@misc{PeterBoldtNiedersteinetal.1990,
  author    = {Peter, Martin G. and Boldt, Peter C. and Niederstein, Yvonne and Peter-Katalinić, Jasna},
  title     = {Synthesen von Galactose-Cluster-haltigen Steroid-Derivaten},
  url       = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-16783},
  year      = {1990},
  abstract  = {The synthesis of galactose clusters that are linked to a steroid moiety by a peptide-like spacer unit is described. The galactose cluster is obtained by Koenigs-Knorr glycosylation of TRIS-Gly-Fmoc (2b) under Helferich conditions. Peptide and ester bonds are formed after activation of carboxylic acids as diphenylthiophene dioxide (TDO) esters. 6a is synthesized in a convergent way by coupling of (Ac4Gal)3-TRIS-Gly (3e) with cholesteryl TDO succinate (5b). Coupling of (Ac4Gal)3-TRIS-Gly hydrogen succinate (3f) with Gly-O-Chol (5d) by means of EEDQ yields 6d. Reaction of (Ac4Gal)3-TRIS-Gly-SUCC-O-TDO (3g) with 25-hydroxycholesterol leads in a linear sequence to the oxysterol derivative 6f. Selective cleavage of the acetyl groups from galactose units yields the known compound 6b and the new derivatives 6e and 6g.},
  language  = {de}
}
@article{MarsatStahlhutLaschewskyetal.2013,
  author    = {Marsat, Jean-Noel and Stahlhut, Frank and Laschewsky, Andr{\´e} and von Berlepsch, Hans and B{\"o}ttcher, Christoph},
  title     = {Multicompartment micelles from silicone-based triphilic block copolymers},
  series = {Colloid and polymer science : official journal of the Kolloid-Gesellschaft},
  volume    = {291},
  journal   = {Colloid and polymer science : official journal of the Kolloid-Gesellschaft},
  number    = {11},
  publisher = {Springer},
  address   = {New York},
  issn      = {0303-402X},
  doi       = {10.1007/s00396-013-3001-2},
  pages     = {2561 -- 2567},
  year      = {2013},
  abstract  = {An amphiphilic linear ternary block copolymer was synthesised in three consecutive steps via reversible addition-fragmentation chain transfer polymerisation. Oligo(ethylene glycol) monomethyl ether acrylate was engaged as a hydrophilic building block, while benzyl acrylate and 3-tris(trimethylsiloxy)silyl propyl acrylate served as hydrophobic building blocks. The resulting "triphilic" copolymer consists thus of a hydrophilic (A) and two mutually incompatible "soft" hydrophobic blocks, namely, a lipophilic (B) and a silicone-based (C) block, with all blocks having glass transition temperatures well below 0 A degrees C. The triphilic copolymer self-assembles into spherical multicompartment micellar aggregates in aqueous solution, where the two hydrophobic blocks undergo local phase separation into various ultrastructures as evidenced by cryogenic transmission electron microscopy. Thus, a silicone-based polymer block can replace the hitherto typically employed fluorocarbon-based hydrophobic blocks in triphilic block copolymers for inducing multicompartmentalisation.},
  language  = {en}
}