@article{Šimik2019, author = {Šim{\´i}k, Radek}, title = {On doubling unconditionals}, series = {Of trees and birds. A Festschrift for Gisbert Fanselow}, journal = {Of trees and birds. A Festschrift for Gisbert Fanselow}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, isbn = {978-3-86956-457-9}, doi = {10.25932/publishup-43226}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-432267}, pages = {155 -- 169}, year = {2019}, language = {en} } @misc{ŚlęzakMetzlerMagdziarz2019, author = {Ślęzak, Jakub and Metzler, Ralf and Magdziarz, Marcin}, title = {Codifference can detect ergodicity breaking and non-Gaussianity}, series = {Postprints der Universit{\"a}t Potsdam Mathematisch-Naturwissenschaftliche Reihe}, journal = {Postprints der Universit{\"a}t Potsdam Mathematisch-Naturwissenschaftliche Reihe}, number = {748}, doi = {10.25932/publishup-43617}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-436178}, pages = {25}, year = {2019}, abstract = {We show that the codifference is a useful tool in studying the ergodicity breaking and non-Gaussianity properties of stochastic time series. While the codifference is a measure of dependence that was previously studied mainly in the context of stable processes, we here extend its range of applicability to random-parameter and diffusing-diffusivity models which are important in contemporary physics, biology and financial engineering. We prove that the codifference detects forms of dependence and ergodicity breaking which are not visible from analysing the covariance and correlation functions. We also discuss a related measure of dispersion, which is a nonlinear analogue of the mean squared displacement.}, language = {en} } @article{ŚlęzakMetzlerMagdziarz2019, author = {Ślęzak, Jakub and Metzler, Ralf and Magdziarz, Marcin}, title = {Codifference can detect ergodicity breaking and non-Gaussianity}, series = {New Journal of Physics}, volume = {21}, journal = {New Journal of Physics}, publisher = {Deutsche Physikalische Gesellschaft}, address = {Bad Honnef}, issn = {1367-2630}, doi = {10.1088/1367-2630/ab13f3}, pages = {25}, year = {2019}, abstract = {We show that the codifference is a useful tool in studying the ergodicity breaking and non-Gaussianity properties of stochastic time series. While the codifference is a measure of dependence that was previously studied mainly in the context of stable processes, we here extend its range of applicability to random-parameter and diffusing-diffusivity models which are important in contemporary physics, biology and financial engineering. We prove that the codifference detects forms of dependence and ergodicity breaking which are not visible from analysing the covariance and correlation functions. We also discuss a related measure of dispersion, which is a nonlinear analogue of the mean squared displacement.}, language = {en} } @misc{ŚlęzakBurneckiMetzler2019, author = {Ślęzak, Jakub and Burnecki, Krzysztof and Metzler, Ralf}, title = {Random coefficient autoregressive processes describe Brownian yet non-Gaussian diffusion in heterogeneous systems}, series = {Postprints der Universit{\"a}t Potsdam Mathematisch-Naturwissenschaftliche Reihe}, journal = {Postprints der Universit{\"a}t Potsdam Mathematisch-Naturwissenschaftliche Reihe}, number = {765}, issn = {1866-8372}, doi = {10.25932/publishup-43792}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-437923}, pages = {18}, year = {2019}, abstract = {Many studies on biological and soft matter systems report the joint presence of a linear mean-squared displacement and a non-Gaussian probability density exhibiting, for instance, exponential or stretched-Gaussian tails. This phenomenon is ascribed to the heterogeneity of the medium and is captured by random parameter models such as 'superstatistics' or 'diffusing diffusivity'. Independently, scientists working in the area of time series analysis and statistics have studied a class of discrete-time processes with similar properties, namely, random coefficient autoregressive models. In this work we try to reconcile these two approaches and thus provide a bridge between physical stochastic processes and autoregressive models.Westart from the basic Langevin equation of motion with time-varying damping or diffusion coefficients and establish the link to random coefficient autoregressive processes. By exploring that link we gain access to efficient statistical methods which can help to identify data exhibiting Brownian yet non-Gaussian diffusion.}, language = {en} } @article{ŚlęzakBurneckiMetzler2019, author = {Ślęzak, Jakub and Burnecki, Krzysztof and Metzler, Ralf}, title = {Random coefficient autoregressive processes describe Brownian yet non-Gaussian diffusion in heterogeneous systems}, series = {New Journal of Physics}, volume = {21}, journal = {New Journal of Physics}, publisher = {Deutsche Physikalische Gesellschaft ; IOP, Institute of Physics}, address = {Bad Honnef und London}, issn = {1367-2630}, doi = {10.1088/1367-2630/ab3366}, pages = {18}, year = {2019}, abstract = {Many studies on biological and soft matter systems report the joint presence of a linear mean-squared displacement and a non-Gaussian probability density exhibiting, for instance, exponential or stretched-Gaussian tails. This phenomenon is ascribed to the heterogeneity of the medium and is captured by random parameter models such as 'superstatistics' or 'diffusing diffusivity'. Independently, scientists working in the area of time series analysis and statistics have studied a class of discrete-time processes with similar properties, namely, random coefficient autoregressive models. In this work we try to reconcile these two approaches and thus provide a bridge between physical stochastic processes and autoregressive models.Westart from the basic Langevin equation of motion with time-varying damping or diffusion coefficients and establish the link to random coefficient autoregressive processes. By exploring that link we gain access to efficient statistical methods which can help to identify data exhibiting Brownian yet non-Gaussian diffusion.}, language = {en} } @article{ZurekFaass2019, author = {Zurek, Peter Paul and Faaß, Marcel}, title = {Pers{\"o}nlichkeitspsychologisch fundierte Studienorientierung durch onlinebasierte Self-Assessments}, series = {Alles auf Anfang! Befunde und Perspektiven zum Studieneingang}, journal = {Alles auf Anfang! Befunde und Perspektiven zum Studieneingang}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, isbn = {978-3-86956-452-4}, issn = {2192-1075}, doi = {10.25932/publishup-42852}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-428529}, pages = {245 -- 256}, year = {2019}, language = {de} } @misc{ZupokIobbiNivolMejeanetal.2019, author = {Zupok, Arkadiusz and Iobbi-Nivol, Chantal and Mejean, Vincent and Leimk{\"u}hler, Silke}, title = {The regulation of Moco biosynthesis and molybdoenzyme gene expression by molybdenum and iron in bacteria}, series = {Metallomics : integrated biometal science}, volume = {11}, journal = {Metallomics : integrated biometal science}, number = {10}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {1756-5901}, doi = {10.1039/c9mt00186g}, pages = {1602 -- 1624}, year = {2019}, abstract = {Bacterial molybdoenzymes are key enzymes involved in the global sulphur, nitrogen and carbon cycles. These enzymes require the insertion of the molybdenum cofactor (Moco) into their active sites and are able to catalyse a large range of redox-reactions. Escherichia coli harbours nineteen different molybdoenzymes that require a tight regulation of their synthesis according to substrate availability, oxygen availability and the cellular concentration of molybdenum and iron. The synthesis and assembly of active molybdoenzymes are regulated at the level of transcription of the structural genes and of translation in addition to the genes involved in Moco biosynthesis. The action of global transcriptional regulators like FNR, NarXL/QP, Fur and ArcA and their roles on the expression of these genes is described in detail. In this review we focus on what is known about the molybdenum- and iron-dependent regulation of molybdoenzyme and Moco biosynthesis genes in the model organism E. coli. The gene regulation in E. coli is compared to two other well studied model organisms Rhodobacter capsulatus and Shewanella oneidensis.}, language = {en} } @article{ZupokGorkaSiemiatkowskaetal.2019, author = {Zupok, Arkadiusz and G{\´o}rka, Michał Jakub and Siemiatkowska, Beata and Skirycz, Aleksandra and Leimk{\"u}hler, Silke}, title = {Iron-Dependent Regulation of Molybdenum Cofactor Biosynthesis Genes in Escherichia coli}, series = {Journal of bacteriology}, volume = {201}, journal = {Journal of bacteriology}, number = {17}, publisher = {American Society for Microbiology}, address = {Washington}, issn = {0021-9193}, doi = {10.1128/JB.00382-19}, pages = {15}, year = {2019}, abstract = {Molybdenum cofactor (Moco) biosynthesis is a complex process that involves the coordinated function of several proteins. In recent years it has become obvious that the availability of iron plays an important role in the biosynthesis of Moco. First, the MoaA protein binds two (4Fe-4S] clusters per monomer. Second, the expression of the moaABCDE and moeAB operons is regulated by FNR, which senses the availability of oxygen via a functional NFe-4S) cluster. Finally, the conversion of cyclic pyranopterin monophosphate to molybdopterin requires the availability of the L-cysteine desulfurase IscS, which is a shared protein with a main role in the assembly of Fe-S clusters. In this report, we investigated the transcriptional regulation of the moaABCDE operon by focusing on its dependence on cellular iron availability. While the abundance of selected molybdoenzymes is largely decreased under iron-limiting conditions, our data show that the regulation of the moaABCDE operon at the level of transcription is only marginally influenced by the availability of iron. Nevertheless, intracellular levels of Moco were decreased under iron-limiting conditions, likely based on an inactive MoaA protein in addition to lower levels of the L-cysteine desulfurase IscS, which simultaneously reduces the sulfur availability for Moco production. IMPORTANCE FNR is a very important transcriptional factor that represents the master switch for the expression of target genes in response to anaerobiosis. Among the FNR-regulated operons in Escherichia coli is the moaABCDE operon, involved in Moco biosynthesis. Molybdoenzymes have essential roles in eukaryotic and prokaryotic organisms. In bacteria, molybdoenzymes are crucial for anaerobic respiration using alternative electron acceptors. This work investigates the connection of iron availability to the biosynthesis of Moco and the production of active molybdoenzymes.}, language = {en} } @article{ZudeSasseHashimHassetal.2019, author = {Zude-Sasse, Manuela and Hashim, Norhashila and Hass, Roland and Polley, Nabarun and Regen, Christian}, title = {Validation study for measuring absorption and reduced scattering coefficients by means of laser-induced backscattering imaging}, series = {Postharvest Biology and Technology}, volume = {153}, journal = {Postharvest Biology and Technology}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0925-5214}, doi = {10.1016/j.postharvbio.2019.04.002}, pages = {161 -- 168}, year = {2019}, abstract = {Decoupling of optical properties appears challenging, but vital to get better insight of the relationship between light and fruit attributes. In this study, nine solid phantoms capturing the ranges of absorption (μa) and reduced scattering (μs') coefficients in fruit were analysed non-destructively using laser-induced backscattering imaging (LLBI) at 1060 nm. Data analysis of LLBI was carried out on the diffuse reflectance, attenuation profile obtained by means of Farrell's diffusion theory either calculating μa [cm-1] and μs' [cm-1] in one fitting step or fitting only one optical variable and providing the other one from a destructive analysis. The nondestructive approach was approved when calculating one unknown coefficient non-destructively, while no ability of the method was found to analysis both, μa and μs', non-destructively. Setting μs' according to destructive photon density wave (PDW) spectroscopy and fitting μa resulted in root mean square error (rmse) of 18.7\% in comparison to fitting μs' resulting in rmse of 2.6\%, pointing to decreased measuring uncertainty, when the highly variable μa was known. The approach was tested on European pear, utilizing destructive PDW spectroscopy for setting one variable, while LLBI was applied for calculating the remaining coefficient. Results indicated that the optical properties of pear obtained from PDW spectroscopy as well as LLBI changed concurrently in correspondence to water content mainly. A destructive batch-wise analysis of μs' and online analysis of μa may be considered in future developments for improved fruit sorting results, when considering fruit with high variability of μs'.