@misc{ŚlęzakMetzlerMagdziarz2018, author = {Ślęzak, Jakub and Metzler, Ralf and Magdziarz, Marcin}, title = {Superstatistical generalised Langevin equation}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-409315}, pages = {25}, year = {2018}, abstract = {Recent advances in single particle tracking and supercomputing techniques demonstrate the emergence of normal or anomalous, viscoelastic diffusion in conjunction with non-Gaussian distributions in soft, biological, and active matter systems. We here formulate a stochastic model based on a generalised Langevin equation in which non-Gaussian shapes of the probability density function and normal or anomalous diffusion have a common origin, namely a random parametrisation of the stochastic force. We perform a detailed analysis demonstrating how various types of parameter distributions for the memory kernel result in exponential, power law, or power-log law tails of the memory functions. The studied system is also shown to exhibit a further unusual property: the velocity has a Gaussian one point probability density but non-Gaussian joint distributions. This behaviour is reflected in the relaxation from a Gaussian to a non-Gaussian distribution observed for the position variable. We show that our theoretical results are in excellent agreement with stochastic simulations.}, language = {en} } @article{ŚlęzakMetzlerMagdziarz2018, author = {Ślęzak, Jakub and Metzler, Ralf and Magdziarz, Marcin}, title = {Superstatistical generalised Langevin equation}, series = {New Journal of Physics}, volume = {20}, journal = {New Journal of Physics}, number = {023026}, publisher = {Deutsche Physikalische Gesellschaft / Institute of Physics}, address = {Bad Honnef und London}, issn = {1367-2630}, doi = {10.1088/1367-2630/aaa3d4}, pages = {1 -- 25}, year = {2018}, abstract = {Recent advances in single particle tracking and supercomputing techniques demonstrate the emergence of normal or anomalous, viscoelastic diffusion in conjunction with non-Gaussian distributions in soft, biological, and active matter systems. We here formulate a stochastic model based on a generalised Langevin equation in which non-Gaussian shapes of the probability density function and normal or anomalous diffusion have a common origin, namely a random parametrisation of the stochastic force. We perform a detailed analysis demonstrating how various types of parameter distributions for the memory kernel result in exponential, power law, or power-log law tails of the memory functions. The studied system is also shown to exhibit a further unusual property: the velocity has a Gaussian one point probability density but non-Gaussian joint distributions. This behaviour is reflected in the relaxation from a Gaussian to a non-Gaussian distribution observed for the position variable. We show that our theoretical results are in excellent agreement with stochastic simulations.}, language = {en} } @article{OeztuerkMarwanvonSpechtetal.2018, author = {{\"O}zt{\"u}rk, Ugur and Marwan, Norbert and von Specht, Sebastian and Korup, Oliver and Jensen, J.}, title = {A new centennial sea-level record for Antalya, Eastern Mediterranean}, series = {Journal of geophysical research-oceans}, volume = {123}, journal = {Journal of geophysical research-oceans}, number = {7}, publisher = {American Geophysical Union}, address = {Washington}, issn = {2169-9275}, doi = {10.1029/2018JC013906}, pages = {4503 -- 4517}, year = {2018}, abstract = {Quantitative estimates of sea-level rise in the Mediterranean Basin become increasingly accurate thanks to detailed satellite monitoring. However, such measuring campaigns cover several years to decades, while longer-term sea-level records are rare for the Mediterranean. We used a data archeological approach to reanalyze monthly mean sea-level data of the Antalya-I (1935-1977) tide gauge to fill this gap. We checked the accuracy and reliability of these data before merging them with the more recent records of the Antalya-II (1985-2009) tide gauge, accounting for an eight-year hiatus. We obtain a composite time series of monthly and annual mean sea levels spanning some 75 years, providing the longest record for the eastern Mediterranean Basin, and thus an essential tool for studying the region's recent sea-level trends. We estimate a relative mean sea-level rise of 2.2 ± 0.5 mm/year between 1935 and 2008, with an annual variability (expressed here as the standard deviation of the residuals, σresiduals = 41.4 mm) above that at the closest tide gauges (e.g., Thessaloniki, Greece, σresiduals = 29.0 mm). Relative sea-level rise accelerated to 6.0 ± 1.5 mm/year at Antalya-II; we attribute roughly half of this rate (~3.6 mm/year) to tectonic crustal motion and anthropogenic land subsidence. Our study highlights the value of data archeology for recovering and integrating historic tide gauge data for long-term sea-level and climate studies.}, language = {en} } @phdthesis{Oeztuerk2018, author = {{\"O}zt{\"u}rk, Ugur}, title = {Learning more to predict landslides}, doi = {10.25932/publishup-42643}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-426439}, school = {Universit{\"a}t Potsdam}, pages = {xxi, 104}, year = {2018}, abstract = {Landslides are frequent natural hazards in rugged terrain, when the resisting frictional force of the surface of rupture yields to the gravitational force. These forces are functions of geological and morphological factors, such as angle of internal friction, local slope gradient or curvature, which remain static over hundreds of years; whereas more dynamic triggering events, such as rainfall and earthquakes, compromise the force balance by temporarily reducing resisting forces or adding transient loads. This thesis investigates landslide distribution and orientation due to landslide triggers (e.g. rainfall) at different scales (6-4∙10^5 km^2) and aims to link rainfall movement with the landslide distribution. It additionally explores the local impacts of the extreme rainstorms on landsliding and the role of precursory stability conditions that could be induced by an earlier trigger, such as an earthquake. Extreme rainfall is a common landslide trigger. Although several studies assessed rainfall intensity and duration to study the distribution of thus triggered landslides, only a few case studies quantified spatial rainfall patterns (i.e. orographic effect). Quantifying the regional trajectories of extreme rainfall could aid predicting landslide prone regions in Japan. To this end, I combined a non-linear correlation metric, namely event synchronization, and radial statistics to assess the general pattern of extreme rainfall tracks over distances of hundreds of kilometers using satellite based rainfall estimates. Results showed that, although the increase in rainfall intensity and duration positively correlates with landslide occurrence, the trajectories of typhoons and frontal storms were insufficient to explain landslide distribution in Japan. Extreme rainfall trajectories inclined northwestwards and were concentrated along some certain locations, such as coastlines of southern Japan, which was unnoticed in the landslide distribution of about 5000 rainfall-triggered landslides. These landslides seemed to respond to the mean annual rainfall rates. Above mentioned findings suggest further investigation on a more local scale to better understand the mechanistic response of landscape to extreme rainfall in terms of landslides. On May 2016 intense rainfall struck southern Germany triggering high waters and landslides. The highest damage was reported at the Braunsbach, which is located on the tributary-mouth fan formed by the Orlacher Bach. Orlacher Bach is a ~3 km long creek that drains a catchment of about ~6 km^2. I visited this catchment in June 2016 and mapped 48 landslides along the creek. Such high landslide activity was not reported in the nearby catchments within ~3300 km^2, despite similar rainfall intensity and duration based on weather radar estimates. My hypothesis was that several landslides were triggered by rainfall-triggered flash floods that undercut hillslope toes along the Orlacher Bach. I found that morphometric features such as slope and curvature play an important role in landslide distribution on this micro scale study site (<10 km^2). In addition, the high number of landslides along the Orlacher Bach could also be boosted by accumulated damages on hillslopes due karst weathering over longer time scales. Precursory damages on hillslopes could also be induced by past triggering events that effect landscape evolution, but this interaction is hard to assess independently from the latest trigger. For example, an earthquake might influence the evolution of a landscape decades long, besides its direct impacts, such as landslides that follow the earthquake. Here I studied the consequences of the 2016 Kumamoto Earthquake (MW 7.1) that triggered some 1500 landslides in an area of ~4000 km^2 in central Kyushu, Japan. Topography, i.e. local slope and curvature, both amplified and attenuated seismic waves, thus controlling the failure mechanism of those landslides (e.g. progressive). I found that topography fails in explaining the distribution and the preferred orientation of the landslides after the earthquake; instead the landslides were concentrated around the northeast of the rupture area and faced mostly normal to the rupture plane. This preferred location of the landslides was dominated mainly by the directivity effect of the strike-slip earthquake, which is the propagation of wave energy along the fault in the rupture direction; whereas amplitude variations of the seismic radiation altered the preferred orientation. I suspect that the earthquake directivity and the asymmetry of seismic radiation damaged hillslopes at those preferred locations increasing landslide susceptibility. Hence a future weak triggering event, e.g. scattered rainfall, could further trigger landslides at those damaged hillslopes.}, language = {en} } @article{OezerScheffler2018, author = {{\"O}zer, Aydan and Scheffler, Christiane}, title = {Affinity to host population stimulates physical growth in adult offspring of Turkish migrants in Germany}, series = {Journal of biological and clinical anthropology}, volume = {74}, journal = {Journal of biological and clinical anthropology}, number = {5}, publisher = {Schweizerbart}, address = {Stuttgart}, issn = {0003-5548}, doi = {10.1127/anthranz/2018/0825}, pages = {359 -- 364}, year = {2018}, abstract = {Because of political conflicts and climate change, migration will be increased worldwide and integration in host societies is a challenge also for migrants. We hypothesize that migrants, who take up the challenge in a new social environment are taller than migrants who do not pose this challenge. We analyze by a questionnaire possible social, nutritional and ethnic influencing factors to body height (BH) of adult offspring of Turkish migrants (n = 82, 39 males) aged from 18 to 34 years (mean age 24.6 years). The results of multiple regression (downward selection) show that the more a male adult offspring of Turkish migrants feels like belonging to the Turkish culture, the smaller he is (95\% CI, -3.79, -0.323). Further, the more a male adult offspring of Turkish migrants feels like belonging to the German culture, the taller he is (95\% CI, -0.152, 1.738). We discussed it comparable to primates taking up their challenge in dominance, where as a result their body size increase is associated with higher IGF-1 level. IGF-1 is associated with emotional belonging and has a fundamental role in the regulation of metabolism and growth of the human body. With all pilot characteristics of our study results show that the successful challenge of integration in a new society is strongly associated with the emotional integration and identification in the sense of a personal sense of belonging to society. We discuss taller BH as a signal of social growth adjustment. In this sense, a secular trend of BH adaptation of migrants to hosts is a sign of integration.}, language = {en} } @article{OezcanBookhagenMusaoglu2018, author = {{\"O}zcan, Orkan and Bookhagen, Bodo and Musaoglu, Nebiye}, title = {Impact of the Ataturk Dam Lake on Agro-Meteorological Aspects of the Southeastern Anatolia Region, Turkey}, series = {Journal of the Indian Society of Remote Sensing}, volume = {46}, journal = {Journal of the Indian Society of Remote Sensing}, number = {3}, publisher = {Springer}, address = {New York}, issn = {0255-660X}, doi = {10.1007/s12524-017-0703-9}, pages = {471 -- 481}, year = {2018}, abstract = {In this study, the spatial and temporal impacts of the Ataturk Dam on agro-meteorological aspects of the Southeastern Anatolia region have been investigated. Change detection and environmental impacts due to water-reserve changes in Ataturk Dam Lake have been determined and evaluated using multi-temporal Landsat satellite imageries and meteorological datasets within a period of 1984-2011. These time series have been evaluated for three time periods. Dam construction period constitutes the first part of the study. Land cover/use changes especially on agricultural fields under the Ataturk Dam Lake and its vicinity have been identified between the periods of 1984-1992. The second period comprises the 10-year period after the completion of filling up the reservoir in 1992. At this period, Landsat and meteorological time-series analyses are examined to assess the impact of the Ataturk Dam Lake on selected irrigated agricultural areas. For the last 9-year period from 2002 to 2011, the relationships between seasonal water-reserve changes and irrigated plains under changing climatic factors primarily driving vegetation activity (monthly, seasonal, and annual fluctuations of rainfall rate, air temperature, humidity) on the watershed have been investigated using a 30-year meteorological time series. The results showed that approximately 368 km(2) of agricultural fields have been affected because of inundation due to the Ataturk Dam Lake. However, irrigated agricultural fields have been increased by 56.3\% of the total area (1552 of 2756 km(2)) on Harran Plain within the period of 1984-2011.}, language = {en} } @article{OenerQuerebilloDavidetal.2018, author = {{\"O}ner, Ibrahim Halil and Querebillo, Christine Joy and David, Christin and Gernert, Ulrich and Walter, Carsten and Driess, Matthias and Leimk{\"u}hler, Silke and Ly, Khoa Hoang and Weidinger, Inez M.}, title = {High electromagnetic field enhancement of TiO2 nanotube electrodes}, series = {Angewandte Chemie : a journal of the Gesellschaft Deutscher Chemiker ; International edition}, volume = {57}, journal = {Angewandte Chemie : a journal of the Gesellschaft Deutscher Chemiker ; International edition}, number = {24}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {1433-7851}, doi = {10.1002/anie.201802597}, pages = {7225 -- 7229}, year = {2018}, abstract = {We present the fabrication of TiO2 nanotube electrodes with high biocompatibility and extraordinary spectroscopic properties. Intense surface-enhanced resonance Raman signals of the heme unit of the redox enzyme Cytochromeb(5) were observed upon covalent immobilization of the protein matrix on the TiO2 surface, revealing overall preserved structural integrity and redox behavior. The enhancement factor could be rationally controlled by varying the electrode annealing temperature, reaching a record maximum value of over 70 at 475 degrees C. For the first time, such high values are reported for non-directly surface-interacting probes, for which the involvement of charge-transfer processes in signal amplification can be excluded. The origin of the surface enhancement is exclusively attributed to enhanced localized electric fields resulting from the specific optical properties of the nanotubular geometry of the electrode.}, language = {en} } @article{ZuehlsdorfWinkler2018, author = {Z{\"u}hlsdorf, Felix and Winkler, Iris}, title = {Jenaer Kooperationsseminare aus Fachwissenschaft und Fachdidaktik}, series = {Koh{\"a}renz in der universit{\"a}ren Lehrerbildung}, journal = {Koh{\"a}renz in der universit{\"a}ren Lehrerbildung}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-418638}, pages = {219 -- 235}, year = {2018}, language = {de} } @misc{ZoellerHolschneider2018, author = {Z{\"o}ller, Gert and Holschneider, Matthias}, title = {Reply to "Comment on 'The Maximum Possible and the Maximum Expected Earthquake Magnitude for Production-Induced Earthquakes at the Gas Field in Groningen, The Netherlands' by Gert Z{\"o}ller and Matthias Holschneider" by Mathias Raschke}, series = {Bulletin of the Seismological Society of America}, volume = {108}, journal = {Bulletin of the Seismological Society of America}, number = {2}, publisher = {Seismological Society of America}, address = {Albany}, issn = {0037-1106}, doi = {10.1785/0120170131}, pages = {1029 -- 1030}, year = {2018}, language = {en} } @article{Zoeller2018, author = {Z{\"o}ller, Gert}, title = {A statistical model for earthquake recurrence based on the assimilation of paleoseismicity, historic seismicity, and instrumental seismicity}, series = {Journal of geophysical research : Solid earth}, volume = {123}, journal = {Journal of geophysical research : Solid earth}, number = {6}, publisher = {American Geophysical Union}, address = {Washington}, issn = {2169-9313}, doi = {10.1029/2017JB015099}, pages = {4906 -- 4921}, year = {2018}, abstract = {Paleoearthquakes and historic earthquakes are the most important source of information for the estimation of long-term earthquake recurrence intervals in fault zones, because corresponding sequences cover more than one seismic cycle. However, these events are often rare, dating uncertainties are enormous, and missing or misinterpreted events lead to additional problems. In the present study, I assume that the time to the next major earthquake depends on the rate of small and intermediate events between the large ones in terms of a clock change model. Mathematically, this leads to a Brownian passage time distribution for recurrence intervals. I take advantage of an earlier finding that under certain assumptions the aperiodicity of this distribution can be related to the Gutenberg-Richter b value, which can be estimated easily from instrumental seismicity in the region under consideration. In this way, both parameters of the Brownian passage time distribution can be attributed with accessible seismological quantities. This allows to reduce the uncertainties in the estimation of the mean recurrence interval, especially for short paleoearthquake sequences and high dating errors. Using a Bayesian framework for parameter estimation results in a statistical model for earthquake recurrence intervals that assimilates in a simple way paleoearthquake sequences and instrumental data. I present illustrative case studies from Southern California and compare the method with the commonly used approach of exponentially distributed recurrence times based on a stationary Poisson process.}, language = {en} } @article{ZwiebackKokeljGuentheretal.2018, author = {Zwieback, Simon and Kokelj, Steven V. and G{\"u}nther, Frank and Boike, Julia and Grosse, Guido and Hajnsek, Irena}, title = {Sub-seasonal thaw slump mass wasting is not consistently energy limited at the landscape scale}, series = {The Cryosphere : TC ; an interactive open access journal of the European Geosciences Union}, volume = {12}, journal = {The Cryosphere : TC ; an interactive open access journal of the European Geosciences Union}, number = {2}, publisher = {Copernicus}, address = {G{\"o}ttingen}, issn = {1994-0416}, doi = {10.5194/tc-12-549-2018}, pages = {549 -- 564}, year = {2018}, abstract = {Predicting future thaw slump activity requires a sound understanding of the atmospheric drivers and geomorphic controls on mass wasting across a range of timescales. On sub-seasonal timescales, sparse measurements indicate that mass wasting at active slumps is often limited by the energy available for melting ground ice, but other factors such as rainfall or the formation of an insulating veneer may also be relevant. To study the sub-seasonal drivers, we derive topographic changes from single-pass radar interferometric data acquired by the TanDEM-X satellites. The estimated elevation changes at 12m resolution complement the commonly observed planimetric retreat rates by providing information on volume losses. Their high vertical precision (around 30 cm), frequent observations (11 days) and large coverage (5000 km(2)) allow us to track mass wasting as drivers such as the available energy change during the summer of 2015 in two study regions. We find that thaw slumps in the Tuktoyaktuk coastlands, Canada, are not energy limited in June, as they undergo limited mass wasting (height loss of around 0 cm day 1) despite the ample available energy, suggesting the widespread presence of early season insulating snow or debris veneer. Later in summer, height losses generally increase (around 3 cm day 1), but they do so in distinct ways. For many slumps, mass wasting tracks the available energy, a temporal pattern that is also observed at coastal yedoma cliffs on the Bykovsky Peninsula, Russia. However, the other two common temporal trajectories are asynchronous with the available energy, as they track strong precipitation events or show a sudden speed-up in late August respectively. The observed temporal patterns are poorly related to slump characteristics like the headwall height. The contrasting temporal behaviour of nearby thaw slumps highlights the importance of complex local and temporally varying controls on mass wasting.}, language = {en} } @misc{ZwiebackKokeljGuentheretal.2018, author = {Zwieback, Simon and Kokelj, Steven V. and G{\"u}nther, Frank and Boike, Julia and Grosse, Guido and Hajnsek, Irena}, title = {Sub-seasonal thaw slump mass wasting is not consistently energy limited at the landscape scale}, series = {Postprints der Universit{\"a}t Potsdam : Mathematisch-Naturwissenschaftliche Reihe}, journal = {Postprints der Universit{\"a}t Potsdam : Mathematisch-Naturwissenschaftliche Reihe}, number = {926}, issn = {1866-8372}, doi = {10.25932/publishup-44568}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-445688}, pages = {549 -- 564}, year = {2018}, abstract = {Predicting future thaw slump activity requires a sound understanding of the atmospheric drivers and geomorphic controls on mass wasting across a range of timescales. On sub-seasonal timescales, sparse measurements indicate that mass wasting at active slumps is often limited by the energy available for melting ground ice, but other factors such as rainfall or the formation of an insulating veneer may also be relevant. To study the sub-seasonal drivers, we derive topographic changes from single-pass radar interferometric data acquired by the TanDEM-X satellites. The estimated elevation changes at 12m resolution complement the commonly observed planimetric retreat rates by providing information on volume losses. Their high vertical precision (around 30 cm), frequent observations (11 days) and large coverage (5000 km(2)) allow us to track mass wasting as drivers such as the available energy change during the summer of 2015 in two study regions. We find that thaw slumps in the Tuktoyaktuk coastlands, Canada, are not energy limited in June, as they undergo limited mass wasting (height loss of around 0 cm day 1) despite the ample available energy, suggesting the widespread presence of early season insulating snow or debris veneer. Later in summer, height losses generally increase (around 3 cm day 1), but they do so in distinct ways. For many slumps, mass wasting tracks the available energy, a temporal pattern that is also observed at coastal yedoma cliffs on the Bykovsky Peninsula, Russia. However, the other two common temporal trajectories are asynchronous with the available energy, as they track strong precipitation events or show a sudden speed-up in late August respectively. The observed temporal patterns are poorly related to slump characteristics like the headwall height. The contrasting temporal behaviour of nearby thaw slumps highlights the importance of complex local and temporally varying controls on mass wasting.