@phdthesis{Duemke2015, author = {D{\"u}mke, Christian}, title = {Daseinsvorsorge, Wettbewerb und kommunale Selbstverwaltung im Bereich der liberalisierten Energiewirtschaft}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, isbn = {978-3-86956-314-5}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-73914}, school = {Universit{\"a}t Potsdam}, pages = {175}, year = {2015}, abstract = {Die Arbeit befasst sich zun{\"a}chst mit der Analyse und Einordnung des Begriffs der Daseinsvorsorge und deren Erbringung durch den Staat. Schwerpunkt der Betrachtung bildet dabei die Energieversorgung als klassische Aufgabe staatlicher Daseinsvorsorge. Weiterhin wird der durch die Liberalisierung der Energieversorgung im Jahr 1998 eingeleitete Wandel von sog. nat{\"u}rlichen Monopolen, hin zu einem wettbewerblichen System betrachtet. Dabei wird aufgezeigt, dass sich durch die Einf{\"u}hrung des Wettbewerbs weder die damit erhofften Kostenreduzierungen, noch das von Kritikern bef{\"u}rchtete Sterben der kommunalen Energieversorger bewahrheitet haben. Statt einer freien Preisbildung im Wettbewerb ist es zu einer faktischen Verlagerung der fr{\"u}her staatlich festgesetzten Energiepreisgenehmigung auf die Gerichte gekommen, die hierf{\"u}r jedoch nicht ausgelegt sind. Kommunale Stadtwerke haben sich in der wettbewerblichen Energieversorgung dagegen so gut behauptet, dass seit einiger Zeit ein Trend zur Rekommunalisierung von Energieversorgung auf kommunaler Ebene zu verzeichnen ist. Diesem offensichtlichen Wunsch nach einer gesteigerten Einflussnahme der Gemeinden auf die {\"o}rtliche Energieversorgung l{\"a}uft der aktuelle Rechtsrahmen der energierechtlichen Konzessionsvergabe in Gestalt des \S 46 EnWG und seiner Auslegung durch die Rechtsprechung der Zivilgerichte zuwider. Die Arbeit zeigt auf, dass von Beginn der Liberalisierung der kommunale Einfluss auf die {\"o}rtliche Konzessionsvergabe schrittweise und stetig beschnitten wurde, so dass gegenw{\"a}rtig ein Zustand der Aush{\"o}hlung erreicht ist, der als unzul{\"a}ssiger Eingriff in den gesch{\"u}tzten Kernbereich der kommunalen Selbstverwaltungsgarantie i.S.d. Art. 28 II GG anzusehen ist.}, language = {de} } @phdthesis{Zajnulina2015, author = {Zajnulina, Marina}, title = {Optical frequency comb generation in optical fibres}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-88776}, school = {Universit{\"a}t Potsdam}, pages = {xii, 103}, year = {2015}, abstract = {Optical frequency combs (OFC) constitute an array of phase-correlated equidistant spectral lines with nearly equal intensities over a broad spectral range. The adaptations of combs generated in mode-locked lasers proved to be highly efficient for the calibration of high-resolution (resolving power > 50000) astronomical spectrographs. The observation of different galaxy structures or the studies of the Milky Way are done using instruments in the low- and medium resolution range. To such instruments belong, for instance, the Multi Unit Spectroscopic Explorer (MUSE) being developed for the Very Large Telescope (VLT) of the European Southern Observatory (ESO) and the 4-metre Multi-Object Spectroscopic Telescope (4MOST) being in development for the ESO VISTA 4.1 m Telescope. The existing adaptations of OFC from mode-locked lasers are not resolvable by these instruments. Within this work, a fibre-based approach for generation of OFC specifically in the low- and medium resolution range is studied numerically. This approach consists of three optical fibres that are fed by two equally intense continuous-wave (CW) lasers. The first fibre is a conventional single-mode fibre, the second one is a suitably pumped amplifying Erbium-doped fibre with anomalous dispersion, and the third one is a low-dispersion highly nonlinear optical fibre. The evolution of a frequency comb in this system is governed by the following processes: as the two initial CW-laser waves with different frequencies propagate through the first fibre, they generate an initial comb via a cascade of four-wave mixing processes. The frequency components of the comb are phase-correlated with the original laser lines and have a frequency spacing that is equal to the initial laser frequency separation (LFS), i.e. the difference in the laser frequencies. In the time domain, a train of pre-compressed pulses with widths of a few pico-seconds arises out of the initial bichromatic deeply-modulated cosine-wave. These pulses undergo strong compression in the subsequent amplifying Erbium-doped fibre: sub-100 fs pulses with broad OFC spectra are formed. In the following low-dispersion highly nonlinear fibre, the OFC experience a further broadening and the intensity of the comb lines are fairly equalised. This approach was mathematically modelled by means of a Generalised Nonlinear Schr{\"o}dinger Equation (GNLS) that contains terms describing the nonlinear optical Kerr effect, the delayed Raman response, the pulse self-steepening, and the linear optical losses as well as the wavelength-dependent Erbium gain profile for the second fibre. The initial condition equation being a deeply-modulated cosine-wave mimics the radiation of the two initial CW lasers. The numerical studies are performed with the help of Matlab scripts that were specifically developed for the integration of the GNLS and the initial condition according to the proposed approach for the OFC generation. The scripts are based on the Fourth-Order Runge-Kutta in the Interaction Picture Method (RK4IP) in combination with the local error method. This work includes the studies and results on the length optimisation of the first and the second fibre depending on different values of the group-velocity dispersion of the first fibre. Such length optimisation studies are necessary because the OFC have the biggest possible broadband and exhibit a low level of noise exactly at the optimum lengths. Further, the optical pulse build-up in the first and the second fibre was studied by means of the numerical technique called Soliton Radiation Beat Analysis (SRBA). It was shown that a common soliton crystal state is formed in the first fibre for low laser input powers. The soliton crystal continuously dissolves into separated optical solitons as the input power increases. The pulse formation in the second fibre is critically dependent on the features of the pulses formed in the first fibre. I showed that, for low input powers, an adiabatic soliton compression delivering low-noise OFC occurs in the second fibre. At high input powers, the pulses in the first fibre have more complicated structures which leads to the pulse break-up in the second fibre with a subsequent degradation of the OFC noise performance. The pulse intensity noise studies that were performed within the framework of this thesis allow making statements about the noise performance of an OFC. They showed that the intensity noise of the whole system decreases with the increasing value of LFS.}, language = {en} } @phdthesis{Prokhorov2015, author = {Prokhorov, Boris E.}, title = {High-latitude coupling processes between thermospheric circulation and solar wind driven magnetospheric currents and plasma convection}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-92353}, school = {Universit{\"a}t Potsdam}, pages = {117}, year = {2015}, abstract = {The high-latitudinal thermospheric processes driven by the solar wind and Interplanetary Magnetic Field (IMF) interaction with the Earth magnetosphere are highly variable parts of the complex dynamic plasma environment, which represent the coupled Magnetosphere - Ionosphere - Thermosphere (MIT) system. The solar wind and IMF interactions transfer energy to the MIT system via reconnection processes at the magnetopause. The Field Aligned Currents (FACs) constitute the energetic links between the magnetosphere and the Earth ionosphere. The MIT system depends on the highly variable solar wind conditions, in particular on changes of the strength and orientation of the IMF. In my thesis, I perform an investigation on the physical background of the complex MIT system using the global physical - numerical, three-dimensional, time-dependent and self-consistent Upper Atmosphere Model (UAM). This model describes the thermosphere, ionosphere, plasmasphere and inner magnetosphere as well as the electrodynamics of the coupled MIT system for the altitudinal range from 80 (60) km up to the 15 Earth radii. In the present study, I developed and investigated several variants of the high-latitudinal electrodynamic coupling by including the IMF dependence of FACs into the UAM model. For testing, the various variants were applied to simulations of the coupled MIT system for different seasons, geomagnetic activities, various solar wind and IMF conditions. Additionally, these variants of the theoretical model with the IMF dependence were compared with global empirical models. The modelling results for the most important thermospheric parameters like neutral wind and mass density were compared with satellite measurements. The variants of the UAM model with IMF dependence show a good agreement with the satellite observations. In comparison with the empirical models, the improved variants of the UAM model reproduce a more realistic meso-scale structures and dynamics of the coupled MIT system than the empirical models, in particular at high latitudes. The new configurations of the UAM model with IMF dependence contribute to the improvement of space weather prediction.}, language = {en} } @phdthesis{Papendiek2015, author = {Papendiek, Franka}, title = {Fodder legumes for Green Biorefineries}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-87198}, school = {Universit{\"a}t Potsdam}, pages = {XI, 111}, year = {2015}, abstract = {Peak oil is forcing our society to shift from fossil to renewable resources. However, such renewable resources are also scarce, and they too must be used in the most efficient and sustainable way possible. Biorefining is a concept that represents both resource efficiency and sustainability. This approach initiates a cascade use, which means food and feed production before material use, and an energy-related use at the end of the value-added chain. However, sustainability should already start in the fields, on the agricultural side, where the industrially-used biomass is produced. Therefore, the aim of my doctoral thesis is to analyse the sustainable feedstock supply for biorefineries. In contrast to most studies on biorefineries, I focus on the sustainable provision of feedstock and not on the bioengineering processing of whatever feedstock is available. Grasslands provide a high biomass potential. They are often inefficiently used, so a new utilisation concept based on the biorefining approach can increase the added value from grasslands. Fodder legumes from temporary and permanent grasslands were chosen for this study. Previous research shows that they are a promising feedstock for industrial uses, and their positive environmental impact is an important byproduct to promote sustainable agricultural production systems. Green Biorefineries are a class of biorefineries that use fresh green biomass, such as grasses or fodder legumes, as feedstock. After fractionation, an organic solution (press juice) forms; this is used for the production of organic acids, chemicals and extracts, as well as fertilisers. A fibre component (press cake) is also created to produce feed, biomaterials and biogas. This thesis examines a specific value chain, using alfalfa and clover/grass as feedstock and generating lactic acid and one type of cattle feed from it. The research question is if biomass production needs to be adapted for the utilisation of fodder legumes in the Green Biorefinery approach. I have attempted to give a holistic analysis of cultivation, processing and utilisation of two specific grassland crops. Field trials with alfalfa and clover/grass at different study sites were carried out to obtain information on biomass quality and quantity depending on the crop, study site and harvest time. The fresh biomass was fractionated with a screw press and the composition of press juices and cakes was analysed. Fermentation experiments took place to determine the usability of press juices for lactic acid production. The harvest time is not of high importance for the quality of press juices as a fermentation medium. For permanent grasslands, late cuts, often needed for reasons of nature conservation, are possible without a major influence on feedstock quality. The press cakes were silaged for feed-value determination. Following evidence that both intermediate products are suitable feedstocks in the Green Biorefinery approach, I developed a cost-benefit analysis, comparing different production scenarios on a farm. Two standard crop rotations for Brandenburg, producing either only market crops or market crops and fodder legumes for ruminant feed production, were compared to a system that uses the cultivated fodder legumes for the Green Biorefinery value chain instead of only feed production. Timely processing of the raw material is important to maintain quality for industrial uses, so on-site processing at the farm is assumed in Green Biorefinery scenario. As a result, more added value stays in the rural area. Two farm sizes, common for many European regions, were chosen to examine the influence of scale. The cost site of farmers has also been analysed in detail to assess which farm characteristics make production of press juices for biochemical industries viable. Results show that for large farm sizes in particular, the potential profits are high. Additionally, the wider spectrum of marketable products generates new sources of income for farmers. The holistic analysis of the supply chain provides evidence that the cultivation processes for fodder legumes do not need to be adapted for use in Green Biorefineries. In fact, the new utilisation approach even widens the cultivation and processing spectrum and can increase economic viability of fodder legume production in conventional farming.}, language = {en} } @phdthesis{Mai2015, author = {Mai, Michael}, title = {Migrationsdiskurse in der deutschen Grenzregion zu Polen}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-87015}, school = {Universit{\"a}t Potsdam}, pages = {294}, year = {2015}, abstract = {In der vorliegenden Dissertation werden Migrationsdiskurse in der deutschen Grenzregion zu Polen im Vorfeld der EU-Erweiterung zum 1. Mai 2004 exemplarisch in drei deutschen Grenzst{\"a}dten, der jeweils westliche Teil der ehemals gemeinsamen, seit 1945 durch eine nationalstaatliche Grenze mit dem jeweils zeitspezifischen Grenzregime geteilten, deutsch-polnischen Zwillingsst{\"a}dte Frankfurt (Oder) - Słubice, Guben - Gubin und G{\"o}rlitz - Zgorzelec, analysiert. Ausgew{\"a}hlt wurde der Untersuchungsraum mit Blick auf die tiefgreifenden europ{\"a}ischen Transformationsprozesse seit den sp{\"a}ten 1980er Jahren, die f{\"u}r die {\"o}rtliche Bev{\"o}lkerung gravierende lebensweltliche Strukturumbr{\"u}che zur Folge hatten. Die Region wurde mit der Vereinigung der beiden deutschen Staaten {\"u}berdies zu einem zentralen Aktionsraum nationaler und internationaler Migrationspolitik; ihr wurde eine wichtige stellvertretende Funktion betreffend die Zutrittsregelung zugewiesen. Mit der EU-Erweiterung waren f{\"u}r die Region neuerliche, unmittelbare Ver{\"a}nderungen verbunden, die vor Ort gerade auch aufgrund damit (mutmaßlich) einhergehender Migration eher als Bedrohung denn als Chance gedeutet wurden. Den diskurstheoretischen Hintergrund der Untersuchungen stellen in erster Linie die Arbeiten von Michel Foucault und die von Siegfried J{\"a}ger darauf aufruhend konzipierte Kritische Diskursanalyse bereit. Diskurs wird - grob vereinfacht - als Fluss von sozialen Wissensbest{\"a}nden und Bewusstseinsinhalten durch die Zeit verstanden, der individuelles und kollektives Handeln von Menschen bestimmt; Diskurse sind der Ort, an dem (Be-)Deutungen von Menschen ausgehandelt, ver{\"a}ndert und der Wirklichkeit zugewiesen werden. Der Forschungszugang versteht sich als Teil der Neuen Kulturgeographie, die konsequent nicht-essentialistisch und erkenntnistheoretisch nicht-fundamentalistisch ist. Die Datenbasis der empirischen Analysen repr{\"a}sentieren zwei Ebenen bzw. Teilsektoren des Diskurses. Zum einen die Berichterstattung der jeweils monopolartigen regionalen Tageszeitung in Frankfurt (Oder), Guben und G{\"o}rlitz (M{\"a}rkische Oderzeitung/Frankfurter Stadtbote, Lausitzer Rundschau/Lokalausgabe Guben, S{\"a}chsische Zeitung/G{\"o}rlitzer Zeitung). Zum anderen ein Sample von insgesamt 17 Experteninterviews mit lokalen Funktionstr{\"a}gern, die mit Blick auf ihr, an ihre spezifische professionelle und/oder ehrenamtliche T{\"a}tigkeit gebundenes, praxisges{\"a}ttigtes Sonder- bzw. Insiderwissen zum Thema Migration ausgew{\"a}hlt und befragt wurden. Die durchgef{\"u}hrten Analysen verdeutlichen unter anderem die Bedeutung diskurssemantischer Grundfiguren des deutschen Migrationsdiskurses im Sinne politisch und alltagskulturell konservierter migrationskritischer Vorstellungsinhalte und Bedeutungszuweisungen zu Kategorien des Fremden und Konstruktionen von Wir und/vs. Sie. Ebenso explizieren sie eine gravierende Diskrepanz zwischen dem lokalen Staat und der Lebenswelt der lokalen Bev{\"o}lkerung.}, language = {de} } @phdthesis{Cattania2015, author = {Cattania, Camilla}, title = {Improvement of aftershock models based on Coulomb stress changes and rate-and-state dependent friction}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-87097}, school = {Universit{\"a}t Potsdam}, pages = {xvi, 123}, year = {2015}, abstract = {Earthquake clustering has proven the most useful tool to forecast changes in seismicity rates in the short and medium term (hours to months), and efforts are currently being made to extend the scope of such models to operational earthquake forecasting. The overarching goal of the research presented in this thesis is to improve physics-based earthquake forecasts, with a focus on aftershock sequences. Physical models of triggered seismicity are based on the redistribution of stresses in the crust, coupled with the rate-and-state constitutive law proposed by Dieterich to calculate changes in seismicity rate. This type of models are known as Coulomb- rate and-state (CRS) models. In spite of the success of the Coulomb hypothesis, CRS models typically performed poorly in comparison to statistical ones, and they have been underepresented in the operational forecasting context. In this thesis, I address some of these issues, and in particular these questions: (1) How can we realistically model the uncertainties and heterogeneity of the mainshock stress field? (2) What is the effect of time dependent stresses in the postseismic phase on seismicity? I focus on two case studies from different tectonic settings: the Mw 9.0 Tohoku megathrust and the Mw 6.0 Parkfield strike slip earthquake. I study aleatoric uncertainties using a Monte Carlo method. I find that the existence of multiple receiver faults is the most important source of intrinsic stress heterogeneity, and CRS models perform better when this variability is taken into account. Epistemic uncertainties inherited from the slip models also have a significant impact on the forecast, and I find that an ensemble model based on several slip distributions outperforms most individual models. I address the role of postseismic stresses due to aseismic slip on the mainshock fault (afterslip) and to the redistribution of stresses by previous aftershocks (secondary triggering). I find that modeling secondary triggering improves model performance. The effect of afterslip is less clear, and difficult to assess for near-fault aftershocks due to the large uncertainties of the afterslip models. Off-fault events, on the other hand, are less sensitive to the details of the slip distribution: I find that following the Tohoku earthquake, afterslip promotes seismicity in the Fukushima region. To evaluate the performance of the improved CRS models in a pseudo-operational context, I submitted them for independent testing to a collaborative experiment carried out by CSEP for the 2010-2012 Canterbury sequence. Preliminary results indicate that physical models generally perform well compared to statistical ones, suggesting that CRS models may have a role to play in the future of operational forecasting. To facilitate efforts in this direction, and to enable future studies of earthquake triggering by time dependent processes, I have made the code open source. In the final part of this thesis I summarize the capabilities of the program and outline technical aspects regarding performance and parallelization strategies.}, language = {en} } @phdthesis{Hildebrandt2015, author = {Hildebrandt, Dominik}, title = {The HI Lyman-alpha opacity at redshift 2.7 < z < 3.6}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-78355}, school = {Universit{\"a}t Potsdam}, pages = {xiv, 292}, year = {2015}, abstract = {Most of the baryonic matter in the Universe resides in a diffuse gaseous phase in-between galaxies consisting mostly of hydrogen and helium. This intergalactic medium (IGM) is distributed in large-scale filaments as part of the overall cosmic web. The luminous extragalactic objects that we can observe today, such as galaxies and quasars, are surrounded by the IGM in the most dense regions within the cosmic web. The radiation of these objects contributes to the so-called ultraviolet background (UVB) which keeps the IGM highly ionized ever since the epoch of reionization. Measuring the amount of absorption due to intergalactic neutral hydrogen (HI) against extragalactic background sources is a very useful tool to constrain the energy input of ionizing sources into the IGM. Observations suggest that the HI Lyman-alpha effective optical depth, τ_eff, decreases with decreasing redshift, which is primarily due to the expansion of the Universe. However, some studies find a smaller value of the effective optical depth than expected at the specific redshift z~3.2, possibly related to the complete reionization of helium in the IGM and a hardening of the UVB. The detection and possible cause of a decrease in τ_eff at z~3.2 is controversially debated in the literature and the observed features need further explanation. To better understand the properties of the mean absorption at high redshift and to provide an answer for whether the detection of a τ_eff feature is real we study 13 high-resolution, high signal-to-noise ratio quasar spectra observed with the Ultraviolet and Visual Echelle Spectrograph (UVES) at the Very Large Telescope (VLT). The redshift evolution of the effective optical depth, τ_eff(z), is measured in the redshift range 2.7≤z≤3.6. The influence of metal absorption features is removed by performing a comprehensive absorption-line-fitting procedure. In the first part of the thesis, a line-parameter analysis of the column density, N, and Doppler parameter, b, of ≈7500 individually fitted absorption lines is performed. The results are in good agreement with findings from previous surveys. The second (main) part of this thesis deals with the analysis of the redshift evolution of the effective optical depth. The τ_eff measurements vary around the empirical power law τ_eff(z)~(1+z)^(γ+1) with γ=2.09±0.52. The same analysis as for the observed spectra is performed on synthetic absorption spectra. From a comparison between observed and synthetic spectral data it can be inferred that the uncertainties of the τ_eff values are likely underestimated and that the scatter is probably caused by high-column-density absorbers with column densities in the range 15≤logN≤17. In the real Universe, such absorbers are rarely observed, however. Hence, the difference in τ_eff from different observational data sets and absorption studies is most likely caused by cosmic variance. If, alternatively, the disagreement between such data is a result of an too optimistic estimate of the (systematic) errors, it is also possible that all τ_eff measurements agree with a smooth evolution within the investigated redshift range. To explore in detail the different analysis techniques of previous studies an extensive literature comparison to the results of this work is presented in this thesis. Although a final explanation for the occurrence of the τ_eff deviation in different studies at z~3.2 cannot be given here, our study, which represents the most detailed line-fitting analysis of its kind performed at the investigated redshifts so far, represents another important benchmark for the characterization of the HI Ly-alpha effective optical depth at high redshift and its indicated unusual behavior at z~3.2.}, language = {en} } @phdthesis{Wettstein2015, author = {Wettstein, Christoph}, title = {Cytochrome c-DNA and cytochrome c-enzyme interactions for the construction of analytical signal chains}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-78367}, school = {Universit{\"a}t Potsdam}, pages = {120}, year = {2015}, abstract = {Electron transfer (ET) reactions play a crucial role in the metabolic pathways of all organisms. In biotechnological approaches, the redox properties of the protein cytochrome c (cyt c), which acts as an electron shuttle in the respiratory chain, was utilized to engineer ET chains on electrode surfaces. With the help of the biopolymer DNA, the redox protein assembles into electro active multilayer (ML) systems, providing a biocompatible matrix for the entrapment of proteins. In this study the characteristics of the cyt c and DNA interaction were defined on the molecular level for the first time and the binding sites of DNA on cyt c were identified. Persistent cyt c/DNA complexes were formed in solution under the assembly conditions of ML architectures, i.e. pH 5.0 and low ionic strength. At pH 7.0, no agglomerates were formed, permitting the characterization of the NMR spectroscopy. Using transverse relaxation-optimized spectroscopy (TROSY)-heteronuclear single quantum coherence (HSQC) experiments, DNAs' binding sites on the protein were identified. In particular, negatively charged AA residues, which are known interaction sites in cyt c/protein binding were identified as the main contact points of cyt c and DNA. Moreover, the sophisticated task of arranging proteins on electrode surfaces to create functional ET chains was addressed. Therefore, two different enzyme types, the flavin dependent fructose dehydrogenase (FDH) and the pyrroloquinoline quinone dependent glucose dehydrogenase (PQQ-GDH), were tested as reaction partners of freely diffusing cyt c and cyt c immobilized on electrodes in mono- and MLs. The characterisation of the ET processes was performed by means of electrochemistry and the protein deposition was monitored by microgravimetric measurements. FDH and PQQ-GDH were found to be generally suitable for combination with the cyt c/DNA ML system, since both enzymes interact with cyt c in solution and in the immobilized state. The immobilization of FDH and cyt c was achieved with the enzyme on top of a cyt c monolayer electrode without the help of a polyelectrolyte. Combining FDH with the cyt c/DNA ML system did not succeed, yet. However, the basic conditions for this protein-protein interaction were defined. PQQ-GDH was successfully coupled with the ML system, demonstrating that that the cyt c/DNA ML system provides a suitable interface for enzymes and that the creation of signal chains, based on the idea of co-immobilized proteins is feasible. Future work may be directed to the investigation of cyt c/DNA interaction under the precise conditions of ML assembly. Therefore, solid state NMR or X-ray crystallography may be required. Based on the results of this study, the combination of FDH with the ML system should be addressed. Moreover, alternative types of enzymes may be tested as catalytic component of the ML assembly, aiming on the development of innovative biosensor applications.}, language = {en} } @phdthesis{Rajasundaram2015, author = {Rajasundaram, Dhivyaa}, title = {Integrative analysis of heterogeneous plant cell wall related data}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-77652}, school = {Universit{\"a}t Potsdam}, pages = {xii, 205}, year = {2015}, abstract = {Plant cell walls are complex structures that underpin plant growth and are widely exploited in diverse human activities thus placing them with a central importance in biology. Cell walls have been a prominent area of research for a long time, but the chemical complexity and diversity of cell walls not just between species, but also within plants, between cell-types, and between cell wall micro-domains pose several challenges. Progress accelerated several-fold in cell wall biology owing to advances in sequencing technology, aided soon thereafter by advances in omics and imaging technologies. This development provides additional perspectives of cell walls across a rapidly growing number of species, highlighting a myriad of architectures, compositions, and functions. Furthermore, rather than the component centric view, integrative analysis of the different cell wall components across system-levels help to gain a more in-depth understanding of the structure and biosynthesis of the cell envelope and its interactions with the environment. To this end, in this work three case studies are detailed, all pertaining to the integrative analysis of heterogeneous cell wall related data arising from different system-levels and analytical techniques. A detailed account of multiblock methods is provided and in particular canonical correlation and regression methods of data integration are discussed. In the first integrative analysis, by employing canonical correlation analysis - a multivariate statistical technique to study the association between two datasets - novel insight to the relationship between glycans and phenotypic traits is gained. In addition, sparse partial least squares regression approach that adapts Lasso penalization and allows for the selection of a subset of variables was employed. The second case study focuses on an integrative analysis of images obtained from different spectroscopic techniques. By employing yet another multiblock approach - multiple co-inertia analysis, insitu biochemical composition of cell walls from different cell-types is studied thereby highlighting the common and complementary parts of the two hyperspectral imaging techniques. Finally, the third integrative analysis facilitates gene expression analysis of the Arabidopsis root transcriptome and translatome for the identification of cell wall related genes and compare expression patterns of cell wall synthesis genes. The computational analysis considered correlation and variation of expression across cell-types at both system-levels, and also provides insight into the degree of co-regulatory relationships that are preserved between the two processes. The integrative analysis of glycan data and phenotypic traits in cotton fibers using canonical methods led to the identification of specific polysaccharides which may play a major role during fiber development for the final fiber characteristics. Furthermore, this analysis provides a base for future studies on glycan arrays in case of developing cotton fibers. The integrative analysis of images from infrared and Raman spectroscopic approaches allowed the coupling of different analytical techniques to characterize complex biological material, thereby, representing various facets of their chemical properties. Moreover, the results from the co-inertia analysis demonstrated that the study was well adapted as it is relevant for coupling data tables in a symmetric way. Several indicators are proposed to investigate how the global and block scores are related. In addition, studying the root cells of \textit{Arabidopsis thaliana} allowed positing a novel pipeline to systematically investigate and integrate the different levels of information available at the global and single-cell level. The conducted analysis also confirms that previously identified key transcriptional activators of secondary cell wall development display highly conserved patterns of transcription and translation across the investigated cell-types. Moreover, the biological processes that display conserved and divergent patterns based on the cell-type-specific expression and translation levels are identified.}, language = {en} } @phdthesis{Schubert2015, author = {Schubert, Tobias}, title = {Der Kampf um das digitalisierte Breitbandkabel}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-77662}, school = {Universit{\"a}t Potsdam}, pages = {356}, year = {2015}, abstract = {Der klassische Fernsehrundfunk genießt verfassungsrechtlich und einfachgesetzliche eine privilegierte Sonderstellung. Diese setzt sich bei der Kabelbelegung fort, wo er - insbesondere der {\"o}ffentliche Rundfunk - gegen{\"u}ber teemedialen Anrufangeboten bevorrechtigt wird. Hintergrund dieser Sonderstellung ist nicht zuletzt die auf den Rundfunk zentrierte Medienordnung. Die Arbeit untersucht, ob diese Medienordnung und damit die Sonderstellung des Rundfunks noch zeitgem{\"a}ß ist und schl{\"a}gt Anpassungen vor.}, language = {de} } @phdthesis{Frenzel2015, author = {Frenzel, Sabine}, title = {Die Rolle der Umamirezeptoruntereinheit Tas1r1 jenseits ihrer gustatorischen Bedeutung}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-79502}, school = {Universit{\"a}t Potsdam}, pages = {XV, 172}, year = {2015}, abstract = {Aminos{\"a}uren sind lebensnotwendige Molek{\"u}le f{\"u}r alle Organismen. Ihre Erkennung im K{\"o}rper erm{\"o}glicht eine bedarfsgerechte Regulation ihrer Aufnahme und ihrer Verwertung. Welcher Chemosensor f{\"u}r diese Erkennung jedoch hauptverantwortlich ist, ist bisher unklar. In der vorliegenden Arbeit wurde die Rolle der Umamigeschmacksrezeptoruntereinheit Tas1r1 jenseits ihrer gustatorischen Bedeutung f{\"u}r die Aminos{\"a}uredetektion in der Mundh{\"o}hle untersucht. In der histologischen Tas1r1-Expressionsanalyse nichtgustatorischer Gewebe der Mauslinie Tas1r1-Cre/ROSA26-tdRFP wurde {\"u}ber die Detektion des Reporterproteins tdRFP die Expression des Tas1r1 in allen untersuchten Geweben (Speiser{\"o}hre, Magen, Darm, Bauchspeicheldr{\"u}se, Leber, Niere, Muskel- und Fettgewebe, Milz, Thymus, Lymphknoten, Lunge sowie Hoden) nachgewiesen. Mit Ausnahme von D{\"u}nndarm und Hoden gelang hierbei der Nachweis erstmals spezifisch auf zellul{\"a}rer Ebene. Caecum und Lymphknoten wurden zudem neu als Expressionsorte des Tas1r1 identifiziert. Trotz der beobachteten weiten Verbreitung des Tas1r1 im Organismus - unter anderem auch in Geweben, die f{\"u}r den Proteinstoffwechsel besonders relevant sind - waren im Zuge der durchgef{\"u}hrten Untersuchung potentieller extraoraler Funktionen des Rezeptors durch ph{\"a}notypische Charakterisierung der Mauslinie Tas1r1-BLiR nur schwache Auswirkungen auf Aminos{\"a}urestoffwechsel bzw. Stickstoffhaushalt im Falle eines Tas1r1-Knockouts detektierbar. W{\"a}hrend sich Ern{\"a}hrungsverhalten, Gesamtphysiologie, Gewebemorphologie sowie Futterverdaulichkeit unver{\"a}ndert zeigten, war die renale Stickstoffausscheidung bei Tas1r1-Knockout-M{\"a}usen auf eiweißarmer sowie auf eiweißreicher Di{\"a}t signifikant verringert. Eine {\"U}berdeckung der Auswirkungen des Tas1r1-Knockouts aufgrund kompensatorischer Effekte durch den Aminos{\"a}uresensor CaSR oder den Peptidsensor Gpr93 war nicht nachweisbar. Es bleibt offen, ob andere Mechanismen oder andere Chemosensoren an einer Kompensation beteiligt sind oder aber Tas1r1 in extraoralem Gewebe andere Funktionen als die der Aminos{\"a}uredetektion {\"u}bernimmt. Unterschiede im extraoralen Expressionsmuster der beiden Umamirezeptor-untereinheiten Tas1r1 und Tasr3 lassen Spekulationen {\"u}ber andere Partner, Liganden und Funktionen zu.}, language = {de} } @phdthesis{Bittermann2015, author = {Bittermann, Klaus}, title = {Semi-empirical sea-level modelling}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-93881}, school = {Universit{\"a}t Potsdam}, pages = {v, 88}, year = {2015}, abstract = {Semi-empirical sea-level models (SEMs) exploit physically motivated empirical relationships between global sea level and certain drivers, in the following global mean temperature. This model class evolved as a supplement to process-based models (Rahmstorf (2007)) which were unable to fully represent all relevant processes. They thus failed to capture past sea-level change (Rahmstorf et al. (2012)) and were thought likely to underestimate future sea-level rise. Semi-empirical models were found to be a fast and useful tool for exploring the uncertainties in future sea-level rise, consistently giving significantly higher projections than process-based models. In the following different aspects of semi-empirical sea-level modelling have been studied. Models were first validated using various data sets of global sea level and temperature. SEMs were then used on the glacier contribution to sea level, and to infer past global temperature from sea-level data via inverse modelling. Periods studied encompass the instrumental period, covered by tide gauges (starting 1700 CE (Common Era) in Amsterdam) and satellites (first launched in 1992 CE), the era from 1000 BCE (before CE) to present, and the full length of the Holocene (using proxy data). Accordingly different data, model formulations and implementations have been used. It could be shown in Bittermann et al. (2013) that SEMs correctly predict 20th century sea-level when calibrated with data until 1900 CE. SEMs also turned out to give better predictions than the Intergovernmental Panel on Climate Change (IPCC) 4th assessment report (AR4, IPCC (2007)) models, for the period from 1961-2003 CE. With the first multi-proxy reconstruction of global sea-level as input, estimate of the human-induced component of modern sea-level change and projections of future sea-level rise were calculated (Kopp et al. (2016)). It turned out with 90\% confidence that more than 40 \% of the observed 20th century sea-level rise is indeed anthropogenic. With the new semi-empirical and IPCC (2013) 5th assessment report (AR5) projections the gap between SEM and process-based model projections closes, giving higher credibility to both. Combining all scenarios, from strong mitigation to business as usual, a global sea-level rise of 28-131 cm relative to 2000 CE, is projected with 90\% confidence. The decision for a low carbon pathway could halve the expected global sea-level rise by 2100 CE. Present day temperature and thus sea level are driven by the globally acting greenhouse-gas forcing. Unlike that, the Milankovich forcing, acting on Holocene timescales, results mainly in a northern-hemisphere temperature change. Therefore a semi-empirical model can be driven with northernhemisphere temperatures, which makes it possible to model the main subcomponent of sea-level change over this period. It showed that an additional positive constant rate of the order of the estimated Antarctic sea-level contribution is then required to explain the sea-level evolution over the Holocene. Thus the global sea level, following the climatic optimum, can be interpreted as the sum of a temperature induced sea-level drop and a positive long-term contribution, likely an ongoing response to deglaciation coming from Antarctica.}, language = {en} } @phdthesis{Ramelli2015, author = {Ramelli, Christian}, title = {Die Rheinische Verlaufsform im rheinfr{\"a}nkischen Dialekt}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-102797}, school = {Universit{\"a}t Potsdam}, pages = {x, 260}, year = {2015}, abstract = {Diese Arbeit befasst sich mit der Rheinischen Verlaufsform (RV) im rheinfr{\"a}nkischen Dialekt. Nach dem DUDEN handelt es sich bei der RV um eine Konstruktion, die aus dem Kopulaverb sein und einer PP mit am und nominalisiertem Infinitiv besteht und dem Ausdruck von progressivem Aspekt dient. Die vorliegenden Arbeiten zur RV besch{\"a}ftigen sich im Wesentlichen entweder mit der Auspr{\"a}gung der Konstruktion im Standarddeutschen (z.B. Reimann (1999), Krause (2002), R{\"o}del (2003), R{\"o}del (2004a), R{\"o}del (2004b), van Pottelberge (2004)) oder im Ripuarischen (z.B. Andersson (1989), Bhatt \& Schmidt (1993)) und kommen zu unterschiedlichen Ergebnissen bez{\"u}glich der Verwendungsm{\"o}glichkeiten und des Aufbaus der Konstruktion, insbesondere des Status des Infinitivs in der Verlaufsform. Hauptziel dieser Arbeit ist es, zu zeigen, dass sich die Grammatikalisierung der Verlaufsform von der im DUDEN beschriebenen Konstruktion zu einer analytischen Verbform entlang eines festen Grammatikalisierungspfades vollzieht und die entsprechenden Teilschritte bei der Entwicklung zu einer analytischen Verbform herauszuarbeiten. Auf dieser Grundlage wird in der Arbeit dargestellt, wie sich mittels eines geeigneten Sets an Indikatoren der Grammatikalisierungsgrad der Verlaufsform in einem Dialektraum oder einem diatopischen Register konkret feststellen l{\"a}sst.}, language = {de} } @phdthesis{Bojahr2015, author = {Bojahr, Juliane}, title = {Aktivierung des humanen S{\"u}ßgeschmacksrezeptors im zellbasierten Testsystem}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-93331}, school = {Universit{\"a}t Potsdam}, pages = {XIII, 174}, year = {2015}, abstract = {Zellbasierte heterologe Expressionssysteme bieten ein einfaches und schnelles Verfahren, um neue S{\"u}ßstoffe oder S{\"u}ßverst{\"a}rker zu finden. Unter Verwendung eines solchen Testsystems, konnte ich in Zusammenarbeit mit der Symrise AG, Holzminden und dem Institut f{\"u}r Pflanzenbiochemie in Halle/Saale die vietnamesische Pflanze Mycetia balansae als Quelle eines neuen S{\"u}ßstoffs identifizieren. Deren Hauptkomponenten, genannt Balansine, aktivieren spezifisch den humanen S{\"u}ßrezeptor. Chim{\"a}re Rezeptoren zeigten, dass die amino-terminalen Dom{\"a}nen der S{\"u}ßrezeptoruntereinheiten, welche ein Großteil der Liganden des S{\"u}ßrezeptors binden, f{\"u}r dessen Aktivierung durch Balansin A nicht notwendig sind. Voraussetzung f{\"u}r die Anwendung zellbasierter Testsysteme zum Auffinden neuer S{\"u}ßstoffe ist jedoch, dass s{\"u}ße Substanzen gesichert identifiziert werden, w{\"a}hrend nicht s{\"u}ße Substanzen zuverl{\"a}ssig keine Rezeptoraktivierung aufweisen. W{\"a}hrend in HEK293 TAS1R2 TAS1R3To Galpha15i3-Zellen S{\"u}ßrezeptoraktivierung gegen{\"u}ber nicht s{\"u}ß schmeckenden Substanzen beobachtet wurde, konnte mit den HEK293PEAKrapid Galpha15-Zellen ein zuverl{\"a}ssiges Testsystem identifiziert, welches den S{\"u}ßgeschmack der untersuchten Substanzen widerspiegelte. Es fanden sich keine Hinweise, dass akzessorische Proteine oder verwandte Rezeptoren des S{\"u}ßrezeptors das unterschiedliche Verhalten der Zellen verursachen. Es konnte gezeigt werden, dass die Verwendung unterschiedlicher G-Proteine die Signalamplituden des S{\"u}ßrezeptors beeinflusst, die Unterschiede zwischen den Zellsystemen jedoch nicht vollst{\"a}ndig erkl{\"a}rt. Keine der untersuchten Galpha-Proteinchim{\"a}ren spiegelte die intrinsische S{\"u}ße der Substanzen wider. Wenn auch nicht urs{\"a}chlich f{\"u}r die Diskrepanz zwischen S{\"u}ßrezeptoraktivierung in vitro und S{\"u}ßgeschmack in vivo, so weisen die Ergebnisse dieser Arbeit auf eine Interaktion der S{\"u}ßrezeptoruntereinheiten mit dem humanen Calcium-sensing Rezeptor hin. Vanillin und Ethylvanillin konnten als neue Agonisten des Calcium-sensing Rezeptors identifiziert werden. Wie die vorliegende Arbeit zeigt, k{\"o}nnen sich kleine Unterschiede im Zellhintergrund deutlich auf die Funktionsweise heterolog exprimierter Rezeptoren auswirken. Dies zeigt wie wichtig die Wahl der Zellen f{\"u}r solche Screeningsysteme ist.}, language = {de} } @phdthesis{Brachs2015, author = {Brachs, Maria}, title = {Genome wide expression analysis and metabolic mechanisms predicting body weight maintenance}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-100767}, school = {Universit{\"a}t Potsdam}, pages = {106}, year = {2015}, abstract = {Obesity is a major health problem for many developing and industrial countries. Increasing rates reach almost 50 \% of the population in some countries and related metabolic diseases including cardiovascular events and T2DM are challenging the health systems. Adiposity, an increase in body fat mass, is a major hallmark of obesity. Adipose tissue is long known not only to store lipids but also to influence whole-body metabolism including food intake, energy expenditure and insulin sensitivity. Adipocytes can store lipids and thereby protect other tissue from lipotoxic damage. However, if the energy intake is higher than the energy expenditure over a sustained time period, adipose tissue will expand. This can lead to an impaired adipose tissue function resulting in higher levels of plasma lipids, which can affect other tissue like skeletal muscle, finally leading to metabolic complications. Several studies showed beneficial metabolic effects of weight reduction in obese subjects immediately after weight loss. However, weight regain is frequently observed along with potential negative effects on cardiovascular risk factors and a high intra-individual response. We performed a body weight maintenance study investigating the mechanisms of weight maintenance after intended WR. Therefore we used a low caloric diet followed by a 12-month life-style intervention. Comprehensive phenotyping including fat and muscle biopsies was conducted to investigate hormonal as well as metabolic influences on body weight regulation. In this study, we showed that weight reduction has numerous potentially beneficial effects on metabolic parameters. After 3-month WR subjects showed significant weight and fat mass reduction, lower TG levels as well as higher insulin sensitivity. Using RNA-Seq to analyse whole fat and muscle transcriptome a strong impact of weight reduction on adipose tissue gene expression was observed. Gene expression alterations over weight reduction included several cellular metabolic genes involved in lipid and glucose metabolism as well as insulin signalling and regulatory pathways. These changes were also associated with anthropometric parameters assigning body composition. Our data indicated that weight reduction leads to a decreased expression of several lipid catabolic as well as anabolic genes. Long-term body weight maintenance might be influenced by several parameters including hormones, metabolic intermediates as well as the transcriptional landscape of metabolic active tissues. Our data showed that genes involved in biosynthesis of unsaturated fatty acids might influence the BMI 18-month after a weight reduction phase. This was further supported by analysing metabolic parameters including RQ and FFA levels. We could show that subjects maintaining their lost body weight had a higher RQ and lower FFA levels, indicating increased metabolic flexibility in subjects. Using this transcriptomic approach we hypothesize that low expression levels of lipid synthetic genes in adipose tissue together with a higher mitochondrial activity in skeletal muscle tissue might be beneficial in terms of body weight maintenance.