}, language = {en} } @article{ZuWolffRalaiarisoaetal.2019, author = {Zu, Fengshuo and Wolff, Christian Michael and Ralaiarisoa, Maryline and Amsalem, Patrick and Neher, Dieter and Koch, Norbert}, title = {Unraveling the Electronic Properties of Lead Halide Perovskites with Surface Photovoltage in Photoemission Studies}, series = {ACS applied materials \& interfaces}, volume = {11}, journal = {ACS applied materials \& interfaces}, number = {24}, publisher = {American Chemical Society}, address = {Washington}, issn = {1944-8244}, doi = {10.1021/acsami.9b05293}, pages = {21578 -- 21583}, year = {2019}, abstract = {The tremendous success of metal-halide perovskites, especially in the field of photovoltaics, has triggered a substantial number of studies in understanding their optoelectronic properties. However, consensus regarding the electronic properties of these perovskites is lacking due to a huge scatter in the reported key parameters, such as work function (Φ) and valence band maximum (VBM) values. Here, we demonstrate that the surface photovoltage (SPV) is a key phenomenon occurring at the perovskite surfaces that feature a non-negligible density of surface states, which is more the rule than an exception for most materials under study. With ultraviolet photoelectron spectroscopy (UPS) and Kelvin probe, we evidence that even minute UV photon fluxes (500 times lower than that used in typical UPS experiments) are sufficient to induce SPV and shift the perovskite Φ and VBM by several 100 meV compared to dark. By combining UV and visible light, we establish flat band conditions (i.e., compensate the surface-state-induced surface band bending) at the surface of four important perovskites, and find that all are p-type in the bulk, despite a pronounced n-type surface character in the dark. The present findings highlight that SPV effects must be considered in all surface studies to fully understand perovskites' photophysical properties.}, language = {en} } @article{ZuAmsalemEggeretal.2019, author = {Zu, Fengshuo and Amsalem, Patrick and Egger, David A. and Wang, Rongbin and Wolff, Christian Michael and Fang, Honghua and Loi, Maria Antonietta and Neher, Dieter and Kronik, Leeor and Duhm, Steffen and Koch, Norbert}, title = {Constructing the Electronic Structure of CH3NH3PbI3 and CH3NH3PbBr3 Perovskite Thin Films from Single-Crystal Band Structure Measurements}, series = {The journal of physical chemistry letters}, volume = {10}, journal = {The journal of physical chemistry letters}, number = {3}, publisher = {American Chemical Society}, address = {Washington}, issn = {1948-7185}, doi = {10.1021/acs.jpclett.8b03728}, pages = {601 -- 609}, year = {2019}, abstract = {Photovoltaic cells based on halide perovskites, possessing remarkably high power conversion efficiencies have been reported. To push the development of such devices further, a comprehensive and reliable understanding of their electronic properties is essential but presently not available. To provide a solid foundation for understanding the electronic properties of polycrystalline thin films, we employ single-crystal band structure data from angle-resolved photoemission measurements. For two prototypical perovskites (CH3NH3PbBr3 and CH3NH3PbI3), we reveal the band dispersion in two high-symmetry directions and identify the global valence band maxima. With these benchmark data, we construct "standard" photoemission spectra from polycrystalline thin film samples and resolve challenges discussed in the literature for determining the valence band onset with high reliability. Within the framework laid out here, the consistency of relating the energy level alignment in perovskite-based photovoltaic and optoelectronic devices with their functional parameters is substantially enhanced.}, language = {en} } @article{ZouhalAbderrahmanDupontetal.2019, author = {Zouhal, Hassane and Abderrahman, Abderraouf Ben and Dupont, Gregory and Truptin, Pablo and Le Bris, R{\´e}gis and Le Postec, Erwan and Sghaeir, Zouita and Brughelli, Matt and Granacher, Urs and Bideau, Benoit}, title = {Effects of Neuromuscular Training on Agility Performance in Elite Soccer Players}, series = {Frontiers in Physiology}, volume = {10}, journal = {Frontiers in Physiology}, publisher = {Frontiers Research Foundation}, address = {Lausanne}, issn = {1664-042X}, doi = {10.3389/fphys.2019.00947}, pages = {9}, year = {2019}, abstract = {Background: Agility in general and change-of-direction speed (CoD) in particular represent important performance determinants in elite soccer. Objectives: The objectives of this study were to determine the effects of a 6-week neuromuscular training program on agility performance, and to determine differences in movement times between the slower and faster turning directions in elite soccer players. Materials and Methods: Twenty male elite soccer players from the Stade Rennais Football Club (Ligue 1, France) participated in this study. The players were randomly assigned to a neuromuscular training group (NTG, n = 10) or an active control (CG, n = 10) according to their playing position. NTG participated in a 6-week, twice per week neuromuscular training program that included CoD, plyometric and dynamic stability exercises. Neuromuscular training replaced the regular warm-up program. Each training session lasted 30 min. CG continued their regular training program. Training volume was similar between groups. Before and after the intervention, the two groups performed a reactive agility test that included 180° left and right body rotations followed by a 5-m linear sprint. The weak side was defined as the left/right turning direction that produced slower overall movement times (MT). Reaction time (RT) was assessed and defined as the time from the first appearance of a visual stimulus until the athlete's first movement. MT corresponded to the time from the first movement until the athlete reached the arrival gate (5 m distance). Results: No significant between-group baseline differences were observed for RT or MT. Significant group x time interactions were found for MT (p = 0.012, effect size = 0.332, small) for the slower and faster directions (p = 0.011, effect size = 0.627, moderate). Significant pre-to post improvements in MT were observed for NTG but not CG (p = 0.011, effect size = 0.877, moderate). For NTG, post hoc analyses revealed significant MT improvements for the slower (p = 0.012, effect size = 0.897, moderate) and faster directions (p = 0.017, effect size = 0.968, moderate). Conclusion: Our results illustrate that 6 weeks of neuromuscular training with two sessions per week included in the warm-up program, significantly enhanced agility performance in elite soccer players. Moreover, improvements were found on both sides during body rotations. Thus, practitioners are advised to focus their training programs on both turning directions.}, language = {en} } @misc{ZouhalAbderrahmanDupontetal.2019, author = {Zouhal, Hassane and Abderrahman, Abderraouf Ben and Dupont, Gregory and Truptin, Pablo and Le Bris, R{\´e}gis and Le Postec, Erwan and Sghaeir, Zouita and Brughelli, Matt and Granacher, Urs and Bideau, Benoit}, title = {Effects of Neuromuscular Training on Agility Performance in Elite Soccer Players}, series = {Postprints der Universit{\"a}t Potsdam Humanwissenschaftliche Reihe}, journal = {Postprints der Universit{\"a}t Potsdam Humanwissenschaftliche Reihe}, number = {575}, issn = {1866-8364}, doi = {10.25932/publishup-43735}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-437358}, pages = {9}, year = {2019}, abstract = {Background: Agility in general and change-of-direction speed (CoD) in particular represent important performance determinants in elite soccer. Objectives: The objectives of this study were to determine the effects of a 6-week neuromuscular training program on agility performance, and to determine differences in movement times between the slower and faster turning directions in elite soccer players. Materials and Methods: Twenty male elite soccer players from the Stade Rennais Football Club (Ligue 1, France) participated in this study. The players were randomly assigned to a neuromuscular training group (NTG, n = 10) or an active control (CG, n = 10) according to their playing position. NTG participated in a 6-week, twice per week neuromuscular training program that included CoD, plyometric and dynamic stability exercises. Neuromuscular training replaced the regular warm-up program. Each training session lasted 30 min. CG continued their regular training program. Training volume was similar between groups. Before and after the intervention, the two groups performed a reactive agility test that included 180° left and right body rotations followed by a 5-m linear sprint. The weak side was defined as the left/right turning direction that produced slower overall movement times (MT). Reaction time (RT) was assessed and defined as the time from the first appearance of a visual stimulus until the athlete's first movement. MT corresponded to the time from the first movement until the athlete reached the arrival gate (5 m distance). Results: No significant between-group baseline differences were observed for RT or MT. Significant group x time interactions were found for MT (p = 0.012, effect size = 0.332, small) for the slower and faster directions (p = 0.011, effect size = 0.627, moderate). Significant pre-to post improvements in MT were observed for NTG but not CG (p = 0.011, effect size = 0.877, moderate). For NTG, post hoc analyses revealed significant MT improvements for the slower (p = 0.012, effect size = 0.897, moderate) and faster directions (p = 0.017, effect size = 0.968, moderate). Conclusion: Our results illustrate that 6 weeks of neuromuscular training with two sessions per week included in the warm-up program, significantly enhanced agility performance in elite soccer players. Moreover, improvements were found on both sides during body rotations. Thus, practitioners are advised to focus their training programs on both turning directions.}, language = {en} } @article{ZornLeCorvecVarleyetal.2019, author = {Zorn, Edgar Ulrich and Le Corvec, Nicolas and Varley, Nick R. and Salzer, Jacqueline T. and Walter, Thomas R. and Navarro-Ochoa, Carlos and Vargas-Bracamontes, Dulce M. and Thiele, Samuel T. and Ar{\´a}mbula Mendoza, Ra{\´u}l}, title = {Load stress controls on directional lava dome growth at Volcan de Colima, Mexico}, series = {Frontiers in Earth Science}, volume = {7}, journal = {Frontiers in Earth Science}, publisher = {Frontiers Media}, address = {Lausanne}, issn = {2296-6463}, doi = {10.3389/feart.2019.00084}, pages = {18}, year = {2019}, abstract = {During eruptive activity of andesitic stratovolcanoes, the extrusion of lava domes, their collapse and intermittent explosions are common volcanic hazards. Many lava domes grow in a preferred direction, in turn affecting the direction of lava flows and pyroclastic density currents. Access to active lava domes is difficult and hazardous, so detailed data characterizing lava dome growth are typically limited, keeping the processes controlling the directionality of extrusions unclear. Here we combine TerraSAR-X satellite radar observations with high-resolution airborne photogrammetry to assess morphological changes, and perform finite element modeling to investigate the impact of loading stress on shallow magma ascent directions associated with lava dome extrusion and crater formation at Volcan de Colima, Mexico. The TerraSAR-X data, acquired in similar to 1-m resolution spotlight mode, enable us to derive a chronology of the eruptive processes from intensity-based time-lapse observations of the general crater and dome evolution. The satellite images are complemented by close-range airborne photos, processed by the Structure-from-Motion workflow. This allows the derivation of high-resolution digital elevation models, providing insight into detailed loading and unloading features. During the observation period from Jan-2013 to Feb-2016, we identify a dominantly W-directed dome growth and lava flow production until Jan-2015. In Feb-2015, following the removal of the active summit dome, the surface crater widened and elongated along a NE-SW axis. Later in May-2015, a new dome grew toward the SW of the crater while a separate vent developed in the NE of the crater, reflecting a change in the direction of magma ascent and possible conduit bifurcation. Finite element models show a significant stress change in agreement with the observed magma ascent direction changes in response to the changing surface loads, both for loading (dome growth) and unloading (crater forming excavation) cases. These results allow insight into shallow dome growth dynamics and the migration of magma ascent in response to changing volcano summit morphology. They further highlight the importance of detailed volcano summit morphology surveillance, as changes in direction or location of dome extrusion may have major implications regarding the directions of potential volcanic hazards, such as pyroclastic density currents generated by dome collapse.