@misc{Hennemann2012, author = {Hennemann, Anja}, title = {The epistemic and evidential use of Spanish modal adverbs and verbs of cognitive attitude}, series = {Postprints der Universit{\"a}t Potsdam : Philosophische Reihe}, journal = {Postprints der Universit{\"a}t Potsdam : Philosophische Reihe}, number = {107}, issn = {1866-8380}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-93929}, pages = {38}, year = {2012}, abstract = {This article deals with Spanish modal adverbs and verbs of cognitive attitude (Capelli 2007) and their epistemic and/or evidential use. The article is based upon the hypothesis that the study of the use of these linguistic devices has to be highly context-sensitive, as it is not always (only) the sentence level that has to be looked at if one wants to find out whether a certain adverb or verb of cognitive attitude is used evidentially or epistemically. In this article, therefore, the context is used to determine which meaning aspects of an element are encoded and which are contributed by the context. The data were retrieved from the daily newspaper El Pa{\´i}s. Nevertheless, the present study is not a quantitative one, but rather a qualitative study. My corpus analysis indicates that it is not possible to differentiate between the linguistic categories of evidentiality and epistemic modality in every case, although it indeed is possible in the vast majority of cases. In verbs of cognitive attitude, evidentiality and epistemic modality seem to be two interwoven categories, while concerning modal adverbs it is usually possible to separate the categories and to distinguish between the different subtypes of evidentiality such as visual evidence, hearsay and inference.}, language = {en} } @article{KraheBieneck2012, author = {Krah{\´e}, Barbara and Bieneck, Steffen}, title = {The effect of music-induced mood on aggressive affect, cognition, and behavior}, series = {Journal of applied social psychology : devoted to applications of experimental behavioral science research to problems of society}, volume = {42}, journal = {Journal of applied social psychology : devoted to applications of experimental behavioral science research to problems of society}, number = {2}, publisher = {Wiley-Blackwell}, address = {Hoboken}, issn = {0021-9029}, doi = {10.1111/j.1559-1816.2011.00887.x}, pages = {271 -- 290}, year = {2012}, abstract = {Two studies explored the role of pleasant music in buffering the adverse effects of provocation. In the first study, 111 participants listened to aversive, pleasant, or no music before receiving a provocation and completing a measure of aggressive behavior. Participants exposed to pleasant music reported more positive mood. Those in the aversive music condition reported more negative mood than did those in the no-music control condition. The more positive the music-induced mood, the less anger was experienced and aggressive behavior was shown after provocation. In Study 2 (N = 142), listening to pleasant music reduced anger following provocation, compared to aversive music and a no-music control condition. Pleasant music also increased response latencies in recognizing aggressive words after provocation.}, language = {en} } @unpublished{KrauseMunzTecklenburgetal.2012, author = {Krause, S. and Munz, Matthias and Tecklenburg, C. and Binley, Andrew}, title = {The effect of groundwater forcing on hyporheic exchange Reply to comment on 'Munz M, Krause S, Tecklenburg C, Binley A. Reducing monitoring gaps at the aquifer-river interface by modelling groundwater-surfacewater exchange flow patterns. Hydrological Processes. DOI: 10.1002/hyp.8080'}, series = {Hydrological processes}, volume = {26}, journal = {Hydrological processes}, number = {10}, publisher = {Wiley-Blackwell}, address = {Hoboken}, issn = {1099-1085}, doi = {10.1002/hyp.9271}, pages = {1589 -- 1592}, year = {2012}, language = {en} } @inproceedings{ReschkeWolterSchoepflinetal.2012, author = {Reschke, Antje and Wolter, Martin and Sch{\"o}pflin, Marlene and K{\"o}nig, Niklas and Mayer, Frank and Baur, Heiner}, title = {The effect of foot orthoses on peroneal H-reflex in treadmill walking a pilot study}, series = {Medicine and science in sports and exercise : official journal of the American College of Sports Medicine}, volume = {44}, booktitle = {Medicine and science in sports and exercise : official journal of the American College of Sports Medicine}, publisher = {Lippincott Williams \& Wilkins}, address = {Philadelphia}, issn = {0195-9131}, pages = {943 -- 943}, year = {2012}, language = {en} } @misc{LinKhajooeiEngeletal.2012, author = {Lin, Chiao-I and Khajooei, Mina and Engel, Tilman and Nair, Alexandra and Heikkila, Mika and Kaplick, Hannes and Mayer, Frank}, title = {The effect of chronic ankle instability on muscle activations in lower extremities}, series = {Postprints der Universit{\"a}t Potsdam : Humanwissenschaftliche