}, language = {en} } @phdthesis{Bettenbuehl2015, author = {Bettenb{\"u}hl, Mario}, title = {Microsaccades}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, isbn = {978-3-86956-122-6}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-72622}, school = {Universit{\"a}t Potsdam}, pages = {iv, 126}, year = {2015}, abstract = {The first thing we do upon waking is open our eyes. Rotating them in our eye sockets, we scan our surroundings and collect the information into a picture in our head. Eye movements can be split into saccades and fixational eye movements, which occur when we attempt to fixate our gaze. The latter consists of microsaccades, drift and tremor. Before we even lift our eye lids, eye movements - such as saccades and microsaccades that let the eyes jump from one to another position - have partially been prepared in the brain stem. Saccades and microsaccades are often assumed to be generated by the same mechanisms. But how saccades and microsaccades can be classified according to shape has not yet been reported in a statistical manner. Research has put more effort into the investigations of microsaccades' properties and generation only since the last decade. Consequently, we are only beginning to understand the dynamic processes governing microsaccadic eye movements. Within this thesis, the dynamics governing the generation of microsaccades is assessed and the development of a model for the underlying processes. Eye movement trajectories from different experiments are used, recorded with a video-based eye tracking technique, and a novel method is proposed for the scale-invariant detection of saccades (events of large amplitude) and microsaccades (events of small amplitude). Using a time-frequency approach, the method is examined with different experiments and validated against simulated data. A shape model is suggested that allows for a simple estimation of saccade- and microsaccade related properties. For sequences of microsaccades, in this thesis a time-dynamic Markov model is proposed, with a memory horizon that changes over time and which can best describe sequences of microsaccades.}, language = {en} } @phdthesis{Doerge2015, author = {D{\"o}rge, Christina}, title = {Informatische Schl{\"u}sselkompetenzen}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, isbn = {978-3-86956-262-9}, issn = {1868-0844}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-70470}, school = {Universit{\"a}t Potsdam}, pages = {458}, year = {2015}, abstract = {Seit den 60er Jahren gibt es im deutschsprachigen Raum Diskussionen um die Begriffe Schl{\"u}sselqualifikation und (Schl{\"u}ssel-)Kompetenz, welche seit ca. 2000 auch in der Informatikdidaktik angekommen sind. Die Diskussionen der Fachdisziplinen und ihre Bedeutung f{\"u}r die Informatikdidaktik sind Gegenstand des ersten Teils dieser Dissertation. Es werden Rahmenmodelle zur Strukturierung und Einordnung von Kompetenzen entworfen, die f{\"u}r alle Fachdisziplinen nutzbar sind. Im zweiten Teil wird ein methodologischer Weg gezeigt, Schl{\"u}sselkompetenzen herzuleiten, ohne normativ vorgehen zu m{\"u}ssen. Hierzu wird das Verfahren der Qualitativen Inhaltsanalyse (QI) auf informatikdidaktische Ansätze angewendet. Die resultierenden Kompetenzen werden in weiteren Schritten verfeinert und in die zuvor entworfenen Rahmenmodelle eingeordnet. Das Ergebnis sind informatische Schl{\"u}sselkompetenzen, welche ein spezifisches Bild der Informatik zeichnen und zur Analyse bereits bestehender Curricula genutzt werden können. Zusätzlich zeigt das Verfahren einen Weg auf, wie Schl{\"u}sselkompetenzen auf nicht-normativem Wege generell hergeleitet werden können.}, language = {de} } @phdthesis{Lamanna2015, author = {Lamanna, Francesco}, title = {Adaptive radiation and speciation in African weakly-electric fish}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-80097}, school = {Universit{\"a}t Potsdam}, pages = {114}, year = {2015}, abstract = {The rise of evolutionary novelties is one of the major drivers of evolutionary diversification. African weakly-electric fishes (Teleostei, Mormyridae) have undergone an outstanding adaptive radiation, putatively owing to their ability to communicate through species-specific Electric Organ Discharges (EODs) produced by a novel, muscle-derived electric organ. Indeed, such EODs might have acted as effective pre-zygotic isolation mechanisms, hence favoring ecological speciation in this group of fishes. Despite the evolutionary importance of this organ, genetic investigations regarding its origin and function have remained limited. The ultimate aim of this study is to better understand the genetic basis of EOD production by exploring the transcriptomic profiles of the electric organ and of its ancestral counterpart, the skeletal muscle, in the genus Campylomormyrus. After having established a set of reference transcriptomes using "Next-Generation Sequencing" (NGS) technologies, I performed in silico analyses of differential expression, in order to identify sets of genes that might be responsible for the functional differences observed between these two kinds of tissues. The results of such analyses indicate that: i) the loss of contractile activity and the decoupling of the excitation-contraction processes are reflected by the down-regulation of the corresponding genes in the electric organ; ii) the metabolic activity of the electric organ might be specialized towards the production and turnover of membrane structures; iii) several ion channels are highly expressed in the electric organ in order to increase excitability, and iv) several myogenic factors might be down-regulated by transcription repressors in the EO. A secondary task of this study is to improve the genus level phylogeny of Campylomormyrus by applying new methods of inference based on the multispecies coalescent model, in order to reduce the conflict among gene trees and to reconstruct a phylogenetic tree as closest as possible to the actual species-tree. By using 1 mitochondrial and 4 nuclear markers, I was able to resolve the phylogenetic relationships among most of the currently described Campylomormyrus species. Additionally, I applied several coalescent-based species delimitation methods, in order to test the hypothesis that putatively cryptic species, which are distinguishable only from their EOD, belong to independently evolving lineages. The results of this analysis were additionally validated by investigating patterns of diversification at 16 microsatellite loci. The results suggest the presence of a new, yet undescribed species of Campylomormyrus.}, language = {en} } @phdthesis{Borschewski2015, author = {Borschewski, Aljona}, title = {Bedeutung der Interaktion von Calcineurin und SORLA f{\"u}r die Regulation des Na⁺,K⁺,2Cl⁻-Kotransporters (NKCC2) in der Niere}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-89205}, school = {Universit{\"a}t Potsdam}, pages = {II, 86}, year = {2015}, abstract = {Der Na⁺-K⁺-2Cl⁻-Kotransporter (NKCC2) wird im distalen Nephron der Niere exprimiert. Seine Verteilung umfasst die Epithelien der medull{\"a}ren und kortikalen Teile der dicken aufsteigenden Henle-Schleife (Thick ascending limb, TAL) und die Macula densa. Resorptiver NaCl-Transport {\"u}ber den NKCC2 dient dem renalen Konzentrierungsmechanismus und reguliert systemisch auch Volumenstatus und Blutdruck. Die Aktivit{\"a}t des NKCC2 ist mit der Phosphorylierung seiner N-terminalen Aminos{\"a}urereste Serin 126 und Threonin 96/101 verbunden. Vermittelt wird diese durch die homologen Kinasen SPAK (SPS-related proline/alanine-rich kinase) und OSR1 (Oxidative stress responsive kinase 1), die hierzu ihrerseits phosphoryliert werden m{\"u}ssen. Der regulatorische Kontext dieser Kinasen ist mittlerweile gut charakterisiert. {\"U}ber Mechanismen und Produkte, die den NKCC2 deaktivieren, war hingegen weniger bekannt. Ziel der Arbeit war daher zu untersuchen, welche Wege zur Deaktivierung des Transporters f{\"u}hren. Der intrazellul{\"a}re Sortierungsrezeptor SORLA (Sorting-protein-related receptor with A-type repeats) war zuvor in seiner Bedeutung f{\"u}r das Nephron charakterisiert worden. Ein SORLA-defizientes Mausmodell weist unter anderem eine stark verringerte NKCC2-Phosphorylierung auf. Unter osmotischem Stress k{\"o}nnen SORLA-defiziente M{\"a}use ihren Urin weniger effizient konzentrieren. Meine Resultate zeigen mit hochaufl{\"o}sender Technik, dass SORLA apikal im TAL lokalisiert ist und dass mit NKCC2 eine anteilige Kolokalisation besteht. Unter SORLA Defizienz war die f{\"u}r die NKCC2 Aktivit{\"a}t maßgebliche SPAK/OSR1-Phosphorylierung gegen{\"u}ber dem Wildtyp nicht ver{\"a}ndert. Jedoch war die ebenfalls im TAL exprimierte Phosphatase Calcineurin Aβ (CnAβ) per Western blot um das zweifache gesteigert. Parallel hierzu wurde immunhistochemisch die Kolokalisation von verst{\"a}rktem CnAβ-Signal und NKCC2 best{\"a}tigt. Beide Befunde geben zusammen den Hinweis auf einen Bezug zwischen der reduzierten NKCC2-Phosphorylierung und der gesteigerten Pr{\"a}senz von CnAβ bei SORLA Defizienz. Die parallel induzierte {\"U}berexpression von SORLA in HEK-Zellen zeigte entsprechend eine Halbierung der CnAβ Proteinmenge. SORLA steuert demzufolge sowohl die Abundanz als auch die zellul{\"a}re Verteilung der Phosphatase. Weiterhin ließ sich die Interaktion zwischen CnAβ und SORLA (intrazellul{\"a}re Dom{\"a}ne) mittels Co-Immunpr{\"a}zipitation bzw. GST-pulldown assay nachweisen. Auch die Interaktion zwischen CnAβ und NKCC2 wurde auf diesem Weg belegt. Da allerdings weder SORLA noch NKCC2 ein spezifisches Bindungsmuster f{\"u}r CnAβ aufweisen, sind vermutlich intermedi{\"a}re Adapterproteine bei ihrer Bindung involviert. Die pharmakologische Inhibition von CnAβ mittels Cyclosporin A (CsA; 1 h) f{\"u}hrte bei SORLA Defizienz zur Normalisierung der NKCC2-Phosphorylierung. Entsprechend f{\"u}hrte in vitro die Gabe von CsA bei TAL Zellen zu einer 7-fach gesteigerten NKCC2-Phosphorylierung. Zusammenfassend zeigen die Ergebnisse, dass die Phosphatase CnAβ {\"u}ber ihre Assoziation mit NKCC2 diesen im adluminalen Zellkompartiment deaktivieren kann. Gesteuert wird dieser Vorgang durch die Eigenschaft von SORLA, CnAβ apikal zu reduzieren und damit die adluminale Phosphorylierung und Aktivit{\"a}t von NKCC2 zu unterst{\"u}tzen. Da Calcineurin-Inhibitoren derzeit die Grundlage der immunsupprimierenden Therapie darstellen, haben die Ergebnisse eine klinische Relevanz. Angesichts der Co-Expression von SORLA und CnAβ in verschiedenen anderen Organen k{\"o}nnen die Ergebnisse auch {\"u}ber die Niere hinaus Bedeutung erlangen.}, language = {de} } @phdthesis{Bora2015, author = {Bora, Sanjay Singh}, title = {Regionally adaptable ground-motion Prediction Equations (GMPEs) for seismic hazard analysis}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-88806}, school = {Universit{\"a}t Potsdam}, pages = {xiv, 138}, year = {2015}, abstract = {Adjustment of empirically derived ground motion prediction equations (GMPEs), from a data- rich region/site where they have been derived to a data-poor region/site, is one of the major challenges associated with the current practice of seismic hazard analysis. Due to the fre- quent use in engineering design practices the GMPEs are often derived for response spectral ordinates (e.g., spectral acceleration) of a single degree of freedom (SDOF) oscillator. The functional forms of such GMPEs are based upon the concepts borrowed from the Fourier spectral representation of ground motion. This assumption regarding the validity of Fourier spectral concepts in the response spectral domain can lead to consequences which cannot be explained physically. In this thesis, firstly results from an investigation that explores the relationship between Fourier and response spectra, and implications of this relationship on the adjustment issues of GMPEs, are presented. The relationship between the Fourier and response spectra is explored by using random vibration theory (RVT), a framework that has been extensively used in earthquake engineering, for instance within the stochastic simulation framework and in the site response analysis. For a 5\% damped SDOF oscillator the RVT perspective of response spectra reveals that no one-to-one correspondence exists between Fourier and response spectral ordinates except in a limited range (i.e., below the peak of the response spectra) of oscillator frequencies. The high oscillator frequency response spectral ordinates are dominated by the contributions from the Fourier spectral ordinates that correspond to the frequencies well below a selected oscillator frequency. The peak ground acceleration (PGA) is found to be related with the integral over the entire Fourier spectrum of ground motion which is in contrast to the popularly held perception that PGA is a high-frequency phenomenon of ground motion. This thesis presents a new perspective for developing a response spectral GMPE that takes the relationship between Fourier and response spectra into account. Essentially, this frame- work involves a two-step method for deriving a response spectral GMPE: in the first step two empirical models for the FAS and for a predetermined estimate of duration of ground motion are derived, in the next step, predictions from the two models are combined within the same RVT framework to obtain the response spectral ordinates. In addition to that, a stochastic model based scheme for extrapolating the individual acceleration spectra beyond the useable frequency limits is also presented. To that end, recorded acceleration traces were inverted to obtain the stochastic model parameters that allow making consistent extrapola- tion in individual (acceleration) Fourier spectra. Moreover an empirical model, for a dura- tion measure that is consistent within the RVT framework, is derived. As a next step, an oscillator-frequency-dependent empirical duration model is derived that allows obtaining the most reliable estimates of response spectral ordinates. The framework of deriving the response spectral GMPE presented herein becomes a self-adjusting model with the inclusion of stress parameter (∆σ) and kappa (κ0) as the predictor variables in the two empirical models. The entire analysis of developing the response spectral GMPE is performed on recently compiled RESORCE-2012 database that contains recordings made from Europe, the Mediterranean and the Middle East. The presented GMPE for response spectral ordinates should be considered valid in the magnitude range of 4 ≤ MW ≤ 7.6 at distances ≤ 200 km.}, language = {en} } @phdthesis{Hanf2015, author = {Hanf, Franziska Stefanie}, title = {South Asian summer monsoon variability: a modelling study with the atmospheric regional climate model HIRHAM5}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-89331}, school = {Universit{\"a}t Potsdam}, pages = {ii, 126}, year = {2015}, abstract = {The lives of more than 1/6 th of the world population is directly affected by the caprices of the South Asian summer monsoon rainfall. India receives around 78 \% of the annual precipitation during the June-September months, the summer monsoon season of South Asia. But, the monsoon circulation is not consistent throughout the entire summer season. Episodes of heavy rainfall (active periods) and low rainfall (break periods) are inherent to the intraseasonal variability of the South Asian summer monsoon. Extended breaks or long-lasting dryness can result in droughts and hence trigger crop failures and in turn famines. Furthermore, India's electricity generation from renewable sources (wind and hydro-power), which is increasingly important in order to satisfy the rapidly rising demand for energy, is highly reliant on the prevailing meteorology. The major drought years 2002 and 2009 for the Indian summer monsoon during the last decades, which are results of the occurrence of multiple extended breaks, emphasise exemplary that the understanding of the monsoon system and its intraseasonal variation is of greatest importance. Although, numerous studies based on observations, reanalysis data and global model simulations have been carried out with the focus on monsoon active and break phases over India, the understanding of the monsoon intraseasonal variability is only in the infancy stage. Regional climate models could benefit the comprehension of monsoon breaks by its resolution advantage. This study investigates moist dynamical processes that initiate and maintain breaks during the South Asian summer monsoon using the atmospheric regional climate model HIRHAM5 at a horizontal resolution of 25 km forced by the ECMWF ERA Interim reanalysis for the period 1979-2012. By calculating moisture and moist static energy budgets the various competing mechanisms leading to extended breaks are quantitatively estimated. Advection of dry air from the deserts of western Asia towards central India is the dominant moist dynamical process in initiating extended break conditions over South Asia. Once initiated, the extended breaks are maintained due to many competing mechanisms: (i) the anomalous easterlies at the southern flank of this anticyclonic anomaly weaken the low-level cross-equatorial jet and thus the moisture transport into the monsoon region, (ii) differential radiative heating over the continental and the oceanic tropical convergence zone induces a local Hadley circulation with anomalous rising over the equatorial Indian Ocean and descent over central India, and (iii) a cyclonic response to positive rainfall anomalies over the near-equatorial Indian Ocean amplifies the anomalous easterlies over India and hence contributes to the low-level divergence over central India. A sensitivity experiment that mimics a scenario of higher atmospheric aerosol concentrations over South Asia addresses a current issue of large uncertainty: the role aerosols play in suppressing monsoon rainfall and hence in triggering breaks. To study the indirect aerosol effects the cloud droplet number concentration was increased to imitate the aerosol's function as cloud condensation nuclei. The sensitivity experiment with altered microphysical cloud properties shows a reduction in the summer monsoon precipitation together with a weakening of the South Asian summer monsoon. Several physical mechanisms are proposed to be responsible for the suppressed monsoon rainfall: (i) according to the first indirect radiative forcing the increase in the number of cloud droplets causes an increase in the cloud reflectivity of solar radiation, leading to a climate cooling over India which in turn reduces the hydrological cycle, (ii) a stabilisation of the troposphere induced by a differential cooling between the surface and the upper troposphere over central India inhibits the growth of deep convective rain clouds, (iii) an increase of the amount of low and mid-level clouds together with a decrease in high-level cloud amount amplify the surface cooling and hence the atmospheric stability, and (iv) dynamical changes of the monsoon manifested as a anomalous anticyclonic circulation over India reduce the moisture transport into the monsoon region. The study suggests that the changes in the total precipitation, which are dominated by changes in the convective precipitation, mainly result from the indirect radiative forcing. Suppression of rainfall due to the direct microphysical effect is found to be negligible over India. Break statistics of the polluted cloud scenario indicate an increase in the occurrence of short breaks (3 days), while the frequency of extended breaks (> 7 days) is clearly not affected. This disproves the hypothesis that more and smaller cloud droplets, caused by a high load of atmospheric aerosols trigger long drought conditions over central India.}, language = {en} } @phdthesis{Mitidieri2015, author = {Mitidieri, Gaetano}, title = {Wissenschaft, Technik und Medien im Werk Alfred D{\"o}blins im Kontext der europ{\"a}ischen Avantgarde}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, isbn = {978-3-86956-364-0}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-89390}, school = {Universit{\"a}t Potsdam}, pages = {970}, year = {2015}, abstract = {Ziel dieser Studie ist es die bislang nur sporadisch untersuchten Wechselverh{\"a}ltnisse zwischen den Kulturbereichen Wissenschaft/Technik und Literatur am herausragenden Beispiel des Oeuvres des Schriftstellers und Arztes Alfred D{\"o}blin aufzusp{\"u}ren. Hierbei scheint seine {\"a}rztlich-psychiatrische Laufbahn, die eine breite Grundlage wissenschaftlicher Diskurse anbietet, wie auch seine avantgardistische Literaturpraxis diese gegenseitige Befruchtung gef{\"o}rdert zu haben. Im Hinblick auf den Forschungsgegenstand und -zweck ist ein kulturwissenschaftlicher Ansatz versucht worden. Dieser vielperspektivische Ansatz, der von der Pr{\"a}misse eines Wechselspiels aller Kulturbereiche untereinander ausgeht, gestattet eine dem Gegenstand angepasste Verkn{\"u}pfung von verschiedenen Arbeitsmethoden wie der philologisch-literarhistorischen mit der konstruktivistischen und der komparatistischen. Hierbei ist eine Einbeziehung wissenschafts- und technikphilosophischer Reflexion wie auch eine dementsprechend erweiterte kulturhistorische Kontextualisierung vorgenommen worden. Die hier vorgelegte Analyse fokussiert auf wissenschaftlich-technische Bez{\"u}ge sowohl in thematischer Hinsicht als auch in der Textgestaltung der schriftstellerischen Werke D{\"o}blins bis 1924. Gleichzeitig wird die diskursgepr{\"a}gte, sprachliche und literarische Dimension seiner wissenschaftlichen Studien und technischer Texte - wie Krankenakte - hervorgehoben. Dieses erweiterte ‚Oeuvre'-Konzept gestattet die Analyse der psychiatrischen, klinisch-{\"a}rztlichen und biochemischen Schriften D{\"o}blins sowie seiner Erz{\"a}hlwerke, seiner vielgestaltigen Publizistik und seiner intermedialen Anregungen aus den neuen audiovisuellen Medien. Dadurch wird eine diskurskritische kultur{\"u}bergreifende Interdiskursivit{\"a}t wie auch eine ‚Hybridit{\"a}t' aller Texte aufgezeigt, die die Grundunterschiede zwischen Textsorten und Gattungsgrenzen relativiert.}, language = {de} } @phdthesis{Otto2015, author = {Otto, Katharina Alexandra}, title = {Mass wasting and the Coriolis effect on asteroid Vesta}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-87390}, school = {Universit{\"a}t Potsdam}, pages = {XVII, 251}, year = {2015}, abstract = {This work investigates the influence of the Coriolis force on mass motion related to the Rheasilvia impact basin on asteroid (4) Vesta's southern hemisphere. The giant basin is 500km in diameter, with a centre which nearly coincides with the rotation axis of Vesta. The Rheasilvia basin partially overlaps an earlier, similarly large impact basin, Veneneia. Mass motion within and in the vicinity of the Rheasilvia basin includes slumping and landslides, which, primarily due to their small linear extents, have not been noticeably affected by the Coriolis force. However, a series of ridges related to the basin exhibit significant curvature, which may record the effect of the Coriolis force on the mass motion which generated them. In this thesis 32 of these curved ridges, in three geologically distinct regions, were examined. The mass motion velocities from which the ridge curvatures may have resulted during the crater modification stage were investigated. Velocity profiles were derived by fitting inertial circles along the curved ridges and considering both the current and past rotation states of Vesta. An iterative, statistical approach was used, whereby the radii of inertial circles were obtained through repeated fitting to triplets of points across the ridges. The most frequently found radius for each central point was then used for velocity derivation at that point. The results of the velocity analysis are strongly supportive of a Coriolis force origin for the curved ridges. Derived velocities (29.6 ± 24.6 m/s) generally agree well with previously published predictions from numerical simulations of mass motion during the impact process. Topographical features such as local slope gradient and mass deposition regions on the curved ridges also independently agree with regions in which the calculated mass motion accelerates or decelerates. Sections of constant acceleration, deceleration and constant velocity are found, showing that mass motion is being governed by varying conditions of topography, regolith structure and friction. Estimates of material properties such as the effective viscosities (1.9-9.0·10⁶ Pa·s) and coefficients of friction (0.02-0.81) are derived from the velocity profile information in these sections. From measured accelerations of mass motions on the crater wall, it is also shown that the crater walls must have been locally steeper at the time of the mass motion. Together with these novel insights into the state and behaviour of material moving during the modification stage of Rheasilvia's formation, this work represents the first time that the Coriolis Effect on mass motions during crater formation has been shown to result in diagnostic features preserved until today.}, language = {en} } @phdthesis{Feldbusch2015, author = {Feldbusch, Elvira}, title = {Geochemische Charakterisierung eines Formationsfluids im Unteren Perm}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-87402}, school = {Universit{\"a}t Potsdam}, pages = {x, 116, XIII}, year = {2015}, abstract = {Diese Arbeit befasst sich mit der ganzheitlichen Betrachtung der Fluideigenschaften eines unterpermischen Reservoirs am Geothermie Forschungsstandort Groß Sch{\"o}nebeck (GrSk) bei Reservoirbedingungen und im Betrieb der Geothermieanlage. Die Untersuchungen zur Fluidherkunft ergeben, dass es sich um ein konnates Wasser meteorischen Ursprungs ohne den Einfluss der dar{\"u}berliegenden Zechsteinw{\"a}sser handelt. Die Ionen und Isotopenverh{\"a}ltnisse im Formationswasser gel{\"o}ster Komponenten in GrSk belegen einen gemeinsamen Genesepfad mit W{\"a}ssern anderer Rotliegend-Reservoire des Nordostdeutschen Beckens (NEGB). Die Isotopenverh{\"a}ltnisse von ⁸⁷Sr/⁸⁶Sr ≈ 0,7158 und von δ³⁴SV CDT ≈ 4,1 per mille des Sulfats weisen auf die Anreicherung des Fluids mit schweren Isotopen durch die Fluid Gestein-Wechselwirkung mit Vulkaniten und Rotliegend Sandsteinen des Unteren Perms hin. Das im Formationswasser bei Reservoirbedingungen gel{\"o}ste Gas (Gas/Wasser ≤ 2 bei STP) enth{\"a}lt Stickstoff (δ¹⁵NAir ≈ 0,6 per mille) und thermogenes Methan (δ¹³CV-PDB ≈ - 18 per mille) aus organischen Karbonablagerungen (Kerogen Typ - III Kohlen) hoher Reife. Die Isotopenverh{\"a}ltnisse der Edelgase belegen eine krustale Herkunft des Gasgemisches. Die berechnete Verweilzeit τ (⁴He) der Gase im Reservoir liegt zwischen 275 und 317 Ma und {\"u}berschreitet damit bei gegebener Konzentration von Mutternukliden im Reservoirgestein das allgemein angenommene Zeitalter der Sedimentgruppe. Das l{\"a}sst sich durch eine Zuwanderung von Gasen aus {\"a}lteren Sedimentfolgen erkl{\"a}ren. Die Ver{\"a}nderungen der physikochemischen Fluidparameter w{\"a}hrend des Anlagenbetriebs sind haupts{\"a}chlich temperaturbedingt. Bei stabilen Produktionsbedingungen und einer Temperatur von ca. 100 °C stabilisieren sich auch die Fluideigenschaften. Bei In situ Bedingungen {\"u}bertage betr{\"a}gt die Dichte ρ = 1,1325 ± 0,0002 g ∙ mL⁻¹, das Redoxpotential Eh = -105,5 ± 1,3 mV und der pH = 6,61 ± 0,002. Die relative Zusammensetzung der Gasphase bei stabilen Produktionsbedingungen zeigt dagegen eine geringe Erh{\"o}hung des Stickstoffanteils sowie des Anteils der Kohlenwasserstoffe (Ethan, Propan, usw.) und Abnahme des relativen Methananteils im Laufe des Betriebs. Die quantitative Untersuchung der sekund{\"a}ren mineralischen Ausf{\"a}llungen im Fluid mittels sequentieller Extraktion zeigte, dass Schwermetalle als eine Hauptkomponente der Fluidfestphase gr{\"o}ßtenteils in Verbindung mit organischen Molek{\"u}len vorliegen. Experimente zum Einfluss organischer Verbindungen unterschiedlicher Substanzklassen auf eine Mobilisierung der Schwermetalle aus dem Reservoirgestein ergaben, dass die Verbindungen wie Fetts{\"a}uren und PAK (polyzyklische aromatische Kohlenwasserstoffe) die Freisetzung von Kupfer, Nickel, Chrom und Blei verhindern bzw. zu derer Immobilisierung beitragen. Im Gegensatz dazu wird die Mobilit{\"a}t von Zink in Anwesenheit von diesen Verbindungen erh{\"o}ht. Niedermolekulare Monocarbons{\"a}uren und stickstoffhaltige Heteroaromaten tragen, mit Ausnahme von Blei, zur Freisetzung bzw. Mobilisierung von Schwermetallen aus dem Reservoirgestein bei. Die gewonnenen Erkenntnisse dieser Arbeit best{\"a}tigen das Risiko massiver Ausf{\"a}llungen auf der kalten Seite der Geothermieanlage bei Inbetriebnahme des Kraftwerks, wenn keine an den Fluidchemismus angepassten Pr{\"a}ventionsmethoden eingesetzt werden. Die Isotopenzusammensetzung der Fluidkomponenten sowie geringf{\"u}gige Schwankungen der Gaszusammensetzung im kontinuierlichen Anlagenbetrieb l{\"a}sst eine Kommunikation des unterpermischen Reservoirs mit dem darunter liegenden Oberkarbon vermuten, was eine nachtr{\"a}gliche Ver{\"a}nderung der Fluidzusammensetzung beim Dauerbetrieb der Anlage bedeuten kann.}, language = {de} } @phdthesis{Jehannin2015, author = {Jehannin, Marie}, title = {About the role of physico-chemical properties and hydrodynamics on the progress of a precipitation reaction}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-88364}, school = {Universit{\"a}t Potsdam}, pages = {xii, 130}, year = {2015}, abstract = {The size and morphology control of precipitated solid particles is a major economic issue for numerous industries. For instance, it is interesting for the nuclear industry, concerning the recovery of radioactive species from used nuclear fuel. The precipitates features, which are a key parameter from the post-precipitate processing, depend on the process local mixing conditions. So far, the relationship between precipitation features and hydrodynamic conditions have not been investigated. In this study, a new experimental configuration consisting of coalescing drops is set to investigate the link between reactive crystallization and hydrodynamics. Two configurations of aqueous drops are examined. The first one corresponds to high contact angle drops (>90°) in oil, as a model system for flowing drops, the second one correspond to sessile drops in air with low contact angle (<25°). In both cases, one reactive is dissolved in each drop, namely oxalic acid and cerium nitrate. When both drops get into contact, they may coalesce; the dissolved species mix and react to produce insoluble cerium oxalate. The precipitates features and effect on hydrodynamics are investigated depending on the solvent. In the case of sessile drops in air, the surface tension difference between the drops generates a gradient which induces a Marangoni flow from the low surface tension drop over the high surface tension drop. By setting the surface tension difference between the two drops and thus the Marangoni flow, the hydrodynamics conditions during the drop coalescence could be modified. Diols/water mixtures are used as solvent, in order to fix the surface tension difference between the liquids of both drops regardless from the reactant concentration. More precisely, the used diols, 1,2-propanediol and 1,3-propanediol, are isomer with identical density and close viscosity. By keeping the water volume fraction constant and playing with the 1,2-propanediol and 1,3-propanediol volume fractions of the solvents, the mixtures surface tensions differ up to 10 mN/m for identical/constant reactant concentration, density and viscosity. 3 precipitation behaviors were identified for the coalescence of water/diols/recatants drops depending on the oxalic excess. The corresponding precipitates patterns are visualized by optical microscopy and the precipitates are characterized by confocal microscopy SEM, XRD and SAXS measurements. In the intermediate oxalic excess regime, formation of periodic patterns can be observed. These patterns consist in alternating cerium oxalate precipitates with distinct morphologies, namely needles and "microflowers". Such periodic fringes can be explained by a feedback mechanism between convection, reaction and the diffusion.}, language = {en} } @phdthesis{Sarem2015, author = {Sarem, Zeinab}, title = {Regulation of IGF-1 bioactivity by dietary hormones, impact of glucagon and insulin-induced hypoglycemia}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-82198}, school = {Universit{\"a}t Potsdam}, pages = {IX, 64, IV, XIII}, year = {2015}, abstract = {Der Zusammenhang zwischen Ern{\"a}hrung und der Entwicklung von chronischen Krankenheiten wie metabolischem Syndrom, Diabetes mellitus, Krebs und kardiovaskul{\"a}ren Erkrankungen wurde untersucht. Ver{\"a}nderungen der GH-IGF-1 Achse in Verbindung mit ern{\"a}hrungsbedingten Erkrankungen wurden fr{\"u}her beschrieben. Das Wechselspiel zwischen GH, gesamt IGF-1 und verschiedenen hemmenden und stimulierenden IGF-1 bindenden Proteinen (IGFBPs) bestimmt die IGF-1 Bioaktivit{\"a}t, die als die F{\"a}higkeit von IGF-1 die Phosphorylierung von seinem Rezeptor und folglich seinem Signalsweg zu induzieren, identifiziert ist. Deshalb reicht die Messung der IGF-1 Bioaktivit{\"a}t aus, um {\"A}nderungen des GH-IGF-1 Systems darzustellen. Studien deuten darauf hin, dass proteinreiche Di{\"a}t, gekennzeichnet durch erh{\"o}hte Glukagonsekretion, und Insulin-induzierte Hypoglyk{\"a}mie die Sterblichkeit erh{\"o}hen, und die Mechanismen sind unklar. Sowohl Glukagon als auch Insulin-induzierte Hypoglyk{\"a}mie stimulieren die GH Sekretion. Das Ziel der vorliegenden Studie war, die Wirkung von Glucagon und Insulin-induzierter Hypoglyk{\"a}mie auf die IGF-1 -Bioaktivit{\"a}t als m{\"o}gliche Mechanismen zu characterizieren. In einer doppelblinden, Placebo-kontrollierten Studie wurde Glukagon intramuskul{\"a}r 13 Patienten mit T1DM (6 M{\"a}nner / 7 Frauen; [ BMI ] : 24,8 ± 0,95 kg / m2) , 11 {\"u}bergewichtigen Teilnehmern (OP ; 5/6 ; 34,4 ± 1,7 kg / m2) und 13 gesunden schlanken Teilnehmern (LP ; 6/7 ; 21,7 ± 0,6 kg / m2) administriert. Zw{\"o}lf {\"u}bergewichtige Teilnehmer (OP ; 6/6 ; 34,4 ± 1,7 kg / m2) und 13 gesunde schlanke Teilnehmer (LP ; 6/7 ; 21,7 ± 0,6 kg / m2) f{\"u}hrten Insulintoleranztests in einer weiteren doppelblinden, Plazebo- kontrollierten Studie durch. {\"A}nderungen des GH, gesamt-IGF-1, der IGF-bindenden Proteinen ( IGFBPs ) und der IGF-1-Bioaktivit{\"a}t wurden durch das zellbasierte KIRA-Verfahren gemessen. Außerdem wurde die Wechselwirkung zwischen den metabolischen Hormonen (Glucagon und Insulin) und GH-IGF-1-System auf der Transkriptionsebene mit prim{\"a}ren Maus-Hepatozyten untersucht. In dieser Arbeit verringerte Glukagon die IGF-1-Bioaktivit{\"a}t bei den Menschen unabh{\"a}ngig von k{\"o}rpereigenen Insulinspiegeln, h{\"o}chstwahrscheinlich durch Modulation des IGFBP-1 und -2. Die Glukagon-induzierte Reduktion der IGF-1-Bioaktivit{\"a}t stellt einen neuen Mechanismus der Wirkung von Glucagon auf die GH-Sekretion dar und kann als m{\"o}gliche Erkl{\"a}rung f{\"u}r die negativen Auswirkungen der proteinreichen Di{\"a}t im Zusammenhang auf das erh{\"o}hte kardiovaskul{\"a}re Risiko und die Mortalit{\"a}t vorgeschlagen werden. Zus{\"a}tzlich wurde die Insulin-induzierten Hypoglyk{\"a}mie eine Abnahme der IGF-1-Bioaktivit{\"a}t durch Hochregulierung von IGFBP-2 zugeordnet. Diese Ergebnisse k{\"o}nnen auf m{\"o}gliche und wenig erforschte Mechanismen zur Erl{\"a}uterung der starken Assoziation zwischen Hypoglyk{\"a}mie und erh{\"o}hter kardiovaskul{\"a}rer Mortalit{\"a}t bei diabetischen Patienten beziehen.}, language = {en} } @phdthesis{Mulyukova2015, author = {Mulyukova, Elvira}, title = {Stability of the large low shear velocity provinces}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-82228}, school = {Universit{\"a}t Potsdam}, pages = {139}, year = {2015}, abstract = {We study segregation of the subducted oceanic crust (OC) at the core mantle boundary and its ability to accumulate and form large thermochemical piles (such as the seismically observed Large Low Shear Velocity Provinces - LLSVPs). Our high-resolution numerical simulations suggest that the longevity of LLSVPs for up to three billion years, and possibly longer, can be ensured by a balance in the rate of segregation of high-density OC-material to the CMB, and the rate of its entrainment away from the CMB by mantle upwellings. For a range of parameters tested in this study, a large-scale compositional anomaly forms at the CMB, similar in shape and size to the LLSVPs. Neutrally buoyant thermochemical piles formed by mechanical stirring - where thermally induced negative density anomaly is balanced by the presence of a fraction of dense anomalous material - best resemble the geometry of LLSVPs. Such neutrally buoyant piles tend to emerge and survive for at least 3Gyr in simulations with quite different parameters. We conclude that for a plausible range of values of density anomaly of OC material in the lower mantle - it is likely that it segregates to the CMB, gets mechanically mixed with the ambient material, and forms neutrally buoyant large scale compositional anomalies similar in shape to the LLSVPs. We have developed an efficient FEM code with dynamically adaptive time and space resolution, and marker-in-cell methodology. This enabled us to model thermochemical mantle convection at realistically high convective vigor, strong thermally induced viscosity variations, and long term evolution of compositional fields.}, language = {en} } @phdthesis{Conforti2015, author = {Conforti, Giovanni}, title = {Reciprocal classes of continuous time Markov Chains}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-82255}, school = {Universit{\"a}t Potsdam}, pages = {xvi, 183}, year = {2015}, abstract = {In this thesis we study reciprocal classes of Markov chains. Given a continuous time Markov chain on a countable state space, acting as reference dynamics, the associated reciprocal class is the set of all probability measures on path space that can be written as a mixture of its bridges. These processes possess a conditional independence property that generalizes the Markov property, and evolved from an idea of Schr{\"o}dinger, who wanted to obtain a probabilistic interpretation of quantum mechanics. Associated to a reciprocal class is a set of reciprocal characteristics, which are space-time functions that determine the reciprocal class. We compute explicitly these characteristics, and divide them into two main families: arc characteristics and cycle characteristics. As a byproduct, we obtain an explicit criterion to check when two different Markov chains share their bridges. Starting from the characteristics we offer two different descriptions of the reciprocal class, including its non-Markov probabilities. The first one is based on a pathwise approach and the second one on short time asymptotic. With the first approach one produces a family of functional equations whose only solutions are precisely the elements of the reciprocal class. These equations are integration by parts on path space associated with derivative operators which perturb the paths by mean of the addition of random loops. Several geometrical tools are employed to construct such formulas. The problem of obtaining sharp characterizations is also considered, showing some interesting connections with discrete geometry. Examples of such formulas are given in the framework of counting processes and random walks on Abelian groups, where the set of loops has a group structure. In addition to this global description, we propose a second approach by looking at the short time behavior of a reciprocal process. In the same way as the Markov property and short time expansions of transition probabilities characterize Markov chains, we show that a reciprocal class is characterized by imposing the reciprocal property and two families of short time expansions for the bridges. Such local approach is suitable to study reciprocal processes on general countable graphs. As application of our characterization, we considered several interesting graphs, such as lattices, planar graphs, the complete graph, and the hypercube. Finally, we obtain some first results about concentration of measure implied by lower bounds on the reciprocal characteristics.}, language = {en} } @phdthesis{Enzenberg2015, author = {Enzenberg, Anne}, title = {Neue fluoreszierende Copolymere f{\"u}r sensitive Detektionssysteme in Wasser}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-82325}, school = {Universit{\"a}t Potsdam}, pages = {xvi, 156, KK}, year = {2015}, abstract = {Ziel dieser Arbeit war die Synthese und Charakterisierung von neuartigen fluoreszierenden Copolymeren zur Analytdetektion in w{\"a}ssrigen Systemen. Das Detektionssystem sollte ein einfaches Schalten der Fluoreszenz bei Analytbindung „Aus" bzw. Verdr{\"a}ngung „An" erm{\"o}glichen. Daf{\"u}r wurde die Synthese eines funktionalisierten Monomers so geplant, dass sich Fluorophor und Analyt innerhalb derselben Monomereinheit in direkter Nachbarschaft zueinander befinden. So sollten bei Erkennung des Analyten durch eine mit einem Fluoreszenzl{\"o}scher funktionalisierte Erkennungsstruktur Fluorophor und L{\"o}scher in einen vorgegebenen Abstand zueinander gezwungen und die Fluoreszenz des Fluorophors effizient gel{\"o}scht werden. Bei anschließender Verdr{\"a}ngung der Erkennungseinheit durch einen st{\"a}rker bindenden Analyten sollte die Fluoreszenz wieder „angeschaltet" werden. Eine weitere Zielstellung f{\"u}r das Detektionssystem war eine hohe L{\"o}slichkeit und Fluoreszenzintensit{\"a}t in Wasser. Da die Anwendung solcher Sensoren besonders in der Medizin und Biologie, z.B. f{\"u}r Schnellerkennungstest von Pathogenen, von Interesse ist, ist die Kompatibilit{\"a}t mit w{\"a}ssrigen Medien essentiell. Die funktionalisierten Monomere wurden frei radikalisch mit N Vinyl-pyrrolidon bzw. N Vinyl¬caprolactam zu wasserl{\"o}slichen, fluoreszierenden Copolymeren umgesetzt. In den N-Vinyl¬pyrrolidon-Polymeren (PNVP) wurde RhodaminB, in den thermoresponsiven N Vinyl¬caprolactam-Polymeren (PNVCL) ein Naphthals{\"a}ureimid als Fluorophor verwendet. W{\"a}hrend Rhodamine eine hohe Fluoreszenzintensit{\"a}t, gute Quantenausbeuten und hohen Extinktionskoeffizienten in Wasser zeigen, sind Naphthals{\"a}ure¬imide umgebungssensitive Chromophore, die bei {\"A}nderung ihrer L{\"o}sungsmittelumgebung, wie z.B. beim Kollaps eines thermoresponsiven Polymers in Wasser, ihre Fluoreszenzintensit{\"a}t und Quantenausbeute drastisch {\"a}ndern k{\"o}nnen. Der Vorteil der hier verwendeten Strategie der Monomersynthese liegt darin, dass bei jeder spezifischen Analytdetektion durch eine Erkennungseinheit die Fluoreszenz effizient gel{\"o}scht bzw. bei Verdr{\"a}ngung durch einen st{\"a}rker bindenden Analyten wieder „angeschaltet" wird. Dieses Prinzip wird bereits vielfach in der Biologie in sogenannten „Molecular Beacons" ausgenutzt, wobei ein Fluorophor und ein L{\"o}scher durch spezifische DNA Basenpaarung in einen vorgegebenen Abstand zueinander gezwungen werden und so ein „Schalten" der Fluoreszenz erm{\"o}glichen. Aufgrund der vorgegebenen Struktur der DNA Basensequenzen ist es jedoch nicht direkt auf andere Erkennungsreaktionen {\"u}bertragbar. Daher wurde ein Modellsystem entwickelt, welches die M{\"o}glichkeit bietet Analyt, Erkennungseinheit und Signalgeber variabel, je nach Anforderungen des Systems, auszutauschen. So soll es m{\"o}glich sein, den Sensor a priori f{\"u}r jede Erkennungs¬reaktion zu verwenden. Als Modell Bindungs¬paare wurden ß Cyclodextrin/Adamantan und Con¬cana¬valinA/Mannose ausgew{\"a}hlt. Adamantan bzw. Mannose wurde als Analyt zusammen mit dem Fluorophor in das Polymer eingebunden. ß Cyclo¬dextrin (ß CD) bzw. ConcanavalinA (ConA) wurde als Erkennungsstruktur an einem Fluoreszenzl{\"o}scher immobilisiert. Polymer-basierte Fluoreszenzsensoren sind in der Fachliteratur gut dokumentiert. In der Regel sind Signalgeber und Analyt jedoch statistisch im Polymer verteilt, da sie sich entweder in unterschiedlichen Monomereinheiten befinden oder die Funktionalisierung durch eine polymeranaloge Umsetzung erfolgt. Der gew{\"a}hlte Ansatz Fluorophor und Analyt innerhalb derselben Monomereinheit einzubinden, soll bei jeder Erkennungsreaktion des Analyten zu einer {\"A}nderung der Signalintensit{\"a}t des Fluorophors f{\"u}hren. Eine hohe Signalintensit{\"a}t bei Analytdetektion ist w{\"u}nschenswert, insbesondere f{\"u}r Erkennungsreaktionen, die mit m{\"o}glichst geringem apparativem Aufwand, am besten mit dem bloßen Auge zu verfolgen sein sollen. Des Weiteren ist es m{\"o}glich den Fluorophorgehalt im Polymer genau einzustellen und so Selbstl{\"o}schung zu vermeiden. Die synthetisierten Polymere haben einen Fluorophorgehalt von 0,01 mol\% bis 0,5 mol\%. F{\"u}r die RhodaminB haltigen Polymere zeigte sich, dass ein Fluorophorgehalt unterhalb 0,1 mol\% im Polymer die h{\"o}chsten Ausbeuten, Molmassen und Quantenausbeuten liefert. F{\"u}r die Naphthals{\"a}ureimid haltigen Polymere hingegen wurden auch f{\"u}r einen Fluorophorgehalt von bis zu 1 mol\% hohe Ausbeuten und Molmassen erreicht. Die Naphthals{\"a}ureimid haltigen Polymere haben jedoch in w{\"a}ssriger L{\"o}sungsmittelumgebung nur geringe Quantenausbeuten. Als Fluoreszenzl{\"o}scher wurden Goldnanopartikel synthetisiert, die mit den entsprechenden Erkennungsstrukturen (ß-CD oder ConA) f{\"u}r den verwendeten Analyten funktionalisiert wurden. Goldnanopartikel als L{\"o}scher bieten den Vorteil, dass ihre Dispergierbarkeit in einem L{\"o}semittel durch Funktionalisierung ihrer H{\"u}lle gezielt gesteuert werden kann. Durch die hohe Affinit{\"a}t von Goldnanopartikeln zu Thiolen und Aminen konnten sie mit Hilfe einfacher Syntheseschritte mit Thio ß CD Derivaten bzw. ConA funktionalisiert werden. In der hier vorgelegten Arbeit sollte ein Modellsystem f{\"u}r einen solches fluoreszenz-basiertes Detektionssystem in Wasser entwickelt werden. Nachfolgend werden die zu erf{\"u}llenden strukturellen Voraussetzungen f{\"u}r die Synthese eines solchen Sensors nochmals zusammengefasst: 1. Verwendung eines Fluorophors, der eine hohe Signalintensit{\"a}t zeigt. 