@article{TimmermanKrmicekKrmičkovaetal.2023, author = {Timmerman, Martin Jan and Krmicek, Lukas and Krm{\´i}čkov{\´a}, Simona and Slama, Jiri and Sudo, Masafumi and Sobel, Edward}, title = {Tonian-Ediacaran evolution of the Brunovistulian microcontinent (Czech Republic) deciphered from LA-ICP-MS U-Pb zircon and 40Ar/39Ar muscovite ages}, series = {Precambrian research}, volume = {387}, journal = {Precambrian research}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0301-9268}, doi = {10.1016/j.precamres.2023.106981}, pages = {20}, year = {2023}, abstract = {Granitoids of the Slavkov Domain of the Brunovistulian microcontinent (BVM) in the Czech Republic have Ediacaran U-Pb zircon crystallization ages with the dominant magmatic activity occurring between ca. 597 and 595 Ma. The ages overlap published ages for the adjacent Thaya Domain, showing that both domains formed coevally in the same subduction setting. The data support published models in which the Slavkov Domain formed as arc crust. The main stage of magmatism stopped after ca. 595-590 Ma and was quickly followed by cooling accompanied by intrusion of small volumes of rhyolite dykes at ca. 594 Ma. Slavkov Domain metasedimentary rocks are dominated by Cryogenian-Ediacaran detrital zircon populations and their protoliths were locally derived erosional products of Cryogenian to Ediacaran arc rocks of the Thaya and Slavkov domains. Metasedi-mentary rocks from the NE part of the BVM contain younger, ca. 550 Ma zircons indicating that the BVM grew northeastward by accretion of progressively younger material derived from magmatic rocks with latest Ediacaran crystallization ages. In contrast to the Thaya and Slavkov domains, the Metavolcanic Zone that lies between them formed between ca. 740 and 725 Ma in the late Tonian to early Cryogenian. It predates the main stage magmatic activity in the BVM by 135 to 150 Ma and is probably a relic of older crust that formed during rifting of the Rodinia supercontinent. At ca. 552-551 Ma in the latest Ediacaran, parts of the BVM were exposed at the surface, during which time red, terrestrial siliciclastic sediments (Basal Clastics) were deposited. These largely had (very) proximal sources such as the main stage granitoids of the Thaya and Slavkov domains. Clasts of (meta)sandstones contain much older zircon populations and provide evidence that Neoarchaean and Palaeo-, meso- and early Neoproterozoic crustal rocks were exposed in erosional position nearby.}, language = {en} } @misc{TerbishalievaTimmermanMikolaichuketal.2021, author = {Terbishalieva, Baiansuluu and Timmerman, Martin Jan and Mikolaichuk, Alexander and Altenberger, Uwe and Slama, Jiri and Schleicher, Anja Maria and Sudo, Masafumi and Sobel, Edward and Cichy, Sarah Bettina}, title = {Calc-alkaline volcanic rocks and zircon ages of the late Tonian}, series = {Zweitver{\"o}ffentlichungen der Universit{\"a}t Potsdam : Mathematisch-Naturwissenschaftliche Reihe}, journal = {Zweitver{\"o}ffentlichungen der Universit{\"a}t Potsdam : Mathematisch-Naturwissenschaftliche Reihe}, number = {1}, issn = {1437-3254}, doi = {10.25932/publishup-56958}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-569585}, pages = {25}, year = {2021}, abstract = {The Big Naryn Complex (BNC) in the East Djetim-Too Range of the Kyrgyz Middle Tianshan block is a tectonized, at least 2 km thick sequence of predominantly felsic to intermediate volcanic rocks intruded by porphyric rhyolite sills. It overlies a basement of metamorphic rocks and is overlain by late Neoproterozoic Djetim-Too Formation sediments; these also occur as tectonic intercalations in the BNC. The up to ca. 1100 m thick Lower Member is composed of predominantly rhyolites-to-dacites and minor basalts, while the at least 900 m thick pyroclastic Upper Member is dominated by rhyolitic-to-dacitic ignimbrites. Porphyric rhyolite sills are concentrated at the top of the Lower Member. A Lower Member rhyolite and a sill sample have LA-ICP-MS U-Pb zircon crystallization ages of 726.1 +/- 2.2 Ma and 720.3 +/- 6.5 Ma, respectively, showing that most of the magmatism occurred within a short time span in the late Tonian-early Cryogenian. Inherited zircons in the sill sample have Neoarchean (2.63, 2.64 Ga), Paleo- (2.33-1.81 Ga), Meso- (1.55 Ga), and Neoproterozoic (ca. 815 Ma) ages, and were derived from a heterogeneous Kuilyu Complex basement. A 1751 +/- 7 Ma Ar-40/Ar-39 age for amphibole from metagabbro is the age of cooling subsequent to Paleoproterozoic metamorphism of the Kuilyu Complex. The large amount of pyroclastic rocks, and their major and trace element compositions, the presence of Neoarchean to Neoproterozoic inherited zircons and a depositional basement of metamorphic rocks point to formation of the BNC in a continental magmatic arc setting.}, language = {en} } @article{FranzSudoKhomenko2022, author = {Franz, Gerhard and Sudo, Masafumi and Khomenko, Vladimir}, title = {40Ar/39Ar dating of a hydrothermal pegmatitic buddingtonite-muscovite assemblage from Volyn, Ukraine}, series = {European journal of mineralogy : EJM : an international journal on mineralogy, petrology, geochemistry, and related sciences}, volume = {34}, journal = {European journal of mineralogy : EJM : an international journal on mineralogy, petrology, geochemistry, and related sciences}, number = {1}, publisher = {Copernicus}, address = {G{\"o}ttingen}, issn = {0935-1221}, doi = {10.5194/ejm-34-7-2022}, pages = {7 -- 18}, year = {2022}, abstract = {We determined Ar-40/Ar-39 ages of buddingtonite, occurring together with muscovite, with the laser-ablation method. This is the first attempt to date the NH4-feldspar buddingtonite, which is typical for sedimentary-diagenetic environments of sediments, rich in organic matter, or in hydrothermal environments, associated with volcanic geyser systems. The sample is a hydrothermal breccia, coming from the Paleoproterozoic pegmatite field of the Korosten Plutonic Complex, Volyn, Ukraine. A detailed characterization by optical methods, electron microprobe analyses, backscattered electron imaging, and IR analyses showed that the buddingtonite consists of euhedral-appearing platy crystals of tens of micrometers wide, 100 or more micrometers in length, which consist of fine-grained fibers of <= 1 mu m thickness. The crystals are sector and growth zoned in terms of K-NH4-H3O content. The content of K allows for an age determination with the Ar-40/Ar-39 method, as well as in the accompanying muscovite, intimately intergrown with the buddingtonite. The determinations on muscovite yielded an age of 1491 +/- 9 Ma, interpreted as the hydrothermal event forming the breccia. However, buddingtonite apparent ages yielded a range of 563 +/- 14 Ma down to 383 +/- 12 Ma, which are interpreted as reset ages due to Ar loss of the fibrous buddingtonite crystals during later heating. We conclude that buddingtonite is suited for Ar-40/Ar-39 age determinations as a supplementary method, together with other methods and minerals; however, it requires a detailed mineralogical characterization, and the ages will likely represent minimum ages.