@phdthesis{Trommer2001, author = {Trommer, Jochen}, title = {Distributed optimality}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-0001377}, school = {Universit{\"a}t Potsdam}, year = {2001}, abstract = {In dieser Dissertation schlage ich eine Synthese (Distributed Optimality, DO) von Optimalit{\"a}tstheorie und einem derivationellen, morphologischem Asatz, Distributed Morphology (DM; Halle \& Marantz, 1993) vor. Durch die Integration von OT in DM wird es m{\"o}glich, Ph{\"a}nomene, die in DM durch sprachspezifische Regeln oder Merkmale von lexikalischen Eintr{\"a}ge erfasst werden, auf die Interaktion von verletzbaren, universellen Constraints zur{\"u}ckzuf{\"u}hren. Andererseits leistet auch DM zwei substantielle Beitr{\"a}ge zu DO, Lokalit{\"a}t und Impoverishment. Lokalit{\"a}t erlaubt eine formal einfache Interpretation von DO, w{\"a}hrend sich Impoverishment als unverzichtbar erweist, um Kongruenz-Morphologie ad{\"a}quat zu beschreiben. Die empirische Grundlage der Arbeit sind die komplexen Kongruenzsysteme von genetisch unterschiedlichen Sprachen. Der theoretische Schwerpunkt liegt in zwei Bereichen: Erstens, sogenannte Direkt/Invers-Markierung, f{\"u}r die gezeigt wird, dass eine Behandlung durch Constraints {\"u}ber Merkmalsrealisierung am angemessensten ist. Zweitens, die Effekte von Abfolge-Constraints, die den Satus von Affixen als Pr{\"a}fixe und Suffixe sowie ihre relative Reihenfolge regeln. Eine konkrete Typologie f{\"u}r die Abfolge von Kongruenz-Affixen auf der Basis von OT-Constraints wird vorgeschlagen.}, language = {en} } @phdthesis{Kukula2001, author = {Kukula, Hildegard}, title = {Lineare und verzweigte Blockcopolymere aus Polypeptiden und synthetischen Polymeren}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-0000040}, school = {Universit{\"a}t Potsdam}, year = {2001}, abstract = {Die vorliegende Arbeit besch{\"a}ftigt sich mit der Synthese und den Eigenschaften von linearen und verzweigten amphiphilen Polypeptid-Blockcopolymeren. Die Frage nach dem Einfluss der Topologie und Konformation der Blockcopolymere auf die supramolekularen und kolloidalen Eigenschaften bildete einen wichtigen Aspekt bei den Untersuchungen. Die Blockcopolymere wurden nach einem mehrstufigen Reaktionsschema durch Kombination von anionischer und ring{\"o}ffnender Polymerisation von Aminos{\"a}uren-N-Carboxyanhydriden (NCA) synthetisiert. Die Untersuchung der Polypeptid-Blockcopolymere hinsichtlich ihres Aggregationsverhaltens in fester Phase sowie in verd{\"u}nnter w{\"a}ssriger L{\"o}sung erfolgte mittels Streumethoden (SAXS, WAXS, DLS) sowie abbildender Methoden (TEM). Durch Einsatz der Blockcopolymere als polymere Stabilisatoren in der Emulsionspolymerisation wurden Oberfl{\"a}chen funktionalisierte Latizes erhalten. Als Beispiel f{\"u}r eine pharmazeutische Anwendung wurden biovertr{\"a}gliche Polypeptid-Blockcopolymere als Wirkstoff-Tr{\"a}gersysteme in der Krebstherapie eingesetzt.}, language = {de} } @phdthesis{Yin2009, author = {Yin, Chunhong}, title = {The interplay of nanostructure and efficiency of polymer solar cells}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-29054}, school = {Universit{\"a}t Potsdam}, year = {2009}, abstract = {The aim of this thesis is to achieve a deep understanding of the working mechanism of polymer based solar cells and to improve the device performance. Two types of the polymer based solar cells are studied here: all-polymer solar cells comprising macromolecular donors and acceptors based on poly(p-phenylene vinylene) and hybrid cells comprising a PPV copolymer in combination with a novel small molecule electron acceptor. To understand the interplay between morphology and photovoltaic properties in all-polymer devices, I compared the photocurrent characteristics and excited state properties of bilayer and blend devices with different nano-morphology, which was fine tuned by using solvents with different boiling points. The main conclusion from these complementary measurements was that the performance-limiting step is the field-dependent