@phdthesis{Boesche2015, author = {B{\"o}sche, Nina Kristine}, title = {Detection of rare earth elements and rare earth oxides with hyperspectral spectroscopy}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-85363}, school = {Universit{\"a}t Potsdam}, pages = {147}, year = {2015}, abstract = {The continuously increasing demand for rare earth elements in technical components of modern technologies, brings the detection of new deposits closer into the focus of global exploration. One promising method to globally map important deposits might be remote sensing, since it has been used for a wide range of mineral mapping in the past. This doctoral thesis investigates the capacity of hyperspectral remote sensing for the detection of rare earth element deposits. The definition and the realization of a fundamental database on the spectral characteristics of rare earth oxides, rare earth metals and rare earth element bearing materials formed the basis of this thesis. To investigate these characteristics in the field, hyperspectral images of four outcrops in Fen Complex, Norway, were collected in the near-field. A new methodology (named REEMAP) was developed to delineate rare earth element enriched zones. The main steps of REEMAP are: 1) multitemporal weighted averaging of multiple images covering the sample area; 2) sharpening the rare earth related signals using a Gaussian high pass deconvolution technique that is calibrated on the standard deviation of a Gaussian-bell shaped curve that represents by the full width of half maxima of the target absorption band; 3) mathematical modeling of the target absorption band and highlighting of rare earth elements. REEMAP was further adapted to different hyperspectral sensors (EO-1 Hyperion and EnMAP) and a new test site (Lofdal, Namibia). Additionally, the hyperspectral signatures of associated minerals were investigated to serve as proxy for the host rocks. Finally, the capacity and limitations of spectroscopic rare earth element detection approaches in general and of the REEMAP approach specifically were investigated and discussed. One result of this doctoral thesis is that eight rare earth oxides show robust absorption bands and, therefore, can be used for hyperspectral detection methods. Additionally, the spectral signatures of iron oxides, iron-bearing sulfates, calcite and kaolinite can be used to detect metasomatic alteration zones and highlight the ore zone. One of the key results of this doctoral work is the developed REEMAP approach, which can be applied from near-field to space. The REEMAP approach enables rare earth element mapping especially for noisy images. Limiting factors are a low signal to noise ratio, a reduced spectral resolution, overlaying materials, atmospheric absorption residuals and non-optimal illumination conditions. Another key result of this doctoral thesis is the finding that the future hyperspectral EnMAP satellite (with its currently published specifications, June 2015) will be theoretically capable to detect absorption bands of erbium, dysprosium, holmium, neodymium and europium, thulium and samarium. This thesis presents a new methodology REEMAP that enables a spatially wide and rapid hyperspectral detection of rare earth elements in order to meet the demand for fast, extensive and efficient rare earth exploration (from near-field to space).}, language = {en} } @phdthesis{Priegnitz2015, author = {Priegnitz, Mike}, title = {Development of geophysical methods to characterize methane hydrate reservoirs on a laboratory scale}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-89321}, school = {Universit{\"a}t Potsdam}, pages = {X, 99}, year = {2015}, abstract = {Gashydrate sind kristalline Feststoffe bestehend aus Wasser und Gasmolek{\"u}len. Sie sind stabil bei erh{\"o}hten Dr{\"u}cken und niedrigen Temperaturen. Nat{\"u}rliche Hydratvorkommen treten daher an Kontinentalh{\"a}ngen, in Permafrostb{\"o}den und in tiefen Seen sowie Binnenmeeren auf. Bei der Hydratbildung orientieren sich die Wassermolek{\"u}le neu und bilden sogenannte K{\"a}figstrukturen, in die Gas eingelagert werden kann. Aufgrund des hohen Drucks bei der Hydratbildung k{\"o}nnen große Mengen an Gas in die Hydratstruktur eingebaut werden. Das Volumenverh{\"a}ltnis von Wasser zu Gas kann dabei bis zu 1:172 bei 0°C und Atmosph{\"a}rendruck betragen. Nat{\"u}rliche Gashydrate enthalten haupts{\"a}chlich Methan. Da Methan sowohl ein Treibhausgas als auch ein Brenngas ist, stellen Gashydrate gleichermaßen eine potentielle Energieressource sowie eine m{\"o}gliche Quelle f{\"u}r Treibhausgase dar. Diese Arbeit untersucht die physikalischen Eigenschaften von Methanhydrat ges{\"a}ttigten Sedimentproben im Labormaßstab. Dazu wurde ein großer Reservoirsimulator (LARS) mit einer eigens entwickelten elektrischen Widerstandstomographie ausger{\"u}stet, die das erste Mal an hydratges{\"a}ttigten Sedimentproben unter kontrollierten Temperatur-, Druck-, und Hydrats{\"a}ttigungsbedingungen im Labormaßstab angewendet wurde. {\"U}blicherweise ist der Porenraum von (marinen) Sedimenten mit elektrisch gut leitendem Salzwasser gef{\"u}llt. Da Hydrate einen elektrischen Isolator darstellen, ergeben sich große Kontraste hinsichtlich der elektrischen Eigenschaften im Porenraum w{\"a}hrend der Hydratbildung und -zersetzung. Durch wiederholte Messungen w{\"a}hrend der Hydraterzeugung ist es m{\"o}glich die r{\"a}umliche Widerstandsverteilung in LARS aufzuzeichnen. Diese Daten bilden in der Folge die Grundlage f{\"u}r eine neue Auswerteroutine, welche die r{\"a}umliche Widerstandsverteilung in die r{\"a}umliche Verteilung der Hydrats{\"a}ttigung {\"u}berf{\"u}hrt. Dadurch ist es m{\"o}glich, die sich {\"a}ndernde Hydrats{\"a}ttigung sowohl r{\"a}umlich als auch zeitlich hoch aufgel{\"o}st w{\"a}hrend der gesamten Hydraterzeugungsphase zu verfolgen. Diese Arbeit zeigt, dass die entwickelte Widerstandstomographie eine gute Datenqualit{\"a}t aufwies und selbst geringe Hydrats{\"a}ttigungen innerhalb der Sedimentprobe detektiert werden konnten. Bei der Umrechnung der Widerstandsverteilung in lokale Hydrat-S{\"a}ttigungswerte wurden die besten Ergebnisse mit dem Archie-var-phi Ansatz erzielt, der die zunehmende Hydratphase dem Sedimentger{\"u}st zuschreibt, was einer Abnahme der Porosit{\"a}t gleichkommt. Die Widerstandsmessungen zeigten weiterhin, dass die schnelle Hydraterzeugung im Labor zur Ausbildung von kleinen Hydratkristallen f{\"u}hrte, die dazu neigten, zu rekristalliesieren. Es wurden weiterhin Hydrat-Abbauversuche durchgef{\"u}hrt, bei denen die Hydratphase {\"u}ber Druckerniedrigung in Anlehnung an den 2007/2008 Mallik Feldtest zersetzt wurde. Dabei konnte beobachtet werden, dass die Muster der Gas- undWasserflussraten im Labor zum Teil gut nachgebildet werden konnten, jedoch auch aufbaubedingte Abweichungen auftraten. In zwei weiteren Langzeitversuchen wurde die Realisierbarkeit und das Verhalten bei CO2-CH4-Hydrat Austauschversuchen in LARS untersucht. Das tomographische Messsystem wurde dabei genutzt um w{\"a}hrend der CH4 Hydrat Aufbauphase die Hydratverteilung innerhalb der Sedimentprobe zu {\"u}berwachen. Im Zuge der anschließenden CO2-Injektion konnte mithilfe der Widerstandstomographie die sich ausbreitende CO2-Front {\"u}berwacht und der Zeitpunkt des CO2 Durchbruchs identifiziert werden.