}, language = {en} } @article{GhignoneSudoBalestroetal.2021, author = {Ghignone, Stefano and Sudo, Masafumi and Balestro, Gianni and Borghi, Alessandro and Gattiglio, Marco and Ferrero, Silvio and Schijndel, Valby van}, title = {Timing of exhumation of meta-ophiolite units in the Western Alps}, series = {Lithos : an international journal of mineralogy, petrology, and geochemistry}, volume = {404-405}, journal = {Lithos : an international journal of mineralogy, petrology, and geochemistry}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0024-4937}, doi = {10.1016/j.lithos.2021.106443}, pages = {18}, year = {2021}, abstract = {A multidisciplinary approach to the study of collisional orogenic belts can improve our knowledge of their geodynamic evolution and may suggest new tectonic models, especially for (U)HP rocks inside the accretionary wedge. In the Western Alps, wherein nappes of different origin are stacked, having recorded different metamorphic peaks at different stages of the orogenic evolution. This study focuses on the External (EPZ) and Internal (IPZ) ophiolitic units of the Piedmont Zone (Susa Valley, Western Alps), which were deformed throughout four tectonometamorphic phases (D1 to D4), developing different foliations and cleavages (S1 to S4) at different metamorphic conditions. The IPZ and EPZ are separated by a shear zone (i.e. the Susa Shear Zone (SSZ)) during which a related mylonitic foliation (SM) developed. S1 developed at high pressure conditions (Epidote-eclogite vs. Lawsonite-blueschist facies conditions for IPZ and EPZ, respectively), as suggested by the composition of white mica (i.e. phengite), whereas S2 developed at low pressure conditions (Epidote-greenschist facies conditions in both IPZ and EPZ) and is defined by muscovite. White mica defining the SM mylonitic foliation (T1) is mostly defined by phengite, while the T2-related disjunctive cleavage is defined by fine-grained muscovite. The relative chronology inferred from meso-and micro-structural observations suggests that T1 was near-coeval with respect to the D2, while T2 developed during D4. A new set of radiometric ages of the main metamorphic foliations were obtained by in situ Ar/Ar dating on white mica. Different generations of white mica defining S1 and S2 foliations in both the IPZ and EPZ and SM in the SSZ, were dated and two main groups of ages were obtained. In both IPZ and EPZ, S1 foliation developed at-46-41 Ma, while S2 foliation developed at-40-36 Ma and was nearly coeval with the SM mylonitic foliation (-39-36 Ma). Comparison between structural, petrological and geochronological data allows to define time of coupling of the different units and consequently to infer new tectonic implications for the exhumation of meta-ophiolites of the Piedmont Zone within axial sector of the Western Alps.}, language = {en} } @article{RiedlMelnickNjueetal.2022, author = {Riedl, Simon and Melnick, Daniel and Njue, Lucy and Sudo, Masafumi and Strecker, Manfred}, title = {Mid-Pleistocene to recent crustal extension in the inner graben of the Northern Kenya Rift}, series = {Geochemistry, geophysics, geosystems}, volume = {23}, journal = {Geochemistry, geophysics, geosystems}, number = {3}, publisher = {American Geophysical Union}, address = {Washington}, issn = {1525-2027}, doi = {10.1029/2021GC010123}, pages = {25}, year = {2022}, abstract = {Magmatic continental rifts often constitute nascent plate boundaries, yet long-term extension rates and transient rate changes associated with these early stages of continental breakup remain difficult to determine. Here, we derive a time-averaged minimum extension rate for the inner graben of the Northern Kenya Rift (NKR) of the East African Rift System for the last 0.5 m.y. We use the TanDEM-X science digital elevation model to evaluate fault-scarp geometries and determine fault throws across the volcano-tectonic axis of the inner graben of the NKR. Along rift-perpendicular profiles, amounts of cumulative extension are determined, and by integrating four new Ar-40/Ar-39 radiometric dates for the Silali volcano into the existing geochronology of the faulted volcanic units, time-averaged extension rates are calculated. This study reveals that in the inner graben of the NKR, the long-term extension rate based on mid-Pleistocene to recent brittle deformation has minimum values of 1.0-1.6 mm yr(-1), locally with values up to 2.0 mm yr(-1). A comparison with the decadal, geodetically determined extension rate reveals that at least 65\% of the extension must be accommodated within a narrow, 20-km-wide zone of the inner rift. In light of virtually inactive border faults of the NKR, we show that extension is focused in the region of the active volcano-tectonic axis in the inner graben, thus highlighting the maturing of continental rifting in the NKR.}, language = {en} } @article{ZozulyaKullerudRibackietal.2020, author = {Zozulya, Dmitry R. and Kullerud, Kare and Ribacki, Enrico and Altenberger, Uwe and Sudo, Masafumi and Savchenko, Yevgeny E.