@phdthesis{ZamoraLopez2009, author = {Zamora-L{\´o}pez, Gorka}, title = {Linking structure and function of complex cortical networks}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-52257}, school = {Universit{\"a}t Potsdam}, year = {2009}, abstract = {The recent discovery of an intricate and nontrivial interaction topology among the elements of a wide range of natural systems has altered the manner we understand complexity. For example, the axonal fibres transmitting electrical information between cortical regions form a network which is neither regular nor completely random. Their structure seems to follow functional principles to balance between segregation (functional specialisation) and integration. Cortical regions are clustered into modules specialised in processing different kinds of information, e.g. visual or auditory. However, in order to generate a global perception of the real world, the brain needs to integrate the distinct types of information. Where this integration happens, nobody knows. We have performed an extensive and detailed graph theoretical analysis of the cortico-cortical organisation in the brain of cats, trying to relate the individual and collective topological properties of the cortical areas to their function. We conclude that the cortex possesses a very rich communication structure, composed of a mixture of parallel and serial processing paths capable of accommodating dynamical processes with a wide variety of time scales. The communication paths between the sensory systems are not random, but largely mediated by a small set of areas. Far from acting as mere transmitters of information, these central areas are densely connected to each other, strongly indicating their functional role as integrators of the multisensory information. In the quest of uncovering the structure-function relationship of cortical networks, the peculiarities of this network have led us to continuously reconsider the stablished graph measures. For example, a normalised formalism to identify the "functional roles" of vertices in networks with community structure is proposed. The tools developed for this purpose open the door to novel community detection techniques which may also characterise the overlap between modules. The concept of integration has been revisited and adapted to the necessities of the network under study. Additionally, analytical and numerical methods have been introduced to facilitate understanding of the complicated statistical interrelations between the distinct network measures. These methods are helpful to construct new significance tests which may help to discriminate the relevant properties of real networks from side-effects of the evolutionary-growth processes.}, language = {en} } @phdthesis{Zakrevskyy2006, author = {Zakrevskyy, Yuriy}, title = {Liquid crystallinity and alignment of ionic self-assembly complexes}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-10048}, school = {Universit{\"a}t Potsdam}, year = {2006}, abstract = {In this work the first observation of new type of liquid crystals is presented. This is ionic self-assembly (ISA) liquid crystals formed by introduction of oppositely charged ions between different low molecular tectonic units. As practically all conventional liquid crystals consist of rigid core and alkyl chains the attention is focused to the simplest case where oppositely charged ions are placed between a rigid core and alkyl tails. The aim of this work is to investigate and understand liquid crystalline and alignment properties of these materials. It was found that ionic interactions within complexes play the main role. Presence of these interactions restricts transition to isotropic phase. In addition, these interactions hold the system (like network) allowing crystallization into a single domain from aligned LC state. Alignment of these simple ISA complexes was spontaneous on a glass substrate. In order to show potentials for application perylenediimide and azobenzene containing ISA complexes have been investigated for correlations between phase behavior and their alignment properties. The best results of macroscopic alignment of perylenediimide-based ISA complexes have been obtained by zone-casting method. In the aligned films the columns of the complex align perpendicular to the phase-transition front. The obtained anisotropy (DR = 18) is thermally stable. The investigated photosensitive (azobenzene-based) ISA complexes show formation of columnar LC phases. It was demonstrated that photo alignment of such complexes was very effective (DR = 50 has been obtained). It was shown that photo-reorientation in the photosensitive ISA complexes is cooperative process. The size of domains has direct influence on efficiency of the photo-reorientation process. In the case of small domains the photo-alignment is the most effective. Under irradiation with linearly polarized light domains reorient in the plane of the film leading to macroscopic alignment of columns parallel to the light polarization and joining of small domains into big ones. Finally, the additional distinguishable properties of the ISA liquid crystalline complexes should be noted: (I) the complexes do not solve in water but readily solve in organic solvents; (II) the complexes have good film-forming properties when cast or spin-coated from organic solvent; (III) alignment of the complexes depends on their structure and secondary interactions between tectonic units.}, subject = {Fl{\"u}ssigkristall}, language = {en} } @phdthesis{Zajnulina2015, author = {Zajnulina, Marina}, title = {Optical frequency comb generation in optical fibres}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-88776}, school = {Universit{\"a}t Potsdam}, pages = {xii, 103}, year = {2015}, abstract = {Optical frequency combs (OFC) constitute an array of phase-correlated equidistant spectral lines with nearly equal intensities over a broad spectral range. The adaptations of combs generated in mode-locked lasers proved to be highly efficient for the calibration of high-resolution (resolving power > 50000) astronomical spectrographs. The observation of different galaxy structures or the studies of the Milky Way are done using instruments in the low- and medium resolution range. To such instruments belong, for instance, the Multi Unit Spectroscopic Explorer (MUSE) being developed for the Very Large Telescope (VLT) of the European Southern Observatory (ESO) and the 4-metre Multi-Object Spectroscopic Telescope (4MOST) being in development for the ESO VISTA 4.1 m Telescope. The existing adaptations of OFC from mode-locked lasers are not resolvable by these instruments. Within this work, a fibre-based approach for generation of OFC specifically in the low- and medium resolution range is studied numerically. This approach consists of three optical fibres that are fed by two equally intense continuous-wave (CW) lasers. The first fibre is a conventional single-mode fibre, the second one is a suitably pumped amplifying Erbium-doped fibre with anomalous dispersion, and the third one is a low-dispersion highly nonlinear optical fibre. The evolution of a frequency comb in this system is governed by the following processes: as the two initial CW-laser waves with different frequencies propagate through the first fibre, they generate an initial comb via a cascade of four-wave mixing processes. The frequency components of the comb are phase-correlated with the original laser lines and have a frequency spacing that is equal to the initial laser frequency separation (LFS), i.e. the difference in the laser frequencies. In the time domain, a train of pre-compressed pulses with widths of a few pico-seconds arises out of the initial bichromatic deeply-modulated cosine-wave. These pulses undergo strong compression in the subsequent amplifying Erbium-doped fibre: sub-100 fs pulses with broad OFC spectra are formed. In the following low-dispersion highly nonlinear fibre, the OFC experience a further broadening and the intensity of the comb lines are fairly equalised. This approach was mathematically modelled by means of a Generalised Nonlinear Schr{\"o}dinger Equation (GNLS) that contains terms describing the nonlinear optical Kerr effect, the delayed Raman response, the pulse self-steepening, and the linear optical losses as well as the wavelength-dependent Erbium gain profile for the second fibre. The initial condition equation being a deeply-modulated cosine-wave mimics the radiation of the two initial CW lasers. The numerical studies are performed with the help of Matlab scripts that were specifically developed for the integration of the GNLS and the initial condition according to the proposed approach for the OFC generation. The scripts are based on the Fourth-Order Runge-Kutta in the Interaction Picture Method (RK4IP) in combination with the local error method. This work includes the studies and results on the length optimisation of the first and the second fibre depending on different values of the group-velocity dispersion of the first fibre. Such length optimisation studies are necessary because the OFC have the biggest possible broadband and exhibit a low level of noise exactly at the optimum lengths. Further, the optical pulse build-up in the first and the second fibre was studied by means of the numerical technique called Soliton Radiation Beat Analysis (SRBA). It was shown that a common soliton crystal state is formed in the first fibre for low laser input powers. The soliton crystal continuously dissolves into separated optical solitons as the input power increases. The pulse formation in the second fibre is critically dependent on the features of the pulses formed in the first fibre. I showed that, for low input powers, an adiabatic soliton compression delivering low-noise OFC occurs in the second fibre. At high input powers, the pulses in the first fibre have more complicated structures which leads to the pulse break-up in the second fibre with a subsequent degradation of the OFC noise performance. The pulse intensity noise studies that were performed within the framework of this thesis allow making statements about the noise performance of an OFC. They showed that the intensity noise of the whole system decreases with the increasing value of LFS.}, language = {en} } @phdthesis{Youakim2020, author = {Youakim, Kris}, title = {Galactic archaeology with metal-poor stars from the Pristine survey}, doi = {10.25932/publishup-47431}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-474314}, school = {Universit{\"a}t Potsdam}, pages = {iv, 151}, year = {2020}, abstract = {The Milky Way is a spiral galaxy consisting of a disc of gas, dust and stars embedded in a halo of dark matter. Within this dark matter halo there is also a diffuse population of stars called the stellar halo, that has been accreting stars for billions of years from smaller galaxies that get pulled in and disrupted by the large gravitational potential of the Milky Way. As they are disrupted, these galaxies leave behind long streams of stars that can take billions of years to mix with the rest of the stars in the halo. Furthermore, the amount of heavy elements (metallicity) of the stars in these galaxies reflects the rate of chemical enrichment that occurred in them, since the Universe has been slowly enriched in heavy elements (e.g. iron) through successive generations of stars which produce them in their cores and supernovae explosions. Therefore, stars that contain small amounts of heavy elements (metal-poor stars) either formed at early times before the Universe was significantly enriched, or in isolated environments. The aim of this thesis is to develop a better understanding of the substructure content and chemistry of the Galactic stellar halo, in order to gain further insight into the formation and evolution of the Milky Way. The Pristine survey uses a narrow-band filter which specifically targets the Ca II H \& K spectral absorption lines to provide photometric metallicities for a large number of stars down to the extremely metal-poor (EMP) regime, making it a very powerful data set for Galactic archaeology studies. In Chapter 2, we quantify the efficiency of the survey using a preliminary spectroscopic follow-up sample of ~ 200 stars. We also use this sample to establish a set of selection criteria to improve the success rate of selecting EMP candidates for follow-up spectroscopy. In Chapter 3, we extend this work and present the full catalogue of ~ 1000 stars from a three year long medium resolution spectroscopic follow-up effort conducted as part of the Pristine survey. From this sample, we compute success rates of 56\% and 23\% for recovering stars with [Fe/H] < -2.5 and [Fe/H] < -3.0, respectively. This demonstrates a high efficiency for finding EMP stars as compared to previous searches with success rates of 3-4\%. In Chapter 4, we select a sample of ~ 80000 halo stars using colour and magnitude cuts to select a main sequence turnoff population in the distance range 6 < dʘ < 20 kpc. We then use the spectroscopic follow-up sample presented in Chapter 3 to statistically rescale the Pristine photometric metallicities of this sample, and present the resulting corrected metallicity distribution function (MDF) of the halo. The slope at the metal-poor end is significantly shallower than previous spectroscopic efforts have shown, suggesting that there may be more metal-poor stars with [Fe/H] < -2.5 in the halo than previously thought. This sample also shows evidence that the MDF of the halo may not be bimodal as was proposed by previous works, and that the lack of globular clusters in the Milky Way may be the result of a physical truncation of the MDF rather than just statistical under-sampling. Chapter 5 showcases the unexpected capability of the Pristine filter for separating blue horizontal branch (BHB) stars from Blue Straggler (BS) stars. We demonstrate a purity of 93\% and completeness of 91\% for identifying BHB stars, a substantial improvement over previous works. We then use this highly pure and complete sample of BHB stars to trace the halo density profile out to d > 100 kpc, and the Sagittarius stream substructure out to ~ 130 kpc. In Chapter 6 we use the photometric metallicities from the Pristine survey to perform a clustering analysis of the halo as a function of metallicity. Separating the Pristine sample into four metallicity bins of [Fe/H] < -2, -2 < [Fe/H] < -1.5, -1.5 < [Fe/H] < -1 and -0.9 < [Fe/H] < -0.8, we compute the two-point correlation function to measure the amount of clustering on scales of < 5 deg. For a smooth comparison sample we make a mock Pristine data set generated using the Galaxia code based on the Besan{\c{c}}on model of the Galaxy. We find enhanced clustering on small scales (< 0.5 deg) for some regions of the Galaxy for the most metal-poor bin ([Fe/H] < -2), while in others we see large scale signals that correspond to known substructures in those directions. This confirms that the substructure content of the halo is highly anisotropic and diverse in different Galactic environments. We discuss the difficulties of removing systematic clustering signals from the data and the limitations of disentangling weak clustering signals from real substructures and residual systematic structure in the data. Taken together, the work presented in this thesis approaches the problem of better understanding the halo of our Galaxy from multiple angles. Firstly, presenting a sizeable sample of EMP stars and improving the selection efficiency of EMP stars for the Pristine survey, paving the way for the further discovery of metal-poor stars to be used as probes to early chemical evolution. Secondly, improving the selection of BHB distance tracers to map out the halo to large distances, and finally, using the large samples of metal-poor stars to derive the MDF of the inner halo and analyse the substructure content at different metallicities. The results of this thesis therefore expand our understanding of the physical and chemical properties of the Milky Way stellar halo, and provide insight into the processes involved in its formation and evolution.}, language = {en} } @phdthesis{Yin2010, author = {Yin, Fan}, title = {Mathematic approaches for the calibration of the CHAMP satellite magnetic field measurements}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-41201}, school = {Universit{\"a}t Potsdam}, year = {2010}, abstract = {CHAMP (CHAllenging Minisatellite Payload) is a German small satellite mission to study the earth's gravity field, magnetic field and upper atmosphere. Thanks to the good condition of the satellite so far, the planned 5 years mission is extended to year 2009. The satellite provides continuously a large quantity of measurement data for the purpose of Earth study. The measurements of the magnetic field are undertaken by two Fluxgate Magnetometers (vector magnetometer) and one Overhauser Magnetometer (scalar magnetometer) flown on CHAMP. In order to ensure the quality of the data during the whole mission, the calibration of the magnetometers has to be performed routinely in orbit. The scalar magnetometer serves as the magnetic reference and its readings are compared with the readings of the vector magnetometer. The readings of the vector magnetometer are corrected by the parameters that are derived from this comparison, which is called the scalar calibration. In the routine processing, these calibration parameters are updated every 15 days by means of scalar calibration. There are also magnetic effects coming from the satellite which disturb the measurements. Most of them have been characterized during tests before launch. Among them are the remanent magnetization of the spacecraft and fields generated by currents. They are all considered to be constant over the mission life. The 8 years of operation experience allow us to investigate the long-term behaviors of the magnetometers and the satellite systems. According to the investigation, it was found that for example the scale factors of the FGM show obvious long-term changes which can be described by logarithmic functions. The other parameters (offsets and angles between the three components) can be considered constant. If these continuous parameters are applied for the FGM data processing, the disagreement between the OVM and the FGM readings is limited to \pm1nT over the whole mission. This demonstrates, the magnetometers on CHAMP exhibit a very good stability. However, the daily correction of the parameter Z component offset of the FGM improves the agreement between the magnetometers markedly. The Z component offset plays a very important role for the data quality. It exhibits a linear relationship with the standard deviation of the disagreement between the OVM and the FGM readings. After Z offset correction, the errors are limited to \pm0.5nT (equivalent to a standard deviation of 0.2nT). We improved the corrections of the spacecraft field which are not taken into account in the routine processing. Such disturbance field, e.g. from the power supply system of the satellite, show some systematic errors in the FGM data and are misinterpreted in 9-parameter calibration, which brings false local time related variation of the calibration parameters. These corrections are made by applying a mathematical model to the measured currents. This non-linear model is derived from an inversion technique. If the disturbance field of the satellite body are fully corrected, the standard deviation of scalar error \triangle B remains about 0.1nT. Additionally, in order to keep the OVM readings a reliable standard, the imperfect coefficients of the torquer current correction for the OVM are redetermined by solving a minimization problem. The temporal variation of the spacecraft remanent field is investigated. It was found that the average magnetic moment of the magneto-torquers reflects well the moment of the satellite. This allows for a continuous correction of the spacecraft field. The reasons for the possible unknown systemic error are discussed in this thesis. Particularly, both temperature uncertainties and time errors have influence on the FGM data. Based on the results of this thesis the data processing of future magnetic missions can be designed in an improved way. In particular, the upcoming ESA mission Swarm can take advantage of our findings and provide all the auxiliary measurements needed for a proper recovery of the ambient magnetic field.}, language = {en} } @phdthesis{Yin2009, author = {Yin, Chunhong}, title = {The interplay of nanostructure and efficiency of polymer solar cells}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-29054}, school = {Universit{\"a}t Potsdam}, year = {2009}, abstract = {The aim of this thesis is to achieve a deep understanding of the working mechanism of polymer based solar cells and to improve the device performance. Two types of the polymer based solar cells are studied here: all-polymer solar cells comprising macromolecular donors and acceptors based on poly(p-phenylene vinylene) and hybrid cells comprising a PPV copolymer in combination with a novel small molecule electron acceptor. To understand the interplay between morphology and photovoltaic properties in all-polymer devices, I compared the photocurrent characteristics and excited state properties of bilayer and blend devices with different nano-morphology, which was fine tuned by using solvents with different boiling points. The main conclusion from these complementary measurements was that the performance-limiting step is the field-dependent generation of free charge carriers, while bimolecular recombination and charge extraction do not compromise device performance. These findings imply that the proper design of the donor-acceptor heterojunction is of major importance towards the goal of high photovoltaic efficiencies. Regarding polymer-small molecular hybrid solar cells I combined the hole-transporting polymer M3EH-PPV with a novel Vinazene-based electron acceptor. This molecule can be either deposited from solution or by thermal evaporation, allowing for a large variety of layer architectures to be realized. I then demonstrated that the layer architecture has a large influence on the photovoltaic properties. Solar cells with very high fill factors of up to 57 \% and an open circuit voltage of 1V could be achieved by realizing a sharp and well-defined donor-acceptor heterojunction. In the past, fill factors exceeding 50 \% have only been observed for polymers in combination with soluble fullerene-derivatives or nanocrystalline inorganic semiconductors as the electron-accepting component. The finding that proper processing of polymer-vinazene devices leads to similar high values is a major step towards the design of efficient polymer-based solar cells.}, language = {en} } @phdthesis{Yeldesbay2014, author = {Yeldesbay, Azamat}, title = {Complex regimes of synchronization}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-73348}, school = {Universit{\"a}t Potsdam}, pages = {ii, 60}, year = {2014}, abstract = {Synchronization is a fundamental phenomenon in nature. It can be considered as a general property of self-sustained oscillators to adjust their rhythm in the presence of an interaction. In this work we investigate complex regimes of synchronization phenomena by means of theoretical analysis, numerical modeling, as well as practical analysis of experimental data. As a subject of our investigation we consider chimera state, where due to spontaneous symmetry-breaking of an initially homogeneous oscillators lattice split the system into two parts with different dynamics. Chimera state as a new synchronization phenomenon was first found in non-locally coupled oscillators system, and has attracted a lot of attention in the last decade. However, the recent studies indicate that this state is also possible in globally coupled systems. In the first part of this work, we show under which conditions the chimera-like state appears in a system of globally coupled identical oscillators with intrinsic delayed feedback. The results of the research explain how initially monostable oscillators became effectivly bistable in the presence of the coupling and create a mean field that sustain the coexistence of synchronized and desynchronized states. Also we discuss other examples, where chimera-like state appears due to frequency dependence of the phase shift in the bistable system. In the second part, we make further investigation of this topic by modeling influence of an external periodic force to an oscillator with intrinsic delayed feedback. We made stability analysis of the synchronized state and constructed Arnold tongues. The results explain formation of the chimera-like state and hysteric behavior of the synchronization area. Also, we consider two sets of parameters of the oscillator with symmetric and asymmetric Arnold tongues, that correspond to mono- and bi-stable regimes of the oscillator. In the third part, we demonstrate the results of the work, which was done in collaboration with our colleagues from Psychology Department of University of Potsdam. The project aimed to study the effect of the cardiac rhythm on human perception of time using synchronization analysis. From our part, we made a statistical analysis of the data obtained from the conducted experiment on free time interval reproduction task. We examined how ones heartbeat influences the time perception and searched for possible phase synchronization between heartbeat cycles and time reproduction responses. The findings support the prediction that cardiac cycles can serve as input signals, and is used for reproduction of time intervals in the range of several seconds.}, language = {en} } @phdthesis{Yadavalli2014, author = {Yadavalli, Nataraja Sekhar}, title = {Advances in experimental methods to probe surface relief grating formation mechanism in photosensitive materials}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-71213}, school = {Universit{\"a}t Potsdam}, year = {2014}, abstract = {When azobenzene-modified photosensitive polymer films are irradiated with light interference patterns, topographic variations in the film develop that follow the electric field vector distribution resulting in the formation of surface relief grating (SRG). The exact correspondence of the electric field vector orientation in interference pattern in relation to the presence of local topographic minima or maxima of SRG is in general difficult to determine. In my thesis, we have established a systematic procedure to accomplish the correlation between different interference patterns and the topography of SRG. For this, we devise a new setup combining an atomic force microscope and a two-beam interferometer (IIAFM). With this set-up, it is possible to track the topography change in-situ, while at the same time changing polarization and phase of the impinging interference pattern. To validate our results, we have compared two photosensitive materials named in short as PAZO and trimer. This is the first time that an absolute correspondence between the local distribution of electric field vectors of interference pattern and the local topography of the relief grating could be established exhaustively. In addition, using our IIAFM we found that for a certain polarization combination of two orthogonally polarized interfering beams namely SP (↕, ↔) interference pattern, the topography forms SRG with only half the period of the interference patterns. Exploiting this phenomenon we are able to fabricate surface relief structures below diffraction limit with characteristic features measuring only 140 nm, by using far field optics with a wavelength of 491 nm. We have also probed for the stresses induced during the polymer mass transport by placing an ultra-thin gold film on top (5-30 nm). During irradiation, the metal film not only deforms along with the SRG formation, but ruptures in regular and complex manner. The morphology of the cracks differs strongly depending on the electric field distribution in the interference pattern even when the magnitude and the kinetic of the strain are kept constant. This implies a complex local distribution of the opto-mechanical stress along the topography grating. The neutron reflectivity measurements of the metal/polymer interface indicate the penetration of metal layer within the polymer resulting in the formation of bonding layer that confirms the transduction of light induced stresses in the polymer layer to a metal film.}, language = {en} } @phdthesis{Xue2004, author = {X{\"u}, Chenggang}, title = {Preparation and characterization of vapour deposited films based on substituted 2,5-diphenyl-1,3,4-oxadiazole derivatives}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-0001358}, school = {Universit{\"a}t Potsdam}, year = {2004}, abstract = {Diese Arbeit befasst sich mit dem Einfluss der molekularen Struktur von 2,5-Diphenyl-1,3,4-Oxadiazol-Derivaten auf die Pr{\"a}parierung d{\"u}nner Schichten mittels Vakuumdeposition. D{\"u}nne Schichten von diesen Substanzen wurden auf Si/SiO2 aufgedampft und ihre Struktur systematisch mittels XSR, AFM und IR untersucht. Das Ergebnis zeigt, dass die Schichtstrukturen offenbar von Substratetemperatur (Ts) abh{\"a}ngig sind. Im untersuchten Ts-Bereich bilden etherverbr{\"u}ckte Oxadiazole immer geordnete Schichten und die Schichtperiodicit{\"a}t h{\"a}ngt linear von der L{\"a}ngen der aliphatischen Ketten, w{\"a}hrend sich bei den amidverbr{\"u}ckten Oxadiazolen nur bei hohen Ts geordnete Schichten bilden k{\"o}nnen. Diese Unterschiede sind auf die intermolekularen Wasserstoffbr{\"u}cken zur{\"u}ckzuf{\"u}hren. Der Tilt-Winkel der Molek{\"u}le ist durch die Wechselwirkung zwischen dem aromatischen Teil bestimmt. Die Wechselwirkungen zwischen den Kopfgruppen k{\"o}nnen durch Tempern abgeschw{\"a}cht werden und f{\"u}hren zur Strukturumwandlung von Schichten, die auf etherverbr{\"u}ckten Oxadiazolen basieren. Alle Schichten von etherverbr{\"u}ckten Oxadiazolen haben Doppelschicht-Struktur, aber amidverbr{\"u}ckte Oxadiazole bilden nur Doppelschicht-Strukturen, wenn die Molek{\"u}le eine Kopfgruppe besitzen.}, language = {en} } @phdthesis{Wunderling2021, author = {Wunderling, Nico}, title = {Nichtlineare Dynamiken und Interaktionen von Kippelementen im Erdsystem}, doi = {10.25932/publishup-52514}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-525140}, school = {Universit{\"a}t Potsdam}, pages = {ix, 303}, year = {2021}, abstract = {With ongoing anthropogenic global warming, some of the most vulnerable components of the Earth system might become unstable and undergo a critical transition. These subsystems are the so-called tipping elements. They are believed to exhibit threshold behaviour and would, if triggered, result in severe consequences for the biosphere and human societies. Furthermore, it has been shown that climate tipping elements are not isolated entities, but interact across the entire Earth system. Therefore, this thesis aims at mapping out the potential for tipping events and feedbacks in the Earth system mainly by the use of complex dynamical systems and network science approaches, but partially also by more detailed process-based models of the Earth system. In the first part of this thesis, the theoretical foundations are laid by the investigation of networks of interacting tipping elements. For this purpose, the conditions for the emergence of global cascades are analysed against the structure of paradigmatic network types such as Erd{\"o}s-R{\´e}nyi, Barab{\´a}si-Albert, Watts-Strogatz and explicitly spatially embedded networks. Furthermore, micro-scale structures are detected that are decisive for the transition of local to global cascades. These so-called motifs link the micro- to the macro-scale in the network of tipping elements. Alongside a model description paper, all these results are entered into the Python software package PyCascades, which is publicly available on github. In the second part of this dissertation, the tipping element framework is first applied to components of the Earth system such as the cryosphere and to parts of the biosphere. Afterwards it is applied to a set of interacting climate tipping elements on a global scale. Using the Earth system Model of Intermediate Complexity (EMIC) CLIMBER-2, the temperature feedbacks are quantified, which would arise if some of the large cryosphere elements disintegrate over a long span of time. The cryosphere components that are investigated are the Arctic summer sea ice, the mountain glaciers, the Greenland and the West Antarctic Ice Sheets. The committed temperature increase, in case the ice masses disintegrate, is on the order of an additional half a degree on a global average (0.39-0.46 °C), while local to regional additional temperature increases can exceed 5 °C. This means that, once tipping has begun, additional reinforcing feedbacks are able to increase global warming and with that the risk of further tipping events. This is also the case in the Amazon rainforest, whose parts are dependent on each other via the so-called moisture-recycling feedback. In this thesis, the importance of drought-induced tipping events in the Amazon rainforest is investigated in detail. Despite the Amazon rainforest is assumed to be adapted to past environmental conditions, it is found that tipping events sharply increase if the drought conditions become too intense in a too short amount of time, outpacing the adaptive capacity of the Amazon rainforest. In these cases, the frequency of tipping cascades also increases to 50\% (or above) of all tipping events. In the model that was developed in this study, the southeastern region of the Amazon basin is hit hardest by the simulated drought patterns. This is also the region that already nowadays suffers a lot from extensive human-induced changes due to large-scale deforestation, cattle ranching or infrastructure projects. Moreover, on the larger Earth system wide scale, a network of conceptualised climate tipping elements is constructed in this dissertation making use of a large literature review, expert knowledge and topological properties of the tipping elements. In global warming scenarios, tipping cascades are detected even under modest scenarios of climate change, limiting global warming to 2 °C above pre-industrial levels. In addition, the structural roles of the climate tipping elements in the network are revealed. While the large ice sheets on Greenland and Antarctica are the initiators of tipping cascades, the Atlantic Meridional Overturning Circulation (AMOC) acts as the transmitter of cascades. Furthermore, in our conceptual climate tipping element model, it is found that the ice sheets are of particular importance for the stability of the entire system of investigated climate tipping elements. In the last part of this thesis, the results from the temperature feedback study with the EMIC CLIMBER-2 are combined with the conceptual model of climate tipping elements. There, it is observed that the likelihood of further tipping events slightly increases due to the temperature feedbacks even if no further CO\$_2\$ would be added to the atmosphere. Although the developed network model is of conceptual nature, it is possible with this work for the first time to quantify the risk of tipping events between interacting components of the Earth system under global warming scenarios, by allowing for dynamic temperature feedbacks at the same time.}, language = {en} } @phdthesis{Wu2010, author = {Wu, Ye}, title = {Nonlinear dynamics in complex networks and modeling human dynamics}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-47358}, school = {Universit{\"a}t Potsdam}, year = {2010}, abstract = {Durch große Datenmengen k{\"o}nnen die Forscher die Eigenschaften komplexer Systeme untersuchen, z.B. komplexe Netzwerk und die Dynamik des menschlichen Verhaltens. Eine große Anzahl an Systemen werden als große und komplexe Netzwerke dargestellt, z.B. das Internet, Stromnetze, Wirtschaftssysteme. Immer mehr Forscher haben großes Interesse an der Dynamik des komplexen Netzwerks. Diese Arbeit besteht aus den folgenden drei Teilen. Der erste Teil ist ein einfacher dynamischer Optimierungs-Kopplungs-Mechanismus, aber sehr wirksam. Durch den Mechanismus kann synchronisation in komplexen Netzwerken mit und ohne Zeitverz{\"o}gerung realisiert, und die F{\"a}higkeit der Synchronisation von small-world und scale-free Netze verbessert werden. Im zweiten Teil geht um die Verst{\"a}rkung der Robustheit der scale-free Netze im Zusammenhang mit der Gemeinden-Struktur. Einige Reaktionsmuster und topologische Gemeinden sind einheitlich. Die Ergebnisse zeigen einen neuen Aspekt der Beziehung zwischen den Funktionen und der Netzwerk-Topologie von komplexen Netzwerken. Im dritten Teil welche eine wichtige Rolle in komplexen Netzwerken spielt, wird die Verhaltens-Dynamik der menschliche Mitteilung durch Daten- und Modellanalysierung erforscht, dann entsteht ein neues Mitteilungsmodell. Mit Hilfe von einem Interaktion priority-Queue Model kann das neue Modell erkl{\"a}rt werden. Mit Hilfe des Models k{\"o}nnen viele praktische Interaktions-Systeme erkl{\"a}rt werden, z.B. E-Mail und Briefe (oder Post). Mit Hilfe meiner Untersuchung kann man menschliches Verhalten auf der Individuums- und Netzwerkebene neu kennenlernen. Im vierter Teil kann ich nachweisen, dass menschliches Kommentar-Verhalten in on-line Sozialsystemen, eine andere Art der Interaktionsdynamik von Mensch non-Poisson ist und dieses am Modell erkl{\"a}ren. Mit Hilfe der non-Poisson Prozesse kann man das pers{\"o}nliche Anziehungskraft-Modell besser verstehen. Die Ergebnisse sind hilfreich zum Kennenlernen des Musters des menschlichen Verhaltens in on-line Gesellschaften und der Entwicklung von {\"o}ffentlicher Meinung nicht nur in der virtuellen Gesellschaftn sondern auch in der Realgesellschaft. Am Ende geht es um eine Prognose von menschlicher Dynamik und komplexen Netzwerken.}, language = {en} } @phdthesis{Worseck2007, author = {Worseck, G{\´a}bor}, title = {The transverse proximity effect in quasar spectra}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-18738}, school = {Universit{\"a}t Potsdam}, year = {2007}, abstract = {The intergalactic medium is kept highly photoionised by the intergalactic UV background radiation field generated by the overall population of quasars and galaxies. In the vicinity of sources of UV photons, such as luminous high-redshift quasars, the UV radiation field is enhanced due to the local source contribution. The higher degree of ionisation is visible as a reduced line density or generally as a decreased level of absorption in the Lyman alpha forest of neutral hydrogen. This so-called proximity effect has been detected with high statistical significance towards luminous quasars. If quasars radiate rather isotropically, background quasar sightlines located near foreground quasars should show a region of decreased Lyman alpha absorption close to the foreground quasar. Despite considerable effort, such a transverse proximity effect has only been detected in a few cases. So far, studies of the transverse proximity effect were mostly limited by the small number of suitable projected pairs or groups of high-redshift quasars. With the aim to substantially increase the number of quasar groups in the vicinity of bright quasars we conduct a targeted survey for faint quasars around 18 well-studied quasars at employing slitless spectroscopy. Among the reduced and calibrated slitless spectra of 29000 objects on a total area of 4.39 square degrees we discover in total 169 previously unknown quasar candidates based on their prominent emission lines. 81 potential z>1.7 quasars are selected for confirmation by slit spectroscopy at the Very Large Telescope (VLT). We are able to confirm 80 of these. 64 of the newly discovered quasars reside at z>1.7. The high success rate of the follow-up observations implies that the majority of the remaining candidates are quasars as well. In 16 of these groups we search for a transverse proximity effect as a systematic underdensity in the HI Lyman alpha absorption. We employ a novel technique to characterise the random absorption fluctuations in the forest in order to estimate the significance of the transverse proximity effect. Neither low-resolution spectra nor high-resolution spectra of background quasars of our groups present evidence for a transverse proximity effect. However, via Monte Carlo simulations the effect should be detectable only at the 1-2sigma level near three of the foreground quasars. Thus, we cannot distinguish between the presence or absence of a weak signature of the transverse proximity effect. The systematic effects of quasar variability, quasar anisotopy and intrinsic overdensities near quasars likely explain the apparent lack of the transverse proximity effect. Even in absence of the systematic effects, we show that a statistically significant detection of the transverse proximity effect requires at least 5 medium-resolution quasar spectra of background quasars near foreground quasars whose UV flux exceeds the UV background by a factor 3. Therefore, statistical studies of the transverse proximity effect require large numbers of suitable pairs. Two sightlines towards the central quasars of our survey fields show intergalactic HeII Lyman alpha absorption. A comparison of the HeII absorption to the corresponding HI absorption yields an estimate of the spectral shape of the intergalactic UV radiation field, typically parameterised by the HeII/HI column density ratio eta. We analyse the fluctuating UV spectral shape on both lines of sight and correlate it with seven foreground quasars. On the line of sight towards Q0302-003 we find a harder radiation field near 4 foreground quasars. In the direct vicinity of the quasars eta is consistent with values of 25-100, whereas at large distances from the quasars eta>200 is required. The second line of sight towards HE2347-4342 probes lower redshifts where eta is directly measurable in the resolved HeII forest. Again we find that the radiation field near the 3 foreground quasars is significantly harder than in general. While eta still shows large fluctuations near the quasars, probably due to radiative transfer, the radiation field is on average harder near the quasars than far away from them. We interpret these discoveries as the first detections of the transverse proximity effect as a local hardness fluctuation in the UV spectral shape. No significant HI proximity effect is predicted for the 7 foreground quasars. In fact, the HI absorption near the quasars is close to or slightly above the average, suggesting that the weak signature of the transverse proximity effect is masked by intrinsic overdensities. However, we show that the UV spectral shape traces the transverse proximity effect even in overdense regions or at large distances. Therefore, the spectral hardness is a sensitive physical measure of the transverse proximity effect that is able to break the density degeneracy affecting the traditional searches.