}, language = {en} } @phdthesis{Hanf2015, author = {Hanf, Franziska Stefanie}, title = {South Asian summer monsoon variability: a modelling study with the atmospheric regional climate model HIRHAM5}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-89331}, school = {Universit{\"a}t Potsdam}, pages = {ii, 126}, year = {2015}, abstract = {The lives of more than 1/6 th of the world population is directly affected by the caprices of the South Asian summer monsoon rainfall. India receives around 78 \% of the annual precipitation during the June-September months, the summer monsoon season of South Asia. But, the monsoon circulation is not consistent throughout the entire summer season. Episodes of heavy rainfall (active periods) and low rainfall (break periods) are inherent to the intraseasonal variability of the South Asian summer monsoon. Extended breaks or long-lasting dryness can result in droughts and hence trigger crop failures and in turn famines. Furthermore, India's electricity generation from renewable sources (wind and hydro-power), which is increasingly important in order to satisfy the rapidly rising demand for energy, is highly reliant on the prevailing meteorology. The major drought years 2002 and 2009 for the Indian summer monsoon during the last decades, which are results of the occurrence of multiple extended breaks, emphasise exemplary that the understanding of the monsoon system and its intraseasonal variation is of greatest importance. Although, numerous studies based on observations, reanalysis data and global model simulations have been carried out with the focus on monsoon active and break phases over India, the understanding of the monsoon intraseasonal variability is only in the infancy stage. Regional climate models could benefit the comprehension of monsoon breaks by its resolution advantage. This study investigates moist dynamical processes that initiate and maintain breaks during the South Asian summer monsoon using the atmospheric regional climate model HIRHAM5 at a horizontal resolution of 25 km forced by the ECMWF ERA Interim reanalysis for the period 1979-2012. By calculating moisture and moist static energy budgets the various competing mechanisms leading to extended breaks are quantitatively estimated. Advection of dry air from the deserts of western Asia towards central India is the dominant moist dynamical process in initiating extended break conditions over South Asia. Once initiated, the extended breaks are maintained due to many competing mechanisms: (i) the anomalous easterlies at the southern flank of this anticyclonic anomaly weaken the low-level cross-equatorial jet and thus the moisture transport into the monsoon region, (ii) differential radiative heating over the continental and the oceanic tropical convergence zone induces a local Hadley circulation with anomalous rising over the equatorial Indian Ocean and descent over central India, and (iii) a cyclonic response to positive rainfall anomalies over the near-equatorial Indian Ocean amplifies the anomalous easterlies over India and hence contributes to the low-level divergence over central India. A sensitivity experiment that mimics a scenario of higher atmospheric aerosol concentrations over South Asia addresses a current issue of large uncertainty: the role aerosols play in suppressing monsoon rainfall and hence in triggering breaks. To study the indirect aerosol effects the cloud droplet number concentration was increased to imitate the aerosol's function as cloud condensation nuclei. The sensitivity experiment with altered microphysical cloud properties shows a reduction in the summer monsoon precipitation together with a weakening of the South Asian summer monsoon. Several physical mechanisms are proposed to be responsible for the suppressed monsoon rainfall: (i) according to the first indirect radiative forcing the increase in the number of cloud droplets causes an increase in the cloud reflectivity of solar radiation, leading to a climate cooling over India which in turn reduces the hydrological cycle, (ii) a stabilisation of the troposphere induced by a differential cooling between the surface and the upper troposphere over central India inhibits the growth of deep convective rain clouds, (iii) an increase of the amount of low and mid-level clouds together with a decrease in high-level cloud amount amplify the surface cooling and hence the atmospheric stability, and (iv) dynamical changes of the monsoon manifested as a anomalous anticyclonic circulation over India reduce the moisture transport into the monsoon region. The study suggests that the changes in the total precipitation, which are dominated by changes in the convective precipitation, mainly result from the indirect radiative forcing. Suppression of rainfall due to the direct microphysical effect is found to be negligible over India. Break statistics of the polluted cloud scenario indicate an increase in the occurrence of short breaks (3 days), while the frequency of extended breaks (> 7 days) is clearly not affected. This disproves the hypothesis that more and smaller cloud droplets, caused by a high load of atmospheric aerosols trigger long drought conditions over central India.}, language = {en} } @phdthesis{Nimz2015, author = {Nimz, Katharina}, title = {Sound perception and production in a foreign language}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, isbn = {978-3-86956-361-9}, issn = {2190-4545}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-88794}, school = {Universit{\"a}t Potsdam}, pages = {xix, 236}, year = {2015}, abstract = {The present study addresses the question of how German vowels are perceived and produced by Polish learners of German as a Foreign Language. It comprises three main experiments: a discrimination experiment, a production experiment, and an identification experiment. With the exception of the discrimination task, the experiments further investigated the influence of orthographic marking on the perception and production of German vowel length. It was assumed that explicit markings such as the Dehnungs-h ("lengthening h") could help Polish GFL learners in perceiving and producing German words more correctly. The discrimination experiment with manipulated nonce words showed that Polish GFL learners detect pure length differences in German vowels