2. Analyt bzw. Erkennungseinheit soll sich im Abstand von wenigen Nanometern zum Signalgeber befinden, um bei jeder Detektionsreaktion die Signalintensit{\"a}t des Signalgebers beeinflussen zu k{\"o}nnen. 3. Die Detektionseinheit ben{\"o}tigt eine funktionelle Gruppe zur Immobilisierung. Immobilisierung kann z.B. durch Einbindung in ein Polymer erfolgen. 4. Der Fluorophor soll bei {\"A}nderung seiner lokalen Umgebung, durch Binden eines L{\"o}schers oder {\"A}nderung seiner L{\"o}semittelumgebung seine Fluoreszenzeigenschaften drastisch {\"a}ndern. 5. Die Reaktion sollte schnell und mit m{\"o}glichst geringem apparativem Aufwand, am besten mit bloßem Auge zu verfolgen sein. F{\"u}r das ß-CD/Adamantan Modellsystem wurde ein Fluoreszenz Aus/An Sensor entwickelt, der bei Binden ß CD funktionalisierter Goldnanopartikel an das polymergebundene Adamantan die Fluoreszenz des RhodaminB Fluorophors effizient l{\"o}scht und bei Verdr{\"a}ngung der Goldnanopartikel wieder zur{\"u}ck gewinnt. Dies konnte auch mit bloßem Auge verfolgt werden. F{\"u}r die Naphthals{\"a}ureimid Monomere, die mit NVCL copolymerisiert wurden, wurde abh{\"a}ngig von der lokalen Umgebung des Fluorophors eine unterschiedliche Verst{\"a}rkung der Fluoreszenzintensit{\"a}t bei {\"U}berschreiten des Tr{\"u}bungspunktes des Polymers gefunden. Dabei zeigte sich, dass die Einf{\"u}hrung eines Abstandshalters zwischen Polymerr{\"u}ckgrat und Fluorophor zu einer großen Fluoreszenz¬verst{\"a}rkung f{\"u}hrt, w{\"a}hrend sich ohne Abstandshalter die Fluoreszenzintensit{\"a}t bei {\"U}ber¬schreiten des Tr{\"u}bungspunktes kaum {\"a}ndert.}, language = {de} } @phdthesis{Kaganova2015, author = {Kaganova, Ekaterina}, title = {Das Lehrpotential von Schulbuchlehrtexten im Fach Mathematik}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-80705}, school = {Universit{\"a}t Potsdam}, pages = {287}, year = {2015}, abstract = {Das Schulbuch ist ein etablierter und bedeutender Bestandteil des Mathematikunterrichts. Lehrer nutzen es, um ihren Unterricht vorzubereiten und/oder zu gestalten; Sch{\"u}ler, um in selbigem zu lernen und zu bestehen, vielleicht sogar aus eigenem Interesse; Eltern, um sich dar{\"u}ber zu informieren, was ihr Kind eigentlich k{\"o}nnen soll und wie sie ihm gegebenenfalls helfen k{\"o}nnen. Dar{\"u}ber hinaus ist das Schulbuch ein markantes gesellschaftliches Produkt, dessen Zweck es ist, das Unterrichtsgeschehen zu steuern und zu beeinflussen. Damit ist es auch ein Anzeiger daf{\"u}r, was und wie im Mathematikunterricht gelehrt werden sollte und wird. Die Lehrtexte als zentrale Bestandteile von Schulb{\"u}chern verweisen in diesem Zusammenhang insbesondere auf die Phasen der Einf{\"u}hrung neuen Lernstoffs. Daraus legitimiert sich {\"u}bergreifend die Fragestellung, was und wie (gut) Mathematikschulbuchlehrtexte lehren bzw. was und wie (gut) adressierte Sch{\"u}ler aus ihnen (selbstst{\"a}ndig) lernen, d.h. Wissen erwerben k{\"o}nnen. Angesichts der komplexen und vielf{\"a}ltigen Bedeutung von Schulbuchlehrtexten verwundert es, dass die mathematikdidaktische Forschung bislang wenig Interesse an ihnen zeigt: Es fehlen sowohl eine theoretische Konzeption der Gr{\"o}ße ‚Lehrpotential eines schulmathematischen Lehrtextes' als auch ein analytisches Verfahren, um das anhand eines Mathematikschulbuchlehrtextes Verstehbare und Lernbare zu ermitteln. Mit der vorliegenden Arbeit wird sowohl in theoretisch-methodologischer als auch in empirischer Hinsicht der Versuch unternommen, diesen Defiziten zu begegnen. Dabei wird das ‚Lehrpotential eines Mathematikschulbuchlehrtextes' auf der Grundlage der kognitionspsychologischen Schematheorie und unter Einbeziehung textlinguistischer Ans{\"a}tze als eine textimmanente und analytisch zug{\"a}ngliche Gr{\"o}ße konzipiert. Anschließend wird das Lehrpotential von f{\"u}nf Lehrtexten ausgew{\"a}hlter aktueller Schulb{\"u}cher der Jahrgangsstufen 6 und 7 zu den Inhaltsbereichen ‚Br{\"u}che' und ‚lineare Funktionen' analysiert. Es zeigt sich, dass die untersuchten Lehrtexte aus deutschen Schulb{\"u}chern f{\"u}r Sch{\"u}ler sehr schwer verst{\"a}ndlich sind, d.h. es ist kompliziert, einigen Teiltexten im Rahmen des Gesamttextes einen Sinn abzugewinnen. Die Lehrtexte sind insbesondere dann kaum sinnhaft lesbar, wenn ein Sch{\"u}ler versucht, die mitgeteilten Sachverhalte zu verstehen, d.h. Antworten auf die Fragen zu erhalten, warum ein mathematischer Sachverhalt gerade so und nicht anders ist, wozu ein neuer Sachverhalt/Begriff gebraucht wird, wie das Neue mit bereits Bekanntem zusammenh{\"a}ngt usw. Deutlich zug{\"a}nglicher und sinnhafter erscheinen die Mathematikschulbuchlehrtexte hingegen unter der Annahme, dass ihre zentrale Botschaft in der Mitteilung besteht, welche Aufgabenstellungen in der jeweiligen Lehreinheit vorkommen und wie man sie bearbeitet. Demnach k{\"o}nnen Sch{\"u}ler anhand dieser Lehrtexte im Wesentlichen lernen, wie sie mit mathematischen Zeichen, die f{\"u}r sie kaum etwas bezeichnen, umgehen sollen. Die hier vorgelegten Analyseergebnisse gewinnen in einem soziologischen Kontext an Tragweite und Brisanz. So l{\"a}sst sich aus ihnen u.a. die These ableiten, dass die analysierten Lehrtexte keine ‚ungl{\"u}cklichen' Einzelf{\"a}lle sind, sondern dass die ‚Aufgabenorientierung in einem mathematischen Gewand' ein Charakteristikum typischer (deutscher) Mathematikschulbuchlehrtexte und - noch grunds{\"a}tzlicher - einen Wesenszug typischer schulmathematischer Kommunikation darstellt.}, language = {de} } @phdthesis{Kuenstler2015, author = {K{\"u}nstler, Andreas}, title = {Spot evolution on the red giant star XX Triangulum}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-84008}, school = {Universit{\"a}t Potsdam}, year = {2015}, abstract = {Spots on stellar surfaces are thought to be stellar analogues of sunspots. Thus, starspots are direct manifestations of strong magnetic fields. Their decay rate is directly related to the magnetic diffusivity, which itself is a key quantity for the deduction of an activity cycle length. So far, no single starspot decay has been observed, and thus no stellar activity cycle was inferred from its corresponding turbulent diffusivity. We investigate the evolution of starspots on the rapidly-rotating K0 giant XX Triangulum. Continuous high-resolution and phase-resolved spectroscopy was obtained with the robotic 1.2-m STELLA telescope on Tenerife over a timespan of six years. With our line-profile inversion code iMap we reconstruct a total of 36 consecutive Doppler maps. To quantify starspot area decay and growth, we match the observed images with simplified spot models based on a Monte-Carlo approach. It is shown that the surface of XX Tri is covered with large high-latitude and even polar spots and with occasional small equatorial spots. Just over the course of six years, we see a systematically changing spot distribution with various time scales and morphology such as spot fragmentation and spot merging as well as spot decay and formation. For the first time, a starspot decay rate on another star than the Sun is determined. From our spot-decay analysis we determine an average linear decay rate of D = -0.067±0.006 Gm^2/day. From this decay rate, we infer a turbulent diffusivity of η_τ = (6.3±0.5) x 10^14 cm^2/s and consequently predict an activity cycle of 26±6 years. The obtained cycle length matches very well with photometric observations. Our time-series of Doppler maps further enables to investigate the differential rotation of XX Tri. We therefore applied a cross-correlation analysis. We detect a weak solar-like differential rotation with a surface shear of α = 0.016±0.003. This value agrees with similar studies of other RS CVn stars. Furthermore, we found evidence for active longitudes and flip-flops. Whereas the more active longitude is located in phase towards the (unseen) companion star, the weaker active longitude is located at the opposite stellar hemisphere. From their periodic appearance, we infer a flip-flop cycle of ~2 years. Both activity phenomena are common on late-type binary stars. Last but not least we redetermine several astrophysical properties of XX Tri and its binary system, as large datasets of photometric and spectroscopic observations are available since its last determination in 1999. Additionally, we compare the rotational spot-modulation from photometric and spectroscopic studies.}, language = {en} } @phdthesis{Mueller2015, author = {M{\"u}ller, Katja}, title = {Analphabetismus und Teilhabe}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, isbn = {978-3-86956-332-9}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-76325}, school = {Universit{\"a}t Potsdam}, pages = {xii, 255}, year = {2015}, abstract = {Aus bildungstheoretisch-gesellschaftskritischer Perspektive stellt sich Lernen als soziales Handeln in gesellschaftlich-vermittelten Verh{\"a}ltnissen - M{\"o}glichkeiten wie auch Begrenzungen - dar. Funktionaler Analphabetismus ist mit einem bundesweiten Anteil von 14\% der erwerbsf{\"a}higen Bev{\"o}lkerung oder 7,5 Millionen Analphabeten in Deutschland nicht nur ein bildungspolitisches und -praktisches, sondern auch ein wissenschaftlich zu untersuchendes Ph{\"a}nomen. Es gibt zahlreiche Untersuchungen, die sich mit dieser Thematik auseinandersetzen und Ankn{\"u}pfungspunkte f{\"u}r die vorliegende Studie bieten. Aus der Zielgruppenforschung beispielsweise ist bekannt, dass die Hauptadressaten der M{\"a}nner, der {\"A}lteren und der Bildungsfernen nicht ad{\"a}quat erreicht bzw. als Teilnehmende gewonnen werden. Aus der Teilnehmendenforschung sind Abbr{\"u}che und Drop-Outs bekannt. Warum Analphabeten im Erwachsenenalter, also nach der Aneignung vielf{\"a}ltigster Bew{\"a}ltigungsstrategien, durch das sich das Ph{\"a}nomen einer direkten Sichtbarkeit entzieht, dennoch beginnen das Lesen und Schreiben (wieder) zu lernen, wird bislang weder bildungs- noch lerntheoretisch untersucht. Im Rahmen der vorliegenden Erwachsenenbildungsstudie werden genau diese Lernanl{\"a}sse empirisch herausgearbeitet. Als Heuristik wird auf eine subjekttheoretische Theoriefolie rekurriert, die sich in besonderer Weise eignet Lernbegr{\"u}ndungen im Kontext gesellschaftlich verhafteter Biografien sichtbar zu machen. Lernforschung im Begr{\"u}ndungsmodell muss dabei auf eine Methodik zur{\"u}ckgreifen, die die Perspektive des Subjekts, Bedeutungszusammenh{\"a}nge und typische Sinnstrukturen hervorbringen kann. Daher wird ein auf Einzelfallstudien basierendes, qualitatives Forschungsdesign gew{\"a}hlt, das Daten aus der Erhebung mittels problemzentrierter Interviews bereitstellt, die eine Auswertung innerhalb der Forschungsstrategie der Grounded Theory erfahren und in einer empirisch begr{\"u}ndeten Typenbildung m{\"u}nden. Dieses Design erm{\"o}glicht die Rekonstruktion typischer Lernanl{\"a}sse und im Ergebnis die Entwicklung einer gegenstandsbezogene Theorie mittlerer Reichweite. Aus der vorliegenden Bedeutungs-Begr{\"u}ndungsanalyse konnten empirisch f{\"u}nf Lernbegr{\"u}ndungstypen ausdifferenziert werden, die sich im Spannungsverh{\"a}ltnis von Teilhabeausrichtung und Widerspr{\"u}chlichkeit bewegen und in ihrer Komplexit{\"a}t mittels der drei Schl{\"u}sselkategorien Bedeutungsraum, Reflexion der sozialen Eingebundenheit und Kompetenzen sowie Lernen bzw. dem Erleben der Diskrepanzerfahrung zwischen Lesen-Wollen und Lesen-K{\"o}nnen dargestellt werden. Das Spektrum der Lernbegr{\"u}ndungstypen reicht von teilhabesicherndem resignierten Lernen, bei dem die Sicherung des bedrohten Status quo im Vordergrund steht und die Welt als nicht gestaltbar erlebt wird, bis hin zu vielschichtigem teilhabeerweiternden Lernen, das auf die Erweiterung der eigenen Handlungsm{\"o}glichkeiten zielt und die umfangreichste Reflexion der sozialen Eingebundenheit und Kompetenzen aufweist. Funktionale Analphabeten begr{\"u}nden ihr Lernen und Nicht-Lernen vor dem Hintergrund ihrer sozialen Situation, ihrer Begrenzungen und M{\"o}glichkeiten: Schriftsprachlernen erh{\"a}lt erst im Kontext gesellschaftlicher Teilhabe und dessen Reflexion eine Bedeutung. Mit der Einordnung der Lernbegr{\"u}ndungen funktionaler Analphabeten in: erstens, Diskurse der Bildungsbenachteiligung durch Exklusionsprozesse; zweitens, die lerntheoretische Bedeutung von Inklusionsprozessen und drittens, den internationalen Theorieansatz transformativen Lernens durch die Integration der Reflexionskategorie, erfolgt eine Erweiterung bildungs- und lerntheoretischer Ans{\"a}tze. In dieser Arbeit werden Alphabetisierungs- und Erwachsenen-bildungsforschung verbunden und in den jeweiligen Diskurs integriert. Weitere Anschluss- und Verwertungsm{\"o}glichkeiten in der Bildungsforschung w{\"a}ren denkbar. Die Untersuchung von Lernbegr{\"u}ndungen im L{\"a}ngsschnitt beispielsweise kann Transformationsprozesse rekonstruierbar machen und somit Ertr{\"a}ge f{\"u}r eine Bildungsprozessforschung liefern. Bildungspraktisch k{\"o}nnen die Lernbegr{\"u}ndungstypen einerseits der Teilnehmergewinnung dienen, andererseits Ausgangspunkt f{\"u}r reflexive Lernbegleitungskonzepte sein, die Lernbegr{\"u}ndungen zur Sprache bringen und die soziale Eingebundenheit thematisieren und damit Lernprozesse unterst{\"u}tzen.}, language = {de} } @phdthesis{Soulie2015, author = {Souli{\´e}, Virginie}, title = {Sessile droplets of salt solutions on inert and metallic surfaces}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-90329}, school = {Universit{\"a}t Potsdam}, year = {2015}, abstract = {In this thesis we investigate the evaporation behaviour of sessile droplets of aqueous saline solutions on planar inert and metallic surfaces and characterise the corrosion phenomenon for iron surfaces. First we study the evaporation behaviour of sessile salty droplets on inert surfaces for a wide range of salt concentrations, relative humidities, droplet sizes and contact angles. Our study reveals the range of validity of the well-accepted diffusion-controlled evaporation model and highlights the impact of salt concentration (surface tension) gradients driven Marangoni flows on the evaporation behaviour and the subsequent salty deposit patterns. Furthermore we study the spatial-temporal evolution of sessile droplets from saline solutions on metallic surfaces. In contrast to the simple, generally accepted Evans droplet model, we show that the corrosion spreads ahead of the macroscopic contact line with a peripheral film. The three-phase contact line is destabilized by surface tension gradients induced by ionic composition changes during the course of the corrosion process and migration of cations towards the droplet perimeter. Finally we investigate the corrosion behaviour under drying salty sessile droplets on metallic surfaces. The corrosion process, in particular the location of anodic and cathodic activities over the footprint droplet area is correlated to the spatial distribution of the salt inside the drying droplet.}, language = {en} } @phdthesis{Schroeder2015, author = {Schr{\"o}der, Sarah}, title = {Modelling surface evolution coupled with tectonics}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-90385}, school = {Universit{\"a}t Potsdam}, pages = {viii, 129}, year = {2015}, abstract = {This study presents the development of 1D and 2D Surface Evolution Codes (SECs) and their coupling to any lithospheric-scale (thermo-)mechanical code with a quadrilateral structured surface mesh. Both SECs involve diffusion as approach for hillslope processes and the stream power law to reflect riverbed incision. The 1D SEC settles sediment that was produced by fluvial incision in the appropriate minimum, while the supply-limited 2D SEC DANSER uses a fast filling algorithm to model sedimantation. It is based on a cellular automaton. A slope-dependent factor in the sediment flux extends the diffusion equation to nonlinear diffusion. The discharge accumulation is achieved with the D8-algorithm and an improved drainage accumulation routine. Lateral incision enhances the incision's modelling. Following empirical laws, it incises channels of several cells width. The coupling method enables different temporal and spatial resolutions of the SEC and the thermo-mechanical code. It transfers vertical as well as horizontal displacements to the surface model. A weighted smoothing of the 3D surface displacements is implemented. The smoothed displacement vectors transmit the deformation by bilinear interpolation to the surface model. These interpolation methods ensure mass conservation in both directions and prevent the two surfaces from drifting apart. The presented applications refer to the evolution of the Pamir orogen. A calibration of DANSER's parameters with geomorphological data and a DEM as initial topography highlights the advantage of lateral incision. Preserving the channel width and reflecting incision peaks in narrow channels, this closes the huge gap between current orogen-scale incision models and observed topographies. River capturing models in a system of fault-bounded block rotations reaffirm the importance of the lateral incision routine for capturing events with channel initiation. The models show a low probability of river capturings with large deflection angles. While the probability of river capturing is directly depending on the uplift rate, the erodibility inside of a dip-slip fault speeds up headward erosion along the fault: The model's capturing speed increases within a fault. Coupling DANSER with the thermo-mechanical code SLIM 3D emphasizes the versatility of the SEC. While DANSER has minor influence on the lithospheric evolution of an indenter model, the brittle surface deformation is strongly affected by its sedimentation, widening a basin in between two forming orogens and also the southern part of the southern orogen to south, east and west.}, language = {en} } @phdthesis{Kniepert2015, author = {Kniepert, Juliane}, title = {Correlation between dynamic parameters and device performance of organic solar cells}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-90087}, school = {Universit{\"a}t Potsdam}, pages = {129}, year = {2015}, abstract = {Organic bulk heterojunction (BHJ) solar cells based on polymer:fullerene blends are a promising alternative for a low-cost solar energy conversion. Despite significant improvements of the power conversion efficiency in recent years, the fundamental working principles of these devices are yet not fully understood. In general, the current output of organic solar cells is determined by the generation of free charge carriers upon light absorption and their transport to the electrodes in competition to the loss of charge carriers due to recombination. The object of this thesis is to provide a comprehensive understanding of the dynamic processes and physical parameters determining the performance. A new approach for analyzing the characteristic current-voltage output was developed comprising the experimental determination of the efficiencies of charge carrier generation, recombination and transport, combined with numerical device simulations. Central issues at the beginning of this work were the influence of an electric field on the free carrier generation process and the contribution of generation, recombination and transport to the current-voltage characteristics. An elegant way to directly measure the field dependence of the free carrier generation is the Time Delayed Collection Field (TDCF) method. In TDCF charge carriers are generated by a short laser pulse and subsequently extracted by a defined rectangular voltage pulse. A new setup was established with an improved time resolution compared to former reports in literature. It was found that charge generation is in general independent of the electric field, in contrast to the current view in literature and opposed to the expectations of the Braun-Onsager model that was commonly used to describe the charge generation process. Even in cases where the charge generation was found to be field-dependend, numerical modelling showed that this field-dependence is in general not capable to account for the voltage dependence of the photocurrent. This highlights the importance of efficient charge extraction in competition to non-geminate recombination, which is the second objective of the thesis. Therefore, two different techniques were combined to characterize the dynamics and efficiency of non-geminate recombination under device-relevant conditions. One new approach is to perform TDCF measurements with increasing delay between generation and extraction of charges. Thus, TDCF was used for the first time to measure charge carrier generation, recombination and transport with the same experimental setup. This excludes experimental errors due to different measurement and preparation conditions and demonstrates the strength of this technique. An analytic model for the description of TDCF transients was developed and revealed the experimental conditions for which reliable results can be obtained. In particular, it turned out that the \$RC\$ time of the setup which is mainly given by the sample geometry has a significant influence on the shape of the transients which has to be considered for correct data analysis. Secondly, a complementary method was applied to characterize charge carrier recombination under steady state bias and illumination, i.e. under realistic operating conditions. This approach relies on the precise determination of the steady state carrier densities established in the active layer. It turned out that current techniques were not sufficient to measure carrier densities with the necessary accuracy. Therefore, a new technique {Bias Assisted Charge Extraction} (BACE) was developed. Here, the charge carriers photogenerated under steady state illumination are extracted by applying a high reverse bias. The accelerated extraction compared to conventional charge extraction minimizes losses through non-geminate recombination and trapping during extraction. By performing numerical device simulations under steady state, conditions were established under which quantitative information on the dynamics can be retrieved from BACE measurements. The applied experimental techniques allowed to sensitively analyse and quantify geminate and non-geminate recombination losses along with charge transport in organic solar cells. A full analysis was exemplarily demonstrated for two prominent polymer-fullerene blends. The model system P3HT:PCBM spincast from chloroform (as prepared) exhibits poor power conversion efficiencies (PCE) on the order of 0.5\%, mainly caused by low fill factors (FF) and currents. It could be shown that the performance of these devices is limited by the hole transport and large bimolecular recombination (BMR) losses, while geminate recombination losses are insignificant. The low polymer crystallinity and poor interconnection between the polymer and fullerene domains leads to a hole mobility of the order of 10^-7 cm^2/Vs which is several orders of magnitude lower than the electron mobility in these devices. The concomitant build up of space charge hinders extraction of both electrons and holes and promotes bimolecular recombination losses. Thermal annealing of P3HT:PCBM blends directly after spin coating improves crystallinity and interconnection of the polymer and the fullerene phase and results in comparatively high electron and hole mobilities in the order of 10^-3 cm^2/Vs and 10^-4 cm^2/Vs, respectively. In addition, a coarsening of the domain sizes leads to a reduction of the BMR by one order of magnitude. High charge carrier mobilities and low recombination losses result in comparatively high FF (>65\%) and short circuit current (J_SC ≈ 10 mA/cm^2). The overall device performance (PCE ≈ 4\%) is only limited by a rather low spectral overlap of absorption and solar emission and a small V_OC, given by the energetics of the P3HT. From this point of view the combination of the low bandgap polymer PTB7 with PCBM is a promising approach. In BHJ solar cells, this polymer leads to a higher V_OC due to optimized energetics with PCBM. However, the J_SC in these (unoptimized) devices is similar to the J_SC in the optimized blend with P3HT and the FF is rather low (≈ 50\%). It turned out that the unoptimized PTB7:PCBM blends suffer from high BMR, a low electron mobility of the order of 10^-5 cm^2/Vs and geminate recombination losses due to field dependent charge carrier generation. The use of the solvent additive DIO optimizes the blend morphology, mainly by suppressing the formation of very large fullerene domains and by forming a more uniform structure of well interconnected donor and acceptor domains of the order of a few nanometers. Our analysis shows that this results in an increase of the electron mobility by about one order of magnitude (3 x 10^-4 cm^2/Vs), while BMR and geminate recombination losses are significantly reduced. In total these effects improve the J_SC (≈ 17 mA/cm^2) and the FF (> 70\%). In 2012 this polymer/fullerene combination resulted in a record PCE for a single junction OSC of 9.2\%. Remarkably, the numerical device simulations revealed that the specific shape of the J-V characteristics depends very sensitively to the variation of not only one, but all dynamic parameters. On the one hand this proves that the experimentally determined parameters, if leading to a good match between simulated and measured J-V curves, are realistic and reliable. On the other hand it also emphasizes the importance to consider all involved dynamic quantities, namely charge carrier generation, geminate and non-geminate recombination as well as electron and hole mobilities. The measurement or investigation of only a subset of these parameters as frequently found in literature will lead to an incomplete picture and possibly to misleading conclusions. Importantly, the comparison of the numerical device simulation employing the measured parameters and the experimental \$J-V\$ characteristics allows to identify loss channels and limitations of OSC. For example, it turned out that inefficient extraction of charge carriers is a criticical limitation factor that is often disobeyed. However, efficient and fast transport of charges becomes more and more important with the development of new low bandgap materials with very high internal quantum efficiencies. Likewise, due to moderate charge carrier mobilities, the active layer thicknesses of current high-performance devices are usually limited to around 100 nm. However, larger layer thicknesses would be more favourable with respect to higher current output and robustness of production. Newly designed donor materials should therefore at best show a high tendency to form crystalline structures, as observed in P3HT, combined with the optimized energetics and quantum efficiency of, for example, PTB7.}, language = {en} } @phdthesis{Neugebauer2015, author = {Neugebauer, Ina}, title = {Reconstructing climate from the Dead Sea sediment record using high-resolution micro-facies analyses}, series = {Dissertation}, journal = {Dissertation}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-85266}, school = {Universit{\"a}t Potsdam}, pages = {xiv, 97, XXIII}, year = {2015}, abstract = {The sedimentary record of the Dead Sea is a key archive for reconstructing climate in the eastern Mediterranean region, as it stores the environmental and tectonic history of the Levant for the entire Quaternary. Moreover, the lake is located at the boundary between Mediterranean sub-humid to semi-arid and Saharo-Arabian hyper-arid climates, so that even small shifts in atmospheric circulation are sensitively recorded in the sediments. This DFG-funded doctoral project was carried out within the ICDP Dead Sea Deep Drilling Project (DSDDP) that intended to gain the first long, continuous and high-resolution sediment core from the deep Dead Sea basin. The drilling campaign was performed in winter 2010-11 and more than 700 m of sediments were recovered. The main aim of this thesis was (1) to establish the lithostratigraphic framework for the ~455 m long sediment core from the deep Dead Sea basin and (2) to apply high-resolution micro-facies analyses for reconstructing and better understanding climate variability from the Dead Sea sediments. Addressing the first aim, the sedimentary facies of the ~455 m long deep-basin core 5017-1 were described in great detail and characterised through continuous overview-XRF element scanning and magnetic susceptibility measurements. Three facies groups were classified: (1) the marl facies group, (2) the halite facies group and (3) a group involving different expressions of massive, graded and slumped deposits including coarse clastic detritus. Core 5017-1 encompasses a succession of four main lithological units. Based on first radiocarbon and U-Th ages and correlation of these units to on-shore stratigraphic sections, the record comprises the last ca 220 ka, i.e. the upper part of the Amora Formation (parts of or entire penultimate interglacial and glacial), the last interglacial Samra Fm. (~135-75 ka), the last glacial Lisan Fm. (~75-14 ka) and the Holocene Ze'elim Formation. A major advancement of this record is that, for the first time, also transitional intervals were recovered that are missing in the exposed formations and that can now be studied in great detail. Micro-facies analyses involve a combination of high-resolution microscopic thin section analysis and µXRF element scanning supported by magnetic susceptibility measurements. This approach allows identifying and characterising micro-facies types, detecting event layers and reconstructing past climate variability with up to seasonal resolution, given that the analysed sediments are annually laminated. Within this thesis, micro-facies analyses, supported by further sedimentological and geochemical analyses (grain size, X-ray diffraction, total organic carbon and calcium carbonate contents) and palynology, were applied for two time intervals: (1) The early last glacial period ~117-75 ka was investigated focusing on millennial-scale hydroclimatic variations and lake level changes recorded in the sediments. Thereby, distinguishing six different micro-facies types with distinct geochemical and sedimentological characteristics allowed estimating relative lake level and water balance changes of the lake. Comparison of the results to other records in the Mediterranean region suggests a close link of the hydroclimate in the Levant to North Atlantic and Mediterranean climates during the time of the build-up of Northern hemisphere ice sheets during the early last glacial period. (2) A mostly annually laminated late Holocene section (~3700-1700 cal yr BP) was analysed in unprecedented detail through a multi-proxy, inter-site correlation approach of a shallow-water core (DSEn) and its deep-basin counterpart (5017-1). Within this study, a ca 1500 years comprising time series of erosion and dust deposition events was established and anchored to the absolute time-scale through 14C dating and age modelling. A particular focus of this study was the characterisation of two dry periods, from ~3500 to 3300 and from ~3000 to 2400 cal yr BP, respectively. Thereby, a major outcome was the coincidence of the latter dry period with a period of moist and cold climate in Europe related to a Grand Solar Minimum around 2800 cal yr BP and an increase in flood events despite overall dry conditions in the Dead Sea region during that time. These contrasting climate signatures in Europe and at the Dead Sea were likely linked through complex teleconnections of atmospheric circulation, causing a change in synoptic weather patterns in the eastern Mediterranean. In summary, within this doctorate the lithostratigraphic framework of a unique long sediment core from the deep Dead Sea basin is established, which serves as a base for any further high-resolution investigations on this core. It is demonstrated in two case studies that micro-facies analyses are an invaluable tool to understand the depositional processes in the Dead Sea and to decipher past climate variability in the Levant on millennial to seasonal time-scales. Hence, this work adds important knowledge helping to establish the deep Dead Sea record as a key climate archive of supra-regional significance.}, language = {en} } @phdthesis{Mucha2015, author = {Mucha, Anne}, title = {Temporal interpretation and cross-linguistic variation}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-85935}, school = {Universit{\"a}t Potsdam}, pages = {x, 249}, year = {2015}, abstract = {This thesis investigates temporal and aspectual reference in the typologically unrelated African languages Hausa (Chadic, Afro-Asiatic) and Medumba (Grassfields Bantu). It argues that Hausa is a genuinely tenseless language and compares the interpretation of temporally unmarked sentences in Hausa to that of morphologically tenseless sentences in Medumba, where tense marking is optional and graded. The empirical behavior of the optional temporal morphemes in Medumba motivates an analysis as existential quantifiers over times and thus provides new evidence suggesting that languages vary in whether their (past) tense is pronominal or quantificational (see also Sharvit 2014). The thesis proposes for both Hausa and Medumba that the alleged future tense marker is a modal element that obligatorily combines with a prospective future shifter (which is covert in Medumba). Cross-linguistic variation in whether or not a future marker is compatible with non-future interpretation is proposed to be predictable from the aspectual architecture of the given language.}, language = {en} } @phdthesis{Meyer2015, author = {Meyer, Andreas}, title = {Data perspective in business process management}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-84806}, school = {Universit{\"a}t Potsdam}, pages = {xxi, 362}, year = {2015}, abstract = {Gesch{\"a}ftsprozessmanagement ist ein strukturierter Ansatz zur Modellierung, Analyse, Steuerung und Ausf{\"u}hrung von Gesch{\"a}ftsprozessen, um Gesch{\"a}ftsziele zu erreichen. Es st{\"u}tzt sich dabei auf konzeptionelle Modelle, von denen Prozessmodelle am weitesten verbreitet sind. Prozessmodelle beschreiben wer welche Aufgabe auszuf{\"u}hren hat, um das Gesch{\"a}ftsziel zu erreichen, und welche Informationen daf{\"u}r ben{\"o}tigt werden. Damit beinhalten Prozessmodelle Informationen {\"u}ber den Kontrollfluss, die Zuweisung von Verantwortlichkeiten, den Datenfluss und Informationssysteme. Die Automatisierung von Gesch{\"a}ftsprozessen erh{\"o}ht die Effizienz der Arbeitserledigung und wird durch Process Engines unterst{\"u}tzt. Daf{\"u}r werden jedoch Informationen {\"u}ber den Kontrollfluss, die Zuweisung von Verantwortlichkeiten f{\"u}r Aufgaben und den Datenfluss ben{\"o}tigt. W{\"a}hrend aktuelle Process Engines die ersten beiden Informationen weitgehend automatisiert verarbeiten k{\"o}nnen, m{\"u}ssen Daten manuell implementiert und gewartet werden. Dem entgegen verspricht ein modell-getriebenes Behandeln von Daten eine vereinfachte Implementation in der Process Engine und verringert gleichzeitig die Fehleranf{\"a}lligkeit dank einer graphischen Visualisierung und reduziert den Entwicklungsaufwand durch Codegenerierung. Die vorliegende Dissertation besch{\"a}ftigt sich mit der Modellierung, der Analyse und der Ausf{\"u}hrung von Daten in Gesch{\"a}ftsprozessen. Als formale Basis f{\"u}r die Prozessausf{\"u}hrung wird ein konzeptuelles Framework f{\"u}r die Integration von Prozessen und Daten eingef{\"u}hrt. Dieses Framework wird durch operationelle Semantik erg{\"a}nzt, die mittels einem um Daten erweiterten Petrinetz-Mapping vorgestellt wird. Die modellgetriebene Ausf{\"u}hrung von Daten muss komplexe Datenabh{\"a}ngigkeiten, Prozessdaten und den Datenaustausch ber{\"u}cksichtigen. Letzterer tritt bei der Kommunikation zwischen mehreren Prozessteilnehmern auf. Diese Arbeit nutzt Konzepte aus dem Bereich der Datenbanken und {\"u}berf{\"u}hrt diese ins Gesch{\"a}ftsprozessmanagement, um Datenoperationen zu unterscheiden, um Abh{\"a}ngigkeiten zwischen Datenobjekten des gleichen und verschiedenen Typs zu spezifizieren, um modellierte Datenknoten sowie empfangene Nachrichten zur richtigen laufenden Prozessinstanz zu korrelieren und um Nachrichten f{\"u}r die Prozess{\"u}bergreifende Kommunikation zu generieren. Der entsprechende Ansatz ist nicht auf eine bestimmte Prozessbeschreibungssprache begrenzt und wurde prototypisch implementiert. Die Automatisierung der Datenbehandlung in Gesch{\"a}ftsprozessen erfordert entsprechend annotierte und korrekte Prozessmodelle. Als Unterst{\"u}tzung zur Datenannotierung f{\"u}hrt diese Arbeit einen Algorithmus ein, welcher Informationen {\"u}ber Datenknoten, deren Zust{\"a}nde und Datenabh{\"a}ngigkeiten aus Kontrollflussinformationen extrahiert und die Prozessmodelle entsprechend annotiert. Allerdings k{\"o}nnen gew{\"o}hnlich nicht alle erforderlichen Informationen aus Kontrollflussinformationen extrahiert werden, da detaillierte Angaben {\"u}ber m{\"o}gliche Datenmanipulationen fehlen. Deshalb sind weitere Prozessmodellverfeinerungen notwendig. Basierend auf einer Menge von Objektlebenszyklen kann ein Prozessmodell derart verfeinert werden, dass die in den Objektlebenszyklen spezifizierten Datenmanipulationen automatisiert in ein Prozessmodell {\"u}berf{\"u}hrt werden k{\"o}nnen. Prozessmodelle stellen eine Abstraktion dar. Somit fokussieren sie auf verschiedene Teilbereiche und stellen diese im Detail dar. Solche Detailbereiche sind beispielsweise die Kontrollflusssicht und die Datenflusssicht, welche oft durch Aktivit{\"a}ts-zentrierte beziehungsweise Objekt-zentrierte Prozessmodelle abgebildet werden. In der vorliegenden Arbeit werden Algorithmen zur Transformation zwischen diesen Sichten beschrieben. Zur Sicherstellung der Modellkorrektheit wird das Konzept der „weak conformance" zur {\"U}berpr{\"u}fung der Konsistenz zwischen Objektlebenszyklen und dem Prozessmodell eingef{\"u}hrt. Dabei darf das Prozessmodell nur Datenmanipulationen enthalten, die auch in einem Objektlebenszyklus spezifiziert sind. Die Korrektheit wird mittels Soundness-{\"U}berpr{\"u}fung einer hybriden Darstellung ermittelt, so dass Kontrollfluss- und Datenkorrektheit integriert {\"u}berpr{\"u}ft werden. Um eine korrekte Ausf{\"u}hrung des Prozessmodells zu gew{\"a}hrleisten, m{\"u}ssen gefundene Inkonsistenzen korrigiert werden. Daf{\"u}r werden f{\"u}r jede Inkonsistenz alternative Vorschl{\"a}ge zur Modelladaption identifiziert und vorgeschlagen. Zusammengefasst, unter Einsatz der Ergebnisse dieser Dissertation k{\"o}nnen Gesch{\"a}ftsprozesse modellgetrieben ausgef{\"u}hrt werden unter Ber{\"u}cksichtigung sowohl von Daten als auch den zuvor bereits unterst{\"u}tzten Perspektiven bez{\"u}glich Kontrollfluss und Verantwortlichkeiten. Dabei wird die Modellerstellung teilweise mit automatisierten Algorithmen unterst{\"u}tzt und die Modellkonsistenz durch Datenkorrektheits{\"u}berpr{\"u}fungen gew{\"a}hrleistet.}, language = {en} } @phdthesis{Reibis2015, author = {Reibis, Robert Alexander}, title = {Regionale Versorgungsaspekte des aktuten Myokardinfarktes im Nordosten Deutschlands}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-85713}, school = {Universit{\"a}t Potsdam}, pages = {VI, 92}, year = {2015}, abstract = {Hintergrund: In Deutschland stellt der akute Myokardinfarkt (MI) eine der h{\"a}ufigsten Todesursachen dar. Als Ursache f{\"u}r regionale Unterschiede bei den Mortalit{\"a}tsraten werden divergente Versorgungsstrukturen vermutet. Ziel der Untersuchung war, diese Fragestellung anhand anonymisierter krankenkassenbasierter Abrechnungsdaten zu evaluieren. Methodik: Standardisierte Hospitalisierungs- sowie Krankenhaus- und Ein-Jahres-Mortalit{\"a}tsraten nach MI wurden anhand anonymisierter Versichertendaten einer gesetzlichen Krankenkasse f{\"u}r das Jahr 2012 und die Bundesl{\"a}nder Berlin, Brandenburg und Mecklenburg-Vorpommern ermittelt (n=1.387.084, 46.3\% male, 60.9 ± 18,2 years). Weiterhin wurden pr{\"a}diktive Einflussfaktoren auf die Ein-Jahres-Mortalit{\"a}t, auf die Durchf{\"u}hrung invasiver Prozeduren und auf eine leitliniengerechte pharmakotherapeutische Sekund{\"a}rpr{\"a}vention analysiert. Ergebnisse: 6.733 Patienten (73,7 ±13,0 Jahre, 56,7\% m{\"a}nnlich) wurden identifiziert. Obwohl f{\"u}r das Bundesland Berlin eine h{\"o}here Hospitalisierungsrate als in Mecklenburg-Vorpommern ermittelt werden konnte, ließen sich bei der Krankenhaus- und 1-Jahres-Mortalit{\"a}t keine signifikant abweichenden Raten zwischen den Bundesl{\"a}ndern beobachten. Die Durchf{\"u}hrung einer Koronarangiographie (OR: 0,42 [0,35-0,51]) und eine leitliniengerechte Pharmakotherapie (OR: 0,14 [0,12-0,17] waren mit einer geringeren 1-Jahres-Mortalit{\"a}t assoziiert. Die Durchf{\"u}hrung einer Koronarangiographie und eine leitliniengerechte Pharmakotherapie von Patienten nach Myokardinfarkt wurde hingegen prim{\"a}r durch Alter und Geschlecht, nicht aber durch das Bundesland determiniert. Folgerung: Eine regional divergierende station{\"a}re und postinfarzielle Versorgung auf Bundesland-Ebene kann anhand der vorliegenden Daten nicht nachgewiesen werden.}, language = {de} } @phdthesis{Hunke2015, author = {Hunke, Philip Paul}, title = {The Brazilian Cerrado: ecohydrological assessment of water and soil degradation in heavily modified meso-scale catchments}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-85110}, school = {Universit{\"a}t Potsdam}, pages = {xi, 124}, year = {2015}, abstract = {The Brazilian Cerrado is recognised as one of the most threatened biomes in the world, as the region has experienced a striking change from natural vegetation to intense cash crop production. The impacts of rapid agricultural expansion on soil and water resources are still poorly understood in the region. Therefore, the overall aim of the thesis is to improve our understanding of the ecohydrological processes causing water and soil degradation in the Brazilian Cerrado. I first present a metaanalysis to provide quantitative evidence and identifying the main impacts of soil and water alterations resulting from land use change. Second, field studies were conducted to (i) examine the effects of land use change on soils of natural cerrado transformed to common croplands and pasture and (ii) indicate how agricultural production affects water quality across a meso-scale catchment. Third, the ecohydrological process-based model SWAT was tested with simple scenario analyses to gain insight into the impacts of land use and climate change on the water cycling in the upper S{\~a}o Louren{\c{c}}o catchment which experienced decreasing discharges in the last 40 years. Soil and water quality parameters from different land uses were extracted from 89 soil and 18 water studies in different regions across the Cerrado. Significant effects on pH, bulk density and available P and K for croplands and less-pronounced effects on pastures were evident. Soil total N did not differ between land uses because most of the cropland sites were N-fixing soybean cultivations, which are not artificially fertilized with N. By contrast, water quality studies showed N enrichment in agricultural catchments, indicating fertilizer impacts and potential susceptibility to eutrophication. Regardless of the land use, P is widely absent because of the high-fixing capacities of deeply weathered soils and the filtering capacity of riparian vegetation. Pesticides, however, were consistently detected throughout the entire aquatic system. In several case studies, extremely high-peak concentrations exceeded Brazilian and EU water quality limits, which pose serious health risks. My field study revealed that land conversion caused a significant reduction in infiltration rates near the soil surface of pasture (-96 \%) and croplands (-90 \% to -93 \%). Soil aggregate stability was significantly reduced in croplands than in cerrado and pasture. Soybean crops had extremely high extractable P (80 mg kg-1), whereas pasture N levels declined. A snapshot water sampling showed strong seasonality in water quality parameters. Higher temperature, oxi-reduction potential (ORP), NO2-, and very low oxygen concentrations (<5 mg•l-1) and saturation (<60 \%) were recorded during the rainy season. By contrast, remarkably high PO43- concentrations (up to 0.8 mg•l-1) were measured during the dry season. Water quality parameters were affected by agricultural activities at all sampled sub-catchments across the catchment, regardless of stream characteristic. Direct NO3- leaching appeared to play a minor role; however, water quality is affected by topsoil fertiliser inputs with impact on small low order streams and larger rivers. Land conversion leaving cropland soils more susceptible to surface erosion by increased overland flow events. In a third study, the field data were used to parameterise SWAT. The model was tested with different input data and calibrated in SWAT-CUP using the SUFI-2 algorithm. The model was judged reliable to simulate the water balance in the Cerrado. A complete cerrado, pasture and cropland cover was used to analyse the impact of land use on water cycling as well as climate change projections (2039-2058) according to the projections of the RCP 8.5 scenario. The actual evapotranspiration (ET) for the cropland scenario was higher compared to the cerrado cover (+100 mm a-1). Land use change scenarios confirmed that deforestation caused higher annual ET rates explaining partly the trend of decreased streamflow. Taking all climate change scenarios into account, the most likely effect is a prolongation of the dry season (by about one month), with higher peak flows in the rainy season. Consequently, potential threats for crop production with lower soil moisture and increased erosion and sediment transport during the rainy season are likely and should be considered in adaption plans. From the three studies of the thesis I conclude that land use intensification is likely to seriously limit the Cerrado's future regarding both agricultural productivity and ecosystem stability. Because only limited data are available for the vast biome, we recommend further field studies to understand the interaction between terrestrial and aquatic systems. This thesis may serve as a valuable database for integrated modelling to investigate the impact of land use and climate change on soil and water resources and to test and develop mitigation measures for the Cerrado in the future.