@phdthesis{Kruesemann2016, author = {Kr{\"u}semann, Henning}, title = {First passage phenomena and single-file motion in ageing continuous time random walks and quenched energy landscapes}, school = {Universit{\"a}t Potsdam}, pages = {122}, year = {2016}, abstract = {In der Physik gibt es viele Prozesse, die auf Grund ihrer Komplexit{\"a}t nicht durch physikalische Gleichungen beschrieben werden k{\"o}nnen, beispielsweise die Bewegung eines Staubkorns in der Luft. Durch die vielen St{\"o}ße mit Luftmolek{\"u}len f{\"u}hrt es eine Zufallsbewegung aus, die so genannte Diffusion. Auch Molek{\"u}le in biologischen Zellen diffundieren, jedoch befinden sich in einer solchen Zelle im selben Volumen viel mehr oder viel gr{\"o}ßere Molek{\"u}le. Das beobachtete Teilchen st{\"o}ßt dementsprechend {\"o}fter mit anderen zusammen und die Diffusion wird langsamer, sie wird subdiffusiv. Mit der Zeit kann sich die Charakteristik der Subdiffusion {\"a}ndern; dies wird als (mikroskopisches) Altern bezeichnet. Ich untersuche in der vorliegenden Arbeit zwei mathematische Modelle f{\"u}r eindimensionale Subdiffusion, einmal den continuous time random walk (CTRW) und einmal die Zufallsbewegung in einer eingefrorenen Energielandschaft (QEL=quenched energy landscape). Beide sind Sprungprozesse, das heißt, sie sind Abfolgen von r{\"a}umlichen Spr{\"u}ngen, die durch zufallsverteilte Wartezeiten getrennt sind. Die Wartezeiten in der QEL sind r{\"a}umlich korrelliert, w{\"a}hrend sie im CTRW unkorrelliert sind. Ich untersuche in der vorliegenden Arbeit verschiedene statistische Gr{\"o}ßen in beiden Modellen. Zun{\"a}chst untersuche ich den Einfluss des Alters und den Einfluss der Korrellationen einer QEL auf die Verteilung der Zeiten, die das diffundierendes Teilchen ben{\"o}tigt, um eine (r{\"a}umliche) Schwelle zu {\"u}berqueren. Ausserdem bestimme ich den Effekt des Alters auf Str{\"o}me von (sub)diffundierenden Partikeln, die sich auf eine absorbierende Barriere zubewegen. Zuletzt besch{\"a}ftige ich mich mit der Diffusion einer eindimensionalen Anordnung von Teilchen in einer QEL, in der diese als harte Kugeln miteinander wechselwirken. Dabei vergleiche ich die gemeinsame Bewegung in einer QEL und als individuelle CTRWs miteinander {\"u}ber die Standartabweichung von der Startposition, f{\"u}r die ich das Mittel {\"u}ber mehrere QELs untersuche. Meine Arbeit setzt sich zusammen aus theoretischen {\"U}berlegungen und Berechnungen sowie der Simulation der Zufallsprozesse. Die Ergebnisse der Simulation und, soweit vorhanden, experimentelle Daten werden mit der Theorie verglichen.}, language = {en} } @phdthesis{Anielski2015, author = {Anielski, Alexander}, title = {Entwicklung einer mikrofluidischen, adaptiv geregelten Messapparatur zur quantitativen Untersuchung von Chemotaxis mit Hilfe der Flussfotolyse}, school = {Universit{\"a}t Potsdam}, pages = {iv, 130 Seiten : Illustrationen, Diagramme + 1 DVD}, year = {2015}, language = {de} } @phdthesis{Wenz2016, author = {Wenz, Leonie}, title = {Climate change impacts in an increasingly connected world}, school = {Universit{\"a}t Potsdam}, pages = {279}, year = {2016}, language = {en} } @article{FeldmannMaduarSanteretal.2016, author = {Feldmann, David and Maduar, Salim R. and Santer, Mark and Lomadze, Nino and Vinogradova, Olga I. and Santer, Svetlana}, title = {Manipulation of small particles at solid liquid interface}, series = {Scientific reports}, volume = {6}, journal = {Scientific reports}, publisher = {Nature Publishing Group}, address = {London}, issn = {2045-2322}, doi = {10.1038/srep36443}, pages = {10}, year = {2016}, abstract = {The strong adhesion of sub-micron sized particles to surfaces is a nuisance, both for removing contaminating colloids from surfaces and for conscious manipulation of particles to create and test novel micro/nano-scale assemblies. The obvious idea of using detergents to ease these processes suffers from a lack of control: the action of any conventional surface-modifying agent is immediate and global. With photosensitive azobenzene containing surfactants we overcome these limitations. Such photo-soaps contain optical switches (azobenzene molecules), which upon illumination with light of appropriate wavelength undergo reversible trans-cis photo-isomerization resulting in a subsequent change of the physico-chemical molecular properties. In this work we show that when a spatial gradient in the composition of trans- and cis- isomers is created near a solid-liquid interface, a substantial hydrodynamic flow can be initiated, the spatial extent of which can be set, e.g., by the shape of a laser spot. We propose the concept of light induced diffusioosmosis driving the flow, which can remove, gather or pattern a particle assembly at a solid-liquid interface. In other words, in addition to providing a soap we implement selectivity: particles are mobilized and moved at the time of illumination, and only across the illuminated area.