less accurately than German native speakers, while this was not the case for pure quality differences. The results of the identification experiment contrast with the results of the discrimination task in that Polish GFL learners were better at judging incorrect vowel length than incorrect vowel quality in manipulated real words. However, orthographic marking did not turn out to be the driving factor and it is suggested that metalinguistic awareness can explain the asymmetry between the two perception experiments. The production experiment supported the results of the identification task in that lengthening h did not help Polish learners in producing German vowel length more correctly. Yet, as far as vowel quality productions are concerned, it is argued that orthography does influence L2 sound productions because Polish learners seem to be negatively influenced by their native grapheme-to-phoneme correspondences. It is concluded that it is important to differentiate between the influence of the L1 and L2 orthographic system. On the one hand, the investigation of the influence of orthographic vowel length markers in German suggests that Polish GFL learners do not make use of length information provided by the L2 orthographic system. On the other hand, the vowel quality data suggest that the L1 orthographic system plays a crucial role in the acquisition of a foreign language. It is therefore proposed that orthography influences the acquisition of foreign sounds, but not in the way it was originally assumed.}, language = {en} } @phdthesis{Senft2015, author = {Senft, Christoph}, title = {Contemporary Indian writing in English between global fiction and transmodern historiography}, series = {Internationale Forschungen zur allgemeinen und vergleichenden Literaturwissenschaft ; 190}, journal = {Internationale Forschungen zur allgemeinen und vergleichenden Literaturwissenschaft ; 190}, publisher = {Rodopi}, address = {Leiden}, isbn = {978-90-04-30906-7}, pages = {239}, year = {2015}, abstract = {Christoph Senft provides a set of re-readings of contemporary Indian narrative texts as decolonial and pluralistic approaches to the past and thus offers a comprehensive overview of the subcontinent s literary landscape in the 21st century.}, language = {en} } @phdthesis{Lischke2015, author = {Lischke, Betty}, title = {Food web regulation under different forcing regimes in shallow lakes}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-89149}, school = {Universit{\"a}t Potsdam}, pages = {131}, year = {2015}, abstract = {The standing stock and production of organismal biomass depends strongly on the organisms' biotic environment, which arises from trophic and non-trophic interactions among them. The trophic interactions between the different groups of organisms form the food web of an ecosystem, with the autotrophic and bacterial production at the basis and potentially several levels of consumers on top of the producers. Feeding interactions can regulate communities either by severe grazing pressure or by shortage of resources or prey production, termed top-down and bottom-up control, respectively. The limitations of all communities conglomerate in the food web regulation, which is subject to abiotic and biotic forcing regimes arising from external and internal constraints. This dissertation presents the effects of alterations in two abiotic, external forcing regimes, terrestrial matter input and long-lasting low temperatures in winter. Diverse methodological approaches, a complex ecosystem model study and the analysis of two whole-lake measurements, were performed to investigate effects for the food web regulation and the resulting consequences at the species, community and ecosystem scale. Thus, all types of organisms, autotrophs and heterotrophs, at all trophic levels were investigated to gain a comprehensive overview of the effects of the two mentioned altered forcing regimes. In addition, an extensive evaluation of the trophic interactions and resulting carbon fluxes along the pelagic and benthic food web was performed to display the efficiencies of the trophic energy transfer within the food webs. All studies were conducted in shallow lakes, which is worldwide the most abundant type of lakes. The specific morphology of shallow lakes allows that the benthic production contributes substantially to the whole-lake production. Further, as shallow lakes are often small they are especially sensitive to both, changes in the input of terrestrial organic matter and the atmospheric temperature. Another characteristic of shallow lakes is their appearance in alternative stable states. They are either in a clear-water or turbid state, where macrophytes and phytoplankton dominate, respectively. Both states can stabilize themselves through various mechanisms. These two alternative states and stabilizing mechanisms are integrated in the complex ecosystem model PCLake, which was used to investigate the effects of the enhanced terrestrial particulate organic matter (t-POM) input to lakes. The food web regulation was altered by three distinct pathways: (1) Zoobenthos received more food, increased in biomass which favored benthivorous fish and those reduced the available light due to bioturbation. (2) Zooplankton substituted autochthonous organic matter in their diet by suspended t-POM, thus the autochthonous organic matter remaining in the water reduced its transparency. (3) T-POM suspended into the water and reduced directly the available light. As macrophytes are more light-sensitive than phytoplankton they suffered the most from the lower transparency. Consequently, the resilience of the clear-water state was reduced by enhanced t-POM inputs, which makes the turbid state more likely at a given nutrient concentration. In two subsequent winters long-lasting low temperatures and a concurrent long duration of ice coverage was observed which resulted in low overall adult fish biomasses in the two study lakes - Schulzensee and Gollinsee, characterized by having and not having submerged macrophytes, respectively. Before the partial winterkill of fish Schulzensee allowed for a higher proportion of piscivorous fish than Gollinsee. However, the partial winterkill of fish aligned both communities as piscivorous fish are more sensitive to low oxygen concentrations. Young of the year fish benefitted extremely from the absence of adult fish due to lower predation pressure. Therefore, they could exert a strong top-down control on crustaceans, which restructured the entire zooplankton community leading to low crustacean biomasses and a community composition characterized by copepodites and nauplii. As a result, ciliates were released from top-down control, increased to high biomasses compared to lakes of various trophic states and depths and dominated the zooplankton