}, language = {en} } @phdthesis{Wolff2020, author = {Wolff, Christian Michael}, title = {Identification and reduction of losses in perovskite solar cells}, doi = {10.25932/publishup-47930}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-479301}, school = {Universit{\"a}t Potsdam}, pages = {x, 158}, year = {2020}, abstract = {Perovskite solar cells have become one of the most studied systems in the quest for new, cheap and efficient solar cell materials. Within a decade device efficiencies have risen to >25\% in single-junction and >29\% in tandem devices on top of silicon. This rapid improvement was in many ways fortunate, as e. g. the energy levels of commonly used halide perovskites are compatible with already existing materials from other photovoltaic technologies such as dye-sensitized or organic solar cells. Despite this rapid success, fundamental working principles must be understood to allow concerted further improvements. This thesis focuses on a comprehensive understanding of recombination processes in functioning devices. First the impact the energy level alignment between the perovskite and the electron transport layer based on fullerenes is investigated. This controversial topic is comprehensively addressed and recombination is mitigated through reducing the energy difference between the perovskite conduction band minimum and the LUMO of the fullerene. Additionally, an insulating blocking layer is introduced, which is even more effective in reducing this recombination, without compromising carrier collection and thus efficiency. With the rapid efficiency development (certified efficiencies have broken through the 20\% ceiling) and thousands of researchers working on perovskite-based optoelectronic devices, reliable protocols on how to reach these efficiencies are lacking. Having established robust methods for >20\% devices, while keeping track of possible pitfalls, a detailed description of the fabrication of perovskite solar cells at the highest efficiency level (>20\%) is provided. The fabrication of low-temperature p-i-n structured devices is described, commenting on important factors such as practical experience, processing atmosphere \& temperature, material purity and solution age. Analogous to reliable fabrication methods, a method to identify recombination losses is needed to further improve efficiencies. Thus, absolute photoluminescence is identified as a direct way to quantify the Quasi-Fermi level splitting of the perovskite absorber (1.21eV) and interfacial recombination losses the transport layers impose, reducing the latter to ~1.1eV. Implementing very thin interlayers at both the p- and n-interface (PFN-P2 and LiF, respectively), these losses are suppressed, enabling a VOC of up to 1.17eV. Optimizing the device dimensions and the bandgap, 20\% devices with 1cm2 active area are demonstrated. Another important consideration is the solar cells' stability if subjected to field-relevant stressors during operation. In particular these are heat, light, bias or a combination thereof. Perovskite layers - especially those incorporating organic cations - have been shown to degrade if subjected to these stressors. Keeping in mind that several interlayers have been successfully used to mitigate recombination losses, a family of perfluorinated self-assembled monolayers (X-PFCn, where X denotes I/Br and n = 7-12) are introduced as interlayers at the n-interface. Indeed, they reduce interfacial recombination losses enabling device efficiencies up to 21.3\%. Even more importantly they improve the stability of the devices. The solar cells with IPFC10 are stable over 3000h stored in the ambient and withstand a harsh 250h of MPP at 85◦C without appreciable efficiency losses. To advance further and improve device efficiencies, a sound understanding of the photophysics of a device is imperative. Many experimental observations in recent years have however drawn an inconclusive picture, often suffering from technical of physical impediments, disguising e. g. capacitive discharge as recombination dynamics. To circumvent these obstacles, fully operational, highly efficient perovskites solar cells are investigated by a combination of multiple optical and optoelectronic probes, allowing to draw a conclusive picture of the recombination dynamics in operation. Supported by drift-diffusion simulations, the device recombination dynamics can be fully described by a combination of first-, second- and third-order recombination and JV curves as well as luminescence efficiencies over multiple illumination intensities are well described within the model. On this basis steady state carrier densities, effective recombination constants, densities-of-states and effective masses are calculated, putting the devices at the brink of the radiative regime. Moreover, a comprehensive review of recombination in state-of-the-art devices is given, highlighting the importance of interfaces in nonradiative recombination. Different strategies to assess these are discussed, before emphasizing successful strategies to reduce interfacial recombination and pointing towards the necessary steps to further improve device efficiency and stability. Overall, the main findings represent an advancement in understanding loss mechanisms in highly efficient solar cells. Different reliable optoelectronic techniques are used and interfacial losses are found to be of grave importance for both efficiency and stability. Addressing the interfaces, several interlayers are introduced, which mitigate recombination losses and degradation.}, language = {en} } @phdthesis{Willig2019, author = {Willig, Lisa}, title = {Ultrafast magneto-optical studies of remagnetisation dynamics in transition metals}, doi = {10.25932/publishup-44194}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-441942}, school = {Universit{\"a}t Potsdam}, pages = {XIV, 113, XVII}, year = {2019}, abstract = {Ultrafast magnetisation dynamics have been investigated intensely for two decades. The recovery process after demagnetisation, however, was rarely studied experimentally and discussed in detail. The focus of this work lies on the investigation of the magnetisation on long timescales after laser excitation. It combines two ultrafast time resolved methods to study the relaxation of the magnetic and lattice system after excitation with a high fluence ultrashort laser pulse. The magnetic system is investigated by time resolved measurements of the magneto-optical Kerr effect. The experimental setup has been implemented in the scope of this work. The lattice dynamics were obtained with ultrafast X-ray diffraction. The combination of both techniques leads to a better understanding of the mechanisms involved in magnetisation recovery from a non-equilibrium condition. Three different groups of samples are investigated in this work: Thin Nickel layers capped with nonmagnetic materials, a continuous sample of the ordered L10 phase of Iron Platinum and a sample consisting of Iron Platinum nanoparticles embedded in a carbon matrix. The study of the remagnetisation reveals a general trend for all of the samples: The remagnetisation process can be described by two time dependences. A first exponential recovery that slows down with an increasing amount of energy absorbed in the system until an approximately linear time dependence is observed. This is followed by a second exponential recovery. In case of low fluence excitation, the first recovery is faster than the second. With increasing fluence the first recovery is slowed down and can be described as a linear function. If the pump-induced temperature increase in the sample is sufficiently high, a phase transition to a paramagnetic state is observed. In the remagnetisation process, the transition into the ferromagnetic state is characterised by a distinct transition between the linear and exponential recovery. From the combination of the transient lattice temperature Tp(t) obtained from ultrafast X-ray measurements and magnetisation M(t) gained from magneto-optical measurements we construct the transient magnetisation versus temperature relations M(Tp). If the lattice temperature remains below the Curie temperature the remagnetisation curve M(Tp) is linear and stays below the M(T) curve in equilibrium in the continuous transition metal layers. When the sample is heated above phase transition, the remagnetisation converges towards the static temperature dependence. For the granular Iron Platinum sample the M(Tp) curves for different fluences coincide, i.e. the remagnetisation follows a similar path irrespective of the initial laser-induced temperature jump.}, language = {en} } @phdthesis{Wilhelm2021, author = {Wilhelm, Alina}, title = {Stochastic re-acceleration of particles in supernova remnants}, doi = {10.25932/publishup-51291}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-512915}, school = {Universit{\"a}t Potsdam}, pages = {IV, 124}, year = {2021}, abstract = {Supernova remnants (SNRs) are discussed as the most promising sources of galactic cosmic rays (CR). The diffusive shock acceleration (DSA) theory predicts particle spectra in a rough agreement with observations. Upon closer inspection, however, the photon spectra of observed SNRs indicate that the particle spectra produced at SNRs shocks deviate from the standard expectation. This work suggests a viable explanation for a softening of the particle spectra in SNRs. The basic idea is the re-acceleration of particles in the turbulent region immediately downstream of the shock. This thesis shows that at the re-acceleration of particles by the fast-mode waves in the downstream region can be efficient enough to impact particle spectra over several decades in energy. To demonstrate this, a generic SNR model is presented, where the evolution of particles is described by the reduced transport equation for CR. It is shown that the resulting particle and the corresponding synchrotron spectra are significantly softer compared to the standard case. Next, this work outlines RATPaC, a code developed to model particle acceleration and corresponding photon emissions in SNRs. RATPaC solves the particle transport equation in test-particle mode using hydrodynamic simulations of the SNR plasma flow. The background magnetic field can be either computed from the induction equation or follows analytic profiles. This work presents an extended version of RATPaC that accounts for stochastic re-acceleration by fast-mode waves that provide diffusion of particles in momentum space. This version is then applied to model the young historical SNR Tycho. According to radio observations, Tycho's SNR features the radio spectral index of approximately -0.65. In previous modeling approaches, this fact has been attributed to the strongly distinctive Alfv{\´e}nic drift, which is assumed to operate in the shock vicinity. In this work, the problems and inconsistencies of this scenario are discussed. Instead, stochastic re-acceleration of electrons in the immediate downstream region of Tycho's SNR is suggested as a cause for the soft radio spectrum. Furthermore, this work investigates two different scenarios for magnetic-field distributions inside Tycho's SNR. It is concluded that magnetic-field damping is needed to account for the observed filaments in the radio range. Two models are presented for Tycho's SNR, both of them feature strong hadronic contribution. Thus, a purely leptonic model is considered as very unlikely. Additionally, to the detailed modeling of Tycho's SNR, this dissertation presents a relatively simple one-zone model for the young SNR Cassiopeia A and an interpretation for the recently analyzed VERITAS and Fermi-LAT data. It shows that the γ-ray emission of Cassiopeia A cannot be explained without a hadronic contribution and that the remnant accelerates protons up to TeV energies. Thus, Cassiopeia A is found to be unlikely a PeVatron.}, language = {en} } @phdthesis{Wieland2015, author = {Wieland, Volkmar}, title = {Particle-in-cell simulations of perpendicular supernova shock fronts}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-74532}, school = {Universit{\"a}t Potsdam}, pages = {v, 89}, year = {2015}, abstract = {The origin of cosmic rays was the subject of several studies for over a century. The investigations done within this dissertation are one small step to shed some more light on this mystery. Locating the sources of cosmic rays is not trivial due to the interstellar magnetic field. However, the Hillas criterion allows us to arrive at the conclusion that supernova remnants are our main suspect for the origin of galactic cosmic rays. The mechanism by which they are accelerating particles is found within the field of shock physics as diffusive shock acceleration. To allow particles to enter this process also known as Fermi acceleration pre-acceleration processes like shock surfing acceleration and shock drift acceleration are necessary. Investigating the processes happening in the plasma shocks of supernova remnants is possible by utilising a simplified model which can be simulated on a computer using Particle-in-Cell simulations. We developed a new and clean setup to simulate the formation of a double shock, i.e., consisting of a forward and a reverse shock and a contact discontinuity, by the collision of two counter-streaming plasmas, in which a magnetic field can be woven into. In a previous work, we investigated the processes at unmagnetised and at magnetised parallel shocks, whereas in the current work, we move our investigation on to magnetised perpendicular shocks. Due to a much stronger confinement of the particles to the collision region the perpendicular shock develops much faster than the parallel shock. On the other hand, this leads to much weaker turbulence. We are able to find indications for shock surfing acceleration and shock drift acceleration happening at the two shocks leading to populations of pre-accelerated particles that are suitable as a seed population to be injected into further diffusive shock acceleration to be accelerated to even higher energies. We observe the development of filamentary structures in the shock ramp of the forward shock, but not at the reverse shock. This leads to the conclusion that the development of such structures in the shock ramp of quasi-perpendicular collisionless shocks might not necessarily be determined by the existence of a critical sonic Mach number but by a critical shock speed. The results of the investigations done within this dissertation might be useful for further studies of oblique shocks and for studies using hybrid or magnetohydrodynamic simulations. Together with more sophisticated observational methods, these studies will help to bring us closer to an answer as to how particles can be accelerated in supernova remnants and eventually become cosmic rays that can be detected on Earth.}, language = {en} } @phdthesis{Werhahn2023, author = {Werhahn, Maria}, title = {Simulating galaxy evolution with cosmic rays: the multi-frequency view}, doi = {10.25932/publishup-57285}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-572851}, school = {Universit{\"a}t Potsdam}, pages = {5, 220}, year = {2023}, abstract = {Cosmic rays (CRs) constitute an important component of the interstellar medium (ISM) of galaxies and are thought to play an essential role in governing their evolution. In particular, they are able to impact the dynamics of a galaxy by driving galactic outflows or heating the ISM and thereby affecting the efficiency of star-formation. Hence, in order to understand galaxy formation and evolution, we need to accurately model this non-thermal constituent of the ISM. But except in our local environment within the Milky Way, we do not have the ability to measure CRs directly in other galaxies. However, there are many ways to indirectly observe CRs via the radiation they emit due to their interaction with magnetic and interstellar radiation fields as well as with the ISM. In this work, I develop a numerical framework to calculate the spectral distribution of CRs in simulations of isolated galaxies where a steady-state between injection and cooling is assumed. Furthermore, I calculate the non-thermal emission processes arising from the modelled CR proton and electron spectra ranging from radio wavelengths up to the very high-energy gamma-ray regime. I apply this code to a number of high-resolution magneto-hydrodynamical (MHD) simulations of isolated galaxies, where CRs are included. This allows me to study their CR spectra and compare them to observations of the CR proton and electron spectra by the Voyager-1 satellite and the AMS-02 instrument in order to reveal the origin of the measured spectral features. Furthermore, I provide detailed emission maps, luminosities and spectra of the non-thermal emission from our simulated galaxies that range from dwarfs to Milk-Way analogues to starburst galaxies at different evolutionary stages. I successfully reproduce the observed relations between the radio and gamma-ray luminosities with the far-infrared (FIR) emission of star-forming (SF) galaxies, respectively, where the latter is a good tracer of the star-formation rate. I find that highly SF galaxies are close to the limit where their CR population would lose all of their energy due to the emission of radiation, whereas CRs tend to escape low SF galaxies more quickly. On top of that, I investigate the properties of CR transport that are needed in order to match the observed gamma-ray spectra. Furthermore, I uncover the underlying processes that enable the FIR-radio correlation (FRC) to be maintained even in starburst galaxies and find that thermal free-free-emission naturally explains the observed radio spectra in SF galaxies like M82 and NGC 253 thus solving the riddle of flat radio spectra that have been proposed to contradict the observed tight FRC. Lastly, I scrutinise the steady-state modelling of the CR proton component by investigating for the first time the influence of spectrally resolved CR transport in MHD simulations on the hadronic gamma-ray emission of SF galaxies revealing new insights into the observational signatures of CR transport both spectrally and spatially.}, language = {en} } @phdthesis{Wechakama2013, author = {Wechakama, Maneenate}, title = {Multi-messenger constraints and pressure from dark matter annihilation into electron-positron pairs}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-67401}, school = {Universit{\"a}t Potsdam}, year = {2013}, abstract = {Despite striking evidence for the existence of dark matter from astrophysical observations, dark matter has still escaped any direct or indirect detection until today. Therefore a proof for its existence and the revelation of its nature belongs to one of the most intriguing challenges of nowadays cosmology and particle physics. The present work tries to investigate the nature of dark matter through indirect signatures from dark matter annihilation into electron-positron pairs in two different ways, pressure from dark matter annihilation and multi-messenger constraints on the dark matter annihilation cross-section. We focus on dark matter annihilation into electron-positron pairs and adopt a model-independent approach, where all the electrons and positrons are injected with the same initial energy E_0 ~ m_dm*c^2. The propagation of these particles is determined by solving the diffusion-loss equation, considering inverse Compton scattering, synchrotron radiation, Coulomb collisions, bremsstrahlung, and ionization. The first part of this work, focusing on pressure from dark matter annihilation, demonstrates that dark matter annihilation into electron-positron pairs may affect the observed rotation curve by a significant amount. The injection rate of this calculation is constrained by INTEGRAL, Fermi, and H.E.S.S. data. The pressure of the relativistic electron-positron gas is computed from the energy spectrum predicted by the diffusion-loss equation. For values of the gas density and magnetic field that are representative of the Milky Way, it is estimated that the pressure gradients are strong enough to balance gravity in the central parts if E_0 < 1 GeV. The exact value depends somewhat on the astrophysical parameters, and it changes dramatically with the slope of the dark matter density profile. For very steep slopes, as those expected from adiabatic contraction, the rotation curves of spiral galaxies would be affected on kiloparsec scales for most values of E_0. By comparing the predicted rotation curves with observations of dwarf and low surface brightness galaxies, we show that the pressure from dark matter annihilation may improve the agreement between theory and observations in some cases, but it also imposes severe constraints on the model parameters (most notably, the inner slope of the halo density profile, as well as the mass and the annihilation cross-section of dark matter particles into electron-positron pairs). In the second part, upper limits on the dark matter annihilation cross-section into electron-positron pairs are obtained by combining observed data at different wavelengths (from Haslam, WMAP, and Fermi all-sky intensity maps) with recent measurements of the electron and positron spectra in the solar neighbourhood by PAMELA, Fermi, and H.E.S.S.. We consider synchrotron emission in the radio and microwave bands, as well as inverse Compton scattering and final-state radiation at gamma-ray energies. For most values of the model parameters, the tightest constraints are imposed by the local positron spectrum and synchrotron emission from the central regions of the Galaxy. According to our results, the annihilation cross-section should not be higher than the canonical value for a thermal relic if the mass of the dark matter candidate is smaller than a few GeV. In addition, we also derive a stringent upper limit on the inner logarithmic slope α of the density profile of the Milky Way dark matter halo (α < 1 if m_dm < 5 GeV, α < 1.3 if m_dm < 100 GeV and α < 1.5 if m_dm < 2 TeV) assuming a dark matter annihilation cross-section into electron-positron pairs (σv) = 3*10^-26 cm^3 s^-1, as predicted for thermal relics from the big bang.}, language = {en} } @phdthesis{Weber2004, author = {Weber, Michael H.}, title = {Robotic telescopes \& Doppler imaging : measuring differential rotation on long-period active stars}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-0001834}, school = {Universit{\"a}t Potsdam}, year = {2004}, abstract = {Auf der Sonne sind viele Ph{\"a}nomene zu sehen die mit der solaren magnetischen Aktivit{\"a}t zusammenh{\"a}ngen. Das daf{\"u}r zust{\"a}ndige Magnetfeld wird durch einen Dynamo erzeugt, der sich vermutlich am Boden der Konvektionszone in der sogenannten Tachocline befindet. Angetrieben wird der Dynamo teils von der differenziellen Rotation, teils von den magnetischen Turbulenzen in der Konvektionszone. Die differentielle Rotation kann an der Sonnenoberfl{\"a}che durch beobachten der Sonnenfleckbewegungen gemessen werden.Um einen gr{\"o}ßeren Parameterraum zum Testen von Dynamotheorien zu erhalten, kann man diese Messungen auch auf andere Sterne ausdehnen. Das prim{\"a}re Problem dabei ist, dass die Oberfl{\"a}chen von Sternen nicht direkt beobachtet werden k{\"o}nnen. Indirekt kann man dies jedoch mit Hilfe der Doppler-imaging Methode erreichen, die die Doppler-Verbreitung der Spektrallinien von schnell rotierenden Sternen ben{\"u}tzt. Um jedoch ein Bild der Sternoberfl{\"a}che zu erhalten, bedarf es vieler hochaufgel{\"o}ster spektroskopischer Beobachtungen, die gleichm{\"a}ßig {\"u}ber eine Sternrotation verteilt sein m{\"u}ssen. F{\"u}r Sterne mit langen Rotationsperioden sind diese Beobachtungen nur schwierig durchzuf{\"u}hren. Das neue robotische Observatorium STELLA adressiert dieses Problem und bietet eine auf Dopplerimaging abgestimmte Ablaufplanung der Beobachtungen an. Dies wird solche Beobachtungen nicht nur leichter durchf{\"u}hrbar machen, sondern auch effektiver gestalten.Als Vorschau welche Ergebnisse mit STELLA erwartet werden k{\"o}nnen dient eine Studie an sieben Sternen die allesamt eine lange (zwischen sieben und 25 Tagen) Rotationsperiode haben. Alle Sterne zeigen differentielle Rotation, allerdings sind die Messfehler aufgrund der nicht zufriedenstellenden Datenqualit{\"a}t von gleicher Gr{\"o}ßenordnung wie die Ergebnisse, ein Problem das bei STELLA nicht auftreten wird. Um die Konsistenz der Ergebnisse zu pr{\"u}fen wurde wenn m{\"o}glich sowohl eine Kreuzkorrelationsanalyse als auch die sheared-image Methode angewandt. Vier von diesen sieben Sternen weisen eine differentielle Rotation in umgekehrter Richtung auf als auf der Sonne zu sehen ist. Die restlichen drei Sterne weisen schwache, aber in der Richtung sonnen{\"a}hnliche differentielle Rotation auf.Abschließend werden diese neuen Messungen mit bereits publizierten Werten kombiniert, und die so erhaltenen Daten auf Korrelationen zwischen differentieller Rotation, Rotationsperiode, Evolutionsstaus, Spektraltyp und Vorhandensein eines Doppelsterns {\"u}berpr{\"u}ft. Alle Sterne zusammen zeigen eine signifikante Korrelation zwischen dem Betrag der differenziellen Rotation und der Rotationsperiode. Unterscheidet man zwischen den Richtungen der differentiellen Rotation, so bleibt nur eine Korrelation der Sterne mit antisolarem Verhalten. Dar{\"u}berhinaus zeigt sich auch, dass Doppelsterne schw{\"a}cher differentiell rotieren.}, language = {en} } @phdthesis{Washuettl2004, author = {Wash{\"u}ttl, Albert}, title = {EI Eridani and the art of doppler imaging : a long-term study}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-0001714}, school = {Universit{\"a}t Potsdam}, year = {2004}, abstract = {Das Verst{\"a}ndnis magnetisch verursachter Aktivit{\"a}t auf Sternen sowie der zugrundeliegenden Dynamoprozesse ist von fundamentaler Bedeutung f{\"u}r das Verst{\"a}ndnis von Entstehung und Entwicklung von Sternen sowie des Lebens im Universum. Sichtbare Erscheinungen dieser stellaren Aktivit{\"a}t sind u.a. Sternflecken, welche als Indikatoren des zugrundeliegenden Magnetfeldes dienen. Solche Flecken k{\"o}nnen auf anderen Sternen als der Sonne nicht direkt beobachtet werden, zumal mit den heutigen technischen Mitteln eine Aufl{\"o}sung der Oberfl{\"a}che selbst der benachbarten Sterne unm{\"o}glich ist. Eine indirekte Rekonstruktionsmethode namens 'Doppler Imaging' erlaubt es jedoch, auf die Temperaturverteilung auf der Sternoberfl{\"a}che zu schließen. F{\"u}r diese Arbeit wurden elf Jahre kontinuierlicher spektroskopischer Beobachtungen des aktiven Doppelsterns EI Eridani herangezogen, um insgesamt 34 Dopplerkarten zu erstellen. In der Folge wird versucht, eine Grundlage zu schaffen f{\"u}r die Analyse des zweidimensionalen Informationsgehalts dieser Karten. Drei Oberfl{\"a}chenkartenparameter werden vorgeschlagen: gemittelte Temperatur, getrennt f{\"u}r verschiedenen stellare Breitenb{\"a}nder; relative Fleckenh{\"a}ufigkeit; und, zum Zwecke der Auswertung der strukturellen Temperaturverteilung, L{\"a}ngen- und Breiten-Ortsfunktion der Sternfleckenh{\"a}ufung. Die resultierenden Werte zeigen deutlich, daß kein zeitlicher Zusammenhang mit dem photometrischen Aktivit{\"a}tszyklus besteht. Die Morphologie der Fleckenverteilung bleibt w{\"a}hrend des kompletten Beobachtungszeitraums im wesentlichen konstant. Im Gegensatz zur Sonne gibt es also, im beobachteten Zeitraum und innerhalb der bestehenden Genauigkeit, keinen Fleckenzyklus auf dem aktiven Stern EI Eri. Dar{\"u}berhinaus wurde eine ausf{\"u}hrliche Studie der stellaren Parameter von EI Eri und eine vorl{\"a}ufige Absch{\"a}tzung der differentiellen Rotation auf EI Eri durchgef{\"u}hrt, die eine anti-solare Ausrichtung aufzuweisen scheint, d.h. der Pol rotiert schneller als der {\"A}quator.}, language = {en} } @phdthesis{Wang2020, author = {Wang, Jingwen}, title = {Electret properties of polypropylene with surface chemical modification and crystalline reconstruction}, doi = {10.25932/publishup-47027}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-470271}, school = {Universit{\"a}t Potsdam}, pages = {vi, 121}, year = {2020}, abstract = {As one of the most-produced commodity polymers, polypropylene draws considerable scientific and commercial interest as an electret material. In the present thesis, the influence of the surface chemical modification and crystalline reconstruction on the electret properties of the polypropylene thin films will be discussed. The chemical treatment with orthophosphoric acid can significantly improve the surface charge stability of the polypropylene electrets by introducing phosphorus- and oxygen-containing structures onto the modified surface. The thermally stimulated discharge measurement and charge profiling by means of piezoelectrically generated pressure steps are used to investigate the electret behaviour. It is concluded that deep traps of limited number density are created during the treatment with inorganic chemicals. Hence, the improvement dramatically decreases when the surface-charge density is substantially higher than ±1.2×10^(-3) C·m^(-2). The newly formed traps also show a higher trapping energy for negative charges. The energetic distributions of the traps in the non-treated and chemically treated samples offer an insight regarding the surface and foreign-chemical dominance on the charge storage and transport in the polypropylene electrets. Additionally, different electret properties are observed on the polypropylene films with the spherulitic and transcrystalline structures. It indicates the dependence of the charge storage and transport on the crystallite and molecular orientations in the crystalline phase. In general, a more diverse crystalline growth in the spherulitic samples can result in a more complex energetic trap distribution, in comparison to that in a transcrystalline polypropylene. The double-layer transcrystalline polypropylene film with a crystalline interface in the middle can be obtained by crystallising the film in contact with rough moulding surfaces on both sides. A layer of heterocharges appears on each side of the interface in the double-layer transcrystalline polypropylene electrets after the thermal poling. However, there is no charge captured within the transcrystalline layers. The phenomenon reveals the importance of the crystalline interface in terms of creating traps with the higher activation energy in polypropylene. The present studies highlight the fact that even slight variations in the polypropylene film may lead to dramatic differences in its electret properties.}, language = {en} } @phdthesis{Vu2022, author = {Vu, Nils Leif}, title = {A task-based parallel elliptic solver for numerical relativity with discontinuous Galerkin methods}, doi = {10.25932/publishup-56226}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-562265}, school = {Universit{\"a}t Potsdam}, pages = {172}, year = {2022}, abstract = {Elliptic partial differential equations are ubiquitous in physics. In numerical relativity---the study of computational solutions to the Einstein field equations of general relativity---elliptic equations govern the initial data that seed every simulation of merging black holes and neutron stars. In the quest to produce detailed numerical simulations of these most cataclysmic astrophysical events in our Universe, numerical relativists resort to the vast computing power offered by current and future supercomputers. To leverage these computational resources, numerical codes for the time evolution of general-relativistic initial value problems are being developed with a renewed focus on parallelization and computational efficiency. Their capability to solve elliptic problems for accurate initial data must keep pace with the increasing detail of the simulations, but elliptic problems are traditionally hard to parallelize effectively. In this thesis, I develop new numerical methods to solve elliptic partial differential equations on computing clusters, with a focus on initial data for orbiting black holes and neutron stars. I develop a discontinuous Galerkin scheme for a wide range of elliptic equations, and a stack of task-based parallel algorithms for their iterative solution. The resulting multigrid-Schwarz preconditioned Newton-Krylov elliptic solver proves capable of parallelizing over 200 million degrees of freedom to at least a few thousand cores, and already solves initial data for a black hole binary about ten times faster than the numerical relativity code SpEC. I also demonstrate the applicability of the new elliptic solver across physical disciplines, simulating the thermal noise in thin mirror coatings of interferometric gravitational-wave detectors to unprecedented accuracy. The elliptic solver is implemented in the new open-source SpECTRE numerical relativity code, and set up to support simulations of astrophysical scenarios for the emerging era of gravitational-wave and multimessenger astronomy.}, language = {en} } @phdthesis{Voroshnin2023, author = {Voroshnin, Vladimir}, title = {Control over spin and electronic structure of MoS₂ monolayer via interactions with substrates}, doi = {10.25932/publishup-59070}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-590709}, school = {Universit{\"a}t Potsdam}, pages = {viii, 125}, year = {2023}, abstract = {The molybdenum disulfide (MoS2) monolayer is a semiconductor with a direct bandgap while it is a robust and affordable material. It is a candidate for applications in optoelectronics and field-effect transistors. MoS2 features a strong spin-orbit coupling which makes its spin structure promising for acquiring the Kane-Mele topological concept with corresponding applications in spintronics and valleytronics. From the optical point of view, the MoS2 monolayer features two valleys in the regions of K and K' points. These valleys are differentiated by opposite spins and a related valley-selective circular dichroism. In this study we aim to manipulate the MoS2 monolayer spin structure in the vicinity of the K and K' points to explore the possibility of getting control over the optical and electronic properties. We focus on two different substrates to demonstrate two distinct routes: a gold substrate to introduce a Rashba effect and a graphene/cobalt substrate to introduce a magnetic proximity effect in MoS2. The Rashba effect is proportional to the out-of-plane projection of the electric field gradient. Such a strong change of the electric field occurs at the surfaces of a high atomic number materials and effectively influence conduction electrons as an in-plane magnetic field. A molybdenum and a sulfur are relatively light atoms, thus, similar to many other 2D materials, intrinsic Rashba effect in MoS2 monolayer is vanishing small. However, proximity of a high atomic number substrate may enhance Rashba effect in a 2D material as it was demonstrated for graphene previously. Another way to modify the spin structure is to apply an external magnetic field of high magnitude (several Tesla), and cause a Zeeman splitting, the conduction electrons. However, a similar effect can be reached via magnetic proximity which allows us to reduce external magnetic fields significantly or even to zero. The graphene on cobalt interface is ferromagnetic and stable for MoS2 monolayer synthesis. Cobalt is not the strongest magnet; therefore, stronger magnets may lead to more significant results. Nowadays most experimental studies on the dichalcogenides (MoS2 included) are performed on encapsulated heterostructures that are produced by mechanical exfoliation. While mechanical exfoliation (or scotch-tape method) allows to produce a huge variety of structures, the shape and the size of the samples as well as distance between layers in heterostructures are impossible to control reproducibly. In our study we used molecular beam epitaxy (MBE) methods to synthesise both MoS2/Au(111) and MoS2/graphene/Co systems. We chose to use MBE, as it is a scalable and reproducible approach, so later industry may adapt it and take over. We used graphene/cobalt instead of just a cobalt substrate because direct contact of MoS2\ monolayer and a metallic substrate may lead to photoluminescence (PL) quenching in the metallic substrate. Graphene and hexagonal boron nitride monolayer are considered building blocks of a new generation of electronics also commonly used as encapsulating materials for PL studies. Moreover graphene is proved to be a suitable substrate for the MBE growth of transitional metal dichalcogenides (TMDCs). In chapter 1, we start with an introduction to TMDCs. Then we focus on MoS2 monolayer state of the art research in the fields of application scenario; synthesis approaches; electronic, spin, and optical properties; and interactions with magnetic fields and magnetic materials. We briefly touch the basics of magnetism in solids and move on to discuss various magnetic exchange interactions and magnetic proximity effect. Then we describe MoS2 optical properties in more detail. We start from basic exciton physics and its manifestation in the MoS2 monolayer. We consider optical selection rules in the MoS2 monolayer and such properties as chirality, spin-valley locking, and coexistence of bright and dark excitons. Chapter 2 contains an overview of the employed surface science methods: angle-integrated, angle-resolved, and spin-resolved photoemission; low energy electron diffraction and scanning tunneling microscopy. In chapter 3, we describe MoS2 monolayer synthesis details for two substrates: gold monocrystal with (111) surface and graphene on cobalt thin film with Co(111) surface orientation. The synthesis descriptions are followed by a detailed characterisation of the obtained structures: fingerprints of MoS2 monolayer formation; MoS2 monolayer symmetry and its relation to the substrate below; characterisation of MoS2 monolayer coverage, domain distribution, sizes and shapes, and moire structures. In chapter~4, we start our discussion with MoS2/Au(111) electronic and spin structure. Combining density functional theory computations (DFT) and spin-resolved photoemission studies, we demonstrate that the MoS2 monolayer band structure features an in-plane Rashba spin splitting. This confirms the possibility of MoS2 monolayer spin structure manipulation via a substrate. Then we investigate the influence of a magnetic proximity in the MoS2/graphene/Co system on the MoS2 monolayer spin structure. We focus our investigation on MoS2 high symmetry points: G and K. First, using spin-resolved measurements, we confirm that electronic states are spin-split at the G point via a magnetic proximity effect. Second, combining spin-resolved measurements and DFT computations for MoS2 monolayer in the K point region, we demonstrate the appearance of a small in-plane spin polarisation in the valence band top and predict a full in-plane spin polarisation for the conduction band bottom. We move forward discussing how these findings are related to the MoS2 monolayer optical properties, in particular the possibility of dark exciton observation. Additionally, we speculate on the control of the MoS2 valley energy via magnetic proximity from cobalt. As graphene is spatially buffering the MoS2 monolayer from the Co thin film, we speculate on the role of graphene in the magnetic proximity transfer by replacing graphene with vacuum and other 2D materials in our computations. We finish our discussion by investigating the K-doped MoS2/graphene/Co system and the influence of this doping on the electronic and spin structure as well as on the magnetic proximity effect. In summary, using a scalable MBE approach we synthesised MoS2/Au(111) and MoS2/graphene/Co systems. We found a Rashba effect taking place in MoS2/Au(111) which proves that the MoS2 monolayer in-plane spin structure can be modified. In MoS2/graphene/Co the in-plane magnetic proximity effect indeed takes place which rises the possibility of fine tuning the MoS2 optical properties via manipulation of the the substrate magnetisation.}, language = {en} } @phdthesis{vonNordheim2018, author = {von Nordheim, Danny}, title = {Dielectric non-linearities of P(VDF-TrFE) single and multilayers for memory applications}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-421778}, school = {Universit{\"a}t Potsdam}, pages = {XVI, 109}, year = {2018}, abstract = {Poly(vinylidene fluoride-trifluoroethylene) (P(VDF-TrFE)) ferroelectric thin films of different molar ratio have been studied with regard to data memory applications. Therefore, films with thicknesses of 200 nm and less have been spin coated from solution. Observations gained from single layers have been extended to multilayer capacitors and three terminal transistor devices. Besides conventional hysteresis measurements, the measurement of dielectric non-linearities has been used as a main tool of characterisation. Being a very sensitive and non-destructive method, non-linearity measurements are well suited for polarisation readout and property studies. Samples have been excited using a high quality, single-frequency sinusoidal voltage with an amplitude significantly smaller than the coercive field of the samples. The response was then measured at the excitation frequency and its higher harmonics. Using the measurement results, the linear and non-linear dielectric permittivities ɛ₁, ɛ₂ and ɛ₃ have been determined. The permittivities have been used to derive the temperature-dependent polarisation behaviour as well as the polarisation state and the order of the phase transitions. The coercive field in VDF-TrFE copolymers is high if compared to their ceramic competitors. Therefore, the film thickness had to be reduced significantly. Considering a switching voltage of 5 V and a coercive field of 50 MV/m, the film thickness has to be 100 nm and below. If the thickness becomes substantially smaller than the other dimensions, surface and interface layer effects become more pronounced. For thicker films of P(VDF-TrFE) with a molar fraction of 56/44 a second-order phase transition without a thermal hysteresis for an ɛ₁(T) temperature cycle has been predicted and observed. This however, could not be confirmed by the measurements of thinner films. A shift of transition temperatures as well as a temperature independent, non-switchable polarisation and a thermal hysteresis for P(VDF-TrFE) 56/44 have been observed. The impact of static electric fields on the polarisation and the phase transition has therefore been studied and simulated, showing that all aforementioned phenomena including a linear temperature dependence of the polarisation might originate from intrinsic electric fields. In further experiments the knowledge gained from single layer capacitors has been extended to bilayer copolymer thin films of different molar composition. Bilayers have been deposited by succeeding cycles of spin coating from solution. Single layers and their bilayer combination have been studied individually in order to prove the layers stability. The individual layers have been found to be physically stable. But while the bilayers reproduced the main ɛ₁(T) properties of the single layers qualitatively, quantitative numbers could not be explained by a simple serial connection of capacitors. Furthermore, a linear behaviour of the polarisation throughout the measured temperature range has been observed. This was found to match the behaviour predicted considering a constant electric field. Retention time is an important quantity for memory applications. Hence, the retention behaviour of VDF-TrFE copolymer thin films has been determined using dielectric non-linearities. The polarisation loss in P(VDF-TrFE) poled samples has been found to be less than 20\% if recorded over several days. The loss increases significantly if the samples have been poled with lower amplitudes, causing an unsaturated polarisation. The main loss was attributed to injected charges. Additionally, measurements of dielectric non-linearities have been proven to be a sensitive and non-destructive tool to measure the retention behaviour. Finally, a ferroelectric field effect transistor using mainly organic materials (FerrOFET) has been successfully studied. DiNaphtho[2,3-b:2',3'-f]Thieno[3,2-b]Thiophene (DNTT) has proven to be a stable, suitable organic semiconductor to build up ferroelectric memory devices. Furthermore, an oxidised aluminium bottom electrode and additional dielectric layers, i.e. parylene C, have proven to reduce the leakage current and therefore enhance the performance significantly.