}, title = {The newly discovered neoproterozoic aillikite occurrence in Vinoren (Southern Norway)}, series = {Minerals}, volume = {10}, journal = {Minerals}, number = {11}, publisher = {MDPI}, address = {Basel}, issn = {2075-163X}, doi = {10.3390/min10111029}, pages = {26}, year = {2020}, abstract = {During the period 750-600 Ma ago, prior to the final break-up of the supercontinent Rodinia, the crust of both the North American Craton and Baltica was intruded by significant amounts of rift-related magmas originating from the mantle. In the Proterozoic crust of Southern Norway, the 580 Ma old Fen carbonatite-ultramafic complex is a representative of this type of rocks. In this paper, we report the occurrence of an ultramafic lamprophyre dyke which possibly is linked to the Fen complex, although Ar-40/Ar-39 data from phenocrystic phlogopite from the dyke gave an age of 686 +/- 9 Ma. The lamprophyre dyke was recently discovered in one of the Kongsberg silver mines at Vinoren, Norway. Whole rock geochemistry, geochronological and mineralogical data from the ultramafic lamprophyre dyke are presented aiming to elucidate its origin and possible geodynamic setting. From the whole-rock composition of the Vinoren dyke, the rock could be recognized as transitional between carbonatite and kimberlite-II (orangeite). From its diagnostic mineralogy, the rock is classified as aillikite. The compositions and xenocrystic nature of several of the major and accessory minerals from the Vinoren aillikite are characteristic for diamondiferous rocks (kimberlites/lamproites/UML): Phlogopite with kinoshitalite-rich rims, chromite-spinel-ulvospinel series, Mg- and Mn-rich ilmenites, rutile and lucasite-(Ce). We suggest that the aillikite melt formed during partial melting of a MARID (mica-amphibole-rutile-ilmenite-diopside)-like source under CO2 fluxing. The pre-rifting geodynamic setting of the Vinoren aillikite before the Rodinia supercontinent breakup suggests a relatively thick SCLM (Subcontinental Lithospheric Mantle) during this stage and might indicate a diamond-bearing source for the parental melt. This is in contrast to the about 100 Ma younger Fen complex, which were derived from a thin SCLM.}, language = {en} } @article{KrmičekTimmermanZiemannetal.2020, author = {Krm{\´i}ček, Luk{\´a}š and Timmerman, Martin Jan and Ziemann, Martin Andreas and Sudo, Masafumi and Ulrych, Jaromir}, title = {40Ar/39Ar step-heating dating of phlogopite and kaersutite megacrysts from the Železn{\´a} hůrka (Eisenb{\"u}hl) Pleistocene scoria cone, Czech Republic}, series = {Geologica Carpathica}, volume = {71}, journal = {Geologica Carpathica}, number = {4}, publisher = {Veda}, address = {Bratislava}, issn = {1335-0552}, doi = {10.31577/GeolCarp.71.4.6}, pages = {382 -- 387}, year = {2020}, abstract = {(40)A/Ar-39 step-heating of mica and amphibole megacrysts from hauyne-bearing olivine melilitite scoria/tephra from the Zelezna hurka yielded a 435 +/- 108 ka isotope correlation age for phlogopite and a more imprecise 1.55 Ma total gas age of the kaersutite megacryst. The amphibole megacrysts may constitute the first, and the younger phlogopite megacrysts the later phase of mafic, hydrous melilitic magma crystallization. It cannot be ruled out that the amphibole megacrysts are petrogenetically unrelated to tephra and phlogopite megacrysts and were derived from mantle xenoliths or disaggregated older, deep crustal pegmatites. This is in line both with the rarity of amphibole at Zelezna hurka and with the observed signs of magmatic resorption at the edges of amphibole crystals.}, language = {en} } @article{ScharfSudoPracejusetal.2020, author = {Scharf, Andreas and Sudo, Masafumi and Pracejus, Bernhard and Mattern, Frank and Callegari, Ivan and Bauer, Wilfried and Scharf, Katharina}, title = {Late Lutetian (Eocene) mafic intrusion into shallow marine platform deposits north of the Oman Mountains (Rusayl Embayment) and its tectonic significance}, series = {Journal of African earth sciences}, volume = {170}, journal = {Journal of African earth sciences}, publisher = {Elsevier}, address = {Oxford}, issn = {1464-343X}, doi = {10.1016/j.jafrearsci.2020.103941}, pages = {15}, year = {2020}, abstract = {A silica undersaturated alkali-olivine basanitic magma intruded the late Paleocene/early Eocene Jafnayn Formation near Muscat. Geochemical analyses indicate that a significant amount of host rock (limestone) was assimilated into the magma. We dated the basanite as 42.7 +/- 1.0 Ma (2 sigma error; late Lutetian), using the whole rock Ar-40/Ar-39 step-wise heating technique. Intrusion occurred in the hanging wall of a major regional extensional shear zone (Frontal Range Fault, FRF) bounding the northern margin of two domes within the Oman Mountains (Jabal Akhdar and Saih Hatat domes). Two shear intervals along the FRF have been documented. The first interval lasted immediately after emplacement of the Semail Ophiolite (latest Cretaceous-early Eocene) while the second and poorly constrained interval was assumed to have occurred during the Oligocene. The proximity of the basanite to the FRF suggests that magma used extensional faults for the upper part of its ascent path. Reactivated Permian rift faults of the Pangaea rift or other preexisting faults may have been used for the lower ascent part. We conclude that the basanite intrusion coincided with the onset of the second deformation interval along the FRF, because (1) the position of the basanite is near a dextral releasing bend, associated with the second shear interval, (2) the overlap of our Ar-40/Ar-39 age with the cooling curves for rocks from the nearby Jabal Akhdar Dome, and (3) the basanite postdates the first FRF deformation episode by > 10 Ma. Thus, the second interval along the FRF had started already during the late Lutetian and probably lasted into the Miocene.}, language = {en} } @article{TerbishalievaTimmermanMikolaichuketal.2021, author = {Terbishalieva, Baiansuluu and Timmerman, Martin Jan and Mikolaichuk, Alexander and Altenberger, Uwe and Slama, Jiri and Schleicher, Anja Maria and Sudo, Masafumi and Sobel, Edward and Cichy, Sarah Bettina}, title = {Calc-alkaline volcanic rocks and zircon ages of the late Tonian}, series = {International journal of earth sciences}, volume = {110}, journal = {International journal of earth sciences}, number = {1}, publisher = {Springer}, address = {New York}, issn = {1437-3254}, doi = {10.1007/s00531-020-01956-z}, pages = {353 -- 375}, year = {2021}, abstract = {The Big Naryn Complex (BNC) in the East Djetim-Too Range of the Kyrgyz Middle Tianshan block is a tectonized, at least 2 km thick sequence of predominantly felsic to intermediate volcanic rocks intruded by porphyric rhyolite sills. It overlies a basement of metamorphic rocks and is overlain by late Neoproterozoic Djetim-Too Formation sediments; these also occur as tectonic intercalations in the BNC. The up to ca. 1100 m thick Lower Member is composed of predominantly rhyolites-to-dacites and minor basalts, while the at least 900 m thick pyroclastic Upper Member is dominated by rhyolitic-to-dacitic ignimbrites. Porphyric rhyolite sills are concentrated at the top of the Lower Member. A Lower Member rhyolite and a sill sample have LA-ICP-MS U-Pb zircon crystallization ages of 726.1 +/- 2.2 Ma and 720.3 +/- 6.5 Ma, respectively, showing that most of the magmatism occurred within a short time span in the late Tonian-early Cryogenian. Inherited zircons in the sill sample have Neoarchean (2.63, 2.64 Ga), Paleo- (2.33-1.81 Ga), Meso- (1.55 Ga), and Neoproterozoic (ca. 815 Ma) ages, and were derived from a heterogeneous Kuilyu Complex basement. A 1751 +/- 7 Ma Ar-40/Ar-39 age for amphibole from metagabbro is the age of cooling subsequent to Paleoproterozoic metamorphism of the Kuilyu Complex. The large amount of pyroclastic rocks, and their major and trace element compositions, the presence of Neoarchean to Neoproterozoic inherited zircons and a depositional basement of metamorphic rocks point to formation of the BNC in a continental magmatic arc setting.