}, language = {en} } @article{deCarvalhoMetzlerCherstvy2016, author = {de Carvalho, Sidney J. and Metzler, Ralf and Cherstvy, Andrey G.}, title = {Critical adsorption of polyelectrolytes onto planar and convex highly charged surfaces}, series = {New journal of physics : the open-access journal for physics}, volume = {18}, journal = {New journal of physics : the open-access journal for physics}, publisher = {IOP Publ.}, address = {London}, issn = {1367-2630}, doi = {10.1088/1367-2630/18/8/083037}, year = {2016}, abstract = {We study the adsorption-desorption transition of polyelectrolyte chains onto planar, cylindrical and spherical surfaces with arbitrarily high surface charge densities by massive Monte Carlo computer simulations. We examine in detail how the well known scaling relations for the threshold transition—demarcating the adsorbed and desorbed domains of a polyelectrolyte near weakly charged surfaces—are altered for highly charged interfaces. In virtue of high surface potentials and large surface charge densities, the Debye-H{\"u}ckel approximation is often not feasible and the nonlinear Poisson-Boltzmann approach should be implemented. At low salt conditions, for instance, the electrostatic potential from the nonlinear Poisson-Boltzmann equation is smaller than the Debye-H{\"u}ckel result, such that the required critical surface charge density for polyelectrolyte adsorption σc increases. The nonlinear relation between the surface charge density and electrostatic potential leads to a sharply increasing critical surface charge density with growing ionic strength, imposing an additional limit to the critical salt concentration above which no polyelectrolyte adsorption occurs at all. We contrast our simulations findings with the known scaling results for weak critical polyelectrolyte adsorption onto oppositely charged surfaces for the three standard geometries. Finally, we discuss some applications of our results for some physical-chemical and biophysical systems.}, language = {en} } @phdthesis{Matuschek2015, author = {Matuschek, Hannes}, title = {Applications of reproducing Kernel Hilbert spaces and their approximations}, school = {Universit{\"a}t Potsdam}, pages = {83}, year = {2015}, language = {en} } @article{ReppertPuddellKocetal.2016, author = {Reppert, Alexander von and Puddell, J. and Koc, A. and Reinhardt, M. and Leitenberger, Wolfram and Dumesnil, K. and Zamponi, Flavio and Bargheer, Matias}, title = {Persistent nonequilibrium dynamics of the thermal energies in the spin and phonon systems of an antiferromagnet}, series = {Structural dynamics}, volume = {3}, journal = {Structural dynamics}, publisher = {AIP Publishing LLC}, address = {Melville, NY}, issn = {2329-7778}, doi = {10.1063/1.4961253}, year = {2016}, abstract = {We present a temperature and fluence dependent Ultrafast X-Ray Diffraction study of a laser-heated antiferromagnetic dysprosium thin film. The loss of antiferromagnetic order is evidenced by a pronounced lattice contraction. We devise a method to determine the energy flow between the phonon and spin system from calibrated Bragg peak positions in thermal equilibrium. Reestablishing the magnetic order is much slower than the cooling of the lattice, especially around the N{\´e}el temperature. Despite the pronounced magnetostriction, the transfer of energy from the spin system to the phonons in Dy is slow after the spin-order is lost.