}, language = {en} } @article{ZollDiehlSiebert2019, author = {Zoll, Felix and Diehl, Katharina and Siebert, Rosemarie}, title = {Integrating sustainability goals in innovation processes}, series = {Sustainability}, volume = {11}, journal = {Sustainability}, number = {14}, publisher = {MDPI}, address = {Basel}, issn = {2071-1050}, doi = {10.3390/su11143761}, pages = {15}, year = {2019}, abstract = {The innovative dual-purpose chicken approach aims at contributing to the transition towards sustainable poultry production by avoiding the culling of male chickens. To successfully integrate sustainability aspects into innovation, goal congruency among actors and clearly communicating the added value within the actor network and to consumers is needed. The challenge of identifying common sustainability goals calls for decision support tools. The objectives of our research were to investigate whether the tool could assist in improving communication and marketing with respect to sustainability and optimizing the value chain organization. Three actor groups participated in the tool application, in which quantitative and qualitative data were collected. The results showed that there were manifold sustainability goals within the innovation network, but only some goals overlapped, and the perception of their implementation also diverged. While easily marketable goals such as 'animal welfare' were perceived as being largely implemented, economic goals were prioritized less often, and the implementation was perceived as being rather low. By visualizing congruencies and differences in the goals, the tool helped identify fields of action, such as improved information flows and prompted thinking processes. We conclude that the tool is useful for managing complex decision processes with several actors involved.}, language = {en} } @misc{ZollDiehlSiebert2019, author = {Zoll, Felix and Diehl, Katharina and Siebert, Rosemarie}, title = {Integrating sustainability goals in innovation processes}, series = {Postprints der Universit{\"a}t Potsdam : Mathematisch Naturwissenschaftliche Reihe}, journal = {Postprints der Universit{\"a}t Potsdam : Mathematisch Naturwissenschaftliche Reihe}, number = {1036}, issn = {1866-8372}, doi = {10.25932/publishup-47342}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-473420}, pages = {17}, year = {2019}, abstract = {The innovative dual-purpose chicken approach aims at contributing to the transition towards sustainable poultry production by avoiding the culling of male chickens. To successfully integrate sustainability aspects into innovation, goal congruency among actors and clearly communicating the added value within the actor network and to consumers is needed. The challenge of identifying common sustainability goals calls for decision support tools. The objectives of our research were to investigate whether the tool could assist in improving communication and marketing with respect to sustainability and optimizing the value chain organization. Three actor groups participated in the tool application, in which quantitative and qualitative data were collected. The results showed that there were manifold sustainability goals within the innovation network, but only some goals overlapped, and the perception of their implementation also diverged. While easily marketable goals such as 'animal welfare' were perceived as being largely implemented, economic goals were prioritized less often, and the implementation was perceived as being rather low. By visualizing congruencies and differences in the goals, the tool helped identify fields of action, such as improved information flows and prompted thinking processes. We conclude that the tool is useful for managing complex decision processes with several actors involved.}, language = {en} } @misc{ZinkeWarnkeGaebleretal.2019, author = {Zinke, Fridolin and Warnke, Torsten and G{\"a}bler, Martijn and Granacher, Urs}, title = {Effects of Isokinetic Training on Trunk Muscle Fitness and Body Composition in World-Class Canoe Sprinters}, series = {Postprints der Universit{\"a}t Potsdam Humanwissenschaftliche Reihe}, journal = {Postprints der Universit{\"a}t Potsdam Humanwissenschaftliche Reihe}, number = {536}, issn = {1866-8364}, doi = {10.25932/publishup-42489}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-424898}, year = {2019}, abstract = {In canoe sprint, the trunk muscles play an important role in stabilizing the body in an unstable environment (boat) and in generating forces that are transmitted through the shoulders and arms to the paddle for propulsion of the boat. Isokinetic training is well suited for sports in which propulsion is generated through water resistance due to similarities in the resistive mode. Thus, the purpose of this study was to determine the effects of isokinetic training in addition to regular sport-specific training on trunk muscular fitness and body composition in world-class canoeists and to evaluate associations between trunk muscular fitness and canoe-specific performance. Nine world-class canoeists (age: 25.6 ± 3.3 years; three females; four world champions; three Olympic gold medalists) participated in an 8-week progressive isokinetic training with a 6-week block "muscle hypertrophy" and a 2-week block "muscle power." Pre- and post-tests included the assessment of peak isokinetic torque at different velocities in concentric (30 and 140∘s-1) and eccentric (30 and 90∘s-1) mode, trunk muscle endurance, and body composition (e.g., body fat, segmental lean mass). Additionally, peak paddle force was assessed in the flume at a water current of 3.4 m/s. Significant pre-to-post increases were found for peak torque of the trunk rotators at 30∘s-1 (p = 0.047; d = 0.4) and 140∘s-1 (p = 0.014; d = 0.7) in concentric mode. No significant pre-to-post changes were detected for eccentric trunk rotator torque, trunk muscle endurance, and body composition (p > 0.148). Significant medium-to-large correlations were observed between concentric trunk rotator torque but not trunk muscle endurance and peak paddle force, irrespective of the isokinetic movement velocity (all r ≥ 0.886; p ≤ 0.008). Isokinetic trunk rotator training is effective in improving concentric trunk rotator strength in world-class canoe sprinters. It is recommended to progressively increase angular velocity from 30∘s-1 to 140∘s-1 over the course of the training period.}, language = {en} } @article{ZinkeWarnkeGaebleretal.2019, author = {Zinke, Fridolin and Warnke, Torsten and G{\"a}bler, Martijn and Granacher, Urs}, title = {Effects of Isokinetic Training on Trunk Muscle Fitness and Body Composition in World-Class Canoe Sprinters}, series = {Frontiers in Physiology}, volume = {10}, journal = {Frontiers in Physiology}, publisher = {Frontiers Research Foundation}, address = {Lausanne}, issn = {1664-042X}, doi = {10.3389/fphys.2019.00021}, pages = {10}, year = {2019}, abstract = {In canoe sprint, the trunk muscles play an important role in stabilizing the body in an unstable environment (boat) and in generating forces that are transmitted through the shoulders and arms to the paddle for propulsion of the boat. Isokinetic training is well suited for sports in which propulsion is generated through water resistance due to similarities in the resistive mode. Thus, the purpose of this study was to determine the effects of isokinetic training in addition to regular sport-specific training on trunk muscular fitness and body composition in world-class canoeists and to evaluate associations between trunk muscular fitness and canoe-specific performance. Nine world-class canoeists (age: 25.6 ± 3.3 years; three females; four world champions; three Olympic gold medalists) participated in an 8-week progressive isokinetic training with a 6-week block "muscle hypertrophy" and a 2-week block "muscle power." Pre- and post-tests included the assessment of peak isokinetic torque at different velocities in concentric (30 and 140∘s-1) and eccentric (30 and 90∘s-1) mode, trunk muscle endurance, and body composition (e.g., body fat, segmental lean mass). Additionally, peak paddle force was assessed in the flume at a water current of 3.4 m/s. Significant pre-to-post increases were found for peak torque of the trunk rotators at 30∘s-1 (p = 0.047; d = 0.4) and 140∘s-1 (p = 0.014; d = 0.7) in concentric mode. No significant pre-to-post changes were detected for eccentric trunk rotator torque, trunk muscle endurance, and body composition (p > 0.148). Significant medium-to-large correlations were observed between concentric trunk rotator torque but not trunk muscle endurance and peak paddle force, irrespective of the isokinetic movement velocity (all r ≥ 0.886; p ≤ 0.008). Isokinetic trunk rotator training is effective in improving concentric trunk rotator strength in world-class canoe sprinters. It is recommended to progressively increase angular velocity from 30∘s-1 to 140∘s-1 over the course of the training period.}, language = {en} } @article{ZinkeGebelGranacheretal.2019, author = {Zinke, Fridolin and Gebel, Arnd and Granacher, Urs and Prieske, Olaf}, title = {Acute Effects of Short-Term Local Tendon Vibration on Plantar Flexor Torque, Muscle Contractile Properties, Neuromuscular and Brain Activity in Young Athletes}, series = {Journal of sports science \& medicine}, volume = {18}, journal = {Journal of sports science \& medicine}, number = {2}, publisher = {Department of Sports Medicine, Medical Faculty of Uludag University}, address = {Bursa}, issn = {1303-2968}, pages = {327 -- 336}, year = {2019}, abstract = {The purpose of this study was to examine the acute effects of short-term Achilles tendon vibration on plantar flexor torque, twitch contractile properties as well as muscle and cortical activity in young athletes. Eleven female elite soccer players aged 15.6 +/- 0.5 years participated in this study. Three different conditions were applied in randomized order: Achilles tendon vibration (80 Hz) for 30 and 300 s, and a passive control condition (300 s). Tests at baseline and following conditions included the assessment of peak plantar flexor torque during maximum voluntary contraction, electrically evoked muscle twitches (e.g., potentiated twitch peak torque [PT]), and electromyographic (EMG) activity of the plantar flexors. Additionally, electroencephalographic (EEG) activity of the primary motor and somatosensory cortex were assessed during a submaximal dynamic concentric-eccentric plantar flexion exercise using an elastic rubber band. Large-sized main effects of condition were found for EEG absolute alpha-1 and beta-1 band power (p <= 0.011; 1.5 <= d <= 2.6). Post-hoc tests indicated that alpha-1 power was significantly lower at 30 and 300 s (p = 0.009; d = 0.8) and beta-1 power significantly lower at 300 s (p < 0.001; d = 0.2) compared to control condition. No significant effect of condition was found for peak plantar flexor torque, electrical evoked muscle twitches, and EMG activity. In conclusion, short-term local Achilles tendon vibration induced lower brain activity (i.e., alpha-1 and beta-1 band power) but did not affect lower limb peak torque, twitch contractile properties, and muscle activity. Lower brain activity following short-term local Achilles tendon vibration may indicate improved cortical function during a submaximal dynamic exercise in female young soccer players.