community. While being very abundant in the study lakes and having the highest weight specific grazing rates among the zooplankton, ciliates exerted potentially a strong top-down control on small phytoplankton and particle-attached bacteria. This resulted in a higher proportion of large phytoplankton compared to other lakes. Additionally, the phytoplankton community was evenly distributed presumably due to the numerous fast growing and highly specific ciliate grazers. Although, the pelagic food web was completely restructured after the subsequent partial winterkills of fish, both lakes were resistant to effects of this forcing regime at the ecosystem scale. The consistently high predation pressure on phytoplankton prevented that Schulzensee switched from the clear-water to the turbid state. Further mechanisms, which potentially stabilized the clear-water state, were allelopathic effects by macrophytes and nutrient limitation in summer. The pelagic autotrophic and bacterial production was an order of magnitude more efficient transferred to animal consumers than the respective benthic production, despite the alterations of the food web structure after the partial winterkill of fish. Thus, the compiled mass-balanced whole-lake food webs suggested that the benthic bacterial and autotrophic production, which exceeded those of the pelagic habitat, was not used by animal consumers. This holds even true if the food quality, additional consumers such as ciliates, benthic protozoa and meiobenthos, the pelagic-benthic link and the potential oxygen limitation of macrobenthos were considered. Therefore, low benthic efficiencies suggest that lakes are primarily pelagic systems at least at the animal consumer level. Overall, this dissertation gives insights into the regulation of organism groups in the pelagic and benthic habitat at each trophic level under two different forcing regimes and displays the efficiency of the carbon transfer in both habitats. The results underline that the alterations of external forcing regimes affect all hierarchical level including the ecosystem.}, language = {en} } @phdthesis{Liput2015, author = {Liput, Magdalena}, title = {Investigation of the biogenesis and use of ribosomes in Arabidopsis thaliana}, school = {Universit{\"a}t Potsdam}, pages = {158}, year = {2015}, language = {en} } @phdthesis{Wang2015, author = {Wang, Rong}, title = {Late quaternary climate and environmental variability inferred from terrigenous sediment records in China and the North Pacific/Bering Sea}, school = {Universit{\"a}t Potsdam}, pages = {91}, year = {2015}, language = {en} } @phdthesis{Cattania2015, author = {Cattania, Camilla}, title = {Improvement of aftershock models based on Coulomb stress changes and rate-and-state dependent friction}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-87097}, school = {Universit{\"a}t Potsdam}, pages = {xvi, 123}, year = {2015}, abstract = {Earthquake clustering has proven the most useful tool to forecast changes in seismicity rates in the short and medium term (hours to months), and efforts are currently being made to extend the scope of such models to operational earthquake forecasting. The overarching goal of the research presented in this thesis is to improve physics-based earthquake forecasts, with a focus on aftershock sequences. Physical models of triggered seismicity are based on the redistribution of stresses in the crust, coupled with the rate-and-state constitutive law proposed by Dieterich to calculate changes in seismicity rate. This type of models are known as Coulomb- rate and-state (CRS) models. In spite of the success of the Coulomb hypothesis, CRS models typically performed poorly in comparison to statistical ones, and they have been underepresented in the operational forecasting context. In this thesis, I address some of these issues, and in particular these questions: (1) How can we realistically model the uncertainties and heterogeneity of the mainshock stress field? (2) What is the effect of time dependent stresses in the postseismic phase on seismicity? I focus on two case studies from different tectonic settings: the Mw 9.0 Tohoku megathrust and the Mw 6.0 Parkfield strike slip earthquake. I study aleatoric uncertainties using a Monte Carlo method. I find that the existence of multiple receiver faults is the most important source of intrinsic stress heterogeneity, and CRS models perform better when this variability is taken into account. Epistemic uncertainties inherited from the slip models also have a significant impact on the forecast, and I find that an ensemble model based on several slip distributions outperforms most individual models. I address the role of postseismic stresses due to aseismic slip on the mainshock fault (afterslip) and to the redistribution of stresses by previous aftershocks (secondary triggering). I find that modeling secondary triggering improves model performance. The effect of afterslip is less clear, and difficult to assess for near-fault aftershocks due to the large uncertainties of the afterslip models. Off-fault events, on the other hand, are less sensitive to the details of the slip distribution: I find that following the Tohoku earthquake, afterslip promotes seismicity in the Fukushima region. To evaluate the performance of the improved CRS models in a pseudo-operational context, I submitted them for independent testing to a collaborative experiment carried out by CSEP for the 2010-2012 Canterbury sequence. Preliminary results indicate that physical models generally perform well compared to statistical ones, suggesting that CRS models may have a role to play in the future of operational forecasting. To facilitate efforts in this direction, and to enable future studies of earthquake triggering by time dependent processes, I have made the code open source. In the final part of this thesis I summarize the capabilities of the program and outline technical aspects regarding performance and parallelization strategies.