}, language = {en} } @article{BodrovaChechkinCherstvyetal.2016, author = {Bodrova, Anna S. and Chechkin, Aleksei V. and Cherstvy, Andrey G. and Safdari, Hadiseh and Sokolov, Igor M. and Metzler, Ralf}, title = {Underdamped scaled Brownian motion}, series = {Scientific reports}, volume = {6}, journal = {Scientific reports}, publisher = {Nature Publishing Group}, address = {London}, issn = {2045-2322}, doi = {10.1038/srep30520}, year = {2016}, abstract = {It is quite generally assumed that the overdamped Langevin equation provides a quantitative description of the dynamics of a classical Brownian particle in the long time limit. We establish and investigate a paradigm anomalous diffusion process governed by an underdamped Langevin equation with an explicit time dependence of the system temperature and thus the diffusion and damping coefficients. We show that for this underdamped scaled Brownian motion (UDSBM) the overdamped limit fails to describe the long time behaviour of the system and may practically even not exist at all for a certain range of the parameter values. Thus persistent inertial effects play a non-negligible role even at significantly long times. From this study a general questions on the applicability of the overdamped limit to describe the long time motion of an anomalously diffusing particle arises, with profound consequences for the relevance of overdamped anomalous diffusion models. We elucidate our results in view of analytical and simulations results for the anomalous diffusion of particles in free cooling granular gases.}, language = {en} } @phdthesis{Dionysopoulou2016, author = {Dionysopoulou, Kyriaki}, title = {General-relativistic magnetohydrodynamics in compact objects}, school = {Universit{\"a}t Potsdam}, pages = {144}, year = {2016}, language = {en} } @article{CherstvyMetzler2016, author = {Cherstvy, Andrey G. and Metzler, Ralf}, title = {Anomalous diffusion in time-fluctuating non-stationary diffusivity landscapes}, series = {Physical chemistry, chemical physics : PCCP ; a journal of European chemical societies}, volume = {18}, journal = {Physical chemistry, chemical physics : PCCP ; a journal of European chemical societies}, publisher = {RSC Publ.}, address = {Cambridge}, issn = {1463-9084}, doi = {10.1039/C6CP03101C}, pages = {23840 -- 23852}, year = {2016}, abstract = {We investigate the ensemble and time averaged mean squared displacements for particle diffusion in a simple model for disordered media by assuming that the local diffusivity is both fluctuating in time and has a deterministic average growth or decay in time. In this study we compare computer simulations of the stochastic Langevin equation for this random diffusion process with analytical results. We explore the regimes of normal Brownian motion as well as anomalous diffusion in the sub- and superdiffusive regimes. We also consider effects of the inertial term on the particle motion. The investigation of the resulting diffusion is performed for unconfined and confined motion.}, language = {en} } @article{GhoshCherstvyPetrovetal.2016, author = {Ghosh, Surya K. and Cherstvy, Andrey G. and Petrov, Eugene P. and Metzler, Ralf}, title = {Interactions of rod-like particles on responsive elastic sheets}, series = {Soft matter}, journal = {Soft matter}, publisher = {RSC}, address = {London}, issn = {1744-6848}, doi = {10.1039/C6SM01522K}, year = {2016}, abstract = {What are the physical laws of the mutual interactions of objects bound to cell membranes, such as various membrane proteins or elongated virus particles? To rationalise this, we here investigate by extensive computer simulations mutual interactions of rod-like particles adsorbed on the surface of responsive elastic two-dimensional sheets. Specifically, we quantify sheet deformations as a response to adhesion of such filamentous particles. We demonstrate that tip-to-tip contacts of rods are favoured for relatively soft sheets, while side-by-side contacts are preferred for stiffer elastic substrates. These attractive orientation-dependent substrate-mediated interactions between the rod-like particles on responsive sheets can drive their aggregation and self-assembly. The optimal orientation of the membrane-bound rods is established via responding to the elastic energy profiles created around the particles. We unveil the phase diagramme of attractive-repulsive rod-rod interactions in the plane of their separation and mutual orientation. Applications of our results to other systems featuring membrane-associated particles are also discussed.