}, language = {en} } @misc{ZimmermannKujauConradetal.2019, author = {Zimmermann, Matthias and Kujau, Josephine and Conrad, Hanno Cornelius and Kampe, Heike and Scholz, Jana and Seidel, Nina-Luisa and Eckardt, Barbara and Horn-Conrad, Antje and von Bode, K{\"a}the}, title = {Portal = Wohnen}, number = {02/2019}, organization = {Universit{\"a}t Potsdam, Referat f{\"u}r Presse- und {\"O}ffentlichkeitsarbeit}, issn = {1618-6893}, doi = {10.25932/publishup-44074}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-440742}, pages = {58}, year = {2019}, abstract = {Zuhause. Ein sch{\"o}nes Wort, wenn man eines hat. Ein Sehnsuchtswort, wenn man keines hat oder das eigene Zuhause nicht sicher ist. Zuhause steht auf dem Spiel, das zeigten die Nachrichten der vergangenen Monate und Jahre - in Potsdam und Berlin ebenso wie in vielen anderen St{\"a}dten. {\"U}berall fehlt Wohnraum, den sich Menschen leisten k{\"o}nnen. Seit Monaten kursiert auch in unserem Referat die Frage: Gibt es etwas Neues wegen deiner Wohnung? Streit mit dem Vermieter, Eigent{\"u}merwechsel oder eine auszehrende Wohnungssuche - was uns pers{\"o}nlich besch{\"a}ftigt, ist derzeit {\"u}berall zu h{\"o}ren. Deswegen m{\"o}chten wir in der aktuellen Ausgabe des Universit{\"a}tsmagazins Portal dem Thema Wohnen auf den Grund gehen. Was bedeutet der Mangel an bezahlbarem Wohnraum f{\"u}r die soziale Mischung und wie kann die Politik hier eingreifen? Das haben wir einen Sozialwissenschaftler gefragt. Und wir haben uns umgeh{\"o}rt, wie Studierende und Besch{\"a}ftigte der Universit{\"a}t Potsdam eigentlich wohnen, was f{\"u}r sie Zuhause ist und was ihnen Sorgen bereitet. Wir haben einen Blick in die Wohnheime auf dem Campus Golm gewagt und zeigen Ihnen eine Vision des Standorts als Lebensraum nach menschlichem Maß. Aber auch das Klima l{\"a}sst uns nicht kalt: Wie kann sich eine Stadt wie Potsdam, Wohnort von fast 180.000 Menschen, k{\"u}nftig besser auf Wetterextreme vorbereiten? Wie Sie sicherlich schon bemerkt haben, erscheint die Portal in einem neuen Gewand. Doch wie eh und je haben wir die Menschen an der Universit{\"a}t besucht - in der Hoffnung, dass Sie einander an dieser großen Einrichtung mit den drei Standorten etwas besser kennenlernen. Und auch die Leserinnen und Leser, die die Uni Potsdam nicht so gut kennen, m{\"o}chten wir in das Leben an unserer Hochschule einf{\"u}hren. Wir haben Studierende getroffen, die sich besonders engagieren: f{\"u}r den Schutz des Klimas, die Gleichstellung aller Geschlechter oder im Fakult{\"a}tsrat. Andere musizieren miteinander. In der Serie „Mein Arbeitstag" fragen wir, welche Aufgaben allt{\"a}glich in der Universit{\"a}tsbibliothek zu bew{\"a}ltigen sind. Eine Auszubildende hat ihren Praktikumsalltag im fernen Hongkong mit uns geteilt, w{\"a}hrend uns ein Seminar der Lehrerbildung in die Virtual Reality entf{\"u}hrt. Wir lernen hyperschnelle Sterne und das beste Mittel gegen R{\"u}ckenschmerzen kennen. Was die menschliche Stimme mit den Bewegungen der Erde zu tun hat, erfahren Sie in einem „Laborbesuch". Im „Gespr{\"a}ch" unterh{\"a}lt sich ein Klimaforscher mit einem Sch{\"u}ler und wir zeigen, wo sich Uni und Stadt gefunden haben. Wir nehmen Sie mit in die entstehende „European Digital UniverCity" und erkundigen uns in einer internen „Expertenanfrage" nach einer neuen Frauenbewegung in der Katholischen Kirche. Neugierig haben wir einem Slavisten 15 forsche Fragen gestellt. Ein Linguist erkl{\"a}rt uns, ob und wie wir Außerirdische verstehen k{\"o}nnen, wenn sie denn mit uns sprechen wollen. Wir haben mit einer ausgezeichneten Juristin {\"u}ber die Todesstrafe gesprochen und mit einer Postdoktorandin {\"u}ber selbstspielende Klaviere. Da auch eine junge Uni wie die unsere {\"a}lter wird, schauen wir in der „Zeitreise" zur{\"u}ck in die Kinderstube der Alma Mater und pusten mit Humor den Staub von den Akten. In der Serie „Es war einmal" {\"a}ußern sich zwei Forschende zu einem geschichtlichen Jubil{\"a}um. Und weil unser (und hoffentlich auch Ihr) Wissensdurst keine Grenzen kennt, haben wir ein Wissenschaftswort herumgedreht: den Turn. Was das ist und warum einem davon schwindelig werden kann - lesen Sie es selbst!}, language = {de} } @misc{ZimmermannHornConradGoerlichetal.2019, author = {Zimmermann, Matthias and Horn-Conrad, Antje and G{\"o}rlich, Petra and Schlegel, Karoline and Kampe, Heike}, title = {Portal Wissen = Artificial intelligence}, number = {01/2019}, editor = {Engel, Silke and Zimmermann, Matthias}, address = {54}, organization = {University of Potsdam, Press and Public Relations Department}, issn = {2198-9974}, doi = {10.25932/publishup-44246}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-442469}, year = {2019}, abstract = {For a long time, there were things on this planet that only humans could do, but this time might be coming to an end. By using the universal tool that makes us unique - our intelligence - we have worked to eliminate our uniqueness, at least when it comes to solving cognitive tasks. Artificial intelligence is now able to play chess, understand language, and drive a car - and often better than we. How did we get here? The philosopher Aristotle formulated the first "laws of thought" in his syllogisms, and the mathematicians Blaise Pascal and Wilhelm Leibniz built some of the earliest calculating machines. The mathematician George Boole was the first to introduce a formal language to represent logic. The natural scientist Alan Turing created his deciphering machine "Colossus," the first programmable computer. Philosophers, mathematicians, psychologists, and linguists - for centuries, scientists have been developing formulas, machines, and theories that were supposed to enable us to reproduce and possibly even enhance our most valuable ability. But what exactly is "artificial intelligence"? Even the name calls for comparison. Is artificial intelligence like human intelligence? Alan Turing came up with a test in 1950 to provide a satisfying operational definition of intelligence: According to him, a machine is intelligent if its thinking abilities equal those of humans. It has to reach human levels for any cognitive task. The machine has to prove this by convincing a human interrogator that it is human. Not an easy task: After all, it has to process natural language, store knowledge, draw conclusions, and learn something new. In fact, over the past ten years, a number of AI systems have emerged that have passed the test one way or another in chat conversations with automatically generated texts or images. Nowadays, the discussion usually centers on other questions: Does AI still need its creators? Will it not only outperform humans but someday replace them - be it in the world of work or even beyond? Will AI solve our problems in the age of all-encompassing digital networking - or will it become a part of the problem? Artificial intelligence, its nature, its limitations, its potential, and its relationship to humans were being discussed even before it existed. Literature and film have created scenarios with very different endings. But what is the view of the scientists who are actually researching with or about artificial intelligence? For the current issue of our research magazine, a cognitive scientist, an education researcher, and a computer scientist shared their views. We also searched the University for projects whose professional environment reveals the numerous opportunities that AI offers for various disciplines. We cover the geosciences and computer science as well as economics, health, and literature studies. At the same time, we have not lost sight of the broad research spectrum at the University: a legal expert introduces us to the not-so-distant sphere of space law while astrophysicists work on ensuring that state-of-the-art telescopes observe those regions in space where something "is happening" at the right time. A chemist explains why the battery of the future will come from a printer, and molecular biologists explain how they will breed stress-resistant plants. You will read about all this in this issue as well as about current studies on restless legs syndrome in children and the situation of Muslims in Brandenburg. Last but not least, we will introduce you to the sheep currently grazing in Sanssouci Park - all on behalf of science. Quite clever! Enjoy your read! THE EDITORS}, language = {en} } @misc{ZimmermannHornConradGoerlichetal.2019, author = {Zimmermann, Matthias and Horn-Conrad, Antje and G{\"o}rlich, Petra and Krafzik, Carolin and Kampe, Heike and Schlegel, Karoline and Eckardt, Barbara and B{\"u}rkner, Hans-Joachim and Engel, Silke}, title = {Portal Wissen = K{\"u}nstliche Intelligenz}, number = {01/2019}, organization = {Universit{\"a}t Potsdam, Referat f{\"u}r Presse- und {\"O}ffentlichkeitsarbeit}, issn = {2194-4237}, doi = {10.25932/publishup-44094}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-440942}, pages = {97}, year = {2019}, abstract = {Lange gab es auf der Erde Dinge, die konnte nur der Mensch. Doch diese Zeit k{\"o}nnte zu Ende gehen. Mithilfe des universalen Werkzeugs, das uns einzigartig macht - unserer Intelligenz -, haben wir daf{\"u}r gesorgt, dass wir es nicht l{\"a}nger sind. Zumindest wenn es darum geht, kognitive Aufgaben zu l{\"o}sen. K{\"u}nstliche Intelligenz kann inzwischen Schach spielen, Sprache verstehen, Auto fahren. Vieles sogar besser als wir. Wie kam es dazu? Der Philosoph Aristoteles schuf mit seinen Syllogismen die ersten „Gesetze des Denkens", die Mathematiker Blaise Pascal und Wilhelm Leibniz bauten einige der fr{\"u}hesten Rechenmaschinen, der Mathematiker George Boole f{\"u}hrte als erster eine formale Sprache zur Darstellung der Logik ein, der Naturwissenschaftler Alan Turing schuf mit seiner Dechiffriermaschine „Colossus" den ersten programmierbaren Computer. Philosophen, Mathematiker, Psychologen, Linguisten - seit Jahrhunderten entwickeln Wissenschaftlerin- nen und Wissenschaftler Formeln, Maschinen und Theorien, die es m{\"o}glich machen sollen, unsere wertvollste F{\"a}higkeit zu reproduzieren und wom{\"o}glich sogar zu verbessern. Aber was ist das eigentlich: „K{\"u}nstliche Intelligenz"? Schon die Bezeichnung fordert zum Vergleich auf. Ist K{\"u}nstliche Intelligenz wie menschliche Intelligenz? Alan Turing formulierte 1950 einen Test, der eine befriedigende operationale Definition von Intelligenz liefern sollte: Intelligent ist eine Maschine demnach, wenn sie ein dem Menschen gleichwertiges Denkverm{\"o}gen besitzt. Sie muss also bei beliebigen kognitiven Aufgaben dasselbe Niveau erreichen. Beweisen muss sie dies, indem sie einen menschlichen Fragenden glauben l{\"a}sst, sie sei ein Mensch. Keine leichte Sache: Immerhin muss sie daf{\"u}r nat{\"u}rliche Sprache verarbeiten, Wissen speichern, aus diesem Schl{\"u}sse ziehen und Neues lernen k{\"o}nnen. Tats{\"a}chlich entstanden in den vergangenen zehn Jahren etliche KI-Systeme, die in Chat- Gespr{\"a}chen, mit automatisch erzeugten Texten oder Bildern den Test auf die eine oder andere Weise bestanden. Im Fokus stehen nun meist andere Fragen: Braucht KI ihre Sch{\"o}pfer {\"u}berhaupt noch? Wird sie den Menschen nicht nur {\"u}berfl{\"u}geln, sondern eines Tages sogar ersetzen - sei es in der Welt der Arbeit oder sogar dar{\"u}ber hinaus? L{\"o}st KI im Zeitalter der allumfassenden digitalen Vernetzung unsere Probleme - oder wird sie Teil davon? {\"U}ber K{\"u}nstliche Intelligenz, ihr Wesen, ihre Beschr{\"a}nkungen, ihr Potenzial und ihr Verh{\"a}ltnis zum Menschen wird nicht erst diskutiert seitdem es sie gibt. Vor allem Literatur und Kino haben Szenarien mit verschiedenstem Ausgang kreiert. Aber wie sehen das Wissenschaftler, die mit oder zu K{\"u}nstlicher Intelligenz forschen? F{\"u}r die aktuelle Ausgabe des Forschungsmagazins kamen ein Kognitionswissenschaftler, eine Bildungsforscherin und ein Informatiker dar{\"u}ber ins Gespr{\"a}ch. Daneben haben wir uns in der Hochschule nach Projekten umgesehen, deren fachliche Heimat die zahlreichen M{\"o}glichkeiten offenbart, die KI f{\"u}r viele Disziplinen erahnen l{\"a}sst. So geht die Reise in die Geowissenschaften und die Informatik ebenso wie die Wirtschafts-, Gesundheits- und Literaturwissenschaften. Daneben haben wir die Breite der Forschung an der Universit{\"a}t nicht aus den Augen verloren: Ein Jurist f{\"u}hrt ein in die gar nicht so weltferne Sph{\"a}re des Weltraumrechts, w{\"a}hrend Astrophysiker daran arbeiten, dass modernste Teleskope zum richtigen Zeitpunkt genau in die Regionen des Weltraums schauen, wo gerade etwas „los ist". Eine Chemikerin erkl{\"a}rt, warum die Batterie der Zukunft aus dem Drucker kommt, und Molekularbiologen berichten, wie sie stressresistente Pflanzen z{\"u}chten wollen. Mit menschlichem Stress in der Arbeitswelt besch{\"a}ftigt sich nicht nur ein Forschungs-, sondern auch ein Gr{\"u}nderprojekt. Dar{\"u}ber ist in diesem Heft genauso zu lesen wie {\"u}ber aktuelle Studien zum Restless Legs Syndrom bei Kindern oder aber der Situation von Muslimen in Brandenburg. Nicht zuletzt machen wir Sie mit jenen Schafen bekannt, die derzeit im Park Sanssouci weiden - im Auftrag der Wissenschaft. Gar nicht so dumm! Viel Vergn{\"u}gen! Die Redaktion}, language = {de} } @article{Zimmermann2019, author = {Zimmermann, Malte}, title = {Im Korpus gibt's keine V{\"o}gel nicht}, series = {Of trees and birds. A Festschrift for Gisbert Fanselow}, journal = {Of trees and birds. A Festschrift for Gisbert Fanselow}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, isbn = {978-3-86956-457-9}, doi = {10.25932/publishup-43254}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-432541}, pages = {287 -- 306}, year = {2019}, language = {en} } @article{Zimmermann2019, author = {Zimmermann, Ilse}, title = {Zur Analysierbarkeit adverbieller Konnektive}, series = {Of trees and birds. A Festschrift for Gisbert Fanselow}, journal = {Of trees and birds. A Festschrift for Gisbert