Reihe}, journal = {Postprints der Universit{\"a}t Potsdam : Humanwissenschaftliche Reihe}, issn = {1866-8364}, doi = {10.25932/publishup-51563}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-515632}, pages = {17}, year = {2012}, abstract = {Background/Purpose Muscular reflex responses of the lower extremities to sudden gait disturbances are related to postural stability and injury risk. Chronic ankle instability (CAI) has shown to affect activities related to the distal leg muscles while walking. Its effects on proximal muscle activities of the leg, both for the injured- (IN) and uninjured-side (NON), remain unclear. Therefore, the aim was to compare the difference of the motor control strategy in ipsilateral and contralateral proximal joints while unperturbed walking and perturbed walking between individuals with CAI and matched controls. Materials and methods In a cross-sectional study, 13 participants with unilateral CAI and 13 controls (CON) walked on a split-belt treadmill with and without random left- and right-sided perturbations. EMG amplitudes of muscles at lower extremities were analyzed 200 ms after perturbations, 200 ms before, and 100 ms after (Post100) heel contact while walking. Onset latencies were analyzed at heel contacts and after perturbations. Statistical significance was set at alpha≤0.05 and 95\% confidence intervals were applied to determine group differences. Cohen's d effect sizes were calculated to evaluate the extent of differences. Results Participants with CAI showed increased EMG amplitudes for NON-rectus abdominus at Post100 and shorter latencies for IN-gluteus maximus after heel contact compared to CON (p<0.05). Overall, leg muscles (rectus femoris, biceps femoris, and gluteus medius) activated earlier and less bilaterally (d = 0.30-0.88) and trunk muscles (bilateral rectus abdominus and NON-erector spinae) activated earlier and more for the CAI group than CON group (d = 0.33-1.09). Conclusion Unilateral CAI alters the pattern of the motor control strategy around proximal joints bilaterally. Neuromuscular training for the muscles, which alters motor control strategy because of CAI, could be taken into consideration when planning rehabilitation for CAI.}, language = {en} } @article{Krause2012, author = {Krause, Uwe}, title = {The Dutch school system}, series = {Potsdamer geographische Praxis}, journal = {Potsdamer geographische Praxis}, number = {1}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, issn = {2194-1599}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-65828}, pages = {67 -- 68}, year = {2012}, language = {en} } @article{BeckerLuedtkeTrautweinetal.2012, author = {Becker, Michael and L{\"u}dtke, Oliver and Trautwein, Ulrich and K{\"o}ller, Olaf and Baumert, J{\"u}rgen}, title = {The differential effects of school racking on psychometric intelligence Do academic-track schools make students smarter?}, series = {The journal of educational psychology}, volume = {104}, journal = {The journal of educational psychology}, number = {3}, publisher = {American Psychological Association}, address = {Washington}, issn = {0022-0663}, doi = {10.1037/a0027608}, pages = {682 -- 699}, year = {2012}, abstract = {Prior research has shown that quantity of schooling affects the development of intelligence in childhood and adolescence. However, it is still debated whether other aspects of schooling-such as ability tracking or, more generally, school quality-can also influence intelligence. In this study, the authors analyzed intelligence gains in academic- and vocational-track schools in Germany, testing for differential effects of school quality (academic vs. vocational track) on psychometric intelligence. Longitudinal data were obtained from a sample of N = 1,038 Grade 7 and 10 students in 49 schools. A nonverbal reasoning test was used as an indicator of general psychometric intelligence, and relevant psychological and social background variables were included in the analyses. Propensity score matching was used to control for selection bias. Results showed a positive effect of attending the academic track.}, language = {en} } @article{CaliendoClementPapiesetal.2012, author = {Caliendo, Marco and Clement, Michel and Papies, Dominik and Scheel-Kopeinig, Sabine}, title = {The cost impact of spam filters measuring the effect of information system technologies in organizations}, series = {Information systems research}, volume = {23}, journal = {Information systems research}, number = {3}, publisher = {INFORMS}, address = {Hannover}, issn = {1047-7047}, doi = {10.1287/isre.1110.0396}, pages = {1068 -- 1080}, year = {2012}, abstract = {Dealing with spam is very costly, and many organizations have tried to reduce spam-related costs by installing spam filters. Relying on modern econometric methods to reduce the selection bias of installing a spam filter, we use a unique data setting