@article{XieMeiXuetal.2021, author = {Xie, Dongjiu and Mei, Shilin and Xu, Yaolin and Quan, Ting and Haerk, Eneli and Kochovski, Zdravko and Lu, Yan}, title = {Efficient sulfur host based on yolk-shell iron oxide/sulfide-carbon nanospindles for lithium-sulfur batteries}, series = {ChemSusChem : chemistry, sustainability, energy, materials}, volume = {14}, journal = {ChemSusChem : chemistry, sustainability, energy, materials}, number = {5}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {1864-5631}, doi = {10.1002/cssc.202002731}, pages = {1404 -- 1413}, year = {2021}, abstract = {Numerous nanostructured materials have been reported as efficient sulfur hosts to suppress the problematic "shuttling" of lithium polysulfides (LiPSs) in lithium-sulfur (Li-S) batteries. However, direct comparison of these materials in their efficiency of suppressing LiPSs shuttling is challenging, owing to the structural and morphological differences between individual materials. This study introduces a simple route to synthesize a series of sulfur host materials with the same yolk-shell nanospindle morphology but tunable compositions (Fe3O4, FeS, or FeS2), which allows for a systematic investigation into the specific effect of chemical composition on the electrochemical performances of Li-S batteries. Among them, the S/FeS2-C electrode exhibits the best performance and delivers an initial capacity of 877.6 mAh g(-1) at 0.5 C with a retention ratio of 86.7 \% after 350 cycles. This approach can also be extended to the optimization of materials for other functionalities and applications.}, language = {en} } @article{QuanHaerkXuetal.2021, author = {Quan, Ting and Haerk, Eneli and Xu, Yaolin and Ahmet, Ibbi and H{\"o}hn, Christian and Mei, Shilin and Lu, Yan}, title = {Unveiling the formation of solid electrolyte interphase and its temperature dependence in "Water-in-Salt" supercapacitors}, series = {ACS applied materials \& interfaces}, volume = {13}, journal = {ACS applied materials \& interfaces}, number = {3}, publisher = {American Chemical Society}, address = {Washington}, issn = {1944-8244}, doi = {10.1021/acsami.0c19506}, pages = {3979 -- 3990}, year = {2021}, abstract = {"Water-in-salt" (WIS) electrolytes have emerged as an excellent superconcentrated ionic medium for high-power energy storage systems such as supercapacitors due to their extended working potential compared to the conventional dilute aqueous electrolyte. In this work, we have investigated the performance of WIS supercapacitors using hollow carbon nanoplates as electrodes and compared it to that based on the conventional "salt-in-water" electrolytes. Moreover, the potentiostatic electrochemical impedance spectroscopy has been employed to provide an insightful look into the charge transport properties, which also, for the first time, reveals the formation of a solid-electrolyte interphase (SEI and their temperature-dependent impedance for charge transfer and adsorption. Furthermore, the effect of temperature on the electrochemical performance of the WIS supercapacitors in the temperature range from 15 to 60 degrees C has been studied, which presents a gravimetric capacitance of 128 F g(-1) and a volumetric capacitance of 197.12 F cm(-3) at 55 degrees C compared to 87.5 F g(-1) and 134.75 F cm(-3) at 15 degrees C. The in-depth understanding about the formation of SEI layer and the electrochemical performance at different temperatures for WIS supercapacitors will assist the efforts toward designing better aqueous electrolytes for supercapacitors.}, language = {en} } @article{QuanGoubardBretescheHaerketal.2019, author = {Quan, Ting and Goubard-Bretesche, Nicolas and Haerk, Eneli and Kochovski, Zdravko and Mei, Shilin and Pinna, Nicola and Ballauff, Matthias and Lu, Yan}, title = {Highly Dispersible Hexagonal Carbon-MoS2-Carbon Nanoplates with Hollow Sandwich Structures for Supercapacitors}, series = {Chemistry - a European journal}, volume = {25}, journal = {Chemistry - a European journal}, number = {18}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {0947-6539}, doi = {10.1002/chem.201806060}, pages = {4757 -- 4766}, year = {2019}, abstract = {MoS2, a typical layered transition-metal dichalcogenide, is promising as an electrode material in supercapacitors. However, its low electrical conductivity could lead to limited capacitance if applied in electrochemical devices. Herein, a new nanostructure composed of hollow carbon-MoS2-carbon was successfully synthesized through an L-cysteine-assisted hydrothermal method by using gibbsite as a template and polydopamine as a carbon precursor. After calcination and etching of the gibbsite template, uniform hollow platelets, which were made of a sandwich-like assembly of partial graphitic carbon and two-dimensional layered MoS2 flakes, were obtained. The platelets showed excellent dispersibility and stability in water, and good electrical conductivity due to carbon provided by the calcination of polydopamine coatings. The hollow nanoplate morphology of the material provided a high specific surface area of 543 m(2) g(-1), a total pore volume of 0.677 cm(3) g(-1), and fairly small mesopores (approximate to 5.3 nm). The material was applied in a symmetric supercapacitor and exhibited a specific capacitance of 248 F g(-1) (0.12 F cm(-2)) at a constant current density of 0.1 Ag-1; thus suggesting that hollow carbon-MoS2 carbon nanoplates are promising candidate materials for supercapacitors.}, language = {en} }