generation of free charge carriers, while bimolecular recombination and charge extraction do not compromise device performance. These findings imply that the proper design of the donor-acceptor heterojunction is of major importance towards the goal of high photovoltaic efficiencies. Regarding polymer-small molecular hybrid solar cells I combined the hole-transporting polymer M3EH-PPV with a novel Vinazene-based electron acceptor. This molecule can be either deposited from solution or by thermal evaporation, allowing for a large variety of layer architectures to be realized. I then demonstrated that the layer architecture has a large influence on the photovoltaic properties. Solar cells with very high fill factors of up to 57 \% and an open circuit voltage of 1V could be achieved by realizing a sharp and well-defined donor-acceptor heterojunction. In the past, fill factors exceeding 50 \% have only been observed for polymers in combination with soluble fullerene-derivatives or nanocrystalline inorganic semiconductors as the electron-accepting component. The finding that proper processing of polymer-vinazene devices leads to similar high values is a major step towards the design of efficient polymer-based solar cells.}, language = {en} } @article{WeberTierschUnterlassetal.2011, author = {Weber, Nancy and Tiersch, Brigitte and Unterlass, Miriam M. and Heilig, Anneliese and Tauer, Klaus}, title = {"Schizomorphic" Emulsion Copolymerization Particles}, series = {Macromolecular rapid communications}, volume = {32}, journal = {Macromolecular rapid communications}, number = {23}, publisher = {Wiley-Blackwell}, address = {Malden}, issn = {1022-1336}, doi = {10.1002/marc.201100491}, pages = {1925 -- 1929}, year = {2011}, abstract = {Cryo-electron microscopy, atomic force microscopy, and light microscopy investigations provide experimental evidence that amphiphilic emulsion copolymerization particles change their morphology in dependence on concentration. The shape of the particles is spherical at solids content above 1\%, but it changes to rod-like, ring-like, and web-like structures at lower concentrations. In addition, the shape and morphology of these particles at low concentrations are not fixed but very flexible and vary with time between spheres, flexible pearlnecklace structures, and stretched rods.}, language = {en} } @phdthesis{Ivakov2011, author = {Ivakov, Alexander}, title = {Metabolic interactions in leaf development in Arabidopsis thaliana}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-59730}, school = {Universit{\"a}t Potsdam}, year = {2011}, abstract = {Das Wachstum und {\"U}berleben von Pflanzen basiert auf der Photosynthese in den Bl{\"a}ttern. Diese beinhaltet die Aufnahme von Kohlenstoffdioxid aus der Atmosph{\"a}re und das simultane Einfangen von Lichtenergie zur Bildung organischer Molek{\"u}le. Diese werden nach dem Eintritt in den Metabolismus in viele andere Komponenten umgewandelt, welche die Grundlage f{\"u}r die Zunahme der Biomasse bilden. Bl{\"a}tter sind Organe, die auf die Fixierung von Kohlenstoffdioxid spezialisiert sind. Die Funktionen der Bl{\"a}tter beinhalten vor allem die Optimierung und Feinregulierung vieler Prozesse, um eine effektive Nutzung von Ressourcen und eine maximale Photosynthese zu gew{\"a}hrleisten. Es ist bekannt, dass sich die Morphologie der Bl{\"a}tter den Wachstumsbedingungen der Pflanze anpasst und eine wichtige Rolle bei der Optimierung der Photosynthese spielt. Trotzdem ist die Regulation dieser Art der Anpassung bisher nicht verstanden. Die allgemeine Zielsetzung dieser vorliegenden Arbeit ist das Verst{\"a}ndnis wie das Wachstum und die Morphologie der Bl{\"a}tter im Modellorganismus Arabidopsis thaliana reguliert werden. Besondere Aufmerksamkeit wurde hierbei der M{\"o}glichkeit geschenkt, dass es interne metabolische Signale in der Pflanze geben k{\"o}nnte, die das Wachstum und die Entwicklung von Bl{\"a}ttern beeinflussen. Um diese Fragestellung zu untersuchen, muss das Wachstum und die Entwicklung von Bl{\"a}ttern oberhalb des Levels des