}, language = {en} } @phdthesis{Vlasov2015, author = {Vlasov, Vladimir}, title = {Synchronization of oscillatory networks in terms of global variables}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-78182}, school = {Universit{\"a}t Potsdam}, pages = {82}, year = {2015}, abstract = {Synchronization of large ensembles of oscillators is an omnipresent phenomenon observed in different fields of science like physics, engineering, life sciences, etc. The most simple setup is that of globally coupled phase oscillators, where all the oscillators contribute to a global field which acts on all oscillators. This formulation of the problem was pioneered by Winfree and Kuramoto. Such a setup gives a possibility for the analysis of these systems in terms of global variables. In this work we describe nontrivial collective dynamics in oscillator populations coupled via mean fields in terms of global variables. We consider problems which cannot be directly reduced to standard Kuramoto and Winfree models. In the first part of the thesis we adopt a method introduced by Watanabe and Strogatz. The main idea is that the system of identical oscillators of particular type can be described by a low-dimensional system of global equations. This approach enables us to perform a complete analytical analysis for a special but vast set of initial conditions. Furthermore, we show how the approach can be expanded for some nonidentical systems. We apply the Watanabe-Strogatz approach to arrays of Josephson junctions and systems of identical phase oscillators with leader-type coupling. In the next parts of the thesis we consider the self-consistent mean-field theory method that can be applied to general nonidentical globally coupled systems of oscillators both with or without noise. For considered systems a regime, where the global field rotates uniformly, is the most important one. With the help of this approach such solutions of the self-consistency equation for an arbitrary distribution of frequencies and coupling parameters can be found analytically in the parametric form, both for noise-free and noisy cases. We apply this method to deterministic Kuramoto-type model with generic coupling and an ensemble of spatially distributed oscillators with leader-type coupling. Furthermore, with the proposed self-consistent approach we fully characterize rotating wave solutions of noisy Kuramoto-type model with generic coupling and an ensemble of noisy oscillators with bi-harmonic coupling. Whenever possible, a complete analysis of global dynamics is performed and compared with direct numerical simulations of large populations.}, language = {en} } @phdthesis{Varykhalov2005, author = {Varykhalov, Andrei}, title = {Quantum-size effects in the electronic structure of novel self-organized systems with reduced dimensionality}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-5784}, school = {Universit{\"a}t Potsdam}, year = {2005}, abstract = {The Thesis is focused on the properties of self-organized nanostructures. Atomic and electronic properties of different systems have been investigated using methods of electron diffraction, scanning tunneling microscopy and photoelectron spectroscopy. Implementation of the STM technique (including design, construction, and tuning of the UHV experimental set-up) has been done in the framework of present work. This time-consuming work is reported to greater detail in the experimental part of this Thesis. The scientific part starts from the study of quantum-size effects in the electronic structure of a two-dimensional Ag film on the supporting substrate Ni(111). Distinct quantum well states in the sp-band of Ag were observed in photoelectron spectra. Analysis of thickness- and angle-dependent photoemission supplies novel information on the properties of the interface. For the first time the Ni(111) relative band gap was indirectly probed in the ground-state through the electronic structure of quantum well states in the adlayer. This is particularly important for Ni where valence electrons are strongly correlated. Comparison of the experiment with calculations performed in the formalism of the extended phase accumulation model gives the substrate gap which is fully consistent with the one obtained by ab-initio LDA calculations. It is, however, in controversy to the band structure of Ni measured directly by photoemission. These results lend credit to the simplest view of photoemission from Ni, assigning early observed contradictions between theory and experiments to electron correlation effects in the final state of photoemission. Further, nanosystems of lower dimensionality have been studied. Stepped surfaces W(331) and W(551) were used as one-dimensional model systems and as templates for self-organization of Au nanoclusters. Photon energy dependent photoemission revealed a surface resonance which was never observed before on W(110) which is the base plane of the terrace microsurfaces. The dispersion E(k) of this state measured on stepped W(331) and W(551) with angle-resolved photoelectron spectroscopy is modified by a strong umklapp effect. It appears as two parabolas shifted symmetrically relative to the microsurface normal by half of the Brillouin zone of the step superlattice. The reported results are very important for understanding of the electronic properties of low-dimensional nanostructures. It was also established that W(331) and W(551) can serve as templates for self-organization of metallic nanostructures. A combined study of electronic and atomic properties of sub-monolayer amounts of gold deposited on these templates have shown that if the substrate is slightly pre-oxidized and the temperature is elevated, then Au can alloy with the first monolayer of W. As a result, a nanostructure of uniform clusters of a surface alloy is produced all over the steps. Such clusters feature a novel sp-band in the vicinity of the Fermi level, which appears split into constant energy levels due to effects of lateral quantization. The last and main part of this work is devoted to large-scale reconstructions on surfaces and nanostructures self-assembled on top. The two-dimensional surface carbide W(110)/C-R(15x3) has been extensively investigated. Photoemission studies of quantum size effects in the electronic structure of this reconstruction, combined with an investigation of its surface geometry, lead to an advanced structural model of the carbide overlayer. It was discovered that W(110)/C-R(15x3) can control self-organization of adlayers into nanostructures with extremely different electronic and structural properties. Thus, it was established that at elevated temperature the R(15x3) superstructure controls the self-assembly of sub-monolayer amounts of Au into nm-wide nanostripes. Based on the results of core level photoemission, the R(15x3)-induced surface alloying which takes place between Au and W can be claimed as driving force of self-organization. The observed stripes exhibit a characteristic one-dimensional electronic structure with laterally quantized d-bands. Obviously, these are very important for applications, since dimensions of electronic devices have already stepped into the nm-range, where quantum-size phenomena must undoubtedly be considered. Moreover, formation of perfectly uniform molecular clusters of C60 was demonstrated and described in terms of the van der Waals formalism. It is the first experimental observation of two-dimensional fullerene nanoclusters with "magic numbers". Calculations of the cluster potentials using the static approach have revealed characteristic minima in the interaction energy. They are achieved for 4 and 7 molecules per cluster. The obtained "magic numbers" and the corresponding cluster structures are fully consistent with the results of the STM measurements.}, subject = {Nanostruktur}, language = {en} } @phdthesis{Valliappan2018, author = {Valliappan, Senthamizh Pavai}, title = {Solar Activity Reconstruction from Historical Observations of Sunspots}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-413600}, school = {Universit{\"a}t Potsdam}, pages = {115}, year = {2018}, abstract = {The solar activity and its consequences affect space weather and Earth's climate. The solar activity exhibits a cyclic behaviour with a period of about 11 years. The solar cycle properties are governed by the dynamo taking place in the interior of the Sun, and they are distinctive. Extending the knowledge about solar cycle properties into the past is essential for understanding the solar dynamo and forecasting space weather. It can be acquired through the analysis of historical sunspot drawings. Sunspots are the dark areas, which are associated with strong magnetic fields, on the solar surface. Sunspots are the oldest and longest available observed features of solar activity. One of the longest available records of sunspot drawings is the collection by Samuel Heinrich Schwabe during 1825-1867. The sunspot sizes measured from digitized Schwabe drawings are not to scale and need to be converted into physical sunspot areas. We employed a statistical approach assuming that the area distribution of sunspots was the same in the 19th century as it was in the 20th century. Umbral areas for about 130 000 sunspots observed by Schwabe were obtained. The annually averaged sunspot areas correlate reasonably well with the sunspot number. Tilt angles and polarity separations of sunspot groups were calculated assuming them to be bipolar. There is, of course, no polarity information in the observations. We derived an average tilt angle by attempting to exclude unipolar groups with a minimum separation of the two surmised polarities and an outlier rejection method, which follows the evolution of each group and detects the moment, when it turns unipolar as it decays. As a result, the tilt angles, although displaying considerable natural scatter, are on average 5.85° ± 0.25°, with the leading polarity located closer to the equator, in good agreement with tilt angles obtained from 20th century data sets. Sources of uncertainties in the tilt angle determination are discussed and need to be addressed whenever different data sets are combined. Digital images of observations printed in the books Rosa Ursina and Prodromus pro sole mobili by Christoph Scheiner, as well as the drawings from Scheiner's letters to Marcus Welser, are analyzed to obtain information on the positions and sizes of sunspots that appeared before the Maunder minimum. In most cases, the given orientation of the ecliptic is used to set up the heliographic coordinate system for the drawings. Positions and sizes are measured manually displaying the drawings on a computer screen. Very early drawings have no indication of the solar orientation. A rotational matching using common spots of adjacent days is used in some cases, while in other cases, the assumption that images were aligned with a zenith-horizon coordinate system appeared to be the most likely. In total, 8167 sunspots were measured. A distribution of sunspot latitudes versus time (butterfly diagram) is obtained for Scheiner's observations. The observations of 1611 are very inaccurate, but the drawings of 1612 have at least an indication of the solar orientation, while the remaining part of the spot positions from 1618-1631 have good to very good accuracy. We also computed 697 tilt angles of apparent bipolar sunspot groups, which were observed in the period 1618-1631. We find that the average tilt angle of nearly 4° does not significantly differ from the 20th century values. The solar cycle properties seem to be related to the tilt angles of sunspot groups, and it is an important parameter in the surface flux transport models. The tilt angles of bipolar sunspot groups from various historical sets of solar drawings including from Schwabe and Scheiner are analyzed. Data by Scheiner, Hevelius, Staudacher, Zucconi, Schwabe, and Spörer deliver a series of average tilt angles spanning a period of 270 years, in addition to previously found values for 20th-century data obtained by other authors. We find that the average tilt angles before the Maunder minimum were not significantly different from modern values. However, the average tilt angles of a period 50 years after the Maunder minimum, namely for cycles 0 and 1, were much lower and near zero. The typical tilt angles before the Maunder minimum suggest that abnormally low tilt angles were not responsible for driving the solar cycle into a grand minimum. With the Schwabe (1826-1867) and Spörer (1866-1880) sunspot data, the butterfly diagram of sunspot groups extends back till 1826. A recently developed method, which separates the wings of the butterfly diagram based on the long gaps present in sunspot group occurrences at different latitudinal bands, is used to separate the wings of the butterfly diagram. The cycle-to-cycle variation in the start (F), end (L), and highest (H) latitudes of the wings with respect to the strength of the wings are analyzed. On the whole, the wings of the stronger cycles tend to start at higher latitudes and have a greater extent. The time spans of the wings and the time difference between the wings in the northern hemisphere display a quasi-periodicity of 5-6 cycles. The average wing overlap is zero in the southern hemisphere, whereas it is 2-3 months in the north. A marginally significant oscillation of about 10 solar cycles is found in the asymmetry of the L latitudes. This latest, extended database of butterfly wings provides new observational constraints, regarding the spatio-temporal distribution of sunspot occurrences over the solar cycle, to solar dynamo models.}, language = {en} } @phdthesis{Uyaver2004, author = {Uyaver, Sahin}, title = {Simulation of annealed polyelectrolytes in poor solvents}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-0001488}, school = {Universit{\"a}t Potsdam}, year = {2004}, abstract = {Polymere sind lange kettenartige Molek{\"u}le. Sie bestehen aus vielen elementaren chemischen Einheiten, den Monomeren, die durch kovalente Bindungen aneinander gekettet sind. Polyelektrolyte sind Polymere, die ionisierbare Monomeren enthalten. Aufgrund ihrer speziellen Eigenschaften sind Polyelektrolyte sowohl in der Molekular- und Zellbiologie von großen Bedeutung als auch in der Chemie großtechnisch relevant. Verglichen mit ungeladenen Polymeren sind Polyelektrolyte theoretisch noch wenig verstanden. Insbesondere gilt dies f{\"u}r Polyelektrolyte in sogenanntem schlechten L{\"o}sungsmittel. Ein schlechtes L{\"o}sungsmittel bewirkt eine effektive Anziehung zwischen den Monomeren. F{\"u}r Polyelektrolyte in schlechtem L{\"o}sungsmittel kommt es daher zu einer Konkurrenz zwischen dieser Anziehung und der elektrostatischen Abstoßung. Geladene Polymere werden im Rahmen der chemischen Klassifikation in starke und schwache Polyelektrolyte unterschieden. Erstere zeigen vollst{\"a}ndige Dissoziation unabh{\"a}ngig vom pH-Wert der L{\"o}sung. Die Position der Ladungen auf der Kette wird ausschließlich w{\"a}hrend der Polymersynthese festgelegt. In der Physik spricht man deshalb von Polyelektrolyten mit eingefrorener Ladungsverteilung (quenched polyelectrolytes). Im Falle von schwachen Polyelektrolyten ist die Ladungsdichte auf der Kette nicht konstant, sondern wird durch der pH-Wert der L{\"o}sung kontrolliert. Durch Rekombinations- und Dissoziationsprozesse sind die Ladungen auf der Kette beweglich. Im allgemeinen stellt sich eine inhomogene Gleichgewichtsverteilung ein, die mit der Struktur der Kette gekoppelt ist. Diese Polymere werden deshalb auch Polyelektrolyte mit Gleichgewichtsladungsverteilung (annealed polyelectrolytes) genannt. Wegen des zus{\"a}tzlichen Freiheitsgrades in der Ladungsverteilung werden eine Reihe ungew{\"o}hnlicher Eigenschaften theoretisch vorhergesagt. Mit Hilfe von Simulationen ist es zum ersten Mal gelungen, zu zeigen daß 'annealed' Polyelektrolyte in relativ schlechtem L{\"o}sungsmittel einen diskontinuierlichen Phasen{\"u}bergang durchlaufen, wenn ein kritischer pH-Werts der L{\"o}sung {\"u}berschritten wird. Bei diesem Phasen{\"u}bergang, gehen die Polyelektolyte von einer schwach geladenen kompakten globul{\"a}ren Struktur zu einer stark geladenen gestreckten Konfiguration {\"u}ber. Aufgrund theoretischer Vorhersagen wird erwartet, daß die globul{\"a}re Struktur in weniger schlechtem L{\"o}sungsmittel instabil wird und sich eine Perlenkettenkonfiguration ausbildet. Diese Vorhersage konnte f{\"u}r 'annealed' Polyelektrolyte mit den durchgef{\"u}hrten Simulationen zum ersten Mal best{\"a}tigt werden - inzwischen auch durch erste experimentelle Ergebnisse. Schließlich zeigen die Simulationen auch, daß annealed Polyelektrolyte bei einer kritischen Salzkonzentration in der L{\"o}sung einen scharfen {\"U}bergang zwischen einem stark geladenen gestreckten Zustand und einem schwach geladenen globul{\"a}ren Zustand aufweisen, wiederum in {\"U}bereinstimmung mit theoretischen Erwartungen.}, language = {en} } @phdthesis{Ullner2004, author = {Ullner, Ekkehard}, title = {Noise-induced phenomena of signal transmission in excitable neural models}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-0001522}, school = {Universit{\"a}t Potsdam}, year = {2004}, abstract = {Meine Dissertation behandelt verschiedene neue rauschinduzierte Ph{\"a}nomene in anregbaren Neuronenmodellen, insbesondere solche mit FitzHugh-Nagumo Dynamik. Ich beschreibe das Auftreten von vibronischer Resonanz in anregbaren Systemen. Sowohl in einer anregbaren elektronischen Schaltung als auch im FitzHugh-Nagumo Modell zeige ich, daß eine optimale Amplitude einer hochfrequenten externen Kraft die Signalantwort bez{\"u}glich eines niederfrequenten Signals verbessert. Weiterhin wird der Einfluß von additivem Rauschen auf das Zusammenwirken von stochastischer und vibronischer Resonanz untersucht. Weiterhin untersuche ich Systeme, die sowohl oszillierende als auch anregbare Eigenschaften beinhalten und dadurch zwei interne Frequenzen aufweisen. Ich zeige, daß in solchen Systemen der Effekt der stochastischen Resonanz deutlich erh{\"o}ht werden kann, wenn eine zus{\"a}tzliche hochfrequente Kraft in Resonanz mit den kleinen Oszillationen unterhalb der Anregungsschwelle hinzugenommen wird. Es ist beachtenswert, daß diese Verst{\"a}rkung der stochastischen Resonanz eine geringere Rauschintensit{\"a}t zum Erreichen des Optimums ben{\"o}tigt als die standartm{\"a}ßige stochastische Resonanz in anregbaren Systemen. Ich untersuche Frequenzselektivit{\"a}t bei der rauschinduzierten Signalverarbeitung von Signalen unterhalb der Anregungsschwelle in Systemen mit vielen rauschunterst{\"u}tzten stochastischen Attraktoren. Diese neuen Attraktoren mit abweichenden gemittelten Perioden weisen auch unterschiedliche Phasenbeziehungen zwischen den einzelnen Elementen auf. Ich zeige, daß die Signalantwort des gekoppelten Systems unter verschiedenen Rauscheinwirkungen deutlich verbessert oder auch reduziert werden kann durch das Treiben einzelner Elemente in Resonanz mit diesen neuen Resonanzfrequenzen, die mit passenden Phasenbeziehungen korrespondieren. Weiterhin konnte ich einen rauschinduzierten Phasen{\"u}bergang von einem selbstoszillierenden System zu einem anregbaren System nachweisen. Dieser {\"U}bergang erfolgt durch eine rauschinduzierte Stabilisierung eines deterministisch instabilen Fixpunktes der lokalen Dynamik, w{\"a}hrend die gesamte Phasenraumstruktur des Systems erhalten bleibt. Die gemeinsame Wirkung von Kopplung und Rauschen f{\"u}hrt zu einem neuen Typ von Phasen{\"u}berg{\"a}ngen und bewirkt eine Stabilisierung des Systems. Das sich daraus ergebende rauschinduziert anregbare Regime zeigt charakteristische Eigenschaften von klassisch anregbaren Systemen, wie stochastische Resonanz und Wellenausbreitung. Dieser rauschinduzierte Phasen{\"u}bergang erm{\"o}glicht dadurch die {\"U}bertragung von Signalen durch ansonsten global oszillierende Systeme und die Kontrolle der Signal{\"u}bertragung durch Ver{\"a}nderung der Rauschintensit{\"a}t. Insbesondere er{\"o}ffnen diese theoretischen Ergebnisse einen m{\"o}glichen Mechanismus zur Unterdr{\"u}ckung unerw{\"u}nschter globaler Oszillationen in neuronalen Netzwerken, welche charakteristisch f{\"u}r abnorme medizinische Zust{\"a}nde, wie z.B. bei der Parkinson\′schen Krankheit oder Epilepsie, sind. Die Wirkung von Rauschen w{\"u}rde dann wieder die Anregbarkeit herstellen, die den normalen Zustand der erkrankten Neuronen darstellt.}, language = {en} } @phdthesis{Toenjes2007, author = {T{\"o}njes, Ralf}, title = {Pattern formation through synchronization in systems of nonidentical autonomous oscillators}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-15973}, school = {Universit{\"a}t Potsdam}, year = {2007}, abstract = {This work is concerned with the spatio-temporal structures that emerge when non-identical, diffusively coupled oscillators synchronize. It contains analytical results and their confirmation through extensive computer simulations. We use the Kuramoto model which reduces general oscillatory systems to phase dynamics. The symmetry of the coupling plays an important role for the formation of patterns. We have studied the ordering influence of an asymmetry (non-isochronicity) in the phase coupling function on the phase profile in synchronization and the intricate interplay between this asymmetry and the frequency heterogeneity in the system. The thesis is divided into three main parts. Chapter 2 and 3 introduce the basic model of Kuramoto and conditions for stable synchronization. In Chapter 4 we characterize the phase profiles in synchronization for various special cases and in an exponential approximation of the phase coupling function, which allows for an analytical treatment. Finally, in the third part (Chapter 5) we study the influence of non-isochronicity on the synchronization frequency in continuous, reaction diffusion systems and discrete networks of oscillators.}, language = {en} } @phdthesis{Tukhlina2008, author = {Tukhlina, Natalia}, title = {Feedback control of complex oscillatory systems}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-18546}, school = {Universit{\"a}t Potsdam}, year = {2008}, abstract = {In the present dissertation paper an approach which ensures an efficient control of such diverse systems as noisy or chaotic oscillators and neural ensembles is developed. This approach is implemented by a simple linear feedback loop. The dissertation paper consists of two main parts. One part of the work is dedicated to the application of the suggested technique to a population of neurons with a goal to suppress their synchronous collective dynamics. The other part is aimed at investigating linear feedback control of coherence of a noisy or chaotic self-sustained oscillator. First we start with a problem of suppressing synchronization in a large population of interacting neurons. The importance of this task is based on the hypothesis that emergence of pathological brain activity in the case of Parkinson's disease and other neurological disorders is caused by synchrony of many thousands of neurons. The established therapy for the patients with such disorders is a permanent high-frequency electrical stimulation via the depth microelectrodes, called Deep Brain Stimulation (DBS). In spite of efficiency of such stimulation, it has several side effects and mechanisms underlying DBS remain unclear. In the present work an efficient and simple control technique is suggested. It is designed to ensure suppression of synchrony in a neural ensemble by a minimized stimulation that vanishes as soon as the tremor is suppressed. This vanishing-stimulation technique would be a useful tool of experimental neuroscience; on the other hand, control of collective dynamics in a large population of units represents an interesting physical problem. The main idea of suggested approach is related to the classical problem of oscillation theory, namely the interaction between a self-sustained (active) oscillator and a passive load (resonator). It is known that under certain conditions the passive oscillator can suppress the oscillations of an active one. In this thesis a much more complicated case of active medium, which itself consists of thousands of oscillators is considered. Coupling this medium to a specially designed passive oscillator, one can control the collective motion of the ensemble, specifically can enhance or suppress it. Having in mind a possible application in neuroscience, the problem of suppression is concentrated upon. Second, the efficiency of suggested suppression scheme is illustrated by considering more complex case, i.e. when the population of neurons generating the undesired rhythm consists of two non-overlapping subpopulations: the first one is affected by the stimulation, while the collective activity is registered from the second one. Generally speaking, the second population can be by itself both active and passive; both cases are considered here. The possible applications of suggested technique are discussed. Third, the influence of the external linear feedback on coherence of a noisy or chaotic self-sustained oscillator is considered. Coherence is one of the main properties of self-oscillating systems and plays a key role in the construction of clocks, electronic generators, lasers, etc. The coherence of a noisy limit cycle oscillator in the context of phase dynamics is evaluated by the phase diffusion constant, which is in its turn proportional to the width of the spectral peak of oscillations. Many chaotic oscillators can be described within the framework of phase dynamics, and, therefore, their coherence can be also quantified by the way of the phase diffusion constant. The analytical theory for a general linear feedback, considering noisy systems in the linear and Gaussian approximation is developed and validated by numerical results.}, language = {en} } @phdthesis{Trabant2014, author = {Trabant, Christoph}, title = {Ultrafast photoinduced phase transitions in complex materials probed by time-resolved resonant soft x-ray diffraction}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-71377}, school = {Universit{\"a}t Potsdam}, year = {2014}, abstract = {In processing and data storage mainly ferromagnetic (FM) materials are being used. Approaching physical limits, new concepts have to be found for faster, smaller switches, for higher data densities and more energy efficiency. Some of the discussed new concepts involve the material classes of correlated oxides and materials with antiferromagnetic coupling. Their applicability depends critically on their switching behavior, i.e., how fast and how energy efficient material properties can be manipulated. This thesis presents investigations of ultrafast non-equilibrium phase transitions on such new materials. In transition metal oxides (TMOs) the coupling of different degrees of freedom and resulting low energy excitation spectrum often result in spectacular changes of macroscopic properties (colossal magneto resistance, superconductivity, metal-to-insulator transitions) often accompanied by nanoscale order of spins, charges, orbital occupation and by lattice distortions, which make these material attractive. Magnetite served as a prototype for functional TMOs showing a metal-to-insulator-transition (MIT) at T = 123 K. By probing the charge and orbital order as well as the structure after an optical excitation we found that the electronic order and the structural distortion, characteristics of the insulating phase in thermal equilibrium, are destroyed within the experimental resolution of 300 fs. The MIT itself occurs on a 1.5 ps timescale. It shows that MITs in functional materials are several thousand times faster than switching processes in semiconductors. Recently ferrimagnetic and antiferromagnetic (AFM) materials have become interesting. It was shown in ferrimagnetic GdFeCo, that the transfer of angular momentum between two opposed FM subsystems with different time constants leads to a switching of the magnetization after laser pulse excitation. In addition it was theoretically predicted that demagnetization dynamics in AFM should occur faster than in FM materials as no net angular momentum has to be transferred out of the spin system. We investigated two different AFM materials in order to learn more about their ultrafast dynamics. In Ho, a metallic AFM below T ≈ 130 K, we found that the AFM Ho can not only be faster but also ten times more energy efficiently destroyed as order in FM comparable metals. In EuTe, an AFM semiconductor below T ≈ 10 K, we compared the loss of magnetization and laser-induced structural distortion in one and the same experiment. Our experiment shows that they are effectively disentangled. An exception is an ultrafast release of lattice dynamics, which we assign to the release of magnetostriction. The results presented here were obtained with time-resolved resonant soft x-ray diffraction at the Femtoslicing source of the Helmholtz-Zentrum Berlin and at the free-electron laser in Stanford (LCLS). In addition the development and setup of a new UHV-diffractometer for these experiments will be reported.}, language = {en} } @phdthesis{Topaj2001, author = {Topaj, Dmitri}, title = {Synchronization transitions in complex systems}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-0000367}, school = {Universit{\"a}t Potsdam}, year = {2001}, abstract = {Gegenstand dieser Arbeit ist die Untersuchung generischer Synchronisierungsph{\"a}nomene in interagierenden komplexen Systemen. Diese Ph{\"a}nomene werden u.a. in gekoppelten deterministischen chaotischen Systemen beobachtet. Bei sehr schwachen Interaktionen zwischen individuellen Systemen kann ein {\"U}bergang zum schwach koh{\"a}renten Verhalten der Systeme stattfinden. In gekoppelten zeitkontinuierlichen chaotischen Systemen manifestiert sich dieser {\"U}bergang durch den Effekt der Phasensynchronisierung, in gekoppelten chaotischen zeitdiskreten Systemen durch den Effekt eines nichtverschwindenden makroskopischen Feldes. Der {\"U}bergang zur Koh{\"a}renz in einer Kette lokal gekoppelter Oszillatoren, beschrieben durch Phasengleichungen, wird im Bezug auf die Symmetrien des Systems untersucht. Es wird gezeigt, daß die durch die Symmetrien verursachte Reversibilit{\"a}t des Systems nichttriviale topologische Eigenschaften der Trajektorien bedingt, so daß das als dissipativ konstruierte System in einem ganzen Parameterbereich quasi-Hamiltonische Z{\"u}ge aufweist, d.h. das Phasenvolumen ist im Schnitt erhalten, und die Lyapunov-Exponenten sind paarweise symmetrisch. Der {\"U}bergang zur Koh{\"a}renz in einem Ensemble global gekoppelter chaotischer Abbildungen wird durch den Verlust der Stabilit{\"a}t des entkoppelten Zustandes beschrieben. Die entwickelte Methode besteht darin, die Selbstkonsistenz des makroskopischen Feldes aufzuheben, und das Ensemble in Analogie mit einem Verst{\"a}rkerschaltkreis mit R{\"u}ckkopplung durch eine komplexe lineare {\"U}bertragungssfunktion zu charakterisieren. Diese Theorie wird anschließend f{\"u}r einige theoretisch interessanten F{\"a}lle verallgemeinert.}, language = {en} } @phdthesis{Todt2009, author = {Todt, Helge Tobias}, title = {Hydrogen-deficient central stars of planetary nebulae}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-41047}, school = {Universit{\"a}t Potsdam}, year = {2009}, abstract = {Central stars of planetary nebulae are low-mass stars on the brink of their final evolution towards white dwarfs. Because of their surface temperature of above 25,000 K their UV radiation ionizes the surrounding material, which was ejected in an earlier phase of their evolution. Such fluorescent circumstellar gas is called a "Planetary Nebula". About one-tenth of the Galactic central stars are hydrogen-deficient. Generally, the surface of these central stars is a mixture of helium, carbon, and oxygen resulting from partial helium burning. Moreover, most of them have a strong stellar wind, similar to massive Pop-I Wolf-Rayet stars, and are in analogy classified as [WC]. The brackets distinguish the special type from the massive WC stars. Qualitative spectral analyses of [WC] stars lead to the assumption of an evolutionary sequence from the cooler, so-called late-type [WCL] stars to the very hot, early-type [WCE] stars. Quantitative analyses of the winds of [WC] stars became possible by means of computer programs that solve the radiative transfer in the co-moving frame, together with the statistical equilibrium equations for the population numbers. First analyses employing models without iron-line blanketing resulted in systematically different abundances for [WCL] and [WCE] stars. While the mass ratio of He:C is roughly 40:50 for [WCL] stars, it is 60:30 in average for [WCE] stars. The postulated evolution from [WCL] to [WCE] however could only lead to an increase of carbon, since heavier elements are built up by nuclear fusion. In the present work, improved models are used to re-analyze the [WCE] stars and to confirm their He:C abundance ratio. Refined models, calculated with the Potsdam WR model atmosphere code (PoWR), account now for line-blanketing due to iron group elements, small scale wind inhomogeneities, and complex model atoms for He, C, O, H, P, N, and Ne. Referring to stellar evolutionary models for the hydrogen-deficient [WC] stars, Ne and N abundances are of particular interest. Only one out of three different evolutionary channels, the VLTP scenario, leads to a Ne and N overabundance of a few percent by mass. A VLTP, a very late thermal pulse, is a rapid increase of the energy production of the helium-burning shell, while hydrogen burning has already ceased. Subsequently, the hydrogen envelope is mixed with deeper layers and completely burnt in the presence of C, He, and O. This results in the formation of N and Ne. A sample of eleven [WCE] stars has been analyzed. For three of them, PB 6, NGC 5189, and [S71d]3, a N overabundance of 1.5\% has been found, while for three other [WCE] stars such high abundances of N can be excluded. In the case of NGC 5189, strong spectral lines of Ne can be reproduced qualitatively by our models. At present, the Ne mass fraction can only be roughly estimated from the Ne emission lines and seems to be in the order of a few percent by mass. Furthermore, using a diagnostic He-C line pair, the He:C abundance ratio of 60:30 for [WCE] stars is confirmed. Within the framework of the analysis, a new class of hydrogen-deficient central stars has been discovered, with PB 8 as its first member. Its atmospheric mixture resembles rather that of the massive WNL stars than of the [WC] stars. The determined mass fractions H:He:C:N:O are 40:55:1.3:2:1.3. As the wind of PB 8 contains significant amounts of O and C, in contrast to WN stars, a classification as [WN/WC] is suggested.}, language = {en} } @phdthesis{Timpanaro2004, author = {Timpanaro, Salvatore}, title = {Conductive properties and morphology of conjugated molecular materials studied by local probe techniques}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-0001929}, school = {Universit{\"a}t Potsdam}, year = {2004}, abstract = {Die vorgelegte Arbeit befasst sich mit der Untersuchung von Zusammenh{\"a}ngen zwischen der Struktur d{\"u}nner organischer Schichten und stellt einen Bezug zur Leitf{\"a}higkeit der Schichten her. Sie liefert einen Beitrag zum vertieften Verst{\"a}ndnis der Transporteigenschaf-ten organischer Halbleiter und soll so zur Verbesserung organischer elektronischer Bauele-mente beitragen. Es ist bekannt, dass die Effizienz von Organischen Leuchtdioden (OLEDs) stark von der Qualit{\"a}t der eingesetzten d{\"u}nnen Filme abh{\"a}ngt. Es ist deshalb interessant, die Strukturen technologisch interessanter organischer Filme mittels Scanning Probe Mikrosko-pie (SPM) zu charakterisieren, um ein besseres Verst{\"a}ndnis sowohl der Oberfl{\"a}chen-Morphologie als auch der molekularen/atomaren Packungen zu erhalten. Die Untersuchung von Quaterthiophen (4T), welches vielfach in Feldeffekt-Transistoren eingesetzt wird, bildet einen ersten Schwerpunkt der Arbeit. Es konnte eine neue Kristall-struktur von 4T gefunden werden, die bisher nicht bekannt war. Daf{\"u}r wurden Quaterthi-ophen-Filme untersucht, welche auf Kaliumphthalat (KAP) aufwuchsen. Die Aufkl{\"a}rung der neuen Struktur gelang durch Kombinierten Einsatz von optischen und R{\"o}ntgen-Beugungsmessungen. Zur Best{\"a}tigung der triklinen Kristall-Einheitszelle mit den Parame-tern a = 0,721 nm, b = 0,632 nm, c = 0,956 nm und α = 91o, β = 91,4o, γ = 91o wurde außer-dem die Atomkraft-Mikroskopie (AFM) angewendet. In Fortf{\"u}hrung der rastermikroskopischen Messungen sind die Morphologien von Filmen vier weiterer organischer Materialien technologischer Relevanz untersucht worden: He-xanthiol-Monoschichten auf Gold, Azobenzenthiol-Monoschichten auf Gold, Para-Phenylenvinylen-Oligomer-Filme auf Gold und Phenyl-Oxadiazol-Filme auf Gold. Daf{\"u}r kam zus{\"a}tzlich die Ultrahochvakuum-Scanning-Tunneling-Mikroskopie (UHV-STM) zum Einsatz. Es zeigte sich eine Vielzahl morphologischer Eigenheiten, deren Besonderheiten sowohl von den gew{\"a}hlten Substraten als auch von der chemischen Struktur der untersuchten organischen Materialien abh{\"a}ngen. So zeigen Para-Phenylenvinylen-Oligomer-Filme eine St{\"a}bchen- und Oxadiazol-Filme eine K{\"o}rnchen-Struktur auf Gold. Auf Basis dieser Kenntnisse gelang es, das optisch induzierte Schalten von Azobenzen durch STM-Untersuchungen und durch Scanning Tunneling Spektroskopie (STS) auf molekularer Skale nachzuweisen. Die Topographie einer Reihe von Poly(3,4-ethylendioxythiophen)-(PEDOT)-Filmen und de-ren Bezug zu den Ladungstransporteigenschaften dieser Filme war ein weiterer Arbeits-schwerpunkt. PEDOT-Filme auf Indium-Zinn-Oxid (ITO) kommen in organischen elektro-nischen Bauelementen als Lochinjektionsschichten zum Einsatz. F{\"u}r die Schichtherstellung kamen Dispersionen des Polymers unterschiedlicher Konzentration zur Anwendung: Mittels AFM und STM konnte gezeigt werden, dass unterschiedliche Konzentrationen zu unter-schiedlichen Topographien f{\"u}hren. Besonders die Oberfl{\"a}che der Filme mit hoher Konzent-ration von PEDOT, d.h. die der leitf{\"a}higsten Filme, wird durch eine k{\"o}rnchenartige Struktur eingebetteter Teilchen charakterisiert. Durch STM Strom-Abstands-(I-d)-Untersuchungen wurde gefunden, dass diese Teilchen die „Spitze eines Eisbergs" leitf{\"a}higer Dom{\"a}nen dar-stellen. Ausgehend von dieser Erkenntnis wird ein Strukturmodell f{\"u}r die Filme vorgeschla-gen, in dem die leitf{\"a}higen Dom{\"a}nen / Partikel in eine weniger leitf{\"a}hige Matrix eingebettet sind. Durch Zugabe von Polyolen wie Sorbitol zur PEDOT-Dispersion ließen sich Filme mit h{\"o}herer Leitf{\"a}higkeit herstellen. Eine klare Abh{\"a}ngigkeit zwischen der Leitf{\"a}higkeit und der bisher nicht beschrieben nano-Morphologie wurde gefunden.}, language = {en} } @phdthesis{Thomas2022, author = {Thomas, Timon}, title = {Cosmic-ray hydrodynamics: theory, numerics, applications}, doi = {10.25932/publishup-56384}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-563843}, school = {Universit{\"a}t Potsdam}, pages = {334}, year = {2022}, abstract = {Cosmic rays (CRs) are a ubiquitous and an important component of astrophysical environments such as the interstellar medium (ISM) and intracluster medium (ICM). Their plasma physical interactions with electromagnetic fields strongly influence their transport properties. Effective models which incorporate the microphysics of CR transport are needed to study the effects of CRs on their surrounding macrophysical media. Developing such models is challenging because of the conceptional, length-scale, and time-scale separation between the microscales of plasma physics and the macroscales of the environment. Hydrodynamical theories of CR transport achieve this by capturing the evolution of CR population in terms of statistical moments. In the well-established one-moment hydrodynamical model for CR transport, the dynamics of the entire CR population are described by a single statistical quantity such as the commonly used CR energy density. In this work, I develop a new hydrodynamical two-moment theory for CR transport that expands the well-established hydrodynamical model by including the CR energy flux as a second independent hydrodynamical quantity. I detail how this model accounts for the interaction between CRs and gyroresonant Alfv{\´e}n waves. The small-scale magnetic fields associated with these Alfv{\´e}n waves scatter CRs which fundamentally alters CR transport along large-scale magnetic field lines. This leads to the effects of CR streaming and diffusion which are both captured within the presented hydrodynamical theory. I use an Eddington-like approximation to close the hydrodynamical equations and investigate the accuracy of this closure-relation by comparing it to high-order approximations of CR transport. In addition, I develop a finite-volume scheme for the new hydrodynamical model and adapt it to the moving-mesh code Arepo. This scheme is applied using a simulation of a CR-driven galactic wind. I investigate how CRs launch the wind and perform a statistical analysis of CR transport properties inside the simulated circumgalactic medium (CGM). I show that the new hydrodynamical model can be used to explain the morphological appearance of a particular type of radio filamentary structures found inside the central molecular zone (CMZ). I argue that these harp-like features are synchrotron-radiating CRs which are injected into braided magnetic field lines by a point-like source such as a stellar wind of a massive star or a pulsar. Lastly, I present the finite-volume code Blinc that uses adaptive mesh refinement (AMR) techniques to perform simulations of radiation and magnetohydrodynamics (MHD). The mesh of Blinc is block-structured and represented in computer memory using a graph-based approach. I describe the implementation of the mesh graph and how a diffusion process is employed to achieve load balancing in parallel computing environments. Various test problems are used to verify the accuracy and robustness of the employed numerical algorithms.}, language = {en} } @phdthesis{ThielemannKuehn2017, author = {Thielemann-K{\"u}hn, Nele}, title = {Optically induced ferro- and antiferromagnetic dynamics in the rare-earth metal dysprosium}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-402994}, school = {Universit{\"a}t Potsdam}, pages = {iv, 121}, year = {2017}, abstract = {Approaching physical limits in speed and size of today's magnetic storage and processing technologies demands new concepts for controlling magnetization and moves researches on optically induced magnetic dynamics. Studies on photoinduced magnetization dynamics and their underlying mechanisms have been primarily performed on ferromagnetic metals. Ferromagnetic dynamics bases on transfer of the conserved angular momentum connected with atomic magnetic moments out of the parallel aligned magnetic system into other degrees of freedom. In this thesis the so far rarely studied response of antiferromagnetic order to ultra-short optical laser pulses in a metal is investigated. The experiments were performed at the FemtoSpex slicing facility at the storage ring BESSY II, an unique source for ultra-short elliptically polarized x-ray pulses. Laser-induced changes of the 4f-magnetic order parameter in ferro- and antiferromagnetic dysprosium (Dy), were studied by x-ray methods, which yield directly comparable quantities. The discovered fundamental differences in the temporal and spatial behavior of ferro- and antiferrmagnetic dynamics are assinged to an additional channel for angular momentum transfer, which reduces the antiferromagnetic order by redistributing angular momentum within the non-parallel aligned magnetic system, and hence conserves the zero net magnetization. It is shown that antiferromagnetic dynamics proceeds considerably faster and more energy-efficient than demagnetization in ferromagnets. By probing antiferromagnetic order in time and space, it is found to be affected along the whole sample depth of an in situ grown 73 nm tick Dy film. Interatomic transfer of angular momentum via fast diffusion of laser-excited 5d electrons is held responsible for the out-most long-ranging effect. Ultrafast ferromagnetic dynamics can be expected to base on the same origin, which however leads to demagnetization only in regions close to interfaces caused by super-diffusive spin transport. Dynamics due to local scattering processes of excited but less mobile electrons, occur in both magnetic alignments only in directly excited regions of the sample and on slower pisosecond timescales. The thesis provides fundamental insights into photoinduced magnetic dynamics by directly comparing ferro- and antiferromagnetic dynamics in the same material and by consideration of the laser-induced magnetic depth profile.