Fanselow}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, isbn = {978-3-86956-457-9}, doi = {10.25932/publishup-43194}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-431942}, pages = {37 -- 60}, year = {2019}, language = {de} } @article{ZimmermannHarmsEppetal.2019, author = {Zimmermann, Heike Hildegard and Harms, Lars and Epp, Laura Saskia and Mewes, Nick and Bernhardt, Nadine and Kruse, Stefan and Stoof-Leichsenring, Kathleen Rosemarie and Pestryakova, Luidmila Agafyevna and Wieczorek, Mareike and Trense, Daronja and Herzschuh, Ulrike}, title = {Chloroplast and mitochondrial genetic variation of larches at the Siberian tundrataiga ecotone revealed by de novo assembly}, series = {PLoS one}, volume = {14}, journal = {PLoS one}, number = {7}, publisher = {PLoS}, address = {San Fransisco}, issn = {1932-6203}, doi = {10.1371/journal.pone.0216966}, pages = {21}, year = {2019}, abstract = {Larix populations at the tundra-taiga ecotone in northern Siberia are highly under-represented in population genetic studies, possibly due to the remoteness of these regions that can only be accessed at extraordinary expense. The genetic signatures of populations in these boundary regions are therefore largely unknown. We aim to generate organelle reference genomes for the detection of single nucleotide polymorphisms (SNPs) that can be used for paleogenetic studies. We present 19 complete chloroplast genomes and mitochondrial genomic sequences of larches from the southern lowlands of the Taymyr Peninsula (northernmost range of Larix gmelinii (Rupr.) Kuzen.), the lower Omoloy River, and the lower Kolyma River (both in the range of Larix cajanderi Mayr). The genomic data reveal 84 chloroplast SNPs and 213 putatively mitochondrial SNPs. Parsimony-based chloroplast haplotype networks show no spatial structure of individuals from different geographic origins, while the mitochondrial haplotype network shows at least a slight spatial structure with haplotypes from the Omoloy and Kolyma populations being more closely related to each other than to most of the haplotypes from the Taymyr populations. Whole genome alignments with publicly available complete chloroplast genomes of different Larix species show that among official plant barcodes only the rcbL gene contains sufficient polymorphisms, but has to be sequenced completely to distinguish the different provenances. We provide 8 novel mitochondrial SNPs that are putatively diagnostic for the separation of L. gmelinii and L. cajanderi, while 4 chloroplast SNPs have the potential to distinguish the L. gmelinii/ L. cajanderi group from other Larix species. Our organelle references can be used for a targeted primer and probe design allowing the generation of short amplicons. This is particularly important with regard to future investigations of, for example, the biogeographic history of Larix by screening ancient sedimentary DNA of Larix.}, language = {en} } @article{ZimmermannWeiss2019, author = {Zimmermann, Andreas and Weiß, Norman}, title = {International Law in Times of Anti-Globalism and Populism - Challenges Ahead}, publisher = {Oxford University Press}, address = {Oxford}, pages = {265 -- 273}, year = {2019}, language = {en} } @book{ZimmermannFreiburgBraun2019, author = {Zimmermann, Andreas and Freiburg-Braun, Elisa}, title = {Aggression under the Rome Statute}, publisher = {Nomos}, address = {Baden-Baden}, isbn = {978-3-8487-4678-1}, pages = {VII, 110}, year = {2019}, abstract = {Das Werk analysiert umfassend das Verbrechen der Aggression im Sinne des R{\"o}mischen Statuts. Ausgehend von der Rechtsgeschichte, werde die einschl{\"a}gigen Artikel 8bis, 15bis und 15ter des R{\"o}mischen Statuts, also die Definition des Verbrechens der Aggression, analysiert. Ebenso behandelt das Buch weiterf{\"u}hrende Entwicklungen des Verbrechens der Aggression {\"u}ber das Jahr 2017 hinaus - das Jahr, in dem es, wahrscheinlich, zu einer Entscheidung {\"u}ber die Aktivierung der Gerichtsbarkeit kommt}, language = {en} } @article{Zimmering2019, author = {Zimmering, Raina}, title = {Basisdemokratische Gesellschaften als alternative kulturelle R{\"a}ume}, series = {Berliner Debatte Initial : sozial- und geisteswissenschaftliches Journal}, volume = {30}, journal = {Berliner Debatte Initial : sozial- und geisteswissenschaftliches Journal}, number = {1}, publisher = {WeltTrends}, address = {Potsdam}, isbn = {978-3-947802-23-4}, issn = {0863-4564}, pages = {53 -- 63}, year = {2019}, language = {de} } @article{ZiesemerHuettelBalderjahn2019, author = {Ziesemer, Florence and H{\"u}ttel, Alexandra and Balderjahn, Ingo}, title = {Anti-Consumption}, series = {Sustainability}, volume = {11}, journal = {Sustainability}, number = {23}, publisher = {MDPI}, address = {Basel}, issn = {2071-1050}, doi = {10.3390/su11236663}, pages = {16}, year = {2019}, abstract = {Transcending the conventional debate around efficiency in sustainable consumption, anti-consumption patterns leading to decreased levels of material consumption have been gaining importance. Change agents are crucial for the promotion of such patterns, so there may be lessons for governance interventions that can be learnt from the every-day experiences of those who actively implement and promote sustainability in the field of anti-consumption. Eighteen social innovation pioneers, who engage in and diffuse practices of voluntary simplicity and collaborative consumption as sustainable options of anti-consumption share their knowledge and personal insights in expert interviews for this research. Our qualitative content analysis reveals drivers, barriers, and governance strategies to strengthen anti-consumption patterns, which are negotiated between the market, the state, and civil society. Recommendations derived from the interviews concern entrepreneurship, municipal infrastructures in support of local grassroots projects, regulative policy measures, more positive communication to strengthen the visibility of initiatives and emphasize individual benefits, establishing a sense of community, anti-consumer activism, and education. We argue for complementary action between top-down strategies, bottom-up initiatives, corporate activities, and consumer behavior. The results are valuable to researchers, activists, marketers, and policymakers who seek to enhance their understanding of materially reduced consumption patterns based on the real-life experiences of active pioneers in the field.}, language = {en} } @misc{ZiesemerHuettelBalderjahn2019, author = {Ziesemer, Florence and H{\"u}ttel, Alexandra and Balderjahn, Ingo}, title = {Pioneers' insights into governing social innovation for sustainable anti-consumption}, series = {Postprints der Universit{\"a}t Potsdam Wirtschafts- und Sozialwissenschaftliche Reihe}, journal = {Postprints der Universit{\"a}t Potsdam Wirtschafts- und Sozialwissenschaftliche Reihe}, number = {116}, issn = {1867-5808}, doi = {10.25932/publishup-43940}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-439404}, pages = {16}, year = {2019}, abstract = {Transcending the conventional debate around efficiency in sustainable consumption, anti-consumption patterns leading to decreased levels of material consumption have been gaining importance. Change agents are crucial for the promotion of such patterns, so there may be lessons for governance interventions that can be learnt from the every-day experiences of those who actively implement and promote sustainability in the field of anti-consumption. Eighteen social innovation pioneers, who engage in and diffuse practices of voluntary simplicity and collaborative consumption as sustainable options of anti-consumption share their knowledge and personal insights in expert interviews for this research. Our qualitative content analysis reveals drivers, barriers, and governance strategies to strengthen anti-consumption patterns, which are negotiated between the market, the state, and civil society. Recommendations derived from the interviews concern entrepreneurship, municipal infrastructures in support of local grassroots projects, regulative policy measures, more positive communication to strengthen the visibility of initiatives and emphasize individual benefits, establishing a sense of community, anti-consumer activism, and education. We argue for complementary action between top-down strategies, bottom-up initiatives, corporate activities, and consumer behavior. The results are valuable to researchers, activists, marketers, and policymakers who seek to enhance their understanding of materially reduced consumption patterns based on the real-life experiences of active pioneers in the field.}, language = {en} } @article{ZhuShpritsSpasojevicetal.2019, author = {Zhu, Hui and Shprits, Yuri Y. and Spasojevic, M. and Drozdov, Alexander Y.}, title = {New hiss and chorus waves diffusion coefficient parameterizations from the Van Allen Probes and their effect on long-term relativistic electron radiation-belt VERB simulations}, series = {Journal of Atmospheric and Solar-Terrestrial Physics}, volume = {193}, journal = {Journal of Atmospheric and Solar-Terrestrial Physics}, publisher = {Elsevier}, address = {Oxford}, issn = {1364-6826}, doi = {10.1016/j.jastp.2019.105090}, pages = {13}, year = {2019}, abstract = {New wave frequency and amplitude models for the nightside and dayside chorus waves are built based on measurements from the Electric and Magnetic Field Instrument Suite and Integrated Science (EMFISIS) instrument onboard the Van Allen Probes. The corresponding 3D diffusion coefficients are systematically obtained. Compared with previous commonly-used (typical) parameterizations, the new parameterizations result in differences in diffusion rates that depend on the energy and pitch angle. Furthermore, one-year 3D diffusive simulations are performed using the Versatile Electron Radiation Belt (VERB) code. Both typical and new wave parameterizations simulation results are in a good agreement with observations at 0.9 MeV. However, the new parameterizations for nightside chorus better reproduce the observed electron fluxes. These parameterizations will be incorporated into future modeling efforts.}, language = {en} } @article{ZhuChenLiuetal.2019, author = {Zhu, Hui and Chen, Lunjin and Liu, Xu and Shprits, Yuri Y.}, title = {Modulation of locally generated equatorial noise by ULF wave}, series = {Journal of geophysical research : Space physics}, volume = {124}, journal = {Journal of geophysical research : Space physics}, number = {4}, publisher = {American Geophysical Union}, address = {Washington}, issn = {2169-9380}, doi = {10.1029/2018JA026199}, pages = {2779 -- 2787}, year = {2019}, abstract = {In this paper we report a rare and fortunate event of fast magnetosonic (MS, also called equatorial noise) waves modulated by compressional ultralow frequency (ULF) waves measured by Van Allen Probes. The characteristics of MS waves, ULF waves, proton distribution, and their potential correlations are analyzed. The results show that ULF waves can modulate the energetic ring proton distribution and in turn modulate the MS generation. Furthermore, the variation of MS intensities is attributed to not only ULF wave activities but also the variation of background parameters, for example, number density. The results confirm the opinion that MS waves are generated by proton ring distribution and propose a new modulation phenomenon.}, language = {en} } @article{ZhuPilzCotton2019, author = {Zhu, Chuanbin and Pilz, Marco and Cotton, Fabrice Pierre}, title = {Which is a better proxy, site period or depth to bedrock, in modelling linear site response in addition to the average shear-wave velocity?}, series = {Bulletin of earthquake engineering : official publication of the European Association for Earthquake Engineering}, volume = {18}, journal = {Bulletin of earthquake engineering : official publication of the European Association for Earthquake Engineering}, number = {3}, publisher = {Springer}, address = {Dordrecht}, issn = {1570-761X}, doi = {10.1007/s10518-019-00738-6}, pages = {797 -- 820}, year = {2019}, abstract = {This study aims to identify the best-performing site characterization proxy alternative and complementary to the conventional 30 m average shear-wave velocity V-S30, as well as the optimal combination of proxies in characterizing linear site response. Investigated proxies include T-0 (site fundamental period obtained from earthquake horizontal-to-vertical spectral ratios), V-Sz (measured average shear-wave velocities to depth z, z = 5, 10, 20 and 30 m), Z(0.8) and Z(1.0) (measured site depths to layers having shear-wave velocity 0.8 and 1.0 km/s, respectively), as well as Z(x-infer) (inferred site depths from a regional velocity model, x = 0.8 and 1.0, 1.5 and 2.5 km/s). To evaluate the performance of a site proxy or a combination, a total of 1840 surface-borehole recordings is selected from KiK-net database. Site amplifications are derived using surface-to-borehole response-, Fourier- and cross-spectral ratio techniques and then are compared across approaches. Next, the efficacies of 7 single-proxies and 11 proxy-pairs are quantified based on the site-to-site standard deviation of amplification residuals of observation about prediction using the proxy or the pair. Our results show that T-0 is the best-performing single-proxy among T-0, Z(0.8), Z(1.0) and V-Sz. Meanwhile, T-0 is also the best-performing proxy among T-0, Z(0.8), Z(1.0) and Z(x-infer) complementary to V-S30 in accounting for the residual amplification after V-S30-correction. Besides, T-0 alone can capture most of the site effects and should be utilized as the primary site indicator. Though (T-0, V-S30) is the best-performing proxy pair among (V-S30, T-0), (V-S30, Z(0.8)), (V-S30, Z(1.0)), (V-S30, Z(x-infer)) and (T-0, V-Sz), it is only slightly better than (T-0, V-S20). Considering both efficacy and engineering utility, the combination of T-0 (primary) and V-S20 (secondary) is recommended. Further study is needed to test the performances of various proxies on sites in deep sedimentary basins.