@article{AllroggenvanSchaikTronicke2015,
  author    = {Allroggen, Niklas and van Schaik, N. Loes M. B. and Tronicke, Jens},
  title     = {4D ground-penetrating radar during a plot scale dye tracer experiment},
  series = {Journal of applied geophysics},
  volume    = {118},
  journal   = {Journal of applied geophysics},
  publisher = {Elsevier},
  address   = {Amsterdam},
  issn      = {0926-9851},
  doi       = {10.1016/j.jappgeo.2015.04.016},
  pages     = {139 -- 144},
  year      = {2015},
  abstract  = {Flow phenomena in the unsaturated zone are highly variable in time and space. Thus, it is challenging to measure and monitor such processes under field conditions. Here, we present a new setup and interpretation approach for combining a dye tracer experiment with a 4D ground-penetrating radar (GPR) survey. Therefore, we designed a rainfall experiment during which we measured three surface-based 3D GPR surveys using a pair of 500 MHz antennas. Such a survey setup requires accurate acquisition and processing techniquesto extract time-lapse information supporting the interpretation of selected cross-sections photographed after excavating the site. Our results reveal patterns of traveltime changes in the measured GPR data, which are associated with soil moisture changes. As distinct horizons are present at our site, such changes can be quantified and transferred into changes in total soil moisture content. Our soil moisture estimates are similar to the amount of infiltrated water, which confirms our experimental approach and makes us confident for further developing this strategy, especially, with respect to improving the temporal and spatial resolution. (C) 2015 Elsevier B.V. All rights reserved.},
  language  = {en}
}
@article{KrmičekTimmermanZiemannetal.2020,
  author    = {Krm{\´i}ček, Luk{\´a}š and Timmerman, Martin Jan and Ziemann, Martin Andreas and Sudo, Masafumi and Ulrych, Jaromir},
  title     = {40Ar/39Ar step-heating dating of phlogopite and kaersutite megacrysts from the Železn{\´a} hůrka (Eisenb{\"u}hl) Pleistocene scoria cone, Czech Republic},
  series = {Geologica Carpathica},
  volume    = {71},
  journal   = {Geologica Carpathica},
  number    = {4},
  publisher = {Veda},
  address   = {Bratislava},
  issn      = {1335-0552},
  doi       = {10.31577/GeolCarp.71.4.6},
  pages     = {382 -- 387},
  year      = {2020},
  abstract  = {(40)A/Ar-39 step-heating of mica and amphibole megacrysts from hauyne-bearing olivine melilitite scoria/tephra from the Zelezna hurka yielded a 435 +/- 108 ka isotope correlation age for phlogopite and a more imprecise 1.55 Ma total gas age of the kaersutite megacryst. The amphibole megacrysts may constitute the first, and the younger phlogopite megacrysts the later phase of mafic, hydrous melilitic magma crystallization. It cannot be ruled out that the amphibole megacrysts are petrogenetically unrelated to tephra and phlogopite megacrysts and were derived from mantle xenoliths or disaggregated older, deep crustal pegmatites. This is in line both with the rarity of amphibole at Zelezna hurka and with the observed signs of magmatic resorption at the edges of amphibole crystals.},
  language  = {en}
}
@article{FranzSudoKhomenko2022,
  author    = {Franz, Gerhard and Sudo, Masafumi and Khomenko, Vladimir},
  title     = {40Ar/39Ar dating of a hydrothermal pegmatitic buddingtonite-muscovite assemblage from Volyn, Ukraine},
  series = {European journal of mineralogy : EJM : an international journal on mineralogy, petrology, geochemistry, and related sciences},
  volume    = {34},
  journal   = {European journal of mineralogy : EJM : an international journal on mineralogy, petrology, geochemistry, and related sciences},
  number    = {1},
  publisher = {Copernicus},
  address   = {G{\"o}ttingen},
  issn      = {0935-1221},
  doi       = {10.5194/ejm-34-7-2022},
  pages     = {7 -- 18},
  year      = {2022},
  abstract  = {We determined Ar-40/Ar-39 ages of buddingtonite, occurring together with muscovite, with the laser-ablation method. This is the first attempt to date the NH4-feldspar buddingtonite, which is typical for sedimentary-diagenetic environments of sediments, rich in organic matter, or in hydrothermal environments, associated with volcanic geyser systems. The sample is a hydrothermal breccia, coming from the Paleoproterozoic pegmatite field of the Korosten Plutonic Complex, Volyn, Ukraine. A detailed characterization by optical methods, electron microprobe analyses, backscattered electron imaging, and IR analyses showed that the buddingtonite consists of euhedral-appearing platy crystals of tens of micrometers wide, 100 or more micrometers in length, which consist of fine-grained fibers of <= 1 mu m thickness. The crystals are sector and growth zoned in terms of K-NH4-H3O content. The content of K allows for an age determination with the Ar-40/Ar-39 method, as well as in the accompanying muscovite, intimately intergrown with the buddingtonite. The determinations on muscovite yielded an age of 1491 +/- 9 Ma, interpreted as the hydrothermal event forming the breccia. However, buddingtonite apparent ages yielded a range of 563 +/- 14 Ma down to 383 +/- 12 Ma, which are interpreted as reset ages due to Ar loss of the fibrous buddingtonite crystals during later heating. We conclude that buddingtonite is suited for Ar-40/Ar-39 age determinations as a supplementary method, together with other methods and minerals; however, it requires a detailed mineralogical characterization, and the ages will likely represent minimum ages.},
  language  = {en}
}
@article{SchwarzerHuamaniCanoetal.2010,
  author    = {Schwarzer, Christian and Huamani, Fatima Cßceres and Cano, Asunci{\´o}n and La Torre, Mar{\´i}a I. La and Weigend, Maximilian},
  title     = {400 years for long-distance dispersal and divergence in the northern atacama desert : insights from the Huaynaputina pumice slopes of Moquegua, Peru},
  issn      = {0140-1963},
  doi       = {10.1016/j.jaridenv.2010.05.034},
  year      = {2010},
  abstract  = {The Huaynaputina eruption (1600 AD, Moquegua, S Peru) in the northern Atacama Desert denuded the Ornate area of all vegetation and deposited deep pumice layers. Data on the flora, climate and soil characteristics of these slopes near Ornate at 1600-2600 m a.s.l. are provided. Fifty-nine angiosperm species established themselves on the pumice slopes in the past ca. 400 years, with the bulk of the small and herbaceous species and several species new records for Peru. Three Ornate sites were sampled in both a dry and a wet year and species numbers differed widely (14 versus 45 spp.). Among areas compared floristic composition is most similar to the Lomas de Tacna, and has less in common with geographically closer Lomas or Sierra formations. Nine species represent highly disjunct populations (200->700 km) from their nearest known living populations in central Peru, Chile, or Argentina/Bolivia and appear to have reached the area via long-distance dispersal. Abiotic conditions may have played an important role in limiting the establishment of species from the neighboring vegetation. Four taxa on the pumice slopes show clear morphological differences to populations elsewhere, two of them may represent neoendemics of the Ornate pumice, indicating rapid morphological divergence. (C) 2010 Elsevier Ltd. All rights reserved.},
  language  = {en}
}
@article{LazarevaShainyanKleinpeter2010,
  author    = {Lazareva, Nataliya F. and Shainyan, Bagrat A. and Kleinpeter, Erich},
  title     = {4-Alkyl-2,2,6,6-tetramethyl-1,4,2,6-oxaazadisilinanes : synthesis, structure, and conformational analysis},
  issn      = {0894-3230},
  doi       = {10.1002/Poc.1605},
  year      = {2010},
  abstract  = {4-Alkyl-2,2,6,6-tetramethyl-1,4,2,6-oxaazadisilinanes RN[CH2Si(Me)2]2O [R = Me (1), i-Pr (2)] were synthesized by two methods which provided good yields up to 84\%. Low temperature NMR study of compounds (1) and (2) revealed a frozen ring inversion with the energy barriers of 8.5 and 7.7 kcal/mol at 163 and 143 K, respectively, which is substantially lower than that for their carbon analog, N-methylmorpholine. DFT calculations performed on the example of molecule (1) showed that N-Meax conformer to exist in the sofa conformation with the coplanar fragment C-Si-O-Si-C, and its N-Meeq conformer in a flattened chair conformation.},
  language  = {en}
}
@article{AwadSchildeStrauch2011,
  author    = {Awad, Duha Jawad and Schilde, Uwe and Strauch, Peter},
  title     = {4,4 '-Bis(tert-butyl)-2,2 '-bipyridinedichlorometal(II) - Synthesis, structure and EPR spectroscopy},
  series = {Inorganica chimica acta : the international inorganic chemistry journal},
  volume    = {365},
  journal   = {Inorganica chimica acta : the international inorganic chemistry journal},
  number    = {1},
  publisher = {Elsevier},
  address   = {Lausanne},
  issn      = {0020-1693},
  doi       = {10.1016/j.ica.2010.08.035},
  pages     = {127 -- 132},
  year      = {2011},