}, language = {en} } @phdthesis{Kieling2015, author = {Kieling, Katrin}, title = {Quantification of ground motions by broadband simulations}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-85989}, school = {Universit{\"a}t Potsdam}, pages = {XIV, 118}, year = {2015}, abstract = {In many procedures of seismic risk mitigation, ground motion simulations are needed to test systems or improve their effectiveness. For example they may be used to estimate the level of ground shaking caused by future earthquakes. Good physical models for ground motion simulation are also thought to be important for hazard assessment, as they could close gaps in the existing datasets. Since the observed ground motion in nature shows a certain variability, part of which cannot be explained by macroscopic parameters such as magnitude or position of an earthquake, it would be desirable that a good physical model is not only able to produce one single seismogram, but also to reveal this natural variability. In this thesis, I develop a method to model realistic ground motions in a way that is computationally simple to handle, permitting multiple scenario simulations. I focus on two aspects of ground motion modelling. First, I use deterministic wave propagation for the whole frequency range - from static deformation to approximately 10 Hz - but account for source variability by implementing self-similar slip distributions and rough fault interfaces. Second, I scale the source spectrum so that the modelled waveforms represent the correct radiated seismic energy. With this scaling I verify whether the energy magnitude is suitable as an explanatory variable, which characterises the amount of energy radiated at high frequencies - the advantage of the energy magnitude being that it can be deduced from observations, even in real-time. Applications of the developed method for the 2008 Wenchuan (China) earthquake, the 2003 Tokachi-Oki (Japan) earthquake and the 1994 Northridge (California, USA) earthquake show that the fine source discretisations combined with the small scale source variability ensure that high frequencies are satisfactorily introduced, justifying the deterministic wave propagation approach even at high frequencies. I demonstrate that the energy magnitude can be used to calibrate the high-frequency content in ground motion simulations. Because deterministic wave propagation is applied to the whole frequency range, the simulation method permits the quantification of the variability in ground motion due to parametric uncertainties in the source description. A large number of scenario simulations for an M=6 earthquake show that the roughness of the source as well as the distribution of fault dislocations have a minor effect on the simulated variability by diminishing directivity effects, while hypocenter location and rupture velocity more strongly influence the variability. The uncertainty in energy magnitude, however, leads to the largest differences of ground motion amplitude between different events, resulting in a variability which is larger than the one observed. For the presented approach, this dissertation shows (i) the verification of the computational correctness of the code, (ii) the ability to reproduce observed ground motions and (iii) the validation of the simulated ground motion variability. Those three steps are essential to evaluate the suitability of the method for means of seismic risk mitigation.}, language = {en} } @phdthesis{Friedmann2015, author = {Friedmann, Ronald}, title = {Arthur Ewert (1890-1959)}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-73024}, school = {Universit{\"a}t Potsdam}, pages = {485}, year = {2015}, abstract = {Arthur Ewert (1890-1959) war in den zwanziger und fr{\"u}hen dreißiger Jahren ein wichtiger Funktion{\"a}r der Kommunistischen Partei Deutschlands und der Kommunistischen Internationale. Er wurde in der Familie eines armen Bauern in Ostpreußen geboren. Nach dem Abschluß der Schule ging er nach Berlin, um hier eine Lehre als Sattler zu absolvieren. {\"U}ber die Berliner Arbeiterjugendbewegung fand er Kontakt zur Sozialdemokratischen Partei Deutschlands, deren Mitglied er 1908 wurde. Im Mai 1914 emigrierte er gemeinsam mit seiner langj{\"a}hrigen Lebensgef{\"a}hrtin und sp{\"a}teren Ehefrau Elise Saborowski (1886-1939) nach Nordamerika, wo er sich sofort der sozialistischen Bewegung anschloß. Anfang 1919 geh{\"o}rte er zu den Mitbegr{\"u}ndern der ersten Kommunistischen Partei Kanadas. Im Sommer 1919 kehrte er nach Deutschland zur{\"u}ck und wurde Mitglied der wenige Monate zuvor gegr{\"u}ndeten KPD. Auf dem Leipziger Parteitag der KPD im Februar 1923 wurde er in die zwanzigk{\"o}pfige Zentrale seiner Partei gew{\"a}hlt und stieg damit in den engeren F{\"u}hrungszirkel auf. Nach der gescheiterten »Deutschen Oktoberrevolution« im Herbst 1923 k{\"a}mpfte er gemeinsam mit Ernst Meyer, Hugo Eberlein, Wilhelm Pieck und anderen um das {\"U}berleben der KPD, doch gelang es seiner Gruppe nicht, den Sieg der Linken und Ultralinken im parteiinternen Machtkampf zu verhindern. Ewert wurde politisch »kaltgestellt« und schied f{\"u}r mehr als ein Jahr aus der Parteif{\"u}hrung aus. In dieser Zeit erf{\"u}llte er verschiedene Aufgaben f{\"u}r die Kommunistische Internationale. Bereits im Juni 1923 war er Berichterstatter zur Lage in der Norwegischen Arbeiterpartei gewesen, ab Ende 1924 war er Abgesandter bei der KP Großbritanniens. Im Sommer und Fr{\"u}hherbst 1927 hielt er sich mehrere Monate in den USA auf. Im Sommer 1925 wurde er auf Veranlassung der Kommunistischen Internationale in die F{\"u}hrung der KPD zur{\"u}ckgeholt. Er trug wesentlich dazu bei, die Parteif{\"u}hrung unter Ernst Th{\"a}lmann zu stabilisieren und sie - zumindest zeitweise - auf einen realpolitischen Kurs zu orientieren. Mit dem erneuten »Links«-Schwenk der KPD ab Anfang 1928 wurde er als »Vers{\"o}hnler« stigmatisiert und zunehmend zur Zielscheibe innerparteilicher Attacken. Der Versuch eines »Befreiungsschlages« unter Ausnutzung der sogenannten Wittorf-Aff{\"a}re im Herbst 1928 scheiterte, bis zum Sommer 1929 wurde Arthur Ewert auf Dr{\"a}ngen Stalins und mit ausdr{\"u}cklicher Zustimmung Th{\"a}lmanns aus allen Funktionen in der KPD entfernt. Nach der Aufl{\"o}sung des Reichstags und dem damit verbundenen Verlust seines Reichstagsmandats im Juli 1930 schied Ewert endg{\"u}ltig aus der deutschen Parteiarbeit aus. Ende 1930 wurde er zum Leiter des S{\"u}damerikanischen B{\"u}ros der Kommunistischen Internationale in Montevideo, der Hauptstadt Uruguays, ernannt. Er trug damit Verantwortung f{\"u}r die unmittelbare Anleitung der Kommunistischen Parteien im sogenannten S{\"u}dkegel S{\"u}damerikas. In diese Zeit fielen seine ersten Kontakte zu Luiz Carlos Prestes, dem legend{\"a}ren »Ritter der Hoffnung«, mit dem er ab Anfang 1935 in Brasilien zusammenarbeitete. Von 1932 bis 1934 leitete Arthur Ewert das B{\"u}ro der Kommunistischen Internationale in Shanghai und spielte dabei eine entscheidende Rolle zugunsten Mao Tse-tungs, dessen politisches {\"U}berleben er in einem innerparteilichen Machtkampf der KP Chinas sicherte. Als Vertreter der Kommunistischen Internationale war Arthur Ewert im Verlaufe des Jahres 1935 an den Versuchen beteiligt, in Brasilien - gest{\"u}tzt auf ein breites B{\"u}ndnis, die »Nationale Befreiungsallianz« - einen politischen Machtwechsel herbeizuf{\"u}hren. Nach dem Scheitern des von Prestes gef{\"u}hrten Aufstandsversuches wurde er Ende 1935 verhaftet. Arthur Ewert verlor in Folge der barbarischen Folterungen in brasilianischer Haft den Verstand. Er kam im Mai 1945 im Ergebnis einer Amnestie frei. 1947 gelang es seiner Schwester, ihn in die sowjetische Besatzungszone zur{\"u}ckzuholen. Die {\"A}rzte dort konnten nur noch feststellen, daß eine Heilung unm{\"o}glich war. Arthur Ewert verbrachte den Rest seines Lebens in einem Pflegeheim in Eberswalde, wo er 1959 starb.}, language = {de} } @phdthesis{Jantz2015, author = {Jantz, Bastian}, title = {The dynamics of accountability in public sector reforms}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-78131}, school = {Universit{\"a}t Potsdam}, pages = {182}, year = {2015}, abstract = {This PhD thesis is essentially a collection of six sequential articles on dynamics of accountability in the reformed employment and welfare administration in different countries. The first article examines how recent changes in the governance of employment services in three European countries (Denmark, Germany and Norway) have influenced accountability relationships from a very wide-ranging perspective. It starts from the overall assumption in the literature that accountability relationships are becoming more numerous and complex, and that these changes may lead to multiple accountability disorder. The article explores these assumptions by analyzing the different actors involved and the information requested in the new governance arrangements in all three countries. It concludes that the considerable changes in organizational arrangements and more managerial information demanded and provided have led to more shared forms of accountability. Nevertheless, a clear development towards less political or administrative accountability could not be observed. The second article analyzes how the structure and development of reform processes affect accountability relationships and via what mechanisms. It is distinguished between an instrumental perspective and an institutional perspective and each of these perspectives takes a different view on the link between reforms and concrete action and results. By taking the welfare reforms in Norway and Germany as an example, it is shown that the reform outcomes in both countries are the result of a complex process of powering, puzzling and institutional constraints where different situational interpretations of problems, interests and administrative legacies had to be balanced. Accountability thus results not from a single process of environmental necessity or strategic choice, but from a dynamic interplay between different actors and institutional spheres. The third article then covers a specific instrument of public sector reforms, i.e. the increasing use of performance management. The article discusses the challenges and ambiguities between performance management and different forms of accountability based on the cases of the reformed welfare administration in Norway and Germany. The findings are that the introduction of performance management creates new accountability structures which influence service delivery, but not necessarily in the direction expected by reform agents. Observed unintended consequences include target fixation, the displacement of political accountability and the predominance of control aspects of accountability. The fourth article analyzes the accountability implications of the increasingly marketized models of welfare governance. It has often been argued that relocating powers and discretion to private contractors involve a trade-off between democratic accountability and efficiency. However, there is limited empirical evidence of how contracting out shapes accountability or is shaped by alternative democratic or administrative forms of accountability. Along these lines the article examines employment service accountability in the era of contracting out in Germany, Denmark and Great Britain. It is found that market accountability instruments are complementary instruments, not substitutes. The findings highlight the importance of administrative and political instruments in legitimizing marketized service provision and shed light on the processes that lead to the development of a hybrid accountability model. The fifth and sixth articles focus on the diagonal accountability relationships between public agencies, supreme audit institutions (SAI) and parental ministry or parliament. The fifth article examines the evolving role of SAIs in Denmark, Germany and Norway focusing particularly on their contribution to public accountability and their ambivalent relationship with some aspects of public sector reform in the welfare sector. The article analyzes how SAIs assess New Public Management inspired reforms in the welfare sector in the three countries. The analysis shows that all three SAIs have taken on an evaluative role when judging New Public Management instruments. At the same time their emphasis on legality and compliance can be at odds with some of the operating principles introduced by New Public Management reforms. The sixth article focuses on the auditing activities of the German SAI in the field of labor market administration as a single in-depth case study. The purpose is to analyze how SAIs gain impact in diagonal accountability settings. The results show that the direct relationship between auditor and auditee based on cooperation and trust is of outstanding importance for SAIs to give effect to their recommendations. However, if an SAI has to rely on actors of diagonal accountability, it is in a vulnerable position as it might lose control over the interpretation of its results.}, language = {en} } @phdthesis{Grubic2015, author = {Grubic, Mira}, title = {Focus and alternative sensitivity in Ngamo (West-Chadic)}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-81666}, school = {Universit{\"a}t Potsdam}, year = {2015}, abstract = {The main research question of this thesis concerns the relation between focus interpretation, focus realization, and association with focus in the West Chadic language Ngamo. Concerning the relation between focus realization and interpretation, this thesis contributes to the question, cross-linguistically, what factors influence a marked realization of the focus/background distinction. There is background-marking rather than focus-marking in Ngamo, and the background marker is related to the definite determiner in the language. Using original fieldwork data as a basis, a formal semantic analysis of the background marker as a definite determiner of situations is proposed. Concerning the relation between focus and association with focus, the thesis adds to the growing body of crosslinguistic evidence that not all so-called focus-sensitive operators always associate with focus. The thesis shows that while the exclusive particle yak('i) (= "only") in Ngamo conventionally associates with focus, the particles har('i) (= "even, as far as, until, already"), and ke('e) (= "also, and") do not. The thesis provides an analysis of these phenomena in a situation semantic framework.}, language = {en} } @phdthesis{EidSabbagh2015, author = {Eid-Sabbagh, Rami-Habib}, title = {Business process architectures}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-79719}, school = {Universit{\"a}t Potsdam}, pages = {xvii, 256}, year = {2015}, abstract = {Business Process Management has become an integral part of modern organizations in the private and public sector for improving their operations. In the course of Business Process Management efforts, companies and organizations assemble large process model repositories with many hundreds and thousands of business process models bearing a large amount of information. With the advent of large business process model collections, new challenges arise as structuring and managing a large amount of process models, their maintenance, and their quality assurance. This is covered by business process architectures that have been introduced for organizing and structuring business process model collections. A variety of business process architecture approaches have been proposed that align business processes along aspects of interest, e. g., goals, functions, or objects. They provide a high level categorization of single processes ignoring their interdependencies, thus hiding valuable information. The production of goods or the delivery of services are often realized by a complex system of interdependent business processes. Hence, taking a holistic view at business processes interdependencies becomes a major necessity to organize, analyze, and assess the impact of their re-/design. Visualizing business processes interdependencies reveals hidden and implicit information from a process model collection. In this thesis, we present a novel Business Process Architecture approach for representing and analyzing business process interdependencies on an abstract level. We propose a formal definition of our Business Process Architecture approach, design correctness criteria, and develop analysis techniques for assessing their quality. We describe a methodology for applying our Business Process Architecture approach top-down and bottom-up. This includes techniques for Business Process Architecture extraction from, and decomposition to process models while considering consistency issues between business process architecture and process model level. Using our extraction algorithm, we present a novel technique to identify and visualize data interdependencies in Business Process Data Architectures. Our Business Process Architecture approach provides business process experts,managers, and other users of a process model collection with an overview that allows reasoning about a large set of process models, understanding, and analyzing their interdependencies in a facilitated way. In this regard we evaluated our Business Process Architecture approach in an experiment and provide implementations of selected techniques.}, language = {en} } @phdthesis{Koehler2015, author = {K{\"o}hler, Anke}, title = {Theoriebasierte Betreuung des Schulpraktikums im Lehramtsstudium Englisch}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-91531}, school = {Universit{\"a}t Potsdam}, year = {2015}, abstract = {Der Beitrag der Dissertation „Theoriebasierte Betreuung vom Schulpraktikum im Lehramtsstudium Englisch" zum wissenschaftlichen Diskurs liegt in der Verbindung von Theoriebereichen der Professionalisierungsforschung und angewandten Linguistik mit Untersuchungen zur hochschuldidaktischen Begleitung und Betreuung im ersten Unterrichtspraktikum des Lehramtsstudiums, dem fachdidaktischen Tagespraktikum, an der Universit{\"a}t Potsdam. Ein interaktionsanalytisches Vorgehen wurde eingesetzt zur Weiterentwicklung des hochschuldidaktischen Settings einer disziplinenverbindenden, fachwissenschaftlichen Begleitung von Praktika im komplexen Kontext Schule. Die Implementierung entsprechender Formate ins regul{\"a}re Studium wurde in einer {\"u}ber drei Jahre angelegten iterativen Studie turnusm{\"a}ßig evaluiert.}, language = {de} } @phdthesis{Lohr2015, author = {Lohr, Frauke}, title = {Konzeption und Evaluation eines F{\"o}rderprogramms zur Entwicklung der schriftlichen Erz{\"a}hlf{\"a}higkeit von F{\"u}nftkl{\"a}sslern}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-395413}, school = {Universit{\"a}t Potsdam}, pages = {271}, year = {2015}, abstract = {Gut ausgebildete Schreibkompetenzen gelten als zentrale Voraussetzung f{\"u}r den schulischen Erfolg. Wenngleich die schriftliche Textproduktion unbestritten fester Bestandteil des Deutschunterrichts ist, wird vielfach beklagt, dass die vorhandenen Schreibkompetenzen unzureichend sind. Blickt man auf die fachdidaktische Forschung so zeigt sich, dass Schreibkompetenz ein schwer zu definierendes Ph{\"a}nomen bleibt und innerhalb der schreibdidaktischen Forschung strittig ist, wie Schreibkompetenz - insbesondere nach Erwerb der grundlegenden Schreibfertigkeiten - am Besten entwickelt werden kann. Zudem gilt f{\"u}r das Fach Deutsch, insbesondere den Aufgabenbereich „Texte verfassen", das eine empirische Fundierung der Fachdidaktik bisher kaum realisiert wurde. Vor diesem Hintergrund wurde in der vorgelegten Arbeit ein Programm zu F{\"o}rderung der schriftlichen Erz{\"a}hlf{\"a}higkeit von F{\"u}nftkl{\"a}sslern entwickelt und anschließend in der regul{\"a}ren Unterrichtspraxis eingesetzt und begleitend evaluiert. Methodisch orientiert sich die Arbeit dabei im Hinblick auf die Konzeption, Umsetzung und Evaluation des F{\"o}rderprogramms an den von Einsiedler postulierten „Standards der (didaktischen) Entwicklungsforschung". Bei der im ersten Schritt erfolgten Konzeption des F{\"o}rderprogramms ging es darum eine spezifische, didaktische Konzeption, die Kombination sprachstruktur- und (lern)prozessbezogenener Elemente, sprachwissenschaftlich basiert und p{\"a}dagogisch-didaktisch begr{\"u}ndet zu entwickeln. Bei der hierzu notwendigen Integration verschiedener theoretischer Zug{\"a}nge unterschiedlicher Fachdisziplinen galt es vorhandene Ans{\"a}tze im Hinblick auf interne Anschlussm{\"o}glichkeiten auszuloten und auf diesem Wege einen sich gegenseitig erg{\"a}nzenden, umfassenden Bezugsrahmen zu schaffen. Dabei gelang - unter Einbeziehung von Modellen und Befunden aus der Schreibentwicklungsforschung - die innerhalb der Schreibforschung vielfach geforderte, jedoch bisher fehlende Integration von strukturellen Ans{\"a}tzen aus der linguistischen Schreibforschung mit den innerhalb der Kognitionspsychologie favorisierten prozessuellen Ans{\"a}tzen. Auf dieser Grundlage wurde ein aufgabenbasiertes Programm mit insgesamt acht verschiedenen F{\"o}rdermodulen entwickelt, aufgabenbasiert deshalb, weil dies nicht nur einen lehrergesteuerten aber sch{\"u}lerzentrierten Unterricht erm{\"o}glicht, sondern auch einen adaptiven Unterricht, somit den spezifischen Anforderungen des Unterrichts in heterogenen Lerngruppen gerecht wird, was angesichts der zunehmenden (sprachlich-kulturellen) Heterogenit{\"a}t in regul{\"a}ren Schulklassen sinnvoll scheint. In einem zweiten Schritt wurde innerhalb einer Pilotstudie die Umsetzbarkeit des F{\"o}rderprogramms im schulischen Kontext erprobt. Unter Kontrolle seiner praktischen Umsetzbarkeit (Machbarkeitshypothese) wurde im Anschluss daran die Wirksamkeit des F{\"o}rderprogramms im Hinblick auf eine Steigerung in den produktbezogenen Schreibmaßen (Wortschatzvarianz, Satzkomplexit{\"a}t, lexikalische Dichte, Koh{\"a}sionsgrade, Textl{\"a}nge) und die Stabilit{\"a}t der F{\"o}rdereffekte untersucht. Dies geschah mittels eines quasiexperimentellen Untersuchungsplans, genauer eines Zweigruppen-Pretest-Posttest-Follow-up-Plans mit Kontrollvariablen. Grundlage hierf{\"u}r war eine m{\"o}glichst heterogene Stichprobe von knapp 200 Sch{\"u}ler/innen. Denn angesichts der angesprochenen zunehmenden Heterogenit{\"a}t in regul{\"a}ren Schulklassen galt es neben der Wirksamkeit und Nachhaltigkeit des F{\"o}rderprogramms auch dessen Eignung f{\"u}r den Unterricht in heterogenen Lerngruppen zu pr{\"u}fen. Die Ergebnisse dieser Pr{\"u}fung sprechen daf{\"u}r, dass es gelungen ist ein entsprechendes F{\"o}rderprogramm zu entwickeln. Trotz dem Auftreten von forschungsmethodischen Schwierigkeiten, die innerhalb der vorgelegten Arbeit ausf{\"u}hrlich im Hinblick auf Ursachen und Wirkungen diskutiert werden, k{\"o}nnen, unter Ber{\"u}cksichtigung des explorativen Charakters der Studie, die Ergebnisse insbesondere zur Wortschatzvarianz und zur Satzkomplexit{\"a}t ebenfalls als Indizien f{\"u}r die Effektivit{\"a}t des F{\"o}rderprogramms gelten.}, language = {de} } @phdthesis{Olszewska2015, author = {Olszewska, Agata}, title = {Forming magnetic chain with the help of biological organisms}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-89767}, school = {Universit{\"a}t Potsdam}, pages = {101}, year = {2015}, abstract = {Magnetite nanoparticles and their assembly comprise a new area of development for new technologies. The magnetic particles can interact and assemble in chains or networks. Magnetotactic bacteria are one of the most interesting microorganisms, in which the assembly of nanoparticles occurs. These microorganisms are a heterogeneous group of gram negative prokaryotes, which all show the production of special magnetic organelles called magnetosomes, consisting of a magnetic nanoparticle, either magnetite (Fe3O4) or greigite (Fe3S4), embedded in a membrane. The chain is assembled along an actin-like scaffold made of MamK protein, which makes the magnetosomes to arrange in mechanically stable chains. The chains work as a compass needle in order to allow cells to orient and swim along the magnetic field of the Earth. The formation of magnetosomes is known to be controlled at the molecular level. The physico-chemical conditions of the surrounding environment also influence biomineralization. The work presented in this manuscript aims to understand how such external conditions, in particular the extracellular oxidation reduction potential (ORP) influence magnetite formation in the strain Magnetospirillum magneticum AMB-1. A controlled cultivation of the microorganism was developed in a bioreactor and the formation of magnetosomes was characterized. Different techniques have been applied in order to characterize the amount of iron taken up by the bacteria and in consequence the size of magnetosomes produced at different ORP conditions. By comparison of iron uptake, morphology of bacteria, size and amount of magnetosomes per cell at different ORP, the formation of magnetosomes was inhibited at ORP 0 mV, whereas reduced conditions, ORP - 500 mV facilitate biomineralization process. Self-assembly of magnetosomes occurring in magnetotactic bacteria became an inspiration to learn from nature and to construct nanoparticles assemblies by using the bacteriophage M13 as a template. The M13 bacteriophage is an 800 nm long filament with encapsulated single-stranded DNA that has been recently used as a scaffold for nanoparticle assembly. I constructed two types of assemblies based on bacteriophages and magnetic nanoparticles. A chain - like assembly was first formed where magnetite nanoparticles are attached along the phage filament. A sperm - like construct was also built with a magnetic head and a tail formed by phage filament. The controlled assembly of magnetite nanoparticles on the phage template was possible due to two different mechanism of nanoparticle assembly. The first one was based on the electrostatic interactions between positively charged polyethylenimine coated magnetite nanoparticles and negatively charged phages. The second phage -nanoparticle assembly was achieved by bioengineered recognition sites. A mCherry protein is displayed on the phage and is was used as a linker to a red binding nanobody (RBP) that is fused to the one of the proteins surrounding the magnetite crystal of a magnetosome. Both assemblies were actuated in water by an external magnetic field showing their swimming behavior and potentially enabling further usage of such structures for medical applications. The speed of the phage - nanoparticles assemblies are relatively slow when compared to those of microswimmers previously published. However, only the largest phage-magnetite assemblies could be imaged and it is therefore still unclear how fast these structures can be in their smaller version.}, language = {en} } @phdthesis{Buss2015, author = {Buß, Claudia}, title = {Instrumente der B{\"u}rgerbeteiligung in St{\"a}dten}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-88888}, school = {Universit{\"a}t Potsdam}, pages = {xi, 468}, year = {2015}, abstract = {Die vergleichende Arbeit besch{\"a}ftigt sich mit der B{\"u}rgerbeteiligung in St{\"a}dten in Deutschland und Frankreich. In den letzten 20 Jahren haben sich die Formen lokaler Demokratie immer wieder ver{\"a}ndert und sich den {\"o}rtlichen Gegebenheiten angepasst. Das Interesse der B{\"u}rger, Verwaltung und politisch gew{\"a}hlten Vertreter an Partizipation w{\"a}chst stetig . Das heißt aber auch, dass sich diese 3 Akteure den neuen Strukturen anpassen und eigene Strategien entwickeln m{\"u}ssen. Die demokratischen Formen der kooperativen bzw. partizipativen Demokratie werden immer h{\"a}ufiger angewandt. Diese Arbeit evaluiert die verschiedenen B{\"u}rgerbeteiligungsinstrumente in Frankreich und Deutschland in dem zwischen Input, Output und Outcome unterschieden wird. Insbesondere die B{\"u}rgerhaushalte, Beir{\"a}te und Quartiersr{\"a}te werden genauer betrachtet. Die Ergebnisse zeigen erste Hinweise in welche demokratische Richtung sich die deutschen St{\"a}dte k{\"u}nftig entwickeln.}, language = {de} } @phdthesis{Ayguel2015, author = {Ayg{\"u}l, Mesut}, title = {Pre-collisional accretion and exhumation along the southern Laurasian active margin, Central Pontides, Turkey}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-416769}, school = {Universit{\"a}t Potsdam}, pages = {xxxiv, 206}, year = {2015}, abstract = {The Central Pontides is an accretionary-type orogenic area within the Alpine-Himalayan orogenic belt characterized by pre-collisional tectonic continental growth. The region comprises Mesozoic subduction-accretionary complexes and an accreted intra-oceanic arc that are sandwiched between the Laurasian active continental margin and Gondwana-derived the K{\i}r{\c{s}}ehir Block. The subduction-accretion complexes mainly consist of an Albian-Turonian accretionary wedge representing the Laurasian active continental margin. To the north, the wedge consists of slate/phyllite and metasandstone intercalation with recrystallized limestone, Na-amphibole-bearing metabasite (PT= 7-12 kbar and 400 ± 70 ºC) and tectonic slices of serpentinite representing accreted distal part of a large Lower Cretaceous submarine turbidite fan deposited on the Laurasian active continental margin that was subsequently accreted and metamorphosed. Raman spectra of carbonaceous material (RSCM) of the metapelitic rocks revealed that the metaflysch sequence consists of metamorphic packets with distinct peak metamorphic temperatures. The majority of the metapelites are low-temperature (ca. 330 °C) slates characterized by lack of differentiation of the graphite (G) and D2 defect bands. They possibly represent offscraped distal turbidites along the toe of the Albian accretionary wedge. The rest are phyllites that are characterized by slightly pronounced G band with D2 defect band occurring on its shoulder. Peak metamorphic temperatures of these phyllites are constrained to 370-385 °C. The phyllites are associated with a strip of incipient blueschist facies metabasites which are found as slivers within the offscraped distal turbidites. They possibly represent underplated continental metasediments together with oceanic crustal basalt along the basal d{\´e}collement. Tectonic emplacement of the underplated rocks into the offscraped distal turbidites was possibly achieved by out-of-sequence thrusting causing tectonic thickening and uplift of the wedge. 40Ar/39Ar phengite ages from the phyllites are ca. 100 Ma, indicating Albian subduction and regional HP metamorphism. The accreted continental metasediments are underlain by HP/LT metamorphic rocks of oceanic origin along an extensional shear zone. The oceanic metamorphic sequence mainly comprises tectonically thickened deep-seated eclogite to blueschist facies metabasites and micaschists. In the studied area, metabasites are epidote-blueschists locally with garnet (PT= 17 ± 1 kbar and 500 ± 40 °C). Lawsonite-blueschists are exposed as blocks along the extensional shear zone (PT= 14 ± 2 kbar and 370-440 °C). They are possibly associated with low shear stress regime of the initial stage of convergence. Close to the shear zone, the footwall micaschists consist of quartz, phengite, paragonite, chlorite, rutile with syn-kinematic albite porphyroblast formed by pervasive shearing during exhumation. These types of micaschists are tourmaline-bearing and their retrograde nature suggests high-fluid flux along shear zones. Peak metamorphic mineral assemblages are partly preserved in the chloritoid-micaschist farther away from the shear zone representing the zero strain domains during exhumation. Three peak metamorphic assemblages are identified and their PT conditions are constrained by pseudosections produced by Theriak-Domino and by Raman spectra of carbonaceous material: 1) garnet-chloritoid-glaucophane with lawsonite pseudomorphs (P= 17.5 ± 1 kbar, T: 390-450 °C) 2) chloritoid with glaucophane pseudomorphs (P= 16-18 kbar, T: 475 ± 40 °C) and 3) relatively high-Mg chloritoid (17\%) with jadeite pseudomorphs (P= 22-25 kbar; T: 440 ± 30 °C) in addition to phengite, paragonite, quartz, chlorite, rutile and apatite. The last mineral assemblage is interpreted as transformation of the chloritoid + glaucophane assemblage to chloritoid + jadeite paragenesis with increasing pressure. Absence of tourmaline suggests that the chloritoid-micaschist did not interact with B-rich fluids during zero strain exhumation. 40Ar/39Ar phengite age of a pervasively sheared footwall micaschist is constrained to 100.6 ± 1.3 Ma and that of a chloritoid-micaschist is constrained to 91.8 ± 1.8 Ma suggesting exhumation during on-going subduction with a southward younging of the basal accretion and the regional metamorphism. To the south, accretionary wedge consists of blueschist and greenschist facies metabasite, marble and volcanogenic metasediment intercalation. 40Ar/39Ar phengite dating reveals that this part of the wedge is of Middle Jurassic age partly overprinted during the Albian. Emplacement of the Middle Jurassic subduction-accretion complexes is possibly associated with obliquity of the Albian convergence. Peak metamorphic assemblages and PT estimates of the deep-seated oceanic metamorphic sequence suggest tectonic stacking within wedge with different depths of burial. Coupling and exhumation of the distinct metamorphic slices are controlled by decompression of the wedge possibly along a retreating slab. Structurally, decompression of the wedge is evident by an extensional shear zone and the footwall micaschists with syn-kinematic albite porphyroblasts. Post-kinematic garnets with increasing grossular content and pseudomorphing minerals within the chloritoid-micaschists also support decompression model without an extra heating. Thickening of subduction-accretionary complexes is attributed to i) significant amount of clastic sediment supply from the overriding continental domain and ii) deep level basal underplating by propagation of the d{\´e}collement along a retreating slab. Underplating by basal d{\´e}collement propagation and subsequent exhumation of the deep-seated subduction-accretion complexes are connected and controlled by slab rollback creating a necessary space for progressive basal accretion along the plate interface and extension of the wedge above for exhumation of the tectonically thickened metamorphic sequences. This might be the most common mechanism of the tectonic thickening and subsequent exhumation of deep-seated HP/LT subduction-accretion complexes. To the south, the Albian-Turonian accretionary wedge structurally overlies a low-grade volcanic arc sequence consisting of low-grade metavolcanic rocks and overlying metasedimentary succession is exposed north of the İzmir-Ankara-Erzincan suture (İAES), separating Laurasia from Gondwana-derived terranes. The metavolcanic rocks mainly consist of basaltic andesite/andesite and mafic cognate xenolith-bearing rhyolite with their pyroclastic equivalents, which are interbedded with recrystallized pelagic limestone and chert. The metavolcanic rocks are stratigraphically overlain by recrystallized micritic limestone with rare volcanogenic metaclastic rocks. Two groups can be identified based on trace and rare earth element characteristics. The first group consists of basaltic andesite/andesite (BA1) and rhyolite with abundant cognate gabbroic xenoliths. It is characterized by relative enrichment of LREE with respect to HREE. The rocks are enriched in fluid mobile LILE, and strongly depleted in Ti and P reflecting fractionation of Fe-Ti oxides and apatite, which are found in the mafic cognate xenoliths. Abundant cognate gabbroic xenoliths and identical trace and rare earth elements compositions suggest that rhyolites and basaltic andesites/andesites (BA1) are cogenetic and felsic rocks were derived from a common mafic parental magma by fractional crystallization and accumulation processes. The second group consists only of basaltic andesites (BA2) with flat REE pattern resembling island arc tholeiites. Although enriched in LILE, this group is not depleted in Ti or P. Geochemistry of the metavolcanic rocks indicates supra-subduction volcanism evidenced by depletion of HFSE and enrichment of LILE. The arc sequence is sandwiched between an Albian-Turonian subduction-accretionary complex representing the Laurasian active margin and an ophiolitic m{\´e}lange. Absence of continent derived detritus in the arc sequence and its tectonic setting in a wide Cretaceous accretionary complex suggest that the K{\"o}sdağ Arc was intra-oceanic. This is in accordance with basaltic andesites (BA2) with island arc tholeiite REE pattern. Zircons from two metarhyolite samples give Late Cretaceous (93.8 ± 1.9 and 94.4 ± 1.9 Ma) U/Pb ages. Low-grade regional metamorphism of the intra-oceanic arc sequence is constrained 69.9 ± 0.4 Ma by 40Ar/39Ar dating on metamorphic muscovite from a metarhyolite indicating that the arc sequence became part of a wide Tethyan Cretaceous accretionary complex by the latest Cretaceous. The youngest 40Ar/39Ar phengite age from the overlying subduction-accretion complexes is 92 Ma confirming southward younging of an accretionary-type orogenic belt. Hence, the arc sequence represents an intra-oceanic paleo-arc that formed above the sinking Tethyan slab and finally accreted to Laurasian active continental margin. Abrupt non-collisional termination of arc volcanism was possibly associated with southward migration of the arc volcanism similar to the Izu-Bonin-Mariana arc system. The intra-oceanic K{\"o}sdağ Arc is coeval with the obducted supra-subduction ophiolites in NW Turkey suggesting that it represents part of the presumed but missing incipient intra-oceanic arc associated with the generation of the regional supra-subduction ophiolites. Remnants of a Late Cretaceous intra-oceanic paleo-arc and supra-subduction ophiolites can be traced eastward within the Alp-Himalayan orogenic belt. This reveals that Late Cretaceous intra-oceanic subduction occurred as connected event above the sinking Tethyan slab. It resulted as arc accretion to Laurasian active margin and supra-subduction ophiolite obduction on Gondwana-derived terranes.}, language = {en} } @phdthesis{Partosch2015, author = {Partosch, Falko}, title = {Computergest{\"u}tzte Analysen in der Toxikologie}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-82334}, school = {Universit{\"a}t Potsdam}, pages = {XVII, 131, ix}, year = {2015}, abstract = {Im Rahmen der EU-weiten REACH-Verordnung haben Alternativmethoden zum Tierversuch in der Toxikologie an Bedeutung gewonnen. Die Alternativmethoden gliedern sich auf in In-vitro- und In-silico-Methoden. In dieser Dissertation wurden verschiedene Konzepte der In-silico-Toxikologie behandelt. Die bearbeiteten Themen reichen von quantitativen Strukturaktivit{\"a}tsbeziehungen (QSAR) {\"u}ber eine neue Herangehensweise an das g{\"a}ngige Konzept zur Festlegung von Grenzwerten bis hin zu computerbasierten Modellierungen zum Alkohol- und Bisphenol-A-Stoffwechsel. Das Kapitel {\"u}ber QSAR befasst sich im Wesentlichen mit der Erstellung und Analyse einer Datenbank mit 878 Substanzen, die sich aus Tierversuchsstudien aus dem Archiv des Bundesinstituts f{\"u}r Risikobewertung zusammensetzt. Das Design wurde dabei an eine bereits bestehende Datenbank angepasst, um so einen m{\"o}glichst großen Datenpool zu generieren. In der Analyse konnte u.a. gezeigt werden, dass Stoffe mit niedrigerem Molekulargewicht ein erh{\"o}htes Potential f{\"u}r toxikologische Sch{\"a}den aufwiesen als gr{\"o}ßere Molek{\"u}le. Mit Hilfe des sogenannten TTC-Konzepts k{\"o}nnen Grenzwerte f{\"u}r Stoffe geringer Exposition festgelegt werden, zu denen keine toxikologischen Daten zur Verf{\"u}gung stehen. In dieser Arbeit wurden f{\"u}r die Stoffe dreier Datenbanken entsprechende Grenzwerte festgelegt. Es erfolgte zun{\"a}chst eine g{\"a}ngige strukturbasierte Aufteilung der Substanzen in die Kategorien "nicht toxisch", "m{\"o}glicherweise toxisch" und "eindeutig toxisch". Substanzen, die aufgrund ihrer Struktur in eine der drei Klassen eingeordnet werden, erhalten den entsprechenden Grenzwert. Da in die dritte Klasse auch Stoffe eingeordnet werden, deren Toxizit{\"a}t nicht bestimmbar ist, ist sie sehr groß. Daher wurden in dieser Arbeit die ersten beiden Klassen zusammengelgt, um einen gr{\"o}ßeren Datenpool zu erm{\"o}glichen. Eine weitere Neuerung umfasst die Erstellung eines internen Grenzwerts. Diese Vorgehensweise hat den Vorteil, dass der Expositionsweg herausgerechnet wird und somit beispielsweise Studien mit oraler Verabreichung mit Studien dermaler Verabreichung verglichen werden k{\"o}nnen. Mittels physiologisch basiertem kinetischem Modelling ist es m{\"o}glich, Vorg{\"a}nge im menschlichen K{\"o}rper mit Hilfe spezieller Software nachzuvollziehen. Durch diese Vorgehensweise k{\"o}nnen Expositionen von Chemikalien simuliert werden. In einem Teil der Arbeit wurden Alkoholexpositionen von gestillten Neugeborenen simuliert, deren M{\"u}tter unmittelbar zuvor alkoholische Getr{\"a}nke konsumiert hatten. Mit dem Modell konnte gezeigt werden, dass die Expositionen des Kindes durchweg gering waren. Nach einem Glas Wein wurden Spitzenkonzentrationen im Blut von Neugeborenen von 0,0034 Promille ermittelt. Zum Vergleich wurde die Exposition durch ein f{\"u}r S{\"a}uglinge zugelassenes alkoholhaltiges pflanzliches Arzneimittel simuliert. Hier wurden Spitzenkonzentrationen von 0,0141 Promille erreicht. Daher scheinen Empfehlungen wie gelegentlicher Konsum ohne sch{\"a}digende Wirkung auf das Kind wissenschaftlich fundiert zu sein. Ein weiteres Kinetik-Modell befasste sich mit dem Stoffwechsel von Bisphenol A. Teils widerspr{\"u}chliche Daten zur Belastung mit BPA in der wissenschaftlichen Literatur f{\"u}hren wiederholt zu Anregungen, den Grenzwert der Chemikalie anzupassen. Die Funktionalit{\"a}t der am Metabolismus beteiligten Enzyme kann je nach Individuum unterschiedlich ausgepr{\"a}gt sein. Mittels Modellings konnte hier gezeigt werden, dass dies maßgeblich dazu f{\"u}hrt, dass sich berechnete Plasmaspiegel von Individuen bis zu 4,7-fach unterscheiden. Die Arbeit konnte somit einen Beitrag zur Nutzung und Weiterentwicklung von In-silico-Modellen f{\"u}r diverse toxikologische Fragestellungen leisten.}, language = {de} } @phdthesis{Priegnitz2015, author = {Priegnitz, Mike}, title = {Development of geophysical methods to characterize methane hydrate reservoirs on a laboratory scale}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-89321}, school = {Universit{\"a}t Potsdam}, pages = {X, 99}, year = {2015}, abstract = {Gashydrate sind kristalline Feststoffe bestehend aus Wasser und Gasmolek{\"u}len. Sie sind stabil bei erh{\"o}hten Dr{\"u}cken und niedrigen Temperaturen. Nat{\"u}rliche Hydratvorkommen treten daher an Kontinentalh{\"a}ngen, in Permafrostb{\"o}den und in tiefen Seen sowie Binnenmeeren auf. Bei der Hydratbildung orientieren sich die Wassermolek{\"u}le neu und bilden sogenannte K{\"a}figstrukturen, in die Gas eingelagert werden kann. Aufgrund des hohen Drucks bei der Hydratbildung k{\"o}nnen große Mengen an Gas in die Hydratstruktur eingebaut werden. Das Volumenverh{\"a}ltnis von Wasser zu Gas kann dabei bis zu 1:172 bei 0°C und Atmosph{\"a}rendruck betragen. Nat{\"u}rliche Gashydrate enthalten haupts{\"a}chlich Methan. Da Methan sowohl ein Treibhausgas als auch ein Brenngas ist, stellen Gashydrate gleichermaßen eine potentielle Energieressource sowie eine m{\"o}gliche Quelle f{\"u}r Treibhausgase dar. Diese Arbeit untersucht die physikalischen Eigenschaften von Methanhydrat ges{\"a}ttigten Sedimentproben im Labormaßstab. Dazu wurde ein großer Reservoirsimulator (LARS) mit einer eigens entwickelten elektrischen Widerstandstomographie ausger{\"u}stet, die das erste Mal an hydratges{\"a}ttigten Sedimentproben unter kontrollierten Temperatur-, Druck-, und Hydrats{\"a}ttigungsbedingungen im Labormaßstab angewendet wurde. {\"U}blicherweise ist der Porenraum von (marinen) Sedimenten mit elektrisch gut leitendem Salzwasser gef{\"u}llt. Da Hydrate einen elektrischen Isolator darstellen, ergeben sich große Kontraste hinsichtlich der elektrischen Eigenschaften im Porenraum w{\"a}hrend der Hydratbildung und -zersetzung. Durch wiederholte Messungen w{\"a}hrend der Hydraterzeugung ist es m{\"o}glich die r{\"a}umliche Widerstandsverteilung in LARS aufzuzeichnen. Diese Daten bilden in der Folge die Grundlage f{\"u}r eine neue Auswerteroutine, welche die r{\"a}umliche Widerstandsverteilung in die r{\"a}umliche Verteilung der Hydrats{\"a}ttigung {\"u}berf{\"u}hrt. Dadurch ist es m{\"o}glich, die sich {\"a}ndernde Hydrats{\"a}ttigung sowohl r{\"a}umlich als auch zeitlich hoch aufgel{\"o}st w{\"a}hrend der gesamten Hydraterzeugungsphase zu verfolgen. Diese Arbeit zeigt, dass die entwickelte Widerstandstomographie eine gute Datenqualit{\"a}t aufwies und selbst geringe Hydrats{\"a}ttigungen innerhalb der Sedimentprobe detektiert werden konnten. Bei der Umrechnung der Widerstandsverteilung in lokale Hydrat-S{\"a}ttigungswerte wurden die besten Ergebnisse mit dem Archie-var-phi Ansatz erzielt, der die zunehmende Hydratphase dem Sedimentger{\"u}st zuschreibt, was einer Abnahme der Porosit{\"a}t gleichkommt. Die Widerstandsmessungen zeigten weiterhin, dass die schnelle Hydraterzeugung im Labor zur Ausbildung von kleinen Hydratkristallen f{\"u}hrte, die dazu neigten, zu rekristalliesieren. Es wurden weiterhin Hydrat-Abbauversuche durchgef{\"u}hrt, bei denen die Hydratphase {\"u}ber Druckerniedrigung in Anlehnung an den 2007/2008 Mallik Feldtest zersetzt wurde. Dabei konnte beobachtet werden, dass die Muster der Gas- undWasserflussraten im Labor zum Teil gut nachgebildet werden konnten, jedoch auch aufbaubedingte Abweichungen auftraten. In zwei weiteren Langzeitversuchen wurde die Realisierbarkeit und das Verhalten bei CO2-CH4-Hydrat Austauschversuchen in LARS untersucht. Das tomographische Messsystem wurde dabei genutzt um w{\"a}hrend der CH4 Hydrat Aufbauphase die Hydratverteilung innerhalb der Sedimentprobe zu {\"u}berwachen. Im Zuge der anschließenden CO2-Injektion konnte mithilfe der Widerstandstomographie die sich ausbreitende CO2-Front {\"u}berwacht und der Zeitpunkt des CO2 Durchbruchs identifiziert werden.