}, language = {en} } @article{ZwickelKahlRychliketal.2018, author = {Zwickel, Theresa and Kahl, Sandra M. and Rychlik, Michael and M{\"u}ller, Marina E. H.}, title = {Chemotaxonomy of Mycotoxigenic Small-Spored Alternaria Fungi}, series = {Frontiers in microbiology}, volume = {9}, journal = {Frontiers in microbiology}, publisher = {Frontiers Research Foundation}, address = {Lausanne}, issn = {1664-302X}, doi = {10.3389/fmicb.2018.01368}, pages = {20}, year = {2018}, abstract = {Necrotrophic as well as saprophytic small-spored Altemaria (A.) species are annually responsible for major losses of agricultural products, such as cereal crops, associated with the contamination of food and feedstuff with potential health-endangering Altemaria toxins. Knowledge of the metabolic capabilities of different species-groups to form mycotoxins is of importance for a reliable risk assessment. 93 Altemaria strains belonging to the four species groups Alternaria tenuissima, A. arborescens, A. altemata, and A. infectoria were isolated from winter wheat kernels harvested from fields in Germany and Russia and incubated under equal conditions. Chemical analysis by means of an HPLC-MS/MS multi-Alternaria-toxin-method showed that 95\% of all strains were able to form at least one of the targeted 17 non-host specific Altemaria toxins. Simultaneous production of up to 15 (modified) Altemaria toxins by members of the A. tenuissima, A. arborescens, A. altemata species-groups and up to seven toxins by A. infectoria strains was demonstrated. Overall tenuazonic acid was the most extensively formed mycotoxin followed by alternariol and alternariol mono methylether, whereas altertoxin I was the most frequently detected toxin. Sulfoconjugated modifications of alternariol, alternariol mono methylether, altenuisol and altenuene were frequently determined. Unknown perylene quinone derivatives were additionally detected. Strains of the species-group A. infectoria could be segregated from strains of the other three species-groups due to significantly lower toxin levels and the specific production of infectopyrone. Apart from infectopyrone, alterperylenol was also frequently produced by 95\% of the A. infectoria strains. Neither by the concentration nor by the composition of the targeted Altemaria toxins a differentiation between the species-groups A. altemata, A. tenuissima and A. arborescens was possible.}, language = {en} } @misc{ZwickelKahlRychliketal.2018, author = {Zwickel, Theresa and Kahl, Sandra M. and Rychlik, Michael and M{\"u}ller, Marina E. H.}, title = {Chemotaxonomy of mycotoxigenic small-spored Alternaria fungi}, series = {Postprints der Universit{\"a}t Potsdam Mathematisch-Naturwissenschaftliche Reihe}, journal = {Postprints der Universit{\"a}t Potsdam Mathematisch-Naturwissenschaftliche Reihe}, number = {696}, issn = {1866-8372}, doi = {10.25932/publishup-42662}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-426623}, pages = {20}, year = {2018}, abstract = {Necrotrophic as well as saprophytic small-spored Altemaria (A.) species are annually responsible for major losses of agricultural products, such as cereal crops, associated with the contamination of food and feedstuff with potential health-endangering Altemaria toxins. Knowledge of the metabolic capabilities of different species-groups to form mycotoxins is of importance for a reliable risk assessment. 93 Altemaria strains belonging to the four species groups Alternaria tenuissima, A. arborescens, A. altemata, and A. infectoria were isolated from winter wheat kernels harvested from fields in Germany and Russia and incubated under equal conditions. Chemical analysis by means of an HPLC-MS/MS multi-Alternaria-toxin-method showed that 95\% of all strains were able to form at least one of the targeted 17 non-host specific Altemaria toxins. Simultaneous production of up to 15 (modified) Altemaria toxins by members of the A. tenuissima, A. arborescens, A. altemata species-groups and up to seven toxins by A. infectoria strains was demonstrated. Overall tenuazonic acid was the most extensively formed mycotoxin followed by alternariol and alternariol mono methylether, whereas altertoxin I was the most frequently detected toxin. Sulfoconjugated modifications of alternariol, alternariol mono methylether, altenuisol and altenuene were frequently determined. Unknown perylene quinone derivatives were additionally detected. Strains of the species-group A. infectoria could be segregated from strains of the other three species-groups due to significantly lower toxin levels and the specific production of infectopyrone. Apart from infectopyrone, alterperylenol was also frequently produced by 95\% of the A. infectoria strains. Neither by the concentration nor by the composition of the targeted Altemaria toxins a differentiation between the species-groups A. altemata, A. tenuissima and A. arborescens was possible.}, language = {en} } @article{ZurellvonWehrdenRoticsetal.2018, author = {Zurell, Damaris and von Wehrden, Henrik and Rotics, Shay and Kaatz, Michael and Gross, Helge and Schlag, Lena and Sch{\"a}fer, Merlin and Sapir, Nir and Turjeman, Sondra and Wikelski, Martin and Nathan, Ran and Jeltsch, Florian}, title = {Home range size and resource use of breeding and non-breeding white storks along a land use gradient}, series = {Frontiers in Ecology and Evolution}, volume = {6}, journal = {Frontiers in Ecology and Evolution}, publisher = {Frontiers Research Foundation}, address = {Lausanne}, issn = {2296-701X}, doi = {10.3389/fevo.2018.00079}, pages = {11}, year = {2018}, abstract = {Biotelemetry is increasingly used to study animal movement at high spatial and temporal resolution and guide conservation and resource management. Yet, limited sample sizes and variation in space and habitat use across regions and life stages may compromise robustness of behavioral analyses and subsequent conservation plans. Here, we assessed variation in (i) home range sizes, (ii) home range selection, and (iii) fine-scale resource selection of white storks across breeding status and regions and test model transferability. Three study areas were chosen within the Central German breeding grounds ranging from agricultural to fluvial and marshland. We monitored GPS-locations of 62 adult white storks equipped with solar-charged GPS/3D-acceleration (ACC) transmitters in 2013-2014. Home range sizes were estimated using minimum convex polygons. Generalized linear mixed models were used to assess home range selection and fine-scale resource selection by relating the home ranges and foraging sites to Corine habitat variables and normalized difference vegetation index in a presence/pseudo-absence design. We found strong variation in home range sizes across breeding stages with significantly larger home ranges in non-breeding compared to breeding white storks, but no variation between regions. Home range selection models had high explanatory power and well predicted overall density of Central German white stork breeding pairs. Also, they showed good transferability across regions and breeding status although variable importance varied considerably. Fine-scale resource selection models showed low explanatory power. Resource preferences differed both across breeding status and across regions, and model transferability was poor. Our results indicate that habitat selection of wild animals may vary considerably within and between populations, and is highly scale dependent. Thereby, home range scale analyses show higher robustness whereas fine-scale resource selection is not easily predictable and not transferable across life stages and regions. Such variation may compromise management decisions when based on data of limited sample size or limited regional coverage. We thus recommend home range scale analyses and sampling designs that cover diverse regional landscapes and ensure robust estimates of habitat suitability to conserve wild animal populations.}, language = {en} } @phdthesis{Zur2018, author = {Zur, Avichai}, title = {פרדוקס 'הידיעה והבחירה' במשנת ר' צדוק הכהן מלובלין}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-412201}, school = {Universit{\"a}t Potsdam}, pages = {371, xxxiii}, year = {2018}, abstract = {This research deals with R. Zadok's innovative writings. According to most scholars R. Zadok continues the doctrine of his rabbi R. Mordechai Yosef Leiner of Izbica and introduces existential fatalism: man has the freedom to act against the customary law, according to God's will which is revealed in his heart, even in his passions, which exceed the Halacha; however, man does not determine the will that is revealed in the root of his soul, but only uncovers it. Many expressions, in content and form, of this fatalism can be found in R. Zadok's writings; yet, he also introduces many remarks about human free choice and its creative power to establish and determine man's root and re-establish and influence the Divine worlds and this world. This research focuses on these passages whose centrality has been so far neglected by research. Hence, its renewed understanding of his doctrine. R. Zadok's position can be explained by means of the paradoxical perception, which claims the full strength of the two opposites and even a mutual influence between them, which creates a difficult yet fertile tension: as opposed to the a priori intellectual and formal process of fatalism where Divine Foreknowledge eliminates free choice, R. Zadok introduces fatality which identifies in reality itself the Divine foreknowledge and will that exist in all things. In R. Zadok's fatality, Divine foreknowledge does not eliminate free choice; on the contrary, without Divine foreknowledge, nothing has existence. Therefore, only the existence of Divine foreknowledge within free choice enables its true and indeed free fulfillment. R. Zadok's ontological perception is realized not only in the direct content of his words but also indirectly, in the method of his exegesis and the sense he gives to the concepts he discusses. Therefore the fatality is revealed in other areas in which there is a gap between the absolute dimension ('Yedi'ah') and the contingent dimension ('Bechirah'): the lie, imagination, evil, sin, suffering etc., indeed contingent compared with the absoluteness of truth, good, etc.; however, according to R. Zadok, God wants them as such - that is to say, they have an essential existence and actuality that are not absolute, but rather as such: as contingent, temporary and relative. However, these essential existence and actuality do not confirm them as they are but create a transformation within them. For example, evil does not become absolute good or remains evil but rather turns into 'Very Good' (Tov Me'od) which includes evil and according to Rabbi Zadok is greater than regular good. From this, rises also the opposite influence: that of free choice, or contingent Bechira in general, on Divine Foreknowledge, or absolute Yediah in general. According to R. Zadok, when the contingency and relativity of "Bechirah" received its essential existence and actuality, it has the power so to speak, to add dynamism to the permanent Divine absoluteness of the 'Yedi'ah': the affliction (Nega; נגע) of sin or suffering turns by itself, by interchanging its letters, into pleasure (Oneg; ענג) which is greater than regular delight. Man has the power to influence the upper worlds by decreeing decrees or by canceling Divine decrees; he also has the power to influence the daily novelties of this world, by the novellaes of the Oral Law and the sanctification of the new month which is capable of changing the movement of the zodiac. The human creativity of the novellae of the Oral Law is included in the Divine truth which is hidden in the Written Law and it only reveals and interprets the latter; but on the other hand, according to R. Zadok, the source of the dynamic vital novellaes of the Oral Law is higher than the source of the permanent absoluteness of Written Law and they are those which create and determine the latter. R. Zadok introduces two main concepts for his paradox: On the ontological perception - Yichud Gamur, the Ultimate Unification of God, in which the contingent duality (between God and His creation, and the choice it enables) of the Lower Unification paradoxically exists with the absolute unification and Divine Foreknowledge of the Upper Unification. On the perception of man's existential situation - HaShoresh HaNe'elam, The Hidden Root: unlike Rabbi Mordechai Yosef, his rabbi, rabbi Zadok claims that man determines his destiny by his willful contingent actions - yet, simultaneously, like his rabbi, he also claims that the man's permanent root is determined by God and His Foreknowledge and it is what determines his actions for better or worse. But above these R. Zadok points to an additional Hidden Root which is higher than the permanent one: it is indeed an absolute root (Yediah) yet is determined and established by man's willful actions (Bechira), similar to the Divine creation of 'ex nihilo'.}, language = {mul} } @article{ZubaWarschburger2018, author = {Zuba, Anna and Warschburger, Petra}, title = {Weight bias internalization across weight categories among school-aged children}, series = {Body image : an international journal of research}, volume = {25}, journal = {Body image : an international journal of research}, publisher = {Elsevier}, address = {Amsterdam}, issn = {1740-1445}, doi = {10.1016/j.bodyim.2018.02.008}, pages = {56 -- 65}, year = {2018}, abstract = {Anti-fat bias is widespread and is linked to the internalization of weight bias and psychosocial problems. The purpose of this study was to examine the internalization of weight bias among children across weight categories and to evaluate the psychometric properties of the Weight Bias Internalization Scale for Children (WBIS-C). Data were collected from 1484 primary school children and their parents. WBIS-C demonstrated good internal consistency (alpha = .86) after exclusion of Item 1. The unitary factor structure was supported using exploratory and confirmatory factor analyses (factorial validity). Girls and overweight children reported higher WBIS-C scores in comparison to boys and non-overweight peers (known-groups validity). Convergent validity was shown by significant correlations with psychosocial problems. Internalization of weight bias explained additional variance in different indicators of psychosocial well-being. The results suggest that the WBIS-C is a psychometrically sound and informative tool to assess weight bias internalization among children.}, language = {en} } @phdthesis{Zuba2018, author = {Zuba, Anna}, title = {The role of weight stigma and weight bias internalization in psychological functioning among school-aged children}, school = {Universit{\"a}t Potsdam}, pages = {146}, year = {2018}, language = {en} } @phdthesis{Zopfi2018, author = {Zopfi, Stephan}, title = {Die t{\"a}gliche Bewegungs- und Sportstunde}, publisher = {Helyas}, address = {Berom{\"u}nster}, isbn = {978-3-9524944-1-7}, school = {Universit{\"a}t Potsdam}, pages = {185}, year = {2018}, abstract = {Die Gesundheit unserer Jugend ist seit je ein gesellschaftspolitisches Primat und verdient die gr{\"o}sstm{\"o}gliche Beachtung. Ein Teilbereich, n{\"a}mlich Bewegung und Sport, ist in der Schweiz auch aus diesem Grund verfassungsm{\"a}ssig geregelt. S{\"a}mtliche Volksschulen m{\"u}ssen bis ins neunte Schuljahr pro Woche drei Lektionen Bewegung und Sport anbieten.. Als einziges Schulfach geniesst Bewegung und Sport diesen bundesgesetzlichen Support im sonst streng f{\"o}deralistisch organisierten Bildungssystem der Schweiz. Trotz diesen drei verordneten Sportlektionen ist die physische Leistungsf{\"a}higkeit unserer Jugend einhergehend mit gesundheitlichen Parametern seit 1985 r{\"u}ckl{\"a}ufig und seit ein paar Jahren auf tiefem Niveau stagnierend. Zudem berichten Lehrpersonen {\"u}ber sinkende Konzentrationsf{\"a}higkeit in den letzten Jahren. Um eine fl{\"a}chendeckende Verbesserung der Situation zu bewirken, bietet sich die Schule als zentraler Ort der Einflussnahme an. Dies gilt im Besonderen f{\"u}r den Bereich Bewegung und Sport. Im Jahr 2005 wurde das Programm einer t{\"a}glichen Bewegungs- und Sportstunde an der Primarschule in Luzern/Schweiz gestartet. Nach einem kontinuierlichen Ausbau kamen ab 2011 etwas {\"u}ber 1300 Kinder von der ersten bis zur sechsten Klasse in den Genuss dieser t{\"a}glichen Bewegungslektion. Die wissenschaftlichen Untersuchungen in den drei gesellschaftlich hoch relevanten Bereichen der Konzentrationsf{\"a}higkeit, des {\"U}bergewichts und der Gleichgewichtsf{\"a}higkeit ergaben positive Resultate. So konnte die Konzentrationsf{\"a}higkeit - die Basis f{\"u}r erfolgreiches Lernen - signifikant gesteigert werden und teilweise signifikant war die Verbesserung des statischen Gleichgewichts. Ein positiver Trend zeigte sich auch bei der Senkung des Body-Mass-Indexes bei Knaben. Dies konnte bei den M{\"a}dchen nicht nachgewiesen werden. Auch wenn nicht alle Hypothesen vollumf{\"a}nglich best{\"a}tigt werden konnten, gilt es festzuhalten, dass das Projekt der t{\"a}glichen Sport- und Bewegungsstunde die Erwartungen in allen drei Messbereichen erf{\"u}llt hat und die Verbesserungen hinsichtlich der Konzentrationsf{\"a}higkeit, des {\"U}bergewichts und der Gleichgewichtsf{\"a}higkeit mehrheitlich ausgewiesen werden k{\"o}nnen. Es lohnt sich also, die t{\"a}gliche Sport- und Bewegungsstunde an der Primarschule einzuf{\"u}hren und den Pr{\"a}ventionsgedanken auch Taten folgen zu lassen.}, language = {de} } @techreport{Zivkovic2018, type = {Working Paper}, author = {Zivkovic, Velimir}, title = {International Rule of Law Through International Investment Law}, series = {KFG Working Paper Series}, journal = {KFG Working Paper Series}, number = {16}, issn = {2509-3770}, doi = {10.25932/publishup-42218}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-422181}, pages = {33}, year = {2018}, abstract = {In challenging times for international law, there might be a heightened need for both analysis and prescription. The international rule of law as a connecting thread that goes through the global legal order is a particularly salient topic. By providing a working understanding of the content and contexts of the international rule of law, and by taking the regime of international investment law as a case study, this paper argues that assessing 'rise' or 'decline' motions in this sphere warrants a nuanced approach that should recognise parallel positive and negative developments. Whilst prominent procedural and substantive aspects of international investment law strongly align with the international rule of law requirements, numerous challenges threaten the future existence of the regime and appeal of international rule of law more broadly. At the same time, opportunities exist to adapt the substantive decision-making processes in investor-State disputes so to pursue parallel goals of enhancing rule of law at both international and national levels. Through recognising the specificities of interaction between international and national sphere, arbitrators can further reinvigorate the legitimacy of international rule of law through international investment law - benefitting thus the future of both.}, language = {en} } @article{ZivanovicKochovskiArenzetal.2018, author = {Zivanovic, Vesna and Kochovski, Zdravko and Arenz, Christoph and Lu, Yan and Kneipp, Janina}, title = {SERS and Cryo-EM Directly Reveal Different Liposome Structures during Interaction with Gold Nanoparticles}, series = {The journal of physical chemistry letters}, volume = {9}, journal = {The journal of physical chemistry letters}, number = {23}, publisher = {American Chemical Society}, address = {Washington}, issn = {1948-7185}, doi = {10.1021/acs.jpclett.8b03191}, pages = {6767 -- 6772}, year = {2018}, abstract = {The combination of gold nanoparticles with liposomes is important for nano- and biotechnology. Here, we present direct, label-free characterization of liposome structure and composition at the site of its interaction with citrate-stabilized gold nanoparticles by surface-enhanced Raman scattering (SERS) and cryogenic electron microscopy (cryo-EM). Evidenced by the vibrational spectra and cryo-EM, the gold nanoparticles destroy the bilayer structure of interacting liposomes in the presence of a high amount of citrate, while at lower citrate concentration the nanoparticles interact with the surface of the intact liposomes. The spectra of phosphatidylcholine and phosphatidylcholine/sphingomyelin liposomes show that at the site of interaction the lipid chains are in the gel phase. The SERS spectra indicate that cholesterol has strong effects on the contacts of the vesicles with the nanoparticles. By combining cryo-EM and SERS, the structure and properties of lipid nanoparticle composites could be tailored for the development of drug delivery systems.}, language = {en} } @misc{ZitzmannWarschburger2018, author = {Zitzmann, Jana and Warschburger, Petra}, title = {Psychometric properties of figure rating scales in children}, series = {Postprints der Universit{\"a}t Potsdam : Humanwissenschaftliche Reihe}, journal = {Postprints der Universit{\"a}t Potsdam : Humanwissenschaftliche Reihe}, number = {487}, issn = {1866-8364}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-416871}, pages = {11}, year = {2018}, abstract = {This study examined psychometric properties of figure rating scales, particularly the effects of ascending silhouette ordering, in 153 children, 9 to 13 years old. Two versions of Collins's (1991) figural rating scale were presented: the original scale (figures arranged ascendingly) and a modified version (randomized figure ordering. Ratings of current and ideal figure were elicited and body dissatisfaction was calculated. All children were randomly assigned to one of two subgroups and completed both scale versions in a different sequence. There were no significant differences in figure selection and body dissatisfaction between the two figure orderings. Regarding the selection of the current figure, results showed that girls are more affected by the silhouette ordering than boys. Our results suggest that figure rating scales are both valid and reliable, whereby correlation coefficients reveal greater stability for ideal figure selections and body dissatisfaction ratings when using the scale with ascending figure ordering.