  abstract  = {Due to the better solubility of the 4,4'-substituted bipyridine ligand a series of 4,4'0-bis(tert-butyl)-2,2'-bipyridinedichlorometal(II) complexes, [M(tbbpy)Cl(2)], with M = Cu, Ni, Zn, Pd, Pt was synthesised and characterised. The blue copper complex 4,4'-bis(tert-butyl)-2,2'-bipyridinedichlorocopper(II) was isolated in two different polymorphic forms, as prisms 1 with a solvent inclusion and solvent-free as needles 2. Both structures were determined by X-ray structure analysis. They crystallise in the monoclinic space group P2(1)/c with four molecules in the unit cell, but with different unit cells and packing motifs. Whereas in the prisms 1, with the unit cell parameters a = 12.1613(12), b = 10.6363(7), c = 16.3074(15) angstrom, eta = 94.446(8)degrees, the packing is dominated by intra-and intermolecular hydrogen bonds, in the needles 2, with a = 7.738(1), b = 18. 333(2), c = 13.291(3) angstrom, beta = 97.512(15)degrees, only intramolecular hydrogen bonds appear and the complex molecules are arranged in columns which are stabilised by p-p-stacking interactions. In both complexes the copper has a tetrahedrally distorted coordination sphere. These copper complexes were also studied by EPR spectroscopy in solution, as frozen glass and diamagnetically diluted powder with the analogue [Pd(tbbpy)Cl(2)] as host lattice.},
  language  = {en}
}
@article{DereseBarasaAkalaetal.2014,
  author    = {Derese, Solomon and Barasa, Leonard and Akala, Hoseah M. and Yusuf, Amir O. and Kamau, Edwin and Heydenreich, Matthias and Yenesew, Abiy},
  title     = {4 '-Prenyloxyderrone from the stem bark of Millettia oblata ssp teitensis and the antiplasmodial activities of isoflavones from some Millettia species},
  series = {Phytochemistry letters},
  volume    = {8},
  journal   = {Phytochemistry letters},
  publisher = {Elsevier},
  address   = {Amsterdam},
  issn      = {1874-3900},
  doi       = {10.1016/j.phytol.2014.02.001},
  pages     = {69 -- 72},
  year      = {2014},
  abstract  = {The CH2Cl2/MeOH (1: 1) extract of the stem bark of Millettia oblata ssp. teitensis showed antiplasmodial activity (IC50 = 10-12 mu g/mL) against the chloroquine-sensitive (D6) and chloroquine-resistant (W2) strains of Plasmodium falciparum. Chromatographic separation of the extract led to the isolation of a new isoflavone, 4'-prenyloxyderrone (1), together with known isoflavones (8-O-methylretusin, durmillone, maximaisoflavone B, maximaisoflavone H and maximaisoflavone J), a rotenoid (tephrosin) and a triterpene (lupeol). Similar investigation of Millettia leucantha resulted in the identification of the isoflavones afrormosin and wistin, and the flavone chrysin. The identification of these compounds was based on their spectroscopic data. Five of the isoflavones isolated from these plants as well as 11 previously reported compounds from Millettia dura were tested and showed good to moderate antiplasmodial activities (IC50 = 13-53 mu M), with the new compound, 4'-prenyloxyderrone, being the most active (IC50 = 13-15 mu M).},
  language  = {en}
}
@article{SarauliPetersXuetal.2014,
  author    = {Sarauli, David and Peters, Kristina and Xu, Chenggang and Schulz, Burkhard and Fattakhova-Rohlfing, Dina and Lisdat, Fred},
  title     = {3D-Electrode architectures for enhanced direct bioelectrocatalysis of pyrroloquinoline quinone-dependent glucose dehydrogenase},
  series = {ACS applied materials \& interfaces},
  volume    = {6},
  journal   = {ACS applied materials \& interfaces},
  number    = {20},
  publisher = {American Chemical Society},
  address   = {Washington},
  issn      = {1944-8244},
  doi       = {10.1021/am5046026},
  pages     = {17887 -- 17893},
  year      = {2014},
  abstract  = {We report on the fabrication of a complex electrode architecture for efficient direct bioelectrocatalysis. In the developed procedure, the redox enzyme pyrroloquinoline quinone-dependent glucose dehydrogenase entrapped in a sulfonated polyaniline [poly(2-methoxyaniline-5-sulfonic acid)-co-aniline] was immobilized on macroporous indium tin oxide (macroITO) electrodes. The use of the 3D-conducting scaffold with a large surface area in combination with the conductive polymer enables immobilization of large amounts of enzyme and its efficient communication with the electrode, leading to enhanced direct bioelectrocatalysis. In the presence of glucose, the fabricated bioelectrodes show an exceptionally high direct bioelectrocatalytical response without any additional mediator. The catalytic current is increased more than 200-fold compared to planar ITO electrodes. Together with a high long-term stability (the current response is maintained for >90\% of the initial value even after 2 weeks of storage), the transparent 3D macroITO structure with a conductive polymer represents a valuable basis for the construction of highly efficient bioelectronic units, which are useful as indicators for processes liberating glucose and allowing optical and electrochemical transduction.},
  language  = {en}
}
@article{ThompsonKliemToeroek2012,
  author    = {Thompson, W. T. and Kliem, Bernhard and Toeroek, Tibor},
  title     = {3D reconstruction of a rotating erupting prominence},
  series = {Solar physics : a journal for solar and solar-stellar research and the study of solar terrestrial physics},
  volume    = {276},
  journal   = {Solar physics : a journal for solar and solar-stellar research and the study of solar terrestrial physics},
  number    = {1-2},
  publisher = {Springer},
  address   = {Dordrecht},
  issn      = {0038-0938},
  doi       = {10.1007/s11207-011-9868-5},
  pages     = {241 -- 259},
  year      = {2012},
  abstract  = {A bright prominence associated with a coronal mass ejection (CME) was seen erupting from the Sun on 9 April 2008. This prominence was tracked by both the Solar Terrestrial Relations Observatory (STEREO) EUVI and COR1 telescopes, and was seen to rotate about the line of sight as it erupted; therefore, the event has been nicknamed the "Cartwheel CME." The threads of the prominence in the core of the CME quite clearly indicate the structure of a weakly to moderately twisted flux rope throughout the field of view, up to heliocentric heights of 4 solar radii. Although the STEREO separation was 48A degrees, it was possible to match some sharp features in the later part of the eruption as seen in the 304 line in EUVI and in the H alpha-sensitive bandpass of COR1 by both STEREO Ahead and Behind. These features could then be traced out in three-dimensional space, and reprojected into a view in which the eruption is directed toward the observer. The reconstructed view shows that the alignment of the prominence to the vertical axis rotates as it rises up to a leading-edge height of a parts per thousand aEuro parts per thousand 2.5 solar radii, and then remains approximately constant. The alignment at 2.5 solar radii differs by about 115A degrees from the original filament orientation inferred from H alpha and EUV data, and the height profile of the rotation, obtained here for the first time, shows that two thirds of the total rotation are reached within a parts per thousand aEuro parts per thousand 0.5 solar radii above the photosphere. These features are well reproduced by numerical simulations of an unstable moderately twisted flux rope embedded in external flux with a relatively strong shear field component.},
  language  = {en}
}
@article{KoyanTronicke2020,
  author    = {Koyan, Philipp and Tronicke, Jens},
  title     = {3D modeling of ground-penetrating radar data across a realistic sedimentary model},
  series = {Computers \& geosciences : an international journal devoted to the publication of papers on all aspects of geocomputation and to the distribution of computer programs and test data sets ; an official journal of the International Association for Mathematical Geology},
  volume    = {137},
  journal   = {Computers \& geosciences : an international journal devoted to the publication of papers on all aspects of geocomputation and to the distribution of computer programs and test data sets ; an official journal of the International Association for Mathematical Geology},
  publisher = {Elsevier},
  address   = {Amsterdam},
  issn      = {0098-3004},
  doi       = {10.1016/j.cageo.2020.104422},
  pages     = {9},
  year      = {2020},
  abstract  = {Ground-penetrating radar (GPR) is an established geophysical tool to explore a wide range of near-surface environments. Today, the use of synthetic GPR data is largely limited to 2D because 3D modeling is computationally more expensive. In fact, only recent developments of modeling tools and powerful hardware allow for a time-efficient computation of extensive 3D data sets. Thus, 3D subsurface models and resulting GPR data sets, which are of great interest to develop and evaluate novel approaches in data analysis and interpretation, have not been made publicly available up to now. <br /> We use a published hydrofacies data set of an aquifer-analog study within fluvio-glacial deposits to infer a realistic 3D porosity model showing heterogeneities at multiple spatial scales. Assuming fresh-water saturated sediments, we generate synthetic 3D GPR data across this model using novel GPU-acceleration included in the open-source software gprMax. We present a numerical approach to examine 3D wave-propagation effects in modeled GPR data. Using the results of this examination study, we conduct a spatial model decomposition to enable a computationally efficient 3D simulation of a typical GPR reflection data set across the entire model surface. We process the resulting GPR data set using a standard 3D structural imaging sequence and compare the results to selected input data to demonstrate the feasibility and potential of the presented modeling studies. We conclude on conceivable applications of our 3D GPR reflection data set and the underlying porosity model, which are both publicly available and, thus, can support future methodological developments in GPR and other near-surface geophysical techniques.},