implemented at a German university to measure the costs associated with spam and the costs savings of spam filters. Our methodological framework accounts for effect heterogeneity and can be easily used to estimate the effect of other IS technologies implemented in organizations. The majority of costs stem from the time that employees spend identifying and deleting spam, amounting to an average of approximately five minutes per employee per day. Our analysis, which accounts for selection bias, finds that the installation of a spam filter reduces these costs by roughly one third. Failing to account for the selection bias would lead to a result that suggests that installing a spam filter does not reduce working time losses. However, cost savings only occur when the spam burden is high, indicating that spam filters do not necessarily reduce costs and are therefore no universal remedy. The analysis further shows that spam filters alone are a countermeasure against spam that exhibits only limited effectiveness because they only reduce costs by one third.}, language = {en} } @article{SzurliesGelukKrijgsmanetal.2012, author = {Szurlies, Michael and Geluk, Mark C. and Krijgsman, Wout and Kurschner, Wolfram M.}, title = {The continental Permian-Triassic boundary in the Netherlands implications for the geomagnetic polarity time scale}, series = {Earth \& planetary science letters}, volume = {317}, journal = {Earth \& planetary science letters}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0012-821X}, doi = {10.1016/j.epsl.2011.11.043}, pages = {165 -- 176}, year = {2012}, abstract = {In Central and NW Europe, the transition from the Permian to the Triassic (i.e., the Zechstein-Buntsandstein boundary interval) is developed mainly in red bed facies. This continental sedimentary succession is marked by relatively high sedimentation rates providing a high temporal resolution favorable for magnetic polarity stratigraphy. Here, we present a Zechstein to Lower Buntsandstein magnetostratigraphy obtained from the c. 100 m thick Everdingen-1 core from the Netherlands. Seven magnetozones (EV1n to EV4n) and five submagnetozones (EV1n.1r to EV3r.1n) have been delineated. The Everdingen-1 magnetostratigraphy has been integrated into the well-established high-resolution Zechstein-Buntsandstein stratigraphic framework, and verifies the geomagnetic polarity record from Central Germany. This confirms the hypothesis of nearly synchronous base-level cycles within the interior of the Central European Basin. These cycles are related to solar-induced similar to 100 ka eccentricity cycles. The most distinctive feature of the Everdingen-1 magnetostratigraphy is a transition from a thin reverse to a thick dominantly normal magnetic polarity interval. This reversal predates both the terrestrial mass extinction, which is indicated by a palynofloral turnover and a major sediment provenance change at the base of the Buntsandstein, and the marine Permian-Triassic Boundary (PTB). The PTB is located within the lowermost Buntsandstein and is approximated by the last occurrence of the conchostracan Falsisca postera and a negative excursion in the carbon isotope record. According to the Buntsandstein cyclostratigraphy, the R/N reversal predates the marine end-Permian extinction event by about 0.1 Ma and the marine biostratigraphic PTB by about 0.2 Ma. The thick normal magnetozone is estimated to have lasted c. 700 ka, and roughly coincides with the main phase of Siberian Trap volcanism.}, language = {en} } @article{CubittEisertWolf2012, author = {Cubitt, Toby S. and Eisert, Jens and Wolf, Michael M.}, title = {The complexity of relating quantum channels to master equations}, series = {Communications in mathematical physics}, volume = {310}, journal = {Communications in mathematical physics}, number = {2}, publisher = {Springer}, address = {New York}, issn = {0010-3616}, doi = {10.1007/s00220-011-1402-y}, pages = {383 -- 418}, year = {2012}, abstract = {Completely positive, trace preserving (CPT) maps and Lindblad master equations are both widely used to describe the dynamics of open quantum systems. The connection between these two descriptions is a classic topic in mathematical physics. One direction was solved by the now famous result due to Lindblad, Kossakowski, Gorini and Sudarshan, who gave a complete characterisation of the master equations that generate completely positive semi-groups. However, the other direction has remained open: given a CPT map, is there a Lindblad master equation that generates it (and if so, can we find its form)? This is sometimes known as the Markovianity problem. Physically, it is asking how one can deduce underlying physical processes from experimental observations. We give a complexity theoretic answer to this problem: it is NP-hard. We also give an explicit algorithm that reduces the problem to integer semi-definite