}, language = {en} } @phdthesis{Thiel2004, author = {Thiel, Marco}, title = {Recurrences : exploiting naturally occurring analogues}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-0001633}, school = {Universit{\"a}t Potsdam}, year = {2004}, abstract = {In der vorliegenden Arbeit wird die Wiederkehr im Phasenraum ausgenutzt. Dabei werden drei Hauptresultate besprochen. 1. Die Wiederkehr erlaubt die Vorhersagbarkeit des Systems zu quantifizieren. 2. Die Wiederkehr enthaelt (unter bestimmten Voraussetzungen) s{\"a}mtliche relevante Information {\"u}ber die Dynamik im Phasenraum 3. Die Wiederkehr erlaubt die Erzeugung dynamischer Ersatzdaten.}, language = {en} } @phdthesis{Thiede2019, author = {Thiede, Tobias}, title = {A multiscale analysis of additively manufactured lattice structures}, doi = {10.25932/publishup-47041}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-470418}, school = {Universit{\"a}t Potsdam}, pages = {xi, 97, LIII}, year = {2019}, abstract = {Additive Manufacturing (AM) in terms of laser powder-bed fusion (L-PBF) offers new prospects regarding the design of parts and enables therefore the production of lattice structures. These lattice structures shall be implemented in various industrial applications (e.g. gas turbines) for reasons of material savings or cooling channels. However, internal defects, residual stress, and structural deviations from the nominal geometry are unavoidable. In this work, the structural integrity of lattice structures manufactured by means of L-PBF was non-destructively investigated on a multiscale approach. A workflow for quantitative 3D powder analysis in terms of particle size, particle shape, particle porosity, inter-particle distance and packing density was established. Synchrotron computed tomography (CT) was used to correlate the packing density with the particle size and particle shape. It was also observed that at least about 50\% of the powder porosity was released during production of the struts. Struts are the component of lattice structures and were investigated by means of laboratory CT. The focus was on the influence of the build angle on part porosity and surface quality. The surface topography analysis was advanced by the quantitative characterisation of re-entrant surface features. This characterisation was compared with conventional surface parameters showing their complementary information, but also the need for AM specific surface parameters. The mechanical behaviour of the lattice structure was investigated with in-situ CT under compression and successive digital volume correlation (DVC). The deformation was found to be knot-dominated, and therefore the lattice folds unit cell layer wise. The residual stress was determined experimentally for the first time in such lattice structures. Neutron diffraction was used for the non-destructive 3D stress investigation. The principal stress directions and values were determined in dependence of the number of measured directions. While a significant uni-axial stress state was found in the strut, a more hydrostatic stress state was found in the knot. In both cases, strut and knot, seven directions were at least needed to find reliable principal stress directions.}, language = {en} } @phdthesis{Theves2013, author = {Theves, Matthias}, title = {Bacterial motility and growth in open and confined environments}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-70313}, school = {Universit{\"a}t Potsdam}, year = {2013}, abstract = {In the presence of a solid-liquid or liquid-air interface, bacteria can choose between a planktonic and a sessile lifestyle. Depending on environmental conditions, cells swimming in close proximity to the interface can irreversibly attach to the surface and grow into three-dimensional aggregates where the majority of cells is sessile and embedded in an extracellular polymer matrix (biofilm). We used microfluidic tools and time lapse microscopy to perform experiments with the polarly flagellated soil bacterium Pseudomonas putida (P. putida), a bacterial species that is able to form biofilms. We analyzed individual trajectories of swimming cells, both in the bulk fluid and in close proximity to a glass-liquid interface. Additionally, surface related growth during the early phase of biofilm formation was investigated. In the bulk fluid, P.putida shows a typical bacterial swimming pattern of alternating periods of persistent displacement along a line (runs) and fast reorientation events (turns) and cells swim with an average speed around 24 micrometer per second. We found that the distribution of turning angles is bimodal with a dominating peak around 180 degrees. In approximately six out of ten turning events, the cell reverses its swimming direction. In addition, our analysis revealed that upon a reversal, the cell systematically changes its swimming speed by a factor of two on average. Based on the experimentally observed values of mean runtime and rotational diffusion, we presented a model to describe the spreading of a population of cells by a run-reverse random walker with alternating speeds. We successfully recover the mean square displacement and, by an extended version of the model, also the negative dip in the directional autocorrelation function as observed in the experiments. The analytical solution of the model demonstrates that alternating speeds enhance a cells ability to explore its environment as compared to a bacterium moving at a constant intermediate speed. As compared to the bulk fluid, for cells swimming near a solid boundary we observed an increase in swimming speed at distances below d= 5 micrometer and an increase in average angular velocity at distances below d= 4 micrometer. While the average speed was maximal with an increase around 15\% at a distance of d= 3 micrometer, the angular velocity was highest in closest proximity to the boundary at d=1 micrometer with an increase around 90\% as compared to the bulk fluid. To investigate the swimming behavior in a confinement between two solid boundaries, we developed an experimental setup to acquire three-dimensional trajectories using a piezo driven objective mount coupled to a high speed camera. Results on speed and angular velocity were consistent with motility statistics in the presence of a single boundary. Additionally, an analysis of the probability density revealed that a majority of cells accumulated near the upper and lower boundaries of the microchannel. The increase in angular velocity is consistent with previous studies, where bacteria near a solid boundary were shown to swim on circular trajectories, an effect which can be attributed to a wall induced torque. The increase in speed at a distance of several times the size of the cell body, however, cannot be explained by existing theories which either consider the drag increase on cell body and flagellum near a boundary (resistive force theory) or model the swimming microorganism by a multipole expansion to account for the flow field interaction between cell and boundary. An accumulation of swimming bacteria near solid boundaries has been observed in similar experiments. Our results confirm that collisions with the surface play an important role and hydrodynamic interactions alone cannot explain the steady-state accumulation of cells near the channel walls. Furthermore, we monitored the number growth of cells in the microchannel under medium rich conditions. We observed that, after a lag time, initially isolated cells at the surface started to grow by division into colonies of increasing size, while coexisting with a comparable smaller number of swimming cells. After 5:50 hours, we observed a sudden jump in the number of swimming cells, which was accompanied by a breakup of bigger clusters on the surface. After approximately 30 minutes where planktonic cells dominated in the microchannel, individual swimming cells reattached to the surface. We interpret this process as an emigration and recolonization event. A number of complementary experiments were performed to investigate the influence of collective effects or a depletion of the growth medium on the transition. Similar to earlier observations on another bacterium from the same family we found that the release of cells to the swimming phase is most likely the result of an individual adaption process, where syntheses of proteins for flagellar motility are upregulated after a number of division cycles at the surface.}, language = {en} } @phdthesis{Thater2019, author = {Thater, Sabine}, title = {The interplay between supermassive black holes and their host galaxies}, doi = {10.25932/publishup-43757}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-437570}, school = {Universit{\"a}t Potsdam}, pages = {iv, 186}, year = {2019}, abstract = {Supermassive black holes reside in the hearts of almost all massive galaxies. Their evolutionary path seems to be strongly linked to the evolution of their host galaxies, as implied by several empirical relations between the black hole mass (M BH ) and different host galaxy properties. The physical driver of this co-evolution is, however, still not understood. More mass measurements over homogeneous samples and a detailed understanding of systematic uncertainties are required to fathom the origin of the scaling relations. In this thesis, I present the mass estimations of supermassive black holes in the nuclei of one late-type and thirteen early-type galaxies. Our SMASHING sample extends from the intermediate to the massive galaxy mass regime and was selected to fill in gaps in number of galaxies along the scaling relations. All galaxies were observed at high spatial resolution, making use of the adaptive-optics mode of integral field unit (IFU) instruments on state-of-the-art telescopes (SINFONI, NIFS, MUSE). I extracted the stellar kinematics from these observations and constructed dynamical Jeans and Schwarzschild models to estimate the mass of the central black holes robustly. My new mass estimates increase the number of early-type galaxies with measured black hole masses by 15\%. The seven measured galaxies with nuclear light deficits ('cores') augment the sample of cored galaxies with measured black holes by 40\%. Next to determining massive black hole masses, evaluating the accuracy of black hole masses is crucial for understanding the intrinsic scatter of the black hole- host galaxy scaling relations. I tested various sources of systematic uncertainty on my derived mass estimates. The M BH estimate of the single late-type galaxy of the sample yielded an upper limit, which I could constrain very robustly. I tested the effects of dust, mass-to-light ratio (M/L) variation, and dark matter on my measured M BH . Based on these tests, the typically assumed constant M/L ratio can be an adequate assumption to account for the small amounts of dark matter in the center of that galaxy. I also tested the effect of a variable M/L variation on the M BH measurement on a second galaxy. By considering stellar M/L variations in the dynamical modeling, the measured M BH decreased by 30\%. In the future, this test should be performed on additional galaxies to learn how an as constant assumed M/L flaws the estimated black hole masses. Based on our upper limit mass measurement, I confirm previous suggestions that resolving the predicted BH sphere-of-influence is not a strict condition to measure black hole masses. Instead, it is only a rough guide for the detection of the black hole if high-quality, and high signal-to-noise IFU data are used for the measurement. About half of our sample consists of massive early-type galaxies which show nuclear surface brightness cores and signs of triaxiality. While these types of galaxies are typically modeled with axisymmetric modeling methods, the effects on M BH are not well studied yet. The massive galaxies of our presented galaxy sample are well suited to test the effect of different stellar dynamical models on the measured black hole mass in evidently triaxial galaxies. I have compared spherical Jeans and axisymmetric Schwarzschild models and will add triaxial Schwarzschild models to this comparison in the future. The constructed Jeans and Schwarzschild models mostly disagree with each other and cannot reproduce many of the triaxial features of the galaxies (e.g., nuclear sub-components, prolate rotation). The consequence of the axisymmetric-triaxial assumption on the accuracy of M BH and its impact on the black hole - host galaxy relation needs to be carefully examined in the future. In the sample of galaxies with published M BH , we find measurements based on different dynamical tracers, requiring different observations, assumptions, and methods. Crucially, different tracers do not always give consistent results. I have used two independent tracers (cold molecular gas and stars) to estimate M BH in a regular galaxy of our sample. While the two estimates are consistent within their errors, the stellar-based measurement is twice as high as the gas-based. Similar trends have also been found in the literature. Therefore, a rigorous test of the systematics associated with the different modeling methods is required in the future. I caution to take the effects of different tracers (and methods) into account when discussing the scaling relations. I conclude this thesis by comparing my galaxy sample with the compilation of galaxies with measured black holes from the literature, also adding six SMASHING galaxies, which were published outside of this thesis. None of the SMASHING galaxies deviates significantly from the literature measurements. Their inclusion to the published early-type galaxies causes a change towards a shallower slope for the M BH - effective velocity dispersion relation, which is mainly driven by the massive galaxies of our sample. More unbiased and homogenous measurements are needed in the future to determine the shape of the relation and understand its physical origin.}, language = {en} } @phdthesis{Teppner2000, author = {Teppner, Randolf}, title = {Adsorptionsschichten an fluiden Grenzfl{\"a}chen : Skalengesetze und Ionenverteilungen}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-0000117}, school = {Universit{\"a}t Potsdam}, year = {2000}, abstract = {In dieser Arbeit wurden zwei Themenbereiche bearbeitet: 1. Ellipsometrie an Adsorpionsschichten niedermolekularer Tenside an der Wasser/Luft-Grenzfl{\"a}che (Ellipsometrie ist geeignet, adsorbierte Mengen von nicht- und zwitterionischen Tensiden zu messen, bei ionischen werden zus{\"a}tzlich die Gegenionen mit erfaßt; Ellipsometrie mißt sich {\"a}ndernde Gegenionenverteilung). 2. Ellipsometrische Untersuchung von endadsorbierten Polymerb{\"u}rsten an der Wasser/{\"O}l-Grenzfl{\"a}che (Ellipsometrie ist nicht in der Lage, verschiedene Segmentkonzentrationsprofile innerhalb der B{\"u}rste aufzul{\"o}sen, ist aber sehr wohl geeignet, Skalengesetze f{\"u}r Dicken und Dr{\"u}cke in Abh{\"a}ngigkeit von Ankerdichte und Kettenl{\"a}nge der Polymere zu {\"u}berpr{\"u}fen; f{\"u}r in Heptan gequollene Poly-isobuten-B{\"u}rsten konnte gezeigt werden, daß sie sich entsprechend den theoretischen Vorhersagen f{\"u}r B{\"u}rsten in einem theta-L{\"o}sungsmittel verhalten)}, language = {de} } @phdthesis{Teichmann2021, author = {Teichmann, Erik}, title = {Partial synchronization in coupled systems with repulsive and attractive interaction}, doi = {10.25932/publishup-52894}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-528943}, school = {Universit{\"a}t Potsdam}, pages = {x, 96}, year = {2021}, abstract = {Partial synchronous states exist in systems of coupled oscillators between full synchrony and asynchrony. They are an important research topic because of their variety of different dynamical states. Frequently, they are studied using phase dynamics. This is a caveat, as phase dynamics are generally obtained in the weak coupling limit of a first-order approximation in the coupling strength. The generalization to higher orders in the coupling strength is an open problem. Of particular interest in the research of partial synchrony are systems containing both attractive and repulsive coupling between the units. Such a mix of coupling yields very specific dynamical states that may help understand the transition between full synchrony and asynchrony. This thesis investigates partial synchronous states in mixed-coupling systems. First, a method for higher-order phase reduction is introduced to observe interactions beyond the pairwise one in the first-order phase description, hoping that these may apply to mixed-coupling systems. This new method for coupled systems with known phase dynamics of the units gives correct results but, like most comparable methods, is computationally expensive. It is applied to three Stuart-Landau oscillators coupled in a line with a uniform coupling strength. A numerical method is derived to verify the analytical results. These results are interesting but give importance to simpler phase models that still exhibit exotic states. Such simple models that are rarely considered are Kuramoto oscillators with attractive and repulsive interactions. Depending on how the units are coupled and the frequency difference between the units, it is possible to achieve many different states. Rich synchronization dynamics, such as a Bellerophon state, are observed when considering a Kuramoto model with attractive interaction in two subpopulations (groups) and repulsive interactions between groups. In two groups, one attractive and one repulsive, of identical oscillators with a frequency difference, an interesting solitary state appears directly between full and partial synchrony. This system can be described very well analytically.}, language = {en} } @phdthesis{Tegtmeier2006, author = {Tegtmeier, Susann}, title = {Variationen der stratosph{\"a}rischen Residualzirkulation und ihr Einfluss auf die Ozonverteilung}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-12118}, school = {Universit{\"a}t Potsdam}, year = {2006}, abstract = {Die Residualzirkulation entspricht der mittleren Massenzirkulation und beschreibt die im zonalen Mittel stattfindenden meridionalen Transportprozesse. Die Variationen der Residualzirkulation bestimmen gemeinsam mit dem anthropogen verursachten Ozonabbau die j{\"a}hrlichen Schwankungen der Ozongesamts{\"a}ule im arktischen Fr{\"u}hling. In der vorliegenden Arbeit wird die Geschwindigkeit des arktischen Astes der Residualzirkulation aus atmosph{\"a}rischen Daten gewonnen. Zu diesem Zweck wird das diabatische Absinken im Polarwirbel mit Hilfe von Trajektorienrechnungen bestimmt. Die vertikalen Bewegungen der Luftpakete k{\"o}nnen mit vertikalen Windfeldern oder entsprechend einem neuen Ansatz mit diabatischen Heizraten angetrieben werden. Die Eingabedaten stammen aus dem 45 Jahre langen Reanalyse-Datensatz des "European Centre for Medium Range Weather Forecast" (ECMWF). Außerdem kann f{\"u}r die Jahre ab 1984 die operationelle ECMWF-Analyse verwendet werden. Die Qualit{\"a}t und Robustheit der Heizraten- und Trajektorienrechnungen werden durch Sensitivit{\"a}tsstudien und Vergleiche mit anderen Modellen untermauert. Anschließend werden umfangreiche Trajektorienensemble statistisch ausgewertet, um ein detailliertes, zeit- und h{\"o}henaufgel{\"o}stes Bild des diabatischen Absinkens zu ermitteln. In diesem Zusammenhang werden zwei Methoden entwickelt, um das Absinken gemittelt im Polarwirbel oder als Funktion der {\"a}quivalenten Breite zu bestimmen. Es wird gezeigt, dass es notwendig ist den Lagrangeschen auf Trajektorienrechnungen basierenden Ansatz zu verfolgen, da die einfachen Eulerschen Mittel Abweichungen zu den Lagrangeschen Vertikalgeschwindigkeiten aufweisen. Das wirbelgemittelte Absinken wird f{\"u}r einzelne Winter mit dem beobachteten Absinken langlebiger Spurengase und anderen Modellstudien verglichen. Der Vergleich zeigt, dass das Absinken basierend auf den vertikalen Windfeldern der ECMWF-Datens{\"a}tze den Nettoluftmassentransport durch die Residualzirkulation sehr stark {\"u}bersch{\"a}tzt. Der neue Ansatz basierend auf den Heizraten ergibt hingegen realistische Ergebnisse und wird aus diesem Grund f{\"u}r alle Rechnungen verwendet. Es wird erstmalig eine Klimatologie des diabatischen Absinkens {\"u}ber einen fast f{\"u}nf Jahrzehnte umfassenden Zeitraum erstellt. Die Klimatologie beinhaltet das vertikal und zeitlich aufgel{\"o}ste diabatische Absinken gemittelt {\"u}ber den gesamten Polarwirbel und Informationen {\"u}ber die r{\"a}umliche Struktur des vertikalen Absinkens. Die nat{\"u}rliche Jahr-zu-Jahr Variabilit{\"a}t des diabatischen Absinkens ist sehr stark ausgepr{\"a}gt. Es wird gezeigt, dass zwischen der ECMWF-Zeitreihe des diabatischen Absinkens und der Zeitreihe aus einem unabh{\"a}ngig analysierten Temperaturdatensatz hohe Korrelationen bestehen. Erstmals wird der Einfluss von Transportprozessen auf die Ozongesamts{\"a}ule im arktischen Fr{\"u}hling direkt quantifiziert. Es wird gezeigt, dass die Jahr-zu-Jahr Variabilit{\"a}t der Ozongesamts{\"a}ule im arktischen Fr{\"u}hling zu gleichen Anteilen durch die Variabilit{\"a}t der dynamischen Komponente und durch die Variabilit{\"a}t der chemischen Komponente beeinflusst wird. Die gefundenen Variabilit{\"a}ten von diabatischem Absinken und Ozoneintrag in hohen Breiten werden mit der vertikalen Ausbreitung planetarer Wellen aus der Troposph{\"a}re in die Stratosph{\"a}re in Beziehung gesetzt.}, language = {de} } @phdthesis{TchoumbaKwamen2018, author = {Tchoumba Kwamen, Christelle Larodia}, title = {Investigating the dynamics of polarization reversal in ferroelectric thin films by time-resolved X-ray diffraction}, doi = {10.25932/publishup-42781}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-427815}, school = {Universit{\"a}t Potsdam}, pages = {xvii, 126, xxiii}, year = {2018}, abstract = {Ferroic materials have attracted a lot of attention over the years due to their wide range of applications in sensors, actuators, and memory devices. Their technological applications originate from their unique properties such as ferroelectricity and piezoelectricity. In order to optimize these materials, it is necessary to understand the coupling between their nanoscale structure and transient response, which are related to the atomic structure of the unit cell. In this thesis, synchrotron X-ray diffraction is used to investigate the structure of ferroelectric thin film capacitors during application of a periodic electric field. Combining electrical measurements with time-resolved X-ray diffraction on a working device allows for visualization of the interplay between charge flow and structural motion. This constitutes the core of this work. The first part of this thesis discusses the electrical and structural dynamics of a ferroelectric Pt/Pb(Zr0.2,Ti0.8)O3/SrRuO3 heterostructure during charging, discharging, and polarization reversal. After polarization reversal a non-linear piezoelectric response develops on a much longer time scale than the RC time constant of the device. The reversal process is inhomogeneous and induces a transient disordered domain state. The structural dynamics under sub-coercive field conditions show that this disordered domain state can be remanent and can be erased with an appropriate voltage pulse sequence. The frequency-dependent dynamic characterization of a Pb(Zr0.52,Ti0.48)O3 layer, at the morphotropic phase boundary, shows that at high frequency, the limited domain wall velocity causes a phase lag between the applied field and both the structural and electrical responses. An external modification of the RC time constant of the measurement delays the switching current and widens the electromechanical hysteresis loop while achieving a higher compressive piezoelectric strain within the crystal. In the second part of this thesis, time-resolved reciprocal space maps of multiferroic BiFeO3 thin films were measured to identify the domain structure and investigate the development of an inhomogeneous piezoelectric response during the polarization reversal. The presence of 109° domains is evidenced by the splitting of the Bragg peak. The last part of this work investigates the effect of an optically excited ultrafast strain or heat pulse propagating through a ferroelectric BaTiO3 layer, where we observed an additional current response due to the laser pulse excitation of the metallic bottom electrode of the heterostructure.}, language = {en} } @phdthesis{Takey2013, author = {Takey, Ali Said Ahmed}, title = {The XMM-Newton/SDSS galaxy cluster survey}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-71229}, school = {Universit{\"a}t Potsdam}, year = {2013}, abstract = {Galaxy clusters are the largest known gravitationally bound objects, their study is important for both an intrinsic understanding of their systems and an investigation of the large scale structure of the universe. The multi- component nature of galaxy clusters offers multiple observable signals across the electromagnetic spectrum. At X-ray wavelengths, galaxy clusters are simply identified as X-ray luminous, spatially extended, and extragalactic sources. X-ray observations offer the most powerful technique for constructing cluster catalogues. The main advantages of the X-ray cluster surveys are their excellent purity and completeness and the X-ray observables are tightly correlated with mass, which is indeed the most fundamental parameter of clusters. In my thesis I have conducted the 2XMMi/SDSS galaxy cluster survey, which is a serendipitous search for galaxy clusters based on the X-ray extended sources in the XMM-Newton Serendipitous Source Catalogue (2XMMi-DR3). The main aims of the survey are to identify new X-ray galaxy clusters, investigate their X-ray scaling relations, identify distant cluster candidates, and study the correlation of the X-ray and optical properties. The survey is constrained to those extended sources that are in the footprint of the Sloan Digital Sky Survey (SDSS) in order to be able to identify the optical counterparts as well as to measure their redshifts that are mandatory to measure their physical properties. The overlap area be- tween the XMM-Newton fields and the SDSS-DR7 imaging, the latest SDSS data release at the starting of the survey, is 210 deg^2. The survey comprises 1180 X-ray cluster candidates with at least 80 background-subtracted photon counts, which passed the quality control process. To measure the optical redshifts of the X-ray cluster candidates, I used three procedures; (i) cross-matching these candidates with the recent and largest optically selected cluster catalogues in the literature, which yielded the photometric redshifts of about a quarter of the X-ray cluster candidates. (ii) I developed a finding algorithm to search for overdensities of galaxies at the positions of the X-ray cluster candidates in the photometric redshift space and to measure their redshifts from the SDSS-DR8 data, which provided the photometric redshifts of 530 groups/clusters. (iii) I developed an algorithm to identify the cluster candidates associated with spectroscopically targeted Luminous Red Galaxies (LRGs) in the SDSS-DR9 and to measure the cluster spectroscopic redshift, which provided 324 groups and clusters with spectroscopic confirmation based on spectroscopic redshift of at least one LRG. In total, the optically confirmed cluster sample comprises 574 groups and clusters with redshifts (0.03 ≤ z ≤ 0.77), which is the largest X-ray selected cluster catalogue to date based on observations from the current X-ray observatories (XMM-Newton, Chandra, Suzaku, and Swift/XRT). Among the cluster sample, about 75 percent are newly X-ray discovered groups/clusters and 40 percent are new systems to the literature. To determine the X-ray properties of the optically confirmed cluster sample, I reduced and analysed their X-ray data in an automated way following the standard pipelines of processing the XMM-Newton data. In this analysis, I extracted the cluster spectra from EPIC(PN, MOS1, MOS2) images within an optimal aperture chosen to maximise the signal-to-noise ratio. The spectral fitting procedure provided the X-ray temperatures kT (0.5 - 7.5 keV) for 345 systems that have good quality X-ray data. For all the optically confirmed cluster sample, I measured the physical properties L500 (0.5 x 10^42 - 1.2 x 10^45 erg s-1 ) and M500 (1.1 x 10^13 - 4.9 x 10^14 M⊙) from an iterative procedure using published scaling relations. The present X-ray detected groups and clusters are in the low and intermediate luminosity regimes apart from few luminous systems, thanks to the XMM-Newton sensitivity and the available XMM-Newton deep fields The optically confirmed cluster sample with measurements of redshift and X-ray properties can be used for various astrophysical applications. As a first application, I investigated the LX - T relation for the first time based on a large cluster sample of 345 systems with X-ray spectroscopic parameters drawn from a single survey. The current sample includes groups and clusters with wide ranges of redshifts, temperatures, and luminosities. The slope of the relation is consistent with the published ones of nearby clusters with higher temperatures and luminosities. The derived relation is still much steeper than that predicted by self-similar evolution. I also investigated the evolution of the slope and the scatter of the LX - T relation with the cluster redshift. After excluding the low luminosity groups, I found no significant changes of the slope and the intrinsic scatter of the relation with redshift when dividing the sample into three redshift bins. When including the low luminosity groups in the low redshift subsample, I found its LX - T relation becomes after than the relation of the intermediate and high redshift subsamples. As a second application of the optically confirmed cluster sample from our ongoing survey, I investigated the correlation between the cluster X-ray and the optical parameters that have been determined in a homogenous way. Firstly, I investigated the correlations between the BCG properties (absolute magnitude and optical luminosity) and the cluster global proper- ties (redshift and mass). Secondly, I computed the richness and the optical luminosity within R500 of a nearby subsample (z ≤ 0.42, with a complete membership detection from the SDSS data) with measured X-ray temperatures from our survey. The relation between the estimated optical luminosity and richness is also presented. Finally, the correlation between the cluster optical properties (richness and luminosity) and the cluster global properties (X-ray luminosity, temperature, mass) are investigated.}, language = {en} } @phdthesis{SanchezBarriga2010, author = {S{\´a}nchez-Barriga, Jaime}, title = {A photoemission study of quasiparticle excitations, electron-correlation effects and magnetization dynamics in thin magnetic systems}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-48499}, school = {Universit{\"a}t Potsdam}, year = {2010}, abstract = {This thesis is focused on the electronic, spin-dependent and dynamical properties of thin magnetic systems. Photoemission-related techniques are combined with synchrotron radiation to study the spin-dependent properties of these systems in the energy and time domains. In the first part of this thesis, the strength of electron correlation effects in the spin-dependent electronic structure of ferromagnetic bcc Fe(110) and hcp Co(0001) is investigated by means of spin- and angle-resolved photoemission spectroscopy. The experimental results are compared to theoretical calculations within the three-body scattering approximation and within the dynamical mean-field theory, together with one-step model calculations of the photoemission process. From this comparison it is demonstrated that the present state of the art many-body calculations, although improving the description of correlation effects in Fe and Co, give too small mass renormalizations and scattering rates thus demanding more refined many-body theories including nonlocal fluctuations. In the second part, it is shown in detail monitoring by photoelectron spectroscopy how graphene can be grown by chemical vapour deposition on the transition-metal surfaces Ni(111) and Co(0001) and intercalated by a monoatomic layer of Au. For both systems, a linear E(k) dispersion of massless Dirac fermions is observed in the graphene pi-band in the vicinity of the Fermi energy. Spin-resolved photoemission from the graphene pi-band shows that the ferromagnetic polarization of graphene/Ni(111) and graphene/Co(0001) is negligible and that graphene on Ni(111) is after intercalation of Au spin-orbit split by the Rashba effect. In the last part, a time-resolved x-ray magnetic circular dichroic-photoelectron emission microscopy study of a permalloy platelet comprising three cross-tie domain walls is presented. It is shown how a fast picosecond magnetic response in the precessional motion of the magnetization can be induced by means of a laser-excited photoswitch. From a comparision to micromagnetic calculations it is demonstrated that the relatively high precessional frequency observed in the experiments is directly linked to the nature of the vortex/antivortex dynamics and its response to the magnetic perturbation. This includes the time-dependent reversal of the vortex core polarization, a process which is beyond the limit of detection in the present experiments.}, language = {en} } @phdthesis{Szklarski2007, author = {Szklarski, Jacek T.}, title = {Helical magnetorotational instability in MHD Taylor-Couette flow}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-16002}, school = {Universit{\"a}t Potsdam}, year = {2007}, abstract = {Magnetorotational instability (MRI) is one of the most important and most common instabilities in astrophysics. Today it is widely accepted that it serves as a major source of turbulent viscosity in accretion disks, the most energy efficient objects in the universe. The importance of the MRI for astrophysics has been realized only in recent fifteen years. However, originally it was discovered much earlier, in 1959, in a very different context. Theoretical flow of a conducting liquid confined between differentially rotating cylinders in the presence of an external magnetic field was analyzed. The central conclusion is that the additional magnetic field parallel to the axis of rotation can destabilize otherwise stable flow. Theory of non-magnetized fluid motion between rotating cylinders has much longer history, though. It has been studied already in 1888 and today such setup is usually referred as a Taylor-Couette flow. To prove experimentally the existence of MRI in a magnetized Taylor-Couette flow is a demanding task and different MHD groups around the world try to achieve it. The main problem lies in the fact that laboratory liquid metals which are used in such experiments are characterized by small magnetic Prandtl number. Consequently rotation rates of the cylinders must be extremely large and vast amount of technical problems emerge. One of the most important difficulties is an influence of plates enclosing the cylinders in any experiment. For fast rotation the plates tend to dominate the whole flow and the MRI can not be observed. In this thesis we discuss a special helical configuration of the applied magnetic field which allows the critical rotation rates to be much smaller. If only the axial magnetic field is present, the cylinders must rotate with angular velocities corresponding to Reynolds numbers of order Re ≈ 10^6. With the helical field this number is dramatically reduced to Re ≈ 10^3. The azimuthal component of the magnetic field can be easily generated by letting an electric current through the axis of rotation, In a Taylor-Couette flow the (primary) instability manifests itself as Taylor vortices. The specific geometry of the helical magnetic field leads to a traveling wave solution and the vortices are drifting in a direction determined by rotation and the magnetic field. In an idealized study for infinitely long cylinders this is not a problem. However, if the cylinders have finite length and are bounded vertically by the plates the situation is different. In this dissertation it is shown, with use of numerical methods, that the traveling wave solution also exists for MHD Taylor-Couette flow at finite aspect ratio H/D, H being height of the cylinders, D width of the gap between them. The nonlinear simulations provide amplitudes of fluid velocity which are helpful in designing an experiment. Although the plates disturb the flow, parameters like the drift velocity indicate that the helical MRI operates in this case. The idea of the helical MRI was implemented in a very recent experiment PROMISE. The results provided, for the first time, an evidence that the (helical) MRI indeed exists. Nevertheless, the influence of the vertical endplates was evident and the experiment can be, in principle, improved. Exemplary methods of reduction of the end-effect are here proposed. Near the vertical boundaries develops an Ekman-Hartmann layer. Study of this layer for the MHD Taylor-Couette system as well as its impact on the global flow properties is presented. It is shown that the plates, especially if they are conducting, can disturb the flow far more then previously thought also for relatively slow rotation rates.}, language = {en} } @phdthesis{SvirejevaHopkins2004, author = {Svirejeva-Hopkins, Anastasia}, title = {Urbanised territories as a specific component of the global carbon cycle}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-0001512}, school = {Universit{\"a}t Potsdam}, year = {2004}, abstract = {Wir betrachten folgende Teile: die zus{\"a}tzlichen Kohlenstoff(C)-emissionen, welche aus der Umwandlung von nat{\"u}rlichem Umland durch Stadtwachstum resultieren, und die {\"A}nderung des C-Flusses durch 'urbanisierte' {\"O}kosysteme, soweit atmosph{\"a}risches C durch diese in umliegende nat{\"u}rliche {\"O}kosysteme entlang der Kette \“Atmosph{\"a}re -> Vegetation -> abgestorbene organische Substanzen\” gepumpt wird: d.h. C-Export; f{\"u}r den Zeitraum von 1980 bis 2050. Als Szenario nutzen wir Prognosen der regionalen Stadtbev{\"o}lkerung, welche durch ein 'Hybridmodell' generiert werden f{\"u}r acht Regionen. Alle Sch{\"a}tzungen der C-Fl{\"u}sse basieren auf zwei Modellen: das Regression Modell und das sogenannte G-Modell. Die Siedlungsfl{\"a}che, welche mit dem Wachstum der Stadtbev{\"o}lkerung zunimmt, wird in 'Gr{\"u}nfl{\"a}chen' (Parks, usw.), Geb{\"a}udefl{\"a}chen und informell st{\"a}dtisch genutzte Fl{\"a}chen (Slums, illegale Lagerpl{\"a}tze, usw.) unterteilt. Es werden j{\"a}hrlich die regionale und globale Dynamik der C-Emissionen und des C-Exports sowie die C-Gesamtbilanz berechnet. Dabei liefern beide Modelle qualitativ {\"a}hnliche Ergebnisse, jedoch gibt es einige quantitative Unterschiede. Im ersten Modell erreicht die globale Jahresemission f{\"u}r die Dekade 2020-2030 resultierend aus der Landnutzungs{\"a}nderung ein Maximum von 205 Mt/a. Die maximalen Beitr{\"a}ge zur globalen Emission werden durch China, die asiatische und die pazifische Region erbracht. Im zweiten Modell erh{\"o}ht sich die j{\"a}hrliche globale Emission von 1.12 GtC/a f{\"u}r 1980 auf 1.25 GtC/a f{\"u}r 2005 (1Gt = 109 t). Danach beginnt eine Reduzierung. Vergleichen wir das Emissionmaximum mit der Emission durch Abholzung im Jahre 1980 (1.36 GtC/a), k{\"o}nnen wir konstatieren, daß die Urbanisierung damit in vergleichbarer Gr{\"o}sse zur Emission beitr{\"a}gt. Bezogen auf die globale Dynamik des j{\"a}hrlichen C-Exports durch Urbanisierung beobachten wir ein monotones Wachstum bis zum nahezu dreifachen Wert von 24 MtC/a f{\"u}r 1980 auf 66 MtC/a f{\"u}r 2050 im ersten Modell, bzw. im zweiten Modell von 249 MtC/a f{\"u}r 1980 auf 505 MtC/a f{\"u}r 2050. Damit ist im zweiten Fall die Transportleistung der Siedlungsgebiete mit dem C-Transport durch Fl{\"u}sse in die Ozeane (196 .. 537 MtC/a) vergleichbar. Bei der Absch{\"a}tzung der Gesamtbilanz finden wir, daß die Urbanisierung die Bilanz in Richtung zu einer 'Senke' verschiebt. Entsprechend dem zweiten Modell beginnt sich die C-Gesamtbilanz (nach ann{\"a}hernder Konstanz) ab dem Jahre 2000 mit einer fast konstanten Rate zu verringern. Wenn das Maximum im Jahre 2000 bei 905MtC/a liegt, f{\"a}llt dieser Wert anschliessend bis zum Jahre 2050 auf 118 MtC/a. Bei Extrapolation dieser Dynamik in die Zukunft k{\"o}nnen wir annehmen, daß am Ende des 21. Jahrhunderts die \“urbane\” C-Gesamtbilanz Null bzw. negative Werte erreicht.}, language = {en} } @phdthesis{Sun2024, author = {Sun, Bowen}, title = {Energy losses in low-offset organic solar cells}, doi = {10.25932/publishup-62143}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-621430}, school = {Universit{\"a}t Potsdam}, pages = {xxi, 190}, year = {2024}, abstract = {Organic solar cells (OSCs) represent a new generation of solar cells with a range of captivating attributes including low-cost, light-weight, aesthetically pleasing appearance, and flexibility. Different from traditional silicon solar cells, the photon-electron conversion in OSCs is usually accomplished in an active layer formed by blending two kinds of organic molecules (donor and acceptor) with different energy levels together. The first part of this thesis focuses on a better understanding of the role of the energetic offset and each recombination channel on the performance of these low-offset OSCs. By combining advanced experimental techniques with optical and electrical simulation, the energetic offsets between CT and excitons, several important insights were achieved: 1. The short circuit current density and fill-factor of low-offset systems are largely determined by field-dependent charge generation in such low-offset OSCs. Interestingly, it is strongly evident that such field-dependent charge generation originates from a field-dependent exciton dissociation yield. 2. The reduced energetic offset was found to be accompanied by strongly enhanced bimolecular recombination coefficient, which cannot be explained solely by exciton repopulation from CT states. This implies the existence of another dark decay channel apart from CT. The second focus of the thesis was on the technical perspective. In this thesis, the influence of optical artifacts in differential absorption spectroscopy upon the change of sample configuration and active layer thickness was studied. It is exemplified and discussed thoroughly and systematically in terms of optical simulations and experiments, how optical artifacts originated from non-uniform carrier profile and interference can manipulate not only the measured spectra, but also the decay dynamics in various measurement conditions. In the end of this study, a generalized methodology based on an inverse optical transfer matrix formalism was provided to correct the spectra and decay dynamics manipulated by optical artifacts. Overall, this thesis paves the way for a deeper understanding of the keys toward higher PCEs in low-offset OSC devices, from the perspectives of both device physics and characterization techniques.