologic units and derived a 3D cryostratigraphic model of the subsurface. Our data example demonstrated that a 3D surveying and processing strategy was crucial at our field site and showed the potential of 3D GPR to image geologic structures in complex ice-rich permafrost landscapes.}, language = {en} } @misc{SchellerSakarDasdan2016, author = {Scheller, Frieder W. and Sakar Dasdan, Dolunay}, title = {Selected papers presented on the 2nd International Conference on the New Trends in Chemistry, Zagreb, Croatia, April 19-22, 2016 Preface}, series = {Bulgarian chemical communications : journal of the Chemical Institutes of the Bulgarian Academy of Sciences and of the Bulgarian Chemical Society = Izvestija po chimija}, volume = {48}, journal = {Bulgarian chemical communications : journal of the Chemical Institutes of the Bulgarian Academy of Sciences and of the Bulgarian Chemical Society = Izvestija po chimija}, publisher = {Bulgarian Academy of Sciences}, address = {Sofia}, issn = {0324-1130}, pages = {4 -- 4}, year = {2016}, language = {en} } @article{SchefflerOberhaensliPourteauetal.2016, author = {Scheffler, Franziska and Oberh{\"a}nsli, Roland and Pourteau, Amaury and Immenhauser, A. and Candan, O.}, title = {Sedimentologic to metamorphic processes recorded in the high-pressure/low-temperature Mesozoic Rosetta Marble of Anatolia}, series = {International journal of earth sciences}, volume = {105}, journal = {International journal of earth sciences}, publisher = {Springer}, address = {New York}, issn = {1437-3254}, doi = {10.1007/s00531-015-1214-y}, pages = {225 -- 246}, year = {2016}, abstract = {Anatolia's high-pressure metamorphic belts are characterized in part by a Neotethyan stratigraphic succession that includes a mid-Cretaceous hemi-pelagic marble sequence. This unit contains, towards its stratigraphic top, dm-to-m-long radiating calcitic rods forming rosette-like textures. Here, we refer to these features as "Rosetta Marble". The remarkable textural similarity of non-metamorphic selenite crystals and radiating calcite rods in the Rosetta Marble strongly suggests that these textures represent pseudomorphs after selenites. Metamorphosed hemi-pelagic limestones, dominated by Rosetta selenite pseudomorphs, are alternating with siliceous meta-sediments containing relictic radiolaria tests. This stratigraphic pattern is indicative of transient phases characterized by evaporites precipitated from basinal brines alternating with non-evaporative hemi-pelagic deposition from normal-marine seawater. The regional distribution of Rosetta Marble exposures over 600 km is indicative of basin-scale evaporitic intervals. High-pressure, low-temperature metamorphism of these rocks is witnessed by Sr-rich (up to 3500 ppm), fibrous calcite pseudomorphs after aragonite and isolated aragonite inclusions in quartz. Peak metamorphic conditions of 1.2 GPa and 300-350 °C are attested by high-Si white mica thermobarometry. The Rosetta Marble case example examines the potential to unravel the complete history from deposition to diagenesis and metamorphism of meta-sedimentary rocks.}, language = {en} } @article{ScharfHandySchmidetal.2016, author = {Scharf, Andreas and Handy, Mark R. and Schmid, Stefan M. and Favaro, Silvia and Sudo, Masafumi and Schuster, Ralf and Hammerschmidt, Konrad}, title = {Grain-size effects on the closure temperature of white mica in a crustal-scale extensional shear - zone - Implications of in-situ Ar-40/Ar-39 laser-ablation of white mica for dating shearing and cooling (Tauern Window, Eastern Alps)}, series = {Tectonophysics : international journal of geotectonics and the geology and physics of the interior of the earth}, volume = {674}, journal = {Tectonophysics : international journal of geotectonics and the geology and physics of the interior of the earth}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0040-1951}, doi = {10.1016/j.tecto.2016.02.014}, pages = {210 -- 226}, year = {2016}, abstract = {In-situ Ar-40/Ar-39 laser ablation dating of white-mica grains was performed on samples from the footwall of a crustal-scale extensional fault (Katschberg Normal Fault; KNF) that accommodated eastward orogen-parallel displacement of Alpine orogenic crust in the eastern part of the Tauern Window. This dating yields predominantly cooling ages ranging from 31 to 13 Myr, with most ages clustering between 21 and 17 Myr. Folded white micas that predate the main Katschberg foliation yield, within error, the same ages as white-mica grains that overgrow this foliation. However, the absolute ages of both generations are older at the base (20 Myr) where their grain size is larger (300-500 mu m), than at the top and adjacent to the hangingwall (17 Myr) of this shear zone where grain size is smaller (<100-300 mu m). This fining-upward trend of white-mica grain size within the KNF is associated with a reduction of the closure temperature from the base (similar to 445 degrees C) to the top (<400 degrees C) and explains the counter-intuitive trend of downward-increasing age of cooling in the footwall. The new data show that rapid cooling within the KNF of the eastern Tauern Window started sometime before 21 Myr according to the Ar-40/Ar-39 white-mica cooling ages and between 25-21 Myr according to the new Rb/Sr white-mica ages, i.e., shortly after the attainment of the thermal peak in the Tauern Window at similar to 25 Myr ago. These new data, combined with literature data, support earlier cooling in the eastern part of then Tauem Window than in the western part by some 3-5 Myr. (C) 2016 Elsevier B.V. All rights reserved.