einzelnen Organs und im Kontext der gesamten Pflanze betrachtet werden, weil Bl{\"a}tter nicht eigenst{\"a}ndig wachsen, sondern von Ressourcen und regulatorischen Einfl{\"u}ssen der ganzen Pflanze abh{\"a}ngig sind. Aufgrund der Komplexit{\"a}t dieser Fragestellung wurden drei komplement{\"a}re Ans{\"a}tze durchgef{\"u}hrt. Im ersten und spezifischsten Ansatz wurde untersucht ob eine flussabw{\"a}rts liegende Komponente des Zucker-Signalwegs, Trehalose-6-Phosphat (Tre-6-P), das Blattwachstum und die Blattentwicklung beinflussen kann. Um diese Frage zu beantworten wurden transgene Arabidopsis-Linien mit einem gest{\"o}rten Gehalt von Tre-6-P durch die Expression von bakteriellen Proteinen die in dem metabolismus von trehalose beteiligt sind. Die Pflanzen-Linien wurden unter Standard-Bendingungen in Erde angebaut und ihr Metabolismus und ihre Blattmorphologie untersucht. Diese Experimente f{\"u}hrten auch zu einem unerwarteten Projekt hinsichtlich einer m{\"o}glichen Rolle von Tre-6-P in der Regulation der Stomata. In einem zweiten, allgemeineren Ansatz wurde untersucht, ob {\"A}nderungen im Zucker-Gehalt der Pflanzen die Morphogenese der Bl{\"a}tter als Antwort auf Licht beeinflussen. Dazu wurden eine Reihe von Mutanten, die im Zentralmetabolismus beeintr{\"a}chtigt sind, in derselben Lichtbedingung angezogen und bez{\"u}glich ihrer Blattmorphologie analysiert. In einem dritten noch allgemeineren Ansatz wurde die nat{\"u}rliche Variation von morphologischen Auspr{\"a}gungen der Bl{\"a}tter und Rosette anhand von wilden Arabidopsis {\"O}kotypen untersucht, um zu verstehen wie sich die Blattmorphologie auf die Blattfunktion und das gesamte Pflanzenwachstum auswirkt und wie unterschiedliche Eigenschaften miteinander verkn{\"u}pft sind. Das Verh{\"a}ltnis der Blattanzahl zum Gesamtwachstum der Pflanze und Blattgr{\"o}ße wurde gesondert weiter untersucht durch eine Normalisierung der Blattanzahl auf das Frischgewicht der Rosette, um den Parameter „leafing Intensity" abzusch{\"a}tzen. Leafing Intensity integrierte Blattanzahl, Blattgr{\"o}ße und gesamtes Rosettenwachstum in einer Reihe von Kompromiss-Interaktionen, die in einem Wachstumsvorteil resultieren, wenn Pflanzen weniger, aber gr{\"o}ßere Bl{\"a}tter pro Einheit Biomasse ausbilden. Dies f{\"u}hrte zu einem theoretischen Ansatz in dem ein einfaches allometrisch mathematisches Modell konstruiert wurde, um Blattanzahl, Blattgr{\"o}ße und Pflanzenwachstum im Kontext der gesamten Pflanze Arabidopsis zu verkn{\"u}pfen.}, language = {en} } @article{OttHoehle2011, author = {Ott, Susan and H{\"o}hle, Barbara}, title = {Verb inflection in German-learning children with typical and atypical language acquisition}, series = {Journal of child language}, volume = {40}, journal = {Journal of child language}, number = {1}, publisher = {Cambridge University Press}, address = {New York}, issn = {0305-0009}, doi = {10.1017/S030500091200027X}, pages = {169 -- 192}, year = {2011}, abstract = {Previous research has shown that high phonotactic frequencies facilitate the production of regularly inflected verbs in English-learning children with specific language impairment (SLI) but not with typical development (TD). We asked whether this finding can be replicated for German, a language with a much more complex inflectional verb paradigm than English. Using an elicitation task, the production of inflected nonce verb forms (3rd person singular with - t suffix) with either high-or low-frequency subsyllables was tested in sixteen German-learning children with SLI (ages 4;1-5;1), sixteen TD-children matched for chronological age (CA) and fourteen TD-children matched for verbal age (VA) (ages 3;0-3;11). The findings revealed that children with SLI, but not CA-or VA-children, showed differential performance between the two types of verbs, producing more inflectional errors when the verb forms resulted in low-frequency subsyllables than when they resulted in high-frequency subsyllables, replicating the results from English-learning children.