}, language = {en} } @phdthesis{Sule2007, author = {Sule, Aniket}, title = {Formation and stability of the solar tachocline in MHD simulations}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-14612}, school = {Universit{\"a}t Potsdam}, year = {2007}, abstract = {The solar tachocline is a thin transition layer between the solar radiative zone rotating uniformly and the solar convection zone, which has a mainly latitudinal differential rotation profile. This layer has a thickness of less than \$0.05R_{\sun}\$ and is subject to extreme radial as well as latitudinal shears. Helioseismological estimates put this layer at roughly \$0.7R_{\sun}\$. The tachocline mostly resides in the sub-adiabatic, non-turbulent radiative interior, except for a small overlap with the convection zone on the top. Many proposed dynamo mechanisms involve strong toroidal magnetic fields in this transition region. The exact mechanisms behind the formation of such a thin layer is still disputed. A very plausible mechanism is the one involving a weak, relic poloidal magnetic field trapped inside the radiative zone, which is responsible for expelling differential rotation outwards. This was first proposed by \citet{RK97}. The present work develops this idea with numerical simulations including additional effects like meridional circulation. It is shown that a relic field of 1~Gauss or smaller would be sufficient to explain the observed thickness of the tachocline. The stability of the solar tachocline is addressed as the next part of the problem. It is shown that the tachocline is stable up to a differential rotation of 52\\% in the absence of magnetic fields. This is a new finding as compared to the earlier two dimensional models which estimated the solar differential rotation (about 28\\%) to be marginally stable or even unstable. The changed stability limit is attributed to the changed stability criterion of the 3-dimensional model which also involves radial gradients of the angular velocity. In the presence of toroidal magnetic field belts, the lowest non-axisymmetric mode is shown to be the most unstable one for the radiative part of the tachocline. It is estimated that the tachocline would become unstable for toroidal fields exceeding about 100~Gauss. With both formation and stability questions satisfactorily addressed, this work presents the most comprehensive analysis of the physical processes in the solar tachocline to date.}, language = {en} } @phdthesis{Straesser2007, author = {Str{\"a}ßer, Alexander}, title = {Neue Prinzipien zur Realisierung von gepulsten, frequenzstabilisierten Lasern mit hoher mittlerer Leistung und exzellenter Strahlqualit{\"a}t}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-17496}, school = {Universit{\"a}t Potsdam}, year = {2007}, abstract = {Wasserdampf in der Stratosph{\"a}re und Troposph{\"a}re ist eines der wichtigsten atmosph{\"a}rischen Treibhausgase. Neben seiner Bedeutung f{\"u}r das Klima hat es großen Einfluss auf die Bildung von polaren stratosph{\"a}rischen Wolken sowie auf die atmosph{\"a}rische Chemie. Weltweit erstmalig soll innerhalb eines Forscherverbundes in Deutschland ein leistungsstarkes, mobiles, abtastendes Wasserdampf-DIAL zur dreidimensional hochaufgel{\"o}sten Messung des atmosph{\"a}rischen Wasserdampfs entwickelt werden. Mit dem Wasserdampf-DIAL k{\"o}nnen Wasserdampfkonzentrationen in der Atmosph{\"a}re mit hoher zeitlicher und r{\"a}umlicher Aufl{\"o}sung gemessen werden. Das DIAL basiert auf einem Titan-Saphir-Laser oder einem dazu alternativen OPO-Laser (optisch parametrischer Oszillator). Der f{\"u}r das optische Pumpen dieser Laser n{\"o}tige Pumplaser wurde im Rahmen dieser Arbeit in der Arbeitsgruppe Nichtlineare Optik des Instituts f{\"u}r Physik der Universit{\"a}t Potsdam entwickelt. Ein hochaufl{\"o}sendes, mobiles DIAL erfordert einen Pumplaser mit großen Pulsenergien, guter Strahlqualit{\"a}t und einer hohen Effizienz. Um diese Ziele zu erreichen, wurde ein MOPA-System (Master Oscillator Power Amplifier) mit Frequenzstabilisierung auf der Basis von doppelbrechungskompensierten, transversal diodengepumpten Laserst{\"a}ben entwickelt und untersucht. Auf dem Weg dahin wurden unterschiedliche Realisierungsm{\"o}glichkeiten des MOPA-Systems gepr{\"u}ft. Im Rahmen dessen wurden die Festk{\"o}rperlasermaterialien Yb:YAG [1], kerndotierte Nd:YAG-Keramik [2] und herk{\"o}mmliches Nd:YAG vorgestellt und hinsichtlich ihrer Eignung f{\"u}r dieses MOPA-System untersucht. Nachdem die Entscheidung f{\"u}r Nd:YAG als laseraktives Material gefallen war, konnte darauf aufbauend die Konzeptionierung des Lasersystems auf der Basis von Verst{\"a}rkungsrechnungen vorgenommen werden. Die entwickelte Verst{\"a}rkungsrechnung tr{\"a}gt den Tatbest{\"a}nden von realen Systemen Rechnung, indem radiusabh{\"a}ngige Intensit{\"a}ten und eine radiale, nicht homogene Inversionsdichte ber{\"u}cksichtigt werden. Die Frequenzstabilisierung des gepulsten Oszillators (Frequenzstabilit{\"a}t von 1 MHz) wurde mittels des Pound-Drever-Hall-Verfahrens vorgenommen. Mit der Heterodynmethode wird die Frequenzstabilit{\"a}t des Oszillators gemessen. Nach Untersuchungen {\"u}ber verschiedene Konfigurationen f{\"u}r lineare und ringf{\"o}rmige Oszillatoren, wurde ein Ringoszillator mit zwei Laserk{\"o}pfen aufgebaut, in welchen von außen mit einem Laser fester Frequenz eingestrahlt wird. Dieser emittiert bei einer Wiederholrate von 400 Hz eine Pulsenergie von Eout = 21 mJ bei nahezu beugungsbegrenzter Strahlqualit{\"a}t (M2 < 1,2). Die Verst{\"a}rkung dieser Laserpulse erfolgte zun{\"a}chst durch eine Vorverst{\"a}rkerstufe und anschließend durch zwei doppelbrechungskompensierte Hauptverst{\"a}rker im Doppeldurchgang. Eine gute Strahlqualit{\"a}t (M2 = 1,75) konnte unter anderem erzielt werden, indem der Doppeldurchgang durch die Hauptverst{\"a}rker mit einem phasenkonjugierenden Spiegel (SF6), auf der Basis der stimulierten Brillouin Streuung, realisiert wurde. Der entwickelte Laser emittiert Pulse mit einer L{\"a}nge von 25 ns und einer Energie von 250 mJ. Insgesamt wurde ein bisher einmaliges Lasersystem entwickelt. In der Literatur sind die erreichte Frequenzstabilit{\"a}t, Strahlqualit{\"a}t und Leistung in dieser Kombination bisher nicht dokumentiert. In der Zukunft soll durch den Einsatz von kerndotierten, keramischen Lasermaterialien, h{\"o}heren Pumpleistungen der Hauptverst{\"a}rker und phasenkonjugierenden Spiegeln aus Quarz die Pulsenergie des Systems weiter erh{\"o}ht werden. [1] M. Ostermeyer, A. Straesser, "Theoretical investigation of Yb:YAG as laser material for nanosecond pulse emission with large energies in the joule range", Optics Communications, Vol. 274, pp. 422-428 (2007) [2] A. Str{\"a}ßer and M. Ostermeyer, "Improving the brightness of side pumped power amplifiers by using core doped ceramic rods", Optics Express, Vol. 14, pp. 6687- 6693 (2006)}, language = {de} } @phdthesis{Streich2015, author = {Streich, David}, title = {Understanding massive disk galaxy formation through resolved stellar populations}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-81027}, school = {Universit{\"a}t Potsdam}, pages = {ix, 140}, year = {2015}, abstract = {In this thesis we utilize resolved stellar populations to improve our understanding of galaxy formation and evolution. In the first part we improve a method for metallicity determination of faint old stellar systems, in the second and third part we analyze the individual history of six nearby disk galaxies outside the Local Group. A New Calibration of the Color Metallicity Relation of Red Giants for HST data: It is well known, that the color distribution of stars on the the Red Giant Branch (RGB) can be used to determine metallicities of old stellar populations that have only shallow photometry. Based on the largest sample of globular clusters ever used for such studies, we quantify the relation between metallicity and color in the widely used HST ACS filters F606W and F814W. We use a sample of globular clusters from the ACS Globular Cluster Survey and measure their RGB color at given absolute magnitudes to derive the color-metallicity relation. We find a clear relation between metallicity and RGB color; we investigate the scatter and the uncertainties in this relation and show its limitations. A comparison with isochrones shows reasonably good agreement with BaSTI models, a small offset to Dartmouth models, and a larger offset to Padua models. Even for the best globular cluster data available, the metallicity of a simple stellar population can be determined from the RGB alone only with an accuracy of 0.3 dex for [M/H]<-1, and 0.15 dex for [M/H]>-1. For mixed populations, as they are observed in external galaxies, the uncertainties will be even larger due to uncertainties in extinction, age, etc. Therefore caution is necessary when interpreting photometric metallicities. The Structural History of Nearby Low Mass Disk Galaxies: We study the individual evolution histories of three nearby, low-mass, edge-on galaxies (IC5052, NGC4244, NGC5023). Using the color magnitude diagrams of resolved stellar populations, we construct star count density maps for populations of different ages and analyze the change of structural parameters with stellar age within each galaxy. The three galaxies show low vertical heating rates, which are much lower than the heating rate of the Milky Way. This indicates that heating agents, as giant molecular clouds and spiral structure are weak in low mass galaxies. We do not detect a separate thick disk in any of the three galaxies, even though our observations cover a larger range in equivalent surface brightness than any integrated light study. While scaleheights increase with age, each population can be well described by a single disk. Only two of the galaxies contain a very weak additional component, which we identify as the faint halo. The mass of these faint halos is less than 1\% of the mass of the disk. All populations in the three galaxies exhibit no or only little flaring. While this finding is consistent with previous integrated light studies, it poses strong constraints on galaxy formation models, because most theoretical simulations often find strong flaring due to interactions or radial migration. Furthermore, we find breaks in the radial profiles of all three galaxies. The radii of these breaks are independent of age, and the break strength is decreasing with age in two of the galaxies (NGC4244 and NGC5023). This is consistent with break formation models, that combine a star formation cutoff with radial migration. The differing behavior of IC5052 can be explained by a recent interaction or minor merger. The Structural History of Massive Disk Galaxies: We extend the structural analysis of stellar populations with distinct ages to three massive galaxies, NGC891, NGC4565 and NGC7814. While confusion effects due to the high stellar number densities in their central region, and the prominent dust lanes inhibit an detailed analysis of the radial profiles, we can study their vertical structure. These massive galaxies also have a slower heating than the Milky Way, comparable to the low mass galaxies. This can be traced back to their already thick young populations and thick layers of their interstellar medium. We do not find a clear separate thick disk in any of these three galaxies; all populations can be described by a single disk plus a S\'ersic bulge/halo component. In contrast to the low mass galaxies, we cannot rule out the presence of thick disks in the massive galaxies, because of the strong influence of the halo, that might hide the possible contribution of the thick disk to the vertical star count profiles. However, the faintness of the possible thick disks still points to problems in the earlier ubiquitous findings of thick disks in external galaxies.}, language = {en} } @phdthesis{Streibel2005, author = {Streibel, Martin Albert Gerhard}, title = {Bestimmung von Ozonabbauraten {\"u}ber der Arktis und Antarktis mittels Ozonsonden- und Satellitendaten}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-6570}, school = {Universit{\"a}t Potsdam}, year = {2005}, abstract = {Diese Arbeit besch{\"a}ftigt sich mit der chemischen Ozonzerst{\"o}rung im arktischen und antarktischen stratosph{\"a}rischen Polarwirbel. Diese wird durch Abbauprodukte von anthropogen emittierten Fluorchlorkohlenwasserstoffen und Halonen, Chlor- und Bromradikale, verursacht. Studien in denen der gemessene und modellierte Ozonabbau verglichen wird zeigen, dass die Prozeße bekannt sind, der quantitative Verlauf allerdings nicht vollst{\"a}ndig verstanden ist. Die Prozesse, die zur Ozonzerst{\"o}rung f{\"u}hren sind in beiden Polarwirbeln {\"a}hnlich. Allerdings f{\"a}llt als Konsequenz unterschiedlicher meteorologischer Bedingungen der chemische Ozonabbau im arktischen Polarwirbel weniger drastisch aus als {\"u}ber der Antarktis. Der arktische Polarwirbel ist im Mittel st{\"a}rker dynamisch gest{\"o}rt als der antarktische und weist eine st{\"a}rkere Jahr-zu-Jahr Variabilit{\"a}t auf. Das erschwert die Messung des chemischen Ozonabbaus. Zur Trennung des chemischen Ozonabbaus von der dynamischen Umverteilung des Ozons im arktischen Polarwirbel wurde die Matchmethode entwickelt. Bei dieser Methode werden Luftpakete innerhalb des Polarwirbels mehrfach beprobt, um den chemischen Anteil der Ozon{\"a}nderung zu quantifizieren. Zur Identifizierung von doppelt beprobten Luftpaketen werden Trajektorien aus Windfeldern berechnet. K{\"o}nnen zwei Messungen im Rahmen bestimmter Qualit{\"a}tskriterien durch eine Trajektorie verbunden werden, kann die Ozondifferenz zwischen beiden Sondierungen berechnet und als chemischer Ozonabbau interpretiert werden. Eine solche Koinzidenz wird Match genannt. Der Matchmethode liegt ein statistischer Ansatz zugrunde, so dass eine Vielzahl solcher doppelt beprobter Luftmassen vorliegen muss, um gesicherte Aussagen {\"u}ber die Ozonzerst{\"o}rung gewinnen zu k{\"o}nnen. So erh{\"a}lt man die Ozonzerst{\"o}rung in einem bestimmten Zeitintervall, also Ozonabbauraten. Um die Anzahl an doppelt beprobten Luftpackten zu erh{\"o}hen wurde eine aktive Koordinierung der Ozonsondenaufstiege entwickelt. Im Rahmen dieser Arbeit wurden Matchkampagnen w{\"a}hrend des arktischen Winters 2002/2003 und zum ersten Mal w{\"a}hrend eines antarktischen Winter (2003) durchgef{\"u}hrt. Aus den gewonnenen Daten wurden Ozonabbauraten in beiden Polarwirbeln bestimmt. Diese Abbauraten dienen zum einen der Evaluierung von Modellen, erm{\"o}glichen aber auch den direkten Vergleich von Ozonabbauraten in beiden Polarwirbeln. Der Winter 2002/2003 war zu Beginn durch sehr tiefe Temperaturen in der mittleren und unteren Stratosph{\"a}re charakterisiert, so dass die Matchkampagne Ende November gestartet wurde. Ab Januar war der Polarwirbel zeitweise stark dynamisch gest{\"o}rt. Die Kampagne ging bis Mitte M{\"a}rz. F{\"u}r den H{\"o}henbereich von 400 bis 550 K potentieller Temperatur (15-23 km) konnten Ozonabbauraten und der Verlust in der Gesamts{\"a}ule berechnet werden. Die Ozonabbauraten wurden in verschiedenen Tests auf ihre Stabilit{\"a}t {\"u}berpr{\"u}ft. Der antarktische Polarwirbel war vom Beginn des Winters bis Mitte Oktober 2003 sehr kalt und stellte Ende September kurzzeitig den Rekord f{\"u}r die gr{\"o}ßte bisher aufgetretene Ozonloch-Fl{\"a}che ein. Es konnten f{\"u}r den Kampagnenzeitraum, Anfang Juni bis Anfang Oktober, Ozonabbauraten im H{\"o}henbereich von 400 bis 550 K potentieller Temperatur ermittelt werden. Der zeitliche Verlauf des Ozonabbaus war dabei auf fast allen H{\"o}henniveaus identisch. Die Zunahme des Sonnenlichtes im Polarwirbel mit der Zeit f{\"u}hrt zu einem starken Anwachsen der Ozonabbauraten. Ab Mitte September gingen die Ozonabbauraten auf Null zur{\"u}ck, da bis zu diesem Zeitpunkt das gesamte Ozon zwischen ca. 14 und 21 km zerst{\"o}rt wurde. Im letzten Teil der Arbeit wird ein neuer Algorithmus auf Basis der multivariaten Regression vorgestellt, mit dem Ozonabbauraten aus Ozonprofilen verschiedener Sensoren gleichzeitig berechnet werden k{\"o}nnen. Dabei k{\"o}nnen neben der Ozonabbaurate die systematischen Fehler zwischen den einzelnen Sensoren bestimmt werden. Dies wurde exemplarisch am antarktischen Winter 2003 f{\"u}r das 475 K potentielle Temperatur Niveau gezeigt. Neben den Ozonprofilen der Sonden wurden Daten von zwei Satellitenexperimenten verwendet. Die mit der multivariaten Matchtechnik berechneten Ozonabbauraten stimmen gut mit den Ozonabbauraten der Einzelsensor-Matchans{\"a}tze {\"u}berein.}, subject = {Ozon}, language = {de} } @phdthesis{Stoyanov2011, author = {Stoyanov, Hristiyan}, title = {Soft nanocomposites with enhanced electromechanical response for dielectric elastomer actuators}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-51194}, school = {Universit{\"a}t Potsdam}, year = {2011}, abstract = {Electromechanical transducers based on elastomer capacitors are presently considered for many soft actuation applications, due to their large reversible deformation in response to electric field induced electrostatic pressure. The high operating voltage of such devices is currently a large drawback, hindering their use in applications such as biomedical devices and biomimetic robots, however, they could be improved with a careful design of their material properties. The main targets for improving their properties are increasing the relative permittivity of the active material, while maintaining high electric breakdown strength and low stiffness, which would lead to enhanced electrostatic storage ability and hence, reduced operating voltage. Improvement of the functional properties is possible through the use of nanocomposites. These exploit the high surface-to-volume ratio of the nanoscale filler, resulting in large effects on macroscale properties. This thesis explores several strategies for nanomaterials design. The resulting nanocomposites are fully characterized with respect to their electrical and mechanical properties, by use of dielectric spectroscopy, tensile mechanical analysis, and electric breakdown tests. First, nanocomposites consisting of high permittivity rutile TiO2 nanoparticles dispersed in thermoplastic block copolymer SEBS (poly-styrene-coethylene-co-butylene-co-styrene) are shown to exhibit permittivity increases of up to 3.7 times, leading to 5.6 times improvement in electrostatic energy density, but with a trade-off in mechanical properties (an 8-fold increase in stiffness). The variation in both electrical and mechanical properties still allows for electromechanical improvement, such that a 27 \% reduction of the electric field is found compared to the pure elastomer. Second, it is shown that the use of nanofiller conductive particles (carbon black (CB)) can lead to a strong increase of relative permittivity through percolation, however, with detrimental side effects. These are due to localized enhancement of the electric field within the composite, which leads to sharp reductions in electric field strength. Hence, the increase in permittivity does not make up for the reduction in breakdown strength in relation to stored electrical energy, which may prohibit their practical use. Third, a completely new approach for increasing the relative permittivity and electrostatic energy density of a polymer based on 'molecular composites' is presented, relying on chemically grafting soft π-conjugated macromolecules to a flexible elastomer backbone. Polarization caused by charge displacement along the conjugated backbone is found to induce a large and controlled permittivity enhancement (470 \% over the elastomer matrix), while chemical bonding, encapsulates the PANI chains manifesting in hardly any reduction in electric breakdown strength, and hence resulting in a large increase in stored electrostatic energy. This is shown to lead to an improvement in the sensitivity of the measured electromechanical response (83 \% reduction of the driving electric field) as well as in the maximum actuation strain (250 \%). These results represent a large step forward in the understanding of the strategies which can be employed to obtain high permittivity polymer materials with practical use for electro-elastomer actuation.}, language = {en} } @phdthesis{Stock2010, author = {Stock, Maria}, title = {Charakterisierung der troposph{\"a}rischen Aerosolvariabilit{\"a}t in der europ{\"a}ischen Arktis}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-49203}, school = {Universit{\"a}t Potsdam}, year = {2010}, abstract = {Auf der Grundlage von Sonnenphotometermessungen an drei Messstationen (AWIPEV/ Koldewey in Ny-{\AA}lesund (78.923 °N, 11.923 °O) 1995-2008, 35. Nordpol Driftstation - NP-35 (84.3-85.5 °N, 41.7-56.6 °O) M{\"a}rz/April 2008, Sodankyl{\"a} (67.37 °N, 26.65 °O) 2004-2007) wird die Aerosolvariabilit{\"a}t in der europ{\"a}ischen Arktis und deren Ursachen untersucht. Der Schwerpunkt liegt dabei auf der Frage des Zusammenhanges zwischen den an den Stationen gemessenen Aerosolparametern (Aerosol optische Dicke, Angstr{\"o}m Koeffizient, usw.) und dem Transport des Aerosols sowohl auf kurzen Zeitskalen (Tagen) als auch auf langen Zeitskalen (Monate, Jahre). Um diesen Zusammenhang herzustellen, werden f{\"u}r die kurzen Zeitskalen mit dem Trajektorienmodell PEP-Tracer 5-Tage R{\"u}ckw{\"a}rtstrajektorien in drei Starth{\"o}hen (850 hPa, 700 hPa, 500 hPa) f{\"u}r die Uhrzeiten 00, 06, 12 und 18 Uhr berechnet. Mit Hilfe der nicht-hierarchischen Clustermethode k-means werden die berechneten R{\"u}ckw{\"a}rtstrajektorien dann zu Gruppen zusammengefasst und bestimmten Quellgebieten und den gemessenen Aerosol optischen Dicken zugeordnet. Die Zuordnung von Aerosol optischer Dicke und Quellregion ergibt keinen eindeutigen Zusammenhang zwischen dem Transport verschmutzter Luftmassen aus Europa oder Russland bzw. Asien und erh{\"o}hter Aerosol optischer Dicke. Dennoch ist f{\"u}r einen konkreten Einzelfall (M{\"a}rz 2008) ein direkter Zusammenhang von Aerosoltransport und hohen Aerosol optischen Dicken nachweisbar. In diesem Fall gelangte Waldbrandaerosol aus S{\"u}dwestrussland in die Arktis und konnte sowohl auf der NP-35 als auch in Ny-{\AA}lesund beobachtet werden. In einem weiteren Schritt wird mit Hilfe der EOF-Analyse untersucht, inwieweit großskalige atmosph{\"a}rische Zirkulationsmuster f{\"u}r die Aerosolvariabilit{\"a}t in der europ{\"a}ischen Arktis verantwortlich sind. {\"A}hnlich wie bei der Trajektorienanalyse ist auch die Verbindung der atmosph{\"a}rischen Zirkulation zu den Photometermessungen an den Stationen in der Regel nur schwach ausgepr{\"a}gt. Eine Ausnahme findet sich bei der Betrachtung des Jahresganges des Bodendruckes und der Aerosol optischen Dicke. Hohe Aerosol optische Dicken treten im Fr{\"u}hjahr zum einen dann auf, wenn durch das Islandtief und das sibirische Hochdruckgebiet Luftmassen aus Europa oder Russland/Asien in die Arktis gelangen, und zum anderen, wenn sich ein kr{\"a}ftiges Hochdruckgebiet {\"u}ber Gr{\"o}nland und weiten Teilen der Arktis befindet. Ebenso zeigt sich, dass der {\"U}bergang zwischen Fr{\"u}hjahr und Sommer zumindest teilweise bedingt ist durch denWechsel vom stabilen Polarhoch im Winter und Fr{\"u}hjahr zu einer st{\"a}rker von Tiefdruckgebieten bestimmten arktischen Atmosph{\"a}re im Sommer. Die geringere Aerosolkonzentration im Sommer kann zum Teil mit einer Zunahme der nassen Deposition als Aerosolsenke begr{\"u}ndet werden. F{\"u}r Ny-{\AA}lesund wird neben den Transportmustern auch die chemische Zusammensetzung des Aerosols mit Hilfe von Impaktormessungen an der Zeppelinstation auf dem Zeppelinberg (474m {\"u}.NN) nahe Ny-{\AA}lesund abgeleitet. Dabei ist die positive Korrelation der Aerosoloptischen Dicke mit der Konzentration von Sulfationen und Ruß sehr deutlich. Beide Stoffe gelangen zu einem Großteil durch anthropogene Emissionen in die Atmosph{\"a}re. Die damit nachweisbar anthropogen gepr{\"a}gte Zusammensetzung des arktischen Aerosols steht im Widerspruch zum nicht eindeutig herstellbaren Zusammenhang mit dem Transport des Aerosols aus Industrieregionen. Dies kann nur durch einen oder mehrere gleichzeitig stattfindende Transformationsprozesse (z. B. Nukleation von Schwefels{\"a}urepartikeln) w{\"a}hrend des Transportes aus den Quellregionen (Europa, Russland) erkl{\"a}rt werden.}, language = {de} } @phdthesis{Steyrleuthner2014, author = {Steyrleuthner, Robert}, title = {Korrelation von Struktur, optischen Eigenschaften und Ladungstransport in einem konjugierten Naphthalindiimid-Bithiophen Copolymer mit herausragender Elektronenmobilit{\"a}t}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-71413}, school = {Universit{\"a}t Potsdam}, year = {2014}, abstract = {Organische Halbleiter besitzen neue, bemerkenswerte Materialeigenschaften, die sie f{\"u}r die grundlegende Forschung wie auch aktuelle technologische Entwicklung (bsw. org. Leuchtdioden, org. Solarzellen) interessant werden lassen. Aufgrund der starken konformative Freiheit der konjugierten Polymerketten f{\"u}hrt die Vielzahl der m{\"o}glichen Anordnungen und die schwache intermolekulare Wechselwirkung f{\"u}r gew{\"o}hnlich zu geringer struktureller Ordnung im Festk{\"o}rper. Die Morphologie hat gleichzeitig direkten Einfluss auf die elektronische Struktur der organischen Halbleiter, welches sich meistens in einer deutlichen Reduktion der Ladungstr{\"a}gerbeweglichkeit gegen{\"u}ber den anorganischen Verwandten zeigt. So stellt die Beweglichkeit der Ladungen im Halbleiter einen der limitierenden Faktoren f{\"u}r die Leistungsf{\"a}higkeit bzw. den Wirkungsgrad von funktionellen organischen Bauteilen dar. Im Jahr 2009 wurde ein neues auf Naphthalindiimid und Bithiophen basierendes Dornor/Akzeptor Copolymer vorgestellt [P(NDI2OD‑T2)], welches sich durch seine außergew{\"o}hnlich hohe Ladungstr{\"a}germobilit{\"a}t auszeichnet. In dieser Arbeit wird die Ladungstr{\"a}germobilit{\"a}t in P(NDI2OD‑T2) bestimmt, und der Transport durch eine geringe energetischer Unordnung charakterisiert. Obwohl dieses Material zun{\"a}chst als amorph beschrieben wurde zeigt eine detaillierte Analyse der optischen Eigenschaften von P(NDI2OD‑T2), dass bereits in L{\"o}sung geordnete Vorstufen supramolekularer Strukturen (Aggregate) existieren. Quantenchemische Berechnungen belegen die beobachteten spektralen {\"A}nderungen. Mithilfe der NMR-Spektroskopie kann die Bildung der Aggregate unabh{\"a}ngig von optischer Spektroskopie best{\"a}tigt werden. Die Analytische Ultrazentrifugation an P(NDI2OD‑T2) L{\"o}sungen legt nahe, dass sich die Aggregation innerhalb der einzelnen Ketten unter Reduktion des hydrodynamischen Radius vollzieht. Die Ausbildung supramolekularen Strukturen nimmt auch eine signifikante Rolle bei der Filmbildung ein und verhindert gleichzeitig die Herstellung amorpher P(NDI2OD‑T2) Filme. Durch chemische Modifikation der P(NDI2OD‑T2)-Kette und verschiedener Prozessierungs-Methoden wurde eine {\"A}nderung des Kristallinit{\"a}tsgrades und gleichzeitig der Orientierung der kristallinen Dom{\"a}nen erreicht und mittels R{\"o}ntgenbeugung quantifiziert. In hochaufl{\"o}senden Elektronenmikroskopie-Messungen werden die Netzebenen und deren Einbettung in die semikristallinen Strukturen direkt abgebildet. Aus der Kombination der verschiedenen Methoden erschließt sich ein Gesamtbild der Nah- und Fernordnung in P(NDI2OD‑T2). {\"U}ber die Messung der Elektronenmobilit{\"a}t dieser Schichten wird die Anisotropie des Ladungstransports in den kristallographischen Raumrichtungen von P(NDI2OD‑T2) charakterisiert und die Bedeutung der intramolekularen Wechselwirkung f{\"u}r effizienten Ladungstransport herausgearbeitet. Gleichzeitig wird deutlich, wie die Verwendung von gr{\"o}ßeren und planaren funktionellen Gruppen zu h{\"o}heren Ladungstr{\"a}germobilit{\"a}ten f{\"u}hrt, welche im Vergleich zu klassischen semikristallinen Polymeren weniger sensitiv auf die strukturelle Unordnung im Film sind.}, language = {de} } @phdthesis{Stete2020, author = {Stete, Felix}, title = {Gold at the nanoscale}, doi = {10.25932/publishup-49605}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-496055}, school = {Universit{\"a}t Potsdam}, pages = {X, 186}, year = {2020}, abstract = {In this cumulative dissertation, I want to present my contributions to the field of plasmonic nanoparticle science. Plasmonic nanoparticles are characterised by resonances of the free electron gas around the spectral range of visible light. In recent years, they have evolved as promising components for light based nanocircuits, light harvesting, nanosensors, cancer therapies, and many more. This work exhibits the articles I authored or co-authored in my time as PhD student at the University of Potsdam. The main focus lies on the coupling between localised plasmons and excitons in organic dyes. Plasmon-exciton coupling brings light-matter coupling to the nanoscale. This size reduction is accompanied by strong enhancements of the light field which can, among others, be utilised to enhance the spectroscopic footprint of molecules down to single molecule detection, improve the efficiency of solar cells, or establish lasing on the nanoscale. When the coupling exceeds all decay channels, the system enters the strong coupling regime. In this case, hybrid light-matter modes emerge utilisable as optical switches, in quantum networks, or as thresholdless lasers. The present work investigates plasmon-exciton coupling in gold-dye core-shell geometries and contains both fundamental insights and technical novelties. It presents a technique which reveals the anticrossing in coupled systems without manipulating the particles themselves. The method is used to investigate the relation between coupling strength and particle size. Additionally, the work demonstrates that pure extinction measurements can be insufficient when trying to assess the coupling regime. Moreover, the fundamental quantum electrodynamic effect of vacuum induced saturation is introduced. This effect causes the vacuum fluctuations to diminish the polarisability of molecules and has not yet been considered in the plasmonic context. The work additionally discusses the reaction of gold nanoparticles to optical heating. Such knowledge is of great importance for all potential optical applications utilising plasmonic nanoparticles since optical excitation always generates heat. This heat can induce a change in the optical properties, but also mechanical changes up to melting can occur. Here, the change of spectra in coupled plasmon-exciton particles is discussed and explained with a precise model. Moreover, the work discusses the behaviour of gold nanotriangles exposed to optical heating. In a pump-probe measurement, X-ray probe pulses directly monitored the particles' breathing modes. In another experiment, the triangles were exposed to cw laser radiation with varying intensities and illumination areas. X-ray diffraction directly measured the particles' temperature. Particle melting was investigated with surface enhanced Raman spectroscopy and SEM imaging demonstrating that larger illumination areas can cause melting at lower intensities. An elaborate methodological and theoretical introduction precedes the articles. This way, also readers without specialist's knowledge get a concise and detailed overview of the theory and methods used in the articles. I introduce localised plasmons in metal nanoparticles of different shapes. For this work, the plasmons were mostly coupled to excitons in J-aggregates. Therefore, I discuss these aggregates of organic dyes with sharp and intense resonances and establish an understanding of the coupling between the two systems. For ab initio simulations of the coupled systems, models for the systems' permittivites are presented, too. Moreover, the route to the sample fabrication - the dye coating of gold nanoparticles, their subsequent deposition on substrates, and the covering with polyelectrolytes - is presented together with the measurement methods that were used for the articles.}, language = {en} } @phdthesis{Steppa2022, author = {Steppa, Constantin Beverly}, title = {Modelling the galactic population of very-high-energy gamma-ray sources}, doi = {10.25932/publishup-54947}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-549478}, school = {Universit{\"a}t Potsdam}, pages = {106}, year = {2022}, abstract = {The current generation of ground-based instruments has rapidly extended the limits of the range accessible to us with very-high-energy (VHE) gamma-rays, and more than a hundred sources have now been detected in the Milky Way. These sources represent only the tip of the iceberg, but their number has reached a level that allows population studies. In this work, a model of the global population of VHE gamma-ray sources based on the most comprehensive census of Galactic sources in this energy regime, the H.E.S.S. Galactic plane survey (HGPS), will be presented. A population synthesis approach was followed in the construction of the model. Particular attention was paid to correcting for the strong observational bias inherent in the sample of detected sources. The methods developed for estimating the model parameters have been validated with extensive Monte Carlo simulations and will be shown to provide unbiased estimates of the model parameters. With these methods, five models for different spatial distributions of sources have been constructed. To test the validity of these models, their predictions for the composition of sources within the sensitivity range of the HGPS are compared with the observed sample. With one exception, similar results are obtained for all spatial distributions, showing that the observed longitude profile and the source distribution over photon flux are in fair agreement with observation. Regarding the latitude profile and the source distribution over angular extent, it becomes apparent that the model needs to be further adjusted to bring its predictions in agreement with observation. Based on the model, predictions of the global properties of the Galactic population of VHE gamma-ray sources and the prospects of the Cherenkov Telescope Array (CTA) will be presented. CTA will significantly increase our knowledge of VHE gamma-ray sources by lowering the threshold for source detection, primarily through a larger detection area compared to current-generation instruments. In ground-based gamma-ray astronomy, the sensitivity of an instrument depends strongly, in addition to the detection area, on the ability to distinguish images of air showers produced by gamma-rays from those produced by cosmic rays, which are a strong background. This means that the number of detectable sources depends on the background rejection algorithm used and therefore may also be increased by improving the performance of such algorithms. In this context, in addition to the population model, this work presents a study on the application of deep-learning techniques to the task of gamma-hadron separation in the analysis of data from ground-based gamma-ray instruments. Based on a systematic survey of different neural-network architectures, it is shown that robust classifiers can be constructed with competitive performance compared to the best existing algorithms. Despite the broad coverage of neural-network architectures discussed, only part of the potential offered by the application of deep-learning techniques to the analysis of gamma-ray data is exploited in the context of this study. Nevertheless, it provides an important basis for further research on this topic.}, language = {en} } @phdthesis{Stephan2007, author = {Stephan, Niels}, title = {Ph{\"a}nomenologische Untersuchungen zur Feuchteempfindlichkeit der elektrischen Eigenschaften von d{\"u}nnen Polymerfilmen und deren Verwendung f{\"u}r neuartige Feuchtesensoren}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-13853}, school = {Universit{\"a}t Potsdam}, year = {2007}, abstract = {Ziel dieser Arbeit ist die ph{\"a}nomenologische Untersuchung der Feuchteempfindlichkeit der elektrischen Eigenschaften d{\"u}nner Polymerschichten. Diese Untersuchungen stellen gleichzeitig Vorarbeiten zur Entwicklung von Prototypen von zwei polymeren D{\"u}nnschicht-Feuchtesensoren dar, die sich durch die spezielle Auswahl der feuchtesensitiven Materialien jeweils durch eine besondere Eigenschaft gegen{\"u}ber kommerziellen Massenprodukten auszeichnen. Ziel der Entwicklungsarbeiten f{\"u}r den ersten Prototypen war die Konstruktion eines schnellen Feuchtesensors, der pl{\"o}tzliche und sprunghafte Feuchte{\"a}nderungen in der umgebenden Atmosph{\"a}re m{\"o}glichst rasch detektieren kann. Daf{\"u}r wurden d{\"u}nne Schichten von Poly-DADMAC auf Interdigitalstrukturen aufgebracht, die einen m{\"o}glichst direkten Kontakt zwischen feuchtesensitiver Schicht und umgebender, feuchter Atmosph{\"a}re gew{\"a}hrleisten. Als Messgr{\"o}ßen dienten die Wechselstromgr{\"o}ßen Widerstand und Kapazit{\"a}t der Schichten. Die Feuchtekennlinien der Schichten zeigen gute Konstanz und hohe Reproduzierbarkeit. Der Widerstand der Schichten {\"a}ndert sich durch den Einfluss von Feuchte je nach Schichtdicke um 3 bis 5 Gr{\"o}ßenordnungen und eignet sich als Messgr{\"o}ße f{\"u}r die Feuchtigkeit im gesamten Feuchtebereich. Die Hysterese der Filme konnte auf kleiner als 2,5\% r.F. bestimmt werden, die Reproduzierbarkeit auf besser als 1\% r.F. Die Ansprechzeit der Schichten l{\"a}sst sich schichtdickenabh{\"a}ngig zu 1 bis 10 Sekunden bestimmen. Hierbei zeigen besonders die d{\"u}nnen Schichten kurze Ansprechzeiten. Zielstellung f{\"u}r den zweiten Feuchtesensor war die Entwicklung eines Prototypen, dessen sensitive Schicht sich biostatisch und biozid verh{\"a}lt, so dass er in biotischen Umgebungen eingesetzt werden kann. Es wurden f{\"u}nf Polysulfobetaine synthetisiert, deren Biozidit{\"a}t und Biostatik mit dem Kontakttest nach R{\"o}nnpagel, dem ISO846-Test und Abbautests bestimmt wurde. Zwei Polymere - Poly-DMMAAPS (BT2) und Poly-[MSA-Styren-Sulfobetain] (BT5) - erwiesen sich als ausreichend biozid und biostatisch. Schichten dieser Polymere wurden auf Interdigitalstrukturen aufgezogen, anschließend wurden die Kennlinien dieser Proben aufgenommen. Die Messwerte zeigen f{\"u}r beide Polymere gute Konstanz und eine hohe Reproduzierbarkeit. BT2-Proben sind zwischen 20\% und 80\% r.F. besonders empfindlich und zeigen {\"u}ber einen Monat keine Langzeitdrift. Vernetzte Proben zeigen bis 50°C keinen temperaturbedingten Abfall der Feuchteempfindlichkeit. Der Einsatz vernetzter BT5-Schichten als kapazitiver Feuchtesensor ist bis etwa 70°C m{\"o}glich, die Schichten sind selbst nach Lagerung im Hochvakuum und mehrfacher Betauung stabil. Damit liegen zwei funktionsf{\"a}hige Prototypen von Feuchtesensoren vor, f{\"u}r die die meisten Kennwerte denen von vergleichbaren kommerziellen Feuchtesensoren entsprechen. Gleichzeitig zeichnen sie sich aber durch eine sehr niedrige Ansprechzeit bzw. eine ausreichende Lebensdauer unter biotischen Bedingungen aus.}, language = {de} } @phdthesis{Steinhaus2014, author = {Steinhaus, Sebastian Peter}, title = {Constructing quantum spacetime}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-72558}, school = {Universit{\"a}t Potsdam}, year = {2014}, abstract = {Despite remarkable progress made in the past century, which has revolutionized our understanding of the universe, there are numerous open questions left in theoretical physics. Particularly important is the fact that the theories describing the fundamental interactions of nature are incompatible. Einstein's theory of general relative describes gravity as a dynamical spacetime, which is curved by matter and whose curvature determines the motion of matter. On the other hand we have quantum field theory, in form of the standard model of particle physics, where particles interact via the remaining interactions - electromagnetic, weak and strong interaction - on a flat, static spacetime without gravity. A theory of quantum gravity is hoped to cure this incompatibility by heuristically replacing classical spacetime by quantum spacetime'. Several approaches exist attempting to define such a theory with differing underlying premises and ideas, where it is not clear which is to be preferred. Yet a minimal requirement is the compatibility with the classical theory, they attempt to generalize. Interestingly many of these models rely on discrete structures in their definition or postulate discreteness of spacetime to be fundamental. Besides the direct advantages discretisations provide, e.g. permitting numerical simulations, they come with serious caveats requiring thorough investigation: In general discretisations break fundamental diffeomorphism symmetry of gravity and are generically not unique. Both complicates establishing the connection to the classical continuum theory. The main focus of this thesis lies in the investigation of this relation for spin foam models. This is done on different levels of the discretisation / triangulation, ranging from few simplices up to the continuum limit. In the regime of very few simplices we confirm and deepen the connection of spin foam models to discrete gravity. Moreover, we discuss dynamical, e.g. diffeomorphism invariance in the discrete, to fix the ambiguities of the models. In order to satisfy these conditions, the discrete models have to be improved in a renormalisation procedure, which also allows us to study their continuum dynamics. Applied to simplified spin foam models, we uncover a rich, non--trivial fixed point structure, which we summarize in a phase diagram. Inspired by these methods, we propose a method to consistently construct the continuum theory, which comes with a unique vacuum state.}, language = {en} } @phdthesis{Stanke2000, author = {Stanke, Thomas}, title = {An unbiased infrared H2 search for embedded flows from young stars in Orion A}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-0000076}, school = {Universit{\"a}t Potsdam}, year = {2000}, abstract = {Gasausstr{\"o}mungen, oft in der Form hoch kollimierter Jets, sind ein allgegenw{\"a}rtiges Ph{\"a}nomen bei der Geburt neuer Sterne. Emission von stossangeregtem molekularem Wasserstoff bei Wellenl{\"a}ngen im nahen Infrarotbereich ist ein Merkmal ihrer Existenz und auch in eingebetteten, im Optischen obskurierten Ausstr{\"o}mungen generell gut zu beobachten. In dieser Arbeit werden die Resultate einer von Auswahleffekten freien, empfindlichen, grossfl{\"a}chigen Suche nach solchen Ausstr{\"o}mungen von Protosternen in der v=1-0 S(1) Linie molekularen Wasserstoffs bei einer Wellenl{\"a}nge von 2.12 µm vorgestellt. Die Durchmusterung umfasst eine Fl{\"a}che von etwa einem Quadratgrad in der Orion A Riesenmolek{\"u}lwolke. Weitere Daten aus einem grossen Wellenl{\"a}ngenbereich werden benutzt, um die Quellen der Ausstr{\"o}mungen zu identifizieren. Das Ziel dieser Arbeit ist es, eine Stichprobe von Ausstr{\"o}mungen zu bekommen, die so weit wie m{\"o}glich frei von Auswahleffekten ist, um die typischen Eigenschaften protostellarer Ausstr{\"o}mungen und deren Entwicklung festzustellen, sowie um die R{\"u}ckwirkung der Ausstr{\"o}mungen auf die umgebende Wolke zu untersuchen. Das erste Ergebnis ist, dass Ausstr{\"o}mungen in Sternentstehungsgebieten tats{\"a}chlich sehr h{\"a}ufig sind: mehr als 70 Jet-Kandidaten werden identifiziert. Die meisten zeigen eine sehr irregul{\"a}re Morphologie anstelle regul{\"a}rer oder symmetrischer Strukturen. Dies ist auf das turbulente, klumpige Medium zur{\"u}ckzuf{\"u}hren, in das sich die Jets hineinbewegen. Die Ausrichtung der Jets ist zuf{\"a}llig verteilt. Insbesondere gibt es keine bevorzugte Ausrichtung der Jets parallel zum grossr{\"a}umigen Magnetfeld in der Wolke. Das legt nahe, dass die Rotations- und Symmetrieachse in einem protostellaren System durch zuf{\"a}llige, turbulente Bewegung in der Wolke bestimmt wird. M{\"o}gliche Ausstr{\"o}mungsquellen werden f{\"u}r 49 Jets identifiziert; f{\"u}r diese wird der Entwicklungsstand und die bolometrische Leuchtkraft abgesch{\"a}tzt. Die Jetl{\"a}nge und die H2 Leuchtkraft entwickeln sich gemeinsam mit der Ausstr{\"o}mungsquelle. Von null startend, dehnen sich die Jets schnell bis auf eine L{\"a}nge von einigen Parsec aus und werden dann langsam wieder k{\"u}rzer. Sie sind zuerst sehr leuchtkr{\"a}ftig, die H2 Helligkeit nimmt aber im Lauf der protostellaren Entwicklung ab. Die L{\"a}ngen- und H2 Leuchtkraftentwicklung l{\"a}sst sich im Wesentlichen durch eine zuerst sehr hohe, dann niedriger werdende Massenausflussrate erkl{\"a}ren, die auf eine zuerst sehr hohe, dann niedriger werdende Gasakkretionsrate auf den Protostern schliessen l{\"a}sst (Akkretion und Ejektion sind eng verkn{\"u}pft!). Die L{\"a}ngenabnahme der Jets erfordert eine st{\"a}ndig wirkende Abbremsung der Jets. Ein einfaches Modell einer simultanen Entwicklung eines Protosterns, seiner zirkumstellaren Umgebung und seiner Ausstr{\"o}mung (Smith 2000) kann die gemessenen H2- und bolometrischen Leuchtkr{\"a}fte der Jets und ihrer Quellen reproduzieren, unter der Annahme, dass die starke Akkretionsaktivit{\"a}t zu Beginn der protostellaren Entwicklung mit einer {\"u}berproportional hohen Massenausflussrate verbunden ist. Im Durchmusterungsgebiet sind 125 dichte Molek{\"u}lwolkenkerne bekannt (Tatematsu et al. 1993). Jets (bzw. Sterne) entstehen in ruhigen Wolkenkernen, d.h. solchen mit einem niedrigen Verh{\"a}ltnis von interner kinetischer Energie zu gravitativer potentieller Energie; dies sind die Wolkenkerne h{\"o}herer Masse. Die Wolkenkerne mit Jets haben im Mittel gr{\"o}ssere Linienbreiten als die ohne Jets. Dies ist darauf zur{\"u}ckzuf{\"u}hren, dass sie bevorzugt in den massereicheren Wolkenkernen zu finden sind, welche generell eine gr{\"o}ssere Linienbreite haben. Es gibt keinen Hinweis auf st{\"a}rkere interne Bewegungen in Wolkenkernen mit Jets, die durch eine Wechselwirkung der Jets mit den Wolkenkernen erzeugt sein k{\"o}nnte. Es gibt, wie von der Theorie vorausgesagt, eine Beziehung zwischen der Linienbreite der Wolkenkerne und der H2 Leuchtkraft der Jets, wenn Jets von Klasse 0 und Klasse I Protosternen separat betrachtet werden; dabei sind Klasse 0 Jets leuchtkr{\"a}ftiger als Klasse I Jets, was ebenfalls auf eine zeitabh{\"a}ngige Akkretionsrate mit einer fr{\"u}hzeitigen Spitze und einem darauffolgenden Abklingen hinweist. Schliesslich wird die R{\"u}ckwirkung der Jetpopulation auf eine Molek{\"u}lwolke unter der Annahme strikter Vorw{\"a}rtsimpulserhaltung betrachtet. Die Jets k{\"o}nnen auf der Skala einer ganzen Riesenmolek{\"u}lwolke und auf den Skalen von Molek{\"u}lwolkenkernen nicht gen{\"u}gend Impuls liefern, um die abklingende Turbulenz wieder anzuregen. Auf der mittleren Skala von molekularen Klumpen, mit einer Gr{\"o}sse von einigen parsec und Massen von einigen hundert Sonnenmassen liefern die Jets jedoch gen{\"u}gend Impuls in hinreichend kurzer Zeit, um die Turbulenz "am Leben zu erhalten" und k{\"o}nnen damit helfen, einen Klumpen gegen seinen Kollaps zu stabilisieren.