}, language = {en} } @article{ZhuCottonPilz2019, author = {Zhu, Chuanbin and Cotton, Fabrice Pierre and Pilz, Marco}, title = {Testing the Depths to 1.0 and 2.5 km/s Velocity Isosurfaces in a Velocity Model for Japan and Implications for Ground-Motion Modeling}, series = {Bulletin of the Seismological Society of America}, volume = {109}, journal = {Bulletin of the Seismological Society of America}, number = {6}, publisher = {Seismological Society of America}, address = {Albany}, issn = {0037-1106}, doi = {10.1785/0120190016}, pages = {2710 -- 2721}, year = {2019}, abstract = {In the Next Generation Attenuation West2 (NGA-West2) project, a 3D subsurface structure model (Japan Seismic Hazard Information Station [J-SHIS]) was queried to establish depths to 1.0 and 2.5 km/s velocity isosurfaces for sites without depth measurement in Japan. In this article, we evaluate the depth parameters in the J-SHIS velocity model by comparing them with their corresponding site-specific depth measurements derived from selected KiK-net velocity profiles. The comparison indicates that the J-SHIS model underestimates site depths at shallow sites and overestimates depths at deep sites. Similar issues were also identified in the southern California basin model. Our results also show that these underestimations and over-estimations have a potentially significant impact on ground-motion prediction using NGA-West2 ground-motion models (GMMs). Site resonant period may be considered as an alternative to depth parameter in the site term of a GMM.}, language = {en} } @article{ZhengPikovskij2019, author = {Zheng, Chunming and Pikovskij, Arkadij}, title = {Stochastic bursting in unidirectionally delay-coupled noisy excitable systems}, series = {Chaos : an interdisciplinary journal of nonlinear science}, volume = {29}, journal = {Chaos : an interdisciplinary journal of nonlinear science}, number = {4}, publisher = {American Institute of Physics}, address = {Melville}, issn = {1054-1500}, doi = {10.1063/1.5093180}, pages = {9}, year = {2019}, abstract = {We show that "stochastic bursting" is observed in a ring of unidirectional delay-coupled noisy excitable systems, thanks to the combinational action of time-delayed coupling and noise. Under the approximation of timescale separation, i.e., when the time delays in each connection are much larger than the characteristic duration of the spikes, the observed rather coherent spike pattern can be described by an idealized coupled point processwith a leader-follower relationship. We derive analytically the statistics of the spikes in each unit, the pairwise correlations between any two units, and the spectrum of the total output from the network. Theory is in good agreement with the simulations with a network of theta-neurons. Published under license by AIP Publishing.}, language = {en} } @article{ZhelayskayaVasileShpritsetal.2019, author = {Zhelayskaya, Irina S. and Vasile, Ruggero and Shprits, Yuri Y. and Stolle, Claudia and Matzka, J{\"u}rgen}, title = {Systematic Analysis of Machine Learning and Feature Selection Techniques for Prediction of the Kp Index}, series = {Space Weather: The International Journal of Research and Applications}, volume = {17}, journal = {Space Weather: The International Journal of Research and Applications}, number = {10}, publisher = {American Geophysical Union}, address = {Washington}, issn = {1542-7390}, doi = {10.1029/2019SW002271}, pages = {1461 -- 1486}, year = {2019}, abstract = {The Kp index is a measure of the midlatitude global geomagnetic activity and represents short-term magnetic variations driven by solar wind plasma and interplanetary magnetic field. The Kp index is one of the most widely used indicators for space weather alerts and serves as input to various models, such as for the thermosphere and the radiation belts. It is therefore crucial to predict the Kp index accurately. Previous work in this area has mostly employed artificial neural networks to nowcast Kp, based their inferences on the recent history of Kp and on solar wind measurements at L1. In this study, we systematically test how different machine learning techniques perform on the task of nowcasting and forecasting Kp for prediction horizons of up to 12 hr. Additionally, we investigate different methods of machine learning and information theory for selecting the optimal inputs to a predictive model. We illustrate how these methods can be applied to select the most important inputs to a predictive model of Kp and to significantly reduce input dimensionality. We compare our best performing models based on a reduced set of optimal inputs with the existing models of Kp, using different test intervals, and show how this selection can affect model performance.}, language = {en} } @article{ZhangRammingHeinkeetal.2019, author = {Zhang, Yunming and Ramming, Anna and Heinke, Lisa and Altschmied, Lothar and Slotkin, R. Keith and Becker, J{\"o}rg D. and Kappel, Christian and Lenhard, Michael}, title = {The poly(A) polymerase PAPS1 interacts with the RNA-directed DNA-methylation pathway in sporophyte and pollen development}, series = {The plant journal}, volume = {99}, journal = {The plant journal}, number = {4}, publisher = {Wiley}, address = {Hoboken}, issn = {0960-7412}, doi = {10.1111/tpj.14348}, pages = {655 -- 672}, year = {2019}, abstract = {RNA-based processes play key roles in the regulation of eukaryotic gene expression. This includes both the processing of pre-mRNAs into mature mRNAs ready for translation and RNA-based silencing processes, such as RNA-directed DNA methylation (RdDM). Polyadenylation of pre-mRNAs is one important step in their processing and is carried out by three functionally specialized canonical nuclear poly(A) polymerases in Arabidopsis thaliana. Null mutations in one of these, termed PAPS1, result in a male gametophytic defect. Using a fluorescence-labelling strategy, we have characterized this defect in more detail using RNA and small-RNA sequencing. In addition to global defects in the expression of pollen-differentiation genes, paps1 null-mutant pollen shows a strong overaccumulation of transposable element (TE) transcripts, yet a depletion of 21- and particularly 24-nucleotide-long short interfering RNAs (siRNAs) and microRNAs (miRNAs) targeting the corresponding TEs. Double-mutant analyses support a specific functional interaction between PAPS1 and components of the RdDM pathway, as evident from strong synergistic phenotypes in mutant combinations involving paps1, but not paps2 paps4, mutations. In particular, the double-mutant of paps1 and rna-dependent rna polymerase 6 (rdr6) shows a synergistic developmental phenotype disrupting the formation of the transmitting tract in the female gynoecium. Thus, our findings in A. thaliana uncover a potentially general link between canonical poly(A) polymerases as components of mRNA processing and RdDM, reflecting an analogous interaction in fission yeast.}, language = {en} } @article{ZhangHuangZhangetal.2019, author = {Zhang, Yang and Huang, Wentao and Zhang, Yuanyuan and Poujol, Marc and Guillot, Stephane and Roperch, Pierrick and Dupont-Nivet, Guillaume and Guo, Zhaojie}, title = {Detrital zircon provenance comparison between the Paleocene-Eocene Nangqian-Xialaxiu and Gongjue basins: New insights for Cenozoic paleogeographic evolution of the eastern Tibetan Plateau}, series = {Palaeogeography, palaeoclimatology, palaeoecology : an international journal for the geo-sciences}, volume = {533}, journal = {Palaeogeography, palaeoclimatology, palaeoecology : an international journal for the geo-sciences}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0031-0182}, doi = {10.1016/j.palaeo.2019.109241}, pages = {19}, year = {2019}, abstract = {Paleogeographic reconstructions of terranes can greatly benefit from the provenance analysis of sediments. A series of Cenozoic basins provide key sedimentary archives for investigating the growth of the Tibetan Plateau, yet the provenance of the sediments in these basins has never been constrained robustly. Here we report sedimentary petrological and detrital zircon geochronological data from the Paleocene-Eocene Nangqian-Xialaxiu and Gongjue basins. Sandstone detrital modes and zircon morphology suggest that the samples collected in these two basins were sourced from recycled orogen. Detrital zircon geochronology indicates that sediments in the Nangqian-Xialaxiu Basin are characterized by two distinct age populations at 220-280 Ma and 405-445 Ma. In contrast, three predominant age populations of 207-256 Ma, 423-445 Ma, and 1851-1868 Ma, and two subordinate age populations of similar to 50 Ma and similar to 2500 Ma, are recognized in the Gongjue Basin. Comparison with detrital zircon ages from the surrounding terranes suggests that sediments in the Nangqian-Xialaxiu Basin come from the neighboring thrust belts, whereas sediments from the Gongjue Basin are predominantly derived from the distant Songpan-Ganzi Terrane with minor contribution from the surrounding areas. A three-stage Cenozoic evolution of the eastern Tibetan Plateau is proposed. During the Paleocene, the Nangqian-Xialaxiu Basin appeared as a set of small intermontane sub-basins and received plentiful sediments from the neighboring mountain belts; during the Eocene, the Gongjue Basin kept a relatively low altitude and was a depression at the edge of a proto-Plateau; since the Oligocene, the Tibetan Plateau further uplifted and the marginal Gongjue Basin was involved in the Tibetan interior orogeny, indicating the eastward propagation of the Tibetan Plateau.}, language = {en} } @phdthesis{Zhang2019, author = {Zhang, Xiaorong}, title = {Electrosynthesis and characterization of molecularly imprinted polymers for peptides and proteins}, school = {Universit{\"a}t Potsdam}, pages = {116}, year = {2019}, language = {en} } @article{ZhangKochovskiLeeetal.2019, author = {Zhang, Su-Yun and Kochovski, Zdravko and Lee, Hui-Chun and Lu, Yan and Zhang, Hemin and Zhang, Jie and Sun, Jian-Ke and Yuan, Jiayin}, title = {Ionic organic cage-encapsulating phase-transferable metal clusters}, series = {Chemical science}, volume = {10}, journal = {Chemical science}, number = {5}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {2041-6520}, doi = {10.1039/c8sc04375b}, pages = {1450 -- 1456}, year = {2019}, abstract = {Exploration of metal clusters (MCs) adaptive to both aqueous and oil phases without disturbing their size is promising for a broad scope of applications. The state-of-the-art approach via ligand-binding may perturb MCs' size due to varied metal-ligand binding strength when shuttling between solvents of different polarity. Herein, we applied physical confinement of a series of small noble MCs (<1 nm) inside ionic organic cages (I-Cages), which by means of anion exchange enables reversible transfer of MCs between aqueous and hydrophobic solutions without varying their ultrasmall size. Moreover, the MCs@I-Cage hybrid serves as a recyclable, reaction-switchable catalyst featuring high activity in liquid-phase NH3BH3 (AB) hydrolysis reaction with a turnover frequency (TOF) of 115 min-1.