  language  = {en}
}
@article{UhligMadaboosiSchmidtetal.2012,
  author    = {Uhlig, Katja and Madaboosi, Narayanan and Schmidt, Stephan and J{\"a}ger, Magnus S. and Rose, J{\"u}rgen and Duschl, Claus and Volodkin, Dmitry V.},
  title     = {3d localization and diffusion of proteins in polyelectrolyte multilayers},
  series = {Soft matter},
  volume    = {8},
  journal   = {Soft matter},
  number    = {47},
  publisher = {Royal Society of Chemistry},
  address   = {Cambridge},
  issn      = {1744-683X},
  doi       = {10.1039/c2sm26500a},
  pages     = {11786 -- 11789},
  year      = {2012},
  abstract  = {The interaction of diverse biomaterials with surfaces is more crucial than ever for biomedical applications to ensure efficiency and reproducibility. Very interesting surface materials are micrometer-thick polyelectrolyte multilayers. Not only their surface but also the bulk can be loaded with biomaterials like proteins or DNA for various purposes. Therefore, we established a method to analyze the lateral and vertical distribution of fluorescently labelled proteins of various size and charge in polyelectrolyte films composed of poly(L-lysine) and hyaluronic acid by confocal laser scanning microscopy. This approach enables us to measure the diffusion coefficients of the proteins via fluorescence recovery after photobleaching as a function of their vertical position in the film and facilitates the understanding of molecular interactions in the film with a high resolution in both space and time. As a result, we confirm that protein loading in the film is driven by electrostatic interactions - uncharged dextran molecules of 10 and 500 kDa do not diffuse into the film. Proteins of different sizes (3-11 nm) can diffuse relatively fast (D = 2-4 mm(2) s(-1)) independent of their net charge, indicating complex interpolymer interactions. This approach is a new powerful experimental tool to design the polyelectrolyte multilayers for bio-applications by finding a relationship between intermolecular interactions and mobility and availability of biomolecules to biological samples (e.g. cells) or detection units (e.g. biosensors).},
  language  = {en}
}
@article{PlatzWeckmannPeketal.2022,
  author    = {Platz, Anna and Weckmann, Ute and Pek, Josef and Kovacikova, Svetlana and Klanica, Radek and Mair, Johannes and Aleid, Basel},
  title     = {3D imaging of the subsurface electrical resistivity structure in West Bohemia/Upper Palatinate covering mofettes and quaternary volcanic structures by using magnetotellurics},
  series = {Tectonophysics : international journal of geotectonics and the geology and physics of the interior of the earth},
  volume    = {833},
  journal   = {Tectonophysics : international journal of geotectonics and the geology and physics of the interior of the earth},
  publisher = {Elsevier},
  address   = {Amsterdam},
  issn      = {0040-1951},
  doi       = {10.1016/j.tecto.2022.229353},
  pages     = {20},
  year      = {2022},
  abstract  = {The region of West Bohemia and Upper Palatinate belongs to the West Bohemian Massif. The study area is situated at the junction of three different Variscan tectonic units and hosts the ENE-WSW trending Ohre Rift as well as many different fault systems. The entire region is characterized by ongoing magmatic processes in the intra-continental lithospheric mantle expressed by a series of phenomena, including e.g. the occurrence of repeated earthquake swarms and massive degassing of mantle derived CO2 in form of mineral springs and mofettes. Ongoing active tectonics is mainly manifested by Cenozoic volcanism represented by different Quaternary volcanic structures. All these phenomena make the Ohre Rift a unique target area for European intra-continental geo-scientific research. With magnetotelluric (MT) measurements we image the subsurface distribution of the electrical resistivity and map possible fluid pathways. Two-dimensional (2D) inversion results by Munoz et al. (2018) reveal a conductive channel in the vicinity of the earthquake swarm region that extends from the lower crust to the surface forming a pathway for fluids into the region of the mofettes. A second conductive channel is present in the south of their model; however, their 2D inversions allow ambiguous interpretations of this feature. Therefore, we conducted a large 3D MT field experiment extending the study area towards the south. The 3D inversion result matches well with the known geology imaging different fluid/magma reservoirs at crust-mantle depth and mapping possible fluid pathways from the reservoirs to the surface feeding known mofettes and spas. A comparison of 3D and 2D inversion results suggests that the 2D inversion results are considerably characterized by 3D and off-profile structures. In this context, the new results advocate for the swarm earthquakes being located in the resistive host rock surrounding the conductive channels; a finding in line with observations e.g. at the San Andreas Fault, California.},
  language  = {en}
}
@article{BrellSeglGuanteretal.2019,
  author    = {Brell, Maximilian and Segl, Karl and Guanter, Luis and Bookhagen, Bodo},
  title     = {3D hyperspectral point cloud generation},
  series = {ISPRS journal of photogrammetry and remote sensing : official publication of the International Society for Photogrammetry and Remote Sensing},
  volume    = {149},
  journal   = {ISPRS journal of photogrammetry and remote sensing : official publication of the International Society for Photogrammetry and Remote Sensing},
  publisher = {Elsevier},
  address   = {Amsterdam},
  issn      = {0924-2716},
  doi       = {10.1016/j.isprsjprs.2019.01.022},
  pages     = {200 -- 214},
  year      = {2019},
  abstract  = {Remote Sensing technologies allow to map biophysical, biochemical, and earth surface parameters of the land surface. Of especial interest for various applications in environmental and urban sciences is the combination of spectral and 3D elevation information. However, those two data streams are provided separately by different instruments, namely airborne laser scanner (ALS) for elevation and a hyperspectral imager (HSI) for high spectral resolution data. The fusion of ALS and HSI data can thus lead to a single data entity consistently featuring rich structural and spectral information. In this study, we present the application of fusing the first pulse return information from ALS data at a sub-decimeter spatial resolution with the lower-spatial resolution hyperspectral information available from the HSI into a hyperspectral point cloud (HSPC). During the processing, a plausible hyperspectral spectrum is assigned to every first-return ALS point. We show that the complementary implementation of spectral and 3D information at the point-cloud scale improves object-based classification and information extraction schemes. This improvements have great potential for numerous land cover mapping and environmental applications.},
  language  = {en}
}
@article{PhamPetreBerquezetal.2009,
  author    = {Pham, Cong Duc and Petre, Anca and Berquez, Laurent and Flores Su{\´a}rez, Rosaura and Mellinger, Axel and Wirges, Werner and Gerhard, Reimund},
  title     = {3D high-resolution mapping of polarization profiles in thin poly(vinylidenefluoride-trifluoroethylene) (PVDF- TrFE) films using two thermal techniques},
  issn      = {1070-9878},
  doi       = {10.1109/TDEI.2009.5128505},
  year      = {2009},
  abstract  = {In this paper, two non-destructive thermal methods are used in order to determine, with a high degree of accuracy, three-dimensional polarization distributions in thin films (12 mu m) of poly(vinylidenefluoride- trifluoroethylene) (PVDF-TrFE). The techniques are the frequency-domain Focused Laser Intensity Modulation Method (FLIMM) and time-domain Thermal-Pulse Tomography (TPT). Samples were first metalized with grid-shaped electrode and poled. 3D polarization mapping yielded profiles which reproduce the electrode-grid shape. The polarization is not uniform across the sample thickness. Significant polarization values are found only at depths beyond 0.5 mu m from the sample surface. Both methods provide similar results, TPT method being faster, whereas the FLIMM technique has a better lateral resolution.},
  language  = {en}
}
@article{SchennenTronickeWetterichetal.2016,
  author    = {Schennen, Stephan and Tronicke, Jens and Wetterich, Sebastian and Allroggen, Niklas and Schwamborn, Georg and Schirrmeister, Lutz},
  title     = {3D ground-penetrating radar imaging of ice complex deposits in northern East Siberia},
  series = {Geophysics},