}, language = {en} } @article{TurnerPingelSteyrleuthneretal.2011, author = {Turner, Sarah T. and Pingel, Patrick and Steyrleuthner, Robert and Crossland, Edward J. W. and Ludwigs, Sabine and Neher, Dieter}, title = {Quantitative analysis of bulk heterojunction films using linear absorption spectroscopy and solar cell performance}, series = {Advanced functional materials}, volume = {21}, journal = {Advanced functional materials}, number = {24}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {1616-301X}, doi = {10.1002/adfm.201101583}, pages = {4640 -- 4652}, year = {2011}, abstract = {A fundamental understanding of the relationship between the bulk morphology and device performance is required for the further development of bulk heterojunction organic solar cells. Here, non-optimized (chloroform cast) and nearly optimized (solvent-annealed o-dichlorobenzene cast) P3HT:PCBM blend films treated over a range of annealing temperatures are studied via optical and photovoltaic device measurements. Parameters related to the P3HT aggregate morphology in the blend are obtained through a recently established analytical model developed by F. C. Spano for the absorption of weakly interacting H-aggregates. Thermally induced changes are related to the glass transition range of the blend. In the chloroform prepared devices, the improvement in device efficiency upon annealing within the glass transition range can be attributed to the growth of P3HT aggregates, an overall increase in the percentage of chain crystallinity, and a concurrent increase in the hole mobilities. Films treated above the glass transition range show an increase in efficiency and fill factor not only associated with the change in chain crystallinity, but also with a decrease in the energetic disorder. On the other hand, the properties of the P3HT phase in the solvent-annealed o-dichlorobenzene cast blends are almost indistinguishable from those of the corresponding pristine P3HT layer and are only weakly affected by thermal annealing. Apparently, slow drying of the blend allows the P3HT chains to crystallize into large domains with low degrees of intra- and interchain disorder. This morphology appears to be most favorable for the efficient generation and extraction of charges.}, language = {en} } @article{SchubertDolfenFrischetal.2012, author = {Schubert, Marcel and Dolfen, Daniel and Frisch, Johannes and Roland, Steffen and Steyrleuthner, Robert and Stiller, Burkhard and Chen, Zhihua and Scherf, Ullrich and Koch, Norbert and Facchetti, Antonio and Neher, Dieter}, title = {Influence of aggregation on the performance of All-Polymer Solar Cells containing Low-Bandgap Naphthalenediimide Copolymers}, series = {dvanced energy materials}, volume = {2}, journal = {dvanced energy materials}, number = {3}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {1614-6832}, doi = {10.1002/aenm.201100601}, pages = {369 -- 380}, year = {2012}, abstract = {The authors present efficient all-polymer solar cells comprising two different low-bandgap naphthalenediimide (NDI)-based copolymers as acceptors and regioregular P3HT as the donor. It is shown that these naphthalene copolymers have a strong tendency to preaggregate in specific organic solvents, and that preaggregation can be completely suppressed when using suitable solvents with large and highly polarizable aromatic cores. Organic solar cells prepared from such nonaggregated polymer solutions show dramatically increased power conversion efficiencies of up to 1.4\%, which is mainly due to a large increase of the short circuit current. In addition, optimized solar cells show remarkable high fill factors of up to 70\%. The analysis of the blend absorbance spectra reveals a surprising anticorrelation between the degree of polymer aggregation in the solid P3HT:NDI copolymer blends and their photovoltaic performance. Scanning near-field optical microscopy (SNOM) and atomic force microscopy (AFM) measurements reveal important information on the blend morphology. It is shown that films with high degree of aggregation and low photocurrents exhibit large-scale phase-separation into rather pure donor and acceptor domains. It is proposed that, by suppressing the aggregation of NDI copolymers at the early stage of film formation, the intermixing of the donor and acceptor component is improved, thereby allowing efficient harvesting of photogenerated excitons at the donoracceptor heterojunction.