}, language = {en} } @phdthesis{TabaresJimenez2015, author = {Tabares Jim{\´e}nez, Adri{\´a}n de Jes{\´u}s}, title = {Palabras de fundadores, forasteros y cachacos}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-85630}, school = {Universit{\"a}t Potsdam}, pages = {227}, year = {2015}, abstract = {Die vorliegende Dissertation analysiert die Mentalit{\"a}ten der b{\"u}rgerlichen Bewohner Bogotas 19. Jahrhundert. Einblicke in die Fremd- und Eigenperspektiven der Bogotaner werden durch die Analyse von Reiseliteratur gewonnen. Methodologisch st{\"u}tzt sich die Arbeit auf den Vergleich zwischen europ{\"a}ischen Reiseberichten aus dem 19. Jh., Chroniken aus dem 16. Jh. sowie zwei kolumbianische Romane aus dem fr{\"u}hen 20.. Jh. Die Texte werden historiographisch behandelt; obwohl sie unterschiedlichen literarischen Genres angeh{\"o}ren, weisen sie einen gemeinsamen autobiographischen Charakter auf. Aus den Erfahrungen und Gedanken der Reisenden werden v.a. die Auswirkungen der geographischen und sozialen Isolation thematisiert, sowie die Einfl{\"u}sse von politischen und religi{\"o}sen Diskursen auf die Bildung von b{\"u}rgerlichem Gedankengut.}, language = {es} } @phdthesis{Ucar2015, author = {U{\c{c}}ar, Magdalena}, title = {Zeugenschaft im Bild}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-406087}, school = {Universit{\"a}t Potsdam}, pages = {145}, year = {2015}, abstract = {Zentrales Anliegen der Dissertation ist, Zeugenschaft als visuelle Strategie zu beleuchten. In Abgrenzung zur These der Undarstellbarkeit der Shoah wird der Begriff der Sichtbarmachung nutzbar gemacht, um Prozesse und die Wirkung von Bildern im Zusammenhang mit Zeugenschaft herauszustellen. Ausgangspunkt dabei ist, dass bildliche Zeugnisse einen Gegenpol zu den standardisierten Visualisierungspraktiken der Shoah bieten, sprich dem historischen Bildmaterial aufgenommen durch die Alliierten und der Nationalsozialisten. In der Arbeit wird das historische Bildmaterial als Visualisierungspraxis problematisiert und visuellen Zeugnissen gegen{\"u}bergestellt, die Augen- und {\"U}berlebenszeugen der Shoah, aber auch authentische Orte des Geschehens aus einer nachtr{\"a}glichen Perspektive zeigen. Dabei werden insbesondere zwei kritische Strategien des Umgangs mit historischen Bildern der Shoah hervorgehoben: das Hinterfragen von Archivbildern innerhalb des Films (Harun Farockis AUFSCHUB, 2007) und die Verweigerung von Archivbildern aus der Zeit des Zweiten Weltkrieges (Claude Lanzmanns SHOAH, 1985). Seit den 1990er Jahren wird Zeugenschaft in der Forschung als philosophische, moralische und erkenntnistheoretische Kategorie in den USA, aber auch in Deutschland viel diskutiert. Dabei wurde die bild- und medienwissenschaftliche Perspektive im Zusammenhang mit Zeugenschaft kaum beleuchtet, darin liegt der Forschungsbeitrag der Arbeit. Insbesondere drei Gesichtspunkte von visueller Zeugenschaft werden herausgearbeitet: 1) die Sichtbarmachung der {\"U}berlebenden und der Orte des Geschehens im Jetzt, 2) die nichtsprachlichen Aspekte von Zeugenaussagen und 3) die Rolle des Zuschauers, der durch den Akt des Sehens in einem Imaginationsprozess eine Verkn{\"u}pfung zwischen den Bildern aus der Jetztzeit und der nicht-sichtbaren Vergangenheit herstellt. Polen nimmt eine besondere historische Rolle als Zentrum des europ{\"a}ischen Judentums bis zum Zweiten Weltkrieg und gleichzeitig als »Schauplatz des Holocaust« und Ort der Augenzeugenschaft ein. Maßgeblich hat Claude Lanzmanns Film SHOAH dazu beigetragen, die Konzentrations- und Vernichtungslager im Polen der Nachkriegszeit sichtbar zu machen, und damit nicht nur Generationen von polnischen Filmemachern und K{\"u}nstlern nach ihm beeinflusst, sondern auch kontroverse Debatten in Polen ausgel{\"o}st. Anhand der ausgew{\"a}hlten Filme l{\"a}sst sich in der polnischen Erinnerungskultur seit der Wende von 1989 eine Hinwendung zur polnisch-j{\"u}dischen Geschichte erkennen, die sich verst{\"a}rkt mit den Fragen der polnischen Mitt{\"a}terschaft und Schuld an der Shoah auseinandersetzt. Der Untersuchungsgegenstand unterteilt sich in zwei Formate: Dokumentar- und Kunstfilm. Einerseits ist das auf ihre unterschiedlichen Produktions- und Rezeptionsbedingungen sowie die L{\"a}nge der Arbeiten zur{\"u}ckzuf{\"u}hren. Andererseits bewegen sich die Kategorien auf verschiedenen Reflexionsebenen und zielen auf unterschiedliche Wirkungen beim Zuschauer ab. W{\"a}hrend sich in den Dokumentarfilmen zum Teil explizite Bez{\"u}ge (aber auch Abgrenzungen) zum Lanzmann'schen Projekt erkennen lassen, handelt es sich bei den Produktionen des zeitgen{\"o}ssischen K{\"u}nstlers Artur Żmijewski um einen Meta-Diskurs, der auf radikale und provokative Art und Weise bestehende erinnerungskulturelle Praktiken ausstellt und kritisch hinterfragt.}, language = {de} } @phdthesis{Helpa2015, author = {Helpa, Vanessa}, title = {Interplay between mineral reaction and deformation via structural defects}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-90332}, school = {Universit{\"a}t Potsdam}, pages = {x, 104}, year = {2015}, abstract = {This thesis contains three experimental studies addressing the interplay between deformation and the mineral reaction between natural calcite and magnesite. The solid-solid mineral reaction between the two carbonates causes the formation of a magnesio-calcite precursor layer and a dolomite reaction rim in every experiment at isostatic annealing and deformation conditions. CHAPTER 1 briefly introduces general aspects concerning mineral reactions in nature and diffusion pathways for mass transport. Moreover, results of previous laboratory studies on the influence of deformation on mineral reactions are summarized. In addition, the main goals of this study are pointed out. In CHAPTER 2, the reaction between calcite and magnesite single crystals is examined at isostatic annealing conditions. Time series performed at a fixed temperature revealed a diffusion-controlled dolomite rim growth. Two microstructural domains could be identified characterized by palisade-shaped dolomite grains growing into the magnesite and granular dolomite growing towards calcite. A model was provided for the dolomite rim growth based on the counter-diffusion of CaO and MgO. All reaction products exhibited a characteristic crystallographic relationship with respect to the calcite reactant. Moreover, kinetic parameters of the mineral reaction were determined out of a temperature series at a fixed time. The main goal of the isostatic test series was to gain information about the microstructure evolution, kinetic parameters, chemical composition and texture development of the reaction products. The results were used as a reference to quantify the influence of deformation on the mineral reaction. CHAPTER 3 deals with the influence of non-isostatic deformation on dolomite and magnesio-calcite layer production between calcite and magnesite single crystals. Deformation was achieved by triaxial compression and by torsion. Triaxial compression up to 38 MPa axial stress at a fixed time showed no significant influence of stress and strain on dolomite formation. Time series conducted at a fixed stress yield no change in growth rates for dolomite and magnesio-calcite at low strains. Slightly larger magnesio-calcite growth rates were observed at strains above >0.1. High strains at similar stresses were caused by the activation of additional glide systems in the calcite single crystal and more mobile dislocations in the magnesio-calcite grains, providing fast diffusion pathways. In torsion experiments a gradual decrease in dolomite and magnesio-calcite layer thickness was observed at a critical shear strain. During deformation, crystallographic orientations of reaction products rearranged with respect to the external framework. A direct effect of the mineral reaction on deformation could not be recognized due to the relatively small reaction product widths. In CHAPTER 4, the influence of starting material microfabrics and the presence of water on the reaction kinetics was evaluated. In these experimental series polycrystalline material was in contact with single crystals or two polycrystalline materials were used as reactants. Isostatic annealing resulted in different dolomite and magnesio-calcite layer thicknesses, depending on starting material microfabrics. The reaction progress at the magnesite interface was faster with smaller magnesite grain size, because grain boundaries provided fast pathways for diffusion and multiple nucleation sites for dolomite formation. Deformation by triaxial compression and torsion yield lower dolomite rim thicknesses compared to annealed samples for the same time. This was caused by grain coarsening of polycrystalline magnesite during deformation. In contrast, magnesio-calcite layers tended to be larger during deformation, which triggered enhanced diffusion along grain boundaries. The presence of excess water had no significant influence on the reaction kinetics, at least if the reactants were single crystals. In CHAPTER 5 general conclusions about the interplay between deformation and the mineral reaction in the carbonate system are presented. Finally, CHAPTER 6 highlights possible future work in the carbonate system based on the results of this study.}, language = {en} } @phdthesis{Streich2015, author = {Streich, David}, title = {Understanding massive disk galaxy formation through resolved stellar populations}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-81027}, school = {Universit{\"a}t Potsdam}, pages = {ix, 140}, year = {2015}, abstract = {In this thesis we utilize resolved stellar populations to improve our understanding of galaxy formation and evolution. In the first part we improve a method for metallicity determination of faint old stellar systems, in the second and third part we analyze the individual history of six nearby disk galaxies outside the Local Group. A New Calibration of the Color Metallicity Relation of Red Giants for HST data: It is well known, that the color distribution of stars on the the Red Giant Branch (RGB) can be used to determine metallicities of old stellar populations that have only shallow photometry. Based on the largest sample of globular clusters ever used for such studies, we quantify the relation between metallicity and color in the widely used HST ACS filters F606W and F814W. We use a sample of globular clusters from the ACS Globular Cluster Survey and measure their RGB color at given absolute magnitudes to derive the color-metallicity relation. We find a clear relation between metallicity and RGB color; we investigate the scatter and the uncertainties in this relation and show its limitations. A comparison with isochrones shows reasonably good agreement with BaSTI models, a small offset to Dartmouth models, and a larger offset to Padua models. Even for the best globular cluster data available, the metallicity of a simple stellar population can be determined from the RGB alone only with an accuracy of 0.3 dex for [M/H]<-1, and 0.15 dex for [M/H]>-1. For mixed populations, as they are observed in external galaxies, the uncertainties will be even larger due to uncertainties in extinction, age, etc. Therefore caution is necessary when interpreting photometric metallicities. The Structural History of Nearby Low Mass Disk Galaxies: We study the individual evolution histories of three nearby, low-mass, edge-on galaxies (IC5052, NGC4244, NGC5023). Using the color magnitude diagrams of resolved stellar populations, we construct star count density maps for populations of different ages and analyze the change of structural parameters with stellar age within each galaxy. The three galaxies show low vertical heating rates, which are much lower than the heating rate of the Milky Way. This indicates that heating agents, as giant molecular clouds and spiral structure are weak in low mass galaxies. We do not detect a separate thick disk in any of the three galaxies, even though our observations cover a larger range in equivalent surface brightness than any integrated light study. While scaleheights increase with age, each population can be well described by a single disk. Only two of the galaxies contain a very weak additional component, which we identify as the faint halo. The mass of these faint halos is less than 1\% of the mass of the disk. All populations in the three galaxies exhibit no or only little flaring. While this finding is consistent with previous integrated light studies, it poses strong constraints on galaxy formation models, because most theoretical simulations often find strong flaring due to interactions or radial migration. Furthermore, we find breaks in the radial profiles of all three galaxies. The radii of these breaks are independent of age, and the break strength is decreasing with age in two of the galaxies (NGC4244 and NGC5023). This is consistent with break formation models, that combine a star formation cutoff with radial migration. The differing behavior of IC5052 can be explained by a recent interaction or minor merger. The Structural History of Massive Disk Galaxies: We extend the structural analysis of stellar populations with distinct ages to three massive galaxies, NGC891, NGC4565 and NGC7814. While confusion effects due to the high stellar number densities in their central region, and the prominent dust lanes inhibit an detailed analysis of the radial profiles, we can study their vertical structure. These massive galaxies also have a slower heating than the Milky Way, comparable to the low mass galaxies. This can be traced back to their already thick young populations and thick layers of their interstellar medium. We do not find a clear separate thick disk in any of these three galaxies; all populations can be described by a single disk plus a S\'ersic bulge/halo component. In contrast to the low mass galaxies, we cannot rule out the presence of thick disks in the massive galaxies, because of the strong influence of the halo, that might hide the possible contribution of the thick disk to the vertical star count profiles. However, the faintness of the possible thick disks still points to problems in the earlier ubiquitous findings of thick disks in external galaxies.}, language = {en} } @phdthesis{Radenacker2015, author = {Radenacker, Anke}, title = {Economic consequences of family dissolution}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-100217}, school = {Universit{\"a}t Potsdam}, pages = {v, 134}, year = {2015}, abstract = {Welfare states and policies have changed greatly over the past decades, mostly characterized by retrenchments in terms of government spending or in terms of restricted access to certain benefits. In the area of family policies, however, a lot of countries have simultaneously expanded provisions and transfers for families. Bringing together the macro analysis of policy variation and household income changes on the micro-level, the main research question of the dissertation is to what extent economic consequences following separation and divorce in families with children have changed between the 1980s and the 2000s in Germany and the United States. The second research question of the dissertation regards the differences in dissolution outcomes between married and cohabiting parents in Germany. The dissertation thus aims to link institutional regulations of welfare states with the actual income situation of families. To achieve this, a research design was developed that has never been used for the analysis of the economic consequences of family dissolution. For this, the two longest running panel datasets, German Socio-economic Panel (GSOEP) and the US American Panel Study of Income Dynamics (PSID), have been used. The analytic strategy applied to estimate the effects of family dissolution on household income is a difference-in-difference design combined with coarsened exact matching (CEM). To begin with, the dissertation confirmed many findings of previous research, for example regarding the gender differences in family dissolution outcomes. Mothers experience clearly higher relative income losses and consequently higher risks of poverty than fathers. This finding is universal, that is it holds for both countries, for all time periods observed, and for all measures of economic outcome that were employed. Another confirmed finding is the higher level of welfare state intervention in Germany compared to the United States. The dissertation also revealed a number of novel findings. The results show that the expansion of family policies in Germany over time has not been accompanied by substantially decreasing income losses for mothers. Though income losses have slightly decreased over time, they have become more persistent during the years following family dissolution. The impact of the German welfare state has meanwhile been quite stable. American mothers' income losses took place on a slightly lower level than those of German mothers. Only during the 1980s their relative losses were clearly lower than those of German mothers. And also American mothers did not recover as much from their income losses during the 2000s than they used to during the 1980s. For them, the 1996 welfare reform brought a considerable decrease in welfare state support. Accordingly, the results for American mothers can certainly be described as a shift from public to private provision. The general finding of previous studies that fathers do not have to suffer income losses, or if at all rather moderate ones compared to mothers, can be confirmed. Nevertheless, both German and US American fathers face a deterioration of the economic consequences of family dissolution over time. German fathers' relative income changes are still positive though they have decreased over time. One reason for this decrease is the increasing loss of partner earnings following union dissolution. Also among American fathers, income gains still prevail in the year of family dissolution. Two years later, however, they have been facing income losses already since the 1980s which have furthermore increased considerably over time. Zooming in on Germany, family dissolution outcomes by marital status show negligible differences between cohabiting and married mothers in disposable income, but considerable differences in losses of income before taxes and transfers. It is the impact of the welfare state that equalizes the differences in income losses between these two groups of mothers. For married mothers, losses are not as high in the year of event but they have difficulties to recover from these losses. Without the income buffering of the welfare state, married mothers would, three years after family dissolution, remain with relative income losses double as high as for cohabiting mothers. Compared to mothers, differences between married and cohabiting fathers are visible in changes of income before as well as after taxes and transfers. The welfare state does not alter the difference between the two groups of fathers. With regard to both income concepts, cohabiting fathers fare worse than married fathers. Cohabiting fathers suffer moderate income losses of disposable income while married fathers experience moderate income gains. Accounting for support payments is decisive for fathers' income changes. If these payments are not deducted from disposable income, both married and cohabiting fathers experience gains in disposable income following family dissolution.}, language = {en} } @phdthesis{Fettkenhauer2015, author = {Fettkenhauer, Christian}, title = {Ionothermale Synthese funktioneller Kohlenstoffnitrid basierter Materialien}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-78087}, school = {Universit{\"a}t Potsdam}, pages = {xii, 123}, year = {2015}, abstract = {Die Doktorarbeit behandelt die Synthese Kohlenstoffnitrid basierter Materialien in eutektischen Mischungen bivalenter Metallchloride. Der Fokus liegt dabei auf ZnCl2-, SnCl2- und CoCl2-haltigen eutektischen Mischungen, in denen die Kondensation gebr{\"a}uchlicher organischer Precursoren durchgef{\"u}hrt wird. Im Rahmen dessen wird untersucht wie durch die Reaktionsf{\"u}hrung in Salzschmelzen unterschiedlicher Lewis-Acidit{\"a}t, neben der Molek{\"u}lstruktur andere charakteristische Eigenschaften, wie Morphologie, Kristallinit{\"a}t und spezifische Oberfl{\"a}chen, der Materialien kontrolliert werden k{\"o}nnen. Dar{\"u}ber hinaus werden die optischen Eigenschaften der Materialien er{\"o}rtert und in diesem Zusammenhang die Eignung als Photokatalysatoren f{\"u}r den oxidativen Abbau organischer Farbstoffe und f{\"u}r die photokatalytische Wasserreduktion bzw. -oxidation untersucht. Zus{\"a}tzlich wird gezeigt, wie im System LiCl/KCl in einem einstufigen Prozess edelmetallfreie Kohlenstoffnitrid Komposite zur photokatalytischen Wasserreduktion hergestellt werden k{\"o}nnen.}, language = {de} } @phdthesis{Grygiel2015, author = {Grygiel, Konrad}, title = {Poly(ionic liquid) stabilizers and new synthetic approaches}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-80367}, school = {Universit{\"a}t Potsdam}, pages = {vii, 126}, year = {2015}, abstract = {The main focus of the present thesis was to investigate the stabilization ability of poly(ionic liquid)s (PILs) in several examples as well as develop novel chemical structures and synthetic routes of PILs. The performed research can be specifically divided into three parts that include synthesis and application of hybrid material composed of PIL and cellulose nanofibers (CNFs), thiazolium-containing PILs, and main-chain imidazolium-type PILs. In the first chapter, a vinylimidazolium-type IL was polymerized in water in the presence of CNFs resulting in the in situ electrostatic grafting of polymeric chains onto the surface of CNFs. The synthesized hybrid material merged advantages of its two components, that is, superior mechanical strength of CNFs and anion dependent solution properties of PILs. In contrast to unmodified CNFs, the hybrid could be stabilized and processed in organic solvents enabling its application as reinforcing agent for porous polyelectrolyte membranes. In the second part, PILs and ionic polymers containing two types of thiazolium repeating units were synthesized. Such polymers displayed counterion dependent thermal stability and solubility in organic solvents of various dielectric constants. This new class of PILs was tested as stabilizers and phase transfer agents for carbon nanotubes in aqueous and organic media, and as binder materials to disperse electroactive powders and carbon additives in solid electrode in lithium-ion batteries. The incorporation of S and N atoms into the polymeric structures make such PILs also potential precursors for S, N - co-doped carbons. In the last chapter, reactants originating from biomass were successfully harnessed to synthesize main-chain imidazolium-type PILs. An imidazolium-type diester IL obtained via a modified Debus-Radziszewski reaction underwent transesterification with diol in a polycondensation reaction. This yielded a polyester-type PIL which CO2 sorption properties were investigated. In the next step, the modified Debus-Radziszewski reaction was further applied to synthesize main-chain PILs according to a convenient, one-step protocol, using water as a green solvent and simple organic molecules as reagents. Depending on the structure of the employed diamine, the synthesized PILs after anion exchange showed superior thermal stability with unusually high carbonization yields. Overall, the outcome of these studies will actively contribute to the current research on PILs by introducing novel PIL chemical structures, improved synthetic routes, and new examples of stabilized materials. The synthesis of main-chain imidazolium-type PILs by a modified Debus-Radziszewski reaction is of a special interest for the future work on porous ionic liquid networks as well as colloidal PIL nanoparticles.}, language = {en} } @phdthesis{Busch2015, author = {Busch, Jan Philip}, title = {Investigations on mobility of carbon colloid supported nanoscale zero-valent iron (nZVI) for groundwater remediation}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-76873}, school = {Universit{\"a}t Potsdam}, pages = {X, 127, XLIII}, year = {2015}, abstract = {Injection of nanoscale zero-valent iron (nZVI) is an innovative technology for in situ installation of a permeable reactive barrier in the subsurface. Zerovalent iron (ZVI) is highly reactive with chlorinated hydrocarbons (CHCs) and renders them into less harmful substances. Application of nZVI instead of granular ZVI can increase rates of dechlorination of CHCs by orders of magnitude, due to its higher surface area. This approach is still difficult to apply due to fast agglomeration and sedimentation of colloidal suspensions of nZVI, which leads to very short transport distances. To overcome this issue of limited mobility, polyanionic stabilisers are added to increase surface charge and stability of suspensions. In field experiments maximum transport distances of a few metres were achieved. A new approach, which is investigated in this thesis, is enhanced mobility of nZVI by a more mobile carrier colloid. The investigated composite material consists of activated carbon, which is loaded with nZVI. In this cumulative thesis, transport characteristics of carbon-colloid supported nZVI (c-nZVI) are investigated. Investigations started with column experiments in 40 cm columns filled with various porous media to investigate on physicochemical influences on transport characteristics. The experimental setup was enlarged to a transport experiment in a 1.2-m-sized two-dimensional aquifer tank experiment, which was filled with granular porous media. Further, a field experiment was performed in a natural aquifer system with a targeted transport distance of 5.3 m. Parallel to these investigations, alternative methods for transport observations were investigated by using noninvasive tomographic methods. Experiments using synchrotron radiation and magnetic resonance (MRI) were performed to investigate in situ transport characteristics in a non-destructive way. Results from column experiments show potentially high mobility under environmental relevant conditions. Addition of mono-and bivalent salts, e.g. more than 0.5 mM/L CaCl2, might decrease mobility. Changes in pH to values below 6 can inhibit mobility at all. Measurements of colloid size show changes in the mean particle size by a factor of ten. Measurements of zeta potential revealed an increase of -62 mV to -82 mV. Results from the 2D-aquifer test system suggest strong particle deposition in the first centimetres and only weak straining in the further travel path and no gravitational influence on particle transport. Straining at the beginning of the travel path in the porous medium was observed with tomographic investigations of transport. MRI experiments revealed similar results to the previous experiments, and observations using synchrotron radiation suggest straining of colloids at pore throats. The potential for high transport distances, which was suggested from laboratory experiments, was confirmed in the field experiment, where the transport distance of 5.3 m was reached by at least 10\% of injected nZVI. Altogether, transport distances of the investigated carbon-colloid supported nZVI are higher than published results of traditional nZVI.}, language = {en} } @phdthesis{Trauth2015, author = {Trauth, Nico}, title = {Flow and reactive transport modeling at the stream-groundwater interface}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-82748}, school = {Universit{\"a}t Potsdam}, pages = {xv, 103}, year = {2015}, abstract = {Stream water and groundwater are important fresh water resources but their water quality is deteriorated by harmful solutes introduced by human activities. The interface between stream water and the subsurface water is an important zone for retention, transformation and attenuation of these solutes. Streambed structures enhance these processes by increased water and solute exchange across this interface, denoted as hyporheic exchange. This thesis investigates the influence of hydrological and morphological factors on hyporheic water and solute exchange as well as redox-reactions in fluvial streambed structures on the intermediate scale (10-30m). For this purpose, a three-dimensional numerical modeling approach for coupling stream water flow with porous media flow is used. Multiple steady state stream water flow scenarios over different generic pool-riffle morphologies and a natural in-stream gravel bar are simulated by a computational fluid dynamics code that provides the hydraulic head distribution at the streambed. These heads are subsequently used as the top boundary condition of a reactive transport groundwater model of the subsurface beneath the streambed. Ambient groundwater that naturally interacts with the stream water is considered in scenarios of different magnitudes of downwelling stream water (losing case) and upwelling groundwater (gaining case). Also, the neutral case, where stream stage and groundwater levels are balanced is considered. Transport of oxygen, nitrate and dissolved organic carbon and their reaction by aerobic respiration and denitrification are modeled. The results show that stream stage and discharge primarily induce hyporheic exchange flux and solute transport with implications for specific residence times and reactions at both the fully and partially submerged structures. Gaining and losing conditions significantly diminish the extent of the hyporheic zone, the water exchange flux, and shorten residence times for both the fully and partially submerged structures. With increasing magnitude of gaining or losing conditions, these metrics exponentially decrease. Stream water solutes are transported mainly advectively into the hyporheic zone and hence their influx corresponds directly to the infiltrating water flux. Aerobic respiration takes place in the shallow streambed sediments, coinciding to large parts with the extent of the hyporheic exchange flow. Denitrification occurs mainly as a "reactive fringe" surrounding the aerobic zone, where oxygen concentration is low and still a sufficient amount of stream water carbon source is available. The solute consumption rates and the efficiency of the aerobic and anaerobic reactions depend primarily on the available reactive areas and the residence times, which are both controlled by the interplay between hydraulic head distribution at the streambed and the gradients between stream stage and ambient groundwater. Highest solute consumption rates can be expected under neutral conditions, where highest solute flux, longest residence times and largest extent of the hyporheic exchange occur. The results of this thesis show that streambed structures on the intermediate scale have a significant potential to contribute to a net solute turnover that can support a healthy status of the aquatic ecosystem.}, language = {en} } @phdthesis{Aich2015, author = {Aich, Valentin}, title = {Floods in the Niger River Basin in the face of global change}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-91577}, school = {Universit{\"a}t Potsdam}, pages = {xxi, 275}, year = {2015}, abstract = {In the last decade, the number and dimensions of catastrophic flooding events in the Niger River Basin (NRB) have markedly increased. Despite the devastating impact of the floods on the population and the mainly agriculturally based economy of the riverine nations, awareness of the hazards in policy and science is still low. The urgency of this topic and the existing research deficits are the motivation for the present dissertation. The thesis is an initial detailed assessment of the increasing flood risk in the NRB. The research strategy is based on four questions regarding (1) features of the change in flood risk, (2) reasons for the change in the flood regime, (3) expected changes of the flood regime given climate and land use changes, and (4) recommendations from previous analysis for reducing the flood risk in the NRB. The question examining the features of change in the flood regime is answered by means of statistical analysis. Trend, correlation, changepoint, and variance analyses show that, in addition to the factors exposure and vulnerability, the hazard itself has also increased significantly in the NRB, in accordance with the decadal climate pattern of West Africa. The northern arid and semi-arid parts of the NRB are those most affected by the changes. As potential reasons for the increase in flood magnitudes, climate and land use changes are attributed by means of a hypothesis-testing framework. Two different approaches, based on either data analysis or simulation, lead to similar results, showing that the influence of climatic changes is generally larger compared to that of land use changes. Only in the dry areas of the NRB is the influence of land use changes comparable to that of climatic alterations. Future changes of the flood regime are evaluated using modelling results. First ensembles of statistically and dynamically downscaled climate models based on different emission scenarios are analyzed. The models agree with a distinct increase in temperature. The precipitation signal, however, is not coherent. The climate scenarios are used to drive an eco-hydrological model. The influence of climatic changes on the flood regime is uncertain due to the unclear precipitation signal. Still, in general, higher flood peaks are expected. In a next step, effects of land use changes are integrated into the model. Different scenarios show that regreening might help to reduce flood peaks. In contrast, an expansion of agriculture might enhance the flood peaks in the NRB. Similarly to the analysis of observed changes in the flood regime, the impacts of climate- and land use changes for the future scenarios are also most severe in the dry areas of the NRB. In order to answer the final research question, the results of the above analysis are integrated into a range of recommendations for science and policy on how to reduce flood risk in the NRB. The main recommendations include a stronger consideration of the enormous natural climate variability in the NRB and a focus on so called "no-regret" adaptation strategies which account for high uncertainty, as well as a stronger consideration of regional differences. Regarding the prevention and mitigation of catastrophic flooding, the most vulnerable and sensitive areas in the basin, the arid and semi-arid Sahelian and Sudano-Sahelian regions, should be prioritized. Eventually, an active, science-based and science-guided flood policy is recommended. The enormous population growth in the NRB in connection with the expected deterioration of environmental and climatic conditions is likely to enhance the region´s vulnerability to flooding. A smart and sustainable flood policy can help mitigate these negative impacts of flooding on the development of riverine societies in West Africa.}, language = {en} } @phdthesis{Obu2015, author = {Obu, Jaroslav}, title = {Effect of mass wasting on soil organic carbon storage and coastal erosion in permafrost environments}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-90599}, school = {Universit{\"a}t Potsdam}, pages = {iii, 93}, year = {2015}, abstract = {Accelerated permafrost thaw under the warming Arctic climate can have a significant impact on Arctic landscapes. Areas underlain by permafrost store high amounts of soil organic carbon (SOC). Permafrost disturbances may contribute to increased release of carbon dioxide and methane to the atmosphere. Coastal erosion, amplified through a decrease in Arctic sea-ice extent, may also mobilise SOC from permafrost. Large expanses of permafrost affected land are characterised by intense mass-wasting processes such as solifluction, active-layer detachments and retrogressive thaw slumping. Our aim is to assess the influence of mass wasting on SOC storage and coastal erosion. We studied SOC storage on Herschel Island by analysing active-layer and permafrost samples, and compared non-disturbed sites to those characterised by mass wasting. Mass-wasting sites showed decreased SOC storage and material compaction, whereas sites characterised by material accumulation showed increased storage. The SOC storage on Herschel Island is also significantly correlated to catenary position and other slope characteristics. We estimated SOC storage on Herschel Island to be 34.8 kg C m-2. This is comparable to similar environments in northwest Canada and Alaska. Coastal erosion was analysed using high resolution digital elevation models (DEMs). Two LIDAR scanning of the Yukon Coast were done in 2012 and 2013. Two DEMs with 1 m horizontal resolution were generated and used to analyse elevation changes along the coast. The results indicate considerable spatial variability in short-term coastline erosion and progradation. The high variability was related to the presence of mass-wasting processes. Erosion and deposition extremes were recorded where the retrogressive thaw slump (RTS) activity was most pronounced. Released sediment can be transported by longshore drift and affects not only the coastal processes in situ but also along adjacent coasts. We also calculated volumetric coastal erosion for Herschel Island by comparing a stereo-photogrammetrically derived DEM from 2004 with LIDAR DEMs. We compared this volumetric erosion to planimetric erosion, which was based on coastlines digitised from satellite imagery. We found a complex relationship between planimetric and volumetric coastal erosion, which we attribute to frequent occurrence of mass-wasting processes along the coasts. Our results suggest that volumetric erosion corresponds better with environmental forcing and is more suitable for the estimation of organic carbon fluxes than planimetric erosion. Mass wasting can decrease SOC storage by several mechanisms. Increased aeration following disturbance may increase microbial activity, which accelerates organic matter decomposition. New hydrological conditions that follow the mass wasting event can cause leaching of freshly exposed material. Organic rich material can also be directly removed into the sea or into a lake. On the other hand the accumulation of mobilised material can result in increased SOC storage. Mass-wasting related accumulations of mobilised material can significantly impact coastal erosion in situ or along the adjacent coast by longshore drift. Therefore, the coastline movement observations cannot completely resolve the actual sediment loss due to these temporary accumulations. The predicted increase of mass-wasting activity in the course of Arctic warming may increase SOC mobilisation and coastal erosion induced carbon fluxes.}, language = {en} } @phdthesis{Lischke2015, author = {Lischke, Betty}, title = {Food web regulation under different forcing regimes in shallow lakes}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-89149}, school = {Universit{\"a}t Potsdam}, pages = {131}, year = {2015}, abstract = {The standing stock and production of organismal biomass depends strongly on the organisms' biotic environment, which arises from trophic and non-trophic interactions among them. The trophic interactions between the different groups of organisms form the food web of an ecosystem, with the autotrophic and bacterial production at the basis and potentially several levels of consumers on top of the producers. Feeding interactions can regulate communities either by severe grazing pressure or by shortage of resources or prey production, termed top-down and bottom-up control, respectively. The limitations of all communities conglomerate in the food web regulation, which is subject to abiotic and biotic forcing regimes arising from external and internal constraints. This dissertation presents the effects of alterations in two abiotic, external forcing regimes, terrestrial matter input and long-lasting low temperatures in winter. Diverse methodological approaches, a complex ecosystem model study and the analysis of two whole-lake measurements, were performed to investigate effects for the food web regulation and the resulting consequences at the species, community and ecosystem scale. Thus, all types of organisms, autotrophs and heterotrophs, at all trophic levels were investigated to gain a comprehensive overview of the effects of the two mentioned altered forcing regimes. In addition, an extensive evaluation of the trophic interactions and resulting carbon fluxes along the pelagic and benthic food web was performed to display the efficiencies of the trophic energy transfer within the food webs. All studies were conducted in shallow lakes, which is worldwide the most abundant type of lakes. The specific morphology of shallow lakes allows that the benthic production contributes substantially to the whole-lake production. Further, as shallow lakes are often small they are especially sensitive to both, changes in the input of terrestrial organic matter and the atmospheric temperature. Another characteristic of shallow lakes is their appearance in alternative stable states. They are either in a clear-water or turbid state, where macrophytes and phytoplankton dominate, respectively. Both states can stabilize themselves through various mechanisms. These two alternative states and stabilizing mechanisms are integrated in the complex ecosystem model PCLake, which was used to investigate the effects of the enhanced terrestrial particulate organic matter (t-POM) input to lakes. The food web regulation was altered by three distinct pathways: (1) Zoobenthos received more food, increased in biomass which favored benthivorous fish and those reduced the available light due to bioturbation. (2) Zooplankton substituted autochthonous organic matter in their diet by suspended t-POM, thus the autochthonous organic matter remaining in the water reduced its transparency. (3) T-POM suspended into the water and reduced directly the available light. As macrophytes are more light-sensitive than phytoplankton they suffered the most from the lower transparency. Consequently, the resilience of the clear-water state was reduced by enhanced t-POM inputs, which makes the turbid state more likely at a given nutrient concentration. In two subsequent winters long-lasting low temperatures and a concurrent long duration of ice coverage was observed which resulted in low overall adult fish biomasses in the two study lakes - Schulzensee and Gollinsee, characterized by having and not having submerged macrophytes, respectively. Before the partial winterkill of fish Schulzensee allowed for a higher proportion of piscivorous fish than Gollinsee. However, the partial winterkill of fish aligned both communities as piscivorous fish are more sensitive to low oxygen concentrations. Young of the year fish benefitted extremely from the absence of adult fish due to lower predation pressure. Therefore, they could exert a strong top-down control on crustaceans, which restructured the entire zooplankton community leading to low crustacean biomasses and a community composition characterized by copepodites and nauplii. As a result, ciliates were released from top-down control, increased to high biomasses compared to lakes of various trophic states and depths and dominated the zooplankton community. While being very abundant in the study lakes and having the highest weight specific grazing rates among the zooplankton, ciliates exerted potentially a strong top-down control on small phytoplankton and particle-attached bacteria. This resulted in a higher proportion of large phytoplankton compared to other lakes. Additionally, the phytoplankton community was evenly distributed presumably due to the numerous fast growing and highly specific ciliate grazers. Although, the pelagic food web was completely restructured after the subsequent partial winterkills of fish, both lakes were resistant to effects of this forcing regime at the ecosystem scale. The consistently high predation pressure on phytoplankton prevented that Schulzensee switched from the clear-water to the turbid state. Further mechanisms, which potentially stabilized the clear-water state, were allelopathic effects by macrophytes and nutrient limitation in summer. The pelagic autotrophic and bacterial production was an order of magnitude more efficient transferred to animal consumers than the respective benthic production, despite the alterations of the food web structure after the partial winterkill of fish. Thus, the compiled mass-balanced whole-lake food webs suggested that the benthic bacterial and autotrophic production, which exceeded those of the pelagic habitat, was not used by animal consumers. This holds even true if the food quality, additional consumers such as ciliates, benthic protozoa and meiobenthos, the pelagic-benthic link and the potential oxygen limitation of macrobenthos were considered. Therefore, low benthic efficiencies suggest that lakes are primarily pelagic systems at least at the animal consumer level. Overall, this dissertation gives insights into the regulation of organism groups in the pelagic and benthic habitat at each trophic level under two different forcing regimes and displays the efficiency of the carbon transfer in both habitats. The results underline that the alterations of external forcing regimes affect all hierarchical level including the ecosystem.