programming, a well-known NP problem. Together, these results imply that resolving the question of which CPT maps can be generated by master equations is tantamount to solving P = NP: any efficiently computable criterion for Markovianity would imply P = NP; whereas a proof that P = NP would imply that our algorithm already gives an efficiently computable criterion. Thus, unless P does equal NP, there cannot exist any simple criterion for determining when a CPT map has a master equation description. However, we also show that if the system dimension is fixed (relevant for current quantum process tomography experiments), then our algorithm scales efficiently in the required precision, allowing an underlying Lindblad master equation to be determined efficiently from even a single snapshot in this case. Our work also leads to similar complexity-theoretic answers to a related long-standing open problem in probability theory.}, language = {en} } @article{Wolf2012, author = {Wolf, Hans-Georg}, title = {The cognitive sociolinguistic approach to the lexicon of Cameroon English and other world englishes}, isbn = {978-1-61451-248-6}, year = {2012}, language = {en} } @article{AdamBovend'EerdtvanDoorenetal.2012, author = {Adam, Jos J. and Bovend'Eerdt, Thamar J. H. and van Dooren, Fleur E. P. and Fischer, Martin H. and Pratt, Jay}, title = {The closer the better hand proximity dynamically affects letter recognition accuracy}, series = {Attention, perception, \& psychophysics : AP\&P ; a journal of the Psychonomic Society, Inc.}, volume = {74}, journal = {Attention, perception, \& psychophysics : AP\&P ; a journal of the Psychonomic Society, Inc.}, number = {7}, publisher = {Springer}, address = {New York}, issn = {1943-3921}, doi = {10.3758/s13414-012-0339-3}, pages = {1533 -- 1538}, year = {2012}, abstract = {A growing literature has suggested that processing of visual information presented near the hands is facilitated. In this study, we investigated whether the near-hands superiority effect also occurs with the hands moving. In two experiments, participants performed a cyclical bimanual movement task requiring concurrent visual identification of briefly presented letters. For both the static and dynamic hand conditions, the results showed improved letter recognition performance with the hands closer to the stimuli. The finding that the encoding advantage for near-hand stimuli also occurred with the hands moving suggests that the effect is regulated in real time, in accordance with the concept of a bimodal neural system that dynamically updates hand position in external space.}, language = {en} } @misc{AdamBovend'EerdtDoorenetal.2012, author = {Adam, Jos J. and Bovend'Eerdt, Thamar J. H. and Dooren, Fleur E. P. van and Fischer, Martin H. and Pratt, Jay}, title = {The closer the better}, series = {Postprints der Universit{\"a}t Potsdam : Humanwissenschaftliche Reihe}, journal = {Postprints der Universit{\"a}t Potsdam : Humanwissenschaftliche Reihe}, number = {607}, issn = {1866-8364}, doi = {10.25932/publishup-43296}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-432963}, pages = {1533 -- 1538}, year = {2012}, abstract = {A growing literature has suggested that processing of visual information presented near the hands is facilitated. In this study, we investigated whether the near-hands superiority effect also occurs with the hands moving. In two experiments, participants performed a cyclical bimanual movement task requiring concurrent visual identification of briefly presented letters. For both the static and dynamic hand conditions, the results showed improved letter recognition performance with the hands closer to the stimuli. The finding that the encoding advantage for near-hand stimuli also occurred with the hands moving suggests that the effect is regulated in real time, in accordance with the concept of a bimodal neural system that dynamically updates hand position in external space.}, language = {en} } @article{WirthSaalfrank2012, author = {Wirth, Jonas and Saalfrank, Peter}, title = {The chemistry of water on alpha-alumina kinetics and nuclear quantum effects from first principles}, series = {The journal of physical chemistry : C, Nanomaterials and interfaces}, volume = {116}, journal = {The journal of physical chemistry : C, Nanomaterials and interfaces}, number = {51}, publisher = {American Chemical Society}, address = {Washington}, issn = {1932-7447}, doi = {10.1021/jp310234h}, pages = {26829 -- 26840}, year = {2012}, abstract = {Water adsorption on an alumina (alpha-Al2O3) surface is studied here from first principles using periodic density functional theory in the generalized gradient approximation. Two different coverage regimes, low and high, are considered. For the low-coverage regime (with a coverage of 1/4 with respect to the number of coordinatively unsaturated Al sites), possible reactions at the surface such