@article{DiezTauerSchulz2006,
  author    = {Diez, Isabel and Tauer, Klaus and Schulz, Burkhard},
  title     = {Unusual polymer dispersions-polypyrrole suspensions made of rings, frames, and platelets},
  series = {Colloid and polymer science : official journal of the Kolloid-Gesellschaft},
  volume    = {284},
  journal   = {Colloid and polymer science : official journal of the Kolloid-Gesellschaft},
  publisher = {Springer},
  address   = {New York},
  issn      = {0303-402X},
  doi       = {10.1007/s00396-006-1521-8},
  pages     = {1431 -- 1442},
  year      = {2006},
  abstract  = {Experimental results show that the polymerization of pyrrole in the presence of beta-naphthalenesulfonic acid and different fluorosurfactants like perfluorooctanesulfonic acid, perfluorooctyldiethanolamide, and ammonium perfluorooctanoate leads to polypyrrole with special morphologies, such as rings or disks and rectangular frames or plates. The formation of these unusually shaped particles of polymer dispersions is explained by the chemical and colloidal peculiarities of the oxidative pyrrole polymerization with ammonium peroxodisulfate in aqueous medium.},
  language  = {en}
}
@article{SchulzDietzelOrgzalletal.2009,
  author    = {Schulz, Burkhard and Dietzel, Birgit and Orgzall, Ingo and Diez, Isabel and Xu, Chenggang},
  title     = {Aspects of morphology control during the oxidative synthesis of electrically conducting polymers},
  issn      = {0954-0083},
  doi       = {10.1177/0954008309339933},
  year      = {2009},
  abstract  = {The formation of micro- and nanostructures during the oxidative polymerization of polypyrrole and polyaniline is investigated using different sulfonic acid dopants. Rod- or tube-like structures are found in polypyrrole as well as in polyaniline without addition of further compounds to the initial reaction mixture of monomer, dopant and oxidant. In these cases, always a crystalline precursor complex composed of a dopand molecule and the pure monomer (aniline) or a trimeric moiety (pyrrole) serves as in-situ template. In most cases the surface of the growing polymer is covered by secondary structures with much smaller sizes so that a hierarchical order of structures at different length scales results. Corresponding model considerations for the polymerization process are outlined. Additionally, unusual structures like platelets, frames, rings, or ribbons are observed in the polypyrrole synthesis in the presence of fluorosurfactants.},
  language  = {en}
}
@article{SchulzOrgzallDiezetal.2010,
  author    = {Schulz, Burkhard and Orgzall, Ingo and Diez, Isabel and Dietzel, Birgit and Tauer, Klaus},
  title     = {Template mediated formation of shaped polypyrrole particles},
  issn      = {0927-7757},
  doi       = {10.1016/j.colsurfa.2009.11.034},
  year      = {2010},
  abstract  = {The formation of different micro- and nanostructures during the chemical synthesis of polypyrrole is reviewed shortly based on the conceptions of hard- and soft-templating models. Contrary to other models that emphasize the role of micelles it is found here that during the oxidative polymerization of pyrole using sulfonic acid dopants a crystalline hard template is found in the first steps of the reaction before the addition of the oxidant. This template is formed by a complex consisting of 2,5-bis(pyrrole-2-yl)pyrrolidine and the sulfonic acid anion. The acid catalyzed formation of this specific tripyrrole is discussed. (C) 2009 Elsevier B.V. All rights reserved.},
  language  = {en}
}