}, language = {en} } @phdthesis{Jehannin2015, author = {Jehannin, Marie}, title = {About the role of physico-chemical properties and hydrodynamics on the progress of a precipitation reaction}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-88364}, school = {Universit{\"a}t Potsdam}, pages = {xii, 130}, year = {2015}, abstract = {The size and morphology control of precipitated solid particles is a major economic issue for numerous industries. For instance, it is interesting for the nuclear industry, concerning the recovery of radioactive species from used nuclear fuel. The precipitates features, which are a key parameter from the post-precipitate processing, depend on the process local mixing conditions. So far, the relationship between precipitation features and hydrodynamic conditions have not been investigated. In this study, a new experimental configuration consisting of coalescing drops is set to investigate the link between reactive crystallization and hydrodynamics. Two configurations of aqueous drops are examined. The first one corresponds to high contact angle drops (>90°) in oil, as a model system for flowing drops, the second one correspond to sessile drops in air with low contact angle (<25°). In both cases, one reactive is dissolved in each drop, namely oxalic acid and cerium nitrate. When both drops get into contact, they may coalesce; the dissolved species mix and react to produce insoluble cerium oxalate. The precipitates features and effect on hydrodynamics are investigated depending on the solvent. In the case of sessile drops in air, the surface tension difference between the drops generates a gradient which induces a Marangoni flow from the low surface tension drop over the high surface tension drop. By setting the surface tension difference between the two drops and thus the Marangoni flow, the hydrodynamics conditions during the drop coalescence could be modified. Diols/water mixtures are used as solvent, in order to fix the surface tension difference between the liquids of both drops regardless from the reactant concentration. More precisely, the used diols, 1,2-propanediol and 1,3-propanediol, are isomer with identical density and close viscosity. By keeping the water volume fraction constant and playing with the 1,2-propanediol and 1,3-propanediol volume fractions of the solvents, the mixtures surface tensions differ up to 10 mN/m for identical/constant reactant concentration, density and viscosity. 3 precipitation behaviors were identified for the coalescence of water/diols/recatants drops depending on the oxalic excess. The corresponding precipitates patterns are visualized by optical microscopy and the precipitates are characterized by confocal microscopy SEM, XRD and SAXS measurements. In the intermediate oxalic excess regime, formation of periodic patterns can be observed. These patterns consist in alternating cerium oxalate precipitates with distinct morphologies, namely needles and "microflowers". Such periodic fringes can be explained by a feedback mechanism between convection, reaction and the diffusion.}, language = {en} } @phdthesis{Bora2015, author = {Bora, Sanjay Singh}, title = {Regionally adaptable ground-motion Prediction Equations (GMPEs) for seismic hazard analysis}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-88806}, school = {Universit{\"a}t Potsdam}, pages = {xiv, 138}, year = {2015}, abstract = {Adjustment of empirically derived ground motion prediction equations (GMPEs), from a data- rich region/site where they have been derived to a data-poor region/site, is one of the major challenges associated with the current practice of seismic hazard analysis. Due to the fre- quent use in engineering design practices the GMPEs are often derived for response spectral ordinates (e.g., spectral acceleration) of a single degree of freedom (SDOF) oscillator. The functional forms of such GMPEs are based upon the concepts borrowed from the Fourier spectral representation of ground motion. This assumption regarding the validity of Fourier spectral concepts in the response spectral domain can lead to consequences which cannot be explained physically. In this thesis, firstly results from an investigation that explores the relationship between Fourier and response spectra, and implications of this relationship on the adjustment issues of GMPEs, are presented. The relationship between the Fourier and response spectra is explored by using random vibration theory (RVT), a framework that has been extensively used in earthquake engineering, for instance within the stochastic simulation framework and in the site response analysis. For a 5\% damped SDOF oscillator the RVT perspective of response spectra reveals that no one-to-one correspondence exists between Fourier and response spectral ordinates except in a limited range (i.e., below the peak of the response spectra) of oscillator frequencies. The high oscillator frequency response spectral ordinates are dominated by the contributions from the Fourier spectral ordinates that correspond to the frequencies well below a selected oscillator frequency. The peak ground acceleration (PGA) is found to be related with the integral over the entire Fourier spectrum of ground motion which is in contrast to the popularly held perception that PGA is a high-frequency phenomenon of ground motion. This thesis presents a new perspective for developing a response spectral GMPE that takes the relationship between Fourier and response spectra into account. Essentially, this frame- work involves a two-step method for deriving a response spectral GMPE: in the first step two empirical models for the FAS and for a predetermined estimate of duration of ground motion are derived, in the next step, predictions from the two models are combined within the same RVT framework to obtain the response spectral ordinates. In addition to that, a stochastic model based scheme for extrapolating the individual acceleration spectra beyond the useable frequency limits is also presented. To that end, recorded acceleration traces were inverted to obtain the stochastic model parameters that allow making consistent extrapola- tion in individual (acceleration) Fourier spectra. Moreover an empirical model, for a dura- tion measure that is consistent within the RVT framework, is derived. As a next step, an oscillator-frequency-dependent empirical duration model is derived that allows obtaining the most reliable estimates of response spectral ordinates. The framework of deriving the response spectral GMPE presented herein becomes a self-adjusting model with the inclusion of stress parameter (∆σ) and kappa (κ0) as the predictor variables in the two empirical models. The entire analysis of developing the response spectral GMPE is performed on recently compiled RESORCE-2012 database that contains recordings made from Europe, the Mediterranean and the Middle East. The presented GMPE for response spectral ordinates should be considered valid in the magnitude range of 4 ≤ MW ≤ 7.6 at distances ≤ 200 km.