as dissociation, rotation, and diffusion of water and its fragments are investigated, using first principles thermodynamics and kinetics. A microkinetic model is set up with rates calculated from Eyring's transition state theory in order to cover a wide range of time scales. Special emphasis of this study is on the magnitude of quantum effects and on anharmonic corrections, particularly for reactions and dynamics. These have often been neglected in the past for water/alumina systems but can influence the system. This is particularly true for processes involving hydrogen atoms, where, for example, tunneling corrections to reaction rates are found to be important even at room temperature. For a higher-coverage regime (with a coverage of 2 ML), hydrogen dynamics becomes even more complex and is characterized, e.g., by concerted atom motion, strong anharmonicity, and delocalization. In this regime, classical molecular dynamics becomes questionable as well as quantum mechanical treatments based on the harmonic approximation.}, language = {en} } @misc{Gassner2012, type = {Master Thesis}, author = {Gassner, Alexandra Carina}, title = {The character of the core-mantle boundary : a systematic study using PcP}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-63590}, school = {Universit{\"a}t Potsdam}, year = {2012}, abstract = {Assuming that liquid iron alloy from the outer core interacts with the solid silicate-rich lower mantle the influence on the core-mantle reflected phase PcP is studied. If the core-mantle boundary is not a sharp discontinuity, this becomes apparent in the waveform and amplitude of PcP. Iron-silicate mixing would lead to regions of partial melting with higher density which in turn reduces the velocity of seismic waves. On the basis of the calculation and interpretation of short-period synthetic seismograms, using the reflectivity and Gauss Beam method, a model space is evaluated for these ultra-low velocity zones (ULVZs). The aim of this thesis is to analyse the behaviour of PcP between 10° and 40° source distance for such models using different velocity and density configurations. Furthermore, the resolution limits of seismic data are discussed. The influence of the assumed layer thickness, dominant source frequency and ULVZ topography are analysed. The Gr{\"a}fenberg and NORSAR arrays are then used to investigate PcP from deep earthquakes and nuclear explosions. The seismic resolution of an ULVZ is limited both for velocity and density contrasts and layer thicknesses. Even a very thin global core-mantle transition zone (CMTZ), rather than a discrete boundary and also with strong impedance contrasts, seems possible: If no precursor is observable but the PcP_model /PcP_smooth amplitude reduction amounts to more than 10\%, a very thin ULVZ of 5 km with a first-order discontinuity may exist. Otherwise, if amplitude reductions of less than 10\% are obtained, this could indicate either a moderate, thin ULVZ or a gradient mantle-side CMTZ. Synthetic computations reveal notable amplitude variations as function of the distance and the impedance contrasts. Thereby a primary density effect in the very steep-angle range and a pronounced velocity dependency in the wide-angle region can be predicted. In view of the modelled findings, there is evidence for a 10 to 13.5 km thick ULVZ 600 km south-eastern of Moscow with a NW-SE extension of about 450 km. Here a single specific assumption about the velocity and density anomaly is not possible. This is in agreement with the synthetic results in which several models create similar amplitude-waveform characteristics. For example, a ULVZ model with contrasts of -5\% VP , -15\% VS and +5\% density explain the measured PcP amplitudes. Moreover, below SW Finland and NNW of the Caspian Sea a CMB topography can be assumed. The amplitude measurements indicate a wavelength of 200 km and a height of 1 km topography, previously also shown in the study by Kampfmann and M{\"u}ller (1989). Better constraints might be provided by a joined analysis of seismological data, mineralogical experiments and geodynamic modelling.}, language = {en} } @article{HerbertPollatos2012, author = {Herbert, Beate M. and Pollatos, Olga}, title = {The body in the mind On the relationship between interoception and embodiment}, series = {Topics in cognitive science}, volume = {4}, journal = {Topics in cognitive science}, number = {4}, publisher = {Wiley-Blackwell}, address = {Hoboken}, issn = {1756-8757}, doi = {10.1111/j.1756-8765.2012.01189.x}, pages = {692 -- 704}, year = {2012}, abstract = {The processing, representation, and perception of bodily signals (interoception) plays an important role for human behavior. Theories of embodied cognition hold that higher cognitive processes operate on perceptual symbols and that concept use involves reactivations of the sensory-motor states that occur during experience with the world. Similarly, activation of interoceptive representations and meta-representations of bodily signals supporting interoceptive awareness are profoundly associated with emotional experience and cognitive functions. This article gives an overview over present findings and models on interoception and mechanisms of embodiment and highlights its relevance for disorders that are suggested to represent a translation deficit of bodily states into subjective feelings and self-awareness.