}, language = {en} } @phdthesis{Kappel2015, author = {Kappel, David}, title = {Multi-spectrum retrieval of maps of Venus' surface emissivity in the infrared}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-85301}, school = {Universit{\"a}t Potsdam}, pages = {xix, 226}, year = {2015}, abstract = {The main goal of this cumulative thesis is the derivation of surface emissivity data in the infrared from radiance measurements of Venus. Since these data are diagnostic of the chemical composition and grain size of the surface material, they can help to improve knowledge of the planet's geology. Spectrally resolved images of nightside emissions in the range 1.0-5.1 μm were recently acquired by the InfraRed Mapping channel of the Visible and InfraRed Thermal Imaging Spectrometer (VIRTIS-M-IR) aboard ESA's Venus EXpress (VEX). Surface and deep atmospheric thermal emissions in this spectral range are strongly obscured by the extremely opaque atmosphere, but three narrow spectral windows at 1.02, 1.10, and 1.18 μm allow the sounding of the surface. Additional windows between 1.3 and 2.6 μm provide information on atmospheric parameters that is required to interpret the surface signals. Quantitative data on surface and atmosphere can be retrieved from the measured spectra by comparing them to simulated spectra. A numerical radiative transfer model is used in this work to simulate the observable radiation as a function of atmospheric, surface, and instrumental parameters. It is a line-by-line model taking into account thermal emissions by surface and atmosphere as well as absorption and multiple scattering by gases and clouds. The VIRTIS-M-IR measurements are first preprocessed to obtain an optimal data basis for the subsequent steps. In this process, a detailed detector responsivity analysis enables the optimization of the data consistency. The measurement data have a relatively low spectral information content, and different parameter vectors can describe the same measured spectrum equally well. A usual method to regularize the retrieval of the wanted parameters from a measured spectrum is to take into account a priori mean values and standard deviations of the parameters to be retrieved. This decreases the probability to obtain unreasonable parameter values. The multi-spectrum retrieval algorithm MSR is developed to additionally consider physically realistic spatial and temporal a priori correlations between retrieval parameters describing different measurements. Neglecting geologic activity, MSR also allows the retrieval of an emissivity map as a parameter vector that is common to several spectrally resolved images that cover the same surface target. Even applying MSR, it is difficult to obtain reliable emissivity maps in absolute values. A detailed retrieval error analysis based on synthetic spectra reveals that this is mainly due to interferences from parameters that cannot be derived from the spectra themselves, but that have to be set to assumed values to enable the radiative transfer simulations. The MSR retrieval of emissivity maps relative to a fixed emissivity is shown to effectively avoid most emissivity retrieval errors. Relative emissivity maps at 1.02, 1.10, and 1.18 μm are finally derived from many VIRTIS-M-IR measurements that cover a surface target at Themis Regio. They are interpreted as spatial variations relative to an assumed emissivity mean of the target. It is verified that the maps are largely independent of the choice of many interfering parameters as well as the utilized measurement data set. These are the first Venus IR emissivity data maps based on a consistent application of a full radiative transfer simulation and a retrieval algorithm that respects a priori information. The maps are sufficiently reliable for future geologic interpretations.}, language = {en} } @phdthesis{Baier2015, author = {Baier, Thomas}, title = {Matching events and activities}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-84548}, school = {Universit{\"a}t Potsdam}, pages = {xxii, 213}, year = {2015}, abstract = {Nowadays, business processes are increasingly supported by IT services that produce massive amounts of event data during process execution. Aiming at a better process understanding and improvement, this event data can be used to analyze processes using process mining techniques. Process models can be automatically discovered and the execution can be checked for conformance to specified behavior. Moreover, existing process models can be enhanced and annotated with valuable information, for example for performance analysis. While the maturity of process mining algorithms is increasing and more tools are entering the market, process mining projects still face the problem of different levels of abstraction when comparing events with modeled business activities. Mapping the recorded events to activities of a given process model is essential for conformance checking, annotation and understanding of process discovery results. Current approaches try to abstract from events in an automated way that does not capture the required domain knowledge to fit business activities. Such techniques can be a good way to quickly reduce complexity in process discovery. Yet, they fail to enable techniques like conformance checking or model annotation, and potentially create misleading process discovery results by not using the known business terminology. In this thesis, we develop approaches that abstract an event log to the same level that is needed by the business. Typically, this abstraction level is defined by a given process model. Thus, the goal of this thesis is to match events from an event log to activities in a given process model. To accomplish this goal, behavioral and linguistic aspects of process models and event logs as well as domain knowledge captured in existing process documentation are taken into account to build semiautomatic matching approaches. The approaches establish a pre--processing for every available process mining technique that produces or annotates a process model, thereby reducing the manual effort for process analysts. While each of the presented approaches can be used in isolation, we also introduce a general framework for the integration of different matching approaches. The approaches have been evaluated in case studies with industry and using a large industry process model collection and simulated event logs. The evaluation demonstrates the effectiveness and efficiency of the approaches and their robustness towards nonconforming execution logs.}, language = {en} } @phdthesis{Vossenkuhl2015, author = {Vossenkuhl, Birgit}, title = {Transmission of MRSA along the meat supply chain}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-85918}, school = {Universit{\"a}t Potsdam}, pages = {141}, year = {2015}, abstract = {Methicillin-resistente Staphylococcus aureus (MRSA) z{\"a}hlen zu den bedeutendsten antibiotikaresistenten Pathogenen, die vor allem in Krankenh{\"a}usern aber auch außerhalb von Einrichtungen des Gesundheitswesens weit verbreitet sind. Seit einigen Jahren ist eine neue Generation von MRSA auf dem Vormarsch, die vor allem Nutztierbest{\"a}nde als neue Nische besiedelt. Diese sogenannten Nutztier-assoziierten MRSA wurden wiederholt bei wirtschaftlich bedeutenden Nutztieren sowie daraus gewonnenem Fleisch nachgewiesen. Im Rahmen der vorliegenden Arbeit wurde ein methodischer Ansatz verfolgt, um die Hypothese einer m{\"o}glichen {\"U}bertragung von Nutztier-assoziierten MRSA entlang der Lebensmittelkette vom Tier auf dessen Fleisch zu best{\"a}tigen. Angepasst an die Unterschiede in den verf{\"u}gbaren Daten wurden daf{\"u}r zwei neue Konzepte erstellt. Zur Analyse der {\"U}bertragung von MRSA entlang der Schlachtkette wurde ein mathematisches Modell des Schweineschlachtprozesses entwickelt, welches dazu geeignet ist, den Verlauf der MRSA-Pr{\"a}valenz entlang der Schlachtkette zu quantifizieren sowie kritische Prozessschritte f{\"u}r eine MRSA-{\"U}bertragung zu identifizieren. Anhand von Pr{\"a}valenzdaten ist es dem Modell m{\"o}glich, die durchschnittlichen MRSA-Eliminations- und Kontaminationsraten jedes einzelnen Prozessschrittes zu sch{\"a}tzen, die anschließend in eine Monte-Carlo-Simulation einfließen. Im Ergebnis konnte gezeigt werden, dass es generell m{\"o}glich ist, die MRSA Pr{\"a}valenz im Laufe des Schlachtprozesses auf ein niedriges finales Niveau zwischen 0,15 bis 1,15\% zu reduzieren. Vor allem das Br{\"u}hen und Abfl{\"a}mmen der Schlachtk{\"o}rper wurden als kritische Prozesse im Hinblick auf eine MRSA-Dekontamination identifiziert. In Deutschland werden regelm{\"a}ßig MRSA-Pr{\"a}valenz und Typisierungsdaten auf allen Stufen der Lebensmittelkette verschiedener Nutztiere erfasst. Um die MRSA-Daten dieser Querschnittstudie hinsichtlich einer m{\"o}glichen {\"U}bertragung entlang der Kette zu analysieren, wurde ein neuer statistischer Ansatz entwickelt. Hierf{\"u}r wurde eine Chi-Quadrat-Statistik mit der Berechnung des Czekanowski-{\"A}hnlichkeitsindex kombiniert, um Unterschiede in der Verteilung stammspezifischer Eigenschaften zwischen MRSA aus dem Stall, von Karkassen nach der Schlachtung und aus Fleisch im Einzelhandel zu quantifizieren. Die Methode wurde am Beispiel der Putenfleischkette implementiert und zudem bei der Analyse der Kalbfleischkette angewendet. Die durchgehend hohen {\"A}hnlichkeitswerte zwischen den einzelnen Proben weisen auf eine m{\"o}gliche {\"U}bertragung von MRSA entlang der Lebensmittelkette hin. Die erarbeiteten Methoden sind nicht spezifisch bez{\"u}glich Prozessketten und Pathogenen. Sie bieten somit einen großen Anwendungsbereich und erweitern das Methodenspektrum zur Bewertung bakterieller {\"U}bertragungswege.}, language = {en} } @phdthesis{Boesche2015, author = {B{\"o}sche, Nina Kristine}, title = {Detection of rare earth elements and rare earth oxides with hyperspectral spectroscopy}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-85363}, school = {Universit{\"a}t Potsdam}, pages = {147}, year = {2015}, abstract = {The continuously increasing demand for rare earth elements in technical components of modern technologies, brings the detection of new deposits closer into the focus of global exploration. One promising method to globally map important deposits might be remote sensing, since it has been used for a wide range of mineral mapping in the past. This doctoral thesis investigates the capacity of hyperspectral remote sensing for the detection of rare earth element deposits. The definition and the realization of a fundamental database on the spectral characteristics of rare earth oxides, rare earth metals and rare earth element bearing materials formed the basis of this thesis. To investigate these characteristics in the field, hyperspectral images of four outcrops in Fen Complex, Norway, were collected in the near-field. A new methodology (named REEMAP) was developed to delineate rare earth element enriched zones. The main steps of REEMAP are: 1) multitemporal weighted averaging of multiple images covering the sample area; 2) sharpening the rare earth related signals using a Gaussian high pass deconvolution technique that is calibrated on the standard deviation of a Gaussian-bell shaped curve that represents by the full width of half maxima of the target absorption band; 3) mathematical modeling of the target absorption band and highlighting of rare earth elements. REEMAP was further adapted to different hyperspectral sensors (EO-1 Hyperion and EnMAP) and a new test site (Lofdal, Namibia). Additionally, the hyperspectral signatures of associated minerals were investigated to serve as proxy for the host rocks. Finally, the capacity and limitations of spectroscopic rare earth element detection approaches in general and of the REEMAP approach specifically were investigated and discussed. One result of this doctoral thesis is that eight rare earth oxides show robust absorption bands and, therefore, can be used for hyperspectral detection methods. Additionally, the spectral signatures of iron oxides, iron-bearing sulfates, calcite and kaolinite can be used to detect metasomatic alteration zones and highlight the ore zone. One of the key results of this doctoral work is the developed REEMAP approach, which can be applied from near-field to space. The REEMAP approach enables rare earth element mapping especially for noisy images. Limiting factors are a low signal to noise ratio, a reduced spectral resolution, overlaying materials, atmospheric absorption residuals and non-optimal illumination conditions. Another key result of this doctoral thesis is the finding that the future hyperspectral EnMAP satellite (with its currently published specifications, June 2015) will be theoretically capable to detect absorption bands of erbium, dysprosium, holmium, neodymium and europium, thulium and samarium. This thesis presents a new methodology REEMAP that enables a spatially wide and rapid hyperspectral detection of rare earth elements in order to meet the demand for fast, extensive and efficient rare earth exploration (from near-field to space).}, language = {en} } @phdthesis{Zakharova2015, author = {Zakharova, Olga}, title = {Analysis and modeling of transient earthquake patterns and their dependence on local stress regimes}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-86455}, school = {Universit{\"a}t Potsdam}, pages = {XVI, 94}, year = {2015}, abstract = {Investigations in the field of earthquake triggering and associated interactions, which includes aftershock triggering as well as induced seismicity, is important for seismic hazard assessment due to earthquakes destructive power. One of the approaches to study earthquake triggering and their interactions is the use of statistical earthquake models, which are based on knowledge of the basic seismicity properties, in particular, the magnitude distribution and spatiotemporal properties of the triggered events. In my PhD thesis I focus on some specific aspects of aftershock properties, namely, the relative seismic moment release of the aftershocks with respect to the mainshocks; the spatial correlation between aftershock occurrence and fault deformation; and on the influence of aseismic transients on the aftershock parameter estimation. For the analysis of aftershock sequences I choose a statistical approach, in particular, the well known Epidemic Type Aftershock Sequence (ETAS) model, which accounts for the input of background and triggered seismicity. For my specific purposes, I develop two ETAS model modifications in collaboration with Sebastian Hainzl. By means of this approach, I estimate the statistical aftershock parameters and performed simulations of aftershock sequences as well. In the case of seismic moment release of aftershocks, I focus on the ratio of cumulative seismic moment release with respect to the mainshocks. Specifically, I investigate the ratio with respect to the focal mechanism of the mainshock and estimate an effective magnitude, which represents the cumulative aftershock energy (similar to Bath's law, which defines the average difference between mainshock and the largest aftershock magnitudes). Furthermore, I compare the observed seismic moment ratios with the results of the ETAS simulations. In particular, I test a restricted ETAS (RETAS) model which is based on results of a clock advanced model and static stress triggering. To analyze spatial variations of triggering parameters I focus in my second approach on the aftershock occurrence triggered by large mainshocks and the study of the aftershock parameter distribution and their spatial correlation with the coseismic/postseismic slip and interseismic locking. To invert the aftershock parameters I improve the modified ETAS (m-ETAS) model, which is able to take the extension of the mainshock rupture into account. I compare the results obtained by the classical approach with the output of the m-ETAS model. My third approach is concerned with the temporal clustering of seismicity, which might not only be related to earthquake-earthquake interactions, but also to a time-dependent background rate, potentially biasing the parameter estimations. Thus, my coauthors and I also applied a modification of the ETAS model, which is able to take into account time-dependent background activity. It can be applicable for two different cases: when an aftershock catalog has a temporal incompleteness or when the background seismicity rate changes with time, due to presence of aseismic forces. An essential part of any research is the testing of the developed models using observational data sets, which are appropriate for the particular study case. Therefore, in the case of seismic moment release I use the global seismicity catalog. For the spatial distribution of triggering parameters I exploit two aftershock sequences of the Mw8.8 2010 Maule (Chile) and Mw 9.0 2011 Tohoku (Japan) mainshocks. In addition, I use published geodetic slip models of different authors. To test our ability to detect aseismic transients my coauthors and I use the data sets from Western Bohemia (Central Europe) and California. Our results indicate that: (1) the seismic moment of aftershocks with respect to mainshocks depends on the static stress changes and is maximal for the normal, intermediate for thrust and minimal for strike-slip stress regimes, where the RETAS model shows a good correspondence with the results; (2) The spatial distribution of aftershock parameters, obtained by the m-ETAS model, shows anomalous values in areas of reactivated crustal fault systems. In addition, the aftershock density is found to be correlated with coseismic slip gradient, afterslip, interseismic coupling and b-values. Aftershock seismic moment is positively correlated with the areas of maximum coseismic slip and interseismically locked areas. These correlations might be related to the stress level or to material properties variations in space; (3) Ignoring aseismic transient forcing or temporal catalog incompleteness can lead to the significant under- or overestimation of the underlying trigger parameters. In the case when a catalog is complete, this method helps to identify aseismic sources.}, language = {en} } @phdthesis{Wallenta2015, author = {Wallenta, Daniel}, title = {Sequences of compact curvature}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-87489}, school = {Universit{\"a}t Potsdam}, pages = {viii, 73}, year = {2015}, abstract = {By perturbing the differential of a (cochain-)complex by "small" operators, one obtains what is referred to as quasicomplexes, i.e. a sequence whose curvature is not equal to zero in general. In this situation the cohomology is no longer defined. Note that it depends on the structure of the underlying spaces whether or not an operator is "small." This leads to a magical mix of perturbation and regularisation theory. In the general setting of Hilbert spaces compact operators are "small." In order to develop this theory, many elements of diverse mathematical disciplines, such as functional analysis, differential geometry, partial differential equation, homological algebra and topology have to be combined. All essential basics are summarised in the first chapter of this thesis. This contains classical elements of index theory, such as Fredholm operators, elliptic pseudodifferential operators and characteristic classes. Moreover we study the de Rham complex and introduce Sobolev spaces of arbitrary order as well as the concept of operator ideals. In the second chapter, the abstract theory of (Fredholm) quasicomplexes of Hilbert spaces will be developed. From the very beginning we will consider quasicomplexes with curvature in an ideal class. We introduce the Euler characteristic, the cone of a quasiendomorphism and the Lefschetz number. In particular, we generalise Euler's identity, which will allow us to develop the Lefschetz theory on nonseparable Hilbert spaces. Finally, in the third chapter the abstract theory will be applied to elliptic quasicomplexes with pseudodifferential operators of arbitrary order. We will show that the Atiyah-Singer index formula holds true for those objects and, as an example, we will compute the Euler characteristic of the connection quasicomplex. In addition to this we introduce geometric quasiendomorphisms and prove a generalisation of the Lefschetz fixed point theorem of Atiyah and Bott.}, language = {en} } @phdthesis{Kaempf2015, author = {K{\"a}mpf, Lucas}, title = {Extreme events in geoarchives}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-85961}, school = {Universit{\"a}t Potsdam}, pages = {xii, 94}, year = {2015}, abstract = {A main limitation in the field of flood hydrology is the short time period covered by instrumental flood time series, rarely exceeding more than 50 to 100 years. However, climate variability acts on short to millennial time scales and identifying causal linkages to extreme hydrological events requires longer datasets. To extend instrumental flood time series back in time, natural geoarchives are increasingly explored as flood recorders. Therefore, annually laminated (varved) lake sediments seem to be the most suitable archives since (i) lake basins act as natural sediment traps in the landscape continuously recording land surface processes including floods and (ii) individual flood events are preserved as detrital layers intercalated in the varved sediment sequence and can be dated with seasonal precision by varve counting. The main goal of this thesis is to improve the understanding about hydrological and sedimentological processes leading to the formation of detrital flood layers and therewith to contribute to an improved interpretation of lake sediments as natural flood archives. This goal was achieved in two ways: first, by comparing detrital layers in sediments of two dissimilar peri-Alpine lakes, Lago Maggiore in Northern Italy and Mondsee in Upper Austria, with local instrumental flood data and, second, by tracking detrital layer formation during floods by a combined hydro-sedimentary monitoring network at Lake Mondsee spanning from the rain fall to the deposition of detrital sediment at the lake floor. Successions of sub-millimetre to 17 mm thick detrital layers were detected in sub-recent lake sediments of the Pallanza Basin in the western part of Lago Maggiore (23 detrital layers) and Lake Mondsee (23 detrital layers) by combining microfacies and high-resolution micro X-ray fluorescence scanning techniques (µ-XRF). The detrital layer records were dated by detailed intra-basin correlation to a previously dated core sequence in Lago Maggiore and varve counting in Mondsee. The intra-basin correlation of detrital layers between five sediment cores in Lago Maggiore and 13 sediment cores in Mondsee allowed distinguishing river runoff events from local erosion. Moreover, characteristic spatial distribution patterns of detrital flood layers revealed different depositional processes in the two dissimilar lakes, underflows in Lago Maggiore as well as under- and interflows in Mondsee. Comparisons with runoff data of the main tributary streams, the Toce River at Lago Maggiore and the Griesler Ache at Mondsee, revealed empirical runoff thresholds above which the deposition of a detrital layer becomes likely. Whereas this threshold is the same for the whole Pallanza Basin in Lago Maggiore (600 m3s-1 daily runoff), it varies within Lake Mondsee. At proximal locations close to the river inflow detrital layer deposition requires floods exceeding a daily runoff of 40 m3s-1, whereas at a location 2 km more distal an hourly runoff of 80 m3s-1 and at least 2 days with runoff above 40 m3s-1 are necessary. A relation between the thickness of individual deposits and runoff amplitude of the triggering events is apparent for both lakes but is obviously further influenced by variable influx and lake internal distribution of detrital sediment. To investigate processes of flood layer formation in lake sediments, hydro-sedimentary dynamics in Lake Mondsee and its main tributary stream, Griesler Ache, were monitored from January 2011 to December 2013. Precipitation, discharge and turbidity were recorded continuously at the rivers outlet to the lake and compared to sediment fluxes trapped close to the lake bottom on a basis of three to twelve days and on a monthly basis in three different water depths at two locations in the lake basin, in a distance of 0.9 (proximal) and 2.8 km (distal) to the Griesler Ache inflow. Within the three-year observation period, 26 river floods of different amplitude (10-110 m3s-1) were recorded resulting in variable sediment fluxes to the lake (4-760 g m-2d-1). Vertical and lateral variations in flood-related sedimentation during the largest floods indicate that interflows are the main processes of lake internal sediment transport in Lake Mondsee. The comparison of hydrological and sedimentological data revealed (i) a rapid sedimentation within three days after the peak runoff in the proximal and within six to ten days in the distal lake basin, (ii) empirical runoff thresholds for triggering sediment flux at the lake floor increasing from the proximal (20 m3s-1) to the distal lake basin (30 m3s-1) and (iii) factors controlling the amount of detrital sediment deposition at a certain location in the lake basin. The total influx of detrital sediment is mainly driven by runoff amplitude, catchment sediment availability and episodic sediment input by local sediment sources. A further role plays the lake internal sediment distribution which is not the same for each event but is favoured by flood duration and the existence of a thermocline and, therewith, the season in which a flood occurred. In summary, the studies reveal a high sensitivity of lake sediments to flood events of different intensity. Certain runoff amplitudes are required to supply enough detrital material to form a visible detrital layer at the lake floor. Reasonable are positive feedback mechanisms between rainfall, runoff, erosion, fluvial sediment transport capacity and lake internal sediment distribution. Therefore, runoff thresholds for detrital layer formation are site-specific due to different lake-catchment characteristics. However, the studies also reveal that flood amplitude is not the only control for the amount of deposited sediment at a certain location in the lake basin even for the strongest flood events. The sediment deposition is rather influenced by a complex interaction of catchment and in-lake processes. This means that the coring location within a lake basin strongly determines the significance of a flood layer record. Moreover, the results show that while lake sediments provide ideal archives for reconstructing flood frequencies, the reconstruction of flood amplitudes is a more complex issue and requires detailed knowledge about relevant catchment and in-lake sediment transport and depositional processes.}, language = {en} } @phdthesis{Sommerfeld2015, author = {Sommerfeld, Anja}, title = {Quantification of internal variability of the arctic summer atmosphere based on HIRHAM5 ensemble simulations}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-85347}, school = {Universit{\"a}t Potsdam}, pages = {VII, 110, vi}, year = {2015}, abstract = {The non-linear behaviour of the atmospheric dynamics is not well understood and makes the evaluation and usage of regional climate models (RCMs) difficult. Due to these non-linearities, chaos and internal variability (IV) within the RCMs are induced, leading to a sensitivity of RCMs to their initial conditions (IC). The IV is the ability of RCMs to realise different solutions of simulations that differ in their IC, but have the same lower and lateral boundary conditions (LBC), hence can be defined as the across-member spread between the ensemble members. For the investigation of the IV and the dynamical and diabatic contributions generating the IV four ensembles of RCM simulations are performed with the atmospheric regional model HIRHAM5. The integration area is the Arctic and each ensemble consists of 20 members. The ensembles cover the time period from July to September for the years 2006, 2007, 2009 and 2012. The ensemble members have the same LBC and differ in their IC only. The different IC are arranged by an initialisation time that shifts successively by six hours. Within each ensemble the first simulation starts on 1st July at 00 UTC and the last simulation starts on 5th July at 18 UTC and each simulation runs until 30th September. The analysed time period ranges from 6th July to 30th September, the time period that is covered by all ensemble members. The model runs without any nudging to allow a free development of each simulation to get the full internal variability within the HIRHAM5. As a measure of the model generated IV, the across-member standard deviation and the across-member variance is used and the dynamical and diabatic processes influencing the IV are estimated by applying a diagnostic budget study for the IV tendency of the potential temperature developed by Nikiema and Laprise [2010] and Nikiema and Laprise [2011]. The diagnostic budget study is based on the first law of thermodynamics for potential temperature and the mass-continuity equation. The resulting budget equation reveals seven contributions to the potential temperature IV tendency. As a first study, this work analyses the IV within the HIRHAM5. Therefore, atmospheric circulation parameters and the potential temperature for all four ensemble years are investigated. Similar to previous studies, the IV fluctuates strongly in time. Further, due to the fact that all ensemble members are forced with the same LBC, the IV depends on the vertical level within the troposphere, with high values in the lower troposphere and at 500 hPa and low values in the upper troposphere and at the surface. By the same reason, the spatial distribution shows low values of IV at the boundaries of the model domain. The diagnostic budget study for the IV tendency of potential temperature reveals that the seven contributions fluctuate in time like the IV. However, the individual terms reach different absolute magnitudes. The budget study identifies the horizontal and vertical 'baroclinic' terms as the main contributors to the IV tendency, with the horizontal 'baroclinic' term producing and the vertical 'baroclinic' term reducing the IV. The other terms fluctuate around zero, because they are small in general or are balanced due to the domain average. The comparison of the results obtained for the four different ensembles (summers 2006, 2007, 2009 and 2012) reveals that on average the findings for each ensemble are quite similar concerning the magnitude and the general pattern of IV and its contributions. However, near the surface a weaker IV is produced with decreasing sea ice extent. This is caused by a smaller impact of the horizontal 'baroclinic' term over some regions and by the changing diabatic processes, particularly a more intense reducing tendency of the IV due to condensative heating. However, it has to be emphasised that the behaviour of the IV and its dynamical and diabatic contributions are influenced mainly by complex atmospheric feedbacks and large-scale processes and not by the sea ice distribution. Additionally, a comparison with a second RCM covering the Arctic and using the same LBCs and IC is performed. For both models very similar results concerning the IV and its dynamical and diabatic contributions are found. Hence, this investigation leads to the conclusion that the IV is a natural phenomenon and is independent from the applied RCM.}, language = {en} } @phdthesis{Wohlfarth2015, author = {Wohlfarth, Kai}, title = {PPP: zu Finanzierungsformen, Kapitalmarktrelevanz und {\"o}ffentlicher Verschuldung}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-90216}, school = {Universit{\"a}t Potsdam}, pages = {X, 184}, year = {2015}, abstract = {Die vorliegende Arbeit thematisiert die Finanzierungsmodelle von Public-Private-Partnership-Projekten (PPP) und deren Refinanzierung durch die Kapitalgeber. Dabei wurden zwei zentrale Fragestellungen thematisiert. Erstens: F{\"u}hren PPP­Projekte zu einer Verschuldung der {\"o}ffentlichen Hand und sind sie entsprechend bei den Berechnungen der Konvergenzkriterien bzw. der Schulden- und Neuverschuldungsquoten zu ber{\"u}cksichtigen? Die zu pr{\"u}fende Arbeitshypothese geht von einer Verschuldung der {\"o}ffentlichen Hand in Folge von PPP-Projekten aus. Zweitens: Unterstellt wird eine bedeutsame Funktion von PPP f{\"u}r die Infrastrukturfinanzierung, wobei im Sinne einer Effizienzsteigerung die Passgenauigkeit beziehungsweise Konsistenz der haushaltsrechtlichen Regelungen mit den regulatorischen Vorgaben f{\"u}r die Kapitalgeber von PPP-Projekten analysiert wird. Diese Schnittstelle und die zur Generierung g{\"u}nstiger („kommunal{\"a}hnlicher") Finanzierungskonditionen notwendigen staatlichen Garantien bei PPP dr{\"a}ngt geradezu zu einem ordnungspolitischen Vergleich von Ans{\"a}tzen bzw. Projekten im Bereich PPP und in Cash-Flow-Kalk{\"u}len. Die Arbeit f{\"u}hrt mit einem gewissen gesamtwirtschaftlichen Fokus der PPP tief in die Analyse des Kapitalmarktes und der Bankenregulierung. Es erfolgt ein Vergleich der gedeckten Refinanzierungsinstrumente f{\"u}r PPP, die durch Forderungen besichert sind (Asset Backed Securities) und solche, die beispielsweise durch Forderungen gegen die {\"o}ffentliche Hand besichert sind (Covered Bonds). Letztere k{\"o}nnen auch grundpfandrechtlich gesichert sein. Hier setzt der Verfasser sp{\"a}ter seine Skizze eines „Infrastructure Covered Bonds" f{\"u}r die Finanzierung notwendiger Infrastrukturmaßnahmen nicht nur in Deutschland an, wobei das Wertpapier hier ausschließlich zur Finanzierung der Infrastruktur bei einem entsprechend neu zuschaffenden (Deckungs-) Registers begeben werden wird.}, language = {de} } @phdthesis{Liebrich2015, author = {Liebrich, Marietta}, title = {Einfluss von Prozessoptimierungen auf die mikrobielle Diversit{\"a}t und die Effizienz der Gasbildung in Co-Verg{\"a}rungsanlagen der Abfallwirtschaft}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-91066}, school = {Universit{\"a}t Potsdam}, pages = {VII, 102}, year = {2015}, abstract = {Im Hinblick auf die Problematik der Umweltverschmutzung durch die Nutzung fossiler Brennstoffe ist es n{\"o}tig, eine langfristig stabile und umweltfreundliche Energieversorgung zu gew{\"a}hrleisten. Eine M{\"o}glichkeit, den Energiebedarf CO2-neutral zu decken, ist die Nutzung von Biogas. Hierbei spielt der Einsatz von biogenen Reststoffen, die durch einen hohen Anteil an Kohlenhydraten, Fetten und Proteinen gekennzeichnet sind und daher ein hohes Biogaspotential besitzen, eine wichtige Rolle. Voraussetzung f{\"u}r die Effizienz und Rentabilit{\"a}t solcher Anlagen ist u. a. ein stabiler Gasbildungsprozess. Da bisher noch nicht alle Aspekte der Biogasbildung vollst{\"a}ndig verstanden sind, werden die Anlagen oft nicht optimal ausgelastet, um Prozessst{\"o}rungen wie z. B. {\"U}bers{\"a}uerung zu vermeiden. Um dennoch auftretende Prozessst{\"o}rungen zu beheben, k{\"o}nnen unterschiedliche Maßnahmen durchgef{\"u}hrt werden. Neben der Senkung der Raumbelastung, ist es m{\"o}glich, den pH-Wert durch die Zugabe von Natronlauge oder Calciumoxid anzuheben. In der vorliegenden Arbeit wurden sowohl Prozessst{\"o}rungen als auch Prozessregenerierungen an einer großtechnischen Biogasanlage und in Laborversuchen untersucht. Dabei galt es, neben den physikalischen und chemischen Parametern, die mikrobielle Bioz{\"o}nose mit Hilfe des genetischen Fingerprintings zu charakterisieren und {\"A}nderungen zu detektieren. W{\"a}hrend der Prozessregenerierungen wurden nach der Zugabe von CaO Ver{\"a}nderungen des G{\"a}rrestes beobachtet. Es bildeten sich Pellets, die im Hinblick auf ihre Funktion f{\"u}r die Prozessregenerierung und die Prozessstabilit{\"a}t molekularbiologisch und mikroskopisch untersucht wurden. Es wurde weiterhin der Frage nachgegangen, welche Rolle die Mikroorganismen bei der Entstehung der Pellets spielen. Die vor allem aus Calcium und Fetts{\"a}uren bestehenden Pellets dienten als Aufwuchsfl{\"a}chen f{\"u}r verschiedene Mikroorganismen. Die Bildung von Biofilmen, wie sie auf und in den Pellets nachgewiesen wurde, bot f{\"u}r Mikroorganismen einen Schutz vor negativen Umwelteinfl{\"u}ssen wie z. B. hohe Propions{\"a}urekonzentrationen. Unter diesen g{\"u}nstigen Bedingungen war die Bildung von Biogas auch unter hohen Wasserstoffpartialdr{\"u}cken, die den Abbau von Propions{\"a}ure hemmten, m{\"o}glich. Als Indikator f{\"u}r bessere Lebensbedingungen wurde im Laborversuch ein Methanoculleus receptaculi-verwandter Organismus identifiziert. Dieses methanogene Archaeon wurde im Pellet nachgewiesen, w{\"a}hrend es im G{\"a}rrest erst nach der Prozessregenerierung detektiert wurde. Der Nachweis eines im Vergleich zum umgebenden G{\"a}rrest h{\"o}heren Anteils an Archaeen im Kern der Pellets sowie von Biofilmen/EPS, verschiedenen Phosphatsalzen und schwerl{\"o}slichen Calciumsalzen zeigte, dass sowohl Pr{\"a}zipitation und Adsorption als auch Degradation von LCFA dazu f{\"u}hren, dass deren Konzentration im fl{\"u}ssigen G{\"a}rrest gesenkt wird. Dadurch nimmt die Hemmung auf die Bioz{\"o}nose ab und die Biogasbildungsrate steigt. Daher ist der Abbau der Fetts{\"a}uren auch bei einem niedrigen pH-Wert und unter hohen Wasserstoffpartialdr{\"u}cken m{\"o}glich und der Biogasbildungsprozess ist langfristig stabil. Die Bildung von Pellets unterst{\"u}tzt die Prozessstabilit{\"a}t, sofern diese nicht zu groß werden und dann u. a. die Durchmischung behindern und den Ablauf verstopfen. Nach erfolgreicher Prozessstabilisierung wurden keine Pellets im G{\"a}rrest beobachtet. Der Abbau des organischen Materials wurde sowohl durch die steigende Calciumkonzentration als auch die steigende Gasproduktion angezeigt.}, language = {de} } @phdthesis{Schnitzler2015, author = {Schnitzler, Carola}, title = {Phonologische Bewusstheit und Schriftspracherwerb}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-92370}, school = {Universit{\"a}t Potsdam}, pages = {IV, 52}, year = {2015}, abstract = {Die vorliegende Arbeit besch{\"a}ftigt sich mit der Fragestellung, inwieweit die Integrit{\"a}t der phonologischen Sprachverarbeitung f{\"u}r den erfolgreichen Schriftspracherwerb bei deutschsprachigen Kindern relevant ist. Hierbei bilden F{\"a}higkeiten zur phonologischen Bewusstheit (PhB) den Schwerpunkt. Der erfolgreiche Schriftspracherwerb ist nicht nur f{\"u}r den Bildungserfolg mit den damit verbundenen beruflichen und sozio‑{\"o}konomischen Perspektiven wichtig, sondern auch f{\"u}r die aktive Teilhabe am sozialen und kulturellen Leben in unserer Gesellschaft. Die Bestandteile dieser publikationsbasierten Dissertation sind eine Monographie (Schnitzler, 2008), ein Beitrag in einem Sammelwerk (Schnitzler, 2013) sowie zwei Zeitschriftenartikel (Schnitzler, 2014, 2015). Die ersten beiden Publikationen besch{\"a}ftigen sich mit der Entwicklung der PhB sowie Zusammenh{\"a}ngen zwischen PhB und Schriftsprachfertigkeiten. Die beiden Zeitschriftenartikel besch{\"a}ftigen sich mit dem LRS‑Risiko deutschsprachiger Kinder, die im Vorschulalter aufgrund phonologischer Aussprachest{\"o}rungen (PhAS) logop{\"a}disch behandelt werden. Hierzu wurden in Schnitzler (2015) die Ergebnisse einer selbst durchgef{\"u}hrten Studie dargestellt. In dieser Studie wurden m{\"o}gliche Einfl{\"u}sse zus{\"a}tzlicher nicht‑phonologischer Symptome und der Art der phonologischen Aussprachest{\"o}rung kontrolliert. Die Ergebnisse weisen darauf hin, dass zum Schulbeginn und w{\"a}hrend der Schuleingangsphase genau beobachtet werden sollte, ob Kinder {\"u}ber altersentsprechende F{\"a}higkeiten zur PhB verf{\"u}gen und ob sie diese segmental‑phonologischen Wissensbest{\"a}nde bewusst aktivieren und beim Lesen und Schreiben effizient nutzen. Dies gilt insbesondere f{\"u}r Kinder, f{\"u}r die ein erh{\"o}htes LRS‑Risiko besteht. Verf{\"u}gen Kinder zu dieser Zeit {\"u}ber unzureichend spezifizierte phonologische Repr{\"a}sentationen, ist eine fr{\"u}hzeitige Intervention im Sinne einer Pr{\"a}vention von LRS angezeigt.}, language = {de} } @phdthesis{Hogenacker2015, author = {Hogenacker, Jens}, title = {Essays on the transition from unemployment to employment with a special emphasis on start-up subsidies in Germany}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-87464}, school = {Universit{\"a}t Potsdam}, pages = {xvi, 272}, year = {2015}, abstract = {The promotion of self-employment as part of active labor market policies is considered to be one of the most important unemployment support schemes in Germany. Against this background the main part of this thesis contributes to the evaluation of start-up support schemes within ALMP. Chapter 2 and 4 focus on the evaluation of the New Start-up Subsidy (NSUS, Gr{\"u}ndungszuschuss) in its first version (from 2006 to the end of 2011). The chapters offer an advancement of the evaluation of start-up subsidies in Germany, and are based on a novel data set of administrative data from the Federal Employment Agency that was enriched with information from a telephone survey. Chapter 2 provides a thorough descriptive analysis of the NSUS that consists of two parts. First, the participant structure of the program is compared with the one of two former programs. In a second step, the study conducts an in-depth characterization of the participants of the NSUS focusing on founding motives, the level of start-up capital and equity used as well as the sectoral distribution of the new business. Furthermore, the business survival, income situation of founders and job creation by the new businesses is analyzed during a period of 19 months after start-up. The contribution of Chapter 4 is to introduce a new explorative data set that allows comparing subsidized start-ups out of unemployment with non-subsidized business start-ups that were founded by individuals who were not unemployed at the time of start-up. Because previous evaluation studies commonly used eligible non-participants amongst the unemployed as control group to assess the labor market effects of the start-up subsidies, the corresponding results hence referred to the effectiveness of the ALMP measure, but could not address the question whether the subsidy leads to similarly successful and innovative businesses compared to non-subsidized businesses. An assessment of this economic/growth aspect is also important, since the subsidy might induce negative effects that may outweigh the positive effects from an ALMP perspective. The main results of Chapter 4 indicate that subsidized founders seem to have no shortages in terms of formal education, but exhibit less employment and industry-specific experience, and are less likely to benefit from intergenerational transmission of start-ups. Moreover, the study finds evidence that necessity start-ups are over-represented among subsidized business founders, which suggests disadvantages in terms of business preparation due to possible time restrictions right before start-up. Finally, the study also detects more capital constraints among the unemployed, both in terms of the availability of personal equity and access to loans. With respect to potential differences between both groups in terms of business development over time, the results indicate that subsidized start-ups out of unemployment face higher business survival rates 19 months after start-up. However, they lag behind regular business founders in terms of income, business growth, and innovation. The arduous data collection process for start-up activities of non-subsidized founders for Chapter 4 made apparent that Germany is missing a central reporting system for business formations. Additionally, the different start-up reporting systems that do exist exhibit substantial discrepancies in data processing procedures, and therefore also in absolute numbers concerning the overall start-up activity. Chapter 3 is therefore placed in front of Chapter 4 and has the aim to provide a comprehensive review of the most important German start-up reporting systems. The second part of the thesis consists of Chapter 5 which contributes to the literature on determinants of job search behavior of the unemployed individuals by analyzing the effectiveness of internet search with regard to search behavior of unemployed individuals and subsequent job quality. The third and final part of the thesis outlines why the German labor market reacted in a very mild fashion to the Great Recession 2008/09, especially compared to other countries. Chapter 6 describes current economic trends of the labor market in light of general trends in the European Union, and reveals some of the main associated challenges. Thereafter, recent reforms of the main institutional settings of the labor market which influence labor supply are analyzed. Finally, based on the status quo of these institutional settings, the chapter gives a brief overview of strategies to adequately combat the challenges in terms of labor supply and to ensure economic growth in the future.}, language = {en} } @phdthesis{Schernthanner2015, author = {Schernthanner, Harald}, title = {Untersuchungen zur r{\"a}umlichen Analyse und Visualisierung von Mietpreisdaten f{\"u}r Immobilienportale}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-89492}, school = {Universit{\"a}t Potsdam}, pages = {xiii, 136}, year = {2015}, abstract = {Die vorliegende Arbeit verfolgt das Ziel, aus geoinformatischer Sicht eine konzeptionelle Grundlage zur r{\"a}umlichen Optimierung von Immobilienportalen zu schaffen. Die Arbeit geht dabei von zwei Hypothesen aus: 1. Verfahren der r{\"a}umlichen Statistik und des Maschinellen Lernens zur Mietpreissch{\"a}tzung sind den bisher eingesetzten Verfahren der hedonischen Regression {\"u}berlegen und eignen sich zur r{\"a}umlichen Optimierung von Immobilienportalen. 