  volume    = {81},
  journal   = {Geophysics},
  publisher = {Society of Exploration Geophysicists},
  address   = {Tulsa},
  issn      = {0016-8033},
  doi       = {10.1190/GEO2015-0129.1},
  pages     = {WA195 -- WA202},
  year      = {2016},
  abstract  = {Ice complex deposits are characteristic, ice-rich formations in northern East Siberia and represent an important part in the arctic carbon pool. Recently, these late Quaternary deposits are the objective of numerous investigations typically relying on outcrop and borehole data. Many of these studies can benefit from a 3D structural model of the subsurface for upscaling their observations or for constraining estimations of inventories, such as the local carbon stock. We have addressed this problem of structural imaging by 3D ground-penetrating radar (GPR), which, in permafrost studies, has been primarily used for 2D profiling. We have used a 3D kinematic GPR surveying strategy at a field site located in the New Siberian Archipelago on top of an ice complex. After applying a 3D GPR processing sequence, we were able to trace two horizons at depths below 20 m. Taking available borehole and outcrop data into account, we have interpreted these two features as interfaces of major lithologic units and derived a 3D cryostratigraphic model of the subsurface. Our data example demonstrated that a 3D surveying and processing strategy was crucial at our field site and showed the potential of 3D GPR to image geologic structures in complex ice-rich permafrost landscapes.},
  language  = {en}
}
@article{KoyanTronickeAllroggen2021,
  author    = {Koyan, Philipp and Tronicke, Jens and Allroggen, Niklas},
  title     = {3D ground-penetrating radar attributes to generate classified facies models},
  series = {Geophysics},
  volume    = {86},
  journal   = {Geophysics},
  number    = {6},
  publisher = {Society of Exploration Geophysicists},
  address   = {Tulsa},
  issn      = {0016-8033},
  doi       = {10.1190/GEO2021-0204.1},
  pages     = {B335 -- B347},
  year      = {2021},
  abstract  = {Ground-penetrating radar (GPR) is a standard geophysical technique used to image near-surface structures in sedimentary environments. In such environments, GPR data acquisition and processing are increasingly following 3D strategies. However, the processed GPR data volumes are typically still interpreted using selected 2D slices and manual concepts such as GPR facies analyses. In seismic volume interpretation, the application of (semi-)automated and reproducible approaches such as 3D attribute analyses as well as the production of attribute-based facies models are common practices today. In contrast, the field of 3D GPR attribute analyses and corresponding facies models is largely untapped. We have developed and applied a workflow to produce 3D attribute-based GPR facies models comprising the dominant sedimentary reflection patterns in a GPR volume, which images complex sandy structures on the dune island of Spiekeroog (Northern Germany). After presenting our field site and details regarding our data acquisition and processing, we calculate and filter 3D texture attributes to generate a database comprising the dominant texture features of our GPR data. Then, we perform a dimensionality reduction of this database to obtain meta texture attributes, which we analyze and integrate using composite imaging and (also considering additional geometric information) fuzzy c-means cluster analysis resulting in a classified GPR facies model. Considering our facies model and a corresponding GPR facies chart, we interpret our GPR data set in terms of near-surface sedimentary units, the corresponding depositional environments, and the recent formation history at our field site. Thus, we demonstrate the potential of our workflow, which represents a novel and clear strategy to perform a more objective and consistent interpretation of 3D GPR data collected across different sedimentary environments.},
  language  = {en}
}
@article{AllroggenHeinckeKoyanetal.2022,
  author    = {Allroggen, Niklas and Heincke, Bjorn H. and Koyan, Philipp and Wheeler, Walter and Ronning, Jan S.},
  title     = {3D ground-penetrating radar attribute classification},
  series = {Geophysics},
  volume    = {87},
  journal   = {Geophysics},
  number    = {4},
  publisher = {Society of Exploration Geophysicists},
  address   = {Tulsa},
  issn      = {0016-8033},
  doi       = {10.1190/GEO2021-0651.1},
  pages     = {WB19 -- WB30},
  year      = {2022},
  abstract  = {Ground-penetrating radar (GPR) is a method that can provide detailed information about the near subsurface in sedimentary and carbonate environments. The classical interpretation of GPR data (e.g., based on manual feature selection) often is labor-intensive and limited by the experience of the intercally used for seismic interpretation, can provide faster, more repeatable, and less biased interpretations. We have recorded a 3D GPD data set collected across a paleokarst breccia pipe in the Billefjorden area on Spitsbergen, Svalbard. After performing advanced processing, we compare the results of a classical GPR interpretation to the results of an attribute-based classification. Our attribute classification incorporates a selection of dip and textural attributes as the input for a k-means clustering approach. Similar to the results of the classical interpretation, the resulting classes differentiate between undisturbed strata and breccias or fault zones. The classes also reveal details inside the breccia pipe that are not discerned in the classical fer that the intrapipe GPR facies result from subtle differences, such as breccia lithology, clast size, or pore-space filling.},
  language  = {en}
}
@article{IbarraLiuMeessenetal.2019,
  author    = {Ibarra, Federico and Liu, Sibiao and Meeßen, Christian and Prezzi, Claudia Beatriz and Bott, Judith and Scheck-Wenderoth, Magdalena and Sobolev, Stephan Vladimir and Strecker, Manfred},
  title     = {3D data-derived lithospheric structure of the Central Andes and its implications for deformation: Insights from gravity and geodynamic modelling},
  series = {Tectonophysics : international journal of geotectonics and the geology and physics of the interior of the earth},
  volume    = {766},
  journal   = {Tectonophysics : international journal of geotectonics and the geology and physics of the interior of the earth},
  publisher = {Elsevier},
  address   = {Amsterdam},
  issn      = {0040-1951},
  doi       = {10.1016/j.tecto.2019.06.025},
  pages     = {453 -- 468},
  year      = {2019},
  abstract  = {We present a new three-dimensional density model of the Central Andes characterizing the structure and composition of the lithosphere together with a geodynamic simulation subjected to continental intraplate shortening. The principal aim of this study is to assess the link between heterogeneities in the lithosphere and different deformation patterns and styles along the orogen-foreland system of the Central Andes. First, we performed a 3D integration of new geological and geophysical data with previous models through forward modelling of Bouguer anomalies. Subsequently, a geodynamic model was set-up and parametrized from the previously obtained 3D structure and composition. We do not find a unambigous correlation between the resulting density configuration and terrane boundaries proposed by other authors. Our models reproduce the observed Bouguer anomaly and deformation patterns in the foreland. We find that thin-skinned deformation in the Subandean fold-and thrust belt is controlled by a thick sedimentary layer and coeval underthrusting of thin crust of the foreland beneath the thick crust of the Andean Plateau. In the adjacent thick-skinned deformation province of the inverted Cretaceous extensional Santa Barbara System sedimentary strata are much thinner and crustal thickness transitions from greater values in the Andean to a more reduced thickness in the foreland. Our results show that deformation processes occur where the highest gradients of lithospheric strength are present between the orogen and the foreland, thus suggesting a spatial correlation between deformation and lithospheric strength.},
  language  = {en}
}
@article{KaiserCacaceScheckWenderoth2013,
  author    = {Kaiser, Bj{\"o}rn Onno and Cacace, Mauro and Scheck-Wenderoth, Magdalena},
  title     = {3D coupled fluid and heat transport simulations of the Northeast German Basin and their sensitivity to the spatial discretization - different sensitivities for different mechanisms of heat transport},
  series = {Environmental earth sciences},
  volume    = {70},
  journal   = {Environmental earth sciences},
  number    = {8},
  publisher = {Springer},
  address   = {New York},
  issn      = {1866-6280},
  doi       = {10.1007/s12665-013-2249-7},
  pages     = {3643 -- 3659},
  year      = {2013},