}, language = {en} } @article{OwenSmithAshwalSudoetal.2017, author = {Owen-Smith, T. M. and Ashwal, L. D. and Sudo, Masafumi and Trumbull, Robert B.}, title = {Age and Petrogenesis of the Doros Complex, Namibia, and Implications for Early Plume-derived Melts in the Parana-Etendeka LIP}, series = {Journal of petrology}, volume = {58}, journal = {Journal of petrology}, number = {3}, publisher = {Oxford Univ. Press}, address = {Oxford}, issn = {0022-3530}, doi = {10.1093/petrology/egx021}, pages = {423 -- 442}, year = {2017}, abstract = {The early Cretaceous Paran{\´a}-Etendeka Large Igneous Province is attributed to the impact of the Tristan mantle plume on the base of the continental lithosphere and the associated opening of the South Atlantic Ocean during the breakup of West Gondwana. Although the geochemistry of the Paran{\´a} and Etendeka volcanic rocks has been extensively studied, there is still disagreement on the role of the mantle plume in the production of the magma types observed, because some of their primary compositions are obscured by continental crustal contamination. However, there are related plutonic rocks that preserve mantle signatures. The Doros Complex is a shallow-level mafic intrusion within the Etendeka Province of Namibia. New 39Ar/40Ar step-heating ages for Doros gabbros from this study (weighted mean of 130 ± 1 Ma; 2σ error) confirm contemporaneity with the Paran{\´a}-Etendeka magmatic event. The Doros suite yields mean ɛNd values of +5·3 ± 1·0 (1σ; n = 11), initial 87Sr/86Sr = 0·70418 ± 0·00017 (n = 11) and 206Pb/204Pb = 18·11 ± 0·06 (n = 13) at 132 Ma. The clustering of isotopic data and trends in incompatible trace element ratios indicate that all the magmas in the complex were derived from the same mantle source components, during the same melting episode. By quantitative isotopic modelling of mixing processes, we constrain the Doros parental magma to comprise 60-80\% melt of a depleted asthenospheric mantle component and 20-40\% melt of a more enriched, Tristan plume-derived, asthenospheric component. No lithospheric mantle component is required to explain the Doros magma compositions. The chilled margin to the complex is the only rock type that shows evidence of significant continental crustal contamination, by assimilation of the metasedimentary host-rock upon emplacement. The identification of a substantial Tristan plume component in the Doros source confirms the integral role of the deep-seated thermal anomaly in Paran{\´a}-Etendeka magmatism. We show, in addition, that the Doros suite has consistent, strong geochemical affinities with the Tafelkop group 'ferropicrite' lavas of the Etendeka Province. This provides crucial evidence in support of Doros as the eruptive site for the Tafelkop lavas, thereby linking the Doros magmatism to the earliest eruptive phase in the Etendeka event. The distinctive chemistry of this magma group has been attributed to relatively deep decompression melting of pyroxenite-bearing material in the heterogeneous Tristan plume head, related to the initial impact of the plume on the base of the lithosphere.}, language = {en} } @article{IshizukaHickeyVargasArculusetal.2017, author = {Ishizuka, Osamu and Hickey-Vargas, Rosemary and Arculus, Richard J. and Yogodzinski, Gene M. and Savov, Ivan P. and Kusano, Yuki and McCarthy, Anders and Brandl, Philipp A. and Sudo, Masafumi}, title = {Age of Izu-Bonin-Mariana arc basement}, series = {Earth \& planetary science letters}, volume = {481}, journal = {Earth \& planetary science letters}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0012-821X}, doi = {10.1016/j.epsl.2017.10.023}, pages = {80 -- 90}, year = {2017}, abstract = {Documenting the early tectonic and magmatic evolution of the lzu-Bonin-Mariana (IBM) arc system in the Western Pacific is critical for understanding the process and cause of subduction initiation along the current convergent margin between the Pacific and Philippine Sea plates. Forearc igneous sections provide firm evidence for seafloor spreading at the time of subduction initiation (52 Ma) and production of "forearc basalt". Ocean floor drilling (International Ocean Discovery Program Expedition 351) recovered basement-forming, low-Ti tholeiitic basalt crust formed shortly after subduction initiation but distal from the convergent margin (nominally reararc) of the future IBM arc (Amami Sankaku Basin: ASB). Radiometric dating of this basement gives an age range (49.3-46.8 Ma with a weighted average of 48.7 Ma) that overlaps that of basalt in the present-day IBM forearc, but up to 3.3 m.y. younger than the onset of forearc basalt activity. Similarity in age range and geochemical character between the reararc and forearc basalts implies that the ocean crust newly formed by seafloor spreading during subduction initiation extends from fore-to reararc of the present-day IBM arc. Given the age difference between the oldest forearc basalt and the ASB crust, asymmetric spreading caused by ridge migration might have taken place. This scenario for the formation of the ASB implies that the Mesozoic remnant arc terrane of the Daito Ridges comprised the overriding plate at subduction initiation. The juxtaposition of a relatively buoyant remnant arc terrane adjacent to an oceanic plate was more favourable for subduction initiation than would have been the case if both downgoing and overriding plates had been oceanic. (C) 2017 The Authors. Published by Elsevier B.V.