2. Die von Immobilienportalen publizierten webbasierten Mietpreiskarten geben nicht die tats{\"a}chlichen r{\"a}umlichen Verh{\"a}ltnisse auf Immobilienm{\"a}rkten wieder. Alternative webbasierte Darstellungsformen, wie z.B. Gridmaps, sind dem Status Quo der Immobilienpreiskarten von Immobilienportalen {\"u}berlegen und visualisieren die tats{\"a}chlichen r{\"a}umlichen Verh{\"a}ltnisse von Immobilienpreisen zweckm{\"a}ßiger. Beide Thesen k{\"o}nnen bewiesen werden. Es erfolgt zun{\"a}chst eine umfangreiche Erhebung des Forschungsbedarfs mittels Literaturstudien und technologischer Recherche. Zur Beantwortung der Forschungsfragen wird als quantitative Datenbasis ein 74.098 Mietangebote umfassender Datensatz (von Januar 2007 bis September 2013) eines Immobilienportals akquiriert. Dieser reicht jedoch nicht in vollem Umfang zur Beantwortung der Fragestellungen aus. Deshalb f{\"u}hrt der Autor Experteninterviews zur Erhebung einer qualitativen Datenbasis. Deren Analyse ergibt in Kombination mit der Literaturstudie und der technologischen Recherche ein umfassendes, bisher so nicht verf{\"u}gbares Bild. Es stellt den Status Quo der r{\"a}umlichen Sicht sowie der raumanalytischen und geovisuellen Defizite von Immobilienportalen dar. Zur Optimierung der raumanalytischen und geovisuellen Defizite werden forschungsbasierte L{\"o}sungsans{\"a}tze herausgearbeitet und teilimplementiert. Methoden des Maschinellen Lernens und r{\"a}umliche Sch{\"a}tzverfahren werden als Alternativen zu den von Immobilienportalen bisher genutzten „nicht r{\"a}umlichen" Analyseverfahren zur Preismodellierung untersucht. Auf Grundlage eines hierf{\"u}r konzipierten Validierungsrahmens werden diese Methoden f{\"u}r die Nutzung im Kontext von Immobilienportalen adaptiert. Die prototypische Teilimplementierung zeigt die programmiertechnische Umsetzung des Konzeptes auf. Eine umfassende Analyse geeigneter Sekund{\"a}rvariablensets zur Mietpreissch{\"a}tzung liefert als methodisches Resultat, dass Interpolatoren, die Sekund{\"a}rvariablen ben{\"o}tigen (Kriging with external drift, Ordinary Cokriging), kaum zu valideren Mietpreissch{\"a}tzergebnissen gelangen als die Methode des Ordinary Kriging, die keine Sekund{\"a}rvariablen ben{\"o}tigt. Die Methoden Random Forest aus dem Maschinellen Lernen und die Geographisch Gewichtete Regression hingegen bergen großes Potential zur Nutzung der r{\"a}umlichen Mietpreissch{\"a}tzung im Kontext von Immobilien-portalen. Die Forschungsergebnisse der r{\"a}umlichen Preismodellierung werden in die r{\"a}umliche Visualisierung von Mietpreisen transferiert. F{\"u}r die webbasierte Mietpreisdarstellung wird ein Set alternativer Darstellungsmethoden entwickelt, um Mietpreiskarten-Prototypen abzuleiten. Ein methodisches Ergebnis der Entwicklung der Mietpreiskarten-Prototypen ist die Entwicklung eines geeigneten Ansatzes der Losl{\"o}sung des Preisbezugs von fachfremd verwendeten Bezugsgeometrien. Hierf{\"u}r wird vom Autor der Begriff der zonenlosen Preiskarte gepr{\"a}gt. Diese werden mit Methoden des Gridmapping erstellt. Es werden optimale Rasteraufl{\"o}sungen zur Darstellung interpolierter Rastergr{\"o}ßen ermittelt. Zonenlose Preiskarten mit Methoden des Gridmapping, gepaart mit einer optionalen geb{\"a}udescharfen Darstellung in gr{\"o}ßeren Maßst{\"a}ben, sind als Resultate der Forschung die bestm{\"o}gliche, sich an realen Verh{\"a}ltnissen orientierende, r{\"a}umliche Mietpreisdarstellung. Die entstandenen Prototypen sind eine Ann{\"a}herung der wahren Verteilung des Mietpreises im Raum und um einiges sch{\"a}rfer, als die auf der hedonischen Regression basierenden Darstellungen. Somit kann die wahre „Topographie" der Mietpreislandschaft abgebildet werden. Ein Einsatz der Karten f{\"u}r Nutzergruppen wie Makler, Investoren oder Kommunen zur Analyse st{\"a}dtischer Mietm{\"a}rkte ist denkbar. Alle entstandenen Prototypen sind unter der Nutzung von Map APIs umgesetzt. Ein Ergebnis dessen ist, dass Map APIs noch an diversen „Kinderkrankheiten" leiden und derart umgesetzte Mietpreiskarten noch einen weiten Weg vor sich haben, bis sie das Niveau thematischer Karten von Immhof oder Arnberger erreichen. Die konzeptionellen {\"U}berlegungen und Teilimplementierungen m{\"u}nden in drei Prozessketten, die Umsetzungsoptionen f{\"u}r eine r{\"a}umliche Optimierung von Immobilienportalen darstellen. Dabei werden zwei Szenarien f{\"u}r eine r{\"a}umlich optimierte Mietpreissch{\"a}tzung und ein Szenario f{\"u}r eine r{\"a}umlich optimierte Mietpreisdarstellung herausgearbeitet.}, language = {de} } @phdthesis{Schirmack2015, author = {Schirmack, Janosch}, title = {Activity of methanogenic archaea under simulated Mars analog conditions}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-73010}, school = {Universit{\"a}t Potsdam}, pages = {VI, 108}, year = {2015}, abstract = {Assumed comparable environmental conditions of early Mars and early Earth in 3.7 Ga ago - at a time when first fossil records of life on Earth could be found - suggest the possibility of life emerging on both planets in parallel. As conditions changed, the hypothetical life on Mars either became extinct or was able to adapt and might still exist in biological niches. The controversial discussed detection of methane on Mars led to the assumption, that it must have a recent origin - either abiotic through active volcanism or chemical processes, or through biogenic production. Spatial and seasonal variations in the detected methane concentrations and correlations between the presence of water vapor and geological features such as subsurface hydrogen, which are occurring together with locally increased detected concentrations of methane, gave fuel to the hypothesis of a possible biological source of the methane on Mars. Therefore the phylogenetically old methanogenic archaea, which have evolved under early Earth conditions, are often used as model-organisms in astrobiological studies to investigate the potential of life to exist in possible extraterrestrial habitats on our neighboring planet. In this thesis methanogenic archaea originating from two extreme environments on Earth were investigated to test their ability to be active under simulated Mars analog conditions. These extreme environments - the Siberian permafrost-affected soil and the chemoautotrophically based terrestrial ecosystem of Movile cave, Romania - are regarded as analogs for possible Martian (subsurface) habitats. Two novel species of methanogenic archaea isolated from these environments were described within the frame of this thesis. It could be shown that concentrations up to 1 wt\% of Mars regolith analogs added to the growth media had a positive influence on the methane production rates of the tested methanogenic archaea, whereas higher concentrations resulted in decreasing rates. Nevertheless it was possible for the organisms to metabolize when incubated on water-saturated soil matrixes made of Mars regolith analogs without any additional nutrients. Long-term desiccation resistance of more than 400 days was proven with reincubation and indirect counting of viable cells through a combined treatment with propidium monoazide (to inactivate DNA of destroyed cells) and quantitative PCR. Phyllosilicate rich regolith analogs seem to be the best soil mixtures for the tested methanogenic archaea to be active under Mars analog conditions. Furthermore, in a simulation chamber experiment the activity of the permafrost methanogen strain Methanosarcina soligelidi SMA-21 under Mars subsurface analog conditions could be proven. Through real-time wavelength modulation spectroscopy measurements the increase in the methane concentration at temperatures down to -5 °C could be detected. The results presented in this thesis contribute to the understanding of the activity potential of methanogenic archaea under Mars analog conditions and therefore provide insights to the possible habitability of present-day Mars (near) subsurface environments. Thus, it contributes also to the data interpretation of future life detection missions on that planet. For example the ExoMars mission of the European Space Agency (ESA) and Roscosmos which is planned to be launched in 2018 and is aiming to drill in the Martian subsurface.}, language = {en} } @phdthesis{Moellers2015, author = {M{\"o}llers, Norma Tamaria}, title = {Forschen im Kontext von Video{\"u}berwachung}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-77677}, school = {Universit{\"a}t Potsdam}, pages = {viii, 183}, year = {2015}, abstract = {Das Thema der Arbeit sind Formen wissenschaftlicher Wissensproduktion in anwendungsbezogenen Forschungsprojekten und ihre Effekte auf Technisierungsprozesse. Diese untersuche ich am Beispiel eines {\"o}ffentlich gef{\"o}rderten Forschungsprojekts, das ein automatisiertes Video{\"u}berwachungssystem entwickelt. Als anwendungsbezogenes Forschungsprojekt unterliegt die Entwicklung des Video{\"u}berwachungssystems besonderen Rahmenbedingungen: Die Arbeit der Forschergruppe soll erstens auf makrosoziale Kriminalit{\"a}tsprobleme reagieren, zweitens politische Hoffnungen auf einen erfolgreichen Technologietransfer erf{\"u}llen, und drittens dem innerdisziplin{\"a}ren Erkenntnisfortschritt dienen. Daraus ergeben sich alltagspraktische Handlungsprobleme f{\"u}r die Forschergruppe, da sie zwischen heterogenen und m{\"o}glicherweise widerspr{\"u}chlichen Erwartungshaltungen vermitteln muss. Diese Vermittlungsstrategien beeinflussen jedoch in die Entscheidungsprozesse, wie und in welchem Ausmaß {\"U}berwachungsprozesse technisiert werden. Das Promotionsprojekt geht der Frage nach, auf welche Weise die Forschergruppe die Integration der verschiedenen Erwartungshaltungen bew{\"a}ltigt, und welche Auswirkungen diese besondere Form des anwendungsbezogenen Forschens auf die Entwicklung der {\"U}berwachungstechnologie hat. Auf der Grundlage einer ethnographischen Fallstudie beantworte ich die Frage durch den Nachweis, dass die pr{\"a}ferierten L{\"o}sungen der Forschergruppe sich eher an disziplin{\"a}ren Fragestellungen ausrichten als an ihrer Praxistauglichkeit. Dies wird besonders darin sichtbar, dass die urspr{\"u}nglichen Problemstellungen im Verlaufe des Arbeitsprozesses anhand der tats{\"a}chlich verf{\"u}gbaren Instrumente umdefiniert werden. Die daraus resultierenden Konflikte mit den gesellschaftlichen Erwartungshaltungen bew{\"a}ltigt die Forschergruppe, indem sie lernt, die Anwendungsbezogenheit gegen{\"u}ber der F{\"o}rderinstitution sorgf{\"a}ltig zu inszenieren.}, language = {de} } @phdthesis{Maerten2015, author = {Maerten, Lena}, title = {Spectroscopic perspectives on ultrafast coupling phenomena in perovskite oxides}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-77623}, school = {Universit{\"a}t Potsdam}, year = {2015}, abstract = {In this thesis, I study ultrafast dynamics in perovskite oxides using time resolved broadband spectroscopy. I focus on the observation of coherent phonon propagation by time resolved Brillouin scattering: following the excition of metal transducer films with a femtosecond infrared pump pulse, coherent phonon dynamics in the GHz frequency range are triggered. Their propagation is monitored using a delayed white light probe pulse. The technique is illustrated on various thin films and multilayered samples. I apply the technique to investigate the linear and nonlinear acoustic response in bulk SrTiO_3, which displays a ferroelastic phase transition from a cubic to a tetragonal structural phase at T_a=105 K. In the linear regime, I observe a coupling of the observed acoustic phonon mode to the softening optic modes describing the phase transition. In the nonlinear regime, I find a giant slowing down of the sound velocity in the low temperature phase that is only observable for a strain amplitude exceeding the tetragonality of the material. It is attributed to a coupling of the high frequency phonons to ferroelastic domain walls in the material. I propose a new mechanism for the coupling of strain waves to the domain walls that is only effective for high amplitude strain. A detailed study of the phonon attenuation across a wide temperature range shows that the phonon attenuation at low temperatures is influenced by the domain configuration, which is determined by interface strain. Preliminary measurements on magnetic-ferroelectric multilayers reveal that the excitation fluence needs to be carefully controlled when dynamics at phase transitions are studied.}, language = {en} } @phdthesis{Schmidt2015, author = {Schmidt, Andreas}, title = {Charakterisierung der Lipopolysaccharid-Bindungseigenschaften von Adh{\"a}sionsproteinen aus Salmonella-Bakteriophagen}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-79529}, school = {Universit{\"a}t Potsdam}, pages = {VIII, 114}, year = {2015}, abstract = {Die Interaktionen von komplexen Kohlenhydraten und Proteinen sind ubiquit{\"a}r. Sie spielen wichtige Rollen in vielen physiologischen Prozessen wie Zelladh{\"a}sion, Signaltransduktion sowie bei viralen Infektionen. Die molekularen Grundlagen der Interaktion sind noch nicht komplett verstanden. Ein Modellsystem f{\"u}r Kohlenhydrat-Protein-Interaktionen besteht aus Adh{\"a}sionsproteinen (Tailspikes) von Bakteriophagen, die komplexe Kohlenhydrate auf bakteriellen Oberfl{\"a}chen (O-Antigen) erkennen. Das Tailspike-Protein (TSP), das in dieser Arbeit betrachtet wurde, stammt aus dem Bakteriophagen 9NA (9NATSP). 9NATSP weist eine hohe strukturelle Homologie zum gut charakterisierten TSP des Phagen P22 (P22TSP) auf, bei einer niedriger sequenzieller {\"A}hnlichkeit. Die Substratspezifit{\"a}ten beider Tailspikes sind {\"a}hnlich mit Ausnahme der Toleranz gegen{\"u}ber den glucosylierten Formen des O-Antigens. Die Struktur der beiden Tailspikes ist bekannt, sodass sie ein geeignetes System f{\"u}r vergleichende Bindungsstudien darstellen, um die strukturellen Grundlagen f{\"u}r die Unterschiede der Spezifit{\"a}t zu untersuchen. Im Rahmen dieser Arbeit wurde der ELISA-like tailspike adsorption assay (ELITA) etabliert, um Binderpaare aus TSPs und O-Antigen zu identifizieren. Dabei wurden 9NATSP und P22TSP als Sonden eingesetzt, deren Bindung an die intakten, an die Mikrotiterplatte adsorbierten Bakterien getestet wurde. Beim Test einer Sammlung aus 44 Salmonella-St{\"a}mmen wurden St{\"a}mme identifiziert, die bindendes O-Antigen exprimieren. Gleichzeitig wurden Unterschiede in der Bindung der beiden TSPs an Salmonella-St{\"a}mme mit gleichem O-Serotyp beobachtet. Die Ergebnisse der ELITA-Messung wurden qualitativ durch eine FACS-basierte Bindungsmessung best{\"a}tigt. Zus{\"a}tzlich erm{\"o}glichte die FACS-Messung bei St{\"a}mmen, die teilweise modifizierte O-Antigene herstellen, den Anteil an Zellen mit und ohne Modifikation zu erfassen. Die Oberfl{\"a}chenplasmonresonanz (SPR)-basierten Interaktionsmessungen wurden eingesetzt, um Bindungsaffinit{\"a}ten f{\"u}r eine TSP-O-Antigen Kombination zu quantifizieren. Daf{\"u}r wurden zwei Methoden getestet, um die Oligosaccharide auf einem SPR-Chip zu immobilisieren. Zum einen wurden die enzymatisch hergestellten O-Antigenfragmente mit einem bifunktionalen Oxaminadapter derivatisiert, der eine prim{\"a}re Aminogruppe f{\"u}r die Immobilisierung bereitstellt. Ein Versuch, diese Oligosaccharidfragmente zu immobilisieren, war jedoch nicht erfolgreich. Dagegen wurde das nicht derivatisierte Polysaccharid, bestehend aus repetitivem O-Antigen und einem konservierten Kernsaccharid, erfolgreich auf einem SPR-Chip immobilisiert. Die Immobilisierung wurde durch Interaktionsmessungen mit P22TSP best{\"a}tigt. Durch die Immobilisierung des Polysaccharids sind somit quantitative SPR-Bindungsmessungen mit einem polydispersen Interaktionspartner m{\"o}glich. Eine Auswahl von Salmonella-St{\"a}mmen mit einer ausgepr{\"a}gt unterschiedlichen Bindung von 9NATSP und P22TSP im ELITA-Testsystem wurde hinsichtlich der Zusammensetzung des O-Antigens mittels HPLC, Kapillargelelektrophorese und MALDI-MS analysiert. Dabei wurden nicht-st{\"o}chiometrische Modifikationen der O-Antigene wie Acetylierung und Glucosylierung detektiert. Das Ausmaß der Glucosylierung korrelierte negativ mit der Effizienz der Bindung und des Verdaus durch die beiden TSPs, wobei der negative Effekt bei 9NATSP weniger stark ausgepr{\"a}gt war als bei P22TSP. Dies stimmt mit den Literaturdaten zu Infektivit{\"a}tsstudien mit 9NA und P22 {\"u}berein, die mit St{\"a}mmen mit vergleichbaren O-Antigenvarianten durchgef{\"u}hrt wurden. Die Korrelation zwischen der Glucosylierung und Bindungseffizienz konnte strukturell interpretiert werden. Auf Grundlage der O-Antigenanalysen sowie der Ergebnisse der ELITA- und FACS-Bindungstests wurden die Salmonella-St{\"a}mme Brancaster und Kalamu identifiziert, die ann{\"a}hernd quantitativ glucosyliertes O-Antigen exprimieren. Damit eignen sich diese St{\"a}mme f{\"u}r weiterf{\"u}hrende Studien, um die Zusammenh{\"a}nge zwischen der Spezifit{\"a}t und der Organisation der Bindestellen der beiden TSPs zu untersuchen.}, language = {de} } @phdthesis{Kreitsch2015, author = {Kreitsch, Thomas}, title = {Demografie und politischer Reduktionismus}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-80794}, school = {Universit{\"a}t Potsdam}, pages = {246}, year = {2015}, abstract = {Die Dissertation mit dem Thema „Demografie und politischer Reduktionismus - eine Diskursanalyse der Demografiepolitik in Deutschland" kn{\"u}pft an die Debatte um die Demografisierung an, die sich damit besch{\"a}ftigt, dass gesellschaftliche Entwicklungen h{\"a}ufig zu sehr aus einer demografischen Perspektive betrachtet und beschrieben werden. Sie analysiert die zum Teil noch jungen Diskurse, die durch Akteure in Wissenschaft, Politik und Publizistik zu den demografiepolitischen Strategien und Aktivit{\"a}ten der Bundesregierung gef{\"u}hrt werden. Dabei werden Teilbereiche der Gesellschaft, darunter insbesondere die soziale Sicherung, die Generationenbeziehungen sowie die {\"o}konomische Entwicklung und auch r{\"a}umliche Aspekte der Demografie, in den Blick genommen. Es werden ausgew{\"a}hlte Zusammenh{\"a}nge zwischen gesellschaftlichen Entwicklungen und demografischen Ver{\"a}nderungen reflektiert, denen ein kausales Beziehungsverh{\"a}ltnis bescheinigt wird. Es wird aufgezeigt, wo mit Verweis auf die Demografie lediglich Deutungsangebote geschaffen und Kausalbehauptungen aufgestellt werden. Von besonderem Untersuchungsinteresse ist hierbei die Demografie als Argument, um politisches, wirtschaftliches und soziales Handeln zu legitimieren und ein gesellschaftliches Klima der Akzeptanz zu erzeugen. Wo erweist sich die Demografie als ein Spekulationsobjekt - wo ist sie erwiesene, {\"u}berpr{\"u}fbare Kausalit{\"a}t? Und wo ist die Grenze zur Instrumentalisierung der Demografie zu ziehen? Es wird belegt, dass eine Gelegenheitsdemografie vor allem aus drei Gr{\"u}nden praktiziert wird: Sie verschafft organisierten Interessen Geh{\"o}r, sie bietet Orientierung in komplexen Gesellschaften und sie dient als Beurteilungsmaßstab der Bewertung von gesellschaftlichen Entwicklungen. Die aktuelle Konjunktur von Diskursen zum demografischen Wandel sorgt daf{\"u}r, dass die Gelegenheiten, mit Demografie zu argumentieren, immer wieder reproduziert werden. In der Folge werden nicht nur gesellschaftliche Entwicklungen zu sehr auf demografische Komponenten zur{\"u}ckgef{\"u}hrt. Auch das familien-, sozial-, migrations- und wirtschaftspolitische Denken und Handeln wird h{\"a}ufig {\"u}ber das Maß tats{\"a}chlicher Ursache-Wirkungs-Zusammenh{\"a}nge hinaus auf vermeintliche demografische Gesetzm{\"a}ßigkeiten reduziert (Reduktionismus). Die Diskursanalyse der Demografiepolitik in Deutschland will die Bedeutung des demografischen Wandels f{\"u}r die Gesellschaft dabei nicht in Frage stellen. Sie soll f{\"u}r einen kritischeren Umgang mit der Demografie sensibilisieren. Dazu geh{\"o}rt auch, aufzuzeigen, dass die Demografie ein Faktor unter vielen ist.}, language = {de} } @phdthesis{Reim2015, author = {Reim, Tina}, title = {Biogene Aminrezeptoren bei der Honigbiene Apis mellifera}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-80982}, school = {Universit{\"a}t Potsdam}, pages = {viii, 106}, year = {2015}, abstract = {Die Honigbiene Apis mellifera zeigt innerhalb einer Kolonie eine an das Alter gekoppelte Arbeitsteilung. Junge Honigbienen versorgen die Brut (Ammenbienen), w{\"a}hrend {\"a}ltere Honigbienen (Sammlerinnen) außerhalb des Stocks Pollen und Nektar eintragen. Die biogenen Amine Octopamin und Tyramin sind an der Steuerung der Arbeitsteilung maßgeblich beteiligt. Sie interagieren mit Zielzellen {\"u}ber die Bindung an G Protein gekoppelte Rezeptoren. A. mellifera besitzt f{\"u}nf charakterisierte Octopaminrezeptoren (AmOctαR1, AmOctβR1-4), einen charakterisierten Tyraminrezeptor (AmTyr1) sowie einen weiteren putativen Tyraminrezeptor. In der vorliegenden Arbeit wurde dieser putative Aminrezeptor als zweiter Tyraminrezeptor (AmTyr2) identifiziert, lokalisiert und pharmakologisch charakterisiert. Die von der cDNA abgeleitete Aminos{\"a}uresequenz weist strukturelle Eigenschaften und konservierte Motive von G Protein gekoppelten Rezeptoren auf. Phylogenetisch ordnet sich der AmTyr2 Rezeptor bei den Tyramin 2 Rezeptoren anderer Insekten ein. Die funktionelle und pharmakologische Charakterisierung des putativen Tyraminrezeptors erfolgte in modifizierten HEK293 Zellen, die mit der Rezeptor cDNA transfiziert wurden. Die Applikation von Tyramin aktiviert Adenylylcyclasen in diesen Zellen und resultiert in einem Anstieg des intrazellul{\"a}ren cAMP Gehalts. Der AmTyr2 Rezeptor kann durch Tyramin in nanomolaren Konzentrationen halbmaximal aktiviert werden. W{\"a}hrend es sich bei Octopamin um einen wirkungsvollen Agonisten des Rezeptors handelt, sind Mianserin und Yohimbin effektive Antagonisten. F{\"u}r die Lokalisierung des Rezeptorproteins wurde ein polyklonaler Antik{\"o}rper generiert. Eine AmTyr2-{\"a}hnliche Immunreaktivit{\"a}t zeigt sich im Gehirn in den optischen Loben, den Antennalloben, dem Zentralkomplex und in den Kenyon Zellen der Pilzk{\"o}rper. Des Weiteren wurde die Rolle der Octopamin- und Tyraminrezeptoren bei der Steuerung der altersabh{\"a}ngigen Arbeitsteilung analysiert. Die Genexpression des AmOctαR1 in verschiedenen Gehirnteilen korreliert unabh{\"a}ngig vom Alter mit der sozialen Rolle, w{\"a}hrend sich die Genexpression von AmOctβR3/4 und den Tyraminrezeptoren AmTyr1 und AmTyr2 maximal mit dem Alter aber nicht der sozialen Rolle {\"a}ndert. Sammlerinnen weisen einen h{\"o}heren Octopamingehalt im Gesamtgehirn auf als Ammenbienen; bei Tyramin zeigen sich keine Unterschiede. W{\"a}hrend Tyramin offensichtlich keine direkte Rolle spielt, werden durch Octopamin gesteuerte Prozesse der altersabh{\"a}ngigen Arbeitsteilung bei der Honigbiene vermutlich {\"u}ber den AmOctαR1 vermittelt. Die Ergebnisse der vorliegenden Arbeit zeigen die wichtige Rolle von biogenen Aminen, insbesondere Octopamin bei der sozialen Organisation von Insektenstaaten.}, language = {de} } @phdthesis{Mitzscherling2015, author = {Mitzscherling, Steffen}, title = {Polyelectrolyte multilayers for plasmonics and picosecond ultrasonics}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-80833}, school = {Universit{\"a}t Potsdam}, pages = {93}, year = {2015}, abstract = {This thesis investigates the application of polyelectrolyte multilayers in plasmonics and picosecond acoustics. The observed samples were fabricated by the spin-assisted layer-by-layer deposition technique that allowed a precise tuning of layer thickness in the range of few nanometers. The first field of interest deals with the interaction of light-induced localized surface plasmons (LSP) of rod-shaped gold nanoparticles with the particles' environment. The environment consists of an air phase and a phase of polyelectrolytes, whose ratio affects the spectral position of the LSP resonance. Measured UV-VIS spectra showed the shift of the LSP absorption peak as a function of the cover layer thickness of the particles. The data are modeled using an average dielectric function instead of the dielectric functions of air and polyelectrolytes. In addition using a measured dielectric function of the gold nanoparticles, the position of the LSP absorption peak could be simulated with good agreement to the data. The analytic model helps to understand the optical properties of metal nanoparticles in an inhomogeneous environment. The second part of this work discusses the applicability of PAzo/PAH and dye-doped PSS/PAH polyelectrolyte multilayers as transducers to generate hypersound pulses. The generated strain pulses were detected by time-domain Brillouin scattering (TDBS) using a pump-probe laser setup. Transducer layers made of polyelectrolytes were compared qualitatively to common aluminum transducers in terms of measured TDBS signal amplitude, degradation due to laser excitation, and sample preparation. The measurements proved that fast and easy prepared polyelectrolyte transducers provided stronger TDBS signals than the aluminum transducer. AFM topography measurements showed a degradation of the polyelectrolyte structures, especially for the PAzo/PAH sample. To quantify the induced strain, optical barriers were introduced to separate the transducer material from the medium of the hypersound propagation. Difficulties in the sample preparation prohibited a reliable quantification. But the experiments showed that a coating with transparent polyelectrolytes increases the efficiency of aluminum transducers and modifies the excited phonon distribution. The adoption of polyelectrolytes to the scientific field of picosecond acoustics enables a cheap and fast fabrication of transducer layers on most surfaces. In contrast to aluminum layers the polyelectrolytes are transparent over a wide spectral range. Thus, the strain modulation can be probed from surface and back.}, language = {en} } @phdthesis{LeBonhomme2015, author = {Le Bonhomme, Fanny}, title = {Psychiatrie et soci{\´e}t{\´e} en R{\´e}publique D{\´e}mocratique Allemande}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-407164}, school = {Universit{\"a}t Potsdam}, pages = {480}, year = {2015}, abstract = {The patients of the Charité Psychiatry and Neurology clinic (East-Berlin, GDR) during the 1960s are at the center of this study. While taking into account the interpretation provided by the medical discourse, this research aims at reconstructing the experiences and the trajectories of these individuals by inscribing them in the context of the socialist society. Relying on patients' records - these records being the main source of this study - the goal of this research is to reach a better understanding of underlying tensions in the socialist society in relation to the political and ideological context. As these sources show, when they talk to the therapist, patients can speak according to rules which differ from the rules implemented in the socialist society. Because they may contain traces of speeches that would usually be silenced as a result of censorship or self-censorship, or of the unspeakable, shameful or delirious nature of this speech, the patients' records prove to be a valuable source for the historian. From marital tensions caused by ideological disagreements to the inner conflicts of an "ardent marxist", from the pain triggered by the exclusion from the party to the pain caused by the construction of the Berlin Wall, from the "reuniting delirium" to the delusions according to which the West appears as a threat, the individual and singular experiences of the patients allow to reconstruct, through a microhistorical approach, certain tensions inherent to the working of the socialist society.}, language = {fr} } @phdthesis{Vlasov2015, author = {Vlasov, Vladimir}, title = {Synchronization of oscillatory networks in terms of global variables}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-78182}, school = {Universit{\"a}t Potsdam}, pages = {82}, year = {2015}, abstract = {Synchronization of large ensembles of oscillators is an omnipresent phenomenon observed in different fields of science like physics, engineering, life sciences, etc. The most simple setup is that of globally coupled phase oscillators, where all the oscillators contribute to a global field which acts on all oscillators. This formulation of the problem was pioneered by Winfree and Kuramoto. Such a setup gives a possibility for the analysis of these systems in terms of global variables. In this work we describe nontrivial collective dynamics in oscillator populations coupled via mean fields in terms of global variables. We consider problems which cannot be directly reduced to standard Kuramoto and Winfree models. In the first part of the thesis we adopt a method introduced by Watanabe and Strogatz. The main idea is that the system of identical oscillators of particular type can be described by a low-dimensional system of global equations. This approach enables us to perform a complete analytical analysis for a special but vast set of initial conditions. Furthermore, we show how the approach can be expanded for some nonidentical systems. We apply the Watanabe-Strogatz approach to arrays of Josephson junctions and systems of identical phase oscillators with leader-type coupling. In the next parts of the thesis we consider the self-consistent mean-field theory method that can be applied to general nonidentical globally coupled systems of oscillators both with or without noise. For considered systems a regime, where the global field rotates uniformly, is the most important one. With the help of this approach such solutions of the self-consistency equation for an arbitrary distribution of frequencies and coupling parameters can be found analytically in the parametric form, both for noise-free and noisy cases. We apply this method to deterministic Kuramoto-type model with generic coupling and an ensemble of spatially distributed oscillators with leader-type coupling. Furthermore, with the proposed self-consistent approach we fully characterize rotating wave solutions of noisy Kuramoto-type model with generic coupling and an ensemble of noisy oscillators with bi-harmonic coupling. Whenever possible, a complete analysis of global dynamics is performed and compared with direct numerical simulations of large populations.}, language = {en} } @phdthesis{Niedl2015, author = {Niedl, Robert Raimund}, title = {Nichtlineare Kinetik und responsive Hydrogele f{\"u}r papierbasierte Schnelltestanwendungen}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-77735}, school = {Universit{\"a}t Potsdam}, pages = {iv, 128}, year = {2015}, abstract = {Viele klinische Schnelltestsysteme ben{\"o}tigen vorpr{\"a}parierte oder aufgereinigte Analyte mit frisch hergestellten L{\"o}sungen. Fernab standardisierter Laborbedingungen wie z.B. in Entwicklungsl{\"a}ndern oder Krisengebieten sind solche Voraussetzungen oft nur unter einem hohen Aufwand herstellbar. Zus{\"a}tzlich stellt die erforderliche Sensitivit{\"a}t die Entwicklung einfach zu handhabender Testsysteme vor große Herausforderungen. Autokatalytische Reaktionen, die sich mit Hilfe sehr geringer Initiatorkonzentrationen ausl{\"o}sen lassen, k{\"o}nnen hier eine Perspektive f{\"u}r Signalverst{\"a}rkungsprozesse bieten. Aus diesem Grund wird im ersten Teil der vorliegenden Arbeit das Verhalten der autokatalytischen Arsenit-Jodat-Reaktion in einem mikrofluidischen Kanal untersucht. Dabei werden insbesondere die diffusiven und konvektiven Einfl{\"u}sse auf die Reaktionskinetik im Vergleich zu makroskopischen Volumenmengen betrachtet. Im zweiten Teil werden thermoresponsive Hydrogele mit einem kanalstrukturierten Papiernetzwerk zu einem neuartigen, kapillargetriebenen, extern steuerbaren Mikrofluidik-System kombiniert. Das hier vorgestellte Konzept durch Hydrogele ein papierbasiertes LOC-System zu steuern, erm{\"o}glicht zuk{\"u}nftig die Herstellung von komplexeren, steuerbaren Point-Of-Care Testsystemen (POCT). Durch z.B. einen thermischen Stimulus, wird das L{\"o}sungsverhalten eines Hydrogels so ver{\"a}ndert, dass die gespeicherte Fl{\"u}ssigkeit freigesetzt und durch die Kapillarkraft des Papierkanals ins System transportiert wird. Die Eigenschaften dieses Gelnetzwerks k{\"o}nnen dabei so eingestellt werden, dass eine Freisetzung von Fl{\"u}ssigkeiten sogar bei K{\"o}rpertemperatur m{\"o}glich w{\"a}re und damit eine Anwendung g{\"a}nzlich ohne weitere Hilfsmittel denkbar ist. F{\"u}r die Anwendung notwendige Chemikalien oder Enzyme lassen sich hierbei bequem in getrocknetem Zustand im Papiersubstrat vorlagern und bei Bedarf in L{\"o}sung bringen. Im abschließenden dritten Teil der Arbeit wird ein durch Hydrogele betriebener, Antik{\"o}rper-basierter Mikroorganismenschnelltest f{\"u}r Escherichia coli pr{\"a}sentiert. Dar{\"u}ber hinaus wird weiterf{\"u}hrend eine einfache Methode zur Funktionalisierung eines Hydrogels mit Biomolek{\"u}len {\"u}ber EDC/NHS-Kopplung vorgestellt.}, language = {de} } @phdthesis{Metzner2015, author = {Metzner, Paul-Philipp}, title = {Eye movements and brain responses in natural reading}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-82806}, school = {Universit{\"a}t Potsdam}, pages = {xv, 160}, year = {2015}, abstract = {Intuitively, it is clear that neural processes and eye movements in reading are closely connected, but only few studies have investigated both signals simultaneously. Instead, the usual approach is to record them in separate experiments and to subsequently consolidate the results. However, studies using this approach have shown that it is feasible to coregister eye movements and EEG in natural reading and contributed greatly to the understanding of oculomotor processes in reading. The present thesis builds upon that work, assessing to what extent coregistration can be helpful for sentence processing research. In the first study, we explore how well coregistration is suited to study subtle effects common to psycholinguistic experiments by investigating the effect of distance on dependency resolution. The results demonstrate that researchers must improve the signal-to-noise ratio to uncover more subdued effects in coregistration. In the second study, we compare oscillatory responses in different presentation modes. Using robust effects from world knowledge violations, we show that the generation and retrieval of memory traces may differ between natural reading and word-by-word presentation. In the third study, we bridge the gap between our knowledge of behavioral and neural responses to integration difficulties in reading by analyzing the EEG in the context of regressive saccades. We find the P600, a neural indicator of recovery processes, when readers make a regressive saccade in response to integration difficulties. The results in the present thesis demonstrate that coregistration can be a useful tool for the study of sentence processing. However, they also show that it may not be suitable for some questions, especially if they involve subtle effects.}, language = {en} } @phdthesis{Kulikova2015, author = {Kulikova, Galina}, title = {Source parameters of the major historical earthquakes in the Tien-Shan region from the late 19th to the early 20th century}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-88370}, school = {Universit{\"a}t Potsdam}, pages = {xiv, 164}, year = {2015}, abstract = {The Tien-Shan and the neighboring Pamir region are two of the largest mountain belts in the world. Their deformation is dominated by intermontane basins bounded by active thrust and reverse faulting. The Tien-Shan mountain belt is characterized by a very high rate of seismicity along its margins as well as within the Tien-Shan interior. The study area of the here presented thesis, the western part of the Tien-Shan region, is currently seismically active with small and moderate sized earthquakes. However, at the end of the 19th beginning of the 20th century, this region was struck by a remarkable series of large magnitude (M>7) earthquakes, two of them reached magnitude 8. Those large earthquakes occurred prior to the installation of the global digital seismic network and therefore were recorded only by analog seismic instruments. The processing of the analog data brings several difficulties, for example, not always the true parameters of the recording system are known. Another complicated task is the digitization of those records - a very time-consuming and delicate part. Therefore a special set of techniques is developed and modern methods are adapted for the digitized instrumental data analysis. The main goal of the presented thesis is to evaluate the impact of large magnitude M≥7.0 earthquakes, which occurred at the turn of 19th to 20th century in the Tien-Shan region, on the overall regional tectonics. A further objective is to investigate the accuracy of previously estimated source parameters for those earthquakes, which were mainly based on macroseismic observations, and re-estimate them based on the instrumental data. An additional aim of this study is to develop the tools and methods for faster and more productive usage of analog seismic data in modern seismology. In this thesis, the ten strongest and most interesting historical earthquakes in Tien-Shan region are analyzed. The methods and tool for digitizing and processing the analog seismic data are presented. The source parameters of the two major M≥8.0 earthquakes in the Northern Tien-Shan are re-estimated in individual case studies. Those studies are published as peer-reviewed scientific articles in reputed journals. Additionally, the Sarez-Pamir earthquake and its connection with one of the largest landslides in the world, Usoy landslide, is investigated by seismic modeling. These results are also published as a research paper. With the developed techniques, the source parameters of seven more major earthquakes in the region are determined and their impact on the regional tectonics was investigated. The large magnitudes of those earthquakes are confirmed by instrumental data. The focal mechanism of these earthquakes were determined providing evidence for responsible faults or fault systems.}, language = {en} } @phdthesis{Prieske2015, author = {Prieske, Olaf}, title = {The role of surface condition in athletic performance}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-80503}, school = {Universit{\"a}t Potsdam}, pages = {viii, 118, ix}, year = {2015}, abstract = {During the last two decades, instability training devices have become a popular means in athletic training and rehabilitation of mimicking unstable surfaces during movements like vertical jumps. Of note, under unstable conditions, trunk muscles seem to have a stabilizing function during exercise to facilitate the transfer of torques and angular momentum between the lower and upper extremities. The present thesis addresses the acute effects of surface instability on performance during jump-landing tasks. Additionally, the long-term effects (i.e., training) of surface instability were examined with a focus on the role of the trunk in athletic performance/physical fitness. Healthy adolescent, and young adult subjects participated in three cross-sectional and one longitudinal study, respectively. Performance in jump-landing tasks on stable and unstable surfaces was assessed by means of a ground reaction force plate. Trunk muscle strength (TMS) was determined using an isokinetic device or the Bourban TMS test. Physical fitness was quantified by standing long jump, sprint, stand-and-reach, jumping sideways, Emery balance, and Y balance test on stable surfaces. In addition, activity of selected trunk and leg muscles and lower limb kinematics were recorded during jump-landing tasks. When performing jump-landing tasks on unstable compared to stable surfaces, jump performance and leg muscle activity were significantly lower. Moreover, significantly smaller knee flexion angles and higher knee valgus angles were observed when jumping and landing on unstable compared to stable conditions and in women compared to men. Significant but small associations were found between behavioral and neuromuscular data, irrespective of surface condition. Core strength training on stable as well as on unstable surfaces significantly improved TMS, balance and coordination. The findings of the present thesis imply that stable rather than unstable surfaces provide sufficient training stimuli during jump exercises (i.e., plyometrics). Additionally, knee motion strategy during plyometrics appears to be modified by surface instability and sex. Of note, irrespective of surface condition, trunk muscles only play a minor role for leg muscle performance/activity during jump exercises. Moreover, when implemented in strength training programs (i.e., core strength training), there is no advantage in using instability training devices compared to stable surfaces in terms of enhancement of athletic performance.}, language = {en} } @phdthesis{Golle2015, author = {Golle, Kathleen}, title = {Physical fitness in school-aged children}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-85949}, school = {Universit{\"a}t Potsdam}, pages = {xi, 147, xii}, year = {2015}, abstract = {Physical fitness is an important marker of health that enables people to carry out activities of daily living with vigour and alertness but without undue fatigue and with sufficient reserve to enjoy active leisure pursuits and to meet unforeseen emergencies. Especially, due to scientific findings that the onset of civilization diseases (e.g., obesity, cardiovascular disease) begins in childhood and that physical fitness tracks (at least) into young adulthood, the regular monitoring and promotion of physical fitness in children is risen up to a public health issue. In relation to the evaluation of a child's physical fitness over time (i.e., development) the use of longitudinally-based percentile values is of particular interest due to their underlined dedication of true physical fitness development within subjects (i.e., individual changes in timing and tempo of growth and maturation). Besides its genetic determination (e.g., sex, body height), physical fitness is influenced by factors that refer to children's environment and behaviour. For instance, disparities in physical fitness according to children's living area are frequently reported concerning the fact that living in rural areas as compared to urban areas seems to be more favourable for children's physical fitness. In addition, cross-sectional studies found higher fitness values in children participating in sports clubs as compared to non-participants. However, up to date, the observed associations between both (i.e., living area and sports club participating) and children's physical fitness are unresolved concerning a long-term effect. In addition, social inequality as determined by the socioeconomic status (SES) extends through many areas of children's life. While evidence indicates that the SES is inversely related to various indices of child's daily life and behaviour like educational success, nutritional habits, and sedentary- and physical activity behaviour, a potential relationship between child's physical fitness and the SES is hardly investigated and indicated inconsistent results. The present thesis addressed three objectives: (1) to generate physical fitness percentiles for 9- to 12- year-old boys and girls using a longitudinal approach and to analyse the age- and sex-specific development of physical fitness, (2) to investigate the long-term effect of living area and sports club participation on physical fitness in third- to sixth-grade primary school students, and (3) to examine associations between the SES and physical fitness in a large and representative (i.e., for a German federal state) sample of third grade primary school students. Methods (i/ii) Healthy third graders were followed over four consecutive years (up to grade 6), including annually assessment of physical fitness and parental questionnaire (i.e., status of sports club participation and living area). Six tests were conducted to estimate various components of physical fitness: speed (50-m sprint test), upper body muscular power (1-kg ball push test), lower body muscular power (triple hop test), flexibility (stand-and-reach test), agility (star agility run test), and cardiorespiratory fitness (CRF) (9-min run test). (iii) Within a cross-sectional study (i.e., third objective), physical fitness of third graders was assessed by six physical fitness tests including: speed (20-m sprint test), upper body muscular power (1-kg ball push test), lower body muscular power (standing long jump [SLJ] test), flexibility (stand-and-reach test), agility (star agility run test), and CRF (6-min run test). By means of questionnaire, students reported their status of organized sports participation (OSP). Results (i) With respect to percentiles of physical fitness development, test performances increased in boys and girls from age 9 to 12, except for males' flexibility (i.e., stable performance over time). Girls revealed significantly better performance in flexibility, whereas boys scored significantly higher in the remaining physical fitness tests. In girls as compared to boys, physical fitness development was slightly faster for upper body muscular power but substantially faster for flexibility. Generated physical fitness percentile curves indicated a timed and capacity-specific physical fitness development (curvilinear) for upper body muscular power, agility, and CRF. (ii) Concerning the effect of living area and sports club participation on physical fitness development, children living in urban areas showed a significantly faster performance development in physical fitness components of upper and lower body muscular power as compared to peers from rural areas. The same direction was noted as a trend in CRF. Additionally, children that regularly participated in a sports club, when compared to those that not continuously participated in a sports club demonstrated a significantly faster performance development in lower body muscular power. A trend of faster performance development in sports club participants occurred in CRF too. (iii) Regarding the association of SES with physical fitness, the percentage of third graders that achieved a high physical fitness level in lower body muscular power and CRF was significantly higher in students attending schools in communities with high SES as compared to middle and low SES, irrespective of sex. Similar, students from the high SES-group performed significantly better in lower body muscular power and CRF than students from the middle and/or the low SES-group. Conclusion (i) The generated percentile values provide an objective tool to estimate childrenʼs physical fitness within the frame of physical education (e.g., age- and sex-specific grading of motor performance) and further to detect children with specific fitness characteristics (low fit or high fit) that may be indicative for the necessity of preventive health promotion or long term athlete development. (ii) It is essential to consider variables of different domains (e.g., environment and behavior) in order to improve knowledge of potential factors which influence physical fitness during childhood. In this regard, the present thesis provide a first input to clarify the causality of living area and sports club participation on physical fitness development in school-aged children. Living in urban areas as well as a regular participation in sports clubs positively affected children´s physical fitness development (i.e., muscular power and CRF). Herein, sports club participation seems to be a key factor within the relationship between living area and physical fitness. (iii) The findings of the present thesis imply that attending schools in communities with high SES refers to better performance in specific physical fitness test items (i.e., muscular power, CRF) in third graders. Extra-curricular physical education classes may represent an important equalizing factor for physical activity opportunities in children of different SES backgrounds. In regard to strong evidence of a positive relationship between physical fitness - in particular muscular fitness/ CRF - and health, more emphasis should be laid on establishing sports clubs and extra-curricular physical education classes as an easy and attractive means to promote fitness-, and hence health- enhancing daily physical activity for all children (i.e. public health approach).