@article{deEspinosaMeier2011, author = {de Espinosa, Lucas Montero and Meier, Michael A. R.}, title = {Synthesis of star- and block-copolymers using ADMET head-to-tail selectivity during step-growth polymerization}, series = {Chemical communications}, volume = {47}, journal = {Chemical communications}, number = {6}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {1359-7345}, doi = {10.1039/c0cc04161k}, pages = {1908 -- 1910}, year = {2011}, abstract = {Control over molecular architectures obtained via ADMET polymerization is limited by the step-growth nature of this technique. A new approach to this polycondensation method is described allowing for the synthesis of diblock and star-shaped polymers with molecular weight control by using the selectivity of olefin cross-metathesis between acrylates and terminal olefins.}, language = {en} }