}, language = {en} } @article{KaroOberhaensliAqrawietal.2018, author = {Karo, Nihad M. and Oberh{\"a}nsli, Roland and Aqrawi, Ahmed M. and Elias, Elias M. and Aswad, Khalid J. and Sudo, Masafumi}, title = {New Ar-40/Ar-39 age constraints on cooling and unroofing history of the metamorphic host rocks (and igneous intrusion associates) from the Bulfat Complex (Bulfat area), NE-Iraq}, series = {Arabian journal of geosciences}, volume = {11}, journal = {Arabian journal of geosciences}, number = {10}, publisher = {Springer}, address = {Heidelberg}, issn = {1866-7511}, doi = {10.1007/s12517-018-3571-x}, pages = {11}, year = {2018}, abstract = {The Northern Zagros Suture Zone (NZSZ), formed as a result of the collision between Arabian and Sanandaj-Sirjan microplate, is considered as part of the Zagros orogenic belt. NZSZ is marked by two allochthonous thrust sheets in upward stacking order: lower and upper allochthon. The Bulfat complex is a part of the upper allochthon or "Ophiolite-bearing terrane" of Albian-Cenomenion age (97-105 Ma). Voluminous highly sheared serpentinites associated with ophiolites occur within this upper allochthon. In addition, the Gemo-Qandil Group is characterized by gabbroic to dioritic Bulfat intrusion with a crystallization age spanning from similar to 45 to similar to 40 Ma, as well as extensive metapelites with contact to the Walash-Naupurdam metavolcanic rocks. Due to the deformation in the Sanandaj-Sirjan Zone along the eastern side of the Iraqi segment of NZSZ, the Gemo-Qandil Group was regionally metamorphosed during late Cretaceous (similar to 80 Ma). This tectono-compressional dynamics ultimately caused an oscillatory deformation against Arabian continental margin deposits as well. During these events, gabbro-diorite intrusion with high-grade contact metamorphic aureoles occurred near Bulfat. Thus, there is an overlap between regional and contact metamorphic conditions in the area. The earlier metamorphic characteristic can be seen only in places where the latter contact influence was insignificant. Generally, this can only observed at a distance of more than 2.5 km from the contact. According to petrographic details and field observations, the thermally metamorphosed metapelitic units of the metasediment have been completely assimilated, with only some streaks of biotite and relicts of initial foliation. They strongly resemble amphibolite-grade slices from the regional metamorphic rocks in the region. Metapelitic samples far from the intrusion give similar biotite cooling ages as the intrusive rocks. Thus, they may be affected by the same thermal event. Ar-40/Ar-39 dating of biotite in metapelite rocks of Bulfat by step-wise heating with laser gave average weighted isotopic ages of 34.78 +/- 0.06 Ma. This is interpreted as crystallization/recrystallization age of biotite possibly representing the time of cooling and uplift history of the Bulfat intrusion. Cooling and exhumation rates for the Bulfat gabbro-diorite rocks were estimated as similar to 400 A degrees C/Ma and similar to 3.3 mm/year respectively. According to petrographic details, field observations and Ar/Ar dating concerning the contact metamorphism near Bulfat due to the gabbro-diorite intrusion, no significant deformation is visible during exhumation processes after the Paleogene tectono-thermal event, indicating that isotopic ages of 34.78 +/- 0.06 Ma could mark the timing of termination of the island arc activity in the Ophiolite-bearing terrane (upper allochthon).}, language = {en} } @article{HalamaGlodnyKonradSchmolkeetal.2018, author = {Halama, Ralf and Glodny, Johannes and Konrad-Schmolke, Matthias and Sudo, Masafumi}, title = {Rb-Sr and in situ Ar-40/Ar-39 dating of exhumation-related shearing and fluid-induced recrystallization in the Sesia zone (Western Alps, Italy)}, series = {Geosphere}, volume = {14}, journal = {Geosphere}, number = {4}, publisher = {American Institute of Physics}, address = {Boulder}, issn = {1553-040X}, doi = {10.1130/GES01521.1}, pages = {1425 -- 1450}, year = {2018}, abstract = {The Sesia zone in the Italian Western Alps is a piece of continental crust that has been subducted to eclogite-facies conditions and records a complex metamorphic history. The exact timing of events and the significance of geochronological information are debated due to the interplay of tectonic, metamorphic, and metasomatic processes. Here we present new geochronological data using Rb-Sr internal mineral isochrons and in situ Ar-40/Ar-39 laser ablation data to provide constraints on the relative importance of fluid-mediated mineral replacement reactions and diffusion for the interpretation of radiogenic isotope signatures, and on the use of these isotopic systems for dating metamorphic and variably deformed rocks. Our study focuses on the shear zone at the contact between two major lithological units of the Sesia zone, the eclogitic micaschists and the gneiss minuti. Metasedimentary rocks of the eclogitic micaschists unit contain phengite with step-like zoning in major element chemistry as evidence for petrologic disequilibrium. Distinct Ar-40/Ar-39 spot ages of relict phengite cores and over-printed rims demonstrate the preservation of individual age domains in the crystals. The eclogitic micaschists also show systematic Sr isotope disequilibria among different phengite populations, so that minimum ages of relict assemblage crystallization can be differentiated from the timing of late increments of deformation. The preservation of these disequilibrium features shows the lack of diffusive re-equilibration and underpins that fluid-assisted dissolution and recrystallization reactions are the main factors controlling the isotope record in these subduction-related metamorphic rocks. Blueschist-facies mylonites record deformation along the major shear zone that separates the eclogitic micaschists from the gneiss minuti. Two Rb-Sr isochrones that comprise several white mica fractions and glaucophane constrain the timing of this deformation and accompanying near-complete blueschist-facies re-equilibration of the Rb-Sr system to 60.1 +/- 0.9 Ma and 60.9 +/- 2.1 Ma, respectively. Overlapping ages in eclogitic micaschists of 60.1 +/- 1.1 (Rb-Sr isochron of sheared matrix assemblage), 58.6 +/- 0.8, and 60.9 +/- 0.4 Ma (white mica Ar-40/Ar-39 inverse isochron ages) support the significance of this age and show that fluid-rock interaction and partial re-equilibration occurred as much as several kilometers away from the shear zone. An earlier equilibration during high-pressure conditions in the eclogitic mica schists is recorded in minimum Rb-Sr ages for relict assemblages (77.2 +/- 0.8 and 72.4 +/- 1.1 Ma) and an Ar-40/Ar-39 inverse isochron age of 75.4 +/- 0.8 Ma for white mica cores, again demonstrating that the two isotope systems provide mutually supporting geochronological information. Local reactivation and recrystallization along the shear zone lasted >15 m.y., as late increments of deformation are recorded in a greenschist-facies mylonite by a Rb-Sr isochron age of 46.5 +/- 0.7 Ma.