  abstract  = {Based on a numerical model of the Northeast German Basin (NEGB), we investigate the sensitivity of the calculated thermal field as resulting from heat conduction, forced and free convection in response to consecutive horizontal and vertical mesh refinements. Our results suggest that computational findings are more sensitive to consecutive horizontal mesh refinements than to changes in the vertical resolution. In addition, the degree of mesh sensitivity depends strongly on the type of the process being investigated, whether heat conduction, forced convection or free thermal convection represents the active heat driver. In this regard, heat conduction exhibits to be relative robust to imposed changes in the spatial discretization. A systematic mesh sensitivity is observed in areas where forced convection promotes an effective role in shorten the background conductive thermal field. In contrast, free thermal convection is to be regarded as the most sensitive heat transport process as demonstrated by non-systematic changes in the temperature field with respect to imposed changes in the model resolution.},
  language  = {en}
}
@article{OstermeyerMenzel1997,
  author    = {Ostermeyer, Martin and Menzel, Ralf},
  title     = {34 Watt flash lamp pumped single rod ND:YAG laser with 1.2 * DL beam quality via special resonator design},
  year      = {1997},
  language  = {en}
}
@article{AtilawHeydenreichNdakalaetal.2014,
  author    = {Atilaw, Yoseph and Heydenreich, Matthias and Ndakala, Albert and Akala, Hoseah M. and Kamau, Edwin and Yenesew, Abiy},
  title     = {3-Oxo-14 alpha, 15 alpha-epoxyschizozygine: A new schizozygane indoline alkaloid from Schizozygia coffaeoides},
  series = {Phytochemistry letters},
  volume    = {10},
  journal   = {Phytochemistry letters},
  publisher = {Elsevier},
  address   = {Amsterdam},
  issn      = {1874-3900},
  doi       = {10.1016/j.phytol.2014.07.003},
  pages     = {28 -- 31},
  year      = {2014},
  abstract  = {The stem bark extract of Schizozygia coffaeoides (Apocynaceae) showed moderate antiplasmodial activity (IC50 = 8-12 mu g/mL) against the chloroquine-sensitive (D6) and chloroquine-resistant (W2) strains of Plasmodium falciparum. Chromatographic separation of the extract led to the isolation of a new schizozygane indoline alkaloid, named 3-oxo-14 alpha, 15 alpha-epoxyschizozygine. In addition, two dimeric anthraquinones, cassiamin A and cassiamin B, were identified for the first time in the family Apocynaceae. The structures of the isolated compounds were deduced on the basis of spectroscopic evidence. The schizozygane indole alkaloids showed good to moderate antiplasmodial activities (IC50 = 13-52 mu m). (C) 2014 Phytochemical Society of Europe. Published by Elsevier B.V. All rights reserved.},
  language  = {en}
}
@article{MutaiHeydenreichThoithietal.2013,
  author    = {Mutai, Peggoty and Heydenreich, Matthias and Thoithi, Grace and Mugumbate, Grace and Chibale, Kelly and Yenesew, Abiy},
  title     = {3-Hydroxyisoflavanones from the stem bark of dalbergia melanoxylon - isolation, antimycobacterial evaluation and molecular docking studies},
  series = {Phytochemistry letters},
  volume    = {6},
  journal   = {Phytochemistry letters},
  number    = {4},
  publisher = {Elsevier},
  address   = {Amsterdam},
  issn      = {1874-3900},
  doi       = {10.1016/j.phytol.2013.08.018},
  pages     = {671 -- 675},
  year      = {2013},
  abstract  = {Two new 3-hydroxyisoflavanones, (S)-3,4',5-trihydroxy-2',7-dimethoxy-3'-prenylisoflavanone (trivial name kenusanone F 7-methyl ether) and (S)-3,5-dihydroxy-2',7-dimethoxy-2 '',2 ''-dimethylpyrano[5 '',6 '':3',4']isoflavanone (trivial name sophoronol-7-methyl ether) along with two known compounds (dalbergin and formononetin) were isolated from the stem bark of Dalbergia melanoxylon. The structures were elucidated using spectroscopic techniques. Kenusanone F 7-methyl ether showed activity against Mycobacterium tuberculosis, whereas both of the new compounds were inactive against the malaria parasite Plasmodium falciparum at 10 mu g/ml. Docking studies showed that the new compounds kenusanone F 7-methyl ether and sophoronol-7-methyl ether have high affinity for the M. tuberculosis drug target INHA.},
  language  = {en}
}
@article{BaesGeryaSobolev2016,
  author    = {Baes, Marzieh and Gerya, Taras V. and Sobolev, Stephan Vladimir},
  title     = {3-D thermo-mechanical modeling of plume-induced subduction initiation},
  series = {Earth \& planetary science letters},
  volume    = {453},
  journal   = {Earth \& planetary science letters},
  publisher = {Elsevier},
  address   = {Amsterdam},
  issn      = {0012-821X},
  doi       = {10.1016/j.epsl.2016.08.023},
  pages     = {193 -- 203},
  year      = {2016},
  abstract  = {Here, we study the 3-D subduction initiation process induced by the interaction between a hot thermochemical mantle plume and oceanic lithosphere using thermo-mechanical viscoplastic finite difference marker-in-cell models. Our numerical modeling results show that self-sustaining subduction is induced by plume-lithosphere interaction when the plume is sufficiently buoyant, the oceanic lithosphere is sufficiently old and the plate is weak enough to allow the buoyant plume to. pass through it. Subduction initiation occurs following penetration of the lithosphere by the hot plume and the downward displacement of broken, nearly circular segments of lithosphere (proto-slabs) as a result of partially molten plume rocks overriding the proto-slabs. Our experiments show four different deformation regimes in response to plume-lithosphere interaction: a) self-sustaining subduction initiation, in which subduction becomes self-sustaining; b) frozen subduction initiation, in which subduction stops at shallow depths; c) slab break-off, in which the subducting circular slab breaks off soon after formation; and d) plume underplating, in which the plume does not pass through the lithosphere and instead spreads beneath it (i.e., failed subduction initiation). These regimes depend on several parameters, such as the size, composition, and temperature of the plume, the brittle/plastic strength and age of the oceanic lithosphere, and the presence/absence of lithospheric heterogeneities. The results show that subduction initiates and becomes self-sustaining when the lithosphere is older than 10 Myr and the non dimensional ratio of the plume buoyancy force and lithospheric strength above the plume is higher than approximately 2. The outcomes of our numerical experiments are applicable for subduction initiation in the modern and Precambrian Earth and for the origin of plume-related corona structures on Venus. (C) 2016 Elsevier B.V. All rights reserved.},
  language  = {en}
}
@article{GomezGarciaMeessenScheckWenderothetal.2019,
  author    = {Gomez-Garcia, Angela Maria and Meeßen, Christian and Scheck-Wenderoth, Magdalena and Monsalve, Gaspar and Bott, Judith and Bernhardt, Anne and Bernal, Gladys},
  title     = {3-D Modeling of Vertical Gravity Gradients and the Delimitation of Tectonic Boundaries: The Caribbean Oceanic Domain as a Case Study},
  series = {Geochemistry, geophysics, geosystems},
  volume    = {20},
  journal   = {Geochemistry, geophysics, geosystems},
  number    = {11},
  publisher = {American Geophysical Union},
  address   = {Washington},
  issn      = {1525-2027},
  doi       = {10.1029/2019GC008340},
  pages     = {5371 -- 5393},
  year      = {2019},
  abstract  = {Geophysical data acquisition in oceanic domains is challenging, implying measurements with low and/or nonhomogeneous spatial resolution. The evolution of satellite gravimetry and altimetry techniques allows testing 3-D density models of the lithosphere, taking advantage of the high spatial resolution and homogeneous coverage of satellites. However, it is not trivial to discretise the source of the gravity field at different depths. Here, we propose a new method for inferring tectonic boundaries at the crustal level. As a novelty, instead of modeling the gravity anomalies and assuming a flat Earth approximation, we model the vertical gravity gradients (VGG) in spherical coordinates, which are especially sensitive to density contrasts in the upper layers of the Earth. To validate the methodology, the complex oceanic domain of the Caribbean region is studied, which includes different crustal domains with a tectonic history since Late Jurassic time. After defining a lithospheric starting model constrained by up-to-date geophysical data sets, we tested several a-priory density distributions and selected the model with the minimum misfits with respect to the VGG calculated from the EIGEN-6C4 data set. Additionally, the density of the crystalline crust was inferred by inverting the VGG field. Our methodology enabled us not only to refine, confirm, and/or propose tectonic boundaries in the study area but also to identify a new anomalous buoyant body, located in the South Lesser Antilles subduction zone, and high-density bodies along the Greater, Lesser, and Leeward Antilles forearcs.},
  language  = {en}
}
@article{GuillemoteauSimonHulinetal.2019,
  author    = {Guillemoteau, Julien and Simon, Francois-Xavier and Hulin, Guillaume and Dousteyssier, Bertrand and Dacko, Marion and Tronicke, Jens},
  title     = {3-D imaging of subsurface magnetic permeability/susceptibility with portable frequency domain electromagnetic sensors for near surface exploration},
  series = {Geophysical journal international},
  volume    = {219},
  journal   = {Geophysical journal international},