}, language = {en} } @misc{BaumannWalz2012, author = {Baumann, Otto and Walz, Bernd}, title = {The blowfly salivary gland - A model system for analyzing the regulation of plasma membrane V-ATPase}, series = {Journal of insect physiology}, volume = {58}, journal = {Journal of insect physiology}, number = {4}, publisher = {Elsevier}, address = {Oxford}, issn = {0022-1910}, doi = {10.1016/j.jinsphys.2011.11.015}, pages = {450 -- 458}, year = {2012}, abstract = {Vacuolar H+-ATPases (V-ATPases) are heteromultimeric proteins that use the energy of ATP hydrolysis for the electrogenic transport of protons across membranes. They are common to all eukaryotic cells and are located in the plasma membrane or in membranes of acid organelles. In many insect epithelia, V-ATPase molecules reside in large numbers in the apical plasma membrane and create an electrochemical proton gradient that is used for the acidification or alkalinization of the extracellular space, the secretion or reabsorption of ions and fluids, the import of nutrients, and diverse other cellular activities. Here, we summarize our results on the functions and regulation of V-ATPase in the tubular salivary gland of the blowfly Calliphora vicina. In this gland, V-ATPase activity energizes the secretion of a KCl-rich saliva in response to the neurohormone serotonin (5-HT). Because of particular morphological and physiological features, the blowfly salivary glands are a superior and exemplary system for the analysis of the intracellular signaling pathways and mechanisms that modulate V-ATPase activity and solute transport in an insect epithelium.}, language = {en} } @article{BriesemeisterHofmannKuchinkeetal.2012, author = {Briesemeister, Benny B. and Hofmann, Markus J. and Kuchinke, Lars and Jacobs, Arthur M.}, title = {The BAWL databases in research on emotional word processing}, series = {Potsdam cognitive science series}, journal = {Potsdam cognitive science series}, number = {3}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, issn = {2190-4545}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-62377}, pages = {61 -- 66}, year = {2012}, abstract = {Inhalt: Introduction A two-dimensional affective space: Valence and arousal effects in word processing Higher dimensional affective space: a role of discrete emotions in word processing? A direct comparison of the affective space models References}, language = {en} } @article{KutzinskiEtte2012, author = {Kutzinski, Vera M. and Ette, Ottmar}, title = {The art of science: Alexander von Humboldt's views of the cultures of the world}, isbn = {0-226-86506-1}, year = {2012}, language = {en} } @article{YarmanGroebeNeumannetal.2012, author = {Yarman, Aysu and Gr{\"o}be, Glenn and Neumann, Bettina and Kinne, Mathias and Gajovic-Eichelmann, Nenad and Wollenberger, Ursula and Hofrichter, Martin and Ullrich, Rene and Scheibner, Katrin and Scheller, Frieder W.}, title = {The aromatic peroxygenase from Marasmius rutola-a new enzyme for biosensor applications}, series = {Analytical \& bioanalytical chemistry}, volume = {402}, journal = {Analytical \& bioanalytical chemistry}, number = {1}, publisher = {Springer}, address = {Heidelberg}, issn = {1618-2642}, doi = {10.1007/s00216-011-5497-y}, pages = {405 -- 412}, year = {2012}, abstract = {The aromatic peroxygenase (APO; EC 1.11.2.1) from the agraric basidomycete Marasmius rotula (MroAPO) immobilized at the chitosan-capped gold-nanoparticle-modified glassy carbon electrode displayed a pair of redox peaks with a midpoint potential of -278.5 mV vs. AgCl/AgCl (1 M KCl) for the Fe(2+)/Fe(3+) redox couple of the heme-thiolate-containing protein. MroAPO oxidizes aromatic substrates such as aniline, p-aminophenol, hydroquinone, resorcinol, catechol, and paracetamol by means of hydrogen peroxide. The substrate spectrum overlaps with those of cytochrome P450s and plant peroxidases which are relevant in environmental analysis and drug monitoring. In M. rotula peroxygenase-based enzyme electrodes, the signal is generated by the reduction of electrode-active reaction products (e.g., p-benzoquinone and p-quinoneimine) with electro-enzymatic recycling of the analyte. In these enzyme electrodes, the signal reflects the conversion of all substrates thus representing an overall parameter in complex media. The performance of these sensors and their further development are discussed.}, language = {en} }