}, language = {en} } @article{ZhangGuoTangetal.2019, author = {Zhang, Su-Yun and Guo, Wen-Bin and Tang, Ying-Ying and Xu, Jin-Qiu and He, Zhang-Zhen}, title = {Observation of Spin Relaxation in a Vanadate Chloride with Quasi-One-Dimensional Linear Chain}, series = {Crystal growth \& design : integrating the fields of crystal engineering and crystal growth for the synthesis and applications of new materials}, volume = {19}, journal = {Crystal growth \& design : integrating the fields of crystal engineering and crystal growth for the synthesis and applications of new materials}, number = {4}, publisher = {American Chemical Society}, address = {Washington}, issn = {1528-7483}, doi = {10.1021/acs.cgd.8b01839}, pages = {2228 -- 2234}, year = {2019}, abstract = {A new cobalt(II) vanadate chloride, Pb2Co(OH)(V2O7)Cl, has been synthesized under mild hydrothermal conditions. It contains quasi-one-dimensional (1D) linear chains built by edge-sharing of (CoO6)-O-II octahedra. The cobalt(II) oxide chains are further interconnected by (V2O7)(4-) dimers into a three-dimensional (3D) anionic framework with Pb2+ and Cl- ions residing in Co4V8 12-member ring tunnels. The intrachain Co center dot center dot center dot Co distance is 3.041 angstrom, while the interchain distances are 8.742 and 9.256 angstrom. Magnetic measurements suggest the ferromagnetic intrachain and the antiferromagnetic interchain interactions with a specific value of J(intra)/J(inter) = 1.7 x 10(3). Zero-field heat capacity demonstrates the magnetic long-range ordering at 5.5 K. Alternating current (AC) magnetic susceptibility under zero external direct current (DC) fields displays two slow magnetic relaxations at low temperatures, giving characteristic relaxations (tau(0)) of 1.2(3) x 10(-12) and 1.9(4) x 10(-10) s with effective energy barriers (Delta(r)) of 76.1(2) and 48.4(5) K. The energy barrier between the spin up and spin-down states can be ascribed to the ferromagnetic spin chain and the Ising-like magnetic anisotropy in Pb2Co(OH)(V2O7)Cl.}, language = {en} } @article{ZhangBramskiTutusetal.2019, author = {Zhang, Shuhao and Bramski, Julia and Tutus, Murat and Pietruszka, J{\"o}rg and B{\"o}ker, Alexander and Reinicke, Stefan}, title = {A Biocatalytically Active Membrane Obtained from Immobilization of 2-Deoxy-D-ribose-5-phosphate Aldolase on a Porous Support}, series = {ACS applied materials \& interfaces}, volume = {11}, journal = {ACS applied materials \& interfaces}, number = {37}, publisher = {American Chemical Society}, address = {Washington}, issn = {1944-8244}, doi = {10.1021/acsami.9b12029}, pages = {34441 -- 34453}, year = {2019}, abstract = {Aldol reactions play an important role in organic synthesis, as they belong to the class of highly beneficial C-C-linking reactions. Aldol-type reactions can be efficiently and stereoselectively catalyzed by the enzyme 2-deoxy-D-ribose-5-phosphate aldolase (DERA) to gain key intermediates for pharmaceuticals such as atorvastatin. The immobilization of DERA would open the opportunity for a continuous operation mode which gives access to an efficient, large-scale production of respective organic intermediates. In this contribution, we synthesize and utilize DERA/polymer conjugates for the generation and fixation of a DERA bearing thin film on a polymeric membrane support. The conjugation strongly increases the tolerance of the enzyme toward the industrial relevant substrate acetaldehyde while UV-cross-linkable groups along the conjugated polymer chains provide the opportunity for covalent binding to the support. First, we provide a thorough characterization of the conjugates followed by immobilization tests on representative, nonporous cycloolefinic copolymer supports. Finally, immobilization on the target supports constituted of polyacrylonitrile (PAN) membranes is performed, and the resulting enzymatically active membranes are implemented in a simple membrane module setup for the first assessment of biocatalytic performance in the continuous operation mode using the combination hexanal/acetaldehyde as the substrate.}, language = {en} } @phdthesis{Zhang2019, author = {Zhang, Shuhao}, title = {Synthesis and self-assembly of protein-polymer conjugates for the preparation of biocatalytically active membranes}, school = {Universit{\"a}t Potsdam}, pages = {VIII, 161}, year = {2019}, abstract = {This thesis covers the synthesis of conjugates of 2-Deoxy-D-ribose-5-phosphate aldolase (DERA) with suitable polymers and the subsequent immobilization of these conjugates in thin films via two different approaches. 2-Deoxy-D-ribose-5-phosphate aldolase (DERA) is a biocatalyst that is capable of converting acetaldehyde and a second aldehyde as acceptor into enantiomerically pure mono- and diyhydroxyaldehydes, which are important structural motifs in a number of pharmaceutically active compounds. Conjugation and immobilization renders the enzyme applicable for utilization in a continuously run biocatalytic process which avoids the common problem of product inhibition. Within this thesis, conjugates of DERA and poly(N-isopropylacrylamide) (PNIPAm) for immobilization via a self-assembly approach were synthesized and isolated, as well as conjugates with poly(N,N-dimethylacrylamide) (PDMAA) for a simplified and scalable spray-coating approach. For the DERA/PNIPAm-conjugates different synthesis routes were tested, including grafting-from and grafting-to, both being common methods for the conjugation. Furthermore, both lysines and cysteines were addressed for the conjugation in order to find optimum conjugation conditions. It turned out that conjugation via lysine causes severe activity loss as one lysine plays a key role in the catalyzing mechanism. The conjugation via the cysteines by a grafting-to approach using pyridyl disulfide (PDS) end-group functionalized polymers led to high conjugation efficiencies in the presence of polymer solubilizing NaSCN. The resulting conjugates maintained enzymatic activity and also gained high acetaldehyde tolerance which is necessary for their use later on in an industrial relevant process after their immobilization. The resulting DERA/PNIPAm conjugates exhibited enhanced interfacial activity at the air/water interface compared to the single components, which is an important pre-requisite for the immobilization via the self-assembly approach. Conjugates with longer polymer chains formed homogeneous films on silicon wafers and glass slides while the ones with short chains could only form isolated aggregates. On top of that, long chain conjugates showed better activity maintenance upon the immobilization. The crosslinking of conjugates, as well as their fixation on the support materials, are important for the mechanical stability of the films obtained from the self-assembly process. Therefore, in a second step, we introduced the UV-crosslinkable monomer DMMIBA to the PNIPAm polymers to be used for conjugation. The introduction of DMMIBA reduced the lower critical solution temperature (LCST) of the polymer and thus the water solubility at ambient conditions, resulting in lower conjugation efficiencies and in turn slightly poorer acetaldehyde tolerance of the resulting conjugates. Unlike the DERA/PNIPAm, the conjugates from the copolymer P(NIPAM-co-DMMIBA) formed continuous, homogenous films only after the crosslinking step via UV-treatment. For a firm binding of the crosslinked films, a functionalization protocol for the model support material cyclic olefin copolymer (COC) and the final target support, PAN based membranes, was developed that introduces analogue UV-reactive groups to the support surface. The conjugates immobilized on the modified COC films maintained enzymatic activity and showed good mechanical stability after several cycles of activity assessment. Conjugates with longer polymer chains, however, showed a higher degree of crosslinking after the UV-treatment leading to a pronounced loss of activity. A porous PAN membrane onto which the conjugates were immobilized as well, was finally transferred to a dead end filtration membrane module to catalyze the aldol reaction of the industrially relevant mixture of acetaldehyde and hexanal in a continuous mode. Mono aldol product was detectable, but yields were comparably low and the operational stability needs to be further improved Another approach towards immobilization of DERA conjugates that was followed, was to generate the conjugates in situ by simply mixing enzyme and polymer and spray coat the mixture onto the membrane support. Compared to the previous approach, the focus was more put on simplicity and a possible scalability of the immobilization. Conjugates were thus only generated in-situ and not further isolated and characterized. For the conjugation, PDMAA equipped with N-2-thiolactone acrylamide (TlaAm) side chains was used, an amine-reactive comonomer that can react with the lysine residues of DERA, as well as with amino groups introduced to a desired support surface. Furthermore disulfide formation after hydrolysis of the Tla groups causes a crosslinking effect. The synthesized copolymer poly(N,N-Dimethylacrylamide-co-N-2-thiolactone acrylamide) (P(DMAA-co-TlaAm)) thus serves a multiple purpose including protein binding, crosslinking and binding to support materials. The mixture of DERA and polymer could be immobilized on the PAN support by spray-coating under partial maintenance of enzymatic activity. To improve the acetaldehyde tolerance, the polymer in used was further equipped with cysteine reactive PDS end-groups that had been used for the conjugation as described in the first part of the thesis. The generated conjugates indeed showed good acetaldehyde tolerance and were thus used to be coated onto PAN membrane supports. Post treatment with a basic aqueous solution of H2O2 was supposed to further crosslink the spray-coated film hydrolysis and oxidation of the thiolactone groups. However, a washing off of the material was observed. Optimization is thus still necessary.}, language = {en} } @article{ZhangHosseiniGunderetal.2019, author = {Zhang, Shanshan and Hosseini, Seyed Mehrdad and Gunder, Rene and Petsiuk, Andrei and Caprioglio, Pietro and Wolff, Christian Michael and Shoaee, Safa and Meredith, Paul and Schorr, Susan and Unold, Thomas and Burn, Paul L. and Neher, Dieter and Stolterfoht, Martin}, title = {The Role of Bulk and Interface Recombination in High-Efficiency Low-Dimensional Perovskite Solar Cells}, series = {Advanced materials}, volume = {31}, journal = {Advanced materials}, number = {30}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {0935-9648}, doi = {10.1002/adma.201901090}, pages = {11}, year = {2019}, abstract = {2D Ruddlesden-Popper perovskite (RPP) solar cells have excellent environmental stability. However, the power conversion efficiency (PCE) of RPP cells remains inferior to 3D perovskite-based cells. Herein, 2D (CH3(CH2)(3)NH3)(2)(CH3NH3)(n-1)PbnI3n+1 perovskite cells with different numbers of [PbI6](4-) sheets (n = 2-4) are analyzed. Photoluminescence quantum yield (PLQY) measurements show that nonradiative open-circuit voltage (V-OC) losses outweigh radiative losses in materials with n > 2. The n = 3 and n = 4 films exhibit a higher PLQY than the standard 3D methylammonium lead iodide perovskite although this is accompanied by increased interfacial recombination at the top perovskite/C-60 interface. This tradeoff results in a similar PLQY in all devices, including the n = 2 system where the perovskite bulk dominates the recombination properties of the cell. In most cases the quasi-Fermi level splitting matches the device V-OC within 20 meV, which indicates minimal recombination losses at the metal contacts. The results show that poor charge transport rather than exciton dissociation is the primary reason for the reduction in fill factor of the RPP devices. Optimized n = 4 RPP solar cells had PCEs of 13\% with significant potential for further improvements.}, language = {en} } @article{ZhangRudolphBenitezetal.2019, author = {Zhang, Quanchao and Rudolph, Tobias and Benitez, Alejandro J. and Gould, Oliver E. C. and Behl, Marc and Kratz, Karl and Lendlein, Andreas}, title = {Temperature-controlled reversible pore size change of electrospun fibrous shape-memory polymer actuator based meshes}, series = {Smart materials and structures}, volume = {28}, journal = {Smart materials and structures}, number = {5}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0964-1726}, doi = {10.1088/1361-665X/ab10a1}, pages = {10}, year = {2019}, abstract = {Fibrous membranes capable of dynamically responding to external stimuli are highly desirable in textiles and biomedical materials, where adaptive behavior is required to accommodate complex environmental changes. For example, the creation of fabrics with temperature-dependent moisture permeability or self-regulating membranes for air filtration is dependent on the development of materials that exhibit a reversible stimuli-responsive pore size change. Here, by imbuing covalently crosslinked poly(ε-caprolactone) (cPCL) fibrous meshes with a reversible bidirectional shape-memory polymer actuation (rbSMPA) we create a material capable of temperature-controlled changes in porosity. Cyclic thermomechanical testing was used to characterize the mechanical properties of the meshes, which were composed of randomly arranged microfibers with diameters of 2.3 ± 0.6 μm giving an average pore size of approx. 