  number    = {3},
  publisher = {Oxford Univ. Press},
  address   = {Oxford},
  issn      = {0956-540X},
  doi       = {10.1093/gji/ggz382},
  pages     = {1773 -- 1785},
  year      = {2019},
  abstract  = {The in-phase response collected by portable loop-loop electromagnetic induction (EMI) sensors operating at low and moderate induction numbers (<= 1) is typically used for sensing the magnetic permeability (or susceptibility) of the subsurface. This is due to the fact that the in-phase response contains a small induction fraction and a preponderant induced magnetization fraction. The magnetization fraction follows the magneto-static equations similarly to the magnetic method but with an active magnetic source. The use of an active source offers the possibility to collect data with several loop-loop configurations, which illuminate the subsurface with different sensitivity patterns. Such multiconfiguration soundings thereby allows the imaging of subsurface magnetic permeability/susceptibility variations through an inversion procedure. This method is not affected by the remnant magnetization and theoretically overcomes the classical depth ambiguity generally encountered with passive geomagnetic data. To invert multiconfiguration in-phase data sets, we propose a novel methodology based on a full-grid 3-D multichannel deconvolution (MCD) procedure. This method allows us to invert large data sets (e.g. consisting of more than a hundred thousand of data points) for a dense voxel-based 3-D model of magnetic susceptibility subject to smoothness constraints. In this study, we first present and discuss synthetic examples of our imaging procedure, which aim at simulating realistic conditions. Finally, we demonstrate the applicability of our method to field data collected across an archaeological site in Auvergne (France) to image the foundations of a Gallo-Roman villa built with basalt rock material. Our synthetic and field data examples demonstrate the potential of the proposed inversion procedure offering new and complementary ways to interpret data sets collected with modern EMI instruments.},
  language  = {en}
}
@article{ReiterHeidbach2014,
  author    = {Reiter, Karsten and Heidbach, Oliver},
  title     = {3-D geomechanical-numerical model of the contemporary crustal stress state in the Alberta Basin (Canada)},
  series = {Solid earth},
  volume    = {5},
  journal   = {Solid earth},
  number    = {2},
  publisher = {Copernicus},
  address   = {G{\"o}ttingen},
  issn      = {1869-9510},
  doi       = {10.5194/se-5-1123-2014},
  pages     = {1123 -- 1149},
  year      = {2014},
  abstract  = {In the context of examining the potential usage of safe and sustainable geothermal energy in the Alberta Basin, whether in deep sediments or crystalline rock, the understanding of the in situ stress state is crucial. It is a key challenge to estimate the 3-D stress state at an arbitrarily chosen point in the crust, based on sparsely distributed in situ stress data. To address this challenge, we present a large-scale 3-D geomechanical-numerical model (700 km x 1200 km x 80 km) from a large portion of the Alberta Basin, to provide a 3-D continuous quantification of the contemporary stress orientations and stress magnitudes. To calibrate the model, we use a large database of in situ stress orientation (321 S-Hmax) as well as stress magnitude data (981 S-V, 1720 S-hmin and 2 (+11) S-Hmax) from the Alberta Basin. To find the best-fit model, we vary the material properties and primarily the displacement boundary conditions of the model. This study focusses in detail on the statistical calibration procedure, because of the large amount of available data, the diversity of data types, and the importance of the order of data tests. The best-fit model provides the total 3-D stress tensor for nearly the whole Alberta Basin, and allows estimation of stress orientation and stress magnitudes in advance of any well. First-order implications for the well design and configuration of enhanced geothermal systems are revealed. Systematic deviations of the modelled stress from the in situ data are found for stress orientations in the Peace River and the Bow Island Arch as well as for leak-off test magnitudes.},
  language  = {en}
}
@article{GholamrezaieScheckWenderothBottetal.2019,
  author    = {Gholamrezaie, Ershad and Scheck-Wenderoth, Magdalena and Bott, Judith and Heidbach, Oliver and Strecker, Manfred},
  title     = {3-D crustal density model of the Sea of Marmara},
  series = {Solid Earth},
  volume    = {10},
  journal   = {Solid Earth},
  publisher = {Copernicus Publ.},
  address   = {G{\"o}ttingen},
  issn      = {1869-9510},
  doi       = {10.5194/se-10-785-2019},
  pages     = {785 -- 807},
  year      = {2019},
  abstract  = {Abstract. The Sea of Marmara, in northwestern Turkey, is a transition zone where the dextral North Anatolian Fault zone (NAFZ) propagates westward from the Anatolian Plate to the Aegean Sea Plate. The area is of interest in the context of seismic hazard of Istanbul, a metropolitan area with about 15 million inhabitants. Geophysical observations indicate that the crust is heterogeneous beneath the Marmara basin, but a detailed characterization of the crustal heterogeneities is still missing. To assess if and how crustal heterogeneities are related to the NAFZ segmentation below the Sea of Marmara, we develop new crustal-scale 3-D density models which integrate geological and seismological data and that are additionally constrained by 3-D gravity modeling. For the latter, we use two different gravity datasets including global satellite data and local marine gravity observation. Considering the two different datasets and the general non-uniqueness in potential field modeling, we suggest three possible "end-member" solutions that are all consistent with the observed gravity field and illustrate the spectrum of possible solutions. These models indicate that the observed gravitational anomalies originate from significant density heterogeneities within the crust. Two layers of sediments, one syn-kinematic and one pre-kinematic with respect to the Sea of Marmara formation are underlain by a heterogeneous crystalline crust. A felsic upper crystalline crust (average density of 2720 kgm⁻³) and an intermediate to mafic lower crystalline crust (average density of 2890 kgm⁻³) appear to be cross-cut by two large, dome-shaped mafic highdensity bodies (density of 2890 to 3150 kgm⁻³) of considerable thickness above a rather uniform lithospheric mantle (3300 kgm⁻³). The spatial correlation between two major bends of the main Marmara fault and the location of the highdensity bodies suggests that the distribution of lithological heterogeneities within the crust controls the rheological behavior along the NAFZ and, consequently, maybe influences fault segmentation and thus the seismic hazard assessment in the region.},
  language  = {en}
}
@article{WiederkehrBousquetZiemannetal.2011,
  author    = {Wiederkehr, Michael and Bousquet, Romain and Ziemann, Martin Andreas and Berger, Alfons and Schmid, Stefan M.},
  title     = {3-D assessment of peak-metamorphic conditions by Raman spectroscopy of carbonaceous material an example from the margin of the Lepontine dome (Swiss Central Alps)},
  series = {International journal of earth sciences},
  volume    = {100},
  journal   = {International journal of earth sciences},
  number    = {5},
  publisher = {Springer},
  address   = {New York},
  issn      = {1437-3254},
  doi       = {10.1007/s00531-010-0622-2},
  pages     = {1029 -- 1063},
  year      = {2011},
  abstract  = {This study monitors regional changes in the crystallinity of carbonaceous matter (CM) by applying Micro-Raman spectroscopy to a total of 214 metasediment samples (largely so-called Bundnerschiefer) dominantly metamorphosed under blueschist- to amphibolite-facies conditions. They were collected within the northeastern margin of the Lepontine dome and easterly adjacent areas of the Swiss Central Alps. Three-dimensional mapping of isotemperature contours in map and profile views shows that the isotemperature contours associated with the Miocene Barrow-type Lepontine metamorphic event cut across refolded nappe contacts, both along and across strike within the northeastern margin of the Lepontine dome and adjacent areas. Further to the northeast, the isotemperature contours reflect temperatures reached during the Late Eocene subduction-related blueschist-facies event and/or during subsequent near-isothermal decompression; these contours appear folded by younger, large-scale post-nappe-stacking folds. A substantial jump in the recorded maximum temperatures across the tectonic contact between the frontal Adula nappe complex and surrounding metasediments indicates that this contact accommodated differential tectonic movement of the Adula nappe with respect to the enveloping Bundnerschiefer after maximum temperatures were reached within the northern Adula nappe, i.e. after Late Eocene time.},
  language  = {en}
}
@article{HoehnkeJohnson1995,
  author    = {Hoehnke, Hans-J{\"u}rgen and Johnson, K. W.},
  title     = {3-characters are sufficient for the group determinant},
  year      = {1995},