}, language = {en} } @misc{ZimmermannScholzEckardtetal.2018, author = {Zimmermann, Matthias and Scholz, Jana and Eckardt, Barbara and Kampe, Heike and G{\"o}rlich, Petra and Horn-Conrad, Antje}, title = {Portal Wissen = Language}, number = {01/2018}, organization = {University of Potsdam, Press and Public Relations Department}, issn = {2198-9974}, doi = {10.25932/publishup-44166}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-441666}, pages = {53}, year = {2018}, abstract = {Language is perhaps the most universal tool of human beings. It enables us to express ourselves, to communicate and understand, to help and get help, to create and share togetherness. However, that does not completely capture the value of language. "Language belongs to the character of man," said the English philosopher Sir Francis Bacon. If you believe the poet Johann Gottfried von Herder, a human is "only a human through language". Ultimately, this means that we live in our world not with, but in, language. We not only describe our reality by means of language, but language is the device through which we open up the world in the first place. It is always there and shapes and influences us and the way we perceive, analyze, describe and ultimately determine everything around us. Since it is so deeply connected with human nature, it is hardly surprising that our language has always been in the center of academic research - and not only in those fields that bear the name linguistics. Philosophy and media studies, neurology and psychology, computer science and semiotics - all of them are based on linguistic structures and their premises and possibilities. Since July 2017, a scientific network at the University of Potsdam has been working on exactly this interface: the Collaborative Research Center "Limits of Variability in Language" (SFB 1287), funded by the German Research Foundation (DFG). Linguists, computer scientists, psychologists, and neurologists examine where language is or is not flexible. They hope to find out more about individual languages and their connections. In this issue of Portal Wissen, we asked SFB spokeswoman Isabell Wartenburger and deputy spokesman Malte Zimmermann to talk about language, its variability and limits, and how they investigate these aspects. We also look over the shoulders of two researchers who are working on sub-projects: Germanist Heike Wiese and her team examine whether the pandemonium of the many different languages spoken at a weekly market in Berlin is creating a new language with its own rules. Linguist Doreen Georgi embarks on a typological journey around the world comparing about 30 languages to find out if they have common limits. We also want to introduce other research projects at the University of Potsdam and the people behind them. We talk to biologists about biodiversity and ecological dynamics, and the founders of the startup "visionYOU" explain how entrepreneurship can be combined with social responsibility. Other discussions center round the effective production of antibodies and the question of whether the continued use of smartphones will eventually make us speechless. But do not worry: we did not run out of words - the magazine is full of them! Enjoy your reading! The Editors}, language = {en} } @misc{ZimmermannScholzEckardtetal.2018, author = {Zimmermann, Matthias and Scholz, Jana and Eckardt, Barbara and Kampe, Heike and G{\"o}rlich, Petra and Horn-Conrad, Antje}, title = {Portal Wissen = Sprache}, number = {01/2018}, organization = {Universit{\"a}t Potsdam, Referat f{\"u}r Presse- und {\"O}ffentlichkeitsarbeit}, issn = {2194-4237}, doi = {10.25932/publishup-44092}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-440921}, pages = {97}, year = {2018}, abstract = {Sprache ist das vielleicht universellste Werkzeug, {\"u}ber das wir Menschen verf{\"u}gen. Mit ihr k{\"o}nnen wir uns ausdr{\"u}cken und mitteilen, verst{\"a}ndigen und verstehen, helfen und Hilfe bekommen, ein Miteinander schaffen und daran teilhaben. Doch damit ist der Wert von Sprache keineswegs vollst{\"a}ndig erfasst. „Die Sprache geh{\"o}rt zum Charakter des Menschen", meinte der englische Philosoph Sir Francis Bacon. Und glaubt man dem Dichter Johann Gottfried von Herder, ist der Mensch gar „Mensch nur durch Sprache". Das bedeutet letztlich, wir sind in der Welt nicht mit, sondern in Sprache. Wir beschreiben unsere Wirklichkeit nicht allein mithilfe sprachlicher Mittel, Sprache ist die Brille, durch die wir uns die Welt {\"u}berhaupt erschließen. Sie ist immer schon da und pr{\"a}gt uns und die Weise, wie wir alles um uns herum wahrnehmen und analysieren, beschreiben und letztlich auch bestimmen. Derart tief mit dem Wesen des Menschen verbunden, wundert es kaum, dass unsere Sprache seit jeher im Fokus wissenschaftlicher Forschung steht. Und zwar nicht nur jener, die sich dem Namen nach als Sprachwissenschaft zu erkennen gibt. Philosophie und Medienwissenschaft, Neurologie und Psychologie, Informatik und Semiotik - sie alle gehen sprachlichen Strukturen, ihren Voraussetzungen und ihren M{\"o}glichkeiten nach. Seit Juli 2017 arbeitet an genau dieser Schnittstelle an der Universit{\"a}t Potsdam ein wissenschaftliches Netzwerk: der von der Deutschen Forschungsgemeinschaft (DFG) gef{\"o}rderte Sonderforschungsbereich „Grenzen der Variabilit{\"a}t in der Sprache" (SFB 1287). Gemeinsam untersuchen darin Linguisten, Informatiker, Psychologen und Neurologen, wo Sprache flexibel ist - und wo nicht. Dadurch hoffen sie, nicht nur mehr {\"u}ber einzelne Sprachen herauszufinden, sondern auch, was sie verbindet. In der vorliegenden Ausgabe der Portal Wissen haben wir die Sprecherin des SFB Isabell Wartenburger und ihrem Stellvertreter Malte Zimmermann gebeten, mit uns ins Gespr{\"a}ch zu kommen - {\"u}ber Sprache, ihre Variabilit{\"a}t, deren Grenzen und wie man beides erforscht. Außerdem haben wir zwei Wissenschaftlerinnen bei der Arbeit an ihren Teilprojekten {\"u}ber die Schulter geschaut: Die Germanistin Heike Wiese untersucht mit ihrem Team, ob auf einem Berliner Wochenmarkt, wo Sprachen aus fast allen Teilen der Welt zu h{\"o}ren sind, aus einem wilden Durcheinander eine neue Sprache mit eigenen Regeln entsteht. Und die Linguistin Doreen Georgi begibt sich auf eine typologische Weltreise, bei der sie rund 30 Sprachen miteinander vergleicht, um herauszufinden, ob sie gemeinsame Grenzen haben. Zugleich wollen wir auch auf andere Forschungsprojekte an der Universit{\"a}t Potsdam und die Menschen dahinter zu sprechen kommen. So ließ uns ein Mathematiker erkennen, was Fußball mit Mathematik zu tun hat und warum diese Verbindung in der Schule gut ankommt. Außerdem sprachen wir mit einer Anglistin {\"u}ber afroamerikanische Literatur im 19. Jahrhundert, f{\"u}hrte uns ein Chemiker durch das Gebiet der Angewandten Analytischen Photonik und eine Juristin erkl{\"a}rte uns den Unterschied zwischen dem franz{\"o}sischen und dem deutschen Strafrecht. Wir diskutierten mit zwei Medienwissenschaftlern und einem Religionswissenschaftler {\"u}ber Computer- und Videospiele von ihren Anf{\"a}ngen bis heute und lernten von den Gr{\"u}ndern des Start-ups „visionYOU", wie sich Unternehmertum mit sozialer Verantwortung verbinden l{\"a}sst. In vielen weiteren Gespr{\"a}chen ging es unter anderem um Fernsehen 4.0, Artenvielfalt und {\"o}kologische Dynamik, ein Training zum achtsamen Essen, die effektive Produktion von Antik{\"o}rpern und die Frage, ob uns die Dauernutzung von Smartphones am Ende sprachlos macht. Aber keine Angst: Uns sind die Worte nicht ausgegangen - das Heft ist voll davon! Viel Vergn{\"u}gen beim Lesen! Die Redaktion}, language = {de} } @misc{ZimmermannGoerlichScholzetal.2018, author = {Zimmermann, Matthias and G{\"o}rlich, Petra and Scholz, Jana and Kampe, Heike and Horn-Conrad, Antje and Eckardt, Barbara and Schittenhelm, Alina}, title = {Portal = Den Wandel gestalten: Arbeitswelten der Zukunft}, number = {02/2018}, organization = {Universit{\"a}t Potsdam, Referat f{\"u}r Presse- und {\"O}ffentlichkeitsarbeit}, issn = {1618-6893}, doi = {10.25932/publishup-44073}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-440737}, pages = {42}, year = {2018}, abstract = {Aus dem Inhalt: - Den Wandel gestalten: Arbeitswelten der Zukunft - Mehr Lehrer f{\"u}r das Land - Im Reich der Drachenfliege}, language = {de} } @article{ZimmermannJohnGrigorievetal.2018, author = {Zimmermann, Marc and John, Daniela and Grigoriev, Dmitry and Puretskiy, Nikolay and B{\"o}ker, Alexander}, title = {From 2D to 3D patches on multifunctional particles}, series = {Soft matter}, volume = {14}, journal = {Soft matter}, number = {12}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {1744-683X}, doi = {10.1039/c8sm00163d}, pages = {2301 -- 2309}, year = {2018}, abstract = {A straightforward approach for the precise multifunctional surface modification of particles with three-dimensional patches using microcontact printing is presented. By comparison to previous works it was possible to not only control the diameter, but also to finely tune the thickness of the deposited layer, opening up the way for three-dimensional structures and orthogonal multifunctionality. The use of PEI as polymeric ink, PDMS stamps for microcontact printing on silica particles and the influence of different solvents during particle release on the creation of functional particles with three-dimensional patches are described. Finally, by introducing fluorescent properties by incorporation of quantum dots into patches and by particle self-assembly via avidin-biotin coupling, the versatility of this novel modification method is demonstrated.}, language = {en} } @article{ZimmermannGrigorievPuretskiyetal.2018, author = {Zimmermann, Marc and Grigoriev, Dmitry and Puretskiy, Nikolay and B{\"o}ker, Alexander}, title = {Characteristics of microcontact printing with polyelectrolyte ink for the precise preparation of patches on silica particles}, series = {RSC Advances}, volume = {8}, journal = {RSC Advances}, number = {69}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {2046-2069}, doi = {10.1039/c8ra07955b}, pages = {39241 -- 39247}, year = {2018}, abstract = {This publication demonstrates the abilities of a precise and straightforward microcontact printing approach for the preparation of patchy silica particles. In a broad particle size range, it is possible to finely tune the number and parameters of three-dimensional patches like diameter and thickness using only polyethyleneimine ink, poly(dimethoxysilane) as stamp material and a suitable release solvent.}, language = {en} } @phdthesis{Zimmermann2018, author = {Zimmermann, Marc}, title = {Multifunctional patchy silica particles via microcontact printing}, doi = {10.25932/publishup-42773}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-427731}, school = {Universit{\"a}t Potsdam}, pages = {IX, 121, xiii}, year = {2018}, abstract = {This research addressed the question, if it is possible to simplify current microcontact printing systems for the production of anisotropic building blocks or patchy particles, by using common chemicals while still maintaining reproducibility, high precision and tunability of the Janus-balance Chapter 2 introduced the microcontact printing materials as well as their defined electrostatic interactions. In particular polydimethylsiloxane stamps, silica particles and high molecular weight polyethylenimine ink were mainly used in this research. All of these components are commercially available in large quantities and affordable, which gives this approach a huge potential for further up-scaling developments. The benefits of polymeric over molecular inks was described including its flexible influence on the printing pressure. With this alteration of the µCP concept, a new method of solvent assisted particle release mechanism enabled the switch from two-dimensional surface modification to three-dimensional structure printing on colloidal silica particles, without changing printing parameters or starting materials. This effect opened the way to use the internal volume of the achieved patches for incorporation of nano additives, introducing additional physical properties into the patches without alteration of the surface chemistry. The success of this system and its achievable range was further investigated in chapter 3 by giving detailed information about patch geometry parameters including diameter, thickness and yield. For this purpose, silica particles in a size range between 1µm and 5µm were printed with different ink concentrations to change the Janus-balance of these single patched particles. A necessary intermediate step, consisting of air-plasma treatment, for the production of trivalent particles using "sandwich" printing was discovered and comparative studies concerning the patch geometry of single and double patched particles were conducted. Additionally, the usage of structured PDMS stamps during printing was described. These results demonstrate the excellent precision of this approach and opens the pathway for even greater accuracy as further parameters can be finely tuned and investigated, e.g. humidity and temperature during stamp loading. The performance of these synthesized anisotropic colloids was further investigated in chapter 4, starting with behaviour studies in alcoholic and aqueous dispersions. Here, the stability of the applied patches was studied in a broad pH range, discovering a release mechanism by disabling the electrostatic bonding between particle surface and polyelectrolyte ink. Furthermore, the absence of strong attractive forces between divalent particles in water was investigated using XPS measurements. These results lead to the conclusion that the transfer of small PDMS oligomers onto the patch surface is shielding charges, preventing colloidal agglomeration. However, based on this knowledge, further patch modifications for particle self-assembly were introduced including physical approaches using magnetic nano additives, chemical patch functionalization with avidin-biotin or the light responsive cyclodextrin-arylazopyrazoles coupling as well as particle surface modification for the synthesis of highly amphiphilic colloids. The successful coupling, its efficiency, stability and behaviour in different solvents were evaluated to find a suitable coupling system for future assembly experiments. Based on these results the possibility of more sophisticated structures by colloidal self-assembly is given. Certain findings needed further analysis to understand their underlying mechanics, including the relatively broad patch diameter distribution and the decreasing patch thickness for smaller silica particles. Mathematical assumptions for both effects are introduced in chapter 5. First, they demonstrate the connection between the naturally occurring particle size distribution and the broadening of the patch diameter, indicating an even higher precision for this µCP approach. Second, explaining the increase of contact area between particle and ink surface due to higher particle packaging, leading to a decrease in printing pressure for smaller particles. These calculations ultimately lead to the development of a new mechanical microcontact printing approach, using centrifugal forces for high pressure control and excellent parallel alignment of printing substrates. First results with this device and the comparison with previously conducted by-hand experiments conclude this research. It furthermore displays the advantages of such a device for future applications using a mechanical printing approach, especially for accessing even smaller nano particles with great precision and excellent yield. In conclusion, this work demonstrates the successful adjustment of the µCP approach using commercially available and affordable silica particles and polyelectrolytes for high flexibility, reduced costs and higher scale-up value. Furthermore, its was possible to increase the modification potential by introducing three-dimensional patches for additional functionalization volume. While keeping a high colloidal stability, different coupling systems showed the self-assembly capabilities of this toolbox for anisotropic particles.}, language = {en} } @article{Zimmermann2018, author = {Zimmermann, Malte}, title = {Wird Schon Stimmen!}, series = {Journal of semantics}, volume = {35}, journal = {Journal of semantics}, number = {4}, publisher = {Oxford Univ. Press}, address = {Oxford}, issn = {0167-5133}, doi = {10.1093/jos/ffy010}, pages = {687 -- 739}, year = {2018}, abstract = {The article puts forward a novel analysis of the German modal particle schon as a modal degree operator over propositional content. The proposed analysis offers a uniform perspective on the semantics of modal schon and its aspectual counterpart meaning 'already': Both particles are analyzed as denoting a degree operator, expressing a scale-based comparison over relevant alternatives. The alternatives are determined by focus in the case of aspectual schon (Krifka 2000), but are restricted to the polar alternatives p and ¬p in the case of modal schon. Semantically, modal schon introduces a presupposition to the effect that the circumstantial conversational background contains more factual evidence in favor of p than in favor of ¬p⁠, thereby making modal schon the not at-issue counterpart of the overt comparative form eher 'rather' (Herburger \& Rubinstein 2014). The analysis incorporates basic insights from earlier analyses of modal schon in a novel way, and it also offers new insights as to the underlying workings of modality in natural language as involving propositions rather than possible worlds (Kratzer 1977, 2012).}, language = {en} } @phdthesis{Zimmermann2018, author = {Zimmermann, Diana}, title = {Direkte Arylierung}, school = {Universit{\"a}t Potsdam}, pages = {221}, year = {2018}, language = {de} } @article{ZimmermannBoos2018, author = {Zimmermann, Andreas and Boos, Felix}, title = {Bringing States to Justice for Crimes against Humanity}, series = {Journal of international criminal justice}, volume = {16}, journal = {Journal of international criminal justice}, number = {4}, publisher = {Oxford Univ. Press}, address = {Oxford}, issn = {1478-1387}, doi = {10.1093/jicj/mqy053}, pages = {835 -- 855}, year = {2018}, abstract = {Draft Article 15 of the International Law Commission's project on crimes against humanity — dealing with the settlement of disputes arising from a proposed convention — attempts to strike a balance between state autonomy and robust judicial supervision. It largely follows Article 22 of the Convention on the Elimination of All Forms of Racial Discrimination, which renders the jurisdiction of the International Court of Justice (ICJ) conditional upon prior negotiations. Hence, the substance of the clause can be interpreted in light of the recent case law of the ICJ, especially in the case Georgia v. Russia. In addition, this contribution discusses several issues regarding the scope ratione temporis of the compromissory clause. It advances several proposals to improve the current draft, addressing its relationship with state responsibility — an explicit reference to which is currently missing — as well as the relationship between the ICJ and a possible treaty body. It also proposes to recalibrate the interplay of the requirement of prior negotiations with, respectively, the possibility of seizing a future treaty body and the indication of provisional measures by the ICJ.}, language = {en} } @techreport{ZimmermannBoos2018, type = {Working Paper}, author = {Zimmermann, Andreas and Boos, Felix}, title = {Bringing States to Justice for Crimes against Humanity}, series = {KFG Working Paper Series}, journal = {KFG Working Paper Series}, number = {12}, issn = {2509-3770}, doi = {10.25932/publishup-42203}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-422035}, pages = {24}, year = {2018}, abstract = {Draft Art. 15 CCAH attempts to strike a balance between State autonomy and robust judicial supervision. It largely follows Article 22 CERD conditioning the jurisdiction of the ICJ on prior negotiations. Hence, the substance of the clause is interpreted in light of the Court's recent case law, especially Georgia v. Russia. Besides, several issues regarding the scope ratione temporis of the compromissory clause are discussed. The article advances several proposals to further improve the current draft, addressing the missing explicit reference to State responsibility, as well as the relationship between the Court and a possible treaty body, It also proposes to recalibrate the interplay of a requirement of prior negotiations respectively the seizing of a future treaty body on the one hand and provisional measures to be indicated by the Court on the other.}, language = {en} } @article{Zimmermann2018, author = {Zimmermann, Andreas}, title = {A victory for international rule of law?}, series = {Journal of international criminal justice}, volume = {16}, journal = {Journal of international criminal justice}, number = {1}, publisher = {Oxford Univ. Press}, address = {Oxford}, issn = {1478-1387}, doi = {10.1093/jicj/mqy008}, pages = {19 -- 29}, year = {2018}, abstract = {On 14 December 2017, the Assembly of States Parties of the Rome Statute decided to activate the International Criminal Court's jurisdiction over the crime of aggression. In doing so, it however seems to have rescinded the Kampala amendment adopted in 2010, and in particular, the need for State Parties to eventually opt out from the Court's aggression-related jurisdiction. This reversal, while being more in line with the Rome Statute than the Kampala amendment itself, raises new (and old) and challenging legal questions which are highlighted in this article.}, language = {en} } @article{Zierke2018, author = {Zierke, Lisa}, title = {Arbeit, Ausbildung und Weiterbildung im Strafvollzug}, series = {Les droits fondamentaux {\`a} l'{\´e}preuve de la prison : publication des actes de la premi{\`e}re {\´e}cole d'{\´e}t{\´e} tripartite entre les Universit{\´e}s de Naples Federico II, Paris Nanterre et Potsdam, 29 mai-1er juin 2017}, journal = {Les droits fondamentaux {\`a} l'{\´e}preuve de la prison : publication des actes de la premi{\`e}re {\´e}cole d'{\´e}t{\´e} tripartite entre les Universit{\´e}s de Naples Federico II, Paris Nanterre et Potsdam, 29 mai-1er juin 2017}, isbn = {978-88-13-36524-0}, pages = {188 -- 198}, year = {2018}, language = {de} } @article{Zierke2018, author = {Zierke, Lisa}, title = {Allgemeines Schadensrecht in der Klausur}, series = {studere : Rechtszeitschrift der Universit{\"a}t Potsdam}, volume = {11}, journal = {studere : Rechtszeitschrift der Universit{\"a}t Potsdam}, number = {20}, publisher = {studere e.v.}, address = {Potsdam}, issn = {1867-6170}, pages = {30 -- 38}, year = {2018}, language = {de} } @article{Zichy2018, author = {Zichy, Michael}, title = {Menschenrechte in der Abw{\"a}gung}, series = {Studien zu Grund- und Menschenrechten}, journal = {Studien zu Grund- und Menschenrechten}, number = {18}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-416442}, pages = {17 -- 40}, year = {2018}, language = {de} } @book{Zhuchok2018, author = {Zhuchok, Anatolii V.}, title = {Relatively free doppelsemigroups}, number = {5}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, isbn = {978-3-86956-427-2}, issn = {2199-4951}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-407719}, publisher = {Universit{\"a}t Potsdam}, pages = {vii, 78}, year = {2018}, abstract = {A doppelalgebra is an algebra defined on a vector space with two binary linear associative operations. Doppelalgebras play a prominent role in algebraic K-theory. We consider doppelsemigroups, that is, sets with two binary associative operations satisfying the axioms of a doppelalgebra. Doppelsemigroups are a generalization of semigroups and they have relationships with such algebraic structures as interassociative semigroups, restrictive bisemigroups, dimonoids, and trioids. In the lecture notes numerous examples of doppelsemigroups and of strong doppelsemigroups are given. The independence of axioms of a strong doppelsemigroup is established. A free product in the variety of doppelsemigroups is presented. We also construct a free (strong) doppelsemigroup, a free commutative (strong) doppelsemigroup, a free n-nilpotent (strong) doppelsemigroup, a free n-dinilpotent (strong) doppelsemigroup, and a free left n-dinilpotent doppelsemigroup. Moreover, the least commutative congruence, the least n-nilpotent congruence, the least n-dinilpotent congruence on a free (strong) doppelsemigroup and the least left n-dinilpotent congruence on a free doppelsemigroup are characterized. The book addresses graduate students, post-graduate students, researchers in algebra and interested readers.