}, language = {de} } @phdthesis{Stange2024, author = {Stange, Maike}, title = {A study on Coronin-A and Aip1 function in motility of Dictyostelium discoideum and on Aip1 interchangeability between Dictyostelium discoideum and Arabidopsis thaliana}, doi = {10.25932/publishup-62856}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-628569}, school = {Universit{\"a}t Potsdam}, pages = {xiv, 168}, year = {2024}, abstract = {Actin is one of the most highly conserved proteins in eukaryotes and distinct actin-related proteins with filament-forming properties are even found in prokaryotes. Due to these commonalities, actin-modulating proteins of many species share similar structural properties and proposed functions. The polymerization and depolymerization of actin are critical processes for a cell as they can contribute to shape changes to adapt to its environment and to move and distribute nutrients and cellular components within the cell. However, to what extent functions of actin-binding proteins are conserved between distantly related species, has only been addressed in a few cases. In this work, functions of Coronin-A (CorA) and Actin-interacting protein 1 (Aip1), two proteins involved in actin dynamics, were characterized. In addition, the interchangeability and function of Aip1 were investigated in two phylogenetically distant model organisms. The flowering plant Arabidopsis thaliana (encoding two homologs, AIP1-1 and AIP1-2) and in the amoeba Dictyostelium discoideum (encoding one homolog, DdAip1) were chosen because the functions of their actin cytoskeletons may differ in many aspects. Functional analyses between species were conducted for AIP1 homologs as flowering plants do not harbor a CorA gene. In the first part of the study, the effect of four different mutation methods on the function of Coronin-A protein and the resulting phenotype in D. discoideum was revealed in two genetic knockouts, one RNAi knockdown and a sudden loss-of-function mutant created by chemical-induced dislocation (CID). The advantages and disadvantages of the different mutation methods on the motility, appearance and development of the amoebae were investigated, and the results showed that not all observed properties were affected with the same intensity. Remarkably, a new combination of Selection-Linked Integration and CID could be established. In the second and third parts of the thesis, the exchange of Aip1 between plant and amoeba was carried out. For A. thaliana, the two homologs (AIP1-1 and AIP1-2) were analyzed for functionality as well as in D. discoideum. In the Aip1-deficient amoeba, rescue with AIP1-1 was more effective than with AIP1-2. The main results in the plant showed that in the aip1-2 mutant background, reintroduced AIP1-2 displayed the most efficient rescue and A. thaliana AIP1-1 rescued better than DdAip1. The choice of the tagging site was important for the function of Aip1 as steric hindrance is a problem. The DdAip1 was less effective when tagged at the C-terminus, while the plant AIP1s showed mixed results depending on the tag position. In conclusion, the foreign proteins partially rescued phenotypes of mutant plants and mutant amoebae, despite the organisms only being very distantly related in evolutionary terms.}, language = {en} } @phdthesis{Stachlewska2005, author = {Stachlewska, Iwona Sylwia}, title = {Investigation of tropospheric arctic aerosol and mixed-phase clouds using airborne lidar technique}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-6984}, school = {Universit{\"a}t Potsdam}, year = {2005}, abstract = {An Airborne Mobile Aerosol Lidar (AMALi) was constructed and built at Alfred-Wegener-Institute for Polar and Marine Research (AWI) in Potsdam, Germany for the lower tropospheric aerosol and cloud research under tough arctic conditions. The system was successfully used during two AWI airborne field campaigns, ASTAR 2004 and SVALEX 2005, performed in vicinity of Spitsbergen in the Arctic. The novel evaluation schemes, the Two-Stream Inversion and the Iterative Airborne Inversion, were applied to the obtained lidar data. Thereby, calculation of the particle extinction and backscatter coefficient profiles with corresponding lidar ratio profiles characteristic for the arctic air was possible. The comparison of these lidar results with the results of other in-situ and remote instrumentation (ground based Koldewey Aerosol Raman Lidar (KARL), sunphotometer, radiosounding, satellite imagery) allowed to provided clean contra polluted (Arctic Haze) characteristics of the arctic aerosols. Moreover, the data interpretation by means of the ECMWF Operational Analyses and small-scale dispersion model EULAG allowed studying the effects of the Spitsbergens orography on the aerosol load in the Planetary Boundary Layer. With respect to the cloud studies a new methodology of alternated remote AMALi measurements with the airborne in-situ cloud optical and microphysical parameters measurements was proved feasible for the low density mixed-phase cloud studies. An example of such approach during observation of the natural cloud seeding (feeder-seeder phenomenon) with ice crystals precipitating into the lower supercooled stratocumulus deck were discussed in terms of the lidar signal intensity profiles and corresponding depolarisation ratio profiles. For parts of the cloud system characterised by almost negligible multiple scattering the calculation of the particle backscatter coefficient profiles was possible using the lidar ratio information obtained from the in-situ measurements in ice-crystal cloud and water cloud.}, subject = {Aerosol}, language = {en} } @phdthesis{Sposini2020, author = {Sposini, Vittoria}, title = {The random diffusivity approach for diffusion in heterogeneous systems}, doi = {10.25932/publishup-48780}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-487808}, school = {Universit{\"a}t Potsdam}, year = {2020}, abstract = {The two hallmark features of Brownian motion are the linear growth < x2(t)> = 2Ddt of the mean squared displacement (MSD) with diffusion coefficient D in d spatial dimensions, and the Gaussian distribution of displacements. With the increasing complexity of the studied systems deviations from these two central properties have been unveiled over the years. Recently, a large variety of systems have been reported in which the MSD exhibits the linear growth in time of Brownian (Fickian) transport, however, the distribution of displacements is pronouncedly non-Gaussian (Brownian yet non-Gaussian, BNG). A similar behaviour is also observed for viscoelastic-type motion where an anomalous trend of the MSD, i.e., ~ ta, is combined with a priori unexpected non-Gaussian distributions (anomalous yet non-Gaussian, ANG). This kind of behaviour observed in BNG and ANG diffusions has been related to the presence of heterogeneities in the systems and a common approach has been established to address it, that is, the random diffusivity approach. This dissertation explores extensively the field of random diffusivity models. Starting from a chronological description of all the main approaches used as an attempt of describing BNG and ANG diffusion, different mathematical methodologies are defined for the resolution and study of these models. The processes that are reported in this work can be classified in three subcategories, i) randomly-scaled Gaussian processes, ii) superstatistical models and iii) diffusing diffusivity models, all belonging to the more general class of random diffusivity models. Eventually, the study focuses more on BNG diffusion, which is by now well-established and relatively well-understood. Nevertheless, many examples are discussed for the description of ANG diffusion, in order to highlight the possible scenarios which are known so far for the study of this class of processes. The second part of the dissertation deals with the statistical analysis of random diffusivity processes. A general description based on the concept of moment-generating function is initially provided to obtain standard statistical properties of the models. Then, the discussion moves to the study of the power spectral analysis and the first passage statistics for some particular random diffusivity models. A comparison between the results coming from the random diffusivity approach and the ones for standard Brownian motion is discussed. In this way, a deeper physical understanding of the systems described by random diffusivity models is also outlined. To conclude, a discussion based on the possible origins of the heterogeneity is sketched, with the main goal of inferring which kind of systems can actually be described by the random diffusivity approach.}, language = {en} } @phdthesis{Sorce2014, author = {Sorce, Jenny}, title = {From Spitzer mid-infrared observations and measurements of peculiar velocities to constrained simulations of the local universe}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-72486}, school = {Universit{\"a}t Potsdam}, pages = {xx, 303}, year = {2014}, abstract = {Galaxies are observational probes to study the Large Scale Structure. Their gravitational motions are tracers of the total matter density and therefore of the Large Scale Structure. Besides, studies of structure formation and galaxy evolution rely on numerical cosmological simulations. Still, only one universe observable from a given position, in time and space, is available for comparisons with simulations. The related cosmic variance affects our ability to interpret the results. Simulations constrained by observational data are a perfect remedy to this problem. Achieving such simulations requires the projects Cosmic flows and CLUES. Cosmic flows builds catalogs of accurate distance measurements to map deviations from the expansion. These measures are mainly obtained with the galaxy luminosity-rotation rate correlation. We present the calibration of that relation in the mid-infrared with observational data from Spitzer Space Telescope. Resulting accurate distance estimates will be included in the third catalog of the project. In the meantime, two catalogs up to 30 and 150 Mpc/h have been released. We report improvements and applications of the CLUES' method on these two catalogs. The technique is based on the constrained realization algorithm. The cosmic displacement field is computed with the Zel'dovich approximation. This latter is then reversed to relocate reconstructed three-dimensional constraints to their precursors' positions in the initial field. The size of the second catalog (8000 galaxies within 150 Mpc/h) highlighted the importance of minimizing the observational biases. By carrying out tests on mock catalogs, built from cosmological simulations, a method to minimize observational bias can be derived. Finally, for the first time, cosmological simulations are constrained solely by peculiar velocities. The process is successful as resulting simulations resemble the Local Universe. The major attractors and voids are simulated at positions approaching observational positions by a few megaparsecs, thus reaching the limit imposed by the linear theory.}, language = {en} } @phdthesis{Sommerfeld2015, author = {Sommerfeld, Anja}, title = {Quantification of internal variability of the arctic summer atmosphere based on HIRHAM5 ensemble simulations}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-85347}, school = {Universit{\"a}t Potsdam}, pages = {VII, 110, vi}, year = {2015}, abstract = {The non-linear behaviour of the atmospheric dynamics is not well understood and makes the evaluation and usage of regional climate models (RCMs) difficult. Due to these non-linearities, chaos and internal variability (IV) within the RCMs are induced, leading to a sensitivity of RCMs to their initial conditions (IC). The IV is the ability of RCMs to realise different solutions of simulations that differ in their IC, but have the same lower and lateral boundary conditions (LBC), hence can be defined as the across-member spread between the ensemble members. For the investigation of the IV and the dynamical and diabatic contributions generating the IV four ensembles of RCM simulations are performed with the atmospheric regional model HIRHAM5. The integration area is the Arctic and each ensemble consists of 20 members. The ensembles cover the time period from July to September for the years 2006, 2007, 2009 and 2012. The ensemble members have the same LBC and differ in their IC only. The different IC are arranged by an initialisation time that shifts successively by six hours. Within each ensemble the first simulation starts on 1st July at 00 UTC and the last simulation starts on 5th July at 18 UTC and each simulation runs until 30th September. The analysed time period ranges from 6th July to 30th September, the time period that is covered by all ensemble members. The model runs without any nudging to allow a free development of each simulation to get the full internal variability within the HIRHAM5. As a measure of the model generated IV, the across-member standard deviation and the across-member variance is used and the dynamical and diabatic processes influencing the IV are estimated by applying a diagnostic budget study for the IV tendency of the potential temperature developed by Nikiema and Laprise [2010] and Nikiema and Laprise [2011]. The diagnostic budget study is based on the first law of thermodynamics for potential temperature and the mass-continuity equation. The resulting budget equation reveals seven contributions to the potential temperature IV tendency. As a first study, this work analyses the IV within the HIRHAM5. Therefore, atmospheric circulation parameters and the potential temperature for all four ensemble years are investigated. Similar to previous studies, the IV fluctuates strongly in time. Further, due to the fact that all ensemble members are forced with the same LBC, the IV depends on the vertical level within the troposphere, with high values in the lower troposphere and at 500 hPa and low values in the upper troposphere and at the surface. By the same reason, the spatial distribution shows low values of IV at the boundaries of the model domain. The diagnostic budget study for the IV tendency of potential temperature reveals that the seven contributions fluctuate in time like the IV. However, the individual terms reach different absolute magnitudes. The budget study identifies the horizontal and vertical 'baroclinic' terms as the main contributors to the IV tendency, with the horizontal 'baroclinic' term producing and the vertical 'baroclinic' term reducing the IV. The other terms fluctuate around zero, because they are small in general or are balanced due to the domain average. The comparison of the results obtained for the four different ensembles (summers 2006, 2007, 2009 and 2012) reveals that on average the findings for each ensemble are quite similar concerning the magnitude and the general pattern of IV and its contributions. However, near the surface a weaker IV is produced with decreasing sea ice extent. This is caused by a smaller impact of the horizontal 'baroclinic' term over some regions and by the changing diabatic processes, particularly a more intense reducing tendency of the IV due to condensative heating. However, it has to be emphasised that the behaviour of the IV and its dynamical and diabatic contributions are influenced mainly by complex atmospheric feedbacks and large-scale processes and not by the sea ice distribution. Additionally, a comparison with a second RCM covering the Arctic and using the same LBCs and IC is performed. For both models very similar results concerning the IV and its dynamical and diabatic contributions are found. Hence, this investigation leads to the conclusion that the IV is a natural phenomenon and is independent from the applied RCM.}, language = {en} } @phdthesis{Solopow2019, author = {Solopow, Sergej}, title = {Wavelength dependent demagnetization dynamics in Co2MnGa Heusler-alloy}, doi = {10.25932/publishup-42786}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-427860}, school = {Universit{\"a}t Potsdam}, pages = {91}, year = {2019}, abstract = {In dieser Arbeit haben wir ultraschnelle Entmagnetisierung an einer Heusler-Legierung untersucht. Es handelt sich um ein Halbmetall, das sich in einer ferromagnetischen Phase befindet. Die Besonderheit dieses Materials besteht im Aufbau einer Bandstruktur. Diese bildet Zustandsdichten, in der die Majorit{\"a}tselektronen eine metallische B{\"a}nderbildung aufweisen und die Minorit{\"a}tselektronen eine Bandl{\"u}cke in der N{\"a}he des Fermi-Niveaus aufweisen, das dem Aufbau eines Halbleiters entspricht. Mit Hilfe der Pump-Probe-Experimente haben wir zeitaufgel{\"o}ste Messungen durchgef{\"u}hrt. F{\"u}r das Pumpen wurden ultrakurze Laserpulse mit einer Pulsdauer von 100 fs benutzt. Wir haben dabei zwei verschiedene Wellenl{\"a}ngen mit 400 nm und 1240 nm benutzt, um den Effekt der Prim{\"a}ranregung und der Bandl{\"u}cke in den Minorit{\"a}tszust{\"a}nden zu untersuchen. Dabei wurde zum ersten Mal OPA (Optical Parametrical Amplifier) f{\"u}r die Erzeugung der langwelligen Pulse an der FEMTOSPEX-Beamline getestet und erfolgreich bei den Experimenten verwendet. Wir haben Wellenl{\"a}ngen bedingte Unterschiede in der Entmagnetisierungszeit gemessen. Mit der Erh{\"o}hung der Photonenenergie ist der Prozess der Entmagnetisierung deutlich schneller als bei einer niedrigeren Photonenenergie. Wir verkn{\"u}pften diese Ergebnisse mit der Existenz der Energiel{\"u}cke f{\"u}r Minorit{\"a}tselektronen. Mit Hilfe lokaler Elliot-Yafet-Streuprozesse k{\"o}nnen die beobachteten Zeiten gut erkl{\"a}rt werden. Wir haben in dieser Arbeit auch eine neue Probe-Methode f{\"u}r die Magnetisierung angewandt und somit experimentell deren Effektivit{\"a}t, n{\"a}mlich XMCD in Refletiongeometry, best{\"a}tigen k{\"o}nnen. Statische Experimente liefern somit deutliche Indizien daf{\"u}r, dass eine magnetische von einer rein elektronischen Antwort des Systems getrennt werden kann. Unter der Voraussetzung, dass die Photonenenergie der R{\"o}ntgenstrahlung auf die L3 Kante des entsprechenden Elements eingestellt, ein geeigneter Einfallswinkel gew{\"a}hlt und die zirkulare Polarisation fixiert wird, ist es m{\"o}glich, diese Methode zur Analyse magnetischer und elektronischer Respons anzuwenden.}, language = {en} } @phdthesis{Smirnov2023, author = {Smirnov, Artem}, title = {Understanding the dynamics of the near-earth space environment utilizing long-term satellite observations}, doi = {10.25932/publishup-61371}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-613711}, school = {Universit{\"a}t Potsdam}, pages = {xxxvi, 286}, year = {2023}, abstract = {The near-Earth space environment is a highly complex system comprised of several regions and particle populations hazardous to satellite operations. The trapped particles in the radiation belts and ring current can cause significant damage to satellites during space weather events, due to deep dielectric and surface charging. Closer to Earth is another important region, the ionosphere, which delays the propagation of radio signals and can adversely affect navigation and positioning. In response to fluctuations in solar and geomagnetic activity, both the inner-magnetospheric and ionospheric populations can undergo drastic and sudden changes within minutes to hours, which creates a challenge for predicting their behavior. Given the increasing reliance of our society on satellite technology, improving our understanding and modeling of these populations is a matter of paramount importance. In recent years, numerous spacecraft have been launched to study the dynamics of particle populations in the near-Earth space, transforming it into a data-rich environment. To extract valuable insights from the abundance of available observations, it is crucial to employ advanced modeling techniques, and machine learning methods are among the most powerful approaches available. This dissertation employs long-term satellite observations to analyze the processes that drive particle dynamics, and builds interdisciplinary links between space physics and machine learning by developing new state-of-the-art models of the inner-magnetospheric and ionospheric particle dynamics. The first aim of this thesis is to investigate the behavior of electrons in Earth's radiation belts and ring current. Using ~18 years of electron flux observations from the Global Positioning System (GPS), we developed the first machine learning model of hundreds-of-keV electron flux at Medium Earth Orbit (MEO) that is driven solely by solar wind and geomagnetic indices and does not require auxiliary flux measurements as inputs. We then proceeded to analyze the directional distributions of electrons, and for the first time, used Fourier sine series to fit electron pitch angle distributions (PADs) in Earth's inner magnetosphere. We performed a superposed epoch analysis of 129 geomagnetic storms during the Van Allen Probes era and demonstrated that electron PADs have a strong energy-dependent response to geomagnetic activity. Additionally, we showed that the solar wind dynamic pressure could be used as a good predictor of the PAD dynamics. Using the observed dependencies, we created the first PAD model with a continuous dependence on L, magnetic local time (MLT) and activity, and developed two techniques to reconstruct near-equatorial electron flux observations from low-PA data using this model. The second objective of this thesis is to develop a novel model of the topside ionosphere. To achieve this goal, we collected observations from five of the most widely used ionospheric missions and intercalibrated these data sets. This allowed us to use these data jointly for model development, validation, and comparison with other existing empirical models. We demonstrated, for the first time, that ion density observations by Swarm Langmuir Probes exhibit overestimation (up to ~40-50\%) at low and mid-latitudes on the night side, and suggested that the influence of light ions could be a potential cause of this overestimation. To develop the topside model, we used 19 years of radio occultation (RO) electron density profiles, which were fitted with a Chapman function with a linear dependence of scale height on altitude. This approximation yields 4 parameters, namely the peak density and height of the F2-layer and the slope and intercept of the linear scale height trend, which were modeled using feedforward neural networks (NNs). The model was extensively validated against both RO and in-situ observations and was found to outperform the International Reference Ionosphere (IRI) model by up to an order of magnitude. Our analysis showed that the most substantial deviations of the IRI model from the data occur at altitudes of 100-200 km above the F2-layer peak. The developed NN-based ionospheric model reproduces the effects of various physical mechanisms observed in the topside ionosphere and provides highly accurate electron density predictions. This dissertation provides an extensive study of geospace dynamics, and the main results of this work contribute to the improvement of models of plasma populations in the near-Earth space environment.}, language = {en} } @phdthesis{Shenar2017, author = {Shenar, Tomer}, title = {Comprehensive analyses of massive binaries and implications on stellar evolution}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-104857}, school = {Universit{\"a}t Potsdam}, pages = {187}, year = {2017}, abstract = {Via their powerful radiation, stellar winds, and supernova explosions, massive stars (Mini \& 8 M☉) bear a tremendous impact on galactic evolution. It became clear in recent decades that the majority of massive stars reside in binary systems. This thesis sets as a goal to quantify the impact of binarity (i.e., the presence of a companion star) on massive stars. For this purpose, massive binary systems in the Local Group, including OB-type binaries, high mass X-ray binaries (HMXBs), and Wolf-Rayet (WR) binaries, were investigated by means of spectral, orbital, and evolutionary analyses. The spectral analyses were performed with the non-local thermodynamic equillibrium (non-LTE) Potsdam Wolf-Rayet (PoWR) model atmosphere code. Thanks to critical updates in the calculation of the hydrostatic layers, the code became a state-of-the-art tool applicable for all types of hot massive stars (Chapter 2). The eclipsing OB-type triple system δ Ori served as an intriguing test-case for the new version of the PoWR code, and provided key insights regarding the formation of X-rays in massive stars (Chapter 3). We further analyzed two prototypical HMXBs, Vela X-1 and IGR J17544-2619, and obtained fundamental conclusions regarding the dichotomy of two basic classes of HMXBs (Chapter 4). We performed an exhaustive analysis of the binary R 145 in the Large Magellanic Cloud (LMC), which was claimed to host the most massive stars known. We were able to disentangle the spectrum of the system, and performed an orbital, polarimetric, and spectral analysis, as well as an analysis of the wind-wind collision region. The true masses of the binary components turned out to be significantly lower than suggested, impacting our understanding of the initial mass function and stellar evolution at low metallicity (Chapter 5). Finally, all known WR binaries in the Small Magellanic Cloud (SMC) were analyzed. Although it was theoretical predicted that virtually all WR stars in the SMC should be formed via mass-transfer in binaries, we find that binarity was not important for the formation of the known WR stars in the SMC, implying a strong discrepancy between theory and observations (Chapter 6).}, language = {en} } @phdthesis{Shaw2024, author = {Shaw, Vasundhara}, title = {Cosmic-ray transport and signatures in their local environment}, doi = {10.25932/publishup-62019}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-620198}, school = {Universit{\"a}t Potsdam}, pages = {143}, year = {2024}, abstract = {The origin and structure of magnetic fields in the Galaxy are largely unknown. What is known is that they are essential for several astrophysical processes, in particular the propagation of cosmic rays. Our ability to describe the propagation of cosmic rays through the Galaxy is severely limited by the lack of observational data needed to probe the structure of the Galactic magnetic field on many different length scales. This is particularly true for modelling the propagation of cosmic rays into the Galactic halo, where our knowledge of the magnetic field is particularly poor. In the last decade, observations of the Galactic halo in different frequency regimes have revealed the existence of out-of-plane bubble emission in the Galactic halo. In gamma rays these bubbles have been termed Fermi bubbles with a radial extent of ≈ 3 kpc and an azimuthal height of ≈ 6 kpc. The radio counterparts of the Fermi bubbles were seen by both the S-PASS telescopes and the Planck satellite, and showed a clear spatial overlap. The X-ray counterparts of the Fermi bubbles were named eROSITA bubbles after the eROSITA satellite, with a radial width of ≈ 7 kpc and an azimuthal height of ≈ 14 kpc. Taken together, these observations suggest the presence of large extended Galactic Halo Bubbles (GHB) and have stimulated interest in exploring the less explored Galactic halo. In this thesis, a new toy model (GHB model) for the magnetic field and non-thermal electron distribution in the Galactic halo has been proposed. The new toy model has been used to produce polarised synchrotron emission sky maps. Chi-square analysis was used to compare the synthetic skymaps with the Planck 30 GHz polarised skymaps. The obtained constraints on the strength and azimuthal height were found to be in agreement with the S-PASS radio observations. The upper, lower and best-fit values obtained from the above chi-squared analysis were used to generate three separate toy models. These three models were used to propagate ultra-high energy cosmic rays. This study was carried out for two potential sources, Centaurus A and NGC 253, to produce magnification maps and arrival direction skymaps. The simulated arrival direction skymaps were found to be consistent with the hotspots of Centaurus A and NGC 253 as seen in the observed arrival direction skymaps provided by the Pierre Auger Observatory (PAO). The turbulent magnetic field component of the GHB model was also used to investigate the extragalactic dipole suppression seen by PAO. UHECRs with an extragalactic dipole were forward-tracked through the turbulent GHB model at different field strengths. The suppression in the dipole due to the varying diffusion coefficient from the simulations was noted. The results could also be compared with an analytical analogy of electrostatics. The simulations of the extragalactic dipole suppression were in agreement with similar studies carried out for galactic cosmic rays.}, language = {en} } @phdthesis{Sempf2005, author = {Sempf, Mario}, title = {Nichtlineare Dynamik atmosph{\"a}rischer Zirkulationsregime in einem idealisierten Modell}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-5989}, school = {Universit{\"a}t Potsdam}, year = {2005}, abstract = {Unter atmosph{\"a}rischen Zirkulationsregimen versteht man bevorzugte quasi-station{\"a}re Zust{\"a}nde der atmosph{\"a}rischen Zirkulation auf der planetaren Skala, die f{\"u}r eine bis mehrere Wochen persistieren k{\"o}nnen. Klima{\"a}nderungen, ob nat{\"u}rlich entstanden oder anthropogen verursacht, {\"a}ußern sich in erster Linie durch {\"A}nderungen der Auftrittswahrscheinlichkeiten der nat{\"u}rlichen Regime. In der vorliegenden Arbeit wurden dynamische Mechanismen des Regimeverhaltens und der dekadischen Klimavariabilit{\"a}t der Atmosph{\"a}re bei Abwesenheit zeitlich ver{\"a}nderlicher externer Einflussfaktoren untersucht. Das Hauptwerkzeug daf{\"u}r war ein quasi-geostrophisches Dreischichtenmodell der winterlichen atmosph{\"a}rischen Zirkulation auf der Nordhemisph{\"a}re, das eine spektrale T21-Aufl{\"o}sung, einen orographischen und einen zeitlich konstanten thermischen Antrieb mit nicht-zonalen Anteilen besitzt. Ein solches Modell vermag großskalige atmosph{\"a}rische Str{\"o}mungsvorg{\"a}nge außerhalb der Tropen mit einiger Genauigkeit zu simulieren. Nicht ber{\"u}cksichtigt werden Feuchteprozesse, die Wechselwirkung der Atmosph{\"a}re mit anderen Teilen des Klimasystems sowie anthropogene Einfl{\"u}sse. F{\"u}r das Dreischichtenmodell wurde ein automatisiertes, iteratives Verfahren zur Anpassung des thermischen Modellantriebs neu entwickelt. Jede Iteration des Verfahrens besteht aus einer Testintegration des Modells, ihrer Auswertung, dem Vergleich der Ergebnisse mit den NCEP-NCAR-Reanalysedaten aus den Wintermonaten Dezember, Januar und Februar sowie einer auf diesem Vergleich basierenden Antriebskorrektur. Nach Konvergenz des Verfahrens stimmt das Modell sowohl bez{\"u}glich des zonal gemittelten Klimazustandes als auch bez{\"u}glich der zeitgemittelten nicht-zonalen außertropischen diabatischen Erw{\"a}rmung nahezu perfekt mit den wintergemittelten Reanalysedaten {\"u}berein. In einer 1000-j{\"a}hrigen Simulation wurden die beobachtete mittlere Zirkulation im Winter sowie ihre Variabilit{\"a}t realit{\"a}tsnah reproduziert, insbesondere die Arktische Oszillation (AO) und ihre vertikale Ausdehnung. Der AO-Index des Modells weist deutliche dekadische Schwankungen auf, die allein durch die interne Modelldynamik bedingt sind. Dar{\"u}ber hinaus zeigt das Modell ein Regimeverhalten, das gut mit den Beobachtungsdaten {\"u}bereintimmt. Es besitzt ein Regime, das in etwa der negativen Phase der Nordatlantischen Oszillation (NAO) entspricht und eines, das der positiven Phase der AO {\"a}hnelt. Eine weit verbreitete Hypothese ist die n{\"a}herungsweise {\"U}bereinstimmung zwischen Regimen und station{\"a}ren L{\"o}sungen der Bewegungsgleichungen. In der vorliegenden Arbeit wurde diese Hypothese f{\"u}r das Dreischichtenmodell {\"u}berpr{\"u}ft, mit negativem Resultat. Es wurden mittels eines Funktionalminimierungsverfahrens sechs verschiedene station{\"a}re Zust{\"a}nde gefunden. Diese sind allesamt durch eine {\"a}ußerst unrealistische Zirkulation gekennzeichnet und sind daher weit vom Modellattraktor entfernt. F{\"u}nf der sechs Zust{\"a}nde zeichnen sich durch einen extrem starken subtropischen Jet in der mittleren und obereren Modellschicht aus. Da die Ursache des Regimeverhaltens des Dreischichtenmodells nach wie vor unklar war, wurde auf ein einfacheres Modell, n{\"a}mlich ein barotropes Modell mit T21-Aufl{\"o}sung zur{\"u}ckgegriffen. F{\"u}r die Anpassung des Oberfl{\"a}chenantriebs wurde eine modifizierte Form der iterativen Prozedur verwendet. Die zeitgemittelte Zirkulation des barotropen Modells stimmt sehr gut mit der zeitlich und vertikal gemittelten Zirkulation des Dreischichtenmodells {\"u}berein. Das dominierende r{\"a}umliche Muster der Variabilit{\"a}t besitzt eine AO-{\"a}hnliche Struktur. Zudem besitzt das barotrope Modell zwei Regime, die n{\"a}herungsweise der positiven und negativen Phase der AO entsprechen und somit auch den Regimen des Dreischichtenmodells {\"a}hneln. Im Verlauf der Justierung des Oberfl{\"a}chenantriebs konnte beobachtet werden, dass die zwei Regime des barotropen Modells durch die Vereinigung zweier koexistierender Attraktoren entstanden. Der wahrscheinliche Mechanismus der Attraktorvereinigung ist eine Randkrise eines der beiden Attraktoren, gefolgt von einer explosiven Bifurkation des anderen Attraktors. Es wird die Hypothese aufgestellt, dass der beim barotropen Modell vorgefundene Mechanismus der Regimeentstehung f{\"u}r atmosph{\"a}rische Zirkulationsmodelle mit realit{\"a}tsnahem Regimeverhalten Allgemeing{\"u}ltigkeit besitzt. Gest{\"u}tzt wird die Hypothese durch vier Experimente mit dem Dreischichtenmodell, bei denen jeweils der Parameter der Bodenreibung verringert und die Antriebsanpassung wiederholt wurde. Bei diesen Experimenten erh{\"o}hte sich die Persistenz und die Separiertheit der Regime bei abnehmender Reibung drastisch und damit auch der Anteil dekadischer Zeitskalen an der Variabilit{\"a}t. Die Zunahme der Persistenz der Regime ist charakteristisch f{\"u}r die Ann{\"a}herung an eine inverse innere Krise, deren Existenz aber nicht nachgewiesen werden konnte.}, subject = {Nichtlineare Dynamik}, language = {de} } @phdthesis{Seewald2011, author = {Seewald, Gunter}, title = {Lineare und nichtlineare optische Untersuchungen am synthetischen Eumelanin und Entwicklung eines Kaskadenmodells}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-59967}, school = {Universit{\"a}t Potsdam}, year = {2011}, abstract = {Eumelanin ist ein Fluorophor mit teilweise recht ungew{\"o}hnlichen spektralen Eigenschaften. Unter anderem konnten in fr{\"u}heren Ver{\"o}ffentlichungen Unterschiede zwischen dem 1- und 2-photonen-angeregtem Fluoreszenzspektrum beobachtet werden, weshalb im nichtlinearen Anregungsfall ein schrittweiser Anregungsprozess vermutet wurde. Um diese und weitere optische Eigenschaften des Eumelanins besser zu verstehen, wurden in der vorliegenden Arbeit vielf{\"a}ltige messmethodische Ans{\"a}tze der linearen und nichtlinearen Optik an synthetischem Eumelanin in 0,1M NaOH verfolgt. Aus den Ergebnissen wurde ein Modell abgeleitet, welches die beobachteten photonischen Eigenschaften konsistent beschreibt. In diesem kaskadierten Zustandsmodell (Kaskaden-Modell) wird die aufgenommene Photonenenergie schrittweise von Anregungszust{\"a}nden hoher {\"U}bergangsenergien zu Anregungszust{\"a}nden niedrigerer {\"U}bergangsenergien transferiert. Messungen der transienten Absorption ergaben dominante Anteile mit kurzen Lebensdauern im ps-Bereich und ließen damit auf eine hohe Relaxationsgeschwindigkeit entlang der Kaskade schließen. Durch Untersuchung der nichtlinear angeregten Fluoreszenz von verschieden großen Eumelanin-Aggregaten konnte gezeigt werden, dass Unterschiede zwischen dem linear und nichtlinear angeregten Fluoreszenzspektrum nicht nur durch einen schrittweisen Anregungsprozess bei nichtlinearer Anregung sondern auch durch Unterschiede in den Verh{\"a}ltnissen der Quantenausbeuten zwischen kleinen und großen Aggregaten beim Wechsel von linearer zu nichtlinearer Anregung begr{\"u}ndet sein k{\"o}nnen. Durch Bestimmung des Anregungswirkungsquerschnitts und der Anregungspulsdauer-Abh{\"a}ngigkeit der nichtlinear angeregten Fluoreszenz von Eumelanin konnte jedoch ein schrittweiser 2-Photonen-Anregungsprozess {\"u}ber einen Zwischenzustand mit Lebendsdauern im ps-Bereich nachgewiesen werden.}, language = {de} } @phdthesis{Seefeldt2008, author = {Seefeldt, Michael}, title = {Pikosekunden-Weißlichterzeugung in mikrostrukturierten Fasern unter Ausnutzung nichtlinear optischer Effekte}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, isbn = {978-3-940793-20-1}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-16461}, school = {Universit{\"a}t Potsdam}, pages = {x, 133}, year = {2008}, abstract = {Im Rahmen der vorliegenden Arbeit ist es erstmals gelungen, mit einem ps-Pumplaser (10 ps) Weißlicht mit einer spektralen Breite von mehr als einer optischen Oktave in einer mikrostrukturierten Faser (MSF) bei einer Pumpwellenl{\"a}nge von 1064 nm zu generieren. Es ließ sich, abgesehen von nichtkonvertierten Resten der Pumpstrahlung, ein unstrukturiertes und zeitlich stabiles Weißlichtspektrum von 700 nm bis 1650 nm generieren. Die maximale Ausgangsleistung dieser Weißlichtstrahlung betrug 3,1 W. Es konnten sehr gute Einkoppeleffizienzen von maximal 62 \% erzielt werden. Die an der Weißlichterzeugung beteiligten dispersiven und nichtlinear optischen Effekte, wie z.B. Selbstphasenmodulation, Vierwellenmischung, Modulationsinstabilit{\"a}ten oder Solitoneneffekte, werden detailliert theoretisch untersucht und erl{\"a}utert. Die Arbeit beinhaltet ebenfalls eine umfangreiche Beschreibung der Wirkungsweise und Eigenschaften von mikrostrukturierten Fasern mit einem festen Faserkern. Aufgrund der großen Variationsvielfalt des mikrostrukturierten Fasermantels und der damit verbundenen Wellenleitereigenschaften ergeben sich, insbesondere f{\"u}r die Anwendung in der nichtlinearen Optik, eine Reihe von interessanten Eigenschaften. Es wurden insgesamt vier verschiedene mikrostrukturierte Fasern experimentell untersucht. F{\"u}r die Interpretation der experimentellen Ergebnisse ist die Pulsausbreitung der ps-Pumppulse in einer dispersiven, nichtlinear optischen Faser anhand der verallgemeinerten nichtlinearen Schr{\"o}dinger-Gleichung berechnet worden. Durch einen Vergleich der Berechnungen mit den Messdaten ließen sich verst{\"a}rkte Modulationsinstabilit{\"a}ten und verschiedene Solitoneneffekte als haupts{\"a}chlich f{\"u}r die Weißlichterzeugung bei ps-Anregungspulsen verantwortlich identifizieren. Auf der Basis der durchgef{\"u}hrten Untersuchungen wurde in Kooperation mit der Fa. Jenoptik Laser, Optik, Systeme GmbH eine kompakte und leistungsstarke Weißlichtquelle entwickelt. Diese wurde erfolgreich in einer Koh{\"a}renztomographiemessung (Optical Coherence Tomography - OCT) getestet: Es konnte in ex vivo-Untersuchungen gezeigt werden, dass sich mit dieser ps-Weißlichtquelle eine hohe Eindringtiefe von ca. 400 µm in die Netzhaut eines Affen erreichen l{\"a}sst.}, language = {de} } @phdthesis{Schuermann2017, author = {Sch{\"u}rmann, Robin Mathis}, title = {Interaction of the potential DNA-radiosensitizer 8-bromoadenine with free and plasmonically generated electrons}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-407017}, school = {Universit{\"a}t Potsdam}, pages = {xi, 120}, year = {2017}, abstract = {In Germany more than 200.000 persons die of cancer every year, which makes it the second most common cause of death. Chemotherapy and radiation therapy are often combined to exploit a supra-additive effect, as some chemotherapeutic agents like halogenated nucleobases sensitize the cancerous tissue to radiation. The radiosensitizing action of certain therapeutic agents can be at least partly assigned to their interaction with secondary low energy electrons (LEEs) that are generated along the track of the ionizing radiation. In the therapy of cancer DNA is an important target, as severe DNA damage like double strand breaks induce the cell death. As there is only a limited number of radiosensitizing agents in clinical practice, which are often strongly cytotoxic, it would be beneficial to get a deeper understanding of the interaction of less toxic potential radiosensitizers with secondary reactive species like LEEs. Beyond that LEEs can be generated by laser illuminated nanoparticles that are applied in photothermal therapy (PTT) of cancer, which is an attempt to treat cancer by an increase of temperature in the cells. However, the application of halogenated nucleobases in PTT has not been taken into account so far. In this thesis the interaction of the potential radiosensitizer 8-bromoadenine (8BrA) with LEEs was studied. In a first step the dissociative electron attachment (DEA) in the gas phase was studied in a crossed electron-molecular beam setup. The main fragmentation pathway was revealed as the cleavage of the C-Br bond. The formation of a stable parent anion was observed for electron energies around 0 eV. Furthermore, DNA origami nanostructures were used as platformed to determine electron induced strand break cross sections of 8BrA sensitized oligonucleotides and the corresponding nonsensitized sequence as a function of the electron energy. In this way the influence of the DEA resonances observed for the free molecules on the DNA strand breaks was examined. As the surrounding medium influences the DEA, pulsed laser illuminated gold nanoparticles (AuNPs) were used as a nanoscale electron source in an aqueous environment. The dissociation of brominated and native nucleobases was tracked with UV-Vis absorption spectroscopy and the generated fragments were identified with surface enhanced Raman scattering (SERS). Beside the electron induced damage, nucleobase analogues are decomposed in the vicinity of the laser illuminatednanoparticles due to the high temperatures. In order to get a deeper understanding of the different dissociation mechanisms, the thermal decomposition of the nucleobases in these systems was studied and the influence of the adsorption kinetics of the molecules was elucidated. In addition to the pulsed laser experiments, a dissociative electron transfer from plasmonically generated "hot electrons" to 8BrA was observed under low energy continuous wave laser illumination and tracked with SERS. The reaction was studied on AgNPs and AuNPs as a function of the laser intensity and wavelength. On dried samples the dissociation of the molecule was described by fractal like kinetics. In solution, the dissociative electron transfer was observed as well. It turned out that the timescale of the reaction rates were slightly below typical integration times of Raman spectra. In consequence such reactions need to be taken into account in the interpretation of SERS spectra of electrophilic molecules. The findings in this thesis help to understand the interaction of brominated nucleobases with plasmonically generated electrons and free electrons. This might help to evaluate the potential radiosensitizing action of such molecules in cancer radiation therapy and PTT.