}, language = {en} } @article{SauterKratzLendlein2013, author = {Sauter, Tilman and Kratz, Karl and Lendlein, Andreas}, title = {Pore-size distribution controls shape-memory properties on the macro- and microscale of polymeric foams}, series = {Macromolecular chemistry and physics}, volume = {214}, journal = {Macromolecular chemistry and physics}, number = {11}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {1022-1352}, doi = {10.1002/macp.201300062}, pages = {1184 -- 1188}, year = {2013}, abstract = {Open porous foams with identical foam density but different pore-size distributions (bimodal or monomodal) are prepared from a shape-memory polyetherurethane (PEU) by thermally induced phase separation. The shape-memory effect of the two PEU foams is explored by cyclic thermomechanical compression tests and microstructural analysis. The obtained results reveal that the PEU foam with a bimodal pore-size distribution exhibits an increased shape-recovery under stress-free conditions, both on the macro- (foam level) as well as the microscale (pore level). While bimodal pore-size distributions induce microscale bending during compression, buckling occurs in foams with monomodal pore-size distributions, leading to both a reduced and delayed shape recovery.}, language = {en} } @article{GardinerKocyanMotesetal.2013, author = {Gardiner, Lauren M. and Kocyan, Alexander and Motes, Martin and Roberts, David L. and Emerson, Brent C.}, title = {Molecular phylogenetics of Vanda and related genera (Orchidaceae)}, series = {Botanical journal of the Linnean Society}, volume = {173}, journal = {Botanical journal of the Linnean Society}, number = {4}, publisher = {Wiley-Blackwell}, address = {Hoboken}, issn = {0024-4074}, doi = {10.1111/boj.12102}, pages = {549 -- 572}, year = {2013}, abstract = {The genus Vanda and its affiliated taxa are a diverse group of horticulturally important species of orchids occurring mainly in South-East Asia, for which generic limits are poorly defined. Here, we present a molecular study using sequence data from three plastid DNA regions. It is shown that Vanda s.l. forms a clade containing approximately 73 species, including the previously accepted genera Ascocentrum, Euanthe, Christensonia, Neofinetia and Trudelia, and the species Aerides flabellata. Resolution of the phylogenetic relationships of species in Vanda s.l. is relatively poor, but existing morphological classifications for Vanda are incongruent with the results produced. Some novel species relationships are revealed, and a new morphological sectional classification is proposed based on support for these groupings and corresponding morphological characters shared by taxa and their geographical distributions. The putative occurrence of multiple pollination syndromes in this group of taxa, combined with complex biogeographical history of the South-East Asian region, is discussed in the context of these results.(c) 2013 The Linnean Society of London, Botanical Journal of the Linnean Society, 2013, 173, 549-572.}, language = {en} } @misc{OttHoehle2013, author = {Ott, Susan and H{\"o}hle, Barbara}, title = {Verb inflection in German-learning children with typical and atypical language acquisition}, series = {Journal of Child Language}, journal = {Journal of Child Language}, number = {530}, issn = {1866-8364}, doi = {10.1017/S030500091200027X}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-416475}, pages = {24}, year = {2013}, abstract = {Previous research has shown that high phonotactic frequencies facilitate the production of regularly inflected verbs in English-learning children with specific language impairment (SLI) but not with typical development (TD). We asked whether