}, language = {en} } @article{ZhuangJohnstoneHouriganetal.2018, author = {Zhuang, Guangsheng and Johnstone, Samuel A. and Hourigan, Jeremy and Ritts, Bradley and Robinson, Alexander and Sobel, Edward}, title = {Understanding the geologic evolution of Northern Tibetan Plateau with multiple thermochronometers}, series = {Gondwana research : international geoscience journal ; official journal of the International Association for Gondwana Research}, volume = {58}, journal = {Gondwana research : international geoscience journal ; official journal of the International Association for Gondwana Research}, publisher = {Elsevier}, address = {Amsterdam}, issn = {1342-937X}, doi = {10.1016/j.gr.2018.02.014}, pages = {195 -- 210}, year = {2018}, abstract = {The early onset of deformation following the India-Asia collision, Neogene expanse of uplift, and complex systems that comprise strike-slip faults, thrust faults, and intermontane basins characterize the Cenozoic tectonism of Northern Tibetan Plateau and raise two prominent questions in orogenic geodynamics: 1) What mechanism(s) control(s) the transfer of stress related to the India-Asia collision across the distance of >2000 km; and 2) Why the development of high topography was delayed in the Northern Tibetan Plateau and what does it reveal about how the internal forces and external boundary conditions evolved. To address these two questions, we reconstruct a holistic spatial-temporal deformation history of the Northern Tibetan Plateau by using a range of thermochronometers, with closure temperature spanning from 350 degrees C to-60-70 degrees C. This multi-thermochronometer study reveals three stages of faulting related cooling, in the early Cretaceous, in Paleocene-Eocene and in middle-late Miocene. We observe that Paleocene-Eocene deformation was spatially restricted and mostly occurred on reactivated Cretaceous structures, indicating a control of pre-existing weakness on early Cenozoic deformation. Extensive Neogene deformation contrasts with restricted Paleocene-Eocene deformation and relatively quiescent shortening during the Oligocene-early Miocene, which implies a change in the regional tectonics regime. Global plate reconstructions show that this tectonic reorganization is coeval with an increase in Pacific-Asia plate convergence rates. We argue that this change in regional tectonics is a result of increasing constrictive environment of the eastern plate boundary, which changed the behavior of the Altyn Tagh fault the boundary fault of Northern Tibetan Plateau, causing it to change from feeding slip into structures out of the plateau to feeding slip into structures at plateau margins.}, language = {en} } @article{ZhuShpritsChenetal.2018, author = {Zhu, Hui and Shprits, Yuri Y. and Chen, Lunjin and Liu, Xu and Kellerman, Adam C.}, title = {An event on simultaneous amplification of exohiss and chorus waves associated with electron density enhancements}, series = {Journal of geophysical research : Space physics}, volume = {123}, journal = {Journal of geophysical research : Space physics}, number = {11}, publisher = {American Geophysical Union}, address = {Washington}, issn = {2169-9380}, doi = {10.1029/2017JA025023}, pages = {8958 -- 8968}, year = {2018}, abstract = {Whistler mode exohiss are the structureless hiss waves observed outside the plasma pause with featured equatorward Poynting flux. An event of the amplification of exohiss as well as chorus waves was recorded by Van Allen Probes during the recovery phase of a weak geomagnetic storm. Amplitudes of both types of the waves showed a significant increase at the regions of electron density enhancements. It is found that the electrons resonant with exohiss and chorus showed moderate pitch angle anisotropies. The ratio of the number of electrons resonating with exohiss to total electron number presented in-phase correlation with density variations, which suggests that exohiss can be amplified due to electron density enhancement in terms of cyclotron instability. The calculation of linear growth rates further supports above conclusion. We suggest that exohiss waves have potential to become more significant due to the background plasma fluctuation.}, language = {en} } @article{ZhouFischer2018, author = {Zhou, Yuefang and Fischer, Martin H.}, title = {Mimicking non-verbal emotional expressions and empathy development in simulated consultations}, series = {Patient education and counseling}, volume = {101}, journal = {Patient education and counseling}, number = {2}, publisher = {Elsevier Science}, address = {Clare}, issn = {0738-3991}, doi = {10.1016/j.pec.2017.08.016}, pages = {304 -- 309}, year = {2018}, abstract = {Objective: To explore the feasibility of applying an experimental design to study the relationship between non-verbal emotions and empathy development in simulated consultations. Method: In video-recorded simulated consultations, twenty clinicians were randomly allocated to either an experimental group (instructed to mimic non-verbal emotions of a simulated patient, SP) or a control group (no such instruction). Baseline empathy scores were obtained before consultation, relational empathy was rated by SP after consultation. Multilevel logistic regression modelled the probability of mimicry occurrence, controlling for baseline empathy and clinical experience. ANCOVA compared group differences on relational empathy and consultation smoothness. Results: Instructed mimicry lasted longer than spontaneous mimicry. Mimicry was marginally related to improved relational empathy. SP felt being treated more like a whole person during consultations with spontaneous mimicry. Clinicians who displayed spontaneous mimicry felt consultations went more smoothly. Conclusion: The experimental approach improved our understanding of how non-verbal emotional mimicry contributed to relational empathy development during consultations. Further work should ascertain the potential of instructed mimicry to enhance empathy development. Practice implications: Understanding how non-verbal emotional mimicry impacts on patients' perceived clinician empathy during consultations may inform training and intervention programme development.}, language = {en} } @article{ZhouWangShuetal.2018, author = {Zhou, Wei and Wang, Aiping and Shu, Hua and Kliegl, Reinhold and Yan, Ming}, title = {Word segmentation by alternating colors facilitates eye guidance in Chinese reading}, series = {Memory \& cognition}, volume = {46}, journal = {Memory \& cognition}, number = {5}, publisher = {Springer}, address = {New York}, issn = {0090-502X}, doi = {10.3758/s13421-018-0797-5}, pages = {729 -- 740}, year = {2018}, abstract = {During sentence reading, low spatial frequency information afforded by spaces between words is the primary factor for eye guidance in spaced writing systems, whereas saccade generation for unspaced writing systems is less clear and under debate. In the present study, we investigated whether word-boundary information, provided by alternating colors (consistent or inconsistent with word-boundary information) influences saccade-target selection in Chinese. In Experiment 1, as compared to a baseline (i.e., uniform color) condition, word segmentation with alternating color shifted fixation location towards the center of words. In contrast, incorrect word segmentation shifted fixation location towards the beginning of words. In Experiment 2, we used a gaze-contingent paradigm to restrict the color manipulation only to the upcoming parafoveal words and replicated the results, including fixation location effects, as observed in Experiment 1. These results indicate that Chinese readers are capable of making use of parafoveal word-boundary knowledge for saccade generation, even if such information is unfamiliar to them. The present study provides novel support for the hypothesis that word segmentation is involved in the decision about where to fixate next during Chinese reading.}, language = {en} } @article{ZhongMiMetwallietal.2018, author = {Zhong, Qi and Mi, Lei and Metwalli, Ezzeldin and Biessmann, Lorenz and Philipp, Martine and Miasnikova, Anna and Laschewsky, Andre and Papadakis, Christine M. and Cubitt, Robert and Schwartzkopf, Matthias and Roth, Stephan V. and Wang, Jiping and M{\"u}ller-Buschbaum, Peter}, title = {Effect of chain architecture on the swelling and thermal response of star-shaped thermo-responsive (poly(methoxy diethylene glycol acrylate)-block-polystyrene)(3) block copolymer films}, series = {Soft matter}, volume = {14}, journal = {Soft matter}, number = {31}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {1744-683X}, doi = {10.1039/c8sm00965a}, pages = {6582 -- 6594}, year = {2018}, abstract = {The effect of chain architecture on the swelling and thermal response of thin films obtained from an amphiphilic three-arm star-shaped thermo-responsive block copolymer poly(methoxy diethylene glycol acrylate)-block-polystyrene ((PMDEGA-b-PS)(3)) is investigated by in situ neutron reflectivity (NR) measurements. The PMDEGA and PS blocks are micro-phase separated with randomly distributed PS nanodomains. The (PMDEGA-b-PS)(3) films show a transition temperature (TT) at 33 degrees C in white light interferometry. The swelling capability of the (PMDEGA-b-PS)(3) films in a D2O vapor atmosphere is better than that of films from linear PS-b-PMDEGA-b-PS triblock copolymers, which can be attributed to the hydrophilic end groups and limited size of the PS blocks in (PMDEGA-b-PS)(3). However, the swelling kinetics of the as-prepared (PMDEGA-b-PS)(3) films and the response of the swollen film to a temperature change above the TT are significantly slower than that in the PS-b-PMDEGA-b-PS films, which may be related to the conformation restriction by the star-shape. Unlike in the PS-b-PMDEGA-b-PS films, the amount of residual D2O in the collapsed (PMDEGA-b-PS)(3) films depends on the final temperature. It decreases from (9.7 +/- 0.3)\% to (7.0 +/- 0.3)\% or (6.0 +/- 0.3)\% when the final temperatures are set to 35 degrees C, 45 degrees C and 50 degrees C, respectively. This temperature-dependent reduction of embedded D2O originates from the hindrance of chain conformation from the star-shaped chain architecture.}, language = {en} } @article{ZhivkovaKieckerLangeretal.2018, author = {Zhivkova, Veselina and Kiecker, Felix and Langer, Peter and Eberle, J{\"u}rgen}, title = {Crucial role of reactive oxygen species (ROS) for the proapoptotic effects of indirubin derivative DKP-073 in melanoma cells}, series = {Molecular carcinogenesis}, volume = {58}, journal = {Molecular carcinogenesis}, number = {2}, publisher = {Wiley}, address = {Hoboken}, issn = {0899-1987}, doi = {10.1002/mc.22924}, pages = {258 -- 269}, year = {2018}, abstract = {Melanoma represents a prime example demonstrating the success of targeted therapy in cancer. Nevertheless, it remained a deadly disease until now, and the identification of new, independent strategies as well as the understanding of their molecular mechanisms may help to finally overcome the high mortality. Both indirubins and TNF-related apoptosis-inducing ligand (TRAIL) represent promising candidates. Here, the indirubin derivative DKP-073 is shown to trigger apoptosis in melanoma cells, which is enhanced by the combination with TRAIL and is accompanied by complete loss of cell viability. Addressing the signaling cascade, characteristic molecular steps were identified as caspase-3 activation, downregulation of XIAP, upregulation of p53 and TRAIL receptor 2, loss of mitochondrial membrane potential, and STAT-3 dephosphorylation. The decisive step, however, turned out to be the early production of ROS already at 1 h. This was proven by antioxidant pretreatment, which completely abolished apoptosis induction and loss of cell viability as well as abrogated all signaling effects listed above. Thus, ROS appeared as upstream of all proapoptotic signaling. The data indicate a dominant role of ROS in apoptosis regulation, and the new pathway may expose a possible Achilles heel of melanoma.}, language = {en} } @article{ZhengPikovskij2018, author = {Zheng, Chunming and Pikovskij, Arkadij}, title = {Delay-induced stochastic bursting in excitable noisy systems}, series = {Physical review : E, Statistical, nonlinear and soft matter physics}, volume = {98}, journal = {Physical review : E, Statistical, nonlinear and soft matter physics}, number = {4}, publisher = {American Physical Society}, address = {College Park}, issn = {2470-0045}, doi = {10.1103/PhysRevE.98.042148}, pages = {8}, year = {2018}, abstract = {We show that a combined action of noise and delayed feedback on an excitable theta-neuron leads to rather coherent stochastic bursting. An idealized point process, valid if the characteristic timescales in the problem are well separated, is used to describe statistical properties such as the power spectral density and the interspike interval distribution. We show how the main parameters of the point process, the spontaneous excitation rate, and the probability to induce a spike during the delay action can be calculated from the solutions of a stationary and a forced Fokker-Planck equation.}, language = {en} } @article{ZhengBaiTaoetal.2018, author = {Zheng, Botuo and Bai, Tianwen and Tao, Xinfeng and Schlaad, Helmut and Ling, Jun}, title = {Identifying the Hydrolysis of Carbonyl Sulfide as a Side Reaction Impeding the Polymerization of N-Substituted Glycine N-Thiocarboxyanhydride}, series = {Biomacromolecules : an interdisciplinary journal focused at the interface of polymer science and the biological sciences}, volume = {19}, journal = {Biomacromolecules : an interdisciplinary journal focused at the interface of polymer science and the biological sciences}, number = {11}, publisher = {American Chemical Society}, address = {Washington}, issn = {1525-7797}, doi = {10.1021/acs.biomac.8b01119}, pages = {4263 -- 4269}, year = {2018}, abstract = {Polypeptoids are noticeable biological materials due to their versatile properties and various applications in drug delivery, surface modification, self-assembly, etc. N-Substituted glycine N-thiocarboxyanhydrides (NNTAs) are more stable monomers than the corresponding N-carboxyanhydrides (NNCAs) and enable one to prepare polypeptoids via ring-opening polymerization even in the presence of water. However, larger amounts of water (>10,000 ppm) cause inhibition of the polymerization. Herein, we discover that during polymerization hydrogen sulfide evolves from the hydrolysis of carbonyl sulfide, which is the byproduct of ring-opening reaction, and reacts with NNTA to produce cyclic oligopeptoids. The capture of N-ethylethanethioic acid as an intermediate product confirms the reaction mechanism together with density functional theory quantum computational results. By bubbling the polymerization solution with argon, the side reaction can be suppressed to allow the synthesis of polysarcosine with high molar mass (M-n = 11,200 g/mol, D = 1.25) even in the presence of similar to 10,000 ppm of water.}, language = {en} } @article{ZhaoXiaWuetal.2018, author = {Zhao, Liming and Xia, Yan and Wu, Xiao-Yuan and Schippers, Jos H. M. and Jing, Hai-Chun}, title = {Phenotypic analysis and molecular markers of leaf senescence}, series = {Plant Senescence: Methods and Protocols}, volume = {1744}, journal = {Plant Senescence: Methods and Protocols}, publisher = {Humana Press Inc.}, address = {Totowa}, isbn = {978-1-4939-7672-0}, issn = {1064-3745}, doi = {10.1007/978-1-4939-7672-0_3}, pages = {35 -- 48}, year = {2018}, abstract = {The process of leaf senescence consists of the final stage of leaf development. It has evolved as a mechanism to degrade macromolecules and micronutrients and remobilize them to other developing parts of the plant; hence it plays a central role for the survival of plants and crop production. During senescence, a range of physiological, morphological, cellular, and molecular events occur, which are generally referred to as the senescence syndrome that includes several hallmarks such as visible yellowing, loss of chlorophyll and water content, increase of ion leakage and cell death, deformation of chloroplast and cell structure, as well as the upregulation of thousands of so-called senescence-associated genes (SAGs) and downregulation of photosynthesis-associated genes (PAGs). This chapter is devoted to methods characterizing the onset and progression of leaf senescence at the morphological, physiological, cellular, and molecular levels. Leaf senescence normally progresses in an age-dependent manner but is also induced prematurely by a variety of environmental stresses in plants. Focused on the hallmarks of the senescence syndrome, a series of protocols is described to asses quantitatively the senescence process caused by developmental cues or environmental perturbations. We first briefly describe the senescence process, the events associated with the senescence syndrome, and the theories and methods to phenotype senescence. Detailed protocols for monitoring senescence in planta and in vitro, using the whole plant and the detached leaf, respectively, are presented. For convenience, most of the protocols use the model plant species Arabidopsis and rice, but they can be easily extended to other plants.}, language = {en} } @phdthesis{Zhang2018, author = {Zhang, Yunming}, title = {Understanding the functional specialization of poly(A) polymerases in Arabidopsis thaliana}, school = {Universit{\"a}t Potsdam}, pages = {131}, year = {2018}, language = {de} } @article{ZhangHuangHuangetal.2018, author = {Zhang, Yang and Huang, Wentao and Huang, Baochun and van Hinsbergen, Douwe J. J. and Yang, Tao and Dupont-Nivet, Guillaume and Guo, Zhaojie}, title = {53-43Ma Deformation of Eastern Tibet Revealed by Three Stages of Tectonic Rotation in the Gongjue Basin}, series = {Journal of geophysical research : Solid earth}, volume = {123}, journal = {Journal of geophysical research : Solid earth}, number = {5}, publisher = {American Geophysical Union}, address = {Washington}, issn = {2169-9313}, doi = {10.1002/2018JB015443}, pages = {3320 -- 3338}, year = {2018}, abstract = {The Gongjue basin from the eastern Qiangtang terrane is located in the transition region where the regional structural lineation curves from east-west-oriented in Tibet to north-south-oriented in Yunnan. In this study, we sampled the red beds in the basin from the lower Gongjue to upper Ranmugou formations for the first time covering the entire stratigraphic profile. The stratigraphic ages are bracketed within 53-43Ma by new detrital zircon U-Pb ages constraining the maximum deposition age to 52.51.5Ma. Rock magnetic and petrographic studies indicate that detrital magnetite and hematite are the magnetic carriers. Positive reversals and fold tests demonstrate that the characteristic remanent magnetization has a primary origin. The Gongjue and Ranmugou formations yield mean characteristic remanent magnetization directions of D-s/I-s=31.0 degrees/21.3 degrees and D-s/I-s=15.9 degrees/22.0 degrees, respectively. The magnetic inclination of these characteristic remanent magnetizations is significantly shallowed compared to the expected inclination for the locality. However, the elongation/inclination correction method does not provide a meaningful correction, likely because of syn-depositional rotation. Rotations relative to the Eurasian apparent polar wander path occurred in three stages: Stage I, 33.33.4 degrees clockwise rotation during the deposition of the Gongjue and lower Ranmugou formations; Stage II, 26.93.7 degrees counterclockwise rotation during deposition of the lower and middle Ranmugou formation; and Stage III, 17.73.3 degrees clockwise rotation after 43Ma. The complex rotation history recorded in the basin is possibly linked to sinistral shear along the Qiangtang block during India indentation into Asia and the early stage of the extrusion of the northwestern Indochina blocks away from eastern Tibet.}, language = {en} } @article{ZhangYarmanErdossyetal.2018, author = {Zhang, Xiaorong and Yarman, Aysu and Erdossy, Julia and Katz, Sagie and Zebger, Ingo and Jetzschmann, Katharina J. and Altintas, Zeynep and Wollenberger, Ulla and Gyurcsanyi, Robert E. and Scheller, Frieder W.}, title = {Electrosynthesized MIPs for transferrin}, series = {Biosensors and bioelectronics : the principal international journal devoted to research, design development and application of biosensors and bioelectronics}, volume = {105}, journal = {Biosensors and bioelectronics : the principal international journal devoted to research, design development and application of biosensors and bioelectronics}, publisher = {Elsevier}, address = {Oxford}, issn = {0956-5663}, doi = {10.1016/j.bios.2018.01.011}, pages = {29 -- 35}, year = {2018}, abstract = {Molecularly imprinted polymer (MP) nanofilrns for transferrin (Trf) have been synthesized on gold surfaces by electro-polymerizing the functional monomer scopoletin in the presence of the protein target or around pre-adsorbed Trf. As determined by atomic force microscopy (AFM) the film thickness was comparable with the molecular dimension of the target. The target (re)binding properties of the electro-synthesized MIP films was evaluated by cyclic voltammetry (CV) and square wave voltammetry (SWV) through the target-binding induced permeability changes of the MIP nanofilms to the ferricyanide redox marker, as well as by surface plasmon resonance (SPR) and surface enhanced infrared absorption spectroscopy (SEIRAS) of the immobilized protein molecules. For Trf a linear concentration dependence in the lower micromolar range and an imprinting factor of similar to 5 was obtained by SWV and SPR. Furthermore, non-target proteins including the iron-free apo-Trf were discriminated by pronounced size and shape specificity. Whilst it is generally assumed that the rebinding of the target or of cross-reacting proteins exclusively takes place at the polymer here we considered also the interaction of the protein molecules with the underlying gold transducers. We demonstrate by SWV that adsorption of proteins suppresses the signal of the redox marker even at the bare gold surface and by SEIRAS that the treatment of the MIP with proteinase K or NaOH only partially removes the target protein. Therefore, we conclude that when interpreting binding of proteins to directly MIP-covered gold electrodes the interactions between the protein and the gold surface should also be considered.}, language = {en} } @article{ZhangStolterfohtArminetal.2018, author = {Zhang, Shanshan and Stolterfoht, Martin and Armin, Ardalan and Lin, Qianqian and Zu, Fengshuo and Sobus, Jan and Jin, Hui and Koch, Norbert and Meredith, Paul and Burn, Paul L. and Neher, Dieter}, title = {Interface Engineering of Solution-Processed Hybrid Organohalide Perovskite Solar Cells}, series = {ACS applied materials \& interfaces}, volume = {10}, journal = {ACS applied materials \& interfaces}, number = {25}, publisher = {American Chemical Society}, address = {Washington}, issn = {1944-8244}, doi = {10.1021/acsami.8b02503}, pages = {21681 -- 21687}, year = {2018}, abstract = {Engineering the interface between the perovskite absorber and the charge-transporting layers has become an important method for improving the charge extraction and open-circuit voltage (V-OC) of hybrid perovskite solar cells. Conjugated polymers are particularly suited to form the hole-transporting layer, but their hydrophobicity renders it difficult to solution-process the perovskite absorber on top. Herein, oxygen plasma treatment is introduced as a simple means to change the surface energy and work function of hydrophobic polymer interlayers for use as p-contacts in perovskite solar cells. We find that upon oxygen plasma treatment, the hydrophobic surfaces of different prototypical p-type polymers became sufficiently hydrophilic to enable subsequent perovskite junction processing. In addition, the oxygen plasma treatment also increased the ionization potential of the polymer such that it became closer to the valance band energy of the perovskite. It was also found that the oxygen plasma treatment could increase the electrical conductivity of the p-type polymers, facilitating more efficient charge extraction. On the basis of this concept, inverted MAPbI(3) perovskite devices with different oxygen plasma-treated polymers such as P3HT, P3OT, polyTPD, or PTAA were fabricated with power conversion efficiencies of up to 19\%.