}, language = {en} } @phdthesis{Schwabedal2010, author = {Schwabedal, Justus Tilmann Caspar}, title = {Phase dynamics of irregular oscillations}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-50115}, school = {Universit{\"a}t Potsdam}, year = {2010}, abstract = {In der vorliegenden Dissertation wird eine Beschreibung der Phasendynamik irregul{\"a}rer Oszillationen und deren Wechselwirkungen vorgestellt. Hierbei werden chaotische und stochastische Oszillationen autonomer dissipativer Systeme betrachtet. F{\"u}r eine Phasenbeschreibung stochastischer Oszillationen m{\"u}ssen zum einen unterschiedliche Werte der Phase zueinander in Beziehung gesetzt werden, um ihre Dynamik unabh{\"a}ngig von der gew{\"a}hlten Parametrisierung der Oszillation beschreiben zu k{\"o}nnen. Zum anderen m{\"u}ssen f{\"u}r stochastische und chaotische Oszillationen diejenigen Systemzust{\"a}nde identifiziert werden, die sich in der gleichen Phase befinden. Im Rahmen dieser Dissertation werden die Werte der Phase {\"u}ber eine gemittelte Phasengeschwindigkeitsfunktion miteinander in Beziehung gesetzt. F{\"u}r stochastische Oszillationen sind jedoch verschiedene Definitionen der mittleren Geschwindigkeit m{\"o}glich. Um die Unterschiede der Geschwindigkeitsdefinitionen besser zu verstehen, werden auf ihrer Basis effektive deterministische Modelle der Oszillationen konstruiert. Hierbei zeigt sich, dass die Modelle unterschiedliche Oszillationseigenschaften, wie z. B. die mittlere Frequenz oder die invariante Wahrscheinlichkeitsverteilung, nachahmen. Je nach Anwendung stellt die effektive Phasengeschwindigkeitsfunktion eines speziellen Modells eine zweckm{\"a}ßige Phasenbeziehung her. Wie anhand einfacher Beispiele erkl{\"a}rt wird, kann so die Theorie der effektiven Phasendynamik auch kontinuierlich und pulsartig wechselwirkende stochastische Oszillationen beschreiben. Weiterhin wird ein Kriterium f{\"u}r die invariante Identifikation von Zust{\"a}nden gleicher Phase irregul{\"a}rer Oszillationen zu sogenannten generalisierten Isophasen beschrieben: Die Zust{\"a}nde einer solchen Isophase sollen in ihrer dynamischen Entwicklung ununterscheidbar werden. F{\"u}r stochastische Oszillationen wird dieses Kriterium in einem mittleren Sinne interpretiert. Wie anhand von Beispielen demonstriert wird, lassen sich so verschiedene Typen stochastischer Oszillationen in einheitlicher Weise auf eine stochastische Phasendynamik reduzieren. Mit Hilfe eines numerischen Algorithmus zur Sch{\"a}tzung der Isophasen aus Daten wird die Anwendbarkeit der Theorie anhand eines Signals regelm{\"a}ßiger Atmung gezeigt. Weiterhin zeigt sich, dass das Kriterium der Phasenidentifikation f{\"u}r chaotische Oszillationen nur approximativ erf{\"u}llt werden kann. Anhand des R{\"o}ssleroszillators wird der tiefgreifende Zusammenhang zwischen approximativen Isophasen, chaotischer Phasendiffusion und instabilen periodischen Orbits dargelegt. Gemeinsam erm{\"o}glichen die Theorien der effektiven Phasendynamik und der generalisierten Isophasen eine umfassende und einheitliche Phasenbeschreibung irregul{\"a}rer Oszillationen.}, language = {de} } @phdthesis{Schulze2011, author = {Schulze, Andreas}, title = {Demographics of supermassive black holes}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-54464}, school = {Universit{\"a}t Potsdam}, year = {2011}, abstract = {Supermassive black holes are a fundamental component of the universe in general and of galaxies in particular. Almost every massive galaxy harbours a supermassive black hole (SMBH) in its center. Furthermore, there is a close connection between the growth of the SMBH and the evolution of its host galaxy, manifested in the relationship between the mass of the black hole and various properties of the galaxy's spheroid component, like its stellar velocity dispersion, luminosity or mass. Understanding this relationship and the growth of SMBHs is essential for our picture of galaxy formation and evolution. In this thesis, I make several contributions to improve our knowledge on the census of SMBHs and on the coevolution of black holes and galaxies. The first route I follow on this road is to obtain a complete census of the black hole population and its properties. Here, I focus particularly on active black holes, observable as Active Galactic Nuclei (AGN) or quasars. These are found in large surveys of the sky. In this thesis, I use one of these surveys, the Hamburg/ESO survey (HES), to study the AGN population in the local volume (z~0). The demographics of AGN are traditionally represented by the AGN luminosity function, the distribution function of AGN at a given luminosity. I determined the local (z<0.3) optical luminosity function of so-called type 1 AGN, based on the broad band B_J magnitudes and AGN broad Halpha emission line luminosities, free of contamination from the host galaxy. I combined this result with fainter data from the Sloan Digital Sky Survey (SDSS) and constructed the best current optical AGN luminosity function at z~0. The comparison of the luminosity function with higher redshifts supports the current notion of 'AGN downsizing', i.e. the space density of the most luminous AGN peaks at higher redshifts and the space density of less luminous AGN peaks at lower redshifts. However, the AGN luminosity function does not reveal the full picture of active black hole demographics. This requires knowledge of the physical quantities, foremost the black hole mass and the accretion rate of the black hole, and the respective distribution functions, the active black hole mass function and the Eddington ratio distribution function. I developed a method for an unbiased estimate of these two distribution functions, employing a maximum likelihood technique and fully account for the selection function. I used this method to determine the active black hole mass function and the Eddington ratio distribution function for the local universe from the HES. I found a wide intrinsic distribution of black hole accretion rates and black hole masses. The comparison of the local active black hole mass function with the local total black hole mass function reveals evidence for 'AGN downsizing', in the sense that in the local universe the most massive black holes are in a less active stage then lower mass black holes. The second route I follow is a study of redshift evolution in the black hole-galaxy relations. While theoretical models can in general explain the existence of these relations, their redshift evolution puts strong constraints on these models. Observational studies on the black hole-galaxy relations naturally suffer from selection effects. These can potentially bias the conclusions inferred from the observations, if they are not taken into account. I investigated the issue of selection effects on type 1 AGN samples in detail and discuss various sources of bias, e.g. an AGN luminosity bias, an active fraction bias and an AGN evolution bias. If the selection function of the observational sample and the underlying distribution functions are known, it is possible to correct for this bias. I present a fitting method to obtain an unbiased estimate of the intrinsic black hole-galaxy relations from samples that are affected by selection effects. Third, I try to improve our census of dormant black holes and the determination of their masses. One of the most important techniques to determine the black hole mass in quiescent galaxies is via stellar dynamical modeling. This method employs photometric and kinematic observations of the galaxy and infers the gravitational potential from the stellar orbits. This method can reveal the presence of the black hole and give its mass, if the sphere of the black hole's gravitational influence is spatially resolved. However, usually the presence of a dark matter halo is ignored in the dynamical modeling, potentially causing a bias on the determined black hole mass. I ran dynamical models for a sample of 12 galaxies, including a dark matter halo. For galaxies for which the black hole's sphere of influence is not well resolved, I found that the black hole mass is systematically underestimated when the dark matter halo is ignored, while there is almost no effect for galaxies with well resolved sphere of influence.}, language = {en} } @phdthesis{Schulz2014, author = {Schulz, Anneli}, title = {Search for gamma-ray emission from bow shocks of runaway stars}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-73905}, school = {Universit{\"a}t Potsdam}, pages = {123}, year = {2014}, abstract = {The mystery of the origin of cosmic rays has been tackled for more than hundred years and is still not solved. Cosmic rays are detected with energies spanning more than 10 orders of magnitude and reaching energies up to ~10²¹ eV, far higher than any man-made accelerator can reach. Different theories on the astrophysical objects and processes creating such highly energetic particles have been proposed. A very prominent explanation for a process producing highly energetic particles is shock acceleration. The observation of high-energy gamma rays from supernova remnants, some of them revealing a shell like structure, is clear evidence that particles are accelerated to ultrarelativistic energies in the shocks of these objects. The environments of supernova remnants are complex and challenge detailed modelling of the processes leading to high-energy gamma-ray emission. The study of shock acceleration at bow shocks, created by the supersonic movement of individual stars through the interstellar medium, offers a unique possibility to determine the physical properties of shocks in a less complex environment. The shocked medium is heated by the stellar and the shock excited radiation, leading to thermal infrared emission. 28 bow shocks have been discovered through their infrared emission. Nonthermal radiation in radio and X-ray wavelengths has been detected from two bow shocks, pointing to the existence of relativistic particles in these systems. Theoretical models of the emission processes predict high-energy and very high-energy emission at a flux level in reach of current instruments. This work presents the search for gamma-ray emission from bow shocks of runaway stars in the energy regime from 100MeV to ~100TeV. The search is performed with the large area telescope (LAT) on-board the Fermi satellite and the H.E.S.S. telescopes located in the Khomas Highland in Namibia. The Fermi-LAT was launched in 2008 and is continuously scanning the sky since then. It detects photons with energies from 20MeV to over 300 GeV and has an unprecedented sensitivity. The all-sky coverage allows us to study all 28 bow shocks of runaway stars listed in the E-BOSS catalogue of infrared bow shocks. No significant emission was detected from any of the objects, although predicted by several theoretical models describing the non-thermal emission of bow shocks of runaway stars. The H.E.S.S. experiment is the most sensitive system of imaging atmospheric Cherenkov telescopes. It detects photons from several tens of GeV to ~100TeV. Seven of the bow shocks have been observed with H.E.S.S. and the data analysis is presented in this thesis. The analyses of the very-high energy data did not reveal significant emission from any of the sources either. This work presents the first systematic search for gamma-ray emission from bow shocks of runaway stars. For the first time Fermi-LAT data was specifically analysed to reveal emission from bow shocks of runaway stars. In the TeV regime no searches for emission from theses objects have been published so far, the study presented here is the first in this energy regime. The level of the gamma-ray emission from bow shocks of runaway stars is constrained by the calculated upper limits over six orders in magnitude in energy. The upper limits calculated for the bow shocks of runaway stars in the course of this work, constrain several models. For the best candidate, ζ Ophiuchi, the upper limits in the Fermi-LAT energy range are lower than the predictions by a factor ~5. This challenges the assumptions made in this model and gives valuable input for further modelling approaches. The analyses were performed with the software packages provided by the H.E.S.S. and Fermi collaborations. The development of a unified analysis framework for gamma-ray data, namely GammaLib/ctools, is rapidly progressing within the CTA consortium. Recent implementations and cross-checks with current software frameworks are presented in the Appendix.}, language = {en} } @phdthesis{Schulz2016, author = {Schulz, Alexander}, title = {Untersuchung der Wechselwirkung synoptisch-skaliger mit orographisch bedingten Prozessen in der arktischen Grenzschicht {\"u}ber Spitzbergen}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-400058}, school = {Universit{\"a}t Potsdam}, pages = {vi, 194}, year = {2016}, abstract = {In der vorliegenden Arbeit wird die planetare Grenzschicht in Ny-{\AA}lesund, Spitzbergen, sowohl bez{\"u}glich kleinskaliger („mikrometeorologischer") Effekte als auch in ihrer Kopplung mit der Synoptik untersucht. Dazu werden verschiedene Beobachtungsdaten aus der S{\"a}ule und in Bodenn{\"a}he zusammengezogen und bewertet. Die so gewonnenen Datens{\"a}tze werden dann zur Validierung eines nicht-hydrostatischen, regionalen Klimamodells genutzt. Weiterhin werden orographisch bedingte Einfl{\"u}sse, die Untergrundbeschaffenheit und die lokale Heterogenit{\"a}t der Unterlage untersucht. Hierzu werden meteorologische Gr{\"o}ßen, wie die Variabilit{\"a}t der Temperatur und insbesondere die j{\"a}hrliche Windverteilung in Bodenn{\"a}he untersucht und es erfolgt ein Vergleich von in-situ gemessenen turbulenten Fl{\"u}ssen von den Eddy-Kovarianz-Messkomplexen bei Ny-{\AA}lesund und im Bayelva-Tal unter demselben Aspekt. Es zeigt sich, dass der Eddy-Kovarianz-Messkomplex im Bayelva-Tal sehr stark durch eine orographisch bedingte Kanalisierung der Str{\"o}mung beeinflusst ist und sich nicht f{\"u}r Vergleiche mit regionalen Klimamodellen mit horizontalen Aufl{\"o}sungen von <1km eignet. Die hohe Bodenfeuchte im Bayelva-Tal f{\"u}hrt zudem zu einem deutlich kleineren Bowen-Verh{\"a}ltnis, als es f{\"u}r diese Region zu erwarten ist. Der Eddy-Kovarianz-Messkomplex bei Ny-{\AA}lesund erweist sich hingegen als geeigneter f{\"u}r solche Modellvergleiche, aufgrund der typischen, k{\"u}stennahen Windverteilung und des repr{\"a}sentativen Footprints. Letzteres wird durch die Bestimmung der Footprint-Klimatologie des Jahres 2013 mit einem aktuellen Footprint-Modell erarbeitet. Weiterhin wird die Auswirkung von (Anti-) Zyklonen {\"u}ber den Archipel auf die zeitliche Variabilit{\"a}t der lokalen Grenzschichteigenschaften untersucht und bewertet. Dazu wird ein Zyklonen-Detektions-Algorithmus auf ERA-Interim-Reanalysedatens{\"a}tze angewendet, wodurch die H{\"a}ufigkeit von nahezu ideal konzentrischen Hoch- und die Tiefdruckgebieten f{\"u}r drei Jahre bestimmt wird. Aus dieser Verteilung werden insgesamt drei interessante Zeitr{\"a}ume zu verschiedenen Jahreszeiten ausgew{\"a}hlt und im Rahmen von Prozessstudien die lokalen bodennahen meteorologischen Messungen, der turbulente Austausch an der Oberfl{\"a}che und die Grenzschichtdynamik in der S{\"a}ule untersucht. Die zeitliche Variabilit{\"a}t der dynamischen Grenzschichtstabilit{\"a}t in der S{\"a}ule wird anhand von zeitlich hoch aufgel{\"o}sten vertikalen Profilen der Bulk-Richardson-Zahl aus Kompositprofilen aus Fernerkundungsinstrumenten (Radiometer, Wind-LIDAR) sowie Mastdaten (BSRN-Mast) untersucht und die Grenzschichth{\"o}he ermittelt. Aus diesen Analysen ergibt sich eine deutliche Abh{\"a}ngigkeit der thermischen Stabilit{\"a}t beim Durchzug von Fronten, eine damit einhergehende erhebliche Abh{\"a}ngigkeit der Grenzschichtdynamik und der Grenzschichth{\"o}he sowie des turbulenten Austauschs von der zeitlichen Variabilit{\"a}t der Windgeschwindigkeit in der S{\"a}ule. Auf Grundlage der Standortanalysen und Prozessstudien erfolgt ein Vergleich der bodennahen Messungen und den Beobachtungen aus der S{\"a}ule, sowohl von den genannten Fernerkundungsinstrumenten als auch von In-situ-Messungen (Radiosonden) f{\"u}r den Zeitraum einer Radiosondierungskampagne mit dem nicht-hydrostatischen, regionalen Klimamodel WRF (ARW). Auf Grundlage der Fragestellung, inwieweit aktuelle Schemata die Grenzschichtcharakteristika in orographisch stark gegliedertem Gel{\"a}nde in der Arktis reproduzieren k{\"o}nnen, werden zwei Grenzschichtparametrisierungsschemata mit verschiedenen Ordnungen der Schließung validiert. Hierzu wird die zeitliche Variabilit{\"a}t der Temperatur, der Feuchte und des Windfeldes in der S{\"a}ule bis 2000m in den Simulationen mit den Beobachtungsdaten vergleichen. Es wird gezeigt, dass durch Modifikation der Initialwertfelder eine sehr gute {\"U}bereinstimmung zwischen den Simulationen und den Beobachtungen bereits bei einer horizontalen Aufl{\"o}sung von 1km erreicht werden kann und die Wahl des Grenzschichtschemas nur untergeordneten Einfluss hat. Hieraus werden Ans{\"a}tze der Weiterentwicklung der Parametrisierungen, aber auch Empfehlungen bez{\"u}glich der Initialwertfelder, wie der Landmaske und der Orographie, vorgeschlagen.}, language = {de} } @phdthesis{Schubert2014, author = {Schubert, Marcel}, title = {Elementary processes in layers of electron transporting Donor-acceptor copolymers : investigation of charge transport and application to organic solar cells}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-70791}, school = {Universit{\"a}t Potsdam}, year = {2014}, abstract = {Donor-acceptor (D-A) copolymers have revolutionized the field of organic electronics over the last decade. Comprised of a electron rich and an electron deficient molecular unit, these copolymers facilitate the systematic modification of the material's optoelectronic properties. The ability to tune the optical band gap and to optimize the molecular frontier orbitals as well as the manifold of structural sites that enable chemical modifications has created a tremendous variety of copolymer structures. Today, these materials reach or even exceed the performance of amorphous inorganic semiconductors. Most impressively, the charge carrier mobility of D-A copolymers has been pushed to the technologically important value of 10 cm^{2}V^{-1}s^{-1}. Furthermore, owed to their enormous variability they are the material of choice for the donor component in organic solar cells, which have recently surpassed the efficiency threshold of 10\%. Because of the great number of available D-A copolymers and due to their fast chemical evolution, there is a significant lack of understanding of the fundamental physical properties of these materials. Furthermore, the complex chemical and electronic structure of D-A copolymers in combination with their semi-crystalline morphology impede a straightforward identification of the microscopic origin of their superior performance. In this thesis, two aspects of prototype D-A copolymers were analysed. These are the investigation of electron transport in several copolymers and the application of low band gap copolymers as acceptor component in organic solar cells. In the first part, the investigation of a series of chemically modified fluorene-based copolymers is presented. The charge carrier mobility varies strongly between the different derivatives, although only moderate structural changes on the copolymers structure were made. Furthermore, rather unusual photocurrent transients were observed for one of the copolymers. Numerical simulations of the experimental results reveal that this behavior arises from a severe trapping of electrons in an exponential distribution of trap states. Based on the comparison of simulation and experiment, the general impact of charge carrier trapping on the shape of photo-CELIV and time-of-flight transients is discussed. In addition, the high performance naphthalenediimide (NDI)-based copolymer P(NDI2OD-T2) was characterized. It is shown that the copolymer posses one of the highest electron mobilities reported so far, which makes it attractive to be used as the electron accepting component in organic photovoltaic cells.\par Solar cells were prepared from two NDI-containing copolymers, blended with the hole transporting polymer P3HT. I demonstrate that the use of appropriate, high boiling point solvents can significantly increase the power conversion efficiency of these devices. Spectroscopic studies reveal that the pre-aggregation of the copolymers is suppressed in these solvents, which has a strong impact on the blend morphology. Finally, a systematic study of P3HT:P(NDI2OD-T2) blends is presented, which quantifies the processes that limit the efficiency of devices. The major loss channel for excited states was determined by transient and steady state spectroscopic investigations: the majority of initially generated electron-hole pairs is annihilated by an ultrafast geminate recombination process. Furthermore, exciton self-trapping in P(NDI2OD-T2) domains account for an additional reduction of the efficiency. The correlation of the photocurrent to microscopic morphology parameters was used to disclose the factors that limit the charge generation efficiency. Our results suggest that the orientation of the donor and acceptor crystallites relative to each other represents the main factor that determines the free charge carrier yield in this material system. This provides an explanation for the overall low efficiencies that are generally observed in all-polymer solar cells.}, language = {en} } @phdthesis{Schroeder2024, author = {Schr{\"o}der, Jakob}, title = {Fundamentals of diffraction-based residual stress and texture analysis of laser powder bed fused Inconel 718}, doi = {10.25932/publishup-62197}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-621972}, school = {Universit{\"a}t Potsdam}, pages = {XVII, 135}, year = {2024}, abstract = {Additive manufacturing (AM) processes enable the production of metal structures with exceptional design freedom, of which laser powder bed fusion (PBF-LB) is one of the most common. In this process, a laser melts a bed of loose feedstock powder particles layer-by-layer to build a structure with the desired geometry. During fabrication, the repeated melting and rapid, directional solidification create large temperature gradients that generate large thermal stress. This thermal stress can itself lead to cracking or delamination during fabrication. More often, large residual stresses remain in the final part as a footprint of the thermal stress. This residual stress can cause premature distortion or even failure of the part in service. Hence, knowledge of the residual stress field is critical for both process optimization and structural integrity. Diffraction-based techniques allow the non-destructive characterization of the residual stress fields. However, such methods require a good knowledge of the material of interest, as certain assumptions must be made to accurately determine residual stress. First, the measured lattice plane spacings must be converted to lattice strains with the knowledge of a strain-free material state. Second, the measured lattice strains must be related to the macroscopic stress using Hooke's law, which requires knowledge of the stiffness of the material. Since most crystal structures exhibit anisotropic material behavior, the elastic behavior is specific to each lattice plane of the single crystal. Thus, the use of individual lattice planes in monochromatic diffraction residual stress analysis requires knowledge of the lattice plane-specific elastic properties. In addition, knowledge of the microstructure of the material is required for a reliable assessment of residual stress. This work presents a toolbox for reliable diffraction-based residual stress analysis. This is presented for a nickel-based superalloy produced by PBF-LB. First, this work reviews the existing literature in the field of residual stress analysis of laser-based AM using diffraction-based techniques. Second, the elastic and plastic anisotropy of the nickel-based superalloy Inconel 718 produced by PBF-LB is studied using in situ energy dispersive synchrotron X-ray and neutron diffraction techniques. These experiments are complemented by ex situ material characterization techniques. These methods establish the relationship between the microstructure and texture of the material and its elastic and plastic anisotropy. Finally, surface, sub-surface, and bulk residual stress are determined using a texture-based approach. Uncertainties of different methods for obtaining stress-free reference values are discussed. The tensile behavior in the as-built condition is shown to be controlled by texture and cellular sub-grain structure, while in the heat-treated condition the precipitation of strengthening phases and grain morphology dictate the behavior. In fact, the results of this thesis show that the diffraction elastic constants depend on the underlying microstructure, including texture and grain morphology. For columnar microstructures in both as-built and heat-treated conditions, the diffraction elastic constants are best described by the Reuss iso-stress model. Furthermore, the low accumulation of intergranular strains during deformation demonstrates the robustness of using the 311 reflection for the diffraction-based residual stress analysis with columnar textured microstructures. The differences between texture-based and quasi-isotropic approaches for the residual stress analysis are shown to be insignificant in the observed case. However, the analysis of the sub-surface residual stress distributions show, that different scanning strategies result in a change in the orientation of the residual stress tensor. Furthermore, the location of the critical sub-surface tensile residual stress is related to the surface roughness and the microstructure. Finally, recommendations are given for the diffraction-based determination and evaluation of residual stress in textured additively manufactured alloys.}, language = {en} } @phdthesis{Schroeder2016, author = {Schr{\"o}der, Henning}, title = {Ultrafast electron dynamics in Fe(CO)5 and Cr(CO)6}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-94589}, school = {Universit{\"a}t Potsdam}, pages = {v, 87}, year = {2016}, abstract = {In this thesis, the two prototype catalysts Fe(CO)₅ and Cr(CO)₆ are investigated with time-resolved photoelectron spectroscopy at a high harmonic setup. In both of these metal carbonyls, a UV photon can induce the dissociation of one or more ligands of the complex. The mechanism of the dissociation has been debated over the last decades. The electronic dynamics of the first dissociation occur on the femtosecond timescale. For the experiment, an existing high harmonic setup was moved to a new location, was extended, and characterized. The modified setup can induce dynamics in gas phase samples with photon energies of 1.55eV, 3.10eV, and 4.65eV. The valence electronic structure of the samples can be probed with photon energies between 20eV and 40eV. The temporal resolution is 111fs to 262fs, depending on the combination of the two photon energies. The electronically excited intermediates of the two complexes, as well as of the reaction product Fe(CO)₄, could be observed with photoelectron spectroscopy in the gas phase for the first time. However, photoelectron spectroscopy gives access only to the final ionic states. Corresponding calculations to simulate these spectra are still in development. The peak energies and their evolution in time with respect to the initiation pump pulse have been determined, these peaks have been assigned based on literature data. The spectra of the two complexes show clear differences. The dynamics have been interpreted with the assumption that the motion of peaks in the spectra relates to the movement of the wave packet in the multidimensional energy landscape. The results largely confirm existing models for the reaction pathways. In both metal carbonyls, this pathway involves a direct excitation of the wave packet to a metal-to-ligand charge transfer state and the subsequent crossing to a dissociative ligand field state. The coupling of the electronic dynamics to the nuclear dynamics could explain the slower dissociation in Fe(CO)₅ as compared to Cr(CO)₆.}, language = {en} } @phdthesis{Scholz2012, author = {Scholz, Markus Reiner}, title = {Spin polarization, circular dichroism, and robustness of topological surface states}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-96686}, school = {Universit{\"a}t Potsdam}, pages = {153}, year = {2012}, abstract = {Dreidimensionale topologische Isolatoren sind ein neues Materialsystem, welches dadurch charakterisiert ist, dass es in seinem Inneren isolierend an der Ober {\"a}che jedoch leitend ist. Urs{\"a}chlich f{\"u}r die Leitf{\"a}higkeit an der Ober {\"a}che sind sogenannte topologische Ober- {\"a}chenzust{\"a}nde, welche das Valenzband des Inneren mit dem Leitungsband des Inneren verbinden. An der Ober {\"a}che ist also die Bandl{\"u}cke, welche die isolierende Eigenschaft verursacht, geschlossen. Die vorliegende Arbeit untersucht diese Ober {\"a}chenzust{\"a}nde mittels spin- und winkelauf- gel{\"o}ster Photoemissionsspektroskopie. Es wird gezeigt, dass in den Materialien Bi2Se3 und Bi2Te3, in {\"u}bereinstimmung mit der Literatur, die entscheidenden Charakteristika eines topologischen Ober {\"a}chenzustands vorzu nden sind: Die Ober {\"a}chenzust{\"a}nde dieser Sys- teme durchqueren die Bandl{\"u}cke in ungerader Anzahl, sie sind nicht entartet und weisen folgerichtig eine hohe Spinpolarisation auf. Weiterhin wird durch Aufdampfen diverser Adsorbate gezeigt, dass der Ober {\"a}chenzust{\"a}n- de von Bi2Se3 und Bi2Te3, wie erwartet, extrem robust ist. Ober {\"a}chenzust{\"a}nde topologisch trivialer Systeme erf{\"u}llen diese Eigenschaft nicht; bereits kleine Verunreinigungen k{\"o}n- nen diese Zust{\"a}nde zerst{\"o}ren, bzw. die Ober {\"a}che isolierend machen. Die topologischen Ober {\"a}chenzust{\"a}nde k{\"o}nnen in der vorliegenden Arbeit noch bis zur Detektionsgrenze der experimentellen Messmethode nachgewiesen werden und die Ober {\"a}che bleibt Leitf{\"a}hig. Unter den Adsorbaten be ndet sich auch Eisen, ein bekanntermaßen magnetisches Materi- al. Eine der Grundvoraussetzungen f{\"u}r topologische Isolatoren ist die Zeitumkehrsymme- trie, die Elektronen, welche den topologischen Ober {\"a}chenzustand besetzen, vorschreibt, dass sie eine bestimmte Spinrichtung haben m{\"u}ssen, wenn sie sich beispielsweise nach links bewegen und den entgegengesetzten Spin wenn sie sich nach rechts bewegen. In magnetischen Materialien ist die Zeitumkehrsymmetrie jedoch explizit gebrochen und die gezeigte Robustheit des Ober {\"a}chenzustands gegen magnetische Materialien daher uner- wartet. Die Zeitumkehrsymmetrie sorgt auch daf{\"u}r, dass eine Streuung der Elektronen um 180°, beispielsweise an einem Gitterdefekt oder an einem Phonon strikt verboten ist. Bei einem solchen Streuprozess bleibt die Spinrichtung erhalten, da aber in der Gegenrichtung nur Zust{\"a}nde mit entgegengesetztem Spin vorhanden sind kann das Elektron nicht in diese Richtung gestreut werden. Dieses Prinzip wird anhand der Lebensdauer der durch Pho- toemission angeregten Zust{\"a}nde untersucht. Hierbei wird gezeigt, dass die Kopplung der Elektronen des Ober {\"a}chenzustands von Bi2Te3 an Phononen unerwartet hoch ist und dass sich eine Anisotropie in der Bandstruktur des Selbigen auch in den Lebensdauern der ange- regten Zust{\"a}nde widerspiegelt. Weiterhin wird gezeigt, dass sich die Ein {\"u}sse von magne- tischen und nicht-magnetischen Verunreinigungen auf die Lebensdauern stark voneinander unterscheiden. Im letzten Teil der vorliegenden Arbeit wird untersucht, ob eine Asymmetrie in der Inten- sit{\"a}tsverteilung der winkelaufgel{\"o}sten Photoemissionsspektren, bei Anregung mit zirku- lar polarisiertem Licht, in Bi2Te3 R{\"u}ckschl{\"u}sse auf die Spinpolarisation der Elektronen erlaubt. Bei Variation der Energie des eingestrahlten Lichts wird ein Vorzeichenwechsel der Asymmetrie beobachtet. Daraus l{\"a}sst sich schlussfolgern, dass die Asymmetrie keine R{\"u}ckschl{\"u}sse auf die Spinpolarisation erlaubt.}, language = {en} } @phdthesis{SchneidervonDeimling2006, author = {Schneider von Deimling, Thomas}, title = {Constraining uncertainty in climate sensitivity : an ensemble simulation approach based on glacial climate}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-7778}, school = {Universit{\"a}t Potsdam}, year = {2006}, abstract = {Uncertainty about the sensitivity of the climate system to changes in the Earth's radiative balance constitutes a primary source of uncertainty for climate projections. Given the continuous increase in atmospheric greenhouse gas concentrations, constraining the uncertainty range in such type of sensitivity is of vital importance. A common measure for expressing this key characteristic for climate models is the climate sensitivity, defined as the simulated change in global-mean equilibrium temperature resulting from a doubling of atmospheric CO2 concentration. The broad range of climate sensitivity estimates (1.5-4.5°C as given in the last Assessment Report of the Intergovernmental Panel on Climate Change, 2001), inferred from comprehensive climate models, illustrates that the strength of simulated feedback mechanisms varies strongly among different models. The central goal of this thesis is to constrain uncertainty in climate sensitivity. For this objective we first generate a large ensemble of model simulations, covering different feedback strengths, and then request their consistency with present-day observational data and proxy-data from the Last Glacial Maximum (LGM). Our analyses are based on an ensemble of fully-coupled simulations, that were realized with a climate model of intermediate complexity (CLIMBER-2). These model versions cover a broad range of different climate sensitivities, ranging from 1.3 to 5.5°C, and have been generated by simultaneously perturbing a set of 11 model parameters. The analysis of the simulated model feedbacks reveals that the spread in climate sensitivity results from different realizations of the feedback strengths in water vapour, clouds, lapse rate and albedo. The calculated spread in the sum of all feedbacks spans almost the entire plausible range inferred from a sampling of more complex models. We show that the requirement for consistency between simulated pre-industrial climate and a set of seven global-mean data constraints represents a comparatively weak test for model sensitivity (the data constrain climate sensitivity to 1.3-4.9°C). Analyses of the simulated latitudinal profile and of the seasonal cycle suggest that additional present-day data constraints, based on these characteristics, do not further constrain uncertainty in climate sensitivity. The novel approach presented in this thesis consists in systematically combining a large set of LGM simulations with data information from reconstructed regional glacial cooling. Irrespective of uncertainties in model parameters and feedback strengths, the set of our model versions reveals a close link between the simulated warming due to a doubling of CO2, and the cooling obtained for the LGM. Based on this close relationship between past and future temperature evolution, we define a method (based on linear regression) that allows us to estimate robust 5-95\% quantiles for climate sensitivity. We thus constrain the range of climate sensitivity to 1.3-3.5°C using proxy-data from the LGM at low and high latitudes. Uncertainties in glacial radiative forcing enlarge this estimate to 1.2-4.3°C, whereas the assumption of large structural uncertainties may increase the upper limit by an additional degree. Using proxy-based data constraints for tropical and Antarctic cooling we show that very different absolute temperature changes in high and low latitudes all yield very similar estimates of climate sensitivity. On the whole, this thesis highlights that LGM proxy-data information can offer an effective means of constraining the uncertainty range in climate sensitivity and thus underlines the potential of paleo-climatic data to reduce uncertainty in future climate projections.}, subject = {Dynamische Modellierung}, language = {en} } @phdthesis{Schneider2004, author = {Schneider, Judith}, title = {Dynamical structures and manifold detection in 2D and 3D chaotic flows}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-0001696}, school = {Universit{\"a}t Potsdam}, year = {2004}, abstract = {In dieser Arbeit werden die dynamischen Strukturen und Mannigfaltigkeiten in geschlossenen chaotischen Systemen untersucht. Das Wissen um diese dynamischen Strukturen (und Mannigfaltigkeiten) ist von Bedeutung, da sie uns einen ersten {\"U}berblick {\"u}ber die Dynamik des Systems geben, dass heisst, mit ihrer Hilfe sind wir in der Lage, das System zu charakterisieren und eventuell sogar seine Dynamik vorherzusagen. Die Visualisierung der dynamischen Strukturen, speziell in geschlossenen chaotischen Systemen, ist ein schwieriger und oft langer Prozess. Hier werden wir die sogenannte 'Leaking-Methode' (an Beispielen einfacher mathematischer Modelle wie der B{\"a}cker- oder der Sinus Abbildung) vorstellen, mit deren Hilfe wir die M{\"o}glichkeit haben, Teile der Mannigfaltigkeiten des chaotischen Sattels des Systems zu visualisieren. Vergleiche zwischen den gewonnenen Strukturen und Strukturen die durch chemische oder biologische Reaktionen hervorgerufen werden, werden anhand eines kinematischen Modells des Golfstroms durchgef{\"u}hrt. Es wird gezeigt, dass mittels der Leaking-Methode dynamische Strukturen auch in Umweltsystemen sichtbar gemacht werden k{\"o}nnen. Am Beispiel eines realistischen Modells des Mittelmeeres erweitern wir die Leaking-Methode zur sogenannten 'Exchange-Methode'. Diese erlaubt es den Transport zwischen zwei Regionen zu charakterisieren, die Transport-Routen und Austausch-Bassins sichtbar zu machen und die Austausch-Zeiten zu berechnen. Austausch-Bassins und Zeiten werden f{\"u}r die n{\"o}rdliche und s{\"u}dliche Region des westlichen Mittelmeeres pr{\"a}sentiert. Weiterhin werden Mischungseigenschaften im Erdmantel charakterisiert und die geometrischen Eigenschaften von Mannigfaltigkeiten in einem 3dimensionalen mathematischen Modell (ABC-Abbildung) untersucht.}, language = {en} } @phdthesis{Schmoll2001, author = {Schmoll, J{\"u}rgen}, title = {3D-Spektrofotometrie extragalaktischer Emissionslinienobjekte}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-0000372}, school = {Universit{\"a}t Potsdam}, year = {2001}, abstract = {Popul{\"a}rwissenschaftlicher Abstract: Bislang gibt es in der beobachtenden optischen Astronomie zwei verschiedene Herangehensweisen: Einerseits werden Objekte durch Kameras abbildend erfaßt, andererseits werden durch die wellenl{\"a}ngenabh{\"a}ngige Zerlegung ihres Lichtes Spektren gewonnen. Das Integral - Field - Verfahren ist eine relativ neue Technik, welche die genannten Beobachtungsmethoden vereint. Das Objektbild im Teleskopfokus wird in r{\"a}umlich zerlegt und jedes Ortselement einem gemeinsamen Spektrografen zugef{\"u}hrt. Hierdurch wird das Objekt nicht nur zweidimensional r{\"a}umlich erfaßt, sondern zus{\"a}tzlich die spektrale Kompenente als dritte Dimension erhalten, weswegen das Verfahren auch als 3D-Methode bezeichnet wird. Anschaulich kann man sich das Datenresultat als eine Abbildung vorstellen, in der jeder einzelne Bildpunkt nicht mehr nur einen Intensit{\"a}tswert enth{\"a}lt, sondern gleich ein ganzes Spektrum. Diese Technik erm{\"o}glicht es, ausgedehnte Objekte im Unterschied zu g{\"a}ngigen Spaltspektrografen komplett zu erfassen. Die besondere St{\"a}rke der Methode ist die M{\"o}glichkeit, die Hintergrundkontamination der unmittelbaren Umgebung des Objektes zu erfassen und in der Auswertung zu ber{\"u}cksichtigen. Durch diese F{\"a}higkeit erscheint die 3D-Methode pr{\"a}destiniert f{\"u}r den durch moderne Großteleskope erschlossenen Bereich der extragalaktischen Stellarastronomie. Die detaillierte Untersuchung aufgel{\"o}ster stellare Populationen in nahegelegenen Galaxien ist erst seit kurzer Zeit dank der Fortschritte mit modernen Grossteleskopen und fortschrittlicher Instrumentierung m{\"o}glich geworden. Wegen der Bedeutung f{\"u}r die Entstehung und Evolution von Galaxien werden diese Arbeiten zuk{\"u}nftig weiter an Bedeutung gewinnen. In der vorliegenden Arbeit wurde die Integral-Field-Spektroskopie an zwei planetarischen Nebeln in der n{\"a}chstgelegenen großen Spiralgalaxie M31 (NGC 224) getestet, deren Helligkeiten und Koordinaten aus einer Durchmusterung vorlagen. Hierzu wurden Beobachtungen mit dem MPFS-Instrument am russischen 6m - Teleskop in Selentschuk/Kaukasus sowie mit INTEGRAL/WYFFOS am englischen William-Herschel-Teleskop auf La Palma gewonnen. Ein {\"u}berraschendes Ergebnis war, daß eins der beiden Objekte falsch klassifiziert wurde. Sowohl die meßbare r{\"a}umliche Ausdehnung des Objektes als auch das spektrale Erscheinungsbild schlossen die Identit{\"a}t mit einem planetarischen Nebel aus. Mit hoher Wahrscheinlichkeit handelt es sich um einen Supernova{\"u}berrest, zumal im Rahmen der Fehler an gleicher Stelle eine vom R{\"o}ntgensatelliten ROSAT detektierte R{\"o}ntgenquelle liegt. Die in diesem Projekt verwendeten Integral-Field-Instrumente wiesen zwei verschiedene Bauweisen auf, die sich miteinander vergleichen ließen. Ein Hauptkritikpunkt der verwendeten Instrumente war ihre geringe Lichtausbeute. Die gesammelten Erfahrung fanden Eingang in das Konzept des derzeit in Potsdam in der Fertigung befindlichen 3D-Instruments PMAS (Potsdamer Multi - Apertur - Spektrophotometer), welcher zun{\"a}chst f{\"u}r das 3.5m-Teleskop des Calar - Alto - Observatoriums in S{\"u}dspanien vorgesehen ist. Um die Effizienz dieses Instrumentes zu verbessern, wurde in dieser Arbeit die Kopplung der zum Bildrasterung verwendeten Optik zu den Lichtleitfasern im Labor untersucht. Die Untersuchungen zur Maximierung von Lichtausbeute und Stabilit{\"a}t zeigen, daß sich die Effizienz durch Auswahl einer geeigneten Koppelmethode um etwa 20 Prozent steigern l{\"a}sst.}, language = {de} } @phdthesis{Schmidt2000, author = {Schmidt, Robert W.