}, language = {en} } @article{WillnervanStaalZagorevskietal.2018, author = {Willner, Arne P. and van Staal, Cees R. and Zagorevski, A. and Glodny, Johannes and Romer, Rolf L. and Sudo, Masafumi}, title = {Tectonometamorphic evolution along the Iapetus suture zone in Newfoundland}, series = {Tectonophysics : international journal of geotectonics and the geology and physics of the interior of the earth}, volume = {742}, journal = {Tectonophysics : international journal of geotectonics and the geology and physics of the interior of the earth}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0040-1951}, doi = {10.1016/j.tecto.2018.05.023}, pages = {137 -- 167}, year = {2018}, abstract = {The Red Indian Line (RIL) in central Newfoundland is the suture, where the main tract of the Iapetus Ocean was closed at similar to 452 Ma during accretion of the peri-Gondwanan Victoria arc with the composite active Laurentian margin. The protracted deformation history of this soft collision started at similar to 471 Ma with accretion of oceanic terranes to the active composite Laurentian margin. After Iapetus closure both colliding active margins were progressively deformed and metamorphosed during Silurian and Devonian (Salinic, Acadian and Neoacadian orogenic cycles). Peak conditions of the very low- to medium-grade, heterogeneously distributed metamorphism were determined by pseudosection techniques within the range of 2-7 kbar, 230-450 degrees C during increase of the metamorphic field gradient from similar to 12 degrees C/km to similar to 32 degrees C/km over time. Multiple metamorphic crystallisation stages were dated by white mica Ar-40/Ar-39 spot and plateau ages, additional Rb-Sr mineral isochrons involving white mica and one U/Pb age of titanite. All resulting ages between 439 +/- 4 Ma and 356 +/- 16 Ma postdate the closure of Iapetus. Results differ along two transects: The oldest ages of 443-421 Ma (Salinic orogenic cycle) were observed along the northern transect through the RIL zone with minimal younger overprint. Hence low temperature, intermediate to high pressure conditions (4.0-7.0 kbar, 230-340 degrees C) achieved during Taconic-Salinic underthrusting are well preserved. During Acadian dextral transpression the Taconic-Salinic structural wedge was tilted subvertically. In contrast, rocks along the southern transect through the RIL zone mainly show Acadian ages of 408-390 Ma with local preservation of older ages. Acadian deformation occurred under low temperature/low pressure conditions (similar to 250-450 degrees C, 2.5-4.6 kbar). Also Silurian terrestrial cover rocks were buried under these conditions. Acadian-Neoacadian deformation (393-340 Ma) becomes younger towards the northwest and progressively localized in transcurrent fault zones. This final foreland deformation at shallow crustal level established the Acadian/Neoacadian orogenic front in central Newfoundland slightly northwest of the RIL.}, language = {en} } @article{SokolHalamaMeliksetianetal.2018, author = {Sokol, Krzysztof and Halama, Ralf and Meliksetian, Khachatur and Savov, Ivan P. and Navasardyan, Gevorg and Sudo, Masafumi}, title = {Alkaline magmas in zones of continental convergence}, series = {Lithos : an international journal of mineralogy, petrology, and geochemistry}, volume = {320}, journal = {Lithos : an international journal of mineralogy, petrology, and geochemistry}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0024-4937}, doi = {10.1016/j.lithos.2018.08.028}, pages = {172 -- 191}, year = {2018}, abstract = {Alkaline igneous rocks are relatively rare in settings of tectonic convergence and little is known about their petrogenesis in these settings. This study aims to contribute to a better understanding of the formation of alkaline igneous rocks by an investigation of the Tezhsar volcano-intrusive alkaline ring complex (TAC) in the Armenian Lesser Caucasus, which is located between the converging Eurasian and Arabian plates. We present new petrological, geochemical and Sr Nd isotope data for the TAC to constrain magma genesis and magma source characteristics. Moreover, we provide a new Ar-40/Ar-39 age of 41.0 +/- 0.5 Ma on amphibole from a nepheline syenite that is integrated into the regional context of ongoing regional convergence and widespread magmatism. The TAC is spatially concentric and measures similar to 10 km in diameter representing the relatively shallow plumbing system of a major stratovolcano juxtaposed by ring faulting with its extrusive products. The plutonic units comprise syenites and nepheline syenites, whereas the extrusive units are dominated by trachytic-phonolitic rocks. The characteristic feature of the TAC is the development of pseudomorphs after leucite in all types of the volcanic, subvolcanic and intrusive alkaline rocks. Whole-rock major element data show a metaluminous (Alkalinity Index = 0-0.1), alkalic and silica-undersaturated (Feldspathoid Silica-Saturation Index <0) character of the TAC. The general trace element enrichment and strong fractionation of REEs (La-N/Yb-N up to 70) indicate a relatively enriched magma source and small degrees of partial melting. All TAC rocks show a negative Nb Ta anomalies typical of subduction zone settings. The initial 87Sr/85Sr ratios (0.704-0.705) and positive sNd values (+3 to +5) indicate an isotopically depleted upper mantle and lack of significant crustal influence, which in turn suggests the TAC magma has formed via differentiation from lithospheric mantle melts.