}, language = {en} } @phdthesis{Zhang2018, author = {Zhang, Quanchao}, title = {Shape-memory properties of polymeric micro-scale objects prepared by electrospinning and electrospraying}, school = {Universit{\"a}t Potsdam}, pages = {xvi, 53}, year = {2018}, abstract = {The ongoing trend of miniaturizing multifunctional devices, especially for minimally-invasive medical or sensor applications demands new strategies for designing the required functional polymeric micro-components or micro-devices. Here, polymers, which are capable of active movement, when an external stimulus is applied (e.g. shape-memory polymers), are intensively discussed as promising material candidates for realization of multifunctional micro-components. In this context further research activities are needed to gain a better knowledge about the underlying working principles for functionalization of polymeric micro-scale objects with a shape-memory effect. First reports about electrospun solid microfiber scaffolds, demonstrated a much more pronounced shape-memory effect than their bulk counterparts, indicating the high potential of electrospun micro-objects. Based on these initial findings this thesis was aimed at exploring whether the alteration of the geometry of micro-scale electrospun polymeric objects can serve as suitable parameter to tailor their shape-memory properties. The central hypothesis was that different geometries should result in different degrees of macromolecular chain orientation in the polymeric micro-scale objects, which will influence their mechanical properties as well as thermally-induced shape-memory function. As electrospun micro-scale objects, microfiber scaffolds composed of hollow microfibers with different wall thickness and electrosprayed microparticles as well as their magneto-sensitive nanocomposites all prepared from the same polymer exhibiting pronounced bulk shape-memory properties were investigated. For this work a thermoplastic multiblock copolymer, named PDC, with excellent bulk shape-memory properties, associated with crystallizable oligo(ε-caprolactone) (OCL) switching domains, was chosen for the preparation of electrospun micro-scale objects, while crystallizable oligo(p-dioxanone) (OPDO) segments serve as hard domains in PDC. In the first part of the thesis microfiber scaffolds with different microfiber geometries (solid or hollow with different wall thickness) were discussed. Hollow microfiber based PDC scaffolds were prepared by coaxial electrospinning from a 1, 1, 1, 3, 3, 3 hexafluoro-2-propanol (HFP) solution with a polymer concentration of 13\% w·v-1. Here as a first step core-shell fiber scaffolds consisting of microfibers with a PDC shell and sacrificial poly(ethylene glycol) (PEG) core are generated. The hollow PDC microfibers were achieved after dissolving the PEG core with water. The utilization of a fixed electrospinning setup and the same polymer concentration of the PDC spinning solution could ensure the fabrication of microfibers with almost identical outer diameters of 1.4 ± 0.3 µm as determined by scanning electron microscopy (SEM). Different hollow microfiber wall thicknesses of 0.5 ± 0.2 and 0.3 ± 0.2 µm (analyzed by SEM) have been realized by variation of the mass flow rate, while solid microfibers were obtained by coaxial electrospinning without supplying any core solution. Differential scanning calorimetry experiments and tensile tests at ambient temperature revealed an increase in degree of OCL crystallinity form χc,OCL = 34 ± 1\% to 43 ± 1\% and a decrease in elongation of break from 800 ± 40\% to 200 ± 50\% associated with an increase in Young´s modulus and failture stress for PDC hollow microfiber scaffolds when compared with soild fibers. The observed effects were enhanced with decreasing wall thickness of the single hollow fibers. The shape-memory properties of the electrospun PDC scaffolds were quantified by cyclic, thermomechanical tensile tests. Here, scaffolds comprising hollow microfibers exhibited lower shape fixity ratios around Rf = 82 ± 1\% and higher shape recovery ratios of Rr = 67 ± 1\% associated to more pronounced relaxation at constant strain during the first test cycle and a lower switching temperature of Tsw = 33 ± 1 °C than the fibrous meshes consisting of solid microfibers. These findings strongly support the central hypothesis that different fiber geometries (solid or hollow with different wall thickness) in electrospun scaffolds result in different degrees of macromolecular chain orientation in the polymeric micro-scale objects, which can be applied as design parameter for tailoring their mechanical and shape-memory properties. The second part of the thesis deals with electrosprayed particulate PDC micro-scale objects. Almost spherical PDC microparticles with diameters of 3.9 ± 0.9 μm (as determined by SEM) were achieved by electrospraying of HFP solution with a polymer concentration of 2\% w·v-1. In contrast, smaller particles with sizes of 400 ± 100 nm or 1.2 ± 0.3 μm were obtained for the magneto-sensitive composite PDC microparticles containing 23 ± 0.5 wt\% superparamagnetic magnetite nanoparticles (mNPs). All prepared PDC microparticles exhibited a similar overall crystallinity like the PDC bulk material as analyzed by DSC. AFM nanoindentation results revealed no influence of the nanofiller incorporation on the local mechanical properties represented by the reduced modulus determined for pure PDC microparticles and magneto-sensitive composite PDC microparticles with similar diameters around 1.3 µm. It was found that the reduced modulus of the nanocomposite microparticles increased substantially with decreasing particles size from 2.4 ± 0.9 GPa (1.2 µm) to 11.9 ± 3.1 GPa (0.4 µm), which can be related to a higher orientation of the macromolecules at the surface of smaller sized microparticles. The magneto-sensitivity of such nanocomposite microparticles could be demonstrated in two aspects. One was by attracting/collecting the composite micro-objects with an external permanent magnet. The other one was by a inductive heating to 44 ± 1 °C, which is well above the melting transition of the OCL switching domains, when compacted to a 10 x 10 mm2 film with a thickness of 10 µm and exposed to an alternating magnet field with an magnetic field strength of 30 kA·m-1. Both functions are of great relevance for designing next generation drug delivery systems combining targeting and on demand release. By a compression approach shape-memory functionalization of individual microparticles could be realized. Here different programming pressures and compression temperatures were applied. The shape-recovery capability of the programmed PDC microparticles was quantified by online and off-line heating experiments analyzed via microscopy measurement. The obtained shape-memory properties were found to be strongly depending on the applied programming pressure and temperature. The best shape-memory performance with a high shape recovery rate of about Rr = 80±1\% was obtained when a low pressure of 0.2 MPa was applied at 55 °C. Finally, it was demonstrated that PDC microparticles can be utilized as micro building parts for preparation of a macroscopic film with temporary stability by compression of a densely packed array of PDC microparticles at 60 °C followed by subsequent cooling to ambient temperature. This film disintegrates into individual microparticles upon heating to 60 °C. Based on this technology the design of stable macroscopic release systems can be envisioned, which can be easily fixed at the site of treatment (i.e. by suturing) and disintegrate on demand to microparticles facilitating the drug release. In summary, the results of this thesis could confirm the central hypothesis that the variation of the geometry of polymeric micro-objects is a suitable parameter to adjust their shape-memory performance by changing the degree of macromolecular chain orientation in the specimens or by enabling new functions like on demand disintegration. These fundamental findings might be relevant for designing novel miniaturized multifunctional polymer-based devices.}, language = {en} } @article{ZhangYanRichter2018, author = {Zhang, Heshou and Yan, Huirong and Richter, Philipp}, title = {The influence of atomic alignment on absorption and emission spectroscopy}, series = {Monthly notices of the Royal Astronomical Society}, volume = {479}, journal = {Monthly notices of the Royal Astronomical Society}, number = {3}, publisher = {Oxford Univ. Press}, address = {Oxford}, issn = {0035-8711}, doi = {10.1093/mnras/sty1594}, pages = {3923 -- 3935}, year = {2018}, abstract = {Spectroscopic observations play essential roles in astrophysics. They are crucial for determining physical parameters in our Universe, providing information about the chemistry of various astronomical environments. The proper execution of the spectroscopic analysis requires accounting for all the physical effects that are compatible to the signal-to-noise ratio. We find in this paper the influence on spectroscopy from the atomic/ground state alignment owing to anisotropic radiation and modulated by interstellar magnetic field, has significant impact on the study of interstellar gas. In different observational scenarios, we comprehensively demonstrate how atomic alignment influences the spectral analysis and provide the expressions for correcting the effect. The variations are even more pronounced for multiplets and line ratios. We show the variation of the deduced physical parameters caused by the atomic alignment effect, including alpha-to-iron ratio ([X/Fe]) and ionization fraction. Synthetic observations are performed to illustrate the visibility of such effect with current facilities. A study of Photodissociation regions in rho Ophiuchi cloud is presented to demonstrate how to account for atomic alignment in practice. Our work has shown that due to its potential impact, atomic alignment has to be included in an accurate spectroscopic analysis of the interstellar gas with current observational capability.}, language = {en} } @article{ZhangYan2018, author = {Zhang, Heshou and Yan, Huirong}, title = {Polarization of submillimetre lines from interstellar medium}, series = {Monthly notices of the Royal Astronomical Society}, volume = {475}, journal = {Monthly notices of the Royal Astronomical Society}, number = {2}, publisher = {Oxford University Press}, address = {Oxford}, issn = {0035-8711}, doi = {10.1093/mnras/stx3164}, pages = {2415 -- 2420}, year = {2018}, abstract = {Magnetic fields play important roles in many astrophysical processes. However, there is no universal diagnostic for the magnetic fields in the interstellar medium (ISM) and each magnetic tracer has its limitation. Any new detection method is thus valuable. Theoretical studies have shown that submillimetre fine-structure lines are polarized due to atomic alignment by ultraviolet photon-excitation, which opens up a new avenue to probe interstellar magnetic fields. We will, for the first time, perform synthetic observations on the simulated three-dimensional ISM to demonstrate the measurability of the polarization of submillimetre atomic lines. The maximum polarization for different absorption and emission lines expected from various sources, including star-forming regions are provided. Our results demonstrate that the polarization of submillimetre atomic lines is a powerful magnetic tracer and add great value to the observational studies of the submilimetre astronomy.}, language = {en} } @article{Zenin2018, author = {Zenin, Sergej}, title = {Auswirkung der Vorstrafe auf das subjektive Wahlrecht}, series = {Vierte Woche des Russischen Rechts, Potsdam, 31.05.-03.06.2016 mit der Moskauer Staatlichen Juristischen O. E. Kutafin Universit{\"a}t (Akademie)}, journal = {Vierte Woche des Russischen Rechts, Potsdam, 31.05.-03.06.2016 mit der Moskauer Staatlichen Juristischen O. E. Kutafin Universit{\"a}t (Akademie)}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-411460}, pages = {41 -- 46}, year = {2018}, language = {de} } @article{Zenin2018, author = {Zenin, Sergej}, title = {Последствия привлечения к уголовной ответственности при реализации субъективного избирательного права}, series = {Vierte Woche des Russischen Rechts, Potsdam, 31.05.-03.06.2016 mit der Moskauer Staatlichen Juristischen O. E. Kutafin Universit{\"a}t (Akademie)}, journal = {Vierte Woche des Russischen Rechts, Potsdam, 31.05.-03.06.2016 mit der Moskauer Staatlichen Juristischen O. E. Kutafin Universit{\"a}t (Akademie)}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-411473}, pages = {47 -- 52}, year = {2018}, language = {ru} } @misc{ZemellaThoringHoffmeisteretal.2018, author = {Zemella, Anne and Thoring, Lena and Hoffmeister, Christian and Šamal{\´i}kov{\´a}, M{\´a}ria and Ehren, Patricia and W{\"u}stenhagen, Doreen Anja and Kubick, Stefan}, title = {Cell-free protein synthesis as a novel tool for directed glycoengineering of active erythropoietin}, series = {Postprints der Universit{\"a}t Potsdam : Mathematisch Naturwissenschaftliche Reihe}, journal = {Postprints der Universit{\"a}t Potsdam : Mathematisch Naturwissenschaftliche Reihe}, number = {824}, doi = {10.25932/publishup-42701}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-427017}, pages = {14}, year = {2018}, abstract = {As one of the most complex post-translational modification, glycosylation is widely involved in cell adhesion, cell proliferation and immune response. Nevertheless glycoproteins with an identical polypeptide backbone mostly differ in their glycosylation patterns. Due to this heterogeneity, the mapping of different glycosylation patterns to their associated function is nearly impossible. In the last years, glycoengineering tools including cell line engineering, chemoenzymatic remodeling and site-specific glycosylation have attracted increasing interest. The therapeutic hormone erythropoietin (EPO) has been investigated in particular by various groups to establish a production process resulting in a defined glycosylation pattern. However commercially available recombinant human EPO shows batch-to-batch variations in its glycoforms. Therefore we present an alternative method for the synthesis of active glycosylated EPO with an engineered O-glycosylation site by combining eukaryotic cell-free protein synthesis and site-directed incorporation of non-canonical amino acids with subsequent chemoselective modifications.}, language = {en} } @article{ZemellaThoringHoffmeisteretal.2018, author = {Zemella, Anne and Thoring, Lena and Hoffmeister, Christian and Samalikova, Maria and Ehren, Patricia and W{\"u}stenhagen, Doreen Anja and Kubick, Stefan}, title = {Cell-free protein synthesis as a novel tool for directed glycoengineering of active erythropoietin}, series = {Scientific reports}, volume = {8}, journal = {Scientific reports}, publisher = {Nature Publ. Group}, address = {London}, issn = {2045-2322}, doi = {10.1038/s41598-018-26936-x}, pages = {12}, year = {2018}, abstract = {As one of the most complex post-translational modification, glycosylation is widely involved in cell adhesion, cell proliferation and immune response. Nevertheless glycoproteins with an identical polypeptide backbone mostly differ in their glycosylation patterns. Due to this heterogeneity, the mapping of different glycosylation patterns to their associated function is nearly impossible. In the last years, glycoengineering tools including cell line engineering, chemoenzymatic remodeling and site-specific glycosylation have attracted increasing interest. The therapeutic hormone erythropoietin (EPO) has been investigated in particular by various groups to establish a production process resulting in a defined glycosylation pattern. However commercially available recombinant human EPO shows batch-to-batch variations in its glycoforms. Therefore we present an alternative method for the synthesis of active glycosylated EPO with an engineered O-glycosylation site by combining eukaryotic cell-free protein synthesis and site-directed incorporation of non-canonical amino acids with subsequent chemoselective modifications.}, language = {en} } @article{ZellmeierBrennerJanietzetal.2018, author = {Zellmeier, M. and Brenner, Thomas J. K. and Janietz, Silvia and Nickel, N. H. and Rappich, J.}, title = {Polythiophenes as emitter layers for crystalline silicon solar cells}, series = {Journal of applied physics}, volume = {123}, journal = {Journal of applied physics}, number = {3}, publisher = {American Institute of Physics}, address = {Melville}, issn = {0021-8979}, doi = {10.1063/1.5006625}, pages = {5}, year = {2018}, abstract = {We investigated the influence of the emitter (amorphous-Si, a-Si, or polythiophene derivatives: poly(3-hexylthiophene), P3HT, and poly(3-[3,6-dioxaheptyl]-thiophene), P3DOT) and the interface passivation (intrinsic a-Si or SiOX and methyl groups or SiOX) on the c-Si based 1 × 1 cm2 planar hybrid heterojunction solar cell parameters. We observed higher short circuit currents for the P3HT or P3DOT/c-Si solar cells than those obtained for a-Si/c-Si devices, independent of the interface passivation. The obtained VOC of 659 mV for the P3DOT/SiOX/c-Si heterojunction solar cell with hydrophilic 3,6-dioxaheptyl side chains is among the highest reported for c-Si/polythiophene devices. The maximum power conversion efficiency, PCE, was 11\% for the P3DOT/SiOX/c-Si heterojunction solar cell. Additionally, our wafer lifetime measurements reveal a field effect passivation in the wafer induced by the polythiophenes when deposited on c-Si.}, language = {en} } @article{Zehl2018, author = {Zehl, Rebecca}, title = {Raumbezogenes (Un-)Sicherheitsempfinden im Fußball}, series = {Potsdamer Geographische Praxis}, journal = {Potsdamer Geographische Praxis}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, isbn = {978-3-86956-416-6}, issn = {2194-1599}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-408721}, pages = {119 -- 140}, year = {2018}, language = {de} } @phdthesis{Zastrow2018, author = {Zastrow, Julie-Enni}, title = {Die Rolle des Ministerkomitees bei der Umsetzung der Urteile des Europ{\"a}ischen Gerichtshofs f{\"u}r Menschenrechte}, series = {Schriften zum V{\"o}lkerrecht ; 229}, journal = {Schriften zum V{\"o}lkerrecht ; 229}, publisher = {Duncker \& Humblot}, address = {Berlin}, isbn = {978-3-428-15435-7}, school = {Universit{\"a}t Potsdam}, pages = {193}, year = {2018}, language = {de} } @article{ZapataCardonaJaramilloetal.2018, author = {Zapata, Sebastian Henao and Cardona, A. and Jaramillo, J. S. and Patino, A. and Valencia, V. and Leon, S. and Mejia, D. and Pardo-Trujillo, A. and Castaneda, J. P.}, title = {Cretaceous extensional and compressional tectonics in the Northwestern Andes, prior to the collision with the Caribbean oceanic plateau}, series = {Gondwana research : international geoscience journal ; official journal of the International Association for Gondwana Research}, volume = {66}, journal = {Gondwana research : international geoscience journal ; official journal of the International Association for Gondwana Research}, publisher = {Elsevier}, address = {Amsterdam}, issn = {1342-937X}, doi = {10.1016/j.gr.2018.10.008}, pages = {207 -- 226}, year = {2018}, abstract = {The Cretaceous units exposed in the northwestern segment of the Colombian Andes preserve the record of extensional and compressional tectonics prior to the collision with Caribbean oceanic terranes. We integrated field, stratigraphic, sedimentary provenance, whole rock geochemistry, Nd isotopes and U-Pb zircon data to understand the Cretaceous tectonostratigraphic and magmatic record of the Colombian Andes. The results suggest that several sedimentary successions including the Abejorral Fm. were deposited on top of the continental basement in an Early Cretaceous backarc basin (150-100 Ma). Between 120 and 100 Ma, the appearance of basaltic and andesitic magmatism (similar to 115-100 Ma), basin deepening, and seafloor spreading were the result of advanced stages of backarc extension. A change to compressional tectonics took place during the Late Cretaceous (100-80 Ma). During this compressional phase, the extended blocks were reincorporated into the margin, closing the former Early Cretaceous backarc basin. Subsequently, a Late Cretaceous volcanic arc was built on the continental margin: as a result, the volcanic rocks of the Quebradagrande Complex were unconformably deposited on top of the faulted and folded rocks of the Abejorral Fm. Between the Late Cretaceous and the Paleocene (80-60 Ma), an arc-continent collision between the Caribbean oceanic plateau and the South-American continental margin deformed the rocks of the Quebradagrande Complex and shut-down the active volcanic arc. Our results suggest an Early Cretaceous extensional event followed by compressional tectonics prior to the collision with the Caribbean oceanic plateau. (C) 2019 International Association for Gondwana Research. Published by Elsevier B.V. All rights reserved.}, language = {en} } @article{Zantke2018, author = {Zantke, Michael}, title = {Die 68er-Bewegung und die Neue Rechte}, series = {WeltTrends : das außenpolitische Journal}, volume = {26}, journal = {WeltTrends : das außenpolitische Journal}, number = {141}, publisher = {WeltTrends}, address = {Potsdam}, isbn = {978-3-945878-94-1}, issn = {0944-8101}, pages = {40 -- 45}, year = {2018}, language = {de} } @phdthesis{Zakarias2018, author = {Zakari{\´a}s, Lilla}, title = {Transfer effects after working memory training in post-stroke aphasia}, doi = {10.25932/publishup-42360}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-423600}, school = {Universit{\"a}t Potsdam}, pages = {178}, year = {2018}, abstract = {Background: Individuals with aphasia after stroke (IWA) often present with working memory (WM) deficits. Research investigating the relationship between WM and language abilities has led to the promising hypothesis that treatments of WM could lead to improvements in language, a phenomenon known as transfer. Although recent treatment protocols have been successful in improving WM, the evidence to date is scarce and the extent to which improvements in trained tasks of WM transfer to untrained memory tasks, spoken sentence comprehension, and functional communication is yet poorly understood. Aims: We aimed at (a) investigating whether WM can be improved through an adaptive n-back training in IWA (Study 1-3); (b) testing whether WM training leads to near transfer to unpracticed WM tasks (Study 1-3), and far transfer to spoken sentence comprehension (Study 1-3), functional communication (Study 2-3), and memory in daily life in IWA (Study 2-3); and (c) evaluating the methodological quality of existing WM treatments in IWA (Study 3). To address these goals, we conducted two empirical studies - a case-controls study with Hungarian speaking IWA (Study 1) and a multiple baseline study with German speaking IWA (Study 2) - and a systematic review (Study 3). Methods: In Study 1 and 2 participants with chronic, post-stroke aphasia performed an adaptive, computerized n-back training. 'Adaptivity' was implemented by adjusting the tasks' difficulty level according to the participants' performance, ensuring that they always practiced at an optimal level of difficulty. To assess the specificity of transfer effects and to better understand the underlying mechanisms of transfer on spoken sentence comprehension, we included an outcome measure testing specific syntactic structures that have been proposed to involve WM processes (e.g., non-canonical structures with varying complexity). Results: We detected a mixed pattern of training and transfer effects across individuals: five participants out of six significantly improved in the n-back training. Our most important finding is that all six participants improved significantly in spoken sentence comprehension (i.e., far transfer effects). In addition, we also found far transfer to functional communication (in two participants out of three in Study 2) and everyday memory functioning (in all three participants in Study 2), and near transfer to unpracticed n-back tasks (in four participants out of six). Pooled data analysis of Study 1 and 2 showed a significant negative relationship between initial spoken sentence comprehension and the amount of improvement in this ability, suggesting that the more severe the participants' spoken sentence comprehension deficit was at the beginning of training, the more they improved after training. Taken together, we detected both near far and transfer effects in our studies, but the effects varied across participants. The systematic review evaluating the methodological quality of existing WM treatments in stroke IWA (Study 3) showed poor internal and external validity across the included 17 studies. Poor internal validity was mainly due to use of inappropriate design, lack of randomization of study phases, lack of blinding of participants and/or assessors, and insufficient sampling. Low external validity was mainly related to incomplete information on the setting, lack of use of appropriate analysis or justification for the suitability of the analysis procedure used, and lack of replication across participants and/or behaviors. Results in terms of WM, spoken sentence comprehension, and reading are promising, but further studies with more rigorous methodology and stronger experimental control are needed to determine the beneficial effects of WM intervention. Conclusions: Results of the empirical studies suggest that WM can be improved with a computerized and adaptive WM training, and improvements can lead to transfer effects to spoken sentence comprehension and functional communication in some individuals with chronic post-stroke aphasia. The fact that improvements were not specific to certain syntactic structures (i.e., non-canonical complex sentences) in spoken sentence comprehension suggest that WM is not involved in the online, automatic processing of syntactic information (i.e., parsing and interpretation), but plays a more general role in the later stage of spoken sentence comprehension (i.e., post-interpretive comprehension). The individual differences in treatment outcomes call for future research to clarify how far these results are generalizable to the population level of IWA. Future studies are needed to identify a few mechanisms that may generalize to at least a subpopulation of IWA as well as to investigate baseline non-linguistic cognitive and language abilities that may play a role in transfer effects and the maintenance of such effects. These may require larger yet homogenous samples.