this finding can be replicated for German, a language with a much more complex inflectional verb paradigm than English. Using an elicitation task, the production of inflected nonce verb forms (3 rd person singular with -t suffix) with either high- or low-frequency subsyllables was tested in sixteen German-learning children with SLI (ages 4;1-5 ;1), sixteen TD-children matched for chronological age (CA) and fourteen TD- children matched for verbal age (VA) (ages 3;0-3 ;11). The findings revealed that children with SLI, but not CA- or VA-children, showed differential performance between the two types of verbs, producing more inflectional errors when the verb forms resulted in low-frequency subsyllables than when they resulted in high-frequency subsyllables, replicating the results from English-learning children.}, language = {en} } @misc{JungingerKuebelSchacheretal.2013, author = {Junginger, Mathias and K{\"u}bel, Christian and Schacher, Felix H. and M{\"u}ller, Axel H. E. and Taubert, Andreas}, title = {Crystal structure and chemical composition of biomimetic calcium phosphate nanofibers}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-95176}, pages = {11301 -- 11308}, year = {2013}, abstract = {Calcium phosphate nanofibers with a diameter of only a few nanometers and a cotton-ball-like aggregate morphology have been reported several times in the literature. Although fiber formation seems reproducible in a variety of conditions, the crystal structure and chemical composition of the fibers have been elusive. Using scanning transmission electron microscopy, low dose electron (nano)diffraction, energy-dispersive X-ray spectroscopy, and energy-filtered transmission electron microscopy, we have assigned crystal structures and chemical compositions to the fibers. Moreover, we demonstrate that the mineralization process yields true polymer/calcium phosphate hybrid materials where the block copolymer template is closely associated with the calcium phosphate.}, language = {en} } @phdthesis{Pingel2013, author = {Pingel, Patrick}, title = {Morphology, charge transport properties, and molecular doping of thiophene-based organic semiconducting thin films}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-69805}, school = {Universit{\"a}t Potsdam}, year = {2013}, abstract = {Organic semiconductors combine the benefits of organic materials, i.e., low-cost production, mechanical flexibility, lightweight, and robustness, with the fundamental semiconductor properties light absorption, emission, and electrical conductivity. This class of material has several advantages over conventional inorganic semiconductors that have led, for instance, to the commercialization of organic light-emitting diodes which can nowadays be found in the displays of TVs and smartphones. Moreover, organic semiconductors will possibly lead to new electronic applications which rely on the unique mechanical and electrical properties of these materials. In order to push the development and the success of organic semiconductors forward, it is essential to understand the fundamental processes in these materials. This thesis concentrates on understanding how the charge transport in thiophene-based semiconductor layers depends on the layer morphology and how the charge transport properties can be intentionally modified by doping these layers with a strong electron acceptor. By means of optical spectroscopy, the layer morphologies of poly(3-hexylthiophene), P3HT, P3HT-fullerene bulk heterojunction blends, and oligomeric polyquaterthiophene, oligo-PQT-12, are studied as a function of temperature, molecular weight, and processing conditions. The analyses rely on the decomposition of the absorption contributions from the ordered and the disordered parts of the layers. The ordered-phase spectra are analyzed using Spano's model. It is figured out that the fraction of aggregated chains and the interconnectivity of these domains is fundamental to a high charge carrier mobility. In P3HT layers, such structures can be grown with high-molecular