}, title = {Cosmological applications of gravitational lensing}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-0000261}, school = {Universit{\"a}t Potsdam}, year = {2000}, abstract = {In dieser Arbeit benutze ich den Gravitationslinseneffekt als ein Werkzeug, um zwei recht unterschiedliche kosmologische Fragestellungen zu bearbeiten: die Natur der dunklen Materie in Galaxienhalos und die Rotation des Universums. Zuerst untersuche ich den Mikrolinseneffekt in den Gravitationlinsensystemen Q0957+561 und Q2237+0305. In diesen Systemen scheint das Licht eines Quasars durch die Linsengalaxie hindurch. Aufgrund der Relativbewegung zwischen Quasar, Linsengalaxie und Beobachter verursachen kompakte Objekte innerhalb der Galaxie oder dem Galaxienhalo Helligkeitsfluktuationen des Hintergrundquasars. Ich vergleiche die am 3.5m Teleskop des Apache Point Observatory zwischen 1995 und 1998 gewonnene Lichtkurve des Doppelquasars Q0957+561 (Colley, Kundic \& Turner 2000) mit numerischen Simulationen, um zu untersuchen, ob der Halo der Linsengalaxie aus massiven kompakten Objekten (MACHOs) besteht. Dieser Test wurde zuerst von Gott (1981) vorgeschlagen. Ich kann MACHO-Massen von 10^-6 M_sun bis zu 10^-2 M_sun ausschliessen, sofern der Quasar kleiner ist als 3x10^14 h_60^-0.5 cm und MACHOs mehr als 50\% des dunklen Halos ausmachen. Im zweiten Teil der Arbeit stelle ich neue Beobachtungsdaten fuer den Vierfachquasar Q2237+0305 vor, die am 3.5m Teleskop des Apache Point Observatory zwischen Juni 1995 und Januar 1998 gewonnen wurden. Obwohl die Daten bei veraenderlichen, oft schlechten Seeing Bedingungen und grober Pixelaufloesung aufgenommen wurden, ist die Photometrie der beiden helleren Quasarbilder A und B mit Hilfe von HST-Beobachtungen moeglich. Ich finde ein Helligkeitsmaximum in Bild A mit einer Amplitude von 0.4 bis 0.5 mag und einer Dauer von wenigstens 100 Tagen. Dies zeigt, dass in der Linsengalaxie der Mikrolinseneffekt stattgefunden hat. Im abschliessenden Teil der Arbeit benutze ich dann den schwachen Gravitationslinseneffekt, um Grenzen fuer eine Klasse von rotierenden Kosmologien vom Goedel-Typ zu ermitteln, die von Korotky \& Obukhov (1996) beschrieben wurde. In Studien des schwachen Linseneffektes werden die Formen von tausenden von Hintergrundgalaxien vermessen und gemittelt. Dabei werden kohaerente Verzerrungen der Galaxienformen gemessen, die von Massenverteilungen im Vordergrund oder von der grossraeumigen Struktur der Raumzeit selbst verursacht werden. Ich berechne die vorhergesagte Scherung als Funktion der Rotverschiebung in rotierenden Kosmologien vom Goedel-Typ und vergleiche diese mit der oberen Grenze fuer die kosmische Scherung gamma_limit von 0.04, die in Studien des schwachen Linseneffektes gewonnen wurde. Dieser Vergleich zeigt, dass Modelle vom Goedel-Typ keine groesseren Rotationen omega als H_0=6.1x10^-11 h_60/Jahr haben koennen, wenn die Grenze fuer die kosmische Scherung fuer den ganzen Himmel gilt.}, language = {en} } @phdthesis{Schmidt2014, author = {Schmidt, Lukas}, title = {Aerosols and boundary layer structure over Arctic sea ice based on airborne lidar and dropsonde measurements}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-75076}, school = {Universit{\"a}t Potsdam}, pages = {vii, 98, xiii}, year = {2014}, abstract = {The atmosphere over the Arctic Ocean is strongly influenced by the distribution of sea ice and open water. Leads in the sea ice produce strong convective fluxes of sensible and latent heat and release aerosol particles into the atmosphere. They increase the occurrence of clouds and modify the structure and characteristics of the atmospheric boundary layer (ABL) and thereby influence the Arctic climate. In the course of this study aircraft measurements were performed over the western Arctic Ocean as part of the campaign PAMARCMIP 2012 of the Alfred Wegener Institute for Polar and Marine Research (AWI). Backscatter from aerosols and clouds within the lower troposphere and the ABL were measured with the nadir pointing Airborne Mobile Aerosol Lidar (AMALi) and dropsondes were launched to obtain profiles of meteorological variables. Furthermore, in situ measurements of aerosol properties, meteorological variables and turbulence were part of the campaign. The measurements covered a broad range of atmospheric and sea ice conditions. In this thesis, properties of the ABL over Arctic sea ice with a focus on the influence of open leads are studied based on the data from the PAMARCMIP campaign. The height of the ABL is determined by different methods that are applied to dropsonde and AMALi backscatter profiles. ABL heights are compared for different flights representing different conditions of the atmosphere and of sea ice and open water influence. The different criteria for ABL height that are applied show large variation in terms of agreement among each other, depending on the characteristics of the ABL and its history. It is shown that ABL height determination from lidar backscatter by methods commonly used under mid-latitude conditions is applicable to the Arctic ABL only under certain conditions. Aerosol or clouds within the ABL are needed as a tracer for ABL height detection from backscatter. Hence an aerosol source close to the surface is necessary, that is typically found under the present influence of open water and therefore convective conditions. However it is not always possible to distinguish residual layers from the actual ABL. Stable boundary layers are generally difficult to detect. To illustrate the complexity of the Arctic ABL and processes therein, four case studies are analyzed each of which represents a snapshot of the interplay between atmosphere and underlying sea ice or water surface. Influences of leads and open water on the aerosol and clouds within the ABL are identified and discussed. Leads are observed to cause the formation of fog and cloud layers within the ABL by humidity emission. Furthermore they decrease the stability and increase the height of the ABL and consequently facilitate entrainment of air and aerosol layers from the free troposphere.}, language = {en} } @phdthesis{Schmeja2006, author = {Schmeja, Stefan}, title = {Properties of turbulent star-forming clusters : models versus observations}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-7364}, school = {Universit{\"a}t Potsdam}, year = {2006}, abstract = {Stars are born in turbulent molecular clouds that fragment and collapse under the influence of their own gravity, forming a cluster of hundred or more stars. The star formation process is controlled by the interplay between supersonic turbulence and gravity. In this work, the properties of stellar clusters created by numerical simulations of gravoturbulent fragmentation are compared to those from observations. This includes the analysis of properties of individual protostars as well as statistical properties of the entire cluster. It is demonstrated that protostellar mass accretion is a highly dynamical and time-variant process. The peak accretion rate is reached shortly after the formation of the protostellar core. It is about one order of magnitude higher than the constant accretion rate predicted by the collapse of a classical singular isothermal sphere, in agreement with the observations. For a more reasonable comparison, the model accretion rates are converted to the observables bolometric temperature, bolometric luminosity, and envelope mass. The accretion rates from the simulations are used as input for an evolutionary scheme. The resulting distribution in the Tbol-Lbol-Menv parameter space is then compared to observational data by means of a 3D Kolmogorov-Smirnov test. The highest probability found that the distributions of model tracks and observational data points are drawn from the same population is 70\%. The ratios of objects belonging to different evolutionary classes in observed star-forming clusters are compared to the temporal evolution of the gravoturbulent models in order to estimate the evolutionary stage of a cluster. While it is difficult to estimate absolute ages, the realtive numbers of young stars reveal the evolutionary status of a cluster with respect to other clusters. The sequence shows Serpens as the youngest and IC 348 as the most evolved of the investigated clusters. Finally the structures of young star clusters are investigated by applying different statistical methods like the normalised mean correlation length and the minimum spanning tree technique and by a newly defined measure for the cluster elongation. The clustering parameters of the model clusters correspond in many cases well to those from observed ones. The temporal evolution of the clustering parameters shows that the star cluster builds up from several subclusters and evolves to a more centrally concentrated cluster, while the cluster expands slower than new stars are formed.}, subject = {Sternentstehung}, language = {en} } @phdthesis{Schlemm2022, author = {Schlemm, Tanja}, title = {The marine ice cliff instability of the Antarctic ice sheet}, doi = {10.25932/publishup-58633}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-586333}, school = {Universit{\"a}t Potsdam}, pages = {107}, year = {2022}, abstract = {The Antarctic ice sheet is the largest freshwater reservoir worldwide. If it were to melt completely, global sea levels would rise by about 58 m. Calculation of projections of the Antarctic contribution to sea level rise under global warming conditions is an ongoing effort which yields large ranges in predictions. Among the reasons for this are uncertainties related to the physics of ice sheet modeling. These uncertainties include two processes that could lead to runaway ice retreat: the Marine Ice Sheet Instability (MISI), which causes rapid grounding line retreat on retrograde bedrock, and the Marine Ice Cliff Instability (MICI), in which tall ice cliffs become unstable and calve off, exposing even taller ice cliffs. In my thesis, I investigated both marine instabilities (MISI and MICI) using the Parallel Ice Sheet Model (PISM), with a focus on MICI.}, language = {en} } @phdthesis{Schiefele2011, author = {Schiefele, J{\"u}rgen}, title = {Casimir-Polder interaction in second quantization}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-54171}, school = {Universit{\"a}t Potsdam}, year = {2011}, abstract = {The Casimir-Polder interaction between a single neutral atom and a nearby surface, arising from the (quantum and thermal) fluctuations of the electromagnetic field, is a cornerstone of cavity quantum electrodynamics (cQED), and theoretically well established. Recently, Bose-Einstein condensates (BECs) of ultracold atoms have been used to test the predictions of cQED. The purpose of the present thesis is to upgrade single-atom cQED with the many-body theory needed to describe trapped atomic BECs. Tools and methods are developed in a second-quantized picture that treats atom and photon fields on the same footing. We formulate a diagrammatic expansion using correlation functions for both the electromagnetic field and the atomic system. The formalism is applied to investigate, for BECs trapped near surfaces, dispersion interactions of the van der Waals-Casimir-Polder type, and the Bosonic stimulation in spontaneous decay of excited atomic states. We also discuss a phononic Casimir effect, which arises from the quantum fluctuations in an interacting BEC.}, language = {en} } @phdthesis{Schick2013, author = {Schick, Daniel}, title = {Ultrafast lattice dynamics in photoexcited nanostructures : femtosecond X-ray diffraction with optimized evaluation schemes}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-68827}, school = {Universit{\"a}t Potsdam}, year = {2013}, abstract = {Within the course of this thesis, I have investigated the complex interplay between electron and lattice dynamics in nanostructures of perovskite oxides. Femtosecond hard X-ray pulses were utilized to probe the evolution of atomic rearrangement directly, which is driven by ultrafast optical excitation of electrons. The physics of complex materials with a large number of degrees of freedom can be interpreted once the exact fingerprint of ultrafast lattice dynamics in time-resolved X-ray diffraction experiments for a simple model system is well known. The motion of atoms in a crystal can be probed directly and in real-time by femtosecond pulses of hard X-ray radiation in a pump-probe scheme. In order to provide such ultrashort X-ray pulses, I have built up a laser-driven plasma X-ray source. The setup was extended by a stable goniometer, a two-dimensional X-ray detector and a cryogen-free cryostat. The data acquisition routines of the diffractometer for these ultrafast X-ray diffraction experiments were further improved in terms of signal-to-noise ratio and angular resolution. The implementation of a high-speed reciprocal-space mapping technique allowed for a two-dimensional structural analysis with femtosecond temporal resolution. I have studied the ultrafast lattice dynamics, namely the excitation and propagation of coherent phonons, in photoexcited thin films and superlattice structures of the metallic perovskite SrRuO3. Due to the quasi-instantaneous coupling of the lattice to the optically excited electrons in this material a spatially and temporally well-defined thermal stress profile is generated in SrRuO3. This enables understanding the effect of the resulting coherent lattice dynamics in time-resolved X-ray diffraction data in great detail, e.g. the appearance of a transient Bragg peak splitting in both thin films and superlattice structures of SrRuO3. In addition, a comprehensive simulation toolbox to calculate the ultrafast lattice dynamics and the resulting X-ray diffraction response in photoexcited one-dimensional crystalline structures was developed in this thesis work. With the powerful experimental and theoretical framework at hand, I have studied the excitation and propagation of coherent phonons in more complex material systems. In particular, I have revealed strongly localized charge carriers after above-bandgap femtosecond photoexcitation of the prototypical multiferroic BiFeO3, which are the origin of a quasi-instantaneous and spatially inhomogeneous stress that drives coherent phonons in a thin film of the multiferroic. In a structurally imperfect thin film of the ferroelectric Pb(Zr0.2Ti0.8)O3, the ultrafast reciprocal-space mapping technique was applied to follow a purely strain-induced change of mosaicity on a picosecond time scale. These results point to a strong coupling of in- and out-of-plane atomic motion exclusively mediated by structural defects.}, language = {en} } @phdthesis{Schemenz2022, author = {Schemenz, Victoria}, title = {Correlations between osteocyte lacuno-canalicular network and material characteristics in bone adaptation and regeneration}, doi = {10.25932/publishup-55959}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-559593}, school = {Universit{\"a}t Potsdam}, pages = {3, xii, 146}, year = {2022}, abstract = {The complex hierarchical structure of bone undergoes a lifelong remodeling process, where it adapts to mechanical needs. Hereby, bone resorption by osteoclasts and bone formation by osteoblasts have to be balanced to sustain a healthy and stable organ. Osteocytes orchestrate this interplay by sensing mechanical strains and translating them into biochemical signals. The osteocytes are located in lacunae and are connected to one another and other bone cells via cell processes through small channels, the canaliculi. Lacunae and canaliculi form a network (LCN) of extracellular spaces that is able to transport ions and enables cell-to-cell communication. Osteocytes might also contribute to mineral homeostasis by direct interactions with the surrounding matrix. If the LCN is acting as a transport system, this should be reflected in the mineralization pattern. The central hypothesis of this thesis is that osteocytes are actively changing their material environment. Characterization methods of material science are used to achieve the aim of detecting traces of this interaction between osteocytes and the extracellular matrix. First, healthy murine bones were characterized. The properties analyzed were then compared with three murine model systems: 1) a loading model, where a bone of the mouse was loaded during its life time; 2) a healing model, where a bone of the mouse was cut to induce a healing response; and 3) a disease model, where the Fbn1 gene is dysfunctional causing defects in the formation of the extracellular tissue. The measurement strategy included routines that make it possible to analyze the organization of the LCN and the material components (i.e., the organic collagen matrix and the mineral particles) in the same bone volumes and compare the spatial distribution of different data sets. The three-dimensional network architecture of the LCN is visualized by confocal laser scanning microscopy (CLSM) after rhodamine staining and is then subsequently quantified. The calcium content is determined via quantitative backscattered electron imaging (qBEI), while small- and wide-angle X-ray scattering (SAXS and WAXS) are employed to determine the thickness and length of local mineral particles. First, tibiae cortices of healthy mice were characterized to investigate how changes in LCN architecture can be attributed to interactions of osteocytes with the surrounding bone matrix. The tibial mid-shaft cross-sections showed two main regions, consisting of a band with unordered LCN surrounded by a region with ordered LCN. The unordered region is a remnant of early bone formation and exhibited short and thin mineral particles. The surrounding, more aligned bone showed ordered and dense LCN as well as thicker and longer mineral particles. The calcium content was unchanged between the two regions. In the mouse loading model, the left tibia underwent two weeks of mechanical stimulation, which results in increased bone formation and decreased resorption in skeletally mature mice. Here the specific research question addressed was how do bone material characteristics change at (re)modeling sites? The new bone formed in response to mechanical stimulation showed similar properties in terms of the mineral particles, like the ordered calcium region but lower calcium content compared to the right, non-loaded control bone of the same mice. There was a clear, recognizable border between mature and newly formed bone. Nevertheless, some canaliculi went through this border connecting the LCN of mature and newly formed bone. Additionally, the question should be answered whether the LCN topology and the bone matrix material properties adapt to loading. Although, mechanically stimulated bones did not show differences in calcium content compared to controls, different correlations were found between the local LCN density and the local Ca content depending on whether the bone was loaded or not. These results suggest that the LCN may serve as a mineral reservoir. For the healing model, the femurs of mice underwent an osteotomy, stabilized with an external fixator and were allowed to heal for 21 days. Thus, the spatial variations in the LCN topology with mineral properties within different tissue types and their interfaces, namely calcified cartilage, bony callus and cortex, could be simultaneously visualized and compared in this model. All tissue types showed structural differences across multiple length scales. Calcium content increased and became more homogeneous from calcified cartilage to bony callus to lamellar cortical bone. The degree of LCN organization increased as well, while the lacunae became smaller, as did the lacunar density between these different tissue types that make up the callus. In the calcified cartilage, the mineral particles were short and thin. The newly formed callus exhibited thicker mineral particles, which still had a low degree of orientation. While most of the callus had a woven-like structure, it also served as a scaffold for more lamellar tissue at the edges. The lamelar bone callus showed thinner mineral particles, but a higher degree of alignment in both, mineral particles and the LCN. The cortex showed the highest values for mineral length, thickness and degree of orientation. At the same time, the lacunae number density was 34\% lower and the lacunar volume 40\% smaller compared to bony callus. The transition zone between cortical and callus regions showed a continuous convergence of bone mineral properties and lacunae shape. Although only a few canaliculi connected callus and the cortical region, this indicates that communication between osteocytes of both tissues should be possible. The presented correlations between LCN architecture and mineral properties across tissue types may suggest that osteocytes have an active role in mineralization processes of healing. A mouse model for the disease marfan syndrome, which includes a genetic defect in the fibrillin-1 gene, was investigated. In humans, Marfan syndrome is characterized by a range of clinical symptoms such as long bone overgrowth, loose joints, reduced bone mineral density, compromised bone microarchitecture, and increased fracture rates. Thus, fibrillin-1 seems to play a role in the skeletal homeostasis. Therefore, the present work studied how marfan syndrome alters LCN architecture and the surrounding bone matrix. The mice with marfan syndrome showed longer tibiae than their healthy littermates from an age of seven weeks onwards. In contrast, the cortical development appeared retarded, which was observed across all measured characteristics, i. e. lower endocortical bone formation, looser and less organized lacuno-canalicular network, less collagen orientation, thinner and shorter mineral particles. In each of the three model systems, this study found that changes in the LCN architecture spatially correlated with bone matrix material parameters. While not knowing the exact mechanism, these results provide indications that osteocytes can actively manipulate a mineral reservoir located around the canaliculi to make a quickly accessible contribution to mineral homeostasis. However, this interaction is most likely not one-sided, but could be understood as an interplay between osteocytes and extra-cellular matrix, since the bone matrix contains biochemical signaling molecules (e.g. non-collagenous proteins) that can change osteocyte behavior. Bone (re)modeling can therefore not only be understood as a method for removing defects or adapting to external mechanical stimuli, but also for increasing the efficiency of possible osteocyte-mineral interactions during bone homeostasis. With these findings, it seems reasonable to consider osteocytes as a target for drug development related to bone diseases that cause changes in bone composition and mechanical properties. It will most likely require the combined effort of materials scientists, cell biologists, and molecular biologists to gain a deeper understanding of how bone cells respond to their material environment.}, language = {en} } @phdthesis{Schattauer2010, author = {Schattauer, Sylvia}, title = {Hybride D{\"u}nnschicht-Solarzellen aus mesopor{\"o}sem Titandioxid und konjugierten Polymeren}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-52619}, school = {Universit{\"a}t Potsdam}, year = {2010}, abstract = {Das Ziel dieser Arbeit ist die Untersuchung der aktiven Komponenten und ihrer Wechselwirkungen in teilorganischen Hybrid-Solarzellen. Diese bestehen aus einer d{\"u}nnen Titandioxidschicht, kombiniert mit einer d{\"u}nnen Polymerschicht. Die Effizienz der Hybrid-Solarzellen wird durch die Lichtabsorption im Polymer, die Dissoziation der gebildeten Exzitonen an der aktiven Grenzfl{\"a}che zwischen TiO2 und Polymer, sowie durch Generation und Extraktion freier Ladungstr{\"a}ger bestimmt. Zur Optimierung der Solarzellen wurden grundlegende physikalische Wechselwirkungen zwischen den verwendeten Materialen sowie der Einfluss verschiedener Herstellungsparameter untersucht. Unter anderem wurden Fragen zum optimalen Materialeinsatz und Pr{\"a}parationsbedingungen beantwortet sowie grundlegende Einfl{\"u}sse wie Schichtmorphologie und Polymerinfiltration n{\"a}her betrachtet. Zun{\"a}chst wurde aus unterschiedlich hergestelltem Titandioxid (Akzeptor-Schicht) eine Auswahl f{\"u}r den Einsatz in Hybrid-Solarzellen getroffen. Kriterium war hierbei die unterschiedliche Morphologie aufgrund der Oberfl{\"a}chenbeschaffenheit, der Film-Struktur, der Kristallinit{\"a}t und die daraus resultierenden Solarzelleneigenschaften. F{\"u}r die anschließenden Untersuchungen wurden mesopor{\"o}se TiO2-Filme aus einer neuen Nanopartikel-Synthese, welche es erlaubt, kristalline Partikel schon w{\"a}hrend der Synthese herzustellen, als Elektronenakzeptor und konjugierte Polymere auf Poly(p-Phenylen-Vinylen) (PPV)- bzw. Thiophenbasis als Donatormaterial verwendet. Bei der thermischen Behandlung der TiO2-Schichten erfolgt eine temperaturabh{\"a}ngige {\"A}nderung der Morphologie, jedoch nicht der Kristallstruktur. Die Auswirkungen auf die Solarzelleneigenschaften wurden dokumentiert und diskutiert. Um die Vorteile der Nanopartikel-Synthese, die Bildung kristalliner TiO2-Partikel bei tiefen Temperaturen, nutzen zu k{\"o}nnen, wurden erste Versuche zur UV-Vernetzung durchgef{\"u}hrt. Neben der Beschaffenheit der Oxidschicht wurde auch der Einfluss der Polymermorphologie, bedingt durch L{\"o}sungsmittelvariation und Tempertemperatur, untersucht. Hierbei konnte gezeigt werden, dass u.a. die Viskosit{\"a}t der Polymerl{\"o}sung die Infiltration in die TiO2-Schicht und dadurch die Effizienz der Solarzelle beeinflusst. Ein weiterer Ansatz zur Erh{\"o}hung der Effizienz ist die Entwicklung neuer lochleitender Polymere, welche m{\"o}glichst {\"u}ber einen weiten spektralen Bereich Licht absorbieren und an die Bandl{\"u}cke des TiO2 angepasst sind. Hierzu wurden einige neuartige Konzepte, z.B. die Kombination von Thiophen- und Phenyl-Einheiten n{\"a}her untersucht. Auch wurde die Sensibilisierung der Titandioxidschicht in Anlehnung an die h{\"o}heren Effizienzen der Farbstoffzellen in Betracht gezogen. Zusammenfassend konnten im Rahmen dieser Arbeit wichtige Einflussparameter auf die Funktion hybrider Solarzellen identifiziert und z.T. n{\"a}her diskutiert werden. F{\"u}r einige limitierende Faktoren wurden Konzepte zur Verbesserung bzw. Vermeidung vorgestellt.}, language = {de} } @phdthesis{Sander2018, author = {Sander, Mathias}, title = {Ultrafast tailored strain fields in nanostructures}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-417863}, school = {Universit{\"a}t Potsdam}, pages = {xvii, 119}, year = {2018}, abstract = {This publication based thesis, which consists of seven published articles, summarizes my contributions to the research field of laser excited ultrafast structural dynamics. The coherent and incoherent lattice dynamics on microscopic length scales are detected by ultrashort optical and X-ray pulses. The understanding of the complex physical processes is essential for future improvements of technological applications. For this purpose, tabletop soruces and large scale facilities, e.g. synchrotrons, are employed to study structural dynamics of longitudinal acoustic strain waves and heat transport. The investigated effects cover timescales from hundreds of femtoseconds up to several microseconds. The main part of this thesis is dedicated to the investigation of tailored phonon wave packets propagating in perovskite nanostructures. Tailoring is achieved either by laser excitation of nanostructured bilayer samples or by a temporal series of laser pulses. Due to the propagation of longitudinal acoustic phonons, the out-of-plane lattice spacing of a thin film insulator-metal bilayer sample is modulated on an ultrafast timescale. This leads to an ultrafast modulation of the X-ray diffraction efficiency which is employed as a phonon Bragg switch to shorten hard X-ray pulses emitted from a 3rd generation synchrotron. In addition, we have observed nonlinear mixing of high amplitude phonon wave packets which originates from an anharmonic interatomic potential. A chirped optical pulse sequence excites a narrow band phonon wave packet with specific momentum and energy. The second harmonic generation of these phonon wave packets is followed by ultrafast X-ray diffraction. Phonon upconversion takes place because the high amplitude phonon wave packet modulates the acoustic properties of the crystal which leads to self steepening and to the successive generation of higher harmonics of the phonon wave packet. Furthermore, we have demonstrated ultrafast strain in direction parallel to the sample surface. Two consecutive so-called transient grating excitations displaced in space and time are used to coherently control thermal gradients and surface acoustic modes. The amplitude of the coherent and incoherent surface excursion is disentangled by time resolved X-ray reflectivity measurements. We calibrate the absolute amplitude of thermal and acoustic surface excursion with measurements of longitudinal phonon propagation. In addition, we develop a diffraction model which allows for measuring the surface excursion on an absolute length scale with sub-{\"A}angstr{\"o}m precision. Finally, I demonstrate full coherent control of an excited surface deformation by amplifying and suppressing thermal and coherent excitations at the surface of a laser-excited Yttrium-manganite sample.}, language = {en} } @phdthesis{Sahlmann2002, author = {Sahlmann, Hanno}, title = {Coupling matter to loop quantum gravity}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-0000602}, school = {Universit{\"a}t Potsdam}, year = {2002}, abstract = {Motiviert durch neuere Vorschl{\"a}ge zur experimentellen Untersuchung von Quantengravitationseffekten werden in der vorliegenden Arbeit Annahmen und Methoden untersucht, die f{\"u}r die Vorhersagen solcher Effekte im Rahmen der Loop-Quantengravitation verwendet werden k{\"o}nnen. Dazu wird als Modellsystem ein skalares Feld, gekoppelt an das Gravitationsfeld, betrachtet. Zun{\"a}chst wird unter bestimmten Annahmen {\"u}ber die Dynamik des gekoppelten Systems eine Quantentheorie f{\"u}r das Skalarfeld vorgeschlagen. Unter der Annahme, dass sich das Gravitationsfeld in einem semiklassischen Zustand befindet, wird dann ein \"QFT auf gekr{\"u}mmter Raumzeit-Limes\" dieser Theorie definiert. Im Gegensatz zur gew{\"o}hnlichen Quantenfeldtheorie auf gekr{\"u}mmter Raumzeit beschreibt die Theorie in diesem Grenzfall jedoch ein quantisiertes Skalarfeld, das auf einem (klassisch beschriebenen) Zufallsgitter propagiert. Sodann werden Methoden vorgeschlagen, den Niederenergieliemes einer solchen Gittertheorie, vor allem hinsichtlich der resultierenden modifizierten Dispersonsrelation, zu berechnen. Diese Methoden werden anhand von einfachen Modellsystemen untersucht. Schließlich werden die entwickelten Methoden unter vereinfachenden Annahmen und der Benutzung einer speziellen Klasse von semiklassischen Zust{\"a}nden angewandt, um Korrekturen zur Dispersionsrelation des skalaren und des elektromagnetischen Feldes im Rahmen der Loop-Quantengravitation zu berechnen. Diese Rechnungen haben vorl{\"a}ufigen Charakter, da viele Annahmen eingehen, deren G{\"u}ltigkeit genauer untersucht werden muss. Zumindest zeigen sie aber Probleme und M{\"o}glichkeiten auf, im Rahmen der Loop-Quantengravitation Vorhersagen zu machen, die sich im Prinzip experimentell verifizieren lassen.}, language = {en} } @phdthesis{Sablowski2019, author = {Sablowski, Daniel}, title = {Spectroscopic analysis of the benchmark system Alpha Aurigae}, doi = {10.25932/publishup-43239}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-432396}, school = {Universit{\"a}t Potsdam}, pages = {169}, year = {2019}, abstract = {Binaries play an important role in observational and theoretical astrophysics. Since the mass and the chemical composition are key ingredients for stellar evolution, high-resolution spectroscopy is an important and necessary tool to derive those parameters to high confidence in binaries. This involves carefully measured orbital motion by the determination of radial velocity (RV) shifts and sophisticated techniques to derive the abundances of elements within the stellar atmosphere. A technique superior to conventional cross-correlation methods to determine RV shifts in known as spectral disentangling. Hence, a major task of this thesis was the design of a sophisticated software package for this approach. In order to investigate secondary effects, such as flux and line-profile variations, imprinting changes on the spectrum the behavior of spectral disentangling on such variability is a key to understand the derived values, to improve them, and to get information about the variability itself. Therefore, the spectral disentangling code presented in this thesis and available to the community combines multiple advantages: separation of the spectra for detailed chemical analysis, derivation of orbital elements, derivation of individual RVs in order to investigate distorted systems (either by third body interaction or relativistic effects), the suppression of telluric contaminations, the derivation of variability, and the possibility to apply the technique to eclipsing binaries (important for orbital inclination) or in general to systems that undergo flux-variations. This code in combination with the spectral synthesis codes MOOG and SME was used in order to derive the carbon 12C/13C isotope ratio (CIR) of the benchmark binary Capella. The observational result will be set into context with theoretical evolution by the use of MESA models and resolves the discrepancy of theory and observations existing since the first measurement of Capella's CIR in 1976. The spectral disentangling code has been made available to the community and its applicability to completely different behaving systems, Wolf-Rayet stars, have also been investigated and resulted in a published article. Additionally, since this technique relies strongly on data quality, continues development of scientific instruments to achieve best observational data is of great importance in observational astrophysics. That is the reason why there has also been effort in astronomical instrumentation during the work on this thesis.}, language = {en} } @phdthesis{SaadHassanin2018, author = {Saad Hassanin, Alshaimaa}, title = {Dynamic coronal mass ejection process and magnetic reconnection}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-419626}, school = {Universit{\"a}t Potsdam}, pages = {xix, 113}, year = {2018}, abstract = {The Sun is the nearest star to the Earth. It consists of an interior and an atmosphere. The convection zone is the outermost layer of the solar interior. A flux rope may emerge as a coherent structure from the convection zone into the solar atmosphere or be formed by magnetic reconnection in the atmosphere. A flux rope is a bundle of magnetic field lines twisting around an axis field line, creating a helical shape by which dense filament material can be supported against gravity. The flux rope is also considered as the key structure of the most energetic phenomena in the solar system, such as coronal mass ejections (CMEs) and flares. These magnetic flux ropes can produce severe geomagnetic storms. In particular, to improve the ability to forecast space weather, it is important to enrich our knowledge about the dynamic formation of flux ropes and the underlying physical mechanisms that initiate their eruption, such as a CME. A confined eruption consists of a filament eruption and usually an associated are, but does not evolve into a CME; rather, the moving plasma is halted in the solar corona and usually seen to fall back. The first detailed observations of a confined filament eruption were obtained on 2002 May 27by the TRACE satellite in the 195 A band. So, in the Chapter 3, we focus on a flux rope instability model. A twisted flux rope can become unstable by entering the kink instability regime. We show that the kink instability, which occurs if the twist of a flux rope exceeds a critical value, is capable of initiating of an eruption. This model is tested against the well observed confined eruption on 2002 May 27 in a parametric magnetohydrodynamic (MHD) simulation study that comprises all phases of the event. Very good agreement with the essential observed properties is obtained, only except for a relatively poor matching of the initial filament height. Therefore, in Chapter 4, we submerge the center point of the flux rope deeper below the photosphere to obtain a flatter coronal rope section and a better matching with the initial height profile of the erupting filament. This implies a more realistic inclusion of the photospheric line tying. All basic assumptions and the other parameter settings are kept the same as in Chapter 3. This complement of the parametric study shows that the flux rope instability model can yield an even better match with the observational data. We also focus in Chapters 3 and 4 on the magnetic reconnection during the confined eruption, demonstrating that it occurs in two distinct locations and phases that correspond to the observed brightenings and changes of topology, and consider the fate of the erupting flux, which can reform a (less twisted) flux rope. The Sun also produces series of homologous eruptions, i.e. eruptions which occur repetitively in the same active region and are of similar morphology. Therefore, in Chapter 5, we employ the reformed flux rope as a new initial condition, to investigate the possibility of subsequent homologous eruptions. Free magnetic energy is built up by imposing motions in the bottom boundary, such as converging motions, leading to flux cancellation. We apply converging motions in the sunspot area, such that a small part of the flux from the sunspots with different polarities is transported toward the polarity inversion line (PIL) and cancels with each other. The reconnection associated with the cancellation process forms more helical magnetic flux around the reformed flux rope, which leads to a second and a third eruption. In this study, we obtain the first MHD simulation results of a homologous sequence of eruptions that show a transition from a confined to two ejective eruptions, based on the reformation of a flux rope after each eruption.}, language = {en} } @phdthesis{Raetzel2013, author = {R{\"a}tzel, Dennis}, title = {Tensorial spacetime geometries and background-independent quantum field theory}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-65731}, school = {Universit{\"a}t Potsdam}, year = {2013}, abstract = {Famously, Einstein read off the geometry of spacetime from Maxwell's equations. Today, we take this geometry that serious that our fundamental theory of matter, the standard model of particle physics, is based on it. However, it seems that there is a gap in our understanding if it comes to the physics outside of the solar system. Independent surveys show that we need concepts like dark matter and dark energy to make our models fit with the observations. But these concepts do not fit in the standard model of particle physics. To overcome this problem, at least, we have to be open to matter fields with kinematics and dynamics beyond the standard model. But these matter fields might then very well correspond to different spacetime geometries. This is the basis of this thesis: it studies the underlying spacetime geometries and ventures into the quantization of those matter fields independently of any background geometry. In the first part of this thesis, conditions are identified that a general tensorial geometry must fulfill to serve as a viable spacetime structure. Kinematics of massless and massive point particles on such geometries are introduced and the physical implications are investigated. Additionally, field equations for massive matter fields are constructed like for example a modified Dirac equation. In the second part, a background independent formulation of quantum field theory, the general boundary formulation, is reviewed. The general boundary formulation is then applied to the Unruh effect as a testing ground and first attempts are made to quantize massive matter fields on tensorial spacetimes.}, language = {en} } @phdthesis{Rust2007, author = {Rust, Henning}, title = {Detection of long-range dependence : applications in climatology and hydrology}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-13347}, school = {Universit{\"a}t Potsdam}, year = {2007}, abstract = {It is desirable to reduce the potential threats that result from the variability of nature, such as droughts or heat waves that lead to food shortage, or the other extreme, floods that lead to severe damage. To prevent such catastrophic events, it is necessary to understand, and to be capable of characterising, nature's variability. Typically one aims to describe the underlying dynamics of geophysical records with differential equations. There are, however, situations where this does not support the objectives, or is not feasible, e.g., when little is known about the system, or it is too complex for the model parameters to be identified. In such situations it is beneficial to regard certain influences as random, and describe them with stochastic processes. In this thesis I focus on such a description with linear stochastic processes of the FARIMA type and concentrate on the detection of long-range dependence. Long-range dependent processes show an algebraic (i.e. slow) decay of the autocorrelation function. Detection of the latter is important with respect to, e.g. trend tests and uncertainty analysis. Aiming to provide a reliable and powerful strategy for the detection of long-range dependence, I suggest a way of addressing the problem which is somewhat different from standard approaches. Commonly used methods are based either on investigating the asymptotic behaviour (e.g., log-periodogram regression), or on finding a suitable potentially long-range dependent model (e.g., FARIMA[p,d,q]) and test the fractional difference parameter d for compatibility with zero. Here, I suggest to rephrase the problem as a model selection task, i.e.comparing the most suitable long-range dependent and the most suitable short-range dependent model. Approaching the task this way requires a) a suitable class of long-range and short-range dependent models along with suitable means for parameter estimation and b) a reliable model selection strategy, capable of discriminating also non-nested models. With the flexible FARIMA model class together with the Whittle estimator the first requirement is fulfilled. Standard model selection strategies, e.g., the likelihood-ratio test, is for a comparison of non-nested models frequently not powerful enough. Thus, I suggest to extend this strategy with a simulation based model selection approach suitable for such a direct comparison. The approach follows the procedure of a statistical test, with the likelihood-ratio as the test statistic. Its distribution is obtained via simulations using the two models under consideration. For two simple models and different parameter values, I investigate the reliability of p-value and power estimates obtained from the simulated distributions. The result turned out to be dependent on the model parameters. However, in many cases the estimates allow an adequate model selection to be established. An important feature of this approach is that it immediately reveals the ability or inability to discriminate between the two models under consideration. Two applications, a trend detection problem in temperature records and an uncertainty analysis for flood return level estimation, accentuate the importance of having reliable methods at hand for the detection of long-range dependence. In the case of trend detection, falsely concluding long-range dependence implies an underestimation of a trend and possibly leads to a delay of measures needed to take in order to counteract the trend. Ignoring long-range dependence, although present, leads to an underestimation of confidence intervals and thus to an unjustified belief in safety, as it is the case for the return level uncertainty analysis. A reliable detection of long-range dependence is thus highly relevant in practical applications. Examples related to extreme value analysis are not limited to hydrological applications. The increased uncertainty of return level estimates is a potentially problem for all records from autocorrelated processes, an interesting examples in this respect is the assessment of the maximum strength of wind gusts, which is important for designing wind turbines. The detection of long-range dependence is also a relevant problem in the exploration of financial market volatility. With rephrasing the detection problem as a model selection task and suggesting refined methods for model comparison, this thesis contributes to the discussion on and development of methods for the detection of long-range dependence.}, language = {en} }