}, language = {en} } @article{ZakariasSalisWartenburger2018, author = {Zakarias, Lilla and Salis, Christos and Wartenburger, Isabell}, title = {Transfer effects on spoken sentence comprehension and functional communication after working memory training in stroke aphasia}, series = {Journal of neurolinguistics : an international journal for the study of brain function in language behavior and experience}, volume = {48}, journal = {Journal of neurolinguistics : an international journal for the study of brain function in language behavior and experience}, publisher = {Elsevier}, address = {Oxford}, issn = {0911-6044}, doi = {10.1016/j.jneuroling.2017.12.002}, pages = {47 -- 63}, year = {2018}, abstract = {Recent treatment protocols have been successful in improving working memory (WM) in individuals with aphasia. However, the evidence to date is small and the extent to which improvements in trained tasks of WM transfer to untrained memory tasks, spoken sentence comprehension, and functional communication is yet poorly understood. To address these issues, we conducted a multiple baseline study with three German-speaking individuals with chronic post stroke aphasia. Participants practised two computerised WM tasks (n-back with pictures and aback with spoken words) four times a week for a month, targeting two WM processes: updating WM representations and resolving interference. All participants showed improvement on at least one measure of spoken sentence comprehension and everyday memory activities. Two of them showed improvement also on measures of WM and functional communication. Our results suggest that WM can be improved through computerised training in chronic aphasia and this can transfer to spoken sentence comprehension and functional communication in some individuals.}, language = {en} } @article{ZabihiGraffSchumacheretal.2018, author = {Zabihi, Fatemeh and Graff, Patrick and Schumacher, Fabian and Kleuser, Burkhard and Hedtrich, Sarah and Haag, Rainer}, title = {Synthesis of poly(lactide-co-glycerol) as a biodegradable and biocompatible polymer with high loading capacity for dermal drug delivery}, series = {Nanoscale}, volume = {10}, journal = {Nanoscale}, number = {35}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {2040-3364}, doi = {10.1039/c8nr05536j}, pages = {16848 -- 16856}, year = {2018}, abstract = {Due to the low cutaneous bioavailability of tacrolimus (TAC), penetration enhancers are used to improve its penetration into the skin. However, poor loading capacity, non-biodegradability, toxicity, and in some cases inefficient skin penetration are challenging issues that hamper their applications for the dermal TAC delivery. Here we present poly(lactide-co-glycerol) (PLG) as a water soluble, biodegradable, and biocompatible TAC-carrier with high loading capacity (14.5\% w/w for TAC) and high drug delivery efficiencies into the skin. PLG was synthesized by cationic ring-opening copolymerization of a mixture of glycidol and lactide and showed 35 nm and 300 nm average sizes in aqueous solutions before and after loading of TAC, respectively. Delivery experiments on human skin, quantified by fluorescence microscopy and LC-MS/MS, showed a high ability for PLG to deposit Nile red and TAC into the stratum corneum and viable epidermis of skin in comparison with Protopic (R) (0.03\% w/w, TAC ointment). The cutaneous distribution profile of delivered TAC proved that 80\%, 16\%, and 4\% of the cutaneous drug level was deposited in the stratum corneum, viable epidermis, and upper dermis, respectively. TAC delivered by PLG was able to efficiently decrease the IL-2 and TSLP expressions in human skin models. Taking advantage of the excellent physicochemical and biological properties of PLG, it can be used for efficient dermal TAC delivery and potential treatment of inflammatory skin diseases.}, language = {en} } @article{YousfiHeweltBaueretal.2018, author = {Yousfi, Alaaeddine and Hewelt, Marcin and Bauer, Christine and Weske, Mathias}, title = {Toward uBPMN-Based patterns for modeling ubiquitous business processes}, series = {IEEE Transactions on Industrial Informatics}, volume = {14}, journal = {IEEE Transactions on Industrial Informatics}, number = {8}, publisher = {Inst. of Electr. and Electronics Engineers}, address = {Piscataway}, issn = {1551-3203}, doi = {10.1109/TII.2017.2777847}, pages = {3358 -- 3367}, year = {2018}, abstract = {Ubiquitous business processes are the new generation of processes that pervade the physical space and interact with their environments using a minimum of human involvement. Although they are now widely deployed in the industry, their deployment is still ad hoc . They are implemented after an arbitrary modeling phase or no modeling phase at all. The absence of a solid modeling phase backing up the implementation generates many loopholes that are stressed in the literature. Here, we tackle the issue of modeling ubiquitous business processes. We propose patterns to represent the recent ubiquitous computing features. These patterns are the outcome of an analysis we conducted in the field of human-computer interaction to examine how the features are actually deployed. The patterns' understandability, ease-of-use, usefulness, and completeness are examined via a user experiment. The results indicate that these four indexes are on the positive track. Hence, the patterns may be the backbone of ubiquitous business process modeling in industrial applications.}, language = {en} } @misc{YoungUedaGuehretal.2018, author = {Young, Linda and Ueda, Kiyoshi and G{\"u}hr, Markus and Bucksbaum, Philip H. and Simon, Marc and Mukamel, Shaul and Rohringer, Nina and Prince, Kevin C. and Masciovecchio, Claudio and Meyer, Michael and Rudenko, Artem and Rolles, Daniel and Bostedt, Christoph and Fuchs, Matthias and Reis, David A. and Santra, Robin and Kapteyn, Henry and Murnane, Margaret and Ibrahim, Heide and L{\´e}gar{\´e}, Fran{\c{c}}ois and Vrakking, Marc and Isinger, Marcus and Kroon, David and Gisselbrecht, Mathieu and L'Huillier, Anne and W{\"o}rner, Hans Jakob and Leone, Stephen R.}, title = {Roadmap of ultrafast x-ray atomic and molecular physics}, series = {Postprints der Universit{\"a}t Potsdam : Mathematisch-Naturwissenschaftliche Reihe}, journal = {Postprints der Universit{\"a}t Potsdam : Mathematisch-Naturwissenschaftliche Reihe}, number = {668}, issn = {1866-8372}, doi = {10.25932/publishup-42423}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-424238}, pages = {46}, year = {2018}, abstract = {X-ray free-electron lasers (XFELs) and table-top sources of x-rays based upon high harmonic generation (HHG) have revolutionized the field of ultrafast x-ray atomic and molecular physics, largely due to an explosive growth in capabilities in the past decade. XFELs now provide unprecedented intensity (1020 W cm-2) of x-rays at wavelengths down to ~1 {\AA}ngstrom, and HHG provides unprecedented time resolution (~50 attoseconds) and a correspondingly large coherent bandwidth at longer wavelengths. For context, timescales can be referenced to the Bohr orbital period in hydrogen atom of 150 attoseconds and the hydrogen-molecule vibrational period of 8 femtoseconds; wavelength scales can be referenced to the chemically significant carbon K-edge at a photon energy of ~280 eV (44 {\AA}ngstroms) and the bond length in methane of ~1 {\AA}ngstrom. With these modern x-ray sources one now has the ability to focus on individual atoms, even when embedded in a complex molecule, and view electronic and nuclear motion on their intrinsic scales (attoseconds and {\AA}ngstroms). These sources have enabled coherent diffractive imaging, where one can image non-crystalline objects in three dimensions on ultrafast timescales, potentially with atomic resolution. The unprecedented intensity available with XFELs has opened new fields of multiphoton and nonlinear x-ray physics where behavior of matter under extreme conditions can be explored. The unprecedented time resolution and pulse synchronization provided by HHG sources has kindled fundamental investigations of time delays in photoionization, charge migration in molecules, and dynamics near conical intersections that are foundational to AMO physics and chemistry. This roadmap coincides with the year when three new XFEL facilities, operating at {\AA}ngstrom wavelengths, opened for users (European XFEL, Swiss-FEL and PAL-FEL in Korea) almost doubling the present worldwide number of XFELs, and documents the remarkable progress in HHG capabilities since its discovery roughly 30 years ago, showcasing experiments in AMO physics and other applications. Here we capture the perspectives of 17 leading groups and organize the contributions into four categories: ultrafast molecular dynamics, multidimensional x-ray spectroscopies; high-intensity x-ray phenomena; attosecond x-ray science.}, language = {en} } @article{YoungUedaGuehretal.2018, author = {Young, Linda and Ueda, Kiyoshi and G{\"u}hr, Markus and Bucksbaum, Philip H. and Simon, Marc and Mukamel, Shaul and Rohringer, Nina and Prince, Kevin C. and Masciovecchio, Claudio and Meyer, Michael and Rudenko, Artem and Rolles, Daniel and Bostedt, Christoph and Fuchs, Matthias and Reis, David A. and Santra, Robin and Kapteyn, Henry and Murnane, Margaret and Ibrahim, Heide and Legare, Francois and Vrakking, Marc and Isinger, Marcus and Kroon, David and Gisselbrecht, Mathieu and W{\"o}rner, Hans Jakob and Leone, Stephen R.}, title = {Roadmap of ultrafast x-ray atomic and molecular physics}, series = {Journal of physics : B, Atomic, molecular and optical physics}, volume = {51}, journal = {Journal of physics : B, Atomic, molecular and optical physics}, number = {3}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0953-4075}, doi = {10.1088/1361-6455/aa9735}, pages = {45}, year = {2018}, abstract = {X-ray free-electron lasers (XFELs) and table-top sources of x-rays based upon high harmonic generation (HHG) have revolutionized the field of ultrafast x-ray atomic and molecular physics, largely due to an explosive growth in capabilities in the past decade. XFELs now provide unprecedented intensity (10(20) W cm(-2)) of x-rays at wavelengths down to similar to 1 Angstrom, and HHG provides unprecedented time resolution (similar to 50 attoseconds) and a correspondingly large coherent bandwidth at longer wavelengths. For context, timescales can be referenced to the Bohr orbital period in hydrogen atom of 150 attoseconds and the hydrogen-molecule vibrational period of 8 femtoseconds; wavelength scales can be referenced to the chemically significant carbon K-edge at a photon energy of similar to 280 eV (44 Angstroms) and the bond length in methane of similar to 1 Angstrom. With these modern x-ray sources one now has the ability to focus on individual atoms, even when embedded in a complex molecule, and view electronic and nuclear motion on their intrinsic scales (attoseconds and Angstroms). These sources have enabled coherent diffractive imaging, where one can image non-crystalline objects in three dimensions on ultrafast timescales, potentially with atomic resolution. The unprecedented intensity available with XFELs has opened new fields of multiphoton and nonlinear x-ray physics where behavior of matter under extreme conditions can be explored. The unprecedented time resolution and pulse synchronization provided by HHG sources has kindled fundamental investigations of time delays in photoionization, charge migration in molecules, and dynamics near conical intersections that are foundational to AMO physics and chemistry. This roadmap coincides with the year when three new XFEL facilities, operating at Angstrom wavelengths, opened for users (European XFEL, Swiss-FEL and PAL-FEL in Korea) almost doubling the present worldwide number of XFELs, and documents the remarkable progress in HHG capabilities since its discovery roughly 30 years ago, showcasing experiments in AMO physics and other applications. Here we capture the perspectives of 17 leading groups and organize the contributions into four categories: ultrafast molecular dynamics, multidimensional x-ray spectroscopies; high-intensity x-ray phenomena; attosecond x-ray science.}, language = {en} } @article{Yilmaz2018, author = {Yilmaz, Zafer}, title = {Revising the culture of political protest after the gezi uprising in Turkey}, series = {Mediterranean Quarterly}, volume = {29}, journal = {Mediterranean Quarterly}, number = {3}, publisher = {Duke Univ. Press}, address = {Durham}, issn = {1047-4552}, doi = {10.1215/10474552-7003168}, pages = {55 -- 77}, year = {2018}, abstract = {The Gezi uprising can be considered a crucial turning in Turkish politics. As a response to countrywide democratic protests, the Justice and Development Party (AKP) government revived the security state, escalated authoritarian tendencies, and started to organize a nationalist, Islamist, and conservative backlash. This essay argues that the Gezi Park protests revealed both the fragility of the AKP's hegemony and the limits of the dominant political group habitus, which were promoted by the party to consolidate political polarization in favor of the party's hegemony. Moreover, it is argued that the Gezi uprising transformed the culture of political protests in the country and paved the way for the emergence of affirmative resistance, radical imagination, and a new politics of desire and dignity against authoritarian and neoliberal policies.}, language = {en} } @article{Yedidya2018, author = {Yedidya, Asaf}, title = {Enlisted History}, series = {PaRDES : Zeitschrift der Vereinigung f{\"u}r J{\"u}dische Studien e. V.}, journal = {PaRDES : Zeitschrift der Vereinigung f{\"u}r J{\"u}dische Studien e. V.}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-417808}, pages = {79 -- 101}, year = {2018}, abstract = {Zeev Jawitz (1847-1924) was active in all spheres of culture: history, language, literature and pedagogy, all the while striving for harmonization with the Orthodox outlook. He understood that a people returning to its homeland needed a national culture, one that was both broad and deep, and that the narrow world of the Halakhah would no longer suffice. His main work was the multi-volume Toldot Israel (History of Israel, published 1895-1924) which encompasses Jewish history from its beginning - Patriarchs - until the end of the 19th century. His historical writing, with its emphasis on internal religious Jewish sources, the unity and continuity of Jewish history, and respect of Orthodox principles, comes as an alternative to the historiography of the celebrated historian Heinrich Graetz. The alternative that Jawitz tried to substitute for Wissenschaft des Judentums, was influenced not only by Orthodox ideology, which he supported, but also by his nationalist ideology. He saw himself and his disciples as the "priests of memory," presenting the true and immanent history and character of the Jewish nation as a platform to the Jewish future in the land of Israel.}, language = {en} } @article{YeKurthHospodarskyetal.2018, author = {Ye, Shengyi and Kurth, William S. and Hospodarsky, George B. and Persoon, Ann M. and Sulaiman, Ali H. and Gurnett, Don A. and Morooka, Michiko and Wahlund, Jan-Erik and Hsu, Hsiang-Wen and Sternovsky, Zoltan and Wang, Xu and Horanyi, M. and Seiss, Martin and Srama, Ralf}, title = {Dust Observations by the Radio and Plasma Wave Science Instrument During}, series = {Geophysical research letters}, volume = {45}, journal = {Geophysical research letters}, number = {19}, publisher = {American Geophysical Union}, address = {Washington}, issn = {0094-8276}, doi = {10.1029/2018GL078059}, pages = {10101 -- 10109}, year = {2018}, abstract = {Plain Language Summary Cassini flew through the gap between Saturn and its rings for 22 times before plunging into the atmosphere of Saturn, ending its 20-year mission. The radio and plasma waves instrument on board Cassini helped quantify the dust hazard in this previously unexplored region. The measured density of large dust particles was much lower than expected, allowing high-value science observations during the subsequent Grand Finale orbits.}, language = {en} } @article{YeKurthHospodarskyetal.2018, author = {Ye, S. -Y. and Kurth, William S. and Hospodarsky, George B. and Persoon, Ann M. and Gurnett, Don A. and Morooka, Michiko and Wahlund, Jan-Erik and Hsu, Hsiang-Wen and Seiss, Martin and Srama, Ralf}, title = {Cassini RPWS dust observation near the Janus/Epimetheus orbit}, series = {Journal of geophysical research : Space physics}, volume = {123}, journal = {Journal of geophysical research : Space physics}, number = {6}, publisher = {American Geophysical Union}, address = {Washington}, issn = {2169-9380}, doi = {10.1029/2017JA025112}, pages = {4952 -- 4960}, year = {2018}, abstract = {During the Ring Grazing orbits near the end of Cassini mission, the spacecraft crossed the equatorial plane near the orbit of Janus/Epimetheus (similar to 2.5 Rs). This region is populated with dust particles that can be detected by the Radio and Plasma Wave Science (RPWS) instrument via an electric field antenna signal. Analysis of the voltage waveforms recorded on the RPWS antennas provides estimations of the density and size distribution of the dust particles. Measured RPWS profiles, fitted with Lorentzian functions, are shown to be mostly consistent with the Cosmic Dust Analyzer, the dedicated dust instrument on board Cassini. The thickness of the dusty ring varies between 600 and 1,000 km. The peak location shifts north and south within 100 km of the ring plane, likely a function of the precession phase of Janus orbit.}, language = {en} } @article{YazmaciyanStolterfohtBurnetal.2018, author = {Yazmaciyan, Aren and Stolterfoht, Martin and Burn, Paul L. and Lin, Qianqian and Meredith, Paul and Armin, Ardalan}, title = {Recombination losses above and below the transport percolation threshold in bulk heterojunction organic solar cells}, series = {Advanced energy materials}, volume = {8}, journal = {Advanced energy materials}, number = {18}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {1614-6832}, doi = {10.1002/aenm.201703339}, pages = {8}, year = {2018}, abstract = {Achieving the highest power conversion efficiencies in bulk heterojunction organic solar cells requires a morphology that delivers electron and hole percolation pathways for optimized transport, plus sufficient donor:acceptor contact area for near unity charge transfer state formation. This is a significant structural challenge, particularly in semiconducting polymer:fullerene systems. This balancing act in the model high efficiency PTB7:PC70BM blend is studied by tuning the donor:acceptor ratio, with a view to understanding the recombination loss mechanisms above and below the fullerene transport percolation threshold. The internal quantum efficiency is found to be strongly correlated to the slower carrier mobility in agreement with other recent studies. Furthermore, second-order recombination losses dominate the shape of the current density-voltage curve in efficient blend combinations, where the fullerene phase is percolated. However, below the charge transport percolation threshold, there is an electric-field dependence of first-order losses, which includes electric-field-dependent photogeneration. In the intermediate regime, the fill factor appears to be limited by both first- and second-order losses. These findings provide additional basic understanding of the interplay between the bulk heterojunction morphology and the order of recombination in organic solar cells. They also shed light on the limitations of widely used transport models below the percolation threshold.}, language = {en} } @misc{YarmanKurbanogluJetzschmannetal.2018, author = {Yarman, Aysu and Kurbanoglu, Sevinc and Jetzschmann, Katharina J. and Ozkan, Sibel A. and Wollenberger, Ulla and Scheller, Frieder W.}, title = {Electrochemical MIP-Sensors for Drugs}, series = {Current Medicinal Chemistry}, volume = {25}, journal = {Current Medicinal Chemistry}, number = {33}, publisher = {Bentham Science Publishers LTD}, address = {Sharjah}, issn = {0929-8673}, doi = {10.2174/0929867324666171005103712}, pages = {4007 -- 4019}, year = {2018}, abstract = {In order to replace bio-macromolecules by stable synthetic materials in separation techniques and bioanalysis biomimetic receptors and catalysts have been developed: Functional monomers are polymerized together with the target analyte and after template removal cavities are formed in the "molecularly imprinted polymer" (MIP) which resemble the active sites of antibodies and enzymes. Starting almost 80 years ago, around 1,100 papers on MIPs were published in 2016. Electropolymerization allows to deposit MIPs directly on voltammetric electrodes or chips for quartz crystal microbalance (QCM) and surface plasmon resonance (SPR). For the readout of MIPs for drugs amperometry, differential pulse voltammetry (DPV) and impedance spectroscopy (EIS) offer higher sensitivity as compared with QCM or SPR. Application of simple electrochemical devices allows both the reproducible preparation of MIP sensors, but also the sensitive signal generation. Electrochemical MIP-sensors for the whole arsenal of drugs, e.g. the most frequently used analgesics, antibiotics and anticancer drugs have been presented in literature and tested under laboratory conditions. These biomimetic sensors typically have measuring ranges covering the lower nano-up to millimolar concentration range and they are stable under extreme pH and in organic solvents like nonaqueous extracts.}, language = {en} } @article{Yarman2018, author = {Yarman, Aysu}, title = {Electrosynthesized Molecularly Imprinted Polymer for Laccase Using the Inactivated Enzyme as the Target}, series = {Bulletin of the Korean chemical society}, volume = {39}, journal = {Bulletin of the Korean chemical society}, number = {4}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {1229-5949}, doi = {10.1002/bkcs.11413}, pages = {483 -- 488}, year = {2018}, abstract = {The first molecularly imprinted polymer (MIP) for the recognition of the copper-enzyme laccase was successfully prepared by electropolymerizing scopoletin in the presence of alkaline-inactivated enzyme. Laccase-MIP and the control polymer without laccase (nonimprinted polymer, NIP) were characterized by voltammetry using the redox marker ferricyanide. After electropolymerization, the signals for ferricyanide for both the MIP and the NIP were almost completely suppressed and increased after removal of the target from the polymer layer. Rebinding of both inactivated and active laccase decreased the ferricyanide peak currents to almost equal extent. The relative decrease of signal suppression approached saturation above 10 nM. Furthermore, the surface activity of rebound laccase toward the oxidation of catechol was investigated. The surface activity approached saturation above 10 nM, a value close to the value of the measurements with ferricyanide. Interaction of NIP with laccase brought about a six times smaller signal of catechol oxidation.