}, language = {en} } @misc{BobosGoncalvesLimaetal.2019, author = {Bobos, Iuliu and Goncalves, Ana and Lima, Luis and Noronha, Fernando and Sudo, Masafumi}, title = {Micas Ar-40/Ar-39 dating of hydrothermal events related with the post-orogenic W (+/- Sn), (Cu, Mo) mineralization from Borralha, Northern Portugal}, series = {Life with Ore Deposits on Earth - 15th SGA Biennial Meeting 2019,}, journal = {Life with Ore Deposits on Earth - 15th SGA Biennial Meeting 2019,}, number = {1}, publisher = {SGA Soc Geology Applied mineral depositis}, address = {Geneva}, pages = {353 -- 356}, year = {2019}, abstract = {Secondary mica minerals collected from the Santa Helena (W- (Cu) mineralization) and Venise (W-Mo mineralization) endogenic breccia structures were Ar-40/Ar-39 dated. The muscovite Ar-40/Ar-39 data yielded 286.8 +/- 1.2 (+/- 1 sigma) Ma (samples 6Ha and 11Ha) which reflect the age of secondary muscovite formation probably from magmatic biotite or feldspar alteration. Sericite Ar-40/Ar-39 data yielded 280.9 +/- 1.2 (+/- 1 sigma) Ma to 279.0 +/- 1.1 (+/- 1 sigma) Ma (samples 6Hb and 11Hb) reflecting the age of greisen alteration (T similar to 300 degrees C) where the W- disseminated mineralization occurs. The muscovite 40Ar/39Ar data of 277.3 +/- 1.3 (+/- 1 sigma) Ma and 281.3 +/- 1.2 (+/- 1 sigma) Ma (samples 5 and 6) also reflect the age of muscovite (selvage) crystallized adjacent to molybdenite veins within the Venise breccia. Geochronological data obtained confirmed that the W mineralization at Santa Helena breccia is older than Mo-mineralization at Venise breccia. Also, the timing of hydrothermal circulation and the cooling history for the W-stage deposition was no longer than 7 Ma and 4 Ma for Mo-deposition.}, language = {en} } @article{TrumbullSudoHarrisetal.2019, author = {Trumbull, Robert B. and Sudo, Masafumi and Harris, C. and Armstrong, R. A. and de Beer, C. H.}, title = {The age of the Koegel Fontein anorogenic complex, South Africa, and its relationship to the regional timing of magmatism and breakup along the South Atlantic rifted margin}, series = {South African Journal of Geology}, volume = {122}, journal = {South African Journal of Geology}, number = {1}, publisher = {Geological Society of South Africa}, address = {Marshalltown}, issn = {1012-0750}, doi = {10.25131/sajg.122.0007}, pages = {69 -- 78}, year = {2019}, abstract = {The early Cretaceous Koegel Fontein intrusive complex is situated near the Atlantic coast in South Africa, about 350 km northwest of Cape Town. The complex comprises felsic units of granite and syenite with compositionally related dykes, and a single intrusive plug of diorite. Existing zircon U-Pb ages of 144 +/- 2 Ma for the syenite and 133.9 +/- 1.3 Ma for the granite suggest that the emplacement of the complex took place over a period of about 10 My. This study provides additional and independent ages of the Koegel Fontein complex by Ar-40/Ar-39 dating to confirm the onset and duration of magmatism and better define the sequence of igneous units that comprise it. New laser step-heating Ar-40/Ar-3(9) ages on plagioclase and biotite from the main intrusive units in the complex are presented here, including samples previously dated by U-Pb dating. The Ar-40/Ar-39 ages for the granite and syenite units (131.1 +/- 0.9 Ma and 143.3 +/- 0.9, respectively) are in good agreement with the zircon U-Pb ages. Other units not previously dated include the Rooivleitjie alkaline granite (150.7 +/- 0.6 Ma), two quartz-porphyry dykes (143.0 +/- 0.9 and 139.4 +/- 1.7 Ma) and the Zout Rivier diorite plug (133.0 +/- 1.0 Ma). The new results confirm an early onset of magmatism at Koegel Fontein relative to that of the Etendeka Province some 1000 km to the north, which is consistent with the regional south-to-north propagation of South Atlantic rifting. The youngest Ar-40/Ar-3(9) ages at Koegel Fontein (134 to 131 Ma, Rietpoort Granite and 133 Ma, Zout Rivier diorite) correspond to the age of the first magnetic seafloor-spreading anomaly offshore, and we suggest that the longevity of Koegel Fontein magmatism relates to a superposition of pre-drift magmatism onshore and spreading-related magmatism as continental separation began.}, language = {en} } @article{FaireyTimmermanSudoetal.2019, author = {Fairey, Brenton J. and Timmerman, Martin Jan and Sudo, Masafumi and Tsikos, Harilaos}, title = {The role of hydrothermal activity in the formation of Karst-hosted manganese deposits of the Postmasburg Mn Field, Northern Cape Province, South Africa}, series = {Minerals}, volume = {9}, journal = {Minerals}, number = {7}, publisher = {MDPI}, address = {Basel}, issn = {2075-163X}, doi = {10.3390/min9070408}, pages = {28}, year = {2019}, abstract = {The Postmasburg Manganese Field (PMF), Northern Cape Province, South Africa, once represented one of the largest sources of manganese ore worldwide. Two belts of manganese ore deposits have been distinguished in the PMF, namely the Western Belt of ferruginous manganese ores and the Eastern Belt of siliceous manganese ores. Prevailing models of ore formation in these two belts invoke karstification of manganese-rich dolomites and residual accumulation of manganese wad which later underwent diagenetic and low-grade metamorphic processes. For the most part, the role of hydrothermal processes and metasomatic alteration towards ore formation has not been adequately discussed. Here we report an abundance of common and some rare Al-, Na-, K- and Ba-bearing minerals, particularly aegirine, albite, microcline, banalsite, serandite-pectolite, paragonite and natrolite in Mn ores of the PMF, indicative of hydrothermal influence. Enrichments in Na, K and/or Ba in the ores are generally on a percentage level for most samples analysed through bulk-rock techniques. The presence of As-rich tokyoite also suggests the presence of As and V in the hydrothermal fluid. The fluid was likely oxidized and alkaline in nature, akin to a mature basinal brine. Various replacement textures, particularly of Na- and K- rich minerals by Ba-bearing phases, suggest sequential deposition of gangue as well as ore-minerals from the hydrothermal fluid, with Ba phases being deposited at a later stage. The stratigraphic variability of the studied ores and their deviation from the strict classification of ferruginous and siliceous ores in the literature, suggests that a re-evaluation of genetic models is warranted. New Ar-Ar ages for K-feldspars suggest a late Neoproterozoic timing for hydrothermal activity. This corroborates previous geochronological evidence for regional hydrothermal activity that affected Mn ores at the PMF but also, possibly, the high-grade Mn ores of the Kalahari Manganese Field to the north. A revised, all-encompassing model for the development of the manganese deposits of the PMF is then proposed, whereby the source of metals is attributed to underlying carbonate rocks beyond the Reivilo Formation of the Campbellrand Subgroup. The main process by which metals are primarily accumulated is attributed to karstification of the dolomitic substrate. The overlying Asbestos Hills Subgroup banded iron formation (BIF) is suggested as a potential source of alkali metals, which also provides a mechanism for leaching of these BIFs to form high-grade residual iron ore deposits.