}, language = {en} } @phdthesis{Schroeder2015, author = {Schr{\"o}der, Christine}, title = {Identifizierung und Charakterisierung der Isoflavon-umsetzenden Enzyme aus dem humanen Darmbakterium Slackia isoflavoniconvertens}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-80065}, school = {Universit{\"a}t Potsdam}, pages = {X, 129}, year = {2015}, abstract = {Aufgrund ihrer potenziell gesundheitsf{\"o}rdernden Wirkung sind die polyphenolischen Isoflavone f{\"u}r die menschliche Ern{\"a}hrung von großem Interesse. Eine Vielzahl an experimentellen und epidemiologischen Studien zeigen f{\"u}r die in Soja enthaltenen Isoflavone Daidzein und Genistein eine pr{\"a}ventive Wirkung bez{\"u}glich hormon-abh{\"a}ngiger und altersbedingter Erkrankungen, wie Brust- und Prostatakrebs, Osteoporose, Herz-Kreislauf-Erkrankungen sowie des menopausalen Syndroms. Die Metabolisierung und Bioaktivierung dieser sekund{\"a}ren Pflanzenstoffe durch die humane intestinale Darmmikrobiota ist individuell unterschiedlich. Nur in einem geringen Teil der westlichen Bev{\"o}lkerung wird der Daidzein-Metabolit Equol durch spezifische Darmbakterien gebildet. Ein isoliertes Equol-produzierendes Bakterium des menschlichen Darmtrakts ist Slackia isoflavoniconvertens. Anhand dieser Spezies sollten die bislang unbekannten, an der Umsetzung von Daidzein und Genistein beteiligten Enzyme identifiziert und charakterisiert werden. Fermentationsexperimente mit S. isoflavoniconvertens zeigten, dass die Gene der Daidzein und Genistein-umsetzenden Enzyme nicht konstitutiv exprimiert werden, sondern induziert werden m{\"u}ssen. Mit Hilfe der zweidimensionalen differentiellen Gelelektrophorese wurden sechs Proteine detektiert, welche in einer S. isoflavoniconvertens-Kultur in Anwesenheit von Daidzein induziert wurden. Auf Grundlage einzelner Peptidsequenzen erfolgte die Sequenzierung eines Genkomplexes mit den in gleicher Orientierung angeordneten Genen der durch Daidzein induzierten Proteine. Sequenzvergleiche identifizierten zudem {\"a}quivalente Genprodukte zu den Proteinen von S. isoflavoniconvertens in anderen Equolproduzierenden Bakterien. Nach der heterologen Expression in Escherichia coli wurden drei dieser Gene durch enzymatische Aktivit{\"a}tstests als Daidzein-Reduktase (DZNR), Dihydrodaidzein-Reduktase (DHDR) und Tetrahydrodaidzein-Reduktase (THDR) identifiziert. Die Kombination der E. coli-Zellextrakte f{\"u}hrte zur vollst{\"a}ndigen Umsetzung von Daidzein {\"u}ber Dihydrodaidzein zu Equol. Neben Daidzein setzte die DZNR auch Genistein zu Dihydrogenistein um. Dies erfolgte mit einer gr{\"o}ßeren Umsatzgeschwindigkeit im Vergleich zur Reduktion von Daidzein zu Dihydrodaidzein. Enzymatische Aktivit{\"a}tstests mit dem Zellextrakt von S. isoflavoniconvertens zeigten ebenfalls eine schnellere Umsetzung von Genistein. Die Kombination der rekombinanten DHDR und THDR f{\"u}hrte zur Umsetzung von Dihydrodaidzein zu Equol. Der korrespondierende Metabolit 5-Hydroxyequol konnte als Endprodukt des Genistein-Metabolismus nicht detektiert werden. Zur Reinigung der drei identifizierten Reduktasen wurden diese genetisch an ein Strep-tag fusioniert und mittels Affinit{\"a}tschromatographie gereinigt. Die {\"u}brigen durch Daidzein induzierten Proteine IfcA, IfcBC und IfcE wurden ebenfalls in E. coli exprimiert und als Strep-Fusionsproteine gereinigt. Vergleichende Aktivit{\"a}tstests identifizierten das induzierte Protein IfcA als Dihydrodaidzein-Racemase. Diese katalysierte die Umsetzung des (R)- und (S)-Enantiomers von Dihydrodaidzein und Dihydrogenistein zum korrespondierenden Racemat. Neben dem Elektronentransfer-Flavoprotein IfcBC wurden auch die THDR, DZNR und IfcE als FAD-haltige Flavoproteine identifiziert. Zudem handelte es sich bei IfcE um ein Eisen-Schwefel-Protein. Nach Induktion der f{\"u}r die Daidzein-Umsetzung kodierenden Gene wurden mehrere verschieden lange mRNA-Transkripte gebildet. Dies zeigte, dass die Transkription des durch Daidzein induzierten Genkomplexes in S. isoflavoniconvertens nicht in Form eines einzelnen Operonsystems erfolgte. Auf Grundlage der identifizierten Daidzein-umsetzenden Enzyme kann der Mechanismus der bakteriellen Umsetzung von Isoflavonen durch S. isoflavoniconvertens eingehend erforscht werden. Die ermittelten Gensequenzen der durch Daidzein induzierten Proteine sowie die korrespondierenden Gene weiterer Equol-produzierender Bakterien bieten zudem die M{\"o}glichkeit der mikrobiellen Metagenomanalyse im humanen Darmtrakt.}, language = {de} } @phdthesis{Jaeger2015, author = {J{\"a}ger, Lena Ann}, title = {Working memory and prediction in human sentence parsing}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-82517}, school = {Universit{\"a}t Potsdam}, pages = {xi, 144}, year = {2015}, abstract = {This dissertation investigates the working memory mechanism subserving human sentence processing and its relative contribution to processing difficulty as compared to syntactic prediction. Within the last decades, evidence for a content-addressable memory system underlying human cognition in general has accumulated (e.g., Anderson et al., 2004). In sentence processing research, it has been proposed that this general content-addressable architecture is also used for language processing (e.g., McElree, 2000). Although there is a growing body of evidence from various kinds of linguistic dependencies that is consistent with a general content-addressable memory subserving sentence processing (e.g., McElree et al., 2003; VanDyke2006), the case of reflexive-antecedent dependencies has challenged this view. It has been proposed that in the processing of reflexive-antecedent dependencies, a syntactic-structure based memory access is used rather than cue-based retrieval within a content-addressable framework (e.g., Sturt, 2003). Two eye-tracking experiments on Chinese reflexives were designed to tease apart accounts assuming a syntactic-structure based memory access mechanism from cue-based retrieval (implemented in ACT-R as proposed by Lewis and Vasishth (2005). In both experiments, interference effects were observed from noun phrases which syntactically do not qualify as the reflexive's antecedent but match the animacy requirement the reflexive imposes on its antecedent. These results are interpreted as evidence against a purely syntactic-structure based memory access. However, the exact pattern of effects observed in the data is only partially compatible with the Lewis and Vasishth cue-based parsing model. Therefore, an extension of the Lewis and Vasishth model is proposed. Two principles are added to the original model, namely 'cue confusion' and 'distractor prominence'. Although interference effects are generally interpreted in favor of a content-addressable memory architecture, an alternative explanation for interference effects in reflexive processing has been proposed which, crucially, might reconcile interference effects with a structure-based account. It has been argued that interference effects do not necessarily reflect cue-based retrieval interference in a content-addressable memory but might equally well be accounted for by interference effects which have already occurred at the moment of encoding the antecedent in memory (Dillon, 2011). Three experiments (eye-tracking and self-paced reading) on German reflexives and Swedish possessives were designed to tease apart cue-based retrieval interference from encoding interference. The results of all three experiments suggest that there is no evidence that encoding interference affects the retrieval of a reflexive's antecedent. Taken together, these findings suggest that the processing of reflexives can be explained with the same cue-based retrieval mechanism that has been invoked to explain syntactic dependency resolution in a range of other structures. This supports the view that the language processing system is located within a general cognitive architecture, with a general-purpose content-addressable working memory system operating on linguistic expressions. Finally, two experiments (self-paced reading and eye-tracking) using Chinese relative clauses were conducted to determine the relative contribution to sentence processing difficulty of working-memory processes as compared to syntactic prediction during incremental parsing. Chinese has the cross-linguistically rare property of being a language with subject-verb-object word order and pre-nominal relative clauses. This property leads to opposing predictions of expectation-based accounts and memory-based accounts with respect to the relative processing difficulty of subject vs. object relatives. Previous studies showed contradictory results, which has been attributed to different kinds local ambiguities confounding the materials (Lin and Bever, 2011). The two experiments presented are the first to compare Chinese relatives clauses in syntactically unambiguous contexts. The results of both experiments were consistent with the predictions of the expectation-based account of sentence processing but not with the memory-based account. From these findings, I conclude that any theory of human sentence processing needs to take into account the power of predictive processes unfolding in the human mind.}, language = {en} } @phdthesis{Gerth2015, author = {Gerth, Sabrina}, title = {Memory limitations in sentence comprehension}, isbn = {978-3-86956-321-3}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-71554}, school = {Universit{\"a}t Potsdam}, pages = {xviii, 157}, year = {2015}, abstract = {This dissertation addresses the question of how linguistic structures can be represented in working memory. We propose a memory-based computational model that derives offline and online complexity profiles in terms of a top-down parser for minimalist grammars (Stabler, 2011). The complexity metric reflects the amount of time an item is stored in memory. The presented architecture links grammatical representations stored in memory directly to the cognitive behavior by deriving predictions about sentence processing difficulty. Results from five different sentence comprehension experiments were used to evaluate the model's assumptions about memory limitations. The predictions of the complexity metric were compared to the locality (integration and storage) cost metric of Dependency Locality Theory (Gibson, 2000). Both metrics make comparable offline and online predictions for four of the five phenomena. The key difference between the two metrics is that the proposed complexity metric accounts for the structural complexity of intervening material. In contrast, DLT's integration cost metric considers the number of discourse referents, not the syntactic structural complexity. We conclude that the syntactic analysis plays a significant role in memory requirements of parsing. An incremental top-down parser based on a grammar formalism easily computes offline and online complexity profiles, which can be used to derive predictions about sentence processing difficulty.}, language = {en} } @phdthesis{Reimer2015, author = {Reimer, Anna Maria}, title = {The poetics of the real and aesthetics of the reel}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-95660}, school = {Universit{\"a}t Potsdam}, pages = {298}, year = {2015}, abstract = {The dissertation proposes that the spread of photography and popular cinema in 19th- and 20th-century-India have shaped an aesthetic and affective code integral to the reading and interpretation of Indian English novels, particularly when they address photography and/or cinema film, as in the case of the four corpus texts. In analyzing the nexus between 'real' and 'reel', the dissertation shows how the texts address the reader as media consumer and virtual image projector. Furthermore, the study discusses the Indian English novel against the backdrop of the cultural and medial transformations of the 20th century to elaborate how these influenced the novel's aesthetics. Drawing upon reception aesthetics, the author devises the concept of the 'implied spectator' to analyze the aesthetic impact of the novels' images as visual textures. No God in Sight (2005) by Altaf Tyrewala comprises of a string of 41 interior monologues, loosely connected through their narrators' random encounters in Mumbai in the year 2000. Although marked by continuous perspective shifts, the text creates a sensation of acute immediacy. Here, the reader is addressed as implied spectator and is sutured into the narrated world like a film spectator ― an effect created through the use of continuity editing as a narrative technique. Similarly, Ruchir Joshi's The Last Jet Engine Laugh (2002) coll(oc)ates disparate narrative perspectives and explores photography as an artistic practice, historiographic recorder and epistemological tool. The narrative appears guided by the random viewing of old photographs by the protagonist and primary narrator, the photographer Paresh Bhatt. However, it is the photographic negative and the practice of superimposition that render this string of episodes and different perspectives narratively consequential and cosmologically meaningful. Photography thus marks the perfect symbiosis of autobiography and historiography. Tabish Khair's Filming. A Love Story (2007) immerses readers in the cine-aesthetic of 1930s and 40s Bombay film, the era in which the embedded plot is set. Plotline, central scenes and characters evoke the key films of Indian cinema history such as Satyajit Ray's "Pather Panchali" or Raj Kapoor's "Awara". Ultimately, the text written as film dissolves the boundary between fiction and (narrated) reality, reel and real, thereby showing that the images of individual memory are inextricably intertwined with and shaped by collective memory. Ultimately, the reconstruction of the past as and through film(s) conquers trauma and endows the Partition of India as a historic experience of brutal contingency with meaning. The Bioscope Man (Indrajit Hazra, 2008) is a picaresque narrative set in Calcutta - India's cultural capital and birthplace of Indian cinema at the beginning of the 20th century. The autodiegetic narrator Abani Chatterjee relates his rise and fall as silent film star, alternating between the modes of tell and show. He is both autodiegetic narrator and spectator or perceiving consciousness, seeing himself in his manifold screen roles. Beyond his film roles however, the narrator remains a void. The marked psychoanalytical symbolism of the text is accentuated by repeated invocations of dark caves and the laterna magica. Here too, 'reel life' mirrors and foreshadows real life as Indian and Bengali history again interlace with private history. Abani Chatterjee thus emerges as a quintessentially modern man of no qualities who assumes definitive shape only in the lost reels of the films he starred in. The final chapter argues that the static images and visual frames forwarded in the texts observe an integral psychological function: Premised upon linear perspective they imply a singular, static subjectivity appealing to the postmodern subject. In the corpus texts, the rise of digital technology in the 1990s thus appears not so much to have displaced older image repertories, practices and media techniques, than it has lent them greater visibility and appeal. Moreover, bricolage and pastiche emerge as cultural techniques which marked modernity from its inception. What the novels thus perpetuate is a media archeology not entirely servant to the poetics of the real. The permeable subject and the notion of the gaze as an active exchange as encapsulated in the concept of darshan - ideas informing all four texts - bespeak the resilience of a mythical universe continually re-instantiated in new technologies and uses. Eventually, the novels convey a sense of subalternity to a substantially Hindu nationalist history and historiography, the centrifugal force of which developed in the twentieth century and continues into the present.}, language = {en} } @phdthesis{Boettle2015, author = {B{\"o}ttle, Markus}, title = {Coastal floods in view of sea level rise}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-91074}, school = {Universit{\"a}t Potsdam}, pages = {xiii, 111}, year = {2015}, abstract = {The sea level rise induced intensification of coastal floods is a serious threat to many regions in proximity to the ocean. Although severe flood events are rare they can entail enormous damage costs, especially when built-up areas are inundated. Fortunately, the mean sea level advances slowly and there is enough time for society to adapt to the changing environment. Most commonly, this is achieved by the construction or reinforcement of flood defence measures such as dykes or sea walls but also land use and disaster management are widely discussed options. Overall, albeit the projection of sea level rise impacts and the elaboration of adequate response strategies is amongst the most prominent topics in climate impact research, global damage estimates are vague and mostly rely on the same assessment models. The thesis at hand contributes to this issue by presenting a distinctive approach which facilitates large scale assessments as well as the comparability of results across regions. Moreover, we aim to improve the general understanding of the interplay between mean sea level rise, adaptation, and coastal flood damage. Our undertaking is based on two basic building blocks. Firstly, we make use of macroscopic flood-damage functions, i.e. damage functions that provide the total monetary damage within a delineated region (e.g. a city) caused by a flood of certain magnitude. After introducing a systematic methodology for the automatised derivation of such functions, we apply it to a total of 140 European cities and obtain a large set of damage curves utilisable for individual as well as comparative damage assessments. By scrutinising the resulting curves, we are further able to characterise the slope of the damage functions by means of a functional model. The proposed function has in general a sigmoidal shape but exhibits a power law increase for the relevant range of flood levels and we detect an average exponent of 3.4 for the considered cities. This finding represents an essential input for subsequent elaborations on the general interrelations of involved quantities. The second basic element of this work is extreme value theory which is employed to characterise the occurrence of flood events and in conjunction with a damage function provides the probability distribution of the annual damage in the area under study. The resulting approach is highly flexible as it assumes non-stationarity in all relevant parameters and can be easily applied to arbitrary regions, sea level, and adaptation scenarios. For instance, we find a doubling of expected flood damage in the city of Copenhagen for a rise in mean sea levels of only 11 cm. By following more general considerations, we succeed in deducing surprisingly simple functional expressions to describe the damage behaviour in a given region for varying mean sea levels, changing storm intensities, and supposed protection levels. We are thus able to project future flood damage by means of a reduced set of parameters, namely the aforementioned damage function exponent and the extreme value parameters. Similar examinations are carried out to quantify the aleatory uncertainty involved in these projections. In this regard, a decrease of (relative) uncertainty with rising mean sea levels is detected. Beyond that, we demonstrate how potential adaptation measures can be assessed in terms of a Cost-Benefit Analysis. This is exemplified by the Danish case study of Kalundborg, where amortisation times for a planned investment are estimated for several sea level scenarios and discount rates.}, language = {en} } @phdthesis{Pradhan2015, author = {Pradhan, Prajal}, title = {Food demand and supply under global change}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-77849}, school = {Universit{\"a}t Potsdam}, pages = {xvi, 141}, year = {2015}, abstract = {Anthropogenic activities have transformed the Earth's environment, not only on local level, but on the planetary-scale causing global change. Besides industrialization, agriculture is a major driver of global change. This change in turn impairs the agriculture sector, reducing crop yields namely due to soil degradation, water scarcity, and climate change. However, this is a more complex issue than it appears. Crop yields can be increased by use of agrochemicals and fertilizers which are mainly produced by fossil energy. This is important to meet the increasing food demand driven by global demographic change, which is further accelerated by changes in regional lifestyles. In this dissertation, we attempt to address this complex problem exploring agricultural potential globally but on a local scale. For this, we considered the influence of lifestyle changes (dietary patterns) as well as technological progress and their effects on climate change, mainly greenhouse gas (GHG) emissions. Furthermore, we examined options for optimizing crop yields in the current cultivated land with the current cropping patterns by closing yield gaps. Using this, we investigated in a five-minute resolution the extent to which food demand can be met locally, and/or by regional and/or global trade. Globally, food consumption habits are shifting towards calorie rich diets. Due to dietary shifts combined with population growth, the global food demand is expected to increase by 60-110\% between 2005 and 2050. Hence, one of the challenges to global sustainability is to meet the growing food demand, while at the same time, reducing agricultural inputs and environmental consequences. In order to address the above problem, we used several freely available datasets and applied multiple interconnected analytical approaches that include artificial neural network, scenario analysis, data aggregation and harmonization, downscaling algorithm, and cross-scale analysis. Globally, we identified sixteen dietary patterns between 1961 and 2007 with food intakes ranging from 1,870 to 3,400 kcal/cap/day. These dietary patterns also reflected changing dietary habits to meat rich diets worldwide. Due to the large share of animal products, very high calorie diets that are common in the developed world, exhibit high total per capita emissions of 3.7-6.1 kg CO2eq./day. This is higher than total per capita emissions of 1.4-4.5 kg CO2eq./day associated with low and moderate calorie diets that are common in developing countries. Currently, 40\% of the global crop calories are fed to livestock and the feed calorie use is four times the produced animal calories. However, these values vary from less than 1 kcal to greater 10 kcal around the world. On the local and national scale, we found that the local and national food production could meet demand of 1.9 and 4.4 billion people in 2000, respectively. However, 1 billion people from Asia and Africa require intercontinental agricultural trade to meet their food demand. Nevertheless, these regions can become food self-sufficient by closing yield gaps that require location specific inputs and agricultural management strategies. Such strategies include: fertilizers, pesticides, soil and land improvement, management targeted on mitigating climate induced yield variability, and improving market accessibility. However, closing yield gaps in particular requires global N-fertilizer application to increase by 45-73\%, P2O5 by 22-46\%, and K2O by 2-3 times compare to 2010. Considering population growth, we found that the global agricultural GHG emissions will approach 7 Gt CO2eq./yr by 2050, while the global livestock feed demand will remain similar to 2000. This changes tremendously when diet shifts are also taken into account, resulting in GHG emissions of 20 Gt CO2eq./yr and an increase of 1.3 times in the crop-based feed demand between 2000 and 2050. However, when population growth, diet shifts, and technological progress by 2050 were considered, GHG emissions can be reduced to 14 Gt CO2eq./yr and the feed demand to nearly 1.8 times compare to that in 2000. Additionally, our findings shows that based on the progress made in closing yield gaps, the number of people depending on international trade can vary between 1.5 and 6 billion by 2050. In medium term, this requires additional fossil energy. Furthermore, climate change, affecting crop yields, will increase the need for international agricultural trade by 4\% to 16\%. In summary, three general conclusions are drawn from this dissertation. First, changing dietary patterns will significantly increase crop demand, agricultural GHG emissions, and international food trade in the future when compared to population growth only. Second, such increments can be reduced by technology transfer and technological progress that will enhance crop yields, decrease agricultural emission intensities, and increase livestock feed conversion efficiencies. Moreover, international trade dependency can be lowered by consuming local and regional food products, by producing diverse types of food, and by closing yield gaps. Third, location specific inputs and management options are required to close yield gaps. Sustainability of such inputs and management largely depends on which options are chosen and how they are implemented. However, while every cultivated land may not need to attain its potential yields to enable food security, closing yield gaps only may not be enough to achieve food self-sufficiency in some regions. Hence, a combination of sustainable implementations of agricultural intensification, expansion, and trade as well as shifting dietary habits towards a lower share of animal products is required to feed the growing population.}, language = {en} } @phdthesis{Rohrmann2015, author = {Rohrmann, Alexander}, title = {The role of wind and water in shaping earth's plateaus}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-77938}, school = {Universit{\"a}t Potsdam}, pages = {XXV, 157}, year = {2015}, abstract = {The overarching goal of this dissertation is to provide a better understanding of the role of wind and water in shaping Earth's Cenozoic orogenic plateaus - prominent high-elevation, low relief sectors in the interior of Cenozoic mountain belts. In particular, the feedbacks between surface uplift, the build-up of topography and ensuing changes in precipitation, erosion, and vegetation patterns are addressed in light of past and future climate change. Regionally, the study focuses on the two world's largest plateaus, the Altiplano-Puna Plateau of the Andes and Tibetan Plateau, both characterized by average elevations of >4 km. Both plateaus feature high, deeply incised flanks with pronounced gradients in rainfall, vegetation, hydrology, and surface processes. These characteristics are rooted in the role of plateaus to act as efficient orographic barriers to rainfall and to force changes in atmospheric flow. The thesis examines the complex topics of tectonic and climatic forcing of the surface-process regime on three different spatial and temporal scales: (1) bedrock wind-erosion rates are quantified in the arid Qaidam Basin of NW Tibet over millennial timescales using cosmogenic radionuclide dating; (2) present-day stable isotope composition in rainfall is examined across the south-central Andes in three transects between 22° S and 28° S; these data are modeled and assessed with remotely sensed rainfall data of the Tropical Rainfall Measuring Mission and the Moderate Resolution Imaging Spectroradiometer; (3) finally, a 2.5-km-long Mio-Pliocene sedimentary record of the intermontane Angastaco Basin (25°45' S, 66°00' W) is presented in the context of hydrogen and carbon compositions of molecular lipid biomarker, and oxygen and carbon isotopes obtained from pedogenic carbonates; these records are compared to other environmental proxies, including hydrated volcanic glass shards from volcanic ashes intercalated in the sedimentary strata. There are few quantitative estimates of eolian bedrock-removal rates from arid, low relief landscapes. Wind-erosion rates from the western Qaidam Basin based on cosmogenic 10Be measurements document erosion rates between 0.05 to 0.4 mm/yr. This finding indicates that in arid environments with strong winds, hyperaridity, exposure of friable strata, and ongoing rock deformation and uplift, wind erosion can outpace fluvial erosion. Large eroded sediment volumes within the Qaidam Basin and coeval dust deposition on the Chinese Loess plateau, exemplify the importance of dust production within arid plateau environments for marine and terrestrial depositional processes, but also health issues and fertilization of soils. In the south-central Andes, the analysis of 234 stream-water samples for oxygen and hydrogen reveals that areas experiencing deep convective storms do not show the commonly observed patterns of isotopic fractionation and the expected co-varying relationships between oxygen and hydrogen with increasing elevation. These convective storms are formed over semi-arid intermontane basins in the transition between the broken foreland of the Sierras Pampeanas, the Eastern Cordillera, and the Puna Plateau in the interior of the orogen. Here, convective rainfall dominates the precipitation budget and no systematic stable isotope-elevation relationship exists. Regions to the north, in the transition between the broken foreland and the Subandean foreland fold-and-thrust belt, the impact of convection is subdued, with lower degrees of storminess and a stronger expected isotope-elevation relationship. This finding of present-day fractionation trends of meteoric water is of great importance for paleoenvironmental studies in attempts to use stable isotope relationships in the reconstruction of paleoelevations. The third part of the thesis focuses on the paleohydrological characteristics of the Mio-Pliocene (10-2 Ma) Angastaco Basin sedimentary record, which reveals far-reaching environmental changes during Andean uplift and orographic barrier formation. A precipitation- evapotranspiration record identifies the onset of a precipitation regime related to the South American Low Level Jet at this latitude after 9 Ma. Humid foreland conditions existed until 7 Ma, followed by orographic barrier uplift to the east of the present-day Angastaco Basin. This was superseded by rapid (~0.5 Myr) aridification in an intermontane basin, highlighting the effects of eastward-directed deformation. A transition in vegetation cover from a humid C3 forest ecosystem to semi-arid C4-dominated vegetation was coeval with continued basin uplift to modern elevations.}, language = {en} } @phdthesis{TorresAcosta2015, author = {Torres Acosta, Ver{\´o}nica}, title = {Denudation processes in a tectonically active rift on different time scales}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-84534}, school = {Universit{\"a}t Potsdam}, pages = {xv, ix, 183}, year = {2015}, abstract = {Continental rifts are excellent regions where the interplay between extension, the build-up of topography, erosion and sedimentation can be evaluated in the context of landscape evolution. Rift basins also constitute important archives that potentially record the evolution and migration of species and the change of sedimentary conditions as a result of climatic change. Finally, rifts have increasingly become targets of resource exploration, such as hydrocarbons or geothermal systems. The study of extensional processes and the factors that further modify the mainly climate-driven surface process regime helps to identify changes in past and present tectonic and geomorphic processes that are ultimately recorded in rift landscapes. The Cenozoic East African Rift System (EARS) is an exemplary continental rift system and ideal natural laboratory to observe such interactions. The eastern and western branches of the EARS constitute first-order tectonic and topographic features in East Africa, which exert a profound influence on the evolution of topography, the distribution and amount of rainfall, and thus the efficiency of surface processes. The Kenya Rift is an integral part of the eastern branch of the EARS and is characterized by high-relief rift escarpments bounded by normal faults, gently tilted rift shoulders, and volcanic centers along the rift axis. Considering the Cenozoic tectonic processes in the Kenya Rift, the tectonically controlled cooling history of rift shoulders, the subsidence history of rift basins, and the sedimentation along and across the rift, may help to elucidate the morphotectonic evolution of this extensional province. While tectonic forcing of surface processes may play a minor role in the low-strain rift on centennial to millennial timescales, it may be hypothesized that erosion and sedimentation processes impacted by climate shifts associated with pronounced changes in the availability in moisture may have left important imprints in the landscape. In this thesis I combined thermochronological, geomorphic field observations, and morphometry of digital elevation models to reconstruct exhumation processes and erosion rates, as well as the effects of climate on the erosion processes in different sectors of the rift. I present three sets of results: (1) new thermochronological data from the northern and central parts of the rift to quantitatively constrain the Tertiary exhumation and thermal evolution of the Kenya Rift. (2) 10Be-derived catchment-wide mean denudation rates from the northern, central and southern rift that characterize erosional processes on millennial to present-day timescales; and (3) paleo-denudation rates in the northern rift to constrain climatically controlled shifts in paleoenvironmental conditions during the early Holocene (African Humid Period). Taken together, my studies show that time-temperature histories derived from apatite fission track (AFT) analysis, zircon (U-Th)/He dating, and thermal modeling bracket the onset of rifting in the Kenya Rift between 65-50 Ma and about 15 Ma to the present. These two episodes are marked by rapid exhumation and, uplift of the rift shoulders. Between 45 and 15 Ma the margins of the rift experienced very slow erosion/exhumation, with the accommodation of sediments in the rift basin. In addition, I determined that present-day denudation rates in sparsely vegetated parts of the Kenya Rift amount to 0.13 mm/yr, whereas denudation rates in humid and more densely vegetated sectors of the rift flanks reach a maximum of 0.08 mm/yr, despite steeper hillslopes. I inferred that hillslope gradient and vegetation cover control most of the variation in denudation rates across the Kenya Rift today. Importantly, my results support the notion that vegetation cover plays a fundamental role in determining the voracity of erosion of hillslopes through its stabilizing effects on the land surface. Finally, in a pilot study I highlighted how paleo-denudation rates in climatic threshold areas changed significantly during times of transient hydrologic conditions and involved a sixfold increase in erosion rates during increased humidity. This assessment is based on cosmogenic nuclide (10Be) dating of quartzitic deltaic sands that were deposited in the northern Kenya Rift during a highstand of Lake Suguta, which was associated with the Holocene African Humid Period. Taken together, my new results document the role of climate variability in erosion processes that impact climatic threshold environments, which may provide a template for potential future impacts of climate-driven changes in surface processes in the course of Global Change.}, language = {en} } @phdthesis{Pingel2015, author = {Pingel, Heiko}, title = {Mountain-range uplift \& climate-system interactions in the Southern Central Andes}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-82301}, school = {Universit{\"a}t Potsdam}, pages = {xii, 178}, year = {2015}, abstract = {Zwei h{\"a}ufig diskutierte Aspekte der sp{\"a}tk{\"a}nozoischen Gebirgsbildung der Anden sind der Zeitpunkt sowie die Art und Weise der Heraushebung des Puna-Plateaus und seiner Randgebiete innerhalb der Ostkordillere und die damit verbundenen klimatischen {\"A}nderungen in NW Argentinien. Die Ostkordillere trennt die Bereiche des endorheischen, ariden Plateaus von semiariden und extern entw{\"a}sserten intermontanen Becken sowie dem humiden Andenvorland im Osten. Diese Unterschiede verdeutlichen die Bedeutung der {\"o}stlichen Flanken der Anden als orografische Barrieren gegen{\"u}ber feuchten Luftmassen aus dem Osten und spiegelt sich auch in ausgepr{\"a}gten Relief- und Topografiegradienten, der Niederschlagsverteilung, und der Effizienz von Oberfl{\"a}chenprozessen wider. Obwohl das {\"u}bergeordnete Deformationsmuster in diesem Teil der Anden eine ostw{\"a}rts gerichtete Wanderung der Deformationsprozesse im Gebirge indiziert, gibt es hier keine klar definierte Deformationsfront. Hebungsvorg{\"a}nge und die damit im Zusammenhang stehenden Sedimentprozesse setzen r{\"a}umlich und zeitlich sehr unterschiedlich ein. Zudem gestalten periodisch wiederkehrende Deformationsereignisse innerhalb intermontaner Becken und diachrone Hebungsvorg{\"a}nge, durch Reaktivierung {\"a}lterer Sockelstrukturen im Vorland, eine detaillierte Auswertung der r{\"a}umlich-zeitlichen Hebungsmuster zus{\"a}tzlich schwierig. Die vorliegende Arbeit konzentriert sich haupts{\"a}chlich auf die tektonische Entwicklung der Ostkordillere im Nordwesten Argentiniens, die Ablagerungsgeschichte ihrer intermontanen Sedimentbecken und die topografische Entwicklung der Ostflanke des andinen Puna-Plateaus. Im Allgemeinen sind sich die Sedimentbecken der Ostkordillere und der angrenzenden Provinzen, den Sierras Pampeanas und der Santa B{\´a}rbara Region, den durch St{\"o}rungen begrenzten und mit Sedimenten verf{\"u}llten Becken der hochandinen Plateauregion sehr {\"a}hnlich. Deutliche Unterschiede zur Puna bestehen aber dennoch, denn wiederholte Deformations-, Erosions- und Sedimentationsprozesse haben in den intermontanen Becken zu einer vielf{\"a}ltigen Stratigrafie, {\"U}berlagerungsprozessen und einer durch tektonische Prozesse und klimatischen Wandel charakterisierten Landschaft beigetragen. Je nach Erhaltungsgrad k{\"o}nnen in einigen F{\"a}llen Spuren dieser sediment{\"a}ren und tektonischen Entwicklung bis in die Zeit zur{\"u}ckreichen, als diese Bereiche des Gebirges noch Teil eines zusammenh{\"a}ngenden und unverformten Vorlandbeckens waren. Im Nordwesten Argentiniens enthalten k{\"a}nozoische Sedimente zahlreiche datierbare und geochemisch korrelierbare Vulkanaschen, die nicht nur als wichtige Leithorizonte zur Entschl{\"u}sselung tektonischer und sediment{\"a}rer Ereignisse dienen. Die vulkanischen Gl{\"a}ser dieser Aschen archivieren außerdem Wasserstoff-Isotopenverh{\"a}ltnisse fr{\"u}herer Oberfl{\"a}chenwasser, mit deren Hilfe - im Vergleich mit den Isotopenverh{\"a}ltnissen rezenter meteorischer W{\"a}sser - die r{\"a}umliche und zeitliche Entstehung orografischer Barrieren und tektonisch erzwungene Klima- und Umweltver{\"a}nderungen verfolgt werden k{\"o}nnen. Uran-Blei-Datierungen an Zirkonen aus den vulkanischen Aschelagen und die Rekonstruktion sediment{\"a}rer Pal{\"a}otransportrichtungen im intermontanen Humahuaca-Becken in der Ostkordillere (23.5° S) deuten an, dass das heutige Becken bis vor etwa 4.2 Ma Bestandteil eines gr{\"o}ßtenteils uneingeschr{\"a}nkten Ablagerungsbereichs war, der sich bis ins Vorland erstreckt haben muss. Deformation und Hebung {\"o}stlich des heutigen Beckens sorgten dabei f{\"u}r eine fortschreitende Entkopplung des Entw{\"a}sserungsnetzes vom Vorland und eine Umlenkung der Flussl{\"a}ufe nach S{\"u}den. In der Folge erzwang die weitere Hebung der Gebirgsbl{\"o}cke das Abregnen {\"o}stlicher Luftmassen in immer {\"o}stlicher gelegene Bereiche. Zudem k{\"o}nnen periodische Schwankungen der hydrologischen Verbindung des Beckens mit dem Vorland im Zusammenhang mit der Ablagerung und Erosion m{\"a}chtiger Beckenf{\"u}llungen identifiziert werden. Systematische Beziehungen zwischen Verwerfungen, regionalen Diskontinuit{\"a}ten und verstellten Terrassenfl{\"a}chen verweisen außerdem auf ein generelles Muster beckeninterner Deformation, vermutlich als Folge umfangreicher Beckenerosion und damit verbundenen {\"A}nderungen im tektonischen Spannungsfeld der Region. Einige dieser Beobachtungen k{\"o}nnen anhand ver{\"a}nderter Wasserstoff-Isotopenkonzentrationen vulkanischer Gl{\"a}ser aus der k{\"a}nozoischen Stratigrafie untermauert werden. Die δDg-Werte zeigen zwei wesentliche Trends, die einerseits in Verbindung mit Oberfl{\"a}chenhebung innerhalb des Einzugsgebiets zwischen 6.0 und 3.5 Ma stehen und andererseits mit dem Einsetzen semiarider Bedingungen durch Erreichen eines Schwellenwertes der Topografie der {\"o}stlich gelegenen Gebirgsz{\"u}ge nach 3.5 Ma erkl{\"a}rt werden k{\"o}nnen. Tektonisch bedingte Unterbrechung der Sedimentzufuhr aus westlich gelegenen Liefergebieten um 4.2 Ma und die folgende Hinterland-Aridifizierung deuten weiterhin auf die M{\"o}glichkeit hin, dass diese Prozesse die Folge eines lateralen Wachstums des Puna-Plateaus sind. Diese Aridifizierung im Bereich der Puna resultierte in einem ineffizienten, endorheischen Entw{\"a}sserungssystem, das dazu beigetragen hat, das Plateau vor Einschneidung und externer Entw{\"a}sserung zu bewahren und Reliefgegens{\"a}tze aufgrund fortgesetzter Beckensedimentation reduzierte. Die diachrone Natur der Hebungen und Beckenbildungen sowie deren Auswirkungen auf das Flusssystem im angrenzenden Vorland wird sowohl durch detaillierte Analysen der Sedimentherkunft und Transportrichtungen als auch Uran-Blei-Datierungen im Lerma- und Met{\´a}n-Becken (25° S) weiterhin unterstrichen. Das wird besonders deutlich am Beispiel der isolierten Hebung der Sierra de Met{\´a}n vor etwa 10 Ma, die mehr als 50 km von der aktiven orogenen Front im Westen entfernt liegt. Ab 5 Ma sind typische Lithologien der Puna nicht mehr in den Vorlandsedimenten nachweisbar, welches die weitere Hebung innerhalb der Ostkordillere und die hydrologische Isolation des Angastaco-Beckens in dieser Region dokumentiert. Im Sp{\"a}tplioz{\"a}n und Quart{\"a}r ist die Deformation letztlich {\"u}ber das gesamte Vorland verteilt und bis heute aktiv. Um die Beziehungen zwischen tektonisch kontrollierten Ver{\"a}nderungen der Topografie und deren Einfluss auf atmosph{\"a}rische Prozesse besser zu verstehen, werden in dieser Arbeit weitere altersspezifische Wasserstoff-Isotopendaten vulkanischer Gl{\"a}ser aus dem zerbrochenen Vorland, dem Angastaco-Becken in der {\"U}bergangsregion zwischen Ostkordillere und Punarand und anderer intermontaner Becken weiter s{\"u}dlich vorgestellt. Die Resultate dokumentieren {\"a}hnliche H{\"o}henlagen der untersuchten Regionen bis ca. 7 Ma, gefolgt von Hebungsprozessen im Bereich des Angastaco-Beckens. Ein Vergleich mit Isotopendaten vom benachbarten Puna-Plateau hilft abrupte δDg-Schwankungen in den intermontanen Daten zu erkl{\"a}ren und untermauert die Existenz wiederkehrender Phasen verst{\"a}rkt konvektiver Wetterlagen im Plioz{\"a}n, {\"a}hnlich heutigen Bedingungen. In dieser Arbeit werden gel{\"a}ndeorientierte und geochemische Methoden kombiniert, um Erkenntnisse {\"u}ber die Abl{\"a}ufe von topografiebildenden Deformations- und Hebungsprozessen zu gewinnen und Wechselwirkungen mit der daraus resultierenden Niederschlagsverteilung, Erosion und Sedimentation innerhalb tektonisch aktiver Gebirge zu erforschen. Diese Erkenntnisse sind f{\"u}r ein besseres Verst{\"a}ndnis von Subduktionsgebirgen essentiell, besonders hinsichtlich des Deformationsstils und der zeitlich-r{\"a}umlichen Beziehungen bei der Hebung und Sedimentbeckenbildung. Diese Arbeit weist dar{\"u}berhinaus auf die Bedeutung stabiler Isotopensysteme zur Beantwortung pal{\"a}oaltimetrischer Fragestellungen und zur Erforschung von Pal{\"a}oumweltbedingungen hin und liefert wichtige Erkenntnisse f{\"u}r einen kritischen Umgang mit solchen Daten in anderen Regionen.}, language = {en} }