}, language = {en} } @phdthesis{Wallenta2015, author = {Wallenta, Daniel}, title = {Sequences of compact curvature}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-87489}, school = {Universit{\"a}t Potsdam}, pages = {viii, 73}, year = {2015}, abstract = {By perturbing the differential of a (cochain-)complex by "small" operators, one obtains what is referred to as quasicomplexes, i.e. a sequence whose curvature is not equal to zero in general. In this situation the cohomology is no longer defined. Note that it depends on the structure of the underlying spaces whether or not an operator is "small." This leads to a magical mix of perturbation and regularisation theory. In the general setting of Hilbert spaces compact operators are "small." In order to develop this theory, many elements of diverse mathematical disciplines, such as functional analysis, differential geometry, partial differential equation, homological algebra and topology have to be combined. All essential basics are summarised in the first chapter of this thesis. This contains classical elements of index theory, such as Fredholm operators, elliptic pseudodifferential operators and characteristic classes. Moreover we study the de Rham complex and introduce Sobolev spaces of arbitrary order as well as the concept of operator ideals. In the second chapter, the abstract theory of (Fredholm) quasicomplexes of Hilbert spaces will be developed. From the very beginning we will consider quasicomplexes with curvature in an ideal class. We introduce the Euler characteristic, the cone of a quasiendomorphism and the Lefschetz number. In particular, we generalise Euler's identity, which will allow us to develop the Lefschetz theory on nonseparable Hilbert spaces. Finally, in the third chapter the abstract theory will be applied to elliptic quasicomplexes with pseudodifferential operators of arbitrary order. We will show that the Atiyah-Singer index formula holds true for those objects and, as an example, we will compute the Euler characteristic of the connection quasicomplex. In addition to this we introduce geometric quasiendomorphisms and prove a generalisation of the Lefschetz fixed point theorem of Atiyah and Bott.}, language = {en} } @phdthesis{Hogenacker2015, author = {Hogenacker, Jens}, title = {Essays on the transition from unemployment to employment with a special emphasis on start-up subsidies in Germany}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-87464}, school = {Universit{\"a}t Potsdam}, pages = {xvi, 272}, year = {2015}, abstract = {The promotion of self-employment as part of active labor market policies is considered to be one of the most important unemployment support schemes in Germany. Against this background the main part of this thesis contributes to the evaluation of start-up support schemes within ALMP. Chapter 2 and 4 focus on the evaluation of the New Start-up Subsidy (NSUS, Gr{\"u}ndungszuschuss) in its first version (from 2006 to the end of 2011). The chapters offer an advancement of the evaluation of start-up subsidies in Germany, and are based on a novel data set of administrative data from the Federal Employment Agency that was enriched with information from a telephone survey. Chapter 2 provides a thorough descriptive analysis of the NSUS that consists of two parts. First, the participant structure of the program is compared with the one of two former programs. In a second step, the study conducts an in-depth characterization of the participants of the NSUS focusing on founding motives, the level of start-up capital and equity used as well as the sectoral distribution of the new business. Furthermore, the business survival, income situation of founders and job creation by the new businesses is analyzed during a period of 19 months after start-up. The contribution of Chapter 4 is to introduce a new explorative data set that allows comparing subsidized start-ups out of unemployment with non-subsidized business start-ups that were founded by individuals who were not unemployed at the time of start-up. Because previous evaluation studies commonly used eligible non-participants amongst the unemployed as control group to assess the labor market effects of the start-up subsidies, the corresponding results hence referred to the effectiveness of the ALMP measure, but could not address the question whether the subsidy leads to similarly successful and innovative businesses compared to non-subsidized businesses. An assessment of this economic/growth aspect is also important, since the subsidy might induce negative effects that may outweigh the positive effects from an ALMP perspective. The main results of Chapter 4 indicate that subsidized founders seem to have no shortages in terms of formal education, but exhibit less employment and industry-specific experience, and are less likely to benefit from intergenerational transmission of start-ups. Moreover, the study finds evidence that necessity start-ups are over-represented among subsidized business founders, which suggests disadvantages in terms of business preparation due to possible time restrictions right before start-up. Finally, the study also detects more capital constraints among the unemployed, both in terms of the availability of personal equity and access to loans. With respect to potential differences between both groups in terms of business development over time, the results indicate that subsidized start-ups out of unemployment face higher business survival rates 19 months after start-up. However, they lag behind regular business founders in terms of income, business growth, and innovation. The arduous data collection process for start-up activities of non-subsidized founders for Chapter 4 made apparent that Germany is missing a central reporting system for business formations. Additionally, the different start-up reporting systems that do exist exhibit substantial discrepancies in data processing procedures, and therefore also in absolute numbers concerning the overall start-up activity. Chapter 3 is therefore placed in front of Chapter 4 and has the aim to provide a comprehensive review of the most important German start-up reporting systems. The second part of the thesis consists of Chapter 5 which contributes to the literature on determinants of job search behavior of the unemployed individuals by analyzing the effectiveness of internet search with regard to search behavior of unemployed individuals and subsequent job quality. The third and final part of the thesis outlines why the German labor market reacted in a very mild fashion to the Great Recession 2008/09, especially compared to other countries. Chapter 6 describes current economic trends of the labor market in light of general trends in the European Union, and reveals some of the main associated challenges. Thereafter, recent reforms of the main institutional settings of the labor market which influence labor supply are analyzed. Finally, based on the status quo of these institutional settings, the chapter gives a brief overview of strategies to adequately combat the challenges in terms of labor supply and to ensure economic growth in the future.