}, language = {en} } @phdthesis{Lehmann2016, author = {Lehmann, Jascha In-su}, title = {Changes in extratropical storm track activity and their implications for extreme weather events}, pages = {221}, year = {2016}, language = {en} } @phdthesis{Feldmann2015, author = {Feldmann, Johannes}, title = {Stability of the West Antarctic Ice Sheet}, pages = {v, 165}, year = {2015}, language = {en} } @article{KopyshevLomadzeFeldmanetal.2015, author = {Kopyshev, Alexey and Lomadze, Nino and Feldman, David and Genzer, Jan and Santer, Svetlana}, title = {Making polymer brush photosensitive with azobenzene containing surfactants}, series = {Polymer : the international journal for the science and technology of polymers}, volume = {79}, journal = {Polymer : the international journal for the science and technology of polymers}, publisher = {Elsevier Science}, address = {Oxford}, issn = {0032-3861}, doi = {10.1016/j.polymer.2015.09.023}, pages = {65 -- 72}, year = {2015}, abstract = {We report on rendering polyelectrolyte brushes photosensitive by loading them with azobenzene-containing cationic surfactants. Planar poly(methacrylic acid) (PMAA) brushes are synthesized using the "grafting from" free-radical polymerization scheme followed by exposure to a solution of photosensitive surfactants consisting of positively-charged head groups and hydrophobic tails into which azobenzene moieties are inserted. In this study the length of the hydrophobic methylene spacer connecting the azobenzene and the charged head group ranges from 4 to 10 CH2 groups. Under irradiation with UV light, the photo-isomerization of azobenzene integrated into a surfactant results in a change in size, geometry, dipole moment and free volume of the whole molecule. When the brush loaded with photosensitive surfactants is exposed to irradiation with UV interference patterns, the topography of the brush deforms following the distribution of the light intensity, exhibiting surface relief gratings (SRG). Since SRG formation is accompanied by a local rupturing of polymer chains in areas from which the polymer material is receding, most of the polymer material is removed from the surface during treatment with good solvent, leaving behind characteristic patterns of lines or dots. The azobenzene molecules still integrated within the polymer film can be removed by washing the brush with water. The remaining nano-structured brush can then be re-used for further functionalization. Although the opto-mechanically induced rupturing occurs for all surfactants, larger species do not penetrate deep enough into the brush such that after rupturing a leftover layer of polymer material remains on the substrate. This indicates that rupturing occurs predominantly in regions of high surfactant density.}, language = {en} } @phdthesis{Rettig2016, author = {Rettig, Robert}, title = {{\"U}ber die Anisotropie der Kosmischen Strahlung}, school = {Universit{\"a}t Potsdam}, pages = {90, XV}, year = {2016}, language = {de} } @phdthesis{Rezanezhad2016, author = {Rezanezhad, Vahid}, title = {Inversion of the 2004 M6.0 Parkfield Earthquake Coseismic Offsets by Partition Model}, school = {Universit{\"a}t Potsdam}, pages = {83}, year = {2016}, language = {en} } @article{KurpiersNeher2016, author = {Kurpiers, Jona and Neher, Dieter}, title = {Dispersive Non-Geminate Recombination in an Amorphous Polymer:Fullerene Blend}, series = {Scientific reports}, volume = {6}, journal = {Scientific reports}, publisher = {Nature Publishing Group}, address = {London}, issn = {2045-2322}, doi = {10.1038/srep26832}, pages = {10}, year = {2016}, abstract = {Recombination of free charge is a key process limiting the performance of solar cells. For low mobility materials, such as organic semiconductors, the kinetics of non-geminate recombination (NGR) is strongly linked to the motion of charges. As these materials possess significant disorder, thermalization of photogenerated carriers in the inhomogeneously broadened density of state distribution is an unavoidable process. Despite its general importance, knowledge about the kinetics of NGR in complete organic solar cells is rather limited. We employ time delayed collection field (TDCF) experiments to study the recombination of photogenerated charge in the high-performance polymer:fullerene blend PCDTBT:PCBM. NGR in the bulk of this amorphous blend is shown