  language  = {en}
}
@article{Gienow1992,
  author    = {Gienow, Wilfried},
  title     = {2nd English Studies Conference at the Freie Universit{\"a}t Berlin},
  year      = {1992},
  language  = {en}
}
@article{EvansvanLoonHainichetal.2015,
  author    = {Evans, Chris J. and van Loon, Jacco Th. and Hainich, Rainer and Bailey, M.},
  title     = {2dF-AAOmega spectroscopy of massive stars in the Magellanic Clouds The north-eastern region of the Large Magellanic Cloud},
  series = {Astronomy and astrophysics : an international weekly journal},
  volume    = {584},
  journal   = {Astronomy and astrophysics : an international weekly journal},
  publisher = {EDP Sciences},
  address   = {Les Ulis},
  issn      = {1432-0746},
  doi       = {10.1051/0004-6361/201525882},
  pages     = {19},
  year      = {2015},
  abstract  = {We present spectral classifications from optical spectroscopy of 263 massive stars in the north-eastern region of the Large Magellanic Cloud. The observed two-degree field includes the massive 30 Doradus star-forming region, the environs of SN1987A, and a number of star-forming complexes to the south of 30 Dor. These are the first classifications for the majority (203) of the stars and include eleven double-lined spectroscopic binaries. The sample also includes the first examples of early OC-type spectra (AA Omega 30 Dor 248 and 280), distinguished by the weakness of their nitrogen spectra and by C IV lambda 4658 emission. We propose that these stars have relatively unprocessed CNO abundances compared to morphologically normal O-type stars, indicative of an earlier evolutionary phase. From analysis of observations obtained on two consecutive nights, we present radial-velocity estimates for 233 stars, finding one apparent single-lined binary and nine (>3 sigma) outliers compared to the systemic velocity; the latter objects could be runaway stars or large-amplitude binary systems and further spectroscopy is required to investigate their nature.},
  language  = {en}
}
@article{OstermeyerHeuerMenzel1998,
  author    = {Ostermeyer, Martin and Heuer, Axel and Menzel, Ralf},
  title     = {27 Watt average output power with 1.2*DL beam quality from a single rod Nd:YAG-Laser with phase conjugating SBS- mirror},
  year      = {1998},
  language  = {en}
}
@article{SchulzeBettBivouretal.2020,
  author    = {Schulze, Patricia S. C. and Bett, Alexander J. and Bivour, Martin and Caprioglio, Pietro and Gerspacher, Fabian M. and Kabakl{\i}, {\"O}zde Ş. and Richter, Armin and Stolterfoht, Martin and Zhang, Qinxin and Neher, Dieter and Hermle, Martin and Hillebrecht, Harald and Glunz, Stefan W. and Goldschmidt, Jan Christoph},
  title     = {25.1\% high-efficiency monolithic perovskite silicon tandem solar cell with a high bandgap perovskite absorber},
  series = {Solar RRL},
  volume    = {4},
  journal   = {Solar RRL},
  number    = {7},
  publisher = {John Wiley \& Sons, Inc.},
  address   = {New Jersey},
  pages     = {10},
  year      = {2020},
  abstract  = {Monolithic perovskite silicon tandem solar cells can overcome the theoretical efficiency limit of silicon solar cells. This requires an optimum bandgap, high quantum efficiency, and high stability of the perovskite. Herein, a silicon heterojunction bottom cell is combined with a perovskite top cell, with an optimum bandgap of 1.68 eV in planar p-i-n tandem configuration. A methylammonium-free FA(0.75)Cs(0.25)Pb(I0.8Br0.2)(3) perovskite with high Cs content is investigated for improved stability. A 10\% molarity increase to 1.1 m of the perovskite precursor solution results in approximate to 75 nm thicker absorber layers and 0.7 mA cm(-2) higher short-circuit current density. With the optimized absorber, tandem devices reach a high fill factor of 80\% and up to 25.1\% certified efficiency. The unencapsulated tandem device shows an efficiency improvement of 2.3\% (absolute) over 5 months, showing the robustness of the absorber against degradation. Moreover, a photoluminescence quantum yield analysis reveals that with adapted charge transport materials and surface passivation, along with improved antireflection measures, the high bandgap perovskite absorber has the potential for 30\% tandem efficiency in the near future.},
  language  = {en}
}
@article{StreichBeckenRitter2011,
  author    = {Streich, Rita and Becken, Michael and Ritter, Oliver},
  title     = {2.5D controlled-source EM modeling with general 3D source geometries},
  series = {Geophysics},
  volume    = {76},
  journal   = {Geophysics},
  number    = {6},
  publisher = {Society of Exploration Geophysicists},
  address   = {Tulsa},
  issn      = {0016-8033},
  doi       = {10.1190/GEO2011-0111.1},
  pages     = {F387 -- F393},
  year      = {2011},
  abstract  = {Most 2.5D controlled-source electromagnetic (CSEM) modeling algorithms presented to date explicitly consider only sources that are point dipoles oriented parallel or perpendicular to the direction of constant conductivity. This makes simulations of complex source geometries expensive, requiring separate evaluations of many point dipole fields, and thus limits the practical applicability of such schemes for simulating and interpreting field data. We present a novel 2.5D CSEM modeling scheme that overcomes this limitation and permits efficient simulations of sources with general shape and orientation by evaluating fields for the entire source at once. We accommodate general sources by using a secondary field approach, in which primary fields are computed for the general source and a 1D background conductivity model. To carry out the required Fourier transforms between space and wavenumber domain using the same fast cosine and sine transform filters as in conventional algorithms, we split the primary and secondary fields into their symmetric and antisymmetric parts. For complex 3D source geometries, this approach is significantly more efficient than previous 2.5D algorithms. Our finite-difference algorithm also includes novel approaches for divergence correction at low frequencies and EM field interpolation across conductivity discontinuities. We describe the modeling scheme and demonstrate its accuracy and efficiency by comparisons of 2.5D-simulated data with 1D and 3D results.},
  language  = {en}
}
@article{KolocourisKochKleinpeteretal.2015,
  author    = {Kolocouris, Antonios and Koch, Andreas and Kleinpeter, Erich and Stylianakis, Ioannis},
  title     = {2-Substituted and 2,2-disubstituted adamantane derivatives as models for studying substituent chemical shifts and C-H-ax center dot center dot center dot Y-ax cyclohexane contacts-results from experimental and theoretical NMR spectroscopic chemical shifts and DFT structures},
  series = {Tetrahedron},
  volume    = {71},
  journal   = {Tetrahedron},
  number    = {16},
  publisher = {Elsevier},
  address   = {Oxford},
  issn      = {0040-4020},
  doi       = {10.1016/j.tet.2015.01.044},
  pages     = {2463 -- 2481},
  year      = {2015},
  abstract  = {The complete H-1 and C-13 NMR chemical shifts assignment for various 2-substituted and 2,2-disubstituted adamantane derivatives 1-38 in CDCl3 solution was realized on the basis of NMR experiments combined with chemical structure information and DFT-GIAO (B3LYP/6-31+G(d,p)-GIAO) calculations of chemical shifts in solution. Substituent-induced C-13 NMR chemical shifts (SCS) are discussed. C-H-ax center dot center dot center dot Y-ax contacts are a textbook prototype of steric hindrance in organic chemistry. The nature of these contacts will be further investigated in this work on basis of new adamantane derivatives, which are substituted at C-2 to provide models for 1,4-C-H-ax center dot center dot center dot Y-ax and 1,5-C-H-ax center dot center dot center dot Y-ax contacts. The B3LYP/6-31+G(d,p) calculations predicted the presence of NBO hyperconjugative attractive interactions between C-H-ax and Y-ax groups along C-H-ax center dot center dot center dot Y-ax contacts. The H-1 NMR signal separation, Delta delta(gamma-CH2), reflects the strength of the H-bonded C-H-ax center dot center dot center dot Y-ax contact. (C) 2015 Elsevier Ltd. All rights reserved.},
  language  = {en}
}
@article{Schmidt1998,
  author    = {Schmidt, Hans-J{\"u}rgen},
  title     = {2-dimensional representations of 4-dimensional gravitational waves},
  year      = {1998},
  language  = {en}
}
@article{GonzalesDiazKasperRainer1998,
  author    = {Gonz{\´a}les-Diaz, P. F. and Kasper, Uwe and Rainer, Martin},
  title     = {2-Dimensional dilatonic gravity from multidimensional Einstein gravity},
  year      = {1998},
  language  = {en}
}
@article{DzambaskiMarkovicKleinpeteretal.2013,
  author    = {Dzambaski, Zdravko and Markovic, Rade and Kleinpeter, Erich and Baranac-Stojanovic, Marija},
  title     = {2-Alkylidene-4-oxothiazolidine S-oxides - synthesis and stereochemistry},
  series = {Tetrahedron},
  volume    = {69},
  journal   = {Tetrahedron},
  number    = {31},
  publisher = {Elsevier},
  address   = {Oxford},
  issn      = {0040-4020},
  doi       = {10.1016/j.tet.2013.05.087},
  pages     = {6436 -- 6447},
  year      = {2013},