weight, long P3HT chains. Low and medium molecular weight P3HT layers do also contain a significant amount of chain aggregates with high intragrain mobility; however, intergranular connectivity and, therefore, efficient macroscopic charge transport are absent. In P3HT-fullerene blend layers, a highly crystalline morphology that favors the hole transport and the solar cell efficiency can be induced by annealing procedures and the choice of a high-boiling point processing solvent. Based on scanning near-field and polarization optical microscopy, the morphology of oligo-PQT-12 layers is found to be highly crystalline which explains the rather high field-effect mobility in this material as compared to low molecular weight polythiophene fractions. On the other hand, crystalline dislocations and grain boundaries are identified which clearly limit the charge carrier mobility in oligo-PQT-12 layers. The charge transport properties of organic semiconductors can be widely tuned by molecular doping. Indeed, molecular doping is a key to highly efficient organic light-emitting diodes and solar cells. Despite this vital role, it is still not understood how mobile charge carriers are induced into the bulk semiconductor upon the doping process. This thesis contains a detailed study of the doping mechanism and the electrical properties of P3HT layers which have been p-doped by the strong molecular acceptor tetrafluorotetracyanoquinodimethane, F4TCNQ. The density of doping-induced mobile holes, their mobility, and the electrical conductivity are characterized in a broad range of acceptor concentrations. A long-standing debate on the nature of the charge transfer between P3HT and F4TCNQ is resolved by showing that almost every F4TCNQ acceptor undergoes a full-electron charge transfer with a P3HT site. However, only 5\% of these charge transfer pairs can dissociate and induce a mobile hole into P3HT which contributes electrical conduction. Moreover, it is shown that the left-behind F4TCNQ ions broaden the density-of-states distribution for the doping-induced mobile holes, which is due to the longrange Coulomb attraction in the low-permittivity organic semiconductors.}, language = {en} } @article{LorenzHeideBurchert2014, author = {Lorenz, Antje and Heide, Judith and Burchert, Frank}, title = {Compound naming in aphasia: effects of complexity, part of speech, and semantic transparency}, series = {Language, cognition and neuroscience}, volume = {29}, journal = {Language, cognition and neuroscience}, number = {1}, publisher = {Routledge, Taylor \& Francis Group}, address = {Abingdon}, issn = {2327-3798}, doi = {10.1080/01690965.2013.766357}, pages = {88 -- 106}, year = {2014}, language = {en} } @article{SchoeneSchulzRichauetal.2014, author = {Sch{\"o}ne, Anne-Christin and Schulz, Burkhard and Richau, Klaus and Kratz, Karl and Lendlein, Andreas}, title = {Characterization of Langmuir films prepared from copolyesterurethanes based on oligo(omega-pentadecalactone) and oligo(epsilon-caprolactone)segments}, series = {Macromolecular chemistry and physics}, volume = {215}, journal = {Macromolecular chemistry and physics}, number = {24}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {1022-1352}, doi = {10.1002/macp.201400377}, pages = {2437 -- 2445}, year = {2014}, abstract = {A series of multiblock copolymers (PDLCL) synthesized from oligo(omega-pentadecalactone) diol (OPDL) and oligo(epsilon-caprolactone) diol (OCL), which are linked by 2,2(4), 4-trimethyl-hexamethylene diisocyanate (TMDI), is investigated by the Langmuir monolayer technique at the air-water interface. Brewster angle microscopy (BAM) and spectroscopic ellipsometry are employed to characterize the polymer film morphologies in situ. PDLCL containing >= 40 wt\% OCL segments form homogeneous Langmuir monofilms after spreading. The film elasticity modulus decreases with increasing amounts of OPDL segments in the copolymer. In contrast, the OCL-free polyesterurethane OPDL-TMDI cannot be spread to monomolecular films on the water surface properly, and movable slabs are observed by BAM even at low surface pressures. The results of the in situ morphological characterization clearly show that essential information concerning the reliability of Langmuir monolayer degradation (LMD) experiments cannot be obtained from the evaluation of the pi-A isotherms only. Consequently, in situ morphological characterization turns out to be indispensable for characterization of Langmuir layers before LMD experiments.