@article{NiedlBerensteinBeta2016, author = {Niedl, Robert Raimund and Berenstein, Igal and Beta, Carsten}, title = {How imperfect mixing and differential diffusion accelerate the rate of nonlinear reactions in microfluidic channels}, series = {Physical chemistry, chemical physics : PCCP ; a journal of European Chemical Societies}, volume = {18}, journal = {Physical chemistry, chemical physics : PCCP ; a journal of European Chemical Societies}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {1463-9076}, doi = {10.1039/c6cp00224b}, pages = {6451 -- 6457}, year = {2016}, abstract = {In this paper, we show experimentally that inside a microfluidic device, where the reactants are segregated, the reaction rate of an autocatalytic clock reaction is accelerated in comparison to the case where all the reactants are well mixed. We also find that, when mixing is enhanced inside the microfluidic device by introducing obstacles into the flow, the clock reaction becomes slower in comparison to the device where mixing is less efficient. Based on numerical simulations, we show that this effect can be explained by the interplay of nonlinear reaction kinetics (cubic autocatalysis) and differential diffusion, where the autocatalytic species diffuses slower than the substrate.}, language = {en} } @article{SchwarzeMuellerAstetal.2014, author = {Schwarze, Thomas and M{\"u}ller, Holger and Ast, Sandra and Steinbr{\"u}ck, D{\"o}rte and Eidner, Sascha and Geißler, Felix and Kumke, Michael Uwe and Holdt, Hans-J{\"u}rgen}, title = {Fluorescence lifetime-based sensing of sodium by an optode}, series = {Chemical Communications}, journal = {Chemical Communications}, editor = {Kumke, Michael Uwe}, publisher = {The Royal Society Chemistry}, address = {Cambridge}, issn = {0022-4936}, pages = {14167 -- 14170}, year = {2014}, abstract = {We report a 1,2,3-triazol fluoroionophore for detecting Na+ that shows in vitro enhancement in the Na+-induced fluorescence intensity and decay time. The Na+-selective molecule 1 was incorporated into a hydrogel as a part of a fiber optical sensor. This sensor allows the direct determination of Na+ in the range of 1-10 mM by measuring reversible fluorescence decay time changes.}, language = {en} }