@misc{Linker2020, author = {Linker, Torsten}, title = {Addition of Heteroatom Radicals to endo-Glycals}, series = {Postprints der Universit{\"a}t Potsdam : Mathematisch-Naturwissenschaftliche Reihe}, journal = {Postprints der Universit{\"a}t Potsdam : Mathematisch-Naturwissenschaftliche Reihe}, number = {873}, issn = {1866-8372}, doi = {10.25932/publishup-45997}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-459970}, pages = {15}, year = {2020}, abstract = {Radical reactions have found many applications in carbohydrate chemistry, especially in the construction of carbon-carbon bonds. The formation of carbon-heteroatom bonds has been less intensively studied. This mini-review will summarize the efforts to add heteroatom radicals to unsaturated carbohydrates like endo-glycals. Starting from early examples, developed more than 50 years ago, the importance of such reactions for carbohydrate chemistry and recent applications will be discussed. After a short introduction, the mini-review is divided in sub-chapters according to the heteroatoms halogen, nitrogen, phosphorus, and sulfur. The mechanisms of radical generation by chemical or photochemical processes and the subsequent reactions of the radicals at the 1-position will be discussed. This mini-review cannot cover all aspects of heteroatom-centered radicals in carbohydrate chemistry, but should provide an overview of the various strategies and future perspectives}, language = {en} } @article{Linker2020, author = {Linker, Torsten}, title = {Addition of Heteroatom Radicals to endo-Glycals}, series = {Chemistry}, volume = {2}, journal = {Chemistry}, number = {1}, publisher = {MDPI}, address = {Basel}, issn = {2624-8549}, doi = {10.3390/chemistry2010008}, pages = {80 -- 92}, year = {2020}, abstract = {Radical reactions have found many applications in carbohydrate chemistry, especially in the construction of carbon-carbon bonds. The formation of carbon-heteroatom bonds has been less intensively studied. This mini-review will summarize the efforts to add heteroatom radicals to unsaturated carbohydrates like endo-glycals. Starting from early examples, developed more than 50 years ago, the importance of such reactions for carbohydrate chemistry and recent applications will be discussed. After a short introduction, the mini-review is divided in sub-chapters according to the heteroatoms halogen, nitrogen, phosphorus, and sulfur. The mechanisms of radical generation by chemical or photochemical processes and the subsequent reactions of the radicals at the 1-position will be discussed. This mini-review cannot cover all aspects of heteroatom-centered radicals in carbohydrate chemistry, but should provide an overview of the various strategies and future perspectives}, language = {en} }