}, language = {en} } @article{ClahsenRothweilerSterneretal.2014, author = {Clahsen, Harald and Rothweiler, Monika and Sterner, Franziska and Chilla, Solveig}, title = {Linguistic markers of specific language impairment in bilingual children: the case of verb morphology}, series = {Clinical linguistics \& phonetics}, volume = {28}, journal = {Clinical linguistics \& phonetics}, number = {9}, publisher = {Taylor \& Francis Group}, address = {London}, issn = {0269-9206}, doi = {10.3109/02699206.2014.886726}, pages = {709 -- 721}, year = {2014}, language = {en} } @article{AlbrechtVandewalTumblestonetal.2014, author = {Albrecht, Steve and Vandewal, Koen and Tumbleston, John R. and Fischer, Florian S. U. and Douglas, Jessica D. and Frechet, Jean M. J. and Ludwigs, Sabine and Ade, Harald W. and Salleo, Alberto and Neher, Dieter}, title = {On the efficiency of charge transfer state splitting in polymer: Fullerene solar cells}, series = {Advanced materials}, volume = {26}, journal = {Advanced materials}, number = {16}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {0935-9648}, doi = {10.1002/adma.201305283}, pages = {2533 -- 2539}, year = {2014}, language = {en} } @misc{WischkeLendlein2016, author = {Wischke, Christian and Lendlein, Andreas}, title = {Functional nanocarriers by miniaturization of polymeric materials}, series = {Nanomedicine}, volume = {11}, journal = {Nanomedicine}, publisher = {Future Medicine}, address = {London}, issn = {1743-5889}, doi = {10.2217/nnm.16.45}, pages = {1507 -- 1509}, year = {2016}, language = {en} } @misc{FarhyVerissimoClahsen2016, author = {Farhy, Yael and Ver{\´i}ssimo, Joao Marques and Clahsen, Harald}, title = {Universal and particular in morphological processing}, series = {Postprints der Universit{\"a}t Potsdam : Humanwissenschaftliche Reihe}, journal = {Postprints der Universit{\"a}t Potsdam : Humanwissenschaftliche Reihe}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-412541}, pages = {9}, year = {2016}, abstract = {Do properties of individual languages shape the mechanisms by which they are processed? By virtue of their non-concatenative morphological structure, the recognition of complex words in Semitic languages has been argued to rely strongly on morphological information and on decomposition into root and pattern constituents. Here, we report results from a masked priming experiment in Hebrew in which we contrasted verb forms belonging to two morphological classes, Paal and Piel, which display similar properties, but crucially differ on whether they are extended to novel verbs. Verbs from the open-class Piel elicited familiar root priming effects, but verbs from the closed-class Paal did not. Our findings indicate that, similarly to other (e.g., Indo-European) languages, down-to-the-root decomposition in Hebrew does not apply to stems of non-productive verbal classes. We conclude that the Semitic word processor is less unique than previously thought: Although it operates on morphological units that are combined in a non-linear way, it engages the same universal mechanisms of storage and computation as those seen in other languages.}, language = {en} } @misc{LeminenLehtonenBozicetal.2016, author = {Leminen, Alina and Lehtonen, Minna and Bozic, Mirjana and Clahsen, Harald}, title = {Editorial}, series = {Postprints der Universit{\"a}t Potsdam : Humanwissenschaftliche Reihe}, journal = {Postprints der Universit{\"a}t Potsdam : Humanwissenschaftliche Reihe}, number = {441}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-407243}, pages = {3}, year = {2016}, abstract = {kein abstract vorhanden}, language = {en} }