to be highly dispersive, with a continuous reduction of the recombination coefficient throughout the entire time scale, until all charge carriers have either been extracted or recombined. Rapid, contact-mediated recombination is identified as an additional loss channel, which, if not properly taken into account, would erroneously suggest a pronounced field dependence of charge generation. These findings are in stark contrast to the results of TDCF experiments on photovoltaic devices made from ordered blends, such as P3HT:PCBM, where non-dispersive recombination was proven to dominate the charge carrier dynamics under application relevant conditions.}, language = {en} } @article{NeherKniepertElimelechetal.2016, author = {Neher, Dieter and Kniepert, Juliane and Elimelech, Arik and Koster, L. Jan Anton}, title = {A New Figure of Merit for Organic Solar Cells with Transport-limited Photocurrents}, series = {Scientific reports}, volume = {6}, journal = {Scientific reports}, publisher = {Nature Publishing Group}, address = {London}, issn = {2045-2322}, doi = {10.1038/srep24861}, pages = {9}, year = {2016}, abstract = {Compared to their inorganic counterparts, organic semiconductors suffer from relatively low charge carrier mobilities. Therefore, expressions derived for inorganic solar cells to correlate characteristic performance parameters to material properties are prone to fail when applied to organic devices. This is especially true for the classical Shockley-equation commonly used to describe current-voltage (JV)-curves, as it assumes a high electrical conductivity of the charge transporting material. Here, an analytical expression for the JV-curves of organic solar cells is derived based on a previously published analytical model. This expression, bearing a similar functional dependence as the Shockley-equation, delivers a new figure of merit α to express the balance between free charge recombination and extraction in low mobility photoactive materials. This figure of merit is shown to determine critical device parameters such as the apparent series resistance and the fill factor.}, language = {en} } @article{RaetzelWilkensMenzel2016, author = {R{\"a}tzel, Dennis and Wilkens, Martin and Menzel, Ralf}, title = {Gravitational properties of light}, series = {New journal of physics : the open-access journal for physics}, volume = {18}, journal = {New journal of physics : the open-access journal for physics}, publisher = {IOP Science}, address = {London}, issn = {1367-2630}, doi = {10.1088/1367-2630/18/2/023009}, pages = {1 -- 16}, year = {2016}, abstract = {The gravitational field of a laser pulse of finite lifetime, is investigated in the framework of linearized gravity. Although the effects are very small, they may be of fundamental physical interest. It is shown that the gravitational field of a linearly polarized light pulse is modulated as the norm of the corresponding electric field strength, while no modulations arise for circular polarization. In general, the gravitational field is independent of the polarization direction. It is shown that all physical effects are confined to spherical shells expanding with the speed of light, and that these shells are imprints of the spacetime events representing emission and absorption of the pulse. Nearby test particles at rest are attracted towards the pulse trajectory by the gravitational field due to the emission of the pulse, and they are repelled from the pulse trajectory by the gravitational field due to its absorption. Examples are given for the size of the attractive effect. It is recovered that massless test particles do not experience any physical effect if they are co-propagating with the pulse, and that the acceleration of massless test particles counter-propagating with respect to the pulse is four times stronger than for massive particles at rest. The similarities between the gravitational effect of a laser pulse and Newtonian gravity in two dimensions are pointed out. The spacetime curvature close to the pulse is compared to that induced by gravitational waves from astronomical sources.}, language = {en} } @phdthesis{Kondic2015, author = {Kondic, Todor}, title = {Hall-MHD Instabilities of Shear Flows in Neutron Stars}, school = {Universit{\"a}t Potsdam}, pages = {80}, year = {2015}, language = {en} }