}, language = {en} } @misc{Yapar2018, type = {Master Thesis}, author = {Yapar, Diren}, title = {Linguistic Landscapes - Eine Untersuchung zur Repr{\"a}sentation von visueller Mehrsprachigkeit in Berliner Krankenh{\"a}usern}, doi = {10.25932/publishup-46001}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-460019}, school = {Universit{\"a}t Potsdam}, pages = {II, 55}, year = {2018}, abstract = {Die empirische Studie untersucht, inwieweit die gesellschaftliche Mehrsprachigkeit in Berlin in den verschiedenen Beschilderungstypen der Berliner Krankenh{\"a}user vertreten ist. Damit f{\"u}gt sich die Arbeit thematisch in die Untersuchung von "Sprachlandschaften" ein, einem neu entstehenden soziolinguistisch orientierten Forschungsfeld, das Zusammenh{\"a}nge zwischen sozialer Mehrsprachigkeit und ihrer {\"o}ffentlichen visuellen Repr{\"a}sentation untersucht und aufdeckt. Welche Sprachen sind in welchen Diskurstypen in Berliner Krankenh{\"a}usern sichtbar? Wie entwickelt sich die Entscheidungspolitik, auf deren Grundlage Mehrsprachigkeit in Krankenh{\"a}usern sichtbar wird? F{\"u}r die Befragung wurde jedes Krankenhaus in jedem der zw{\"o}lf Berliner Bezirke besucht und die Ergebnisse durch Bilddateien dokumentiert. Das Ergebnis dieser Studie ist ein umfassendes Korpus.}, language = {de} } @article{YaoubaKochGuantaietal.2018, author = {Yaouba, Souaibou and Koch, Andreas and Guantai, Eric M. and Derese, Solomon and Irungu, Beatrice and Heydenreich, Matthias and Yenesew, Abiy}, title = {Alkenyl cyclohexanone derivatives from Lannea rivae and Lannea schweinfurthii}, series = {Phytochemistry letters / Phytochemical Society of Europe}, volume = {23}, journal = {Phytochemistry letters / Phytochemical Society of Europe}, publisher = {Elsevier}, address = {Amsterdam}, issn = {1874-3900}, doi = {10.1016/j.phytol.2017.12.001}, pages = {141 -- 148}, year = {2018}, abstract = {Phytochemical investigation of the CH2Cl2/MeOH (1:1) extract of the roots of Lannea rivae (Chiov) Sacleux (Anacardiaceae) led to the isolation of a new alkenyl cyclohexenone derivative: (4R,6S)-4,6-dihydroxy-6-((Z)-nonadec-14′-en-1-yl)cyclohex-2-en-1-one (1), and a new alkenyl cyclohexanol derivative: (2S*,4R*,5S*)-2,4,5-trihydroxy-2-((Z)-nonadec-14′-en-1-yl)cyclohexanone (2) along with four known compounds, namely epicatechin gallate, taraxerol, taraxerone and β-sitosterol; while the stem bark afforded two known compounds, daucosterol and lupeol. Similar investigation of the roots of Lannea schweinfurthii (Engl.) Engl. led to the isolation of four known compounds: 3-((E)-nonadec-16′-enyl)phenol, 1-((E)-heptadec-14′-enyl)cyclohex-4-ene-1,3-diol, catechin, and 1-((E)-pentadec-12′-enyl)cyclohex-4-ene-1,3-diol. The structures of the isolated compounds were determined by NMR spectroscopy and mass spectrometry. The absolute configuration of compound 1 was established by quantum chemical ECD calculations. In an antibacterial activity assay using the microbroth kinetic method, compound 1 showed moderate activity against Escherichia coli while compound 2 exhibited moderate activity against Staphylococcus aureus. Compound 1 also showed moderate activity against E. coli using the disc diffusion method. The roots extract of L. rivae was notably cytotoxic against both the DU-145 prostate cancer cell line and the Vero mammalian cell line (CC50 = 5.24 and 5.20 μg/mL, respectively). Compound 1 was also strongly cytotoxic against the DU-145 cell line (CC50 = 0.55 μg/mL) but showed no observable cytotoxicity (CC50 > 100 μg/mL) against the Vero cell line. The roots extract of L. rivae and L. schweinfurthii, epicatechin gallate as well as compound 1 exhibited inhibition of carageenan-induced inflammation.}, language = {en} } @article{YannelliKarrerHalletal.2018, author = {Yannelli, Florencia A. and Karrer, Gerhard and Hall, Rea and Kollmann, Johannes and Heger, Tina}, title = {Seed density is more effective than multi-trait limiting similarity in controlling grassland resistance against plant invasions in mesocosms}, series = {Applied vegetation science : official organ of the International Association for Vegetation Science}, volume = {21}, journal = {Applied vegetation science : official organ of the International Association for Vegetation Science}, number = {3}, publisher = {Wiley}, address = {Hoboken}, issn = {1402-2001}, doi = {10.1111/avsc.12373}, pages = {411 -- 418}, year = {2018}, abstract = {QuestionDisturbed areas offer great opportunities for restoring native biodiversity, but they are also prone to invasion by alien plants. Following the limiting similarity hypothesis, we address the question of whether or not similarity of plant functional traits helps developing seed mixtures of native communities with high resistance to invasive species at an early stage of restoration. LocationCentre of Greenhouses and Laboratories Durnast, Technische Universitat Munchen, Freising, Germany. MethodsUsing a system of linear equations, we designed native communities maximizing the similarity between the native and two invasive species according to ten functional traits. We used native grassland plants, two invasive alien species that are often problematic in disturbed areas (i.e., Ambrosia artemisiifolia and Solidago gigantea) and trait information obtained from databases. The two communities were then tested for resistance against establishment of the two invaders separately in a greenhouse experiment. We measured height of the invasive species and above-ground biomass, along with leaf area index, 4 and 8months after sowing respectively. ResultsBoth invasive species were successfully reduced by the native community designed to suppress S. gigantea dominated by small-seeded species. These results could be considered as partial support for the limiting similarity hypothesis. However, given the success of this mixture against both invasive species, suppression was better explained by a seed density effect resulting from the smaller seed mass of the native species included in this mixture. Further, the dominance of a fast-developing competitive species could also contribute to its success. ConclusionsThere was no unequivocal support for the limiting similarity hypothesis in terms of the traits selected. Instead we found that increasing seeding density of native species and selecting species with a fast vegetative development is an effective way to suppress invasive plants during early stages of restoration. If limiting similarity is used to design communities for restoration, early life-history traits should be taken into account.}, language = {en} } @article{YangZhuWolfetal.2018, author = {Yang, Jie and Zhu, Xiaolei and Wolf, Thomas J. A. and Li, Zheng and Nunes, Jo{\~a}o Pedro Figueira and Coffee, Ryan and Cryan, James P. and G{\"u}hr, Markus and Hegazy, Kareem and Heinz, Tony F. and Jobe, Keith and Li, Renkai and Shen, Xiaozhe and Veccione, Theodore and Weathersby, Stephen and Wilkin, Kyle J. and Yoneda, Charles and Zheng, Qiang and Martinez, Todd J. and Centurion, Martin and Wang, Xijie}, title = {Imaging CF3I conical intersection and photodissociation dynamics with ultrafast electron diffraction}, series = {Science}, volume = {361}, journal = {Science}, number = {6397}, publisher = {American Assoc. for the Advancement of Science}, address = {Washington}, issn = {0036-8075}, doi = {10.1126/science.aat0049}, pages = {64 -- 67}, year = {2018}, abstract = {Conical intersections play a critical role in excited-state dynamics of polyatomic molecules because they govern the reaction pathways of many nonadiabatic processes. However, ultrafast probes have lacked sufficient spatial resolution to image wave-packet trajectories through these intersections directly. Here, we present the simultaneous experimental characterization of one-photon and two-photon excitation channels in isolated CF3I molecules using ultrafast gas-phase electron diffraction. In the two-photon channel, we have mapped out the real-space trajectories of a coherent nuclear wave packet, which bifurcates onto two potential energy surfaces when passing through a conical intersection. In the one-photon channel, we have resolved excitation of both the umbrella and the breathing vibrational modes in the CF3 fragment in multiple nuclear dimensions. These findings benchmark and validate ab initio nonadiabatic dynamics calculations.}, language = {en} } @article{YangHuDingetal.2018, author = {Yang, Guang and Hu, Rongting and Ding, Hong-ming and Kochovski, Zdravko and Mei, Shilin and Lu, Yan and Ma, Yu-qiang and Chen, Guosong and Jiang, Ming}, title = {CO2-switchable response of protein microtubules}, series = {Materials chemistry frontiers}, volume = {2}, journal = {Materials chemistry frontiers}, number = {9}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {2052-1537}, doi = {10.1039/c8qm00245b}, pages = {1642 -- 1646}, year = {2018}, abstract = {Recently, we proposed a small molecular inducing ligand strategy to assemble proteins into highly-ordered structures via dual non-covalent interactions, i.e. carbohydrate-protein interaction and dimerization of Rhodamine B. Using this approach, artificial protein microtubules were successfully constructed. In this study, we find that these microtubules exhibit a perfect CO2 responsiveness; assembly and disassembly of these microtubules were nicely controlled by the alternative passage of CO2 and N-2. Upon the injection of CO2, a negative net-charged SBA turns into a neutral or positive net-charged SBA, which elongated, to some extent, the effective distance between SBA and Rhodamine B, resulting in the disassociation of the Rhodamine B dimer. Further experimental and simulation results reveal that the CO2-responsive mechanism differs from that of solubility change of the previously reported CO2-responsive synthetic materials.}, language = {en} } @article{YanRudolphNoecheletal.2018, author = {Yan, Wan and Rudolph, Tobias and N{\"o}chel, Ulrich and Gould, Oliver E. C. and Behl, Marc and Kratz, Karl and Lendlein, Andreas}, title = {Reversible actuation of thermoplastic multiblock copolymers with overlapping thermal transitions of crystalline and glassy domains}, series = {Macromolecules : a publication of the American Chemical Society}, volume = {51}, journal = {Macromolecules : a publication of the American Chemical Society}, number = {12}, publisher = {American Chemical Society}, address = {Washington}, issn = {0024-9297}, doi = {10.1021/acs.macromol.8b00322}, pages = {4624 -- 4632}, year = {2018}, abstract = {Polymeric materials possessing specific features like programmability, high deformability, and easy processability are highly desirable for creating modern actuating systems. In this study, thermoplastic shape-memory polymer actuators obtained by combining crystallizable poly(epsilon-caprolactone) (PCL) and poly(3S-isobutylmorpholin-2,5-dione) (PIBMD) segments in multiblock copolymers are described. We designed these materials according to our hypothesis that the confinement of glassy PIBMD domains present at the upper actuation temperature contribute to the stability of the actuator skeleton, especially at large programming strains. The copolymers have a phase-segregated morphology, indicated by the well-separated melting and glass transition temperatures for PIBMD and PCL, but possess a partially overlapping T-m of PCL and T-g of PIBMD in the temperature interval from 40 to 60 degrees C. Crystalline PIBMD hard domains act as strong physical netpoints in the PIBMD-PCL bulk material enabling high deformability (up to 2000\%) and good elastic recoverability (up to 80\% at 50 degrees C above T-m,T-PCL). In the programmed thermoplastic actuators a high content of crystallizable PCL actuation domains ensures pronounced thermoreversible shape changes upon repetitive cooling and heating. The programmed actuator skeleton, composed of PCL crystals present at the upper actuation temperature T-high and the remaining glassy PIBMD domains, enabled oriented crystallization upon cooling. The actuation performance of PIBMD-PCL could be tailored by balancing the interplay between actuation and skeleton, but also by varying the quantity of crystalline PIBMD hard domains via the copolymer composition, the applied programming strain, and the choice of T-high. The actuator with 17 mol\% PIBMD showed the highest reversible elongation of 11.4\% when programmed to a strain of 900\% at 50 degrees C. It is anticipated that the presented thermoplastic actuator materials can be applied as modern compression textiles.}, language = {en} } @article{YanFangNoecheletal.2018, author = {Yan, Wan and Fang, Liang and N{\"o}chel, Ulrich and Gould, Oliver E. C. and Behl, Marc and Kratz, Karl and Lendlein, Andreas}, title = {Investigating the roles of crystallizable and glassy switching segments within multiblock copolymer shape-memory materials}, series = {MRS Advances}, volume = {3}, journal = {MRS Advances}, number = {63}, publisher = {Cambridge Univ. Press}, address = {New York}, issn = {2059-8521}, doi = {10.1557/adv.2018.590}, pages = {3741 -- 3749}, year = {2018}, abstract = {The variation of the molecular architecture of multiblock copolymers has enabled the introduction of functional behaviour and the control of key mechanical properties. In the current study, we explore the synergistic relationship of two structural components in a shape-memory material formed of a multiblock copolymer with crystallizable poly(epsilon-caprolactone) and crystallizable polyfoligo(3S-iso-butylmorpholine-2,5-dione) segments (PCL-PIBMD). The thermal and structural properties of PCL-PIBMD films were compared with PCI.-PU and PMMD-PU investigated by means of DSC, SAXS and WARS measurements. The shape-memory properties were quantified by cyclic, thermomechanical tensile tests, where deformation strains up to 900\% were applied for programming PCL-PIBMD films at 50 degrees C. Toluene vapor treatment experiments demonstrated that the temporary shape was fixed mainly by glassy PIBMD domains at strains lower than 600\% with the PCL contribution to fixation increasing to 42 +/- 2\% at programming strains of 900\% This study into the shape-memory mechanism of PCL-PIBMD provides insight into the structure function relation in multiblock copolymers with both crystallizable and glassy switching segments.}, language = {en} } @article{YamazakiStolleMatzkaetal.2018, author = {Yamazaki, Yosuke and Stolle, Claudia and Matzka, J{\"u}rgen and Liu, Huixin and Tao, Chihiro}, title = {Interannual variability of the daytime equatorial ionospheric electric field}, series = {Journal of geophysical research : Space physics}, volume = {123}, journal = {Journal of geophysical research : Space physics}, number = {5}, publisher = {American Geophysical Union}, address = {Washington}, issn = {2169-9380}, doi = {10.1029/2017JA025165}, pages = {4241 -- 4256}, year = {2018}, abstract = {Understanding the variability of the ionosphere is important for the prediction of space weather and climate. Recent studies have shown that forcing from the lower atmosphere plays a significant role for the short-term (day-to-day) variability of the low-latitude ionosphere. The present study aims to assess the importance of atmospheric forcing for the variability of the daytime equatorial ionospheric electric field on the interannual (year-to-year) time scale. Magnetic field measurements from Huancayo (12.05 degrees S, 75.33 degrees W) are used to augment the equatorial vertical plasma drift velocity (V-Z) measurements from the Jicamarca Unattended Long-term Investigations of the Ionosphere and Atmosphere radar during 2001-2016. V-Z can be regarded as a measure of the zonal electric field. After removing the seasonal variation of similar to 10m/s, midday values of V-Z show an interannual variation of similar to 2m/s with an oscillation period of 2-3years. No evidence of solar cycle influence is found. The Ground-to-topside Atmosphere-Ionosphere model for Aeronomy, which takes into account realistic atmospheric variability below 30km, reproduces the pattern of the observed interannual variation without having to include variable forcing from the magnetosphere. The results indicate that lower atmospheric forcing plays a dominant role for the observed interannual variability of V-Z at 1200 local time.}, language = {en} } @article{YamazakiStolleMatzkaetal.2018, author = {Yamazaki, Yosuke and Stolle, Claudia and Matzka, J{\"u}rgen and Alken, Patrick}, title = {Quasi-6-Day Wave Modulation of the Equatorial Electrojet}, series = {Journal of geophysical research : Space physics}, volume = {123}, journal = {Journal of geophysical research : Space physics}, number = {5}, publisher = {American Geophysical Union}, address = {Washington}, issn = {2169-9380}, doi = {10.1029/2018JA025365}, pages = {4094 -- 4109}, year = {2018}, abstract = {The equatorial electrojet is an enhanced eastward current in the dayside E region ionosphere flowing along the magnetic equator. The equatorial electrojet is highly variable as it is subject to various forcing mechanisms including atmospheric waves from the lower layers of the atmosphere. There are occasionally times when the intensity of the equatorial electrojet at a fixed longitude shows an oscillatory variation with a period of approximately 6days. We present case studies of such events based on the equatorial electrojet measurements from the CHAMP and Swarm satellites. The spatial and temporal variability of the equatorial electrojet intensity during these events reveals characteristics of a westward propagating wave with zonal wavenumber 1, consistent with the effect of the quasi-6-day planetary wave. Analyses of the geopotential height data from the Aura satellite confirm the presence of the quasi-6-day planetary wave in the lower thermosphere during the events. The amplitude of the quasi-6-day variation in the equatorial electrojet intensity depends on longitude, but no systematic longitudinal dependence is found for different events. During the event of August 2010, quasi-6-day variations are also observed by ground-based magnetometers and a radar in the Peruvian sector. The effect of the quasi-6-day wave accounts for up to +/- 5.9m/s in the equatorial vertical plasma velocity at noon, which is much larger than previously predicted by a numerical model. These results suggest that the quasi-6-day planetary wave is an important source of short-term variability in the equatorial ionosphere.}, language = {en} } @article{YalewPilzSchweitzeretal.2018, author = {Yalew, S. G. and Pilz, Tobias and Schweitzer, C. and Liersch, Stefan and van der Kwast, J. and van Griensven, A. and Mul, Marloes L. and Dickens, Chris and van der Zaag, Pieter}, title = {Coupling land-use change and hydrologic models for quantification of catchment ecosystem services}, series = {Environmental modelling \& software with environment data news}, volume = {109}, journal = {Environmental modelling \& software with environment data news}, publisher = {Elsevier}, address = {Oxford}, issn = {1364-8152}, doi = {10.1016/j.envsoft.2018.08.029}, pages = {315 -- 328}, year = {2018}, abstract = {Representation of land-use and hydrologic interactions in respective models has traditionally been problematic. The use of static land-use in most hydrologic models or that of the use of simple hydrologic proxies in land-use change models call for more integrated approaches. The objective of this study is to assess whether dynamic feedback between land-use change and hydrology can (1) improve model performances, and/or (2) produce a more realistic quantification of ecosystem services. To test this, we coupled a land-use change model and a hydrologic mode. First, the land-use change and the hydrologic models were separately developed and calibrated. Then, the two models were dynamically coupled to exchange data at yearly time-steps. The approach is applied to a catchment in South Africa. Performance of coupled models when compared to the uncoupled models were marginal, but the coupled models excelled at the quantification of catchment ecosystem services more robustly.}, language = {en} } @article{YalcinkayaBresselLindneretal.2018, author = {Yalcinkaya, Hacer and Bressel, Katharina and Lindner, Peter and Gradzielski, Michael}, title = {Controlled formation of vesicles with added styrene and their fixation by polymerization}, series = {Journal of colloid and interface science}, volume = {531}, journal = {Journal of colloid and interface science}, publisher = {Elsevier}, address = {San Diego}, issn = {0021-9797}, doi = {10.1016/j.jcis.2018.07.097}, pages = {672 -- 680}, year = {2018}, abstract = {Hypothesis: An effective way for fixating vesicle structures is the insertion of monomers and cross-linking agents into their bilayer, and their subsequent polymerization can lead to the formation of polymeric nanocapsules. Particularly attractive here are vesicle systems that form spontaneously well-defined small vesicles, as obtaining such small nanocapsules with sizes below 100 nm is still challenging. Experiments: A spontaneously forming well-defined vesicle system composed of the surfactants TDMAO (tetradecyldimethylamine oxide), Pluronic L35, and LiPFOS (lithium perfluorooctylsulfonate) mixture was used as template for fixation by polymerization. Therefore, styrene monomer was incorporated into the vesicle bilayer and ultimately these structures were fixated by UV induced radical polymerization. Structural alteration of the vesicles upon loading with monomer and the cross-linker as well as the effect of subsequent polymerization in the membrane were investigated in detail by turbidity measurements, dynamic and static light scattering, (DLS, SLS), and small angle neutron scattering (SANS). Findings: The analysis showed the changes on vesicle structures due to the monomer loading, and that these structures can become permanently fixed by the polymerization process. The potential of this approach to produce well-defined nanocapsules starting from a self-assembled system and following polymerization is critically evaluated. (C) 2018 Elsevier Inc. All rights reserved.}, language = {en} } @misc{YadavalliLoebnerPapkeetal.2018, author = {Yadavalli, Nataraja Sekhar and Loebner, Sarah and Papke, Thomas and Sava, Elena and Hurduc, Nicolae and Santer, Svetlana}, title = {A comparative study of photoinduced deformation in azobenzene containing polymer films}, series = {Postprints der Universit{\"a}t Potsdam : Mathematisch-Naturwissenschaftliche Reihe}, journal = {Postprints der Universit{\"a}t Potsdam : Mathematisch-Naturwissenschaftliche Reihe}, number = {458}, issn = {1866-8372}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-413510}, year = {2018}, abstract = {In this paper two groups supporting different views on the mechanism of light induced polymer deformation argue about the respective underlying theoretical conceptions, in order to bring this interesting debate to the attention of the scientific community. The group of Prof. Nicolae Hurduc supports the model claiming that the cyclic isomerization of azobenzenes may cause an athermal transition of the glassy azobenzene containing polymer into a fluid state, the so-called photo-fluidization concept. This concept is quite convenient for an intuitive understanding of the deformation process as an anisotropic flow of the polymer material. The group of Prof. Svetlana Santer supports the re-orientational model where the mass-transport of the polymer material accomplished during polymer deformation is stated to be generated by the light-induced re-orientation of the azobenzene side chains and as a consequence of the polymer backbone that in turn results in local mechanical stress, which is enough to irreversibly deform an azobenzene containing material even in the glassy state. For the debate we chose three polymers differing in the glass transition temperature, 32 °C, 87 °C and 95 °C, representing extreme cases of flexible and rigid materials. Polymer film deformation occurring during irradiation with different interference patterns is recorded using a homemade set-up combining an optical part for the generation of interference patterns and an atomic force microscope for acquiring the kinetics of film deformation. We also demonstrated the unique behaviour of azobenzene containing polymeric films to switch the topography in situ and reversibly by changing the irradiation conditions. We discuss the results of reversible deformation of three polymers induced by irradiation with intensity (IIP) and polarization (PIP) interference patterns, and the light of homogeneous intensity in terms of two approaches: the re-orientational and the photo-fluidization concepts. Both agree in that the formation of opto-mechanically induced stresses is a necessary prerequisite for the process of deformation. Using this argument, the deformation process can be characterized either as a flow or mass transport.