10 μm. When subjected to programming strains of εm = 300\% and 100\% reversible strain changes of εʹrev = 22\% ± 1\% and 6\% ± 1\% were measured, with switching temperature ranges of 10 °C-30 °C and 45 °C-60 °C for heating and cooling, respectively. The rbSMPA of cPCL fibrous meshes generated a microscale reversible pore size change of 11\% ± 3\% (an average of 1.5 ± 0.6 μm), as measured by scanning electron microscopy. The incorporation of a two-way shape-memory actuation capability into fibrous meshes is anticipated to advance the development and application of smart membrane materials, creating commercially viable textiles and devices with enhanced performance and novel functionality.}, language = {en} } @article{ZhangBehlPengetal.2019, author = {Zhang, Pengfei and Behl, Marc and Peng, Xingzhou and Balk, Maria and Lendlein, Andreas}, title = {Chemoresponsive Shape-Memory Effect of Rhodium-Phosphine Coordination Polymer Networks}, series = {Chemistry of materials : a publication of the American Chemical Society}, volume = {31}, journal = {Chemistry of materials : a publication of the American Chemical Society}, number = {15}, publisher = {American Chemical Society}, address = {Washington}, issn = {0897-4756}, doi = {10.1021/acs.chemmater.9b00363}, pages = {5402 -- 5407}, year = {2019}, abstract = {Chemoresponsive polymers are of technological significance for smart sensors or systems capable of molecular recognition. An important key requirement for these applications is the material's structural integrity after stimulation. We explored whether covalently cross-linked metal ion-phosphine coordination polymers (MPN) can be shaped into any temporary shape and are capable of recovering from this upon chemoresponsive exposure to triphenylphosphine (Ph3P) ligands, whereas the MPN provide structural integrity. Depending on the metal-ion concentration used during synthesis of the MPN, the degree of swelling of the coordination polymer networks could be adjusted. Once the MPN was immersed into Ph3P solution, the reversible ligand-exchange reaction between the metal ions and the free Ph3P in solution causes a decrease of the coordination cross-link density in MPN again. The Ph3P-treated MPN was able to maintain its original shape, indicating a certain stability of shape even after stimulation. In this way, chemoresponsive control of the elastic properties (increase in volume and decrease of mechanical strength) of the MPN was demonstrated. This remarkable behavior motivated us to explore whether the MPN are capable of a chemoresponsive shape-memory effect. In initial experiments, shape fixity of around 60\% and shape recovery of almost 90\% were achieved when the MPN was exposed to Ph3P in case of rhodium. Potential applications for chemoresponsive shape-memory systems could be shapable semiconductors, e.g., for lighting or catalysts, which provide catalytic activity on demand.}, language = {en} } @article{ZhangNajmanMeietal.2019, author = {Zhang, Peng and Najman, Yani and Mei, Lianfu and Millar, Ian and Sobel, Edward and Carter, Andrew and Barfod, Dan and Dhuime, Bruno and Garzanti, Eduardo and Govin, Gwladys and Vezzoli, Giovanni and Hu, Xiaolin}, title = {Palaeodrainage evolution of the large rivers of East Asia, and Himalayan-Tibet tectonics}, series = {Earth science reviews}, volume = {192}, journal = {Earth science reviews}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0012-8252}, doi = {10.1016/j.earscirev.2019.02.003}, pages = {601 -- 630}, year = {2019}, abstract = {A number of sedimentary provenance studies have been undertaken in order to determine whether the palaeo-Red River was once a river of continental proportions into which the upper reaches of the Yangtze, Salween, Mekong, Irrawaddy, and Yarlung drained. We have assessed the evidence that the Yarlung originally flowed into the palaeo-Red river, and then sequentially into the Irrawaddy and Brahmaputra, connecting to the latter first via the Lohit and then the Siang. For this river system, we have integrated our new data from the Paleogene-Recent Irrawaddy drainage basin (detrital zircon U-Pb with Hf and fission track, rutile U-Pb, mica Ar-Ar, bulk rock Sr-Nd, and petrography) with previously published data, to produce a palaeodrainage model that is consistent with all datasets. In our model, the Yarlung never flowed into the Irrawaddy drainage: during the Paleogene, the Yarlung suture zone was an internally drained basin, and from Neogene times onwards the Yarlung drained into the Brahmaputra in the Bengal Basin. The Central Myanmar Basin, through which the Irrawaddy River flows today, received predominantly locally-derived detritus until the Middle Eocene, the Irrawaddy initiated as a through-going river draining the Mogok Metamorphic Belt and Bomi-Chayu granites to the north sometime in the Late Eocene to Early Oligocene, and the river was dominated by a stable MMB-dominated drainage throughout the Neogene to present day. Existing evidence does not support any connection between the Yarlung and the Red River in the past, but there is a paucity of suitable palaeo-Red River deposits with which to make a robust comparison. We argue that this limitation also precludes a robust assessment of a palaeo-connection between the Yangtze/ Salween/Mekong and the Red River; it is difficult to unequivocally interpret the recorded provenance changes as the result of specific drainage reorganisations. We highlight the palaeo-Red River deposits of the Hanoi Basin as a potential location for future research focus in view of the near-complete Cenozoic record of palaeo-Red River deposits at this location. A majority of previous studies consider that if a major continental-scale drainage ever existed at all, it fragmented early in the Cenozoic. Such a viewpoint would agree with the growing body of evidence from palaeoaltitude studies that large parts of SE Tibet were uplifted by this period. This then leads towards the intriguing question as to the mechanisms which caused the major period of river incision in the Miocene in this region.}, language = {en} } @article{ZghalColsonBlainetal.2019, author = {Zghal, Firas and Colson, Serge S. and Blain, Gr{\´e}gory and Behm, David George and Granacher, Urs and Chaouachi, Anis}, title = {Combined Resistance and Plyometric Training Is More Effective Than Plyometric Training Alone for Improving Physical Fitness of Pubertal Soccer Players}, series = {frontiers in Physiology}, volume = {10}, journal = {frontiers in Physiology}, number = {August 2019}, publisher = {Frontiers Research Foundation}, address = {Lausanne}, issn = {1664-042X}, doi = {10.3389/fphys.2019.01026}, pages = {11}, year = {2019}, abstract = {The purpose of this study was to compare the effects of combined resistance and plyometric/sprint training with plyometric/sprint training or typical soccer training alone on muscle strength and power, speed, change-of-direction ability in young soccer players. Thirty-one young (14.5 ± 0.52 years; tanner stage 3-4) soccer players were randomly assigned to either a combined- (COMB, n = 14), plyometric-training (PLYO, n = 9) or an active control group (CONT, n = 8). Two training sessions were added to the regular soccer training consisting of one session of light-load high-velocity resistance exercises combined with one session of plyometric/sprint training (COMB), two sessions of plyometric/sprint training (PLYO) or two soccer training sessions (CONT). Training volume was similar between the experimental groups. Before and after 7-weeks of training, peak torque, as well as absolute and relative (normalized to torque; RTDr) rate of torque development (RTD) during maximal voluntary isometric contraction of the knee extensors (KE) were monitored at time intervals from the onset of contraction to 200 ms. Jump height, sprinting speed at 5, 10, 20-m and change-of-direction ability performances were also assessed. There were no significant between-group baseline differences. Both COMB and PLYO significantly increased their jump height (Δ14.3\%; ES = 0.94; Δ12.1\%; ES = 0.54, respectively) and RTD at mid to late phases but with greater within effect sizes in COMB in comparison with PLYO. However, significant increases in peak torque (Δ16.9\%; p < 0.001; ES = 0.58), RTD (Δ44.3\%; ES = 0.71), RTDr (Δ27.3\%; ES = 0.62) and sprint performance at 5-m (Δ-4.7\%; p < 0.001; ES = 0.73) were found in COMB without any significant pre-to-post change in PLYO and CONT groups. Our results suggest that COMB is more effective than PLYO or CONT for enhancing strength, sprint and jump performances.}, language = {en} } @misc{ZghalColsonBlainetal.2019, author = {Zghal, Firas and Colson, Serge S. and Blain, Gr{\´e}gory and Behm, David George and Granacher, Urs and Chaouachi, Anis}, title = {Combined Resistance and Plyometric Training Is More Effective Than Plyometric Training Alone for Improving Physical Fitness of Pubertal Soccer Players}, series = {Postprints der Universit{\"a}t Potsdam Humanwissenschaftliche Reihe}, journal = {Postprints der Universit{\"a}t Potsdam Humanwissenschaftliche Reihe}, number = {576}, issn = {1866-8364}, doi = {10.25932/publishup-43781}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-437810}, pages = {12}, year = {2019}, abstract = {The purpose of this study was to compare the effects of combined resistance and plyometric/sprint training with plyometric/sprint training or typical soccer training alone on muscle strength and power, speed, change-of-direction ability in young soccer players. Thirty-one young (14.5 ± 0.52 years; tanner stage 3-4) soccer players were randomly assigned to either a combined- (COMB, n = 14), plyometric-training (PLYO, n = 9) or an active control group (CONT, n = 8). Two training sessions were added to the regular soccer training consisting of one session of light-load high-velocity resistance exercises combined with one session of plyometric/sprint training (COMB), two sessions of plyometric/sprint training (PLYO) or two soccer training sessions (CONT). Training volume was similar between the experimental groups. Before and after 7-weeks of training, peak torque, as well as absolute and relative (normalized to torque; RTDr) rate of torque development (RTD) during maximal voluntary isometric contraction of the knee extensors (KE) were monitored at time intervals from the onset of contraction to 200 ms. Jump height, sprinting speed at 5, 10, 20-m and change-of-direction ability performances were also assessed. There were no significant between-group baseline differences. Both COMB and PLYO significantly increased their jump height (Δ14.3\%; ES = 0.94; Δ12.1\%; ES = 0.54, respectively) and RTD at mid to late phases but with greater within effect sizes in COMB in comparison with PLYO. However, significant increases in peak torque (Δ16.9\%; p < 0.001; ES = 0.58), RTD (Δ44.3\%; ES = 0.71), RTDr (Δ27.3\%; ES = 0.62) and sprint performance at 5-m (Δ-4.7\%; p < 0.001; ES = 0.73) were found in COMB without any significant pre-to-post change in PLYO and CONT groups. Our results suggest that COMB is more effective than PLYO or CONT for enhancing strength, sprint and jump performances.}, language = {en} } @article{ZeuschnerParpiievPezeriletal.2019, author = {Zeuschner, Steffen and Parpiiev, Tymur and Pezeril, Thomas and Hillion, Arnaud and Dumesnil, Karine and Anane, Abdelmadjid and Pudell, Jan-Etienne and Willig, Lisa and R{\"o}ssle, Matthias and Herzog, Marc and von Reppert, Alexander and Bargheer, Matias}, title = {Tracking picosecond strain pulses in heterostructures that exhibit giant magnetostriction}, series = {Structural Dynamics}, volume = {6}, journal = {Structural Dynamics}, number = {2}, publisher = {AIP Publishing LLC}, address = {Melville, NY}, issn = {2329-7778}, doi = {10.1063/1.5084140}, pages = {9}, year = {2019}, abstract = {We combine ultrafast X-ray diffraction (UXRD) and time-resolved Magneto-Optical Kerr Effect (MOKE) measurements to monitor the strain pulses in laser-excited TbFe2/Nb heterostructures. Spatial separation of the Nb detection layer from the laser excitation region allows for a background-free characterization of the laser-generated strain pulses. We clearly observe symmetric bipolar strain pulses if the excited TbFe2 surface terminates the sample and a decomposition of the strain wavepacket into an asymmetric bipolar and a unipolar pulse, if a SiO2 glass capping layer covers the excited TbFe2 layer. The inverse magnetostriction of the temporally separated unipolar strain pulses in this sample leads to a MOKE signal that linearly depends on the strain pulse amplitude measured through UXRD. Linear chain model simulations accurately predict the timing and shape of UXRD and MOKE signals that are caused by the strain reflections from multiple interfaces in the heterostructure.}, language = {en} }