}, language = {en} } @article{SchaffnerPhilippSchiefele2016, author = {Schaffner, Ellen and Philipp, Maik and Schiefele, Ulrich}, title = {Reciprocal effects between intrinsic reading motivation and reading competence? A cross-lagged panel model for academic track and nonacademic track students}, series = {Journal of research in reading : a journal of the United Kingdom Reading Association}, volume = {39}, journal = {Journal of research in reading : a journal of the United Kingdom Reading Association}, publisher = {Wiley-Blackwell}, address = {Hoboken}, issn = {0141-0423}, doi = {10.1111/1467-9817.12027}, pages = {19 -- 36}, year = {2016}, abstract = {Previous research has demonstrated positive relations between intrinsic reading motivation and reading competence. However, the causal direction of these relations and the moderating role of relevant background variables (e.g., students' achievement level) are not well understood. In the present study, a cross-lagged panel model was applied to academic track and nonacademic track fifth grade students (N = 396) to test whether intrinsic reading motivation and reading competence are reciprocally related depending on the students' achievement level (indicated by school track affiliation). According to expectations, the cross-lagged effect of intrinsic reading motivation on reading competence was only significant for academic track students. In the nonacademic track group, neither the effect of intrinsic reading motivation on reading competence nor the reverse effect proved to be significant. Thus, the nature of the relation between intrinsic reading motivation and reading competence seems to depend on students' school track affiliation.}, language = {en} } @article{SchafferIdzikWilkeetal.2016, author = {Schaffer, Mario and Idzik, Krzysztof R. and Wilke, Max and Licha, Tobias}, title = {Amides as thermo-sensitive tracers for investigating the thermal state of geothermal reservoirs}, series = {Geothermics : an international journal of geothermal research and its applications}, volume = {64}, journal = {Geothermics : an international journal of geothermal research and its applications}, publisher = {Elsevier}, address = {Oxford}, issn = {0375-6505}, doi = {10.1016/j.geothermics.2016.05.004}, pages = {180 -- 186}, year = {2016}, abstract = {The application of thermo-sensitive tracers is a promising technique for evaluating the thermal state of geothermal reservoirs. To extend the compound spectrum for hydrolyzable compounds to reservoir temperatures between 100 and 200 degrees C carboxamides were studied. The kinetic parameters of 17 self-synthesized amides were determined in hydrothermal batch and autoclave experiments. The influence of the molecular structure and the role of pH/pOH on hydrolysis kinetics were studied. Additionally, the thermal stabilities of the hydrolysis products were evaluated. The results demonstrate the high potential of tracers based on amide hydrolysis for use in medium enthalpy reservoirs. (C) 2016 Elsevier Ltd. All rights reserved.}, language = {en} } @article{SchachnerNoackVandeVijveretal.2016, author = {Schachner, Maja Katharina and Noack, Peter and Van de Vijver, Fons J. R. and Eckstein, Katharina}, title = {Cultural Diversity Climate and Psychological Adjustment at School-Equality and Inclusion Versus Cultural Pluralism}, series = {Child development}, volume = {87}, journal = {Child development}, publisher = {Wiley}, address = {Hoboken}, issn = {0009-3920}, doi = {10.1111/cdev.12536}, pages = {1175 -- 1191}, year = {2016}, abstract = {The present study is concerned with cultural diversity climate at school and how it relates to acculturation orientations and psychological school adjustment of early adolescent immigrants. Specifically, the distinct role of two types of diversity policy is investigated, namely (a) fostering equality and inclusion and (b) acknowledging cultural pluralism. Longitudinal multilevel analyses based on 386 early adolescent immigrant students (M-age=10.49years) in 44 ethnically heterogeneous classrooms in Germany revealed that the manifestations of both types of policies promote psychological school adjustment (i.e., better well-being and fewer psychological and behavioral problems) at the individual level. However, they differ in their effects on acculturation orientations. At the classroom level, equality and inclusion promote assimilation. Implications for research and educational practice are discussed.}, language = {en} }