}, language = {en} } @phdthesis{Zajnulina2015, author = {Zajnulina, Marina}, title = {Optical frequency comb generation in optical fibres}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-88776}, school = {Universit{\"a}t Potsdam}, pages = {xii, 103}, year = {2015}, abstract = {Optical frequency combs (OFC) constitute an array of phase-correlated equidistant spectral lines with nearly equal intensities over a broad spectral range. The adaptations of combs generated in mode-locked lasers proved to be highly efficient for the calibration of high-resolution (resolving power > 50000) astronomical spectrographs. The observation of different galaxy structures or the studies of the Milky Way are done using instruments in the low- and medium resolution range. To such instruments belong, for instance, the Multi Unit Spectroscopic Explorer (MUSE) being developed for the Very Large Telescope (VLT) of the European Southern Observatory (ESO) and the 4-metre Multi-Object Spectroscopic Telescope (4MOST) being in development for the ESO VISTA 4.1 m Telescope. The existing adaptations of OFC from mode-locked lasers are not resolvable by these instruments. Within this work, a fibre-based approach for generation of OFC specifically in the low- and medium resolution range is studied numerically. This approach consists of three optical fibres that are fed by two equally intense continuous-wave (CW) lasers. The first fibre is a conventional single-mode fibre, the second one is a suitably pumped amplifying Erbium-doped fibre with anomalous dispersion, and the third one is a low-dispersion highly nonlinear optical fibre. The evolution of a frequency comb in this system is governed by the following processes: as the two initial CW-laser waves with different frequencies propagate through the first fibre, they generate an initial comb via a cascade of four-wave mixing processes. The frequency components of the comb are phase-correlated with the original laser lines and have a frequency spacing that is equal to the initial laser frequency separation (LFS), i.e. the difference in the laser frequencies. In the time domain, a train of pre-compressed pulses with widths of a few pico-seconds arises out of the initial bichromatic deeply-modulated cosine-wave. These pulses undergo strong compression in the subsequent amplifying Erbium-doped fibre: sub-100 fs pulses with broad OFC spectra are formed. In the following low-dispersion highly nonlinear fibre, the OFC experience a further broadening and the intensity of the comb lines are fairly equalised. This approach was mathematically modelled by means of a Generalised Nonlinear Schr{\"o}dinger Equation (GNLS) that contains terms describing the nonlinear optical Kerr effect, the delayed Raman response, the pulse self-steepening, and the linear optical losses as well as the wavelength-dependent Erbium gain profile for the second fibre. The initial condition equation being a deeply-modulated cosine-wave mimics the radiation of the two initial CW lasers. The numerical studies are performed with the help of Matlab scripts that were specifically developed for the integration of the GNLS and the initial condition according to the proposed approach for the OFC generation. The scripts are based on the Fourth-Order Runge-Kutta in the Interaction Picture Method (RK4IP) in combination with the local error method. This work includes the studies and results on the length optimisation of the first and the second fibre depending on different values of the group-velocity dispersion of the first fibre. Such length optimisation studies are necessary because the OFC have the biggest possible broadband and exhibit a low level of noise exactly at the optimum lengths. Further, the optical pulse build-up in the first and the second fibre was studied by means of the numerical technique called Soliton Radiation Beat Analysis (SRBA). It was shown that a common soliton crystal state is formed in the first fibre for low laser input powers. The soliton crystal continuously dissolves into separated optical solitons as the input power increases. The pulse formation in the second fibre is critically dependent on the features of the pulses formed in the first fibre. I showed that, for low input powers, an adiabatic soliton compression delivering low-noise OFC occurs in the second fibre. At high input powers, the pulses in the first fibre have more complicated structures which leads to the pulse break-up in the second fibre with a subsequent degradation of the OFC noise performance. The pulse intensity noise studies that were performed within the framework of this thesis allow making statements about the noise performance of an OFC. They showed that the intensity noise of the whole system decreases with the increasing value of LFS.}, language = {en} } @phdthesis{Otto2015, author = {Otto, Katharina Alexandra}, title = {Mass wasting and the Coriolis effect on asteroid Vesta}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-87390}, school = {Universit{\"a}t Potsdam}, pages = {XVII, 251}, year = {2015}, abstract = {This work investigates the influence of the Coriolis force on mass motion related to the Rheasilvia impact basin on asteroid (4) Vesta's southern hemisphere. The giant basin is 500km in diameter, with a centre which nearly coincides with the rotation axis of Vesta. The Rheasilvia basin partially overlaps an earlier, similarly large impact basin, Veneneia. Mass motion within and in the vicinity of the Rheasilvia basin includes slumping and landslides, which, primarily due to their small linear extents, have not been noticeably affected by the Coriolis force. However, a series of ridges related to the basin exhibit significant curvature, which may record the effect of the Coriolis force on the mass motion which generated them. In this thesis 32 of these curved ridges, in three geologically distinct regions, were examined. The mass motion velocities from which the ridge curvatures may have resulted during the crater modification stage were investigated. Velocity profiles were derived by fitting inertial circles along the curved ridges and considering both the current and past rotation states of Vesta. An iterative, statistical approach was used, whereby the radii of inertial circles were obtained through repeated fitting to triplets of points across the ridges. The most frequently found radius for each central point was then used for velocity derivation at that point. The results of the velocity analysis are strongly supportive of a Coriolis force origin for the curved ridges. Derived velocities (29.6 ± 24.6 m/s) generally agree well with previously published predictions from numerical simulations of mass motion during the impact process. Topographical features such as local slope gradient and mass deposition regions on the curved ridges also independently agree with regions in which the calculated mass motion accelerates or decelerates. Sections of constant acceleration, deceleration and constant velocity are found, showing that mass motion is being governed by varying conditions of topography, regolith structure and friction. Estimates of material properties such as the effective viscosities (1.9-9.0·10⁶ Pa·s) and coefficients of friction (0.02-0.81) are derived from the velocity profile information in these sections. From measured accelerations of mass motions on the crater wall, it is also shown that the crater walls must have been locally steeper at the time of the mass motion. Together with these novel insights into the state and behaviour of material moving during the modification stage of Rheasilvia's formation, this work represents the first time that the Coriolis Effect on mass motions during crater formation has been shown to result in diagnostic features preserved until today.