}, language = {en} } @article{XuAngiolettiUbertiLuetal.2018, author = {Xu, Xiao and Angioletti-Uberti, Stefano and Lu, Yan and Dzubiella, Joachim and Ballauff, Matthias}, title = {Interaction of Proteins with Polyelectrolytes}, series = {Langmuir}, volume = {35}, journal = {Langmuir}, number = {16}, publisher = {American Chemical Society}, address = {Washington}, issn = {0743-7463}, doi = {10.1021/acs.langmuir.8b01802}, pages = {5373 -- 5391}, year = {2018}, abstract = {We discuss recent investigations of the interaction of polyelectrolytes with proteins. In particular, we review our recent studies on the interaction of simple proteins such as human serum albumin (HSA) and lysozyme with linear polyelectrolytes, charged dendrimers, charged networks, and polyelectrolyte brushes. In all cases discussed here, we combined experimental work with molecular dynamics (MD) simulations and mean-field theories. In particular, isothermal titration calorimetry (ITC) has been employed to obtain the respective binding constants K-b and the Gibbs free energy of binding. MD simulations with explicit counterions but implicit water demonstrate that counterion release is the main driving force for the binding of proteins to strongly charged polyelectrolytes: patches of positive charges located on the surface of the protein become multivalent counterions of the polyelectrolyte, thereby releasing a number of counterions condensed on the polyelectrolyte. The binding Gibbs free energy due to counterion release is predicted to scale with the logarithm of the salt concentration in the system, which is verified by both simulations and experiment. In several cases, namely, for the interaction of proteins with linear polyelectrolytes and highly charged hydrophilic dendrimers, the binding constant could be calculated from simulations to very good approximation. This finding demonstrated that in these cases explicit hydration effects do not contribute to the Gibbs free energy of binding. The Gibbs free energy can also be used to predict the kinetics of protein uptake by microgels for a given system by applying dynamic density functional theory. The entire discussion demonstrates that the direct comparison of theory with experiments can lead to a full understanding of the interaction of proteins with charged polymers. Possible implications for applications, such as drug design, are discussed.}, language = {en} } @article{XiongWłodarczykGallandietal.2018, author = {Xiong, Tao and Włodarczyk, Radosław Stanisław and Gallandi, Lukas and K{\"o}rzd{\"o}rfer, Thomas and Saalfrank, Peter}, title = {Vibrationally resolved photoelectron spectra of lower diamondoids}, series = {The journal of chemical physics : bridges a gap between journals of physics and journals of chemistry}, volume = {148}, journal = {The journal of chemical physics : bridges a gap between journals of physics and journals of chemistry}, number = {4}, publisher = {American Institute of Physics}, address = {Melville}, issn = {0021-9606}, doi = {10.1063/1.5012131}, pages = {9}, year = {2018}, abstract = {Vibrationally resolved lowest-energy bands of the photoelectron spectra (PES) of adamantane, diamantane, and urotropine were simulated by a time-dependent correlation function approach within the harmonic approximation. Geometries and normal modes for neutral and cationic molecules were obtained from B3LYP hybrid density functional theory (DFT). It is shown that the simulated spectra reproduce the experimentally observed vibrational finestructure (or its absence) quite well. Origins of the finestructure are discussed and related to recurrences of autocorrelation functions and dominant vibrations. Remaining quantitative and qualitative errors of the DFT-derived PES spectra refer to (i) an overall redshift by ∼0.5 eV and (ii) the absence of satellites in the high-energy region of the spectra. The former error is shown to be due to the neglect of many-body corrections to ordinary Kohn-Sham methods, while the latter has been argued to be due to electron-nuclear couplings beyond the Born-Oppenheimer approximation [Gali et al., Nat. Commun. 7, 11327 (2016)].}, language = {en} } @article{XiongWlodarczykSaalfrank2018, author = {Xiong, Tao and Wlodarczyk, Radoslaw and Saalfrank, Peter}, title = {Vibrationally resolved absorption and fluorescence spectra of perylene and N-substituted derivatives from autocorrelation function approaches}, series = {Chemical physics : a journal devoted to experimental and theoretical research involving problems of both a chemical and physical nature}, volume = {515}, journal = {Chemical physics : a journal devoted to experimental and theoretical research involving problems of both a chemical and physical nature}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0301-0104}, doi = {10.1016/j.chemphys.2018.06.011}, pages = {728 -- 736}, year = {2018}, abstract = {Vibrationally resolved absorption and emission (fluorescence) spectra of perylene and its N-derivatives in gas phase and in solution (acetonitrile) were simulated using a time-dependent approach based on correlation functions determined by density functional theory. By systematically varying the number and position of N atoms, it is shown that the presence of nitrogen heteroatoms has a negligible effect on the molecular structure and geometric distortions upon electronic transitions, while spectral properties change: in particular the number of N atoms is important while their position is less decisive. Thus, the N-substitution can be used to fine-tune the optical properties of perylene-based molecules.}, language = {en} } @phdthesis{Xiong2018, author = {Xiong, Tao}, title = {Vibrationally resolved absorption, emission, resonance Raman and photoelectron spectra of selected organic molecules, associated radicals and cations}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-418105}, school = {Universit{\"a}t Potsdam}, pages = {iv, 100}, year = {2018}, abstract = {Time-dependent correlation function based methods to study optical spectroscopy involving electronic transitions can be traced back to the work of Heller and coworkers. This intuitive methodology can be expected to be computationally efficient and is applied in the current work to study the vibronic absorption, emission, and resonance Raman spectra of selected organic molecules. Besides, the "non-standard" application of this approach to photoionization processes is also explored. The application section consists of four chapters as described below. In Chapter 4, the molar absorptivities and vibronic absorption/emission spectra of perylene and several of its N-substituted derivatives are investigated. By systematically varying the number and position of N atoms, it is shown that the presence of nitrogen heteroatoms has a negligible effect on the molecular structure and geometric distortions upon electronic transitions, while spectral properties are more sensitive: In particular the number of N atoms is important while their position is less decisive. Thus, N-substitution can be used to fine-tune the optical properties of perylene-based molecules. In Chapter 5, the same methods are applied to study the vibronic absorption/emission and resonance Raman spectra of a newly synthesized donor-acceptor type molecule. The simulated absorption/emission spectra agree fairly well with experimental data, with discrepancies being attributed to solvent effects. Possible modes which may dominate the fine-structure in the vibronic spectra are proposed by analyzing the correlation function with the aid of Raman and resonance Raman spectra. In the next two chapters, besides the above types of spectra, the methods are extended to study photoelectron spectra of several small diamondoid-related systems (molecules, radicals, and cations). Comparison of the photoelectron spectra with available experimental data suggests that the correlation function based approach can describe ionization processes reasonably well. Some of these systems, cationic species in particular, exhibit somewhat peculiar optical behavior, which presents them as possible candidates for functional devices. Correlation function based methods in a more general sense can be very versatile. In fact, besides the above radiative processes, formulas for non-radiative processes such as internal conversion have been derived in literature. Further implementation of the available methods is among our next goals.}, language = {en} } @article{XiongFangOsipovetal.2018, author = {Xiong, Hui and Fang, Li and Osipov, Timur and Kling, Nora G. and Wolf, Thomas J. A. and Sistrunk, Emily and Obaid, Razib and G{\"u}hr, Markus and Berrah, Nora}, title = {Fragmentation of endohedral fullerene Ho3N@C-80 in an intense femtosecond near-infrared laser field}, series = {Physical review : A, Atomic, molecular, and optical physics}, volume = {97}, journal = {Physical review : A, Atomic, molecular, and optical physics}, number = {2}, publisher = {American Physical Society}, address = {College Park}, issn = {2469-9926}, doi = {10.1103/PhysRevA.97.023419}, pages = {7}, year = {2018}, abstract = {The fragmentation of gas phase endohedral fullerene, Ho3N@C-80, was investigated using femtosecond near-infrared laser pulses with an ion velocity map imaging spectrometer. We observed that Ho+ abundance associated with carbon cage opening dominates at an intensity of 1.1 x 10(14) W/cm(2). As the intensity increases, the Ho+ yield associated with multifragmentation of the carbon cage exceeds the prominence of Ho+ associated with the gentler carbon cage opening. Moreover, the power law dependence of Ho+ on laser intensity indicates that the transition of the most likely fragmentation mechanisms occurs around 2.0 x 10(14) W/cm(2).}, language = {en} } @article{XiongStollePark2018, author = {Xiong, Chao and Stolle, Claudia and Park, Jaeheung}, title = {Climatology of GPS signal loss observed by Swarm satellites}, series = {Annales geophysicae}, volume = {36}, journal = {Annales geophysicae}, number = {2}, publisher = {Copernicus}, address = {G{\"o}ttingen}, issn = {0992-7689}, doi = {10.5194/angeo-36-679-2018}, pages = {679 -- 693}, year = {2018}, abstract = {By using 3-year global positioning system (GPS) measurements from December 2013 to November 2016, we provide in this study a detailed survey on the climatology of the GPS signal loss of Swarm onboard receivers. Our results show that the GPS signal losses prefer to occur at both low latitudes between +/- 5 and +/- 20 degrees magnetic latitude (MLAT) and high latitudes above 60 degrees MLAT in both hemispheres. These events at all latitudes are observed mainly during equinoxes and December solstice months, while totally absent during June solstice months. At low latitudes the GPS signal losses are caused by the equatorial plasma irregularities shortly after sunset, and at high latitude they are also highly related to the large density gradients associated with ionospheric irregularities. Additionally, the high-latitude events are more often observed in the Southern Hemisphere, occurring mainly at the cusp region and along nightside auroral latitudes. The signal losses mainly happen for those GPS rays with elevation angles less than 20 degrees, and more commonly occur when the line of sight between GPS and Swarm satellites is aligned with the shell structure of plasma irregularities. Our results also confirm that the capability of the Swarm receiver has been improved after the bandwidth of the phase-locked loop (PLL) widened, but the updates cannot radically avoid the interruption in tracking GPS satellites caused by the ionospheric plasma irregularities. Additionally, after the PLL bandwidth increased larger than 0.5 Hz, some unexpected signal losses are observed even at middle latitudes, which are not related to the ionospheric plasma irregularities. Our results suggest that rather than 1.0 Hz, a PLL bandwidth of 0.5 Hz is a more suitable value for the Swarm receiver.}, language = {en} } @misc{XiongStollePark2018, author = {Xiong, Chao and Stolle, Claudia and Park, Jaeheung}, title = {Climatology of GPS signal loss observed by Swarm satellites}, series = {Postprints der Universit{\"a}t Potsdam Mathematisch-Naturwissenschaftliche Reihe}, journal = {Postprints der Universit{\"a}t Potsdam Mathematisch-Naturwissenschaftliche Reihe}, number = {712}, issn = {1866-8372}, doi = {10.25932/publishup-42739}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-427391}, pages = {15}, year = {2018}, abstract = {By using 3-year global positioning system (GPS)measurements from December 2013 to November 2016, we provide in this study a detailed survey on the climatology of the GPS signal loss of Swarm onboard receivers. Our results show that the GPS signal losses prefer to occur at both low latitudes between ±5 and ±20 ◦ magnetic latitude (MLAT) and high latitudes above 60 ◦ MLAT in both hemispheres. These events at all latitudes are observed mainly during equinoxes and December solstice months, while totally absent during June solstice months. At low latitudes the GPS signal losses are caused by the equatorial plasma irregularities shortly after sunset, and at high latitude they are also highly related to the large density gradients associated with ionospheric irregularities. Additionally, the high-latitude events are more often observed in the Southern Hemisphere, occurring mainly at the cusp region and along nightside auroral latitudes. The signal losses mainly happen for those GPS rays with elevation angles less than 20 ◦ , and more commonly occur when the line of sight between GPS and Swarm satellites is aligned with the shell structure of plasma irregularities. Our results also confirm that the capability of the Swarm receiver has been improved after the bandwidth of the phase-locked loop (PLL) widened, but the updates cannot radically avoid the interruption in tracking GPS satellites caused by the ionospheric plasma irregularities. Additionally, after the PLL bandwidth increased larger than 0.5 Hz, some unexpected signal losses are observed even at middle latitudes, which are not related to the ionospheric plasma irregularities. Our results suggest that rather than 1.0 Hz, a PLL bandwidth of 0.5 Hz is a more suitable value for the Swarm receiver.}, language = {en} } @article{Xiang2018, author = {Xiang, Zairong}, title = {Transdualism}, series = {TSQ-Transgender studies quarterly}, volume = {5}, journal = {TSQ-Transgender studies quarterly}, number = {3}, publisher = {Duke Univ. Press}, address = {Durham}, issn = {2328-9252}, doi = {10.1215/23289252-6900795}, pages = {425 -- 442}, year = {2018}, abstract = {The author introduces the concept of transdualism to critique dualism without relying on a dualistic model of critique, the modus operandi necessary for a critique against sexual dualism and hetero/cisnormativity. Transdualism offers an opportunity to dwell within that operation by staying below (not beyond) the "dualism," that is, below the logic of either/or. The essay will explore the notion of "transdualism" through the hexagram Tai of the Yi Jing, which is often used in medical contexts to illustrate the body-of-orifices of Huangdi Neijing or the Inner Canon of the Yellow Emperor. The author reads this body-of-orifices, which is primarily represented by its nine major bodily tunnels, with yinyang philosophy as gender/sex indeterminant and shows that the Inner Canon's yinyang body-of-orifices points to something more transgressive, which could unsettle from within the naturalism of gender and sexual dualism and the nature/culture as well as other dualistic divides that have informed contemporary critical rethinking of embodiment. By unpacking the hexagram Tai alongside Inner Canon's body-of-orifices. as well as contemporary feminist, queer, and transgender theorizations of the body and sexuality, this essay aims at rethinking the materio-discursive complexity of the body-of-orifices, which has been either dualistically separated into antagonisms between man and woman, sex and gender, body and discourse, yin and yang; or one-sidedly reduced to a function of "social construction," knowable only through language—or problematically lumped together in a gender-is-fluid postmodern "both-and," which supposedly overcomes the metaphysico-theological "either/or."}, language = {en} } @article{WoernerSchildgenReich2018, author = {W{\"o}rner, Gerhard and Schildgen, Taylor F. and Reich, Martin}, title = {The central Andes}, series = {Elements : an international magazine of mineralogy, geochemistry, and petrology}, volume = {14}, journal = {Elements : an international magazine of mineralogy, geochemistry, and petrology}, number = {4}, publisher = {Mineralogical Society of America}, address = {Chantilly}, issn = {1811-5209}, doi = {10.2138/gselements.14.4.225}, pages = {225 -- 230}, year = {2018}, abstract = {The Central Andes and the Atacama Desert represent a unique geological, climatic, and magmatic setting on our planet. It is the only place on Earth where subduction of an oceanic plate below an active continental margin has led to an extensive mountain chain and an orogenic plateau that is second in size only to the Tibetan Plateau, which resulted from continental collision. In this article, we introduce the history of the Central Andes and the evolution of its landscape. We also discuss links between tectonic forces, magmatism, and the extreme hyperarid climate of this land that, in turn, has led to rich deposits of precious ores and minerals.}, language = {en} } @article{Wysujack2018, author = {Wysujack, Jan}, title = {K{\"u}nstlerische Stimmarbeit mit Menschen mit dem Down-Syndrom}, series = {Potsdamer Schriftenreihe zur Musikp{\"a}dagogik}, journal = {Potsdamer Schriftenreihe zur Musikp{\"a}dagogik}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-417623}, pages = {63 -- 95}, year = {2018}, language = {de} } @misc{Wyrwa2018, author = {Wyrwa, Ulrich}, title = {Rezension zu: Enzyklop{\"a}die j{\"u}discher Geschichte und Kultur, ed. Dan Diner, Sächsische Akademie der Wissenschaften zu Leipzig, (Stuttgart -Weimar: Metzler, 2011-2017), 7 Vol}, series = {Quest-Issues in Contemporary Jewish History}, volume = {2018}, journal = {Quest-Issues in Contemporary Jewish History}, number = {14}, publisher = {Fondazione Centro Documentazione Ebraica Contemporanea}, address = {Milano}, issn = {2037-741X}, doi = {10.48248/issn.2037-741X/682}, pages = {123 -- 131}, year = {2018}, language = {en} } @article{WutkeSandovalCastellanosBeneckeetal.2018, author = {Wutke, Saskia and Sandoval-Castellanos, Edson and Benecke, Norbert and D{\"o}hle, Hans-J{\"u}rgen and Friederich, Susanne and Gonzalez, Javier and Hofreiter, Michael and Lougas, Lembi and Magnell, Ola and Malaspinas, Anna-Sapfo and Morales-Muniz, Arturo and Orlando, Ludovic and Reissmann, Monika and Trinks, Alexandra and Ludwig, Arne}, title = {Decline of genetic diversity in ancient domestic stallions in Europe}, series = {Science Advances}, volume = {4}, journal = {Science Advances}, number = {4}, publisher = {American Assoc. for the Advancement of Science}, address = {Washington}, issn = {2375-2548}, doi = {10.1126/sciadv.aap9691}, pages = {7}, year = {2018}, abstract = {Present-day domestic horses are immensely diverse in their maternally inherited mitochondrial DNA, yet they show very little variation on their paternally inherited Y chromosome. Although it has recently been shown that Y chromosomal diversity in domestic horses was higher at least until the Iron Age, when and why this diversity disappeared remain controversial questions. We genotyped 16 recently discovered Y chromosomal single-nucleotide polymorphisms in 96 ancient Eurasian stallions spanning the early domestication stages (Copper and Bronze Age) to the Middle Ages. Using this Y chromosomal time series, which covers nearly the entire history of horse domestication, we reveal how Y chromosomal diversity changed over time. Our results also show that the lack of multiple stallion lineages in the extant domestic population is caused by neither a founder effect nor random demographic effects but instead is the result of artificial selection-initially during the Iron Age by nomadic people from the Eurasian steppes and later during the Roman period. Moreover, the modern domestic haplotype probably derived from another, already advantageous, haplotype, most likely after the beginning of the domestication. In line with recent findings indicating that the Przewalski and domestic horse lineages remained connected by gene flow after they diverged about 45,000 years ago, we present evidence for Y chromosomal introgression of Przewalski horses into the gene pool of European domestic horses at least until medieval times.}, language = {en} } @article{WusterChirioTrapeetal.2018, author = {Wuster, Wolfgang and Chirio, Laurent and Trape, Jean-Francois and Ineich, Ivan and Jackson, Kate and Greenbaum, Eli and Barron, Cesar and Kusamba, Chifundera and Nagy, Zoltan T. and Storey, Richard and Hall, Cara and Wuster, Catharine E. and Barlow, Axel and Broadley, Donald G.}, title = {Integration of nuclear and mitochondrial gene sequences and morphology reveals unexpected diversity in the forest cobra (Naja melanoleuca) species complex in Central and West Africa (Serpentes: Elapidae)}, series = {Zootaxa : an international journal of zootaxonomy ; a rapid international journal for animal taxonomists}, volume = {4455}, journal = {Zootaxa : an international journal of zootaxonomy ; a rapid international journal for animal taxonomists}, number = {1}, publisher = {Magnolia Press}, address = {Auckland}, issn = {1175-5326}, doi = {10.11646/zootaxa.4455.1.3}, pages = {68 -- 98}, year = {2018}, abstract = {Cobras are among the most widely known venomous snakes, and yet their taxonomy remains incompletely understood, particularly in Africa. Here, we use a combination of mitochondrial and nuclear gene sequences and morphological data to diagnose species limits within the African forest cobra, Naja (Boulengerina) melanoleuca. Mitochondrial DNA sequences reveal deep divergences within this taxon. Congruent patterns of variation in mtDNA, nuclear genes and morphology support the recognition of five separate species, confirming the species status of N. subfulva and N. peroescobari, and revealing two previously unnamed West African species, which are described as new: Naja (Boulengerina) guineensis sp. nov. Broadley, Trape, Chirio, Ineich \& Wuster, from the Upper Guinea forest of West Africa, and Naja (Boulengerina) savannula sp. nov. Broadley, Trape, Chirio \& Wuster, a banded form from the savanna-forest mosaic of the Guinea and Sudanian savannas of West Africa. The discovery of cryptic diversity in this iconic group highlights our limited understanding of tropical African biodiversity, hindering our ability to conserve it effectively.}, language = {en} }