}, language = {en} } @misc{FaireyTimmermanSudoetal.2019, author = {Fairey, Brenton J. and Timmerman, Martin Jan and Sudo, Masafumi and Tsikos, Harilaos}, title = {The role of hydrothermal activity in the formation of Karst-hosted manganese deposits of the Postmasburg Mn Field, Northern Cape Province, South Africa}, series = {Postprints der Universit{\"a}t Potsdam : Mathematisch-Naturwissenschaftliche Reihe}, journal = {Postprints der Universit{\"a}t Potsdam : Mathematisch-Naturwissenschaftliche Reihe}, number = {966}, issn = {1866-8372}, doi = {10.25932/publishup-47330}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-473304}, pages = {30}, year = {2019}, abstract = {The Postmasburg Manganese Field (PMF), Northern Cape Province, South Africa, once represented one of the largest sources of manganese ore worldwide. Two belts of manganese ore deposits have been distinguished in the PMF, namely the Western Belt of ferruginous manganese ores and the Eastern Belt of siliceous manganese ores. Prevailing models of ore formation in these two belts invoke karstification of manganese-rich dolomites and residual accumulation of manganese wad which later underwent diagenetic and low-grade metamorphic processes. For the most part, the role of hydrothermal processes and metasomatic alteration towards ore formation has not been adequately discussed. Here we report an abundance of common and some rare Al-, Na-, K- and Ba-bearing minerals, particularly aegirine, albite, microcline, banalsite, s{\´e}randite-pectolite, paragonite and natrolite in Mn ores of the PMF, indicative of hydrothermal influence. Enrichments in Na, K and/or Ba in the ores are generally on a percentage level for most samples analysed through bulk-rock techniques. The presence of As-rich tokyoite also suggests the presence of As and V in the hydrothermal fluid. The fluid was likely oxidized and alkaline in nature, akin to a mature basinal brine. Various replacement textures, particularly of Na- and K- rich minerals by Ba-bearing phases, suggest sequential deposition of gangue as well as ore-minerals from the hydrothermal fluid, with Ba phases being deposited at a later stage. The stratigraphic variability of the studied ores and their deviation from the strict classification of ferruginous and siliceous ores in the literature, suggests that a re-evaluation of genetic models is warranted. New Ar-Ar ages for K-feldspars suggest a late Neoproterozoic timing for hydrothermal activity. This corroborates previous geochronological evidence for regional hydrothermal activity that affected Mn ores at the PMF but also, possibly, the high-grade Mn ores of the Kalahari Manganese Field to the north. A revised, all-encompassing model for the development of the manganese deposits of the PMF is then proposed, whereby the source of metals is attributed to underlying carbonate rocks beyond the Reivilo Formation of the Campbellrand Subgroup. The main process by which metals are primarily accumulated is attributed to karstification of the dolomitic substrate. The overlying Asbestos Hills Subgroup banded iron formation (BIF) is suggested as a potential source of alkali metals, which also provides a mechanism for leaching of these BIFs to form high-grade residual iron ore deposits.}, language = {en} } @article{AramayoGuzmanHongnetal.2017, author = {Aramayo, Alejandro and Guzman, Silvina and Hongn, Fernando D. and del Papa, Cecilia and Montero-Lopez, Carolina and Sudo, Masafumi}, title = {A Middle Miocene (13.5-12 Ma) deformational event constrained by volcanism along the Puna-Eastern Cordillera border, NW Argentina}, series = {Tectonophysics : international journal of geotectonics and the geology and physics of the interior of the earth}, volume = {703}, journal = {Tectonophysics : international journal of geotectonics and the geology and physics of the interior of the earth}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0040-1951}, doi = {10.1016/j.tecto.2017.02.018}, pages = {9 -- 22}, year = {2017}, abstract = {The features of Middle Miocene deposits in the Puna-Eastern Cordillera transition (Valles Calchaquies) indicate that Cenozoic deformation, sedimentation and volcanism follow a complex spatiotemporal relationship. The intense volcanic activity recorded in the eastern Puna border between 14 and 11.5 Ma coincides with the occurrence of one of the most important deformation events of the Neogene tectonic evolution in the region. Studies performed across the Puna-Eastern Cordillera transition show different relationships between volcanic deposits of ca. 13.5-12.1 Ma and the Oligocene-Miocene Angastaco Formation. In this paper we describe the ash-flow tuff deposits which are the first of this type found concordant in the sedimentary fill of Valles Calchaquies. Several analyses performed on these pyroclastic deposits allow a correlation to be made with the Alto de Las Lagunas Ignimbrite (ca. 13.5 Ma) of the Pucarilla-Cerro Tipillas Volcanic Complex located in the Puna. Outcrops of the ca. 13.5 Ma pyroclastic deposits are recognised within the Puna and the Valle Calchaqui. However, in the southern prolongation of the Valle de Hualfin (Tiopampa-Pucarilla depression) that separates the Puna from the Valle Calchaqui at these latitudes, these deposits are partially eroded and buried, and thus their occurrence is recorded only by abundant volcanic clasts included in conglomerates of the Angastaco Formation. The sedimentation of the Angastaco Formation was aborted at ca. 12 Ma in the Tiopampa-Pucarilla depression by the Pucarilla Ignimbrite, which unconformably covers the synorogenic units. On the contrary, in the Valle Calchaqui the sedimentation of the Angastaco Formation continued until the Late Miocene. The different relationships between the Miocene Angastaco Formation and the ignimbrites with ages of ca. 13.5 and ca. 12 Ma reveal that in this short period (-1.5 m.y.) a significant deformation event took place and resulted in marked palaeogeographic changes, as evidenced by stratigraphic-sedimentological and chronological records in the Angastaco Formation. (C) 2017 Elsevier B.V. All rights reserved.}, language = {en} }