}, language = {en} } @phdthesis{Fuenfgeld2015, author = {F{\"u}nfgeld, Maximilian}, title = {Compartmentation of adenine nucleotide metabolism}, school = {Universit{\"a}t Potsdam}, pages = {113}, year = {2015}, language = {en} } @phdthesis{Sauma2015, author = {Sauma, Natalia Zamora}, title = {Tsunami hazard analysis in Central America with emphasis on uncertainties}, school = {Universit{\"a}t Potsdam}, pages = {184}, year = {2015}, language = {en} } @phdthesis{Kormann2015, author = {Kormann, Christoph Martin}, title = {Regional climate change effects on hydroclimatic conditions in the Alpine region}, school = {Universit{\"a}t Potsdam}, pages = {129}, year = {2015}, language = {en} } @phdthesis{Zaccarella2015, author = {Zaccarella, Emiliano}, title = {Breaking down complexity}, series = {MPI series human cognitive and brain sciences ; 175}, journal = {MPI series human cognitive and brain sciences ; 175}, publisher = {Max-Planck-Institute}, address = {Leipzig}, isbn = {978-3-941504-60-8}, school = {Universit{\"a}t Potsdam}, pages = {217}, year = {2015}, abstract = {The unbounded expressive capacity of human language cannot boil down to an infinite list of sentences stored in a finite brain. Our linguistic knowledge is rather grounded around a rule-based universal syntactic computation—called Merge—which takes categorized units in input (e.g. this and ship), and generates structures by binding words recursively into more complex hierarchies of any length (e.g. this ship; this ship sinks…). Here we present data from different fMRI datasets probing the cortical implementation of this fundamental process. We first pushed complexity down to a three-word level, to explore how Merge creates minimally hierarchical phrases and sentences. We then moved to the most fundamental two-word level, to directly assess the universal invariant nature of Merge, when no additive mechanisms are involved. Our most general finding is that Merge as the basic syntactic operation is primarily performed by confined area, namely BA 44 in the IFG. Activity reduces to its most ventral-anterior portion at the most fundamental level, following fine-grained sub-anatomical parcellation proposed for the region. The deep frontal operculum/anterior-dorsal insula (FOP/adINS), a phylogenetically older and less specialized region, rather appears to support word-accumulation processing in which the categorical information of the word is first accessed based on its lexical status, and then maintained on hold before further processing takes place. The present data confirm the general notion of BA 44 being activated as a function of complex structural hierarchy, but they go beyond this view by proposing that structural sensitivity in BA 44 is already appreciated at the lowest levels of complexity during which minimal phrase-structures are build up, and syntactic Merge is assessed. Further, they call for a redefinition of BA 44 from multimodal area to a macro-region with internal localizable functional profiles}, language = {en} } @phdthesis{Kulikova2015, author = {Kulikova, Galina}, title = {Source parameters of the major historical earthquakes in the Tien-Shan region from the late 19th to the early 20th century}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-88370}, school = {Universit{\"a}t Potsdam}, pages = {xiv, 164}, year = {2015}, abstract = {The Tien-Shan and the neighboring Pamir region are two of the largest mountain belts in the world. Their deformation is dominated by intermontane basins bounded by active thrust and reverse faulting. The Tien-Shan mountain belt is characterized by a very high rate of seismicity along its margins as well as within the Tien-Shan interior. The study area of the here presented thesis, the western part of the Tien-Shan region, is currently seismically active with small and moderate sized earthquakes. However, at the end of the 19th beginning of the 20th century, this region was struck by a remarkable series of large magnitude (M>7) earthquakes, two of them reached magnitude 8. Those large earthquakes occurred prior to the installation of the global digital seismic network and therefore were recorded only by analog seismic instruments. The processing of the analog data brings several difficulties, for example, not always the true parameters of the recording system are known. Another complicated task is the digitization of those records - a very time-consuming and delicate part. Therefore a special set of techniques is developed and modern methods are adapted for the digitized instrumental data analysis. The main goal of the presented thesis is to evaluate the impact of large magnitude M≥7.0 earthquakes, which occurred at the turn of 19th to 20th century in the Tien-Shan region, on the overall regional tectonics. A further objective is to investigate the accuracy of previously estimated source parameters for those earthquakes, which were mainly based on macroseismic observations, and re-estimate them based on the instrumental data. An additional aim of this study is to develop the tools and methods for faster and more productive usage of analog seismic data in modern seismology. In this thesis, the ten strongest and most interesting historical earthquakes in Tien-Shan region are analyzed. The methods and tool for digitizing and processing the analog seismic data are presented. The source parameters of the two major M≥8.0 earthquakes in the Northern Tien-Shan are re-estimated in individual case studies. Those studies are published as peer-reviewed scientific articles in reputed journals. Additionally, the Sarez-Pamir earthquake and its connection with one of the largest landslides in the world, Usoy landslide, is investigated by seismic modeling. These results are also published as a research paper. With the developed techniques, the source parameters of seven more major earthquakes in the region are determined and their impact on the regional tectonics was investigated. The large magnitudes of those earthquakes are confirmed by instrumental data. The focal mechanism of these earthquakes were determined providing evidence for responsible faults or fault systems.}, language = {en} }