  abstract  = {A series of 5-unsubstituted and 5-substituted 2-alkylidene-4-oxothiazolidine-S-oxides were synthesized by the sulfur-oxidation with m-CPBA. The stereochemistry of 5-substituted sulfoxides was determined by means of NMR spectroscopy and DFT theoretical calculations. It was found that the thermodynamically less stable anti-isomer was initially formed in the course of the oxidation, but it underwent epimerization to the mixture enriched in the more stable syn-isomer, during the work-up process. The higher stability of syn-isomers is ascribed to the stronger hyperconjugative sigma(C-H)->sigma*(S-O) interaction versus the weaker sigma(C-C)->sigma*(S-O) delocalization in their anti-counterparts and to the existence of intramolecular 1,5-CH center dot center dot center dot C hydrogen bonds.},
  language  = {en}
}
@article{StrehmelRexhausenStrauch2010,
  author    = {Strehmel, Veronika and Rexhausen, Hans and Strauch, Peter},
  title     = {2,2,6,6-Tetramethylpiperidine-1-yloxyl bound to the imidazolium ion by an acetamido group for investigation of ionic liquids},
  issn      = {0040-4039},
  doi       = {10.1016/j.tetlet.2009.11.124},
  year      = {2010},
  abstract  = {New spin probes bearing the 2,2,6,6-tetramethylpiperidine-1-yloxyl covalently bound to the imidazolium ion via a methylene spacer and an amide group are synthesized. If the anion is bis(trifluoromethylsulfonylimide) instead of iodide, the new spin probe has a similar structure as that of an ionic liquid. Nevertheless, the new spin probes are useful tools to investigate ionic liquids.},
  language  = {en}
}
@article{SchmidtRiemerKarras2013,
  author    = {Schmidt, Bernd and Riemer, Martin and Karras, Manfred},
  title     = {2,2 '-Biphenols via protecting group-free thermal or microwave-accelerated suzuki-miyaura coupling in water},
  series = {The journal of organic chemistry},
  volume    = {78},
  journal   = {The journal of organic chemistry},
  number    = {17},
  publisher = {American Chemical Society},
  address   = {Washington},
  issn      = {0022-3263},
  doi       = {10.1021/jo401398n},
  pages     = {8680 -- 8688},
  year      = {2013},
  abstract  = {User-friendly protocols for the protecting group-free synthesis of 2,2'-biphenols via Suzuki-Miyaura coupling of o-halophenols and o-boronophenol are presented. The reactions proceed in water in the presence of simple additives such as K2CO3, KOH, KF, or TBAF and with commercially available Pd/C as precatalyst. Expensive or laboriously synthesized ligands or other additives are not required. In the case of bromophenols, efficient rate acceleration and short reaction times were accomplished by microwave irradiation.},
  language  = {en}
}
@article{KammerKellingBaieretal.2009,
  author    = {Kammer, Stefan and Kelling, Alexandra and Baier, Heiko and Mickler, Wulfhard and Dosche, Carsten and Rurack, Knut and Kapp, Andreas and Lisdat, Fred and Holdt, Hans-J{\"u}rgen},
  title     = {2,11-dialkylated 1,12-diazaperylene copper(I) complexes : first supramolecular column assemblies by pi-pi stacking between homoleptic tetrahedral metal complexes, exhibiting low-energy MLCT transitions},
  issn      = {1434-1948},
  doi       = {10.1002/ejic.200900695},
  year      = {2009},
  abstract  = {2,11-Dialkylated 1,12-diazaperylenes (alkyl = Me, Et, iPr) dmedap, detdap and dipdap have been synthesized by reductive cyclization of 3,3-dialkylated 1,1-biisoquinolines 3a-c, resulting in the first copper(I) complexes of a large- surface ligand. The new copper(I) complexes show low-energy MLCT absorptions unprecedented for bis(-diimin)copper(I) complexes. The solid structures of the complexes[Cu(dipdap)2]BF4·CH2Cl2·1.5H2O, [Cu(dipdap)2]OTf·CH2Cl2, [Cu(dipdap)2]I·C2H4Cl2·THF·2H2O, [Cu(dmedap)2]OTf and [Cu(dipdap)2]AQSO3·H2O (AQSO3 = sodium 9,10-dihydro-9,10-dioxo-2- anthracenesulfonate) are reported. In [Cu(dipdap)2]BF4·CH2Cl2·1.5H2O, each copper(I) complex cation interacts with two others by - stacking interactions forming a novel supramolecular column structural motif running along the crystallographic c axis. In the crystalline compound [Cu(dipdap)2]AQSO3·H2O, aggregation between two complex cations and two additional anions by - stacking interactions is observed, leading to a tetrameric assembly. Furthermore, the three complex compounds [Cu(L)2]BF4 (L = dmedap, detdap, dipdap) were tested for sensory applications in aqueous buffer solutions in electrochemical studies of the complex immobilized on glassy carbon electrodes.},
  language  = {en}
}
@article{DzhunushalievSchmidt1999,
  author    = {Dzhunushaliev, Vladimir and Schmidt, Hans-J{\"u}rgen},
  title     = {2+2-decomposable solutions of weyl gravity},
  year      = {1999},
  language  = {en}
}
@article{SchreiberHosemannBeuermann2011,
  author    = {Schreiber, Ulrike and Hosemann, Benjamin and Beuermann, Sabine},
  title     = {1H,1H,2H,2H-Perfluorodecyl-Acrylate-Containing block copolymers from ARGET ATRP},
  series = {Macromolecular chemistry and physics},
  volume    = {212},
  journal   = {Macromolecular chemistry and physics},
  number    = {2},
  publisher = {Wiley-VCH},
  address   = {Weinheim},
  issn      = {1022-1352},
  doi       = {10.1002/macp.201000307},
  pages     = {168 -- 179},
  year      = {2011},
  abstract  = {Block copolymers of 1H,1H,2H,2H-perfluorodecyl acrylate (AC8) were obtained from ARGET ATRP. To obtain block copolymers of low dispersity the PAC8 block was synthesized in anisole with a CuBr(2)/PMDETA catalyst in the presence of tin(II) 2-ethylhexanoate as a reducing agent. The PAC8 block was subsequently used as macroinitiator for copolymerization with butyl and tert-butyl acrylate carried out in scCO(2). To achieve catalyst solubility in CO(2) two fluorinated ligands were employed. The formation of block copolymers was confirmed by size exclusion chromatography and DSC.},
  language  = {en}
}
@article{StarkeKochHoldtetal.1995,
  author    = {Starke, Ines and Koch, Andreas and Holdt, Hans-J{\"u}rgen and Kleinpeter, Erich},
  title     = {1H, 13C, and 15N NMR study of the solution structure of metabridged bis(benzo-15-crown-5-ether)s},
  year      = {1995},
  language  = {en}
}
@article{HilfertSarodnickKempteretal.1998,
  author    = {Hilfert, Liane and Sarodnick, Gerhard and Kempter, Gerhard and Kleinpeter, Erich},
  title     = {1H, 13C and 15 N NMR study and molecular modelling of 2,3- disubstituted quinoxalines with sterically hinderered aromatic and heteroaromatic substituents},
  year      = {1998},
  language  = {en}
}
@article{LehmannKleinpeter1993,
  author    = {Lehmann, J. and Kleinpeter, Erich},
  title     = {1H NMR Lanthanideinduced Shift (LIS) investigations of highly flexible molecules : a new approach ; Part II},
  year      = {1993},
  language  = {en}
}
@article{LehmannKleinpeter1993,
  author    = {Lehmann, J. and Kleinpeter, Erich},
  title     = {1H NMR Lanthanideinduced Shift (LIS) investigations of highly flexible molecules : a new approach},
  year      = {1993},
  language  = {en}
}
@article{LehmannKleinpeter1995,
  author    = {Lehmann, J. and Kleinpeter, Erich},
  title     = {1H NMR lanthanide-induced shift investigations of highly flexible molecules, part III. Applications to alcohols, aldehydes, esters and amines},
  year      = {1995},
  language  = {en}
}
@article{PoleschnerHeydenreich1997,
  author    = {Poleschner, Helmut and Heydenreich, Matthias},
  title     = {1H and 13C NMR Spectra and One-Bond 13C,13C Coupling Constants of 2-Alken-4-yn-1-ols, (E)-2-Alken-4-yn-1-yl Acetates and (E)-2-Alken-4-yn-1-als},
  year      = {1997},
  language  = {en}
}
@article{GuillemoteauSimonLuecketal.2016,
  author    = {Guillemoteau, Julien and Simon, Francois-Xavier and L{\"u}ck, Erika and Tronicke, Jens},
  title     = {1D sequential inversion of portable multi-configuration electromagnetic induction data},
  series = {Near surface geophysics},
  volume    = {14},
  journal   = {Near surface geophysics},
  publisher = {Wiley-VCH},
  address   = {Houten},
  issn      = {1569-4445},
  doi       = {10.3997/1873-0604.2016029},
  pages     = {423 -- 432},
  year      = {2016},
  abstract  = {We present an algorithm that performs sequentially one-dimensional inversion of subsurface magnetic permeability and electrical conductivity by using multi-configuration electromagnetic induction sensor data. The presented method is based on the conversion of the in-phase and out-of-phase data into effective magnetic permeability and electrical conductivity of the equivalent homogeneous half-space. In the case of small-offset systems, such as portable electromagnetic induction sensors, for which in-phase and out-of-phase data are moderately coupled, the effective half-space magnetic permeability and electrical conductivity can be inverted sequentially within an iterative scheme. We test and evaluate the proposed inversion strategy using synthetic and field examples. First, we apply it to synthetic data for some highly magnetic environments. Then, the method is tested on real field data acquired in a basaltic environment to image a formation of archaeological interest. These examples demonstrate that a joint